DOCSLIB.ORG

The Combustion of Carbon-Tetrachloride in a High

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
The Combustion of Carbon-Tetrachloride in a High Louisiana State University LSU Digital Commons LSU Historical Dissertations and Theses Graduate School 1988 The ombuC stion of Carbon-Tetrachloride in a High Temperature Methane-Air Flame Environment. John Samuel Morse Louisiana State University and Agricultural & Mechanical College Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_disstheses Recommended Citation Morse, John Samuel, "The ombusC tion of Carbon-Tetrachloride in a High Temperature Methane-Air Flame Environment." (1988). LSU Historical Dissertations and Theses. 4662. https://digitalcommons.lsu.edu/gradschool_disstheses/4662 This Dissertation is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Historical Dissertations and Theses by an authorized administrator of LSU Digital Commons. For more information, please contact [email protected]. INFORMATION TO USERS The most advanced technology has been used to photo­ graph and reproduce this manuscript from the microfilm master. UMI films the text directly from the original or copy submitted. Thus, some thesis and dissertation copies are in typewriter face, while others may be from any type of computer printer. The quality of this reproduction is dependent upon the quality of the copy submitted. Broken or indistinct print, colored or poor quality illustrations and photographs, print bleedthrough, substandard margins, and improper alignment can adversely affect reproduction. In the unlikely event that the author did not send UMI a complete manuscript and there are missing pages, these will be noted. Also, if unauthorized copyright material had to be removed, a note will indicate the deletion. Oversize materials (e.g., maps, drawings, charts) are re­ produced by sectioning the original, beginning at the upper left-hand corner and continuing from left to right in equal sections with small overlaps. Each original is also photographed in one exposure and is included in reduced form at the back of the book. These are also available as one exposure on a standard 35mm slide or as a 17" x 23" black and white photographic print for an additional charge. Photographs included in the original manuscript have been reproduced xerographically in this copy. Higher quality 6" x 9" black and white photographic prints are available for any photographs or illustrations appearing in this copy for an additional charge. Contact UMI directly to order. University Microfilms International A Bell & Howell Information Company 3 0 0 North Z eeb Road, Ann Arbor, Ml 48106-1346 USA 313/761-4700 800/521-0600 Order Number 8917841 The combustion of carbon tetrachloride in a high temperature methane-air flat dame environment Morse, John Samuel, Ph.D. The Louisiana State University and Agricultural and Mechanical Col., 1988 Copyright ©1988 "by Morse, John Samuel. AI1 rights reserved. 300 N. Zeeb Rd. Ann Arbor, MI 48106 THE COMBUSTION OF CARBON TETRACHLORIDE IN A HIGH TEMPERATURE METHANE-AIR FLAT FLAME ENVIRONMENT A Dissertation submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College in partial fulfillment of the requirements for the degree of Doctor of Philosophy in The Department of Mechanical Engineering by John Samuel Morse B.S.M.E., John Brown University, 1984 December 1988 Copyright © 1988 by John Samuel Morse PREFACE This dissertation is composed of five chapters. The first is an introduction to the subject matter and discusses the motivation for the research project. The second chapter is a comprehensive literature search on fundamental studies of chlorinated hydrocarbon combustion. The third chapter is a description of the experimental facility. It contains a paper submitted to Review of Scientific Instruments that describes one section of the experimental facility. The fourth chapter is composed of two papers that will be submitted to Combustion Science and Technology. These papers contain the experimental data and associated discussion. The chapter ends with a discussion of the net reaction rate analyses performed on the experimental data. Chapter five is a summary, containing conclusions and recommendations. This is followed by a comprehensive list of the references used. The four appendices follow the references. Appendix I describes the procedure used for net reaction rate analysis. Ap­ pendix II describes the algorithm utilized for calculating gas temperature in the flame from measured bead temperatures. Appendix III is a listing of the molecular transport parameters used to calculate transport properties. The molecular transport properties are used in the procedures in Appendices I and n. The fourth appendix is a discussion of the problems encountered in the net reaction rate analysis of Flame 4. The figures and tables accompanying the three journal articles are grouped at the end of each paper, according to the journal's publication guidelines. Figures and tables appearing elsewhere in the dissertation are integrated into the text. iii ACKNOWLEDGEMENTS The author wishes to thank his major professor, Dr. Vic A. Cundy, for introducing him to hazardous waste research and for providing support and guidance throughout his time at LSU. Dr. Thomas W. Lester also provided direction and advice for the author’s research effort. A wealth of practical advice was provided by Dr. Ted Westlake and Ms. Anita Thompson of Dow Chemical Company's Louisiana Division. The author extends thanks to his coworkers in the Incineration Laboratory, without whom this research would not have been possible: