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Journal of Reinforced Plastics and Composites http://jrp.sagepub.com/ Some natural fibers used in polymer composites and their extraction processes: A review K Palani Kumar and A Shadrach Jeya Sekaran Journal of Reinforced Plastics and Composites 2014 33: 1879 originally published online 3 September 2014 DOI: 10.1177/0731684414548612 The online version of this article can be found at: http://jrp.sagepub.com/content/33/20/1879 Published by: http://www.sagepublications.com Additional services and information for Journal of Reinforced Plastics and Composites can be found at: Email Alerts: http://jrp.sagepub.com/cgi/alerts Subscriptions: http://jrp.sagepub.com/subscriptions Reprints: http://www.sagepub.com/journalsReprints.nav Permissions: http://www.sagepub.com/journalsPermissions.nav Citations: http://jrp.sagepub.com/content/33/20/1879.refs.html >> Version of Record - Sep 26, 2014 OnlineFirst Version of Record - Sep 3, 2014 What is This? Downloaded from jrp.sagepub.com by guest on September 26, 2014 Original Article Journal of Reinforced Plastics and Composites 2014, Vol. 33(20) 1879–1892 Some natural fibers used in polymer ! The Author(s) 2014 Reprints and permissions: composites and their extraction sagepub.co.uk/journalsPermissions.nav DOI: 10.1177/0731684414548612 processes: A review jrp.sagepub.com K Palani Kumar1 and A Shadrach Jeya Sekaran2 Abstract Natural fibers are used as reinforcing materials for more than 2000 years. The need for natural fibers has been emerged due to its weight saving, cost effective, and environmentally superior alternatives to synthetic fibers in composites. The interest in natural fiber reinforced polymer composites has been increased rapidly, due to high performance in mech- anical properties, significant processing advantages, and it also provides a solution to environmental pollution. The main objective of this paper is to review and discuss the natural fibers like banana, aloe vera, kenaf, and sisal fibers and their extraction processes. Keywords Natural fibers, polymer composites, extraction process, review Introduction natural fiber composites is not a new or recent one. Nature is full of examples where in the idea of compos- Natural fibers have good prospective as reinforcements ite materials is used. The coconut palm leaf, for exam- in polymer (thermoplastics, thermosets, and elasto- ple, is nothing but a cantilever, using the concept of mers) composites. Because of high specific properties fiber reinforcement. Wood is a fibrous composite: cel- and low density of natural fibers, composites based lulose fibers have a lignin matrix. The cellulose fibers on these fibers have very good implications in industry.1 have high tensile strength, but they are very flexible, The use of natural fiber composites has been studied by when the lignin matrix joins the fibers and furnishes many researchers. Saravana Bavan and Mohan the stiffness. Bone is yet another example of a natural Kumar2 have studied the potential use of natural composite that supports the weight of various members fibers in composite materials, their availability, process- of the body. It consists of short and soft collagen fibers ing features, mechanical and physical properties, and embedded in a mineral matrix called apatite.5 Fiber some of their applications in India. Lehtiniemi et al.3 reinforced composites have been more prominent have studied the natural fiber-based reinforcements in than other types of composites because most of the epoxy composites processed by filament winding. materials are stronger and stiffer in the fibrous form Nunna et al.4 have studied the significant aspects of natural fiber-based hybrid composites which are found to be predominantly affected by factors which 1Department of Mechanical Engineering, Sri Sai Ram Institute of include variation in fiber volume/weight fraction, vari- Technology, Chennai, India ation in stacking sequence of fiber layers, fiber treat- 2Department of Mechanical Engineering, St. Peter’s College of ment, and environmental conditions. Engineering and Technology, Anna University, Chennai, India The technological development depends on advances in the field of materials. Whatever the field may be, the Corresponding author: K Palani Kumar, Department of Mechanical Engineering, Sri Sai Ram final limitation on advancement depends on materials. Institute of Technology, Sai Leo Nagar West, Tambaram, Chennai Composite materials, in this regard represent a constant 600 044, India. endeavor of optimization in materials. The idea of Email: [email protected] Downloaded from jrp.sagepub.com by guest on September 26, 2014 1880 Journal of Reinforced Plastics and Composites 33(20) than in any other form. The ultimate aim of the natural The incorporation of natural fibers such as sisal (in fiber composite is to avoid expensive glass fibers and to the form of fibers), ridge gourd (in the form of natural go for biodegradable materials. The biggest advantages woven mat), and coconut leaf sheath (in the form of of using natural fibers in composites are the cost of natural woven mat) into the epoxy matrix shows the materials, their sustainability and density; mainly they moderate improvement in the tensile properties of the have no health hazard. Natural fiber reinforced com- composites. The hybridization of these natural fibers posite has a plate material, which uses sisal, banana, has provided considerable improvement of tensile and roselle for internal and external fixation on human strength when compared to individual reinforcement; body for fractured bone.6 The benefits of using natural this is due to transfer of loads and sharing of loads fiber reinforced composites include improvement of among the fibers.11 Natural fibers have a good potential plastic shrinkage, settlement cracking, low permeabil- in the future. Many types of natural fibers have been ity, greater impact, abrasion, and shatter resistance of investigated and some are under investigation for repla- the matrix material. However, it is clear that the prob- cing plastics. This paper reviews the processing meth- lems of durability are associated with compatibility of ods of selected natural fibers such as banana, aloe vera, fibers and matrix material and environmental effect on kenaf, and sisal. The natural fibers considered in the stress corrosion resulting from interfacial debonding.7 present review and their woven fabric form is presented Analytical hierarchy process method is used to deter- in Figure 1. mine the most suitable natural fiber composites for automotive dashboard panel. Analysis reveals that Banana fiber kenaf 60% +PP is the most suitable material for auto- motive dashboard panel, as it has the highest value Banana fiber, a lignocellulosic fiber, obtained from the (5.2%) among other natural fiber materials.8 Abdul pseudostem of banana plant (Musa sapientum), is a bast Khalil et al.9 have indicated that the best alternative fiber with relatively good mechanical properties. Plant for synthetic fiber composites is natural fiber compos- fibers are sclerenchymatous cells with heavily lignified ites. The natural fiber reinforced composites are typic- cell walls having a narrow lumen in cross section. ally filled or reinforced with plant fibers, as well as Natural fibers possess several advantages over synthetic plastics such as polyvinyl chloride or recently, even fibers such as low density, appropriate stiffness, and bioplastics. Sathiskumar et al.10 have reviewed the mechanical properties and also have high disposability mechanical properties such as tensile, flexural, impact, and renewability. Also, they are recyclable and bio- and dynamic properties as well as thermal and machin- degradable. Banana fibers are used for various pur- ability properties of the composites with and without poses such as in textile, paper, or handicrafts chemically treated fibers. The water absorption capabil- industry. Banana paper is versatile, as it is waterproof ity of the composites and its effect on mechanical prop- and stronger than wood-pulp paper, which means it has erties is also reported. been used in packaging and even as a basis for building Figure 1. Fibers and woven fabrics of different natural fibers. (a) Banana, (b) aloe vera, (c) kenaf, (d) sisal. Downloaded from jrp.sagepub.com by guest on September 26, 2014 Kumar and Jeya Sekaran 1881 materials.12 Banana is a well-known fruit crop which decrease by increasing the diameter of fibers. The diam- has been grown extensively in Indian peninsula. The eter variability has a normal distribution. At lower banana plantation is presented in Figure 2(a). In fact, strain rate, an increase in strain facilitates the amorph- India is the leading producer of this perennial crop. It is ous to crystalline sharing of load. At higher speed, the estimated that, after the harvest of fruits, huge quantity faults dominate with catastrophic failure at the highest of biomass residues (60–80 t/ha) is left over as waste strain rates. Stress–strain curves show strain harden- that constitutes pseudostem, leaves, sucker, etc. There ing.17 The hybrid composites of equivalent weight exists a vast potential of extracting fibers from the ratio of jute and banana reinforced epoxy hybrid com- banana pseudostem. It is estimated that annually posite posses better thermal property and have less 17,000 tons of fibers are extracted from this waste water absorption capacity comparatively. The addition that has been roughly valued as Rs. 85 crores.13 The of banana fiber in the composites increases the tensile, fiber volume fraction and fibers aspect ratio are the flexural,