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3. Anammox Process

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3. Anammox Process 3. Anammox Process 1 Outline of Anammox Process Anammox (anaerobic ammonium oxidation) is a novel anaerobically autotrophic nitrogen transformation pathway. + - - + 1 NH4 + 1.32 NO2 + 0.066 HCO3 + 0.13 H - → 1.02 N2 + 0.26 NO3 + 0.066 CH2O0.5N0.15 + 2.03 H2O The advantages of anammox process compared with conventional BNR process N2 Organic Energy saving: Reduction anammox matter of O2 requirement denitrification Cost saving: Organic - - NH3 NO2 NO3 matter (methanol) for nitrification denitrification is not necessary O2 Copyright (c) 2012 Japan Sewage Works Agency All rights reserved. 2 Application of Anammox Process to Municipal Wastewater Target of application to municipal wastewater Treatment of filtrate from a dewatering process of anaerobically digested sludge Characteristically high levels ammonia, relatively little organic matter High water temperature (optimum growth temperature of anammox bacteria: 30-40C˚) Two different processes are required; Converting ammonia to nitrite (nitritation) Converting ammonia and nitrite into nitrogen gas (anammox) 3 Basic Flow of Anammox Process Two-stage type process Pretreatment Nitritation Anammox + + NH4 -N NH4 -N Influent ? ＋ Effluent - - NO2 -N NO2 -N (Bypass) N2 Single-stage type process Nitritation ＋ Pretreatment Anammox + NH4 -N Influent ＋ Effluent - NO2 -N 4 N2 Outline of Anammox Processes Evaluated in JS Technology Evaluation Process A Process B Process C Flow equalization Flow equalization Flow equalization Pretreatment (BOD removal) (BOD removal) (Coagulation) Screen (Coagulation) (Pre-aeration) Immobilization in PEG gel Fixed bed Sponge carrier Nitritation reactor Partial nitritation One-pass Bypass One-pass Water temperature and Water temperature and Nitritation control Heating of PEG gel pH control pH control NO2/NH4 ratio control Aeration flow rate Bypass flow rate Aeration flow rate Immobilization in PEG gel Fixed bed Granule Anammox reactor Water temperature and Water temperature and Water temperature and Anammox control pH control pH control pH control 5 Example of Pilot-scale Plant Experiment Results (Process A) Performance of nitritation reactor Performance of anammox reactor Evaluation Results of Characteristics of Anammox Process N removal rate of 70-80% can be expected by combining partial nitritation and anammox. Applicable NH4-N concentration is 700-1000mg/L and N volume load is 0.7-2.0kgN/m3/d. Stable nitritation can be maintained and NO2/NH4 ratio is kept appropriate. In the anammox reactor, N conversion rate of 80% or more (rate of decrease of total NH4-N and NO2-N) can be expected. However, N removal rate falls by up to 10% compared to N conversion rate. Required start-up period: 0.5-1.0 months (partial nitritation) , 2.0-3.0 months(anammox) 7 Results of Case-study Compared Anammox and Conventional BNR AnammoxAssuming introductionprocess can of be a expectedsidestream to treatmentrealize more (dewatering effective andfiltrate less 290m expensive3/d, T-N sidestreen 1,060mg/L) treatment to a WWTP of 60,000m3/d Wecapacity expect which that performsthe application anaerobic of anammox digestion will of sludgepromote the introduction of anaerobic digestion in Japan Anammox process Conventional BNR process* 3 Reactor 475-981 m 1,515 m3 volume (Reduction rate:35-69%) Construction 1.2-2.7 million JPY/kgN 3.4 million JPY/kgN costs (Reduction rate:22-58%) Utility 240-370 JPY/kgN costs (Reduction rate:24-57%) 600 JPY/kgN GHGs 5.7-8.6 kgCO /kgN 2 11.3 kgCO /kgN emission** (Reduction rate:24-50%) 2 *:Carrier-added step-feed biological nitrogen removal process 8 **:Volume of greenhouse gas emission from utility consumption.
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