Dr. Dwight W. Senser, Dr. David L. Miller, Chris Leger, A1 Montestruc, and Gary Miller. The help of a number of student workers is also much appreciated: Richard Doucet, Craig Ledet, Thomas Harkins, Robert Breaux, and Glynn Eliot Generous fellowship support for the author was provided by the Louisiana State University Alumni Federation and the Mechanical Engineering Department during his stay at LSU, and this is much appreciated. The reasearch effort was underwritten in part by the Hazardous Waste Research Center of Louisiana State University through cooperative agreements No. CR813888 and CR809714010 with the United States Environmental Protection Agency. The author wishes to especially thank his wife, Leah, for her invaluable assistance in the research effort and for her constant support and understanding during their stay at LSU. iv TABLE OF CONTENTS PREFACE........................................................................................................................iii ACKNOWLEDGEMENTS............................................................................................iv TABLE OF CONTENTS........................................................ ........................................ v LIST OF FIGURES..........................................................................................................viii LIST OF TABLES ..................................................................................................... xi ABSTRACT.....................................................................................................................xiii CHAPTER I INTRODUCTION............................................................................ 1 BACKGROUND..................................................................................................1 CURRENT INCINERATION REGULATIONS................................................2 FOCUS OF STUDY.............................................................................................7 CHOICE OF WASTE TO STUDY...................................................................... 11 CHAPTER n SURVEY OF LITERATURE ................................................................13 FLAME INHIBITION STUDIES....................................................................... 13 FLAME STUDIES...............................................................................................15 NON-FLAME STUDIES.....................................................................................22 FLOW REACTOR STUDIES................................................................2 2 SHOCK TUBE STUDIES......................................................................26 MODELING STUDIES.......................................................................................28 SCALE-UP STUDIES........................................................................................ 31 SUMMARY.........................................................................................................33 CHAPTER in EXPERIMENTAL FACILITY AND TECHNIQUES ........................ 36 CHOICE OF EXPERIMENTAL TECHNIQUE................... 36 DESCRIPTION OF FACILITY AND TECHNIQUES......................................39 EXPERIMENTAL FACILITY............................................................... 39 Combustion Chamber. ................................................................. 41 Burner Supply ...............................................................................42 Exhaust Gas Collection and Treatment ........................................ 44 Gas Sampling ............................................................................... 45 Temperature Collection .................................................................47 Burner Translation. ........................................................................49 Spatial Measurements ...................................................................49 Gas Analysis ......................................
Load more

Recommended publications
  • Toxicological Profile for Carbon Tetrachloride
    CARBON TETRACHLORIDE 1 1. PUBLIC HEALTH STATEMENT This public health statement tells you about carbon tetrachloride and the effects of exposure to it. The Environmental Protection Agency (EPA) identifies the most serious hazardous waste sites in the nation. These sites are then placed on the National Priorities List (NPL) and are targeted for long-term federal clean-up activities. Carbon tetrachloride has been found in at least 430 of the 1,662 current or former NPL sites. Although the total number of NPL sites evaluated for this substance is not known, the possibility exists that the number of sites at which carbon tetrachloride is found may increase in the future as more sites are evaluated. This information is important because these sites may be sources of exposure and exposure to this substance may harm you. When a substance is released either from a large area, such as an industrial plant, or from a container, such as a drum or bottle, it enters the environment. Such a release does not always lead to exposure. You can be exposed to a substance only when you come in contact with it. You may be exposed by breathing, eating, or drinking the substance, or by skin contact. If you are exposed to carbon tetrachloride, many factors will determine whether you will be harmed. These factors include the dose (how much), the duration (how long), and how you come in contact with it. You must also consider any other chemicals you are exposed to and your age, sex, diet, family traits, lifestyle, and state of health.
