Lone Star Chemistry Soluons

Lone Star Chemistry Soluons iBook: hps://itunes.apple.com/us/book/lone-star-chemistry-soluons/id635036317?mt=11 Abstract Calling all nave Texans and those who got here as fast as you could! A notable bull rider once said, "It ain't braggin', if it's true!" This class explores the facts, ficon, and folklore of Texas as they relate to the study of chemistry. The stories imparted serve to make chemistry engaging and you'll get to leave with all the bragging rights that make Texas and Texans extraordinary. We do get to have our cake and eat it, too! What Startd in Texas Has Changed te World Part I

Emeritus College Spring 2015

Diana Mason, PhD, ACSF (rered) Professor Emeritus, Department of Chemistry University of North Texas April 14, 2015

Introducon

• Interests – Research – Chemistry Educaon – Teaching – Chemistry – Service – Chemical Demonstraons; Teacher PD • Passion – Texas history – facts, ficon, and folklore

Schedule

• April 14: Texas on the World’s Stage • April 16: Early Statehood • April 21: 1880s to the Moon (Celebraon!) • April 23: Texas Today

Texas Enters the World’s Stage 1. Braggin’ or True? Flags over Texas • Spain • France • 3 Nacogdoches flags • Mexico • Republic of Texas • Republic of Rio Grande • Confederate States of America • United States Spain’s Flag over Texas

Flew over Texas from 1529 to 1684 France’s Flag over Texas

Flew over Texas 1684 to 1689 Fort Saint Louis

Fort St. Louis

• French colony established 1685 – Near present-day Arenosa Creek and Matagorda Bay – By explorer Robert Cavelier de la Salle • Intended to sele: mouth of Mississippi River • Colony survived unl 1688 – Inez, Texas later developed here Houston County

San Francisco de la Espada

• 1689: First mission within the boundaries of – Between Trinity and Red Rivers near Augusta in Houston County • Spanish authories found remnants of French selement – Fort St. Louis • The mission was reestablished on July 3, 1716, as Nuestro Padre San Francisco de los Tejas – In 1721, renamed Mission San Francisco de los Neches – In 1731, moved to Rivers of Texas

Nacogdoches Spain’s Flag over Texas

Flew over Texas from 1690 to 1821 United States & Territories 1783-1853 East Texas: Caddo Selement

• Evidence of selement dates back 10,000 years • Village: Nacogdoche tribe – Existed unl the 19th Century Natchitoches and Nacogdoches

• Selement on Sabine • Chief Caddo’s twin boys: Natchitoches and Nacogdoches • Chief was near death and his sons needed to be split • Chief told one to walk three days towards the morning sun and the other to walk three days towards the seng son – About 100 miles between Nine Flags over the City of Nacogdoches

Guérrez-Magee Expedion 1812-1813 Dr. James Long Expedion 1819 -1821 Fredonia Rebellion 1826 -1827 Mexico’s Flag over Texas

Flew over Texas 1821 through 1836. • 1820: People from the U.S. began moving here • Published the first English-language newspaper • 1832: Bale of Nacogdoches – Brought many local selers together – United to support a federalist form of government – Successful venture drove Mexican military from east Texas

Nacogdoches Co.

Huntsville seled in 1836. Walker Co. Old Stone Fort Nacogdoches, TX

Gateway from the U.S. to the Texas froner. The Republic of Texas Texas was an independent Republic from 1836-1845.

First Flag Second Flag: Burnet (1836-1839)

August 31, 1933 (originally adopted on January 25, 1839, de facto use between 1879-1933) Proper Vertical Display Republic of Rio Grande • Existed from January 17 – November 6, 1840 • Centered in the city of Laredo, its capital

Webb County

Only the area around Laredo, Texas is considered to have been under 7 flags! Treaty with the United States Failed (Flag with 28 stars approved July 4, 1846)

Texas entered the U.S. December 29, 1845 by Annexation. Texas Honor Day

• February 19

• Texas Statehood Day – Joined U.S. on December 29, 1845 – February 19, 1846: Official end of The Republic • Two governments (Republic and State) existed from December 29, 1845 to February 19, 1846

Confederate States of America

The First National CSA Battle Flag "The Stars and Bars” "The Southern Cross” (March 4, 1861 - May 1, 1863) (November 1861 - present) Reconstrucon & Today

U.S. flag of 1867 13 stripes = 13 original Today’s U.S. Flag. colonies 13 stripes = 13 original colonies 36 stars = 36 states 50 stars = 50 states 2. Braggin’ or True? Mexico’s Flag over Texas

Flew over Texas 1821 through 1836. Father of Texas: Moses or Stephen F. Ausn?

