Speed of Sound in Water by a Direct Method 1 Martin Greenspan and Carroll E
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Journal of Rese arch of the National Bureau of Standards Vol. 59, No.4, October 1957 Research Paper 2795 Speed of Sound in Water by a Direct Method 1 Martin Greenspan and Carroll E. Tschiegg The speed of sound in distilled water wa,s m easured over the temperature ra nge 0° to 100° C with an accuracy of 1 part in 30,000. The results are given as a fifth-degree poly nomial and in tables. The water was contained in a cylindrical tank of fix ed length, termi nated at each end by a plane transducer, and the end-to-end time of flight of a pulse of sound was determined from a measurement of t he pulse-repetition frequency required to set the successive echoes into t im e coincidence. 1. Introduction as the two pulses have different shapes, the accurac.,' with which the coincidence could be set would be The speed of sound in water, c, is a physical very poor. Instead, the oscillator is run at about property of fundamental interest; it, together with half this frequency and the coincidence to be set is the density, determines the adiabatie compressibility, that among the first received pulses corresponding to and eventually the ratio of specific heats. The vari a particular electrical pulse, the first echo correspond ation with temperature is anomalous; water is the ing to the electrical pulse next preceding, and so on . only pure liquid for which it is known that the speed Figure 1 illustrates the uccessive signals correspond of sound does not decrcase monotonically with ing to three electrical input pul es. The input pulses temperature. fall halfway between the pulses for which the coinci There is also a practical interest in c in that water dence is set, so that they do not tend to overload is used as a standard liquid for the calibration of the amplifier or distort the oscill oscope traces. The instruments that measure the speed of sound in period of the oscillator, when properly se t, multi liquids automatically, both in the laboratory and in plied by twice the length of Ul e tank, is the speed of the field. In fact, it was in connection with the cali sound in the sample. bration of such "velocimeters" [1] 2 that our interest The oscilloscope trace actually looks like that in this work was first aroused. In the first place, shown in the in se t (fig. 1). The firs t cycle corre the available data scatter widely, as recent sum sponds to sound reHected from the inner faces only maries [2 , 3] clearly show. In many cases, the di s of the transducers, whereas the succeeding cycle crepancies far exceed the claimed accuracy or at correspond to sound reflected. one or more times from least the precision of the methods, even when the an outer face. Therefore, the coincidence is set by methods compared are the same. In the second maximizing the peak on eitllcr the first or second place, there exists no set of data that gives a smooth balf-cycle; the same result is obtained in either case variation with temperature over any considerable but the second half cycle is easier to use because it range. In particular, the best of these data yield is bigger. What we are mea uring h ere is the speed calibration curves for OUT velocimeters which are corresponding to the fi1" t arrival of the signal ; in a badly curved instead of straight (as they should be), nondispersive liquid this is the same as the phase and about which the data scatter irregularly, but velocity. It is true that the coin cidence is made at a reproducibly. The results here presented are free of these objections. 2. Method At the top of figure 1 is a schematic of the appa ratus. The sample is confined in a tube of which the ends are plane, parallel, electroacoustic trans ducers, quartz crystals in this case. If the left-hand crystal, say, is excited by a short pulse from the blocking oscillator, the oscilloscope, which measures the voltage on tne right-hand crystal, will show a received pulse and a series of echoes, as indicated n in idealized form on the line below (fig. 1). The pulse repetition frequency of the blocking oscillator is controlled by a sine-wave oscillator, and if this I frequency were adjusted so that each blocking oscil n lator pulse coincided with the first received pulse of the next preceding cycle, then the oscillator period I ~I would equal the time of flight of the pulse. However, n FIGURE 1. Schematic of method. I 1'bis work was supported in part by the Omce of Naval R esearch under contract NA-oTU"-7<J-4S. 'fhe three lower lines show in idealized form the events co rresponding to three , Figures in brackets indicate the literature referen ces at the end of this paper. sneccssh'e electri cal pulses. The short , thick line represents Lhe input pulse. 249 ' Lime one-fourth or three-quarters of the transducer period later Lhan the til!le o~ first arrival, by. which time there is opportumty for sOlll;d travclmg .by paths other than the shortest to affect the 10e~ t JOn of the maximum. However, the results are lllde pendent of whether til e first or second half c'y cl ~ is used · they are also not affected by substltutmg crystals of twice the thickness, or by changing the diameters of tlle tank, or of the hot electrodes. These results lead us to believe that the error introduced by this maximization technique is negligible. The question has been examined also in another way. Suppose a coin cidence to have been mac~e at frequency j; others can then be ma.de at submultlJ?les of j. At the frequency / /2 for lI1 stan?e, the. first received pulse correspondmg to a partIcular mput FIGUR E 2. Delay line, disassembled. pulse coincides with the second echo (not the first, Above tbe tank are tbe plugs whicb close the filling holes. and at the ends are tbe caps tbrougb which pass the electri cal cables and wblcb also clam p t he as before) corresponding to the electrical pulse next crystals seen in the foreg round. preceding, and so on. Effectively, the sOllnd pul~ e is timed over a path twice as long as before. It IS found that the measurements at j and ncar j /2 are substantially id entical, so that the error in question is less than, or at most comparable to, the expen mental error of the time meaS llrement. 3 . Appar a tus 3 .1. The Delay Line The disassembled delay line is shown in the photo graph, figure 2. The length of the tank i s about 200 mm, and the bore about 13 mm. The filling holes are sealed by plugs having T eflon gaskets; a small hole in one plug provides pressure.r elease. The tank is of a chromium steel 3 which, after heat treatmen t, takes a good optical fini sh. Because this steel is not so corrosion r esistant as the nickel chromium stainless steels, the bore of the tank was heavily gold plated. The ends of the tank are optically flat and parallel to within less than 1 f.1. To these ends are carefully wrung the 0.8-mm thick x-cut quartz crystals, which also are optically flat. The caps, when bolted on, clamp the crystals through neoprene O-rings. A FIGURE 3. Schematic oj one end of the tank, showing th e crystal coaxial cable passes through a seal in each cap, and and cap assembly. the center conductor makes contact with the outer 1. 'rank; 2. cap; 3. pl ug sealed with Teflon O-ring (thermocouple pasSf'S t hro ugh pressure relief tu be); 4. quartz crystal wrun g on to end of tank (springs (hot) electrode of the crystal through a light spring. make conta ct to electrodes) ; 5, neoprene O·ring; and 6, coaxial cable. The outer electrode is a 9 mm circle of aluminum backed pressure-sensitive adhesive tape. The inner was th e tank and heat-treated together with it. (ground) electrode is of fired-on gold and is about From these data, the length of the sound path is 12 mm in diameter. Contact is made through a known to better than 2 parts in 105 at any tempera light gold-plated helical spring which touches the ture between 0° and 100 0 C. It is, of course, electrode around the edge and bears on a shoulder necessary that the crystals be wrung down with machined into the bore. The inner electrodes and great care so that the fringes disappear all around springs are unnecessary if the sample has high con the periphery, to achieve this accuracy. The clamp ductivity or a high dielectric constant; they are ing gaskets must bear direc tly over the contacting usually omitted for water and aqueous solutions of surface and not spread out over the unsupported salts. Figure 3 is a schematic drawing of one end area, else the crystal will benel. With these pre of the assembly. cautions, the delay line may be disassembled and The length of the tank was measured at 20° C, reassembled repeatedly with reproducible results. and the coefficient of thermal expansion of the steel If the crystals have been properly wTung on and was measured on a sample cut from the same bar as clamped, they cannot be removed by hand after 3 F irtb-Sterling typelB-440A.