    [Show full text]
  • Carbon Tetrachloride
    CARBON TETRACHLORIDE Data were last reviewed in IARC (1979) and the compound was classified in IARC Monographs Supplement 7 (1987a). 1. Exposure Data 1.1 Chemical and physical data 1.1.1 Nomenclature Chem. Abstr. Serv. Reg. No.: 56-23-5 Chem. Abstr. Name: Tetrachloromethane IUPAC Systematic Name: Carbon tetrachloride Synonyms: Benzinoform; carbona 1.1.2 Structural and molecular formulae and relative molecular mass Cl Cl CCl Cl CCl4 Relative molecular mass: 153.82 1.1.3 Chemical and physical properties of the pure substance (a) Description: Colourless, clear, nonflammable, liquid with a characteristic odour (Budavari, 1996) (b) Boiling-point: 76.8°C (Lide, 1997) (c) Melting-point: –23°C (Lide, 1997) (d) Solubility: Very slightly soluble in water (0.05% by volume); miscible with benzene, chloroform, diethyl ether, carbon disulfide and ethanol (Budavari, 1996) (e) Vapour pressure: 12 kPa at 20°C; relative vapour density (air = 1), 5.3 at the boiling-point (American Conference of Governmental Industrial Hygienists, 1991) (f) Conversion factor: mg/m3 = 6.3 × ppm 1.2 Production and use Production in the United States in 1991 was reported to be approximately 143 thousand tonnes (United States International Trade Commission, 1993). Information –401– 402 IARC MONOGRAPHS VOLUME 71 available in 1995 indicated that carbon tetrachloride was produced in 24 countries (Che- mical Information Services, 1995). Carbon tetrachloride is used in the synthesis of chlorinated organic compounds, including chlorofluorocarbon refrigerants. It is also used as an agricultural fumigant and as a solvent in the production of semiconductors, in the processing of fats, oils and rubber and in laboratory applications (Lewis, 1993; Kauppinen et al., 1998).
    [Show full text]
  • Toxicological Profile for Carbon Tetrachloride
    CARBON TETRACHLORIDE 171 4. CHEMICAL AND PHYSICAL INFORMATION 4.1 CHEMICAL IDENTITY Information regarding the chemical identity of carbon tetrachloride is located in Table 4-1. 4.2 PHYSICAL AND CHEMICAL PROPERTIES Information regarding the physical and chemical properties of carbon tetrachloride is located in Table 4-2. CARBON TETRACHLORIDE 172 4. CHEMICAL AND PHYSICAL INFORMATION Table 4-1. Chemical Identity of Carbon Tetrachloride Characteristic Information Reference Chemical name Carbon tetrachloride IARC 1979 Synonym(s) Carbona; carbon chloride; carbon tet; methane tetrachloride; HSDB 2004 perchloromethane; tetrachloromethane; benzinoform Registered trade name(s) Benzinoform; Fasciolin; Flukoids; Freon 10; Halon 104; IARC 1979 Tetraform; Tetrasol Chemical formula CCl4 IARC 1979 Chemical structure Cl IARC 1979 Cl Cl Cl Identification numbers: CAS registry 56-23-5 NLM 1988 NIOSH RTECS FG4900000 HSDB 2004 EPA hazardous waste U211; D019 HSDB 2004 OHM/TADS 7216634 HSDB 2004 DOT/UN/NA/IMCO UN1846; IMCO 6.1 HSDB 2004 shipping HSDB 53 HSDB 2004 NCI No data CAS = Chemical Abstracts Service; DOT/UN/NA/IMCO = Department of Transportation/United Nations/North America/International Maritime Dangerous Goods Code; EPA = Environmental Protection Agency; HSDB = Hazardous Substances Data Bank; NCI = National Cancer Institute; NIOSH = National Institute for Occupational Safety and Health; OHM/TADS = Oil and Hazardous Materials/Technical Assistance Data System; RTECS = Registry of Toxic Effects of Chemical Substances CARBON TETRACHLORIDE 173 4. CHEMICAL
    [Show full text]
  • Product Stewardship Summary Carbon Tetrachloride
