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CANADA

VERMONT Lake Ontario

Lake Erie MASSACHUSETTS

PENNSYLVANIA CONNECTICUT

Oswego Oneida

River OSWEGO COUNTY River

Oneida Lake Seneca

Seneca River Cross River

Cross Lake Lake

SYRACUSE Ninemile Creek Green Lake FAYETTEVILLE

ONONDAGA COUNTY

Skaneateles MADISON COUNTY

CAYUGA COUNTY CAYUGA Otisco Lake

Lake

CORTLAND COUNTY

Source: Exponent, 2001c

Figure 1-1. Location of Onondaga Lake S Creek e c a r l n e R e il i v m w Lake Outlet a S

Liverpool ,'90

k o ro B dy o Mattydale lo Onondaga B Lakeland Lake Galeville

k e N e inem r ile C Cr y eek 690 e ,' L

Wes t F T lum r e ib k u o ta o r Onondaga Creek r y M B 5 A e s tr e o Unnamed Creek d d East Flume e H G ar bo Syracuse Solvay r B 695 ro ,' o k

Fairmount

k o o r Westvale B

r bo ar H ,'81

LEGEND

River or brook River or brook (below grade) Major road Minor road 0 1 2 Miles 0 1 2 3 Kilometers Source: NYSDOT (no date) Modified from Exponent, 2001c

Figure 1-2. Onondaga Lake Area Tributaries and Roads LEGEND Creek a Approximate Location Sawmill and Extent Lake Outlet

LIVERPOOL

Brook

Bloody O n o n d a g a L a k e GALEVILLE Dredge Spoils Areaa

LAKELAND

Creek

Ninemile Creek Ley

Former Willis Brook In-lake West Avenue Plant Semet Waste SYRACUSE East Deposita Flume Residue Flume Ponds Tributary Onondaga

Geddes 5A Creek

Metro

Former Mathews LCP Bridge Main Plant Brook Ave. Harbor Landfill Street Facility Willis Avenue 0 2000 4000 6000 Ballfield Site SOLVAY feet Wastebed B/ meters Harbor Brook Site 0 1000 2000 Source: Modified from Exponent, 2001c

Figure 1-3. Locations of Former Facilities and Referenced Disposal Areas near Onondaga Lake ƒene™—2‚iver v—ke2yutlet ƒ‰‡EIW E2x‰ƒhig22‡etl—nd ƒ‰‡ET

w—rin—2 hredge2ƒpoils f—sin ƒt—te2 xinemile2greek p—irgrounds ƒ‰‡EIH €—rking xy‚„ri‚x2feƒsx gl—ss2f

ƒt—te2 p—irgrounds ‡—ter2 se2gl—ssifi™—tion2found—ry

„ri˜ut—ry2Se ƒy „ri‚x2feƒsx vey2greek ƒemet2€onds gl—ss2g ƒ‰‡EIP ‡illis2eve2 i—st2plume €l—nt2ƒite

‡illis2eve2 FTWH f—llfield2ƒite DE r—r˜or2frook2ƒite‡—ste˜ed2fG g—rousel2w—ll ynond—g—2greek

r—r˜or2frook wi„‚y ƒ‰‡EIW

pigure2IER ynond—g—2v—ke2‚s ynond—g—2v—ke2—nd2†i™inity xoteX2figure2not2to2s™—le 1653 - Simon LeMoyne visits Onondaga Lake 1650

1750

1786 - Ephraim Webster establishes trading post at the mouth of Onondaga Creek 1794 - Salt manufacturing begins 1800 1817 - Population of Onondaga Lake area reaches 30,000 1822 - Lake level lowered to elevation of Seneca River during construction of barge canal 1848 - Population of Onondaga Lake area reaches 60,000 1850

1896 - City of Syracuse installs combined sanitary and stormwater sewers that discharge untreated waste 1884 - Company begins production of to Onondaga Creek and Harbor Brook soda ash 1900 - Population of Onondaga Lake area reaches 160,000 1900 1901 - Ice harvesting prohibited because of sewage contamination