Moses Ausn

Moses received permission from the Mexican government to bring the first selers to Coahuila y Tejas Father of Texas: Stephen F. Ausn • Stephen F. brought the original families now known as the Old Three Hundred. – Seled by summer of 1824 in San Felipe

• Ausn's Colony was the first legal selement San Felipe of North American families in Mexican-owned Texas.

Main area of Ausn's Colony: bounded by the Lavaca and San Jacinto rivers, the San Antonio Road, and the coast.

A small selement, called the "lile colony," was also established along the Colorado River above the San Antonio Road, near the present-day city of Ausn. Texas Honor Day

• November 3

• Stephen F. Ausn’s birthday – November 3, 1793 Capital: San Felipe de Ausn

Town Hall

Original water well. • West bank of the Brazos River • Social, economic, and polical center of the colony • Founding spot of the Texas Rangers (August 1823) – Term "Texas Ranger" did not appear officially in a piece of legislaon unl 1874 • Home to the first post office and one of the earliest newspapers and land offices in Texas • Capital for the provisional government of Texas unl the Convenon of 1836 – Burned in 1836 to prevent the Mexican army from capturing it Selement’s Land Rights

• Married heads of families – receive at least one labor (177 acres) if farmed – one league (4,428 acres) if they raised stock • Virtually every man—whether doctor, nsmith, or blacksmith—listed his occupaon as farmer and stock raiser to receive the maximum amount of land at 12.5 cents per acre. Constuon of 1824 Flag

AKA the Alamo Flag, 1836 Silver

Fredericksburg

• In 1831, Stephen F., while trying to recruit more colonists – Published in a promoonal booklet with one of the legends associated with Enchanted Rock of Llano County (north of Fredericksburg). – Enchanted Rock (Llano County) hosts a lost silver mine or the lost El Dorado gold mine. State Precious Metal: Silver

• Named the official precious metal by the 80th Legislature in 2007. Texas Honor Day

• 3rd Saturday in September

• Texas Navy Day – Official Navy of the Republic of Texas – In 1835 the Texian privateer (armed ship), the San Felipe, and a Mexican schooner, the Correo, baled and the Mexican ship forced to uncondional surrender October 2, 1835 (Bale of Gonzales) Texas Honor Day

• October 2

• Gonzales Day – October 2, 1835 – Bale of Gonzales: War begins Washington-on-the-Brazos March 2, 1836: Sam Houston’s birthday and signing of the Declaraon of Independence.

Washington-on-the-Brazos Texas Honor Day

• March 2

• Texas Independence Day – March 2, 1836 3. Braggin’ or True? Battle of the Alamo (San Antonio, Texas)

Dr. Diana’s Uncle!

William Barret Travis 1809-1836 Commander-in-Chief Alamo fell on March 6, 1836 Santa Anna: 1600-2400 troops Alamo: 189 troops Irish at the Alamo

• Renowned Author James Michener once said "The Irish gave Texas its basic character.” • Of the 189 men that fought and died at the Alamo, 29 are known to be from the United Kingdom: England, Wales, Scotland and Ireland. – "...The largest proporon of defenders were foreign immigrants from the United Kingdom.” – 13 were born in Ireland Texas Honor Day

• March 6

• Alamo Heroes Day – March 6, 1836: Fall of the Alamo Ireland Kilkenny, Ireland

Don’t Mess with Texas!

Restaurant Limerick, Ireland Durt Nely’s Bunraty, Ireland and San Antnio

Bunray Castle is a large 15th century tower house in County Clare, Ireland. It is located in the center of Bunray village, between Limerick and Ennis, near Shannon Town and its airport. Durty Nelly’s in San Antonio is a piano bar! Alamo Heroes’ Marble Tomb San Fernando Cathedral, San Antonio, Texas

Herein lie the remains of David Crocke, , and William Barret Travis.

Is it possible that Crocke escaped?

Plaque in Kentucky

David Crocke

• U.S. House of Representaves from Tennessee’s 9th District and two years later from the 12th District • “You can go to hell, I’m going to Texas!” • Died, March 6, 1836 at the Fall of the Alamo? David Crocke • Colonel Jose Enrique de la Pena, officer in Santa Anna's army – Crocke was captured with a handful of others and executed. • (several interviews) – Saw Crocke’s body between the chapel and the barracks – Same as the account of Francisco Antonio Ruiz, Mayor of San Antonio • Another account – David Crocke gave Fellow Mason, Santa Anna, the sign of distress and his life was spared. – Family in Alabama aests they have a land deed signed by Crocke in the 1850s, but the signature has never been verified. James Bowie

• Born ca. 1796, – Logan County, Kentucky • Land speculator • Rank, Colonel – Bales: • Long Expedion • Bale of Nacogdoches • Bale of Concepciôn • Died, March 6, 1836 at the Fall of the Alamo Spoils of War

Sam Houston defeated Santa Anna on April 21, 1836 at San Jacinto aer an 18-minute bale.