    Product Stewardship Summary Carbon Tetrachloride May 31, 2017 version Summary This Product Stewardship Summary is intended to give general information about Carbon Tetrachloride. It is not intended to provide an in-depth discussion of all health and safety information about the product or to replace any required regulatory communications. Carbon tetrachloride is a colorless liquid with a sweet smell that can be detected at low levels; however, odor is not a reliable indicator that occupational exposure levels have not been exceeded. Its chemical formula is CC14. Most emissive uses of carbon tetrachloride, a “Class I” ozone-depleting substance (ODS), have been phased out under the Montreal Protocol on Substances that Deplete the Ozone Layer (Montreal Protocol). Certain industrial uses (e.g. feedstock/intermediate, essential laboratory and analytical procedures, and process agent) are allowed under the Montreal Protocol. 1. Chemical Identity Name: carbon tetrachloride Synonyms: tetrachloromethane, methane tetrachloride, perchloromethane, benzinoform Chemical Abstracts Service (CAS) number: 56-23-5 Chemical Formula: CC14 Molecular Weight: 153.8 Carbon tetrachloride is a colorless liquid. It has a sweet odor, and is practically nonflammable at ambient temperatures. 2. Production Carbon tetrachloride can be manufactured by the chlorination of methyl chloride according to the following reaction: CH3C1+ 3C12 —> CC14 + 3HC1 Carbon tetrachloride can also be formed as a byproduct of the manufacture of chloromethanes or perchloroethylene. OxyChem manufactures carbon tetrachloride at facilities in Geismar, Louisiana and Wichita, Kansas. Page 1 of 7 3. Uses The use of carbon tetrachloride in consumer products is banned by the Consumer Product Safety Commission (CPSC), under the Federal Hazardous Substance Act (FHSA) 16 CFR 1500.17.
    [Show full text]
  • 13C NMR Study of Co-Contamination of Clays with Carbon Tetrachloride
    Environ. Sci. Technol. 1998, 32, 350-357 13 sometimes make it the equal of solid acids like zeolites or C NMR Study of Co-Contamination silica-aluminas. Benesi (7-9) measured the Hammett acidity of Clays with Carbon Tetrachloride function H0 for a number of clays; these H0 values range from +1.5 to -8.2 (in comparison to H0 )-12 for 100% ) and Benzene sulfuric acid and H0 5 for pure acetic acid). Therefore, one can expect that certain chemical transformations might occur in/on clays that are similar to what are observed in zeolite TING TAO AND GARY E. MACIEL* systems. Thus, it is of interest to examine what happens Department of Chemistry, Colorado State University, when carbon tetrachloride and benzene are ªco-contami- Fort Collins, Colorado 80523 nantsº in a clay. This kind of information would be useful in a long-term view for understanding chemical transforma- tions of contaminants in soil at contaminated sites. Data on 13 these phenomena could also be useful for designing predic- Both solid-sample and liquid-sample C NMR experiments tive models and/or effective pollution remediation strategies. have been carried out to identify the species produced by Solid-state NMR results, based on 13C detection and line the reaction between carbon tetrachloride and benzene narrowing by magic angle spinning (MAS) and high-power when adsorbed on clays, kaolinite, and montmorillonite. Liquid- 1H decoupling (10), have been reported on a variety of organic sample 13C and 1H NMR spectra of perdeuteriobenzene soil components such as humic samples (11-13). Appar- extracts confirm the identities determined by solid-sample ently, there have been few NMR studies concerned directly 13C NMR and provide quantitative measures of the amounts with elucidating the interactions of organic compounds with of the products identifiedsbenzoic acid, benzophenone, and soil or its major components.
