Geochemistry and Petrogenesis of the Mcelroy and Larder Lake Assemblages, Abitibi Greenstone Belt, Northeastern Ontario by Chris
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Geochemistry and Petrogenesis of the McElroy and Larder Lake assemblages, Abitibi Greenstone Belt, Northeastern Ontario by Christopher T. Kimmerly, B.Sc. A Thesis submitted to the Department of Geological Sciences in partial fulfIllment of the requirements for the degree of Master of Science September 1992 Brock University St. Catharines, Ontario © Christopher T. Kimmerly, 1992 2 Abstract The McElroy and Larder Lake assemblages, located in the southern Abitibi Greenstone Belt are two late Archean metavolcanic sequences having markedly contrasting physical characteristics arid are separated from one another by a regional fault. An assemblage is an informal term which describes stratified volcanic and/or sedimentary rock units built during a specific time period in a similar depositional or volcanic setting and are commonly bounded by faults, unconformities or intrusions. The petrology and petrogenesis of these assemblages have been investigated to determine if a genetic link exists between the two adjacent assemblages. The McElroy assemblage is homoclinal sequence of evolved massive and pillowed fl.ows, which except for the basal unit represents a progressively fractionated volcanic pile. From the base to the top of the assemblage the lithologies include Fe-tholeiitic, dendritic flows; komatiite basaltic, ultramafic flows; Mg-tholeiitic, leucogabbro; Mg-tholeiitic, massive flows and Fe-tholeiitic, pillowed flows. Massive flows range from coarse grained to aphanitic and are commonly plagioclase glomerophyric. The Larder Lake assemblage consists of komatiitic, Mg-rich and Fe-rich tholeiitic basalts, structurally disrupted by folds and faults. Tholeiitic rocks in the Larder Lake assemblage range from aphanitic to coarse grained massive and pillowed flows. Komatiitic flows contain both spinifex and massive textures. Geochemical variability within both assemblages is attributed to different petrogenetic histories. The lithologies of the McElroy assemblage were derived by partial melting of a primitive mantle source followed by various degrees of crystal fractionation. Partial melting of a primitive mantle source generated the ultramafic flows and possibly other flows in the assemblage. Fractionation of ultramafic flows may have also produced the more evolved McElroy lithologies. The highly evolved, basal, dendritic flow may represent the upper unit 3 of a missing volcanic pile in which continued magmatism generated the remaining McElroy lithologies. Alternatively, the dendritic flows may represent a primary lava derived from a low degree (10-15%) partial melt of a primitive mantle source which was followed by continued partial melting to generate the ultramafic flows. The Larder Lake lithologies were derived by partial melting of a komatiitic source followed by gabbroic fractionation. The tectonic environment for both assemblages is interpreted to be an oceanic arc setting. The McElroy assemblage lavas were generated in a mature back arc setting whereas the Larder Lake lithologies were produced during the early stages of komatiitc crust subduction. This setting is consistent with previous models involving plate tectonic processes for the generation of other metavolcanic assemblages in the Abitibi Greenstone Belt. 4 Ackowledgements I would to thank Dr. Greg Finn for supervising, supporting and showing patience while this thesis developed. I benefited greatly from discussions and suggestions with Dr. Wayne Jolly and Dr. Frank Fueten. Dr. Steve Jackson of the Ontario Geological Survey initially suggested that studying rocks in the Larder Lake area could be a good project (and he was right). His suggestions and discussions were also valuable. Lori Wilkinson, Seppo Kakko, Elaine Lau, in 1990, and Mike Johnston, in 1991, helped in the field and made bashing through the bush a little more bearable. Dan Redmond, co-founder of the Precambrian Think-Tank, was a great office partner. Mike Lozon was very helpful when it came to advice in the generation of figures (especially with AutoCAD). Candy Kramer produced good thin sections. Geochemical analyses were conducted at the OGS Geoscience Laboratories and the Memorial University of Newfoundland. Financial support from an Ontario Graduate Scholarship in 1991 and an N.S.E.R.C. scholarship in 1992 is greatfully acknowledged. A Lithoprobe grant supported field expenses in 1992. Finally, many thanks go to my family for their support and understanding. 5 Table. of Contents Page Abstract ... 2 Acknowledgements .. .4 Table of Contents ... 5 List of Figures ... 7 List of Tables ... 8 List of Appendices ... 8 Chapter 1: Introduction ... 9 1.1 Introduction ... 9 1.2 Regional Geology ... 9 1.3 Larder Lake Group ... 14 1.4 Purpose of Study ... 16 1.5 Location and Access ... 16 1.6 Previous Work ... 17 1.6.1 Field Studies ... 17 1.6.2 Petrogenetic Studies ... 18 Chapter 2: Local Geology ... 20 2.1 McElroy assemblage ... 20 2.1.1 Introduction ... 20 2.1.2 Dendritic flows ... 23 2.1.3 Leucogabbro ... 