1917 - Honeywell begins production of benzene, toluene, 1918 - Honeywell begins production of chlorine and and other compounds from distillation of coal chlorinated benzenes 1925 - City of Syracuse begins sewage treatment 1918 - Honeywell opens Willis Avenue chlor-alkali plant 1938 - Disposal of Honeywell waste into Onondaga Lake (non-mercury cell) ongoing in the vicinity of Wastebed B Prior to 1947 - Honeywell adds mercury cell to 1950 Willis Avenue chlor-alkali plant 1953 - Honeywell opens mercury cell chlor-alkali plant at Bridge Street 1960 1960 - Metro sewage treatment plant built

1970 - Fishing banned in Onondaga Lake because of 1970 1970 - Honeywell reduces plant effluent mercury loading mercury contamination from 21 to 1 lbs per day as stipulated in an August 1970 consent order 1970 - Honeywell closes BTX plant

1974 - Honeywell receives SPDES permit with total allowable loading of mercury to the lake set at 1.38 lbs per day 1977 - Honeywell closes chlorinated benzene plant 1977 - Honeywell closes Willis Avenue chlor-alkali plant and further reduces Bridge Street chlor-alkali process waste mercury loading to 0.028 lbs per day 1979 - Honeywell sells Bridge Street chlor-alkali plant to 1980 LCP 1981 - Solvay settling basin overflow directed to Metro

1985 - Phase I of the Onondaga County Combined Sewer 1986 - Catch and release fishing allowed in Onondaga Lake Overflow abatement program completed 1986 - Honeywell closes soda ash manufacturing operations

1988 - LCP closes Bridge Street chlor-alkali plant

1989 - State files Onondaga Lake suit against Honeywell 1990 - Phase II of the Onondaga County combined sewer 1990 overflow abatement program completed

1992 - AlliedSignal signs consent decree for Onondaga Lake RI/FS

1998 - AlliedSignal and NYSDEC sign amended consent decree for Onondaga Lake RI/FS

1999 - Fishing advisory amended to restricted consumption 2000 Source: Modified from Exponent, 2001c

Figure 1-5. Significant Events in the History of Onondaga Lake 1870 1880 1890 1900 1910 1920 1930 1940 1950 1960 1970 1980 1990

18,000 TPY 135,000 TPY 652,000 TPY New Plant 260,000 TPY 983 ,000 TPY Soda Ash New Plant Refined bicarbonate of soda

New Plant Snowflake (sodium sesquicarbonate) Process Changes Sodium nitrite

New Plant Ammonium bicarbonate

New Plant Ammonium chloride

New Plant Calcium chloride

Caustic soda

Chlor-alkali Prior to 1947 Diaphragm Cells Mercury Cells added Caustic soda (Willis Avenue) Diaphragm Cells Mercury Cells added Caustic soda (Bridge Street) Prior to 1947 KOH Plant On-Line Mercury Cells added Caustic potash (Willis Avenue)

Chlorine

New Plant Potassium carbonate

Potassium bicarbonate

BTX/Chlorinated Benzenes

Benzene, toluene, and xylene

Dichlorobenzene Separation Chlorinated benzenes

Hydrochloric acid

Note: TPY = tons per year

Source: Modified from Exponent, 2001c

Figure 1-6. Periods of Production and Production Milestones for Major Product Lines at the Syracuse Works Creek

Lake Sawmill Outlet

LIVERPOOL

O n o n d a g a L a k e Bloody Brook GALEVILLE LAKELAND

6 5

4 11 3 Creek 9-10 Ley Ninemile Creek 8 2 L

Geddes 13 7 1 12 West Flume SYRACUSE Brook 14 Tributary 5A H 15 A Onondaga

Metro C B East Creek K

Flume Harbor G F Brook J SOLVAY E M D I

0 2000 4000 6000 feet meters 0 1000 2000

Source: Blasland & Bouck (1989) Modified from Exponent, 2001c

Figure 1-7. Historical Locations of Solvay Wastebeds