    [Show full text]
  • Ozone Depleting Substances
    Ozone Depleting Substances What are they? Ozone depleting substances are chemicals that destroy the earth’s protective ozone layer. They include: • chlorofluorocarbons (CFCs) • halons • carbon tetrachloride (CCl4) • methyl chloroform (CH3CCl3) • hydrobromofluorocarbons (HBFCs) • hydrochlorofluorocarbons (HCFCs) • methyl bromide (CH3Br) • bromochloromethane (CH2BrCl) The use of these chemicals is controlled by the Montreal Protocol on Substances that Deplete the Ozone Layer (the Montreal Protocol). There are other ozone depleting substances, but their ozone depleting effects are very small, so they are not controlled by the Montreal Protocol. One kilogram of halon 1211 can destroy 50 tonnes of ozone What is ozone depleting potential? Ozone depleting potential is a measure of how much damage a chemical can cause to the ozone layer compared with a similar mass What did we use ozone depleting of trichlorofluoromethane (CFC-11). CFC-11, with an ozone depleting potential of 1.0, is substances for? used as the base figure for measuring ozone depletion potential. The higher the number, The main uses of ozone depleting substances the more damage a chemical can cause to include; CFCs and HCFCs in refrigerators and the ozone layer. Bromotrifluoromethane air conditioners, HCFCs and halons in fire (halon -1301) has an ozone depleting potential extinguishers, CFCs and HCFCs in foam, CFCs of 10.0. Carbon dioxide (CO2) is a naturally and HCFCs as aerosol propellants and methyl occurring greenhouse gas, but has an ozone bromide for fumigation of soil, structures and depleting potential of 0. goods to be imported or exported. Have we stopped using ozone Why do we still use some ozone depleting substances? depleting substances? Production of most ozone depleting Some substances with a high ozone depleting substances has been phased out under the potential are still used in quarantine and Montreal Protocol.
    [Show full text]
  • Carbon Tetrachloride Poisoning Patient Education and Care
    Carbon Tetrachloride Poisoning Patient Education and Care Instruction Sheet Overview of Carbon tetrachloride (CCl4) is a manufactured chemical. It Carbon does not occur naturally, but it is present in the Tetrachloride environment because it does not break down very easily and has built up over time from human activities. CCl4 is a clear liquid that evaporates into the air easily. It has a sweet odor that can be smelled at low levels. CCl4 is most often found in the air as a colorless gas. CCl4 is not flammable and does not dissolve very easily in water. CCl4 was previously used • In the production of refrigeration fluid and propellants for aerosol cans, • As a pesticide, • As a cleaning fluid and degreasing agent, • In fire extinguishers, and • In spot removers. Due to the harmful health effects from exposure, consumer uses of CCl4 were discontinued in the mid- 1960s and pesticide uses were stopped in 1986. However, use of older products that might contain CCl4 or use of household cleaning products containing bleach that might produce carbon tetrachloride have been reported since 1986. Only industrial and research uses remain in the United States. How Can Very low levels (called background levels) of CCl4 can be People Be found in Exposed to Carbon • Air, Tetrachloride? • Water, and • Soil. 1 Exposure to levels of CCl4 higher than background levels is likely to occur • At work in specific industrial locations where CCl4 is still used or • Near chemical waste sites where emissions into air, water, or soil are not properly controlled. Some ways that CCl4 can get into the body include • Breathing CCl4 present in the air, • Drinking water or eating food contaminated with CCl4, • Getting CCl4 liquid spilled on skin, or • Getting CCl4 contaminated soil or water on the skin.
    [Show full text]
  • Toxicological Profile for Carbon Tetrachloride
    CARBON TETRACHLORIDE 175 5. PRODUCTION, IMPORT/EXPORT, USE, AND DISPOSAL 5.1 PRODUCTION Carbon tetrachloride is produced by exhaustive chlorination of a variety of low molecular weight hydrocarbons such as carbon disulfide, methane, ethane, propane, and ethylene dichloride (HSDB 2004). It is also produced by thermal chlorination of methyl chloride (HSDB 2004). Carbon tetrachloride is a feedstock for chlorofluorocarbon gases, such as dichlorodifluoromethane (F-12) and trichlorofluoro­ methane (F-11), which were used as aerosol propellants in the 1950s and 1960s (Holbrook 1991). Following this, the growth rate for the production of carbon tetrachloride averaged 10.7% per year from 1960 to 1970 (Holbrook 1991). This rate slowed to 7.2% per year from 1970 to 1974, when the production of this chemical was at its peak, as other forms of propellants became commercially available (Anonymous 1981; Holbrook 1991). The FDA banned the sale of carbon tetrachloride in any product used in the home and the EPA regulated the use of chlorofluorocarbon gases as aerosols or propellants. Since then, production of carbon tetrachloride has declined at approximately 8% a year from 1974 to 1994 (Anonymous 1995; Holbrook 1991). Carbon tetrachloride is currently manufactured in the United States by Vulcan Materials Company at two plants: Geismar, Louisiana and Wichita, Kansas, with a combined 130 million pound capacity (HSDB 2004; SRI 2004). It should be noted, however, that these capacities are flexible, since other chlorinated solvents are made using the same equipment (SRI 2004). This recent decline in production is due to the adoption of an international agreement (the Montreal Protocol) to reduce environmental concentrations of ozone-depleting chemicals (including carbon tetrachloride), and to the provisions of Title VI of the Clean Air Act Amendments of 1990 addressing these chemicals.