28 2.1.4 Ultramafic flows ... 28 2.1.5 Intermediate to felsic volcaniclastic rocks ... 30 2.1.6 Medium to coarse grained flows ... 32 2.1.7 Aphanitic to fine grained flows ... 34 2.2 Assemblage Boundaries ... 36 2.2.1 Lincoln Nipissing Peridotite ... 36 2.2.2 Lincoln Nipissing Shear Zone ... 37 2.2.3 Boston Creek Fault ... 39 2.2.4 Skead assemblage .. .39 2.2.5 Huronian sedimentary rocks ... 39 2.3 Larder Lake assemblage ... 39 2.4 Summary .. .44 Chapter 3: Geochemistry of the McElroy and Larder Lake assemblages .. .49 3.1 Introduction .. .49 3.1.1 Purpose of Geochemical Study .. .49 3.1.2 Methods .. .49 3.1.3 Sample Selection ... 57 3.2 Alteration ... 58 3.2.1 Introduction ... 58 3.2.2 Major Element Alteration ... 60 3.2.3 Trace Element Alteration ... 67 6 3.3 Classification of the McElroy and Larder Lake assemblages ... 69 3.3.1 Major Elements ... 69 3.3.2 Trace Elements ... 73 3.3.3 Rare Earth Elements ... 76 Chapter 4: Geochemical Variations ... 79 4.1 Introduction ... 79 4.2 Major Element Variation ... 80 . 4.3 Trace Element Variation ... 85 4.4 Molecular Proportion Ratios ... 88 4.5 Discussion ... 90 4.6 Summary ... 91 Chapter 5: Generation of McElroy and Larder Lake assemblages ... 94 5.1 Introduction ... 94 5.2 Magma Genesis in the Kirkland Lake Area ... 94 5.3 Magma Genesis in the McElroy and Larder Lake assemblages ... 96 5.3.1 Introduction ... 96 5.3.2 Partial Melting Modelling ... 99 5.3.3 Crystal Fractionation Modelling ... 105 5.3.4 Crustal Contamination ... 114 5.3.5 Summary ... 116 Chapter 6: Comparison with Phanerozoic Rocks of Known Tectonic Settings ... 118 6.1 Introduction ... 118 6.2 Discriminant Diagrams ... 119 6.3 Tectonic Setting of McElroy and Larder Lake assemblages ... 119 Chapter 7: Discussion ... 124 7.1 Discussion ... 124 7.2 Archean Heat Flow and Tectonics ... 127 Chapter 8: Conclusions ... 129 References ... 131 Appendices ... 138 7 List of Figures 1-1 Location map of Abitibi Subprovince within the Superior Province. 1-2 Regional geology of the Kirkland Lake-Larder Lake area. 1-3 Photomicrograph of section from the Lincoln Nipissing Shear Zone. 2-1 Geological map of the McElroy assemblage. 2-2 Simplified cross-section of SW portion of McElroy assemblage. 2-3 Outcrop photograph of dendritic flow displaying spinifex-type texture. 2-4 Photomicrograph of dendritic flow showing preferred orientation of actinolite. 2-5 Outcrop photograph of randomly oriented dendritic flow. 2-6 Photomicrograph of random orientation within the denritic flow. 2-7 Photomicrograph of leucogabbro. 2-8 Photomicrograph of ultramafic flow. 2-9 Photomicrograph of intermediate crystal tuff. 2-10 Field photograph of intermediate tuff breccia. 2-11 Plagioclase phenocrysts in a coarse grained flow with knobby gabbroic texture. 2-12 Gradational contact between aphanitic flow and medium grained flow from McElroy assemblage. 2-13 Pillowed flow within McElroy assemblage. 2-14 Plagioclase glomerophyric texture in fme to medium grained massive flow. 2-15 Polygonal jointing in Lincoln Nipissing Peridotite. 2-16 Photomicrograph of Lincoln Nipissing Peridotite. 2-17 Deformed contact between intermediate and mafic rocks. 2-18 Undeformed contact between intermediate and mafic lithologies. 2-19 Geological map of Larder Lake assemblage distribution. 2-20 Slightly deformed pillowed flow from Larder Lake assemblage. 2-21 Spinifex textured komatiite from Larder Lake assemblage. 2-22 Syenite intruding massive mafic volcanic in northwest portion of McElroy assemblage. 2-23 Epidote veining in medium grained massive flow. 3-1 Location map for geochemical samples from the McElroy assemblage. 3-2 Variation plot between AlZ0 3 and TiOz. 3-3 Molecular ratio plots for major and trace elements of McElroy and Larder Lake assemblage. 3-4 Tholeiitic/calc-alkaline discriminant plots for tholeiitic units in the Larder Lake area. 3-5 Lithologic discriminant plots for the tholeiitic units in the Larder Lake area. 3-6 Jensen Cation Plots for tholeiitic units in the Larder Lake area. 3-7 Chondrite normalized extended trace element plots for tholeiitic units in the Larder Lake area. 3-8 Chondrite normalized rare earth element plots for the tholeiitic units in the Larder Lake area. 3-9 High field strength and rare earth element patterns for the McElroy and Larder Lake assemblages. 4-1 Mg#-major oxide variation diagrams for McElroy and Larder Lake assemblages. 4-2 Zr-major oxide variation diagrams for the McElroy and Larder Lake assemblages. 4-3 Mg#-trace element variation diagrams for the McElroy and Larder Lake assemblages. 4-4 Zr-trace element variation diagrams for the McElroy and Larder Lake assemblages. 4-5 Molecular proportion ratios for McElroy and Larder Lake assemblages. 4-6 Contact between dendritic and massive flow. 8 5-1 Elemental variation in the Larder Lake and McElroy assemblages with respect to chondrite data. 5-2 Results of partial melting calculations of McElroy assemblage from a primitive mantle source. 5-3 Results of partial melting calculations of Larder Lake assemblages from a primitive mantle source. 5-4 Results of partial melting calculations of McElroy assemblage from a komatiitic source.