Fellow Mason, Santa Anna, asked General Sam Houston what could he do to spare his own life? Houston responded that he wanted, TEXAS!

Emily West (1815-1891), aka Emily Morgan “The Yellow Rose of Texas”

• Emily West: free African-American (mulao) servant – Kidnapped by Santa Anna's army on April 16, 1836 – Forced to accompany the Mexican army to the Bale of San Jacinto. • Aer the Mexican defeat, stories began to circulate that Emily helped the Texan cause by keeping General Santa Anna occupied in his tent while the Texans aacked. – Though the story has no basis in historical fact, it Emily Morgan Hotel became a popular Texas myth San Antonio, TX – It is thought that she returned to her home in New York in 1837. Sam Houston

Sam Houston in Huntsville (his home)

• Governor of Tennessee • Defeated Santa Anna at the Bale of San Jacinto (near La Porte), April 21, 1836 winning the our independence from Mexico. Muskogee, Oklahoma

Naonal Cemetery Sam Houston’s Cherokee Wife

Ring of Honor Vacated Governorship of TN in 1829 to live with Cherokee unl 1832. Texas Honor Day

• April 21

• San Jacinto Day – April 21, 1836: Santa Anna defeated and independence secured Governing The Republic

Texas Ranger Museum, Waco

• Sam Houston was the 1st and 3rd President – U.S. Senator from the state of Texas – 7th Governor of the state of Texas • 2nd President Mirabeau B. Lamar – Father of Texas Educaon, approved the adopon of a new naonal flag on January 25, 1839 – A dictum in one of his messages to Congress: “A culvated mind is the guardian genius of democracy.” • 4th President, Anson Jones Texas Honor Day

• January 26

• Mirabeau B. Lamar Day – January 26, 1839 – In Houston, Lamar signed the Texas Educaon Act, thereby creang for himself the designaon of Father of Texas Educaon The Masons

• 1828: Stephen F. Ausn and six other Masons aempted to obtain a charter from the Grand York Lodge of Mexico (not granted) • 1835: Dr. Anson Jones (last President) and five other Masons were granted a charter from the Grand Lodge of Louisiana and the lodge , the Holland Lodge, named in the honor of its Grand Master, John Henry Holland. • 1837: Texas Masons formed the Grand Lodge of Texas with Anson Jones, first Grand Master Masons for Independence

• Comprised about 1% of the populaon of Texas, but filled some 80% of the Republic’s higher offices: all presidents, vice presidents, and secretaries of state • Texas military and other leaders – Stephen F. Ausn, Edward Burleson, Benjamin Rush Milam, Juan Sequin, Sam Houston, David G. Burner, Lorenzo deZavala, Thomas Rusk, Mirabeau B. Lamar, John A. Wharton, and James W. Fannin • Alamo – James B. Bonham, James Bowie, David Crocke, Almeron Dickinson, and William B. Travis Mount Vernon

Plantaon Home of President George Public Entrance (restored 1988) Washington, near Alexandria, VA Kalamazoo County, Michigan Charter Township of Texas (1838) Empresario Colonies in the Republic of Texas

• Four colonies established under contracts with the Republic of Texas: – Peters' Colony (1841) (Denton DRT Chapter!) – Fisher and Miller's Colony (1842) – Castro's Colony (1842) – Mercer's Colony (1844) • Heads of families were eligible for land grants of 640 acres while single men were eligible for 320 acres – Selers were required to culvate at least fieen acres in order to receive the patent.

4. Braggin’ or True? Oldest Universies

• Several universies claim to be the oldest – Southwestern University (1840) – University of Mary Hardin Baylor (1845) – Ausn College (1849) • Charter granted by the Republic of Texas Legislature to establish four instuons: Rutersville, Wesleyan, McKenzie, and Soule • Founded 1840 (Rutersville College opened) • Oldest university in Texas sll located in the same place (Georgetown) • Second oldest coeducaonal liberal arts college west of the Mississippi

Roy and Lillie Cullen Building Georgetown University of Mary Hardin Baylor • Established by the Republic of Texas • Originally located in Washington-on- the-Brazos (now located in Belton) • First university west of Mississippi River to admit women (1845)