    [Show full text]
  • Organo-Transition Metal Chemistry Some Studies
    ORGANO-TRANSITION METAL CHEMISTRY SOME STUDIES IN ORGANO-TRANSITION METAL CHEMISTRY By COLIN CRINDROD, B.Sc. A Thesis Submitted to the Faculty of Graduate Studies in Partial Fulfilment of the Requirements for the Degree Master of Science McMaster University October 1966 MASTER OF SCIENCE (1966) MCMASTER UNIVERSITY (Chemistry) Hamilton, Ontario TITLE: Some Studies in Organo-Transition Metal Chemistry AUTHOR: Colin Grindrod, B.Sc. (Manchester University) SUPERVISOR: Dr. P. M. Maitlis NUMBER OF PAGES: iv, 71 SCOPE AND CONTENTS: The work described is an extension of the ligand-transfer reactions of substituted cyclobutadienes and cyclopentadienyls previously carried out by Maitlis et al. Efforts were directed particularly to ligand­ transfer reactions of n-allyl-transition metal complexes. The reactions of organic halides with metal carbonyls were also studied in attempts to isolate new organometallic derivatives. (ii) ACKNOWLEDGEMENTS The author wishes to express his sincere gratitude for the stimulating advice and constant encouragement provided by Dr. P. M. Maitlis, under whose guidance this work was carried out. Thanks are also extended to Imperial Oil Co. Ltd. for providing the financial support which made this study possible. (iii) CONTENTS Page INTRODUCTION Historical................................... 1 Cyclobutadiene-transition metal oompeeees... 7 Ligand-transfer reactions................... 10 Allyl-transition metal complexes............ 13 Reactions of metal carbonyls with organic halides.... ..................... 25 DISCUSSION
    [Show full text]
  • Carbonyl-Phosphine Hetero-Ligated Half-Metallocene Iron(II) Catalysts for Living Radical Polymerization: Concomitant Activity and Stability
    Polymer Journal (2010) 42, 17–24 & The Society of Polymer Science, Japan (SPSJ) All rights reserved 0032-3896/10 $32.00 www.nature.com/pj INVITED ARTICLE Carbonyl-phosphine hetero-ligated half-metallocene iron(II) catalysts for living radical polymerization: concomitant activity and stability Muneki Ishio, Takaya Terashima, Makoto Ouchi and Mitsuo Sawamoto Two neutral ligands, carbonyl (CO) and phosphine, were cooperatively incorporated into half-metallocene iron(II) complexes (CpFeBr(CO)(PR3); Cp¼C5H5;PR3¼PPh3, P(OPh)3, PMePh2, PMe2Ph, P(n-Bu)3) for more active and versatile systems in transition metal-catalyzed living radical polymerization. For methyl methacrylate (MMA) with a bromide initiator [Me2C(CO2Me)CH2C(Me)-(CO2Me)Br; Me¼CH3] [H-(MMA)2-Br], these hetero-ligated catalysts are superior, in terms of catalytic activity and molecular weight control, to similar homo-ligated half-metallocenes carrying two identical ligands such as CpFeBr(CO)2 and CpFeBr(PR3)2. Among the CpFeBr(CO)(PR3) complexes examined, CpFeBr(CO)(PMePh2) showed the highest activity and the best controllability (490% conversion within 24 h; Mw/Mn¼1.29), and the ‘living’ character of the polymerizations therewith was proved by sequential monomer addition experiments. In spite of the high activity, the Fe(II) complex is stable and robust enough to be handled under air, rendering it suitable for practical use. The concomitant high activity and high stability were attributed to the in situ generation of a real active catalyst with a 16-electron configuration by the irreversible release of the CO group from CpFeBr(CO)(PR3) on the activation of a terminal C–Br bond, as confirmed by the Fourier transform infrared monitoring of model reactions with the initiator as a dormant-end model compound.
