NOTICE: this is the author’s version of a work that was accepted for publication in Applied Geochemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Applied Geochemistry, 26, 9-10, 2011. DOI 10.1016/j.apgeochem.2011.04.026 Applied Geochemistry The significance of 24-norcholestanes, 4-methylsteranes and dinosteranes in oils and source-rocks from East Sirte Basin (Libya) S. Aboglila1*, K. Grice1*, K. Trinajstic1, C. Snape2 and K.H. Williford1 1 WA Organic and Isotope Geochemistry Centre, Department of Chemistry, Curtin University, GPO Box U1987, Perth WA 6845, Australia 2 Energy Technologies Research Institute, University of Nottingham, School of Chemical and Environmental Engineering, University Park, Nottingham NG7 2RD, UK. *Corresponding Authors. Fax: +61 8 9266 2300. E-mail address:
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[email protected] 1 Abstract The present paper involves a detailed evaluation of specific steroid biomarkers by gas chromatography- mass spectrometry (GC-MS) and GC- metastable reaction monitoring (MRM) analyses of several crude oils and source rocks from the East Sirte Basin. 24-nor -methyl-24- ethylcholestanes and triaromatic steroidscholestanes, have been dinosteranes, identified in 4α both source- rocks and crude oils of the East Sirte Basin. Diatoms, dinoflagellates, (including those potentially associated with corals) and/or their direct ancestors are amongst the proposed sources of these biomarkers.