Belton Sherman Hall

• Founded 1849 Ideas Building • Oldest instuon of higher educaon in Texas operang under its original name and charter (as recognized by the State Historical Survey Commiee) Grayson County • First campus in Huntsville • Moved to Sherman in 1876 • Co-ed in 1918 Houston, Texas County Seat, Missouri Founded in 1857; Named for Sam Houston 5. Braggin’ or True? TREATIES ESTABLISHED WITH FRANCE, ENGLAND AND THE NEDERLANDS

Texas Embassy, Paris • First embassy: September 25, 1839 • Plaque testifying to its authenticity is located at Tuileries Palace

Tuileries Palace 1 Place Vendome Paris, France French Legaon Oldest House in Ausn Le: London, England (about ½ mile from Trafalgar Square) Plaque on side of building where the original Texas Legaon (lile embassy) was housed.

Above: Business that now occupies site. January 22, 1842-1845 Texas Embassy Canna London, England Trafalgar Square

The University of Texas Show Band of the Southwest Alumni Band, December 2014. The 185 members played in London at a New Year’s Day parade with 10,000 others. Manhaan Project and Big Bertha • Purchased for $1.00 from University of Chicago by Col. D. Harold Byrd in 1955 (former band member) – Longhorn Band's sweetheart – Largest bass drum in the world – Svelte figure is 8 feet in diameter, 44 inches in width and 10 feet tall on her four- wheel cart, and weighs more than 500 pounds. • Byrd thought the biggest state (remember in 1955 Alaska was not yet a state!) should have the biggest drum in the world, so he had Bertha decontaminated, renovated and sent to Texas. • U of Chicago abandoned its football program because of WW II – Bertha went into seclusion under the university stadium's bleachers, Stagg Field, home of one of the three parts to the Manhaan Project. – During the war years, Bertha was contaminated by early atomic bomb research conducted in the stadium. Treaty of Amity, Commerce and Navigaon with The Netherlands

Republic of Texas Treaty with the Kingdom of the Nederlands 18th day of September 1844

Signed at the Hague; Embassy of the Netherlands located in Ausn. 6. Braggin’ or True? Monuments

Washington Monument, 169.294 m, 1884. San Jacinto Monument, 172.92 m, February 2015: “554 feet, 7 and eleven- dedicated on April 21, 1939 thirty-seconds of an inch” = 169.045732 m Start 7:00 min. United States 1842-1845 Mexican-American War (1846-1848)

• U.S. declares war on Mexico • Santa Anna (an amputee) declared himself President of Mexico (President 11 mes!) – Lost his leg in 1838 – Hit by cannon fire during melee with French – Leg was interred with full military honors – Captured by Illinois soldiers in 1847 • Decisive U.S. victory – Ended February 2, 1848 – Treaty of Guadalupe Hidalgo • Mexico recognized Texas (and other territories) as independent • Conflict between Texas and Mexico ended

Santa Anna’s Leg at the Illinois State Military Museum 7. Braggin’ or True? Court Cases

• Supreme Court decision in Texas v. Johnson (which held that an-desecraon statutes are unconstuonal if aimed at suppressing one type of expression) • Congress enacted the Flag Protecon Act of 1989 to provide criminal penales for certain acts which violate the physical integrity of the flag. – This law imposed a fine and/or up to one year in prison for knowingly mulang, defacing, physically defiling, maintaining on the floor, or trampling upon any flag of the United States. • In 1990, however, the Supreme Court held that the Flag Protecon Act was unconstuonal as applied to a burning of the flag in a public protest. Texas Flag Code Under Treaty

If Texas had entered the United States under a treaty instead of annexation, Texas would have the same privileges on flag flying as the United States.

Just like the US Flag: Blue: Loyalty; White: Purity; Red: Bravery The Texas Flag Code

• Adopted 1933, completely revised in 1993. – When flown from adjacent flagpoles, the naonal flag and the state flag should be of approximately the same size and on flagpoles of equal height, and the naonal flag should be on the flag's own right (observer's le). – The state flag should neither be flown above the flags of other U.S. states, naons and internaonal organizaons on the same flagpole, nor be flown from a higher adjacent flagpole. Alamo Today Worldwide Texas Influence 2014

Le: Jyväskylä, Finland; Middle & Right: Helsinki, Finland

Toronto, Canada Let’s Review 1. Braggin’ or True? 2. Braggin’ or True? 3. Braggin’ or True? 4. Braggin’ or True? 5. Braggin’ or True? 6. Braggin’ or True? 7. Braggin’ or True? Texas Has Braggin’ Rights! SEE YA THURSDAY!