    [Show full text]
  • Carbon Tetrachloride Standard
    Page 1/10 Safety Data Sheet acc. to OSHA HCS Printing date 03/28/2019 Version Number 3 Reviewed on 03/28/2019 * 1 Identification · Product identifier · Trade name: Carbon Tetrachloride Standard (1X1 mL) · Part number: HC-040-1 · Application of the substance / the mixture Reagents and Standards for Analytical Chemical Laboratory Use · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Agilent Technologies, Inc. 5301 Stevens Creek Blvd. Santa Clara, CA 95051 USA · Information department: Telephone: 800-227-9770 e-mail: [email protected] · Emergency telephone number: CHEMTREC®: 1-800-424-9300 * 2 Hazard(s) identification · Classification of the substance or mixture GHS02 Flame Flam. Liq. 2 H225 Highly flammable liquid and vapor. GHS06 Skull and crossbones Acute Tox. 3 H331 Toxic if inhaled. GHS08 Health hazard STOT SE 1 H370 Causes damage to organs. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS02 GHS06 GHS08 · Signal word Danger · Hazard-determining components of labeling: methanol · Hazard statements Highly flammable liquid and vapor. Toxic if inhaled. Causes damage to organs. (Contd. on page 2) US 48.1.26 Page 2/10 Safety Data Sheet acc. to OSHA HCS Printing date 03/28/2019 Version Number 3 Reviewed on 03/28/2019 Trade name: Carbon Tetrachloride Standard (1X1 mL) (Contd. of page 1) · Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge.
    [Show full text]
  • Toward Resolving the Budget Discrepancy of Ozone-Depleting Carbon Tetrachloride (Ccl4): an Analysis of Top-Down Emissions from China
    Atmos. Chem. Phys., 18, 11729–11738, 2018 https://doi.org/10.5194/acp-18-11729-2018 © Author(s) 2018. This work is distributed under the Creative Commons Attribution 4.0 License. Toward resolving the budget discrepancy of ozone-depleting carbon tetrachloride (CCl4): an analysis of top-down emissions from China Sunyoung Park1,2, Shanlan Li2,3, Jens Mühle4, Simon O’Doherty5, Ray F. Weiss4, Xuekun Fang6, Stefan Reimann7, and Ronald G. Prinn6 1Department of Oceanography Kyungpook National University, Daegu 41566, Republic of Korea 2Kyungpook Institute of Oceanography Kyungpook National University, Daegu 41566, Republic of Korea 3Climate Research Division, National Institute of Meteorological Sciences, Seogwipo, Korea 4Scripps Institution of Oceanography, University of California, San Diego, La Jolla, CA 92093, USA 5School of Chemistry, University of Bristol, Bristol, UK 6Center for Global Change Science, Massachusetts Institute of Technology, Cambridge, MA 02139, USA 7Empa, Laboratory for Air Pollution and Environmental Technology, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, 8600 Dübendorf, Switzerland Correspondence: Sunyoung Park ([email protected]) Received: 1 March 2018 – Discussion started: 12 March 2018 Revised: 17 July 2018 – Accepted: 22 July 2018 – Published: 17 August 2018 Abstract. Carbon tetrachloride (CCl4) is a first-generation and better regulation strategies to reduce evaporative losses ozone-depleting substance, and its emissive use and produc- of CCl4 occurring at the factory and/or process levels. tion were globally banned by the Montreal Protocol with a 2010 phase-out; however, production and consumption for non-dispersive use as a chemical feedstock and as a process 1 Introduction agent are still allowed. This study uses the high frequency and magnitude of CCl pollution events from an 8-year real- 4 Carbon tetrachloride (CCl4) is a long-lived greenhouse gas time atmospheric measurement record obtained at Gosan sta- and an ozone-depleting substance.
    [Show full text]