Geochemical Characteristics and Correlation of Oil and Nonmarine Source Rocks the Zuunbayan Il Fields Are Shown
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Type of Primary Producers and the Rate of Nutrient Supply
石 油 技 術 協 会 誌 第60巻 第1号 (平 成7年1月) JOURNAL OF THE JAPANESE ASSOCIATION FOR PETROLEUM TECHNOLOGY VOL. 60, NO. 1 (Jan., 1995) 論 文 ・報 告 Molecular geochemical approach to the Paleoceano graphicassessment of Neogene sediments of Yashima area, Akita Basin, Japan* Masanobu Yamamoto** and Yoshio Watanabe** (Received July 28, 1994; accepted November 9, 1994) Abstract: Specific source marker compounds were analyzed for solvent extracts from the Onnagawa, Funakawa and Tentokuji Formations, Yashima, Akita, NE Japan. Relative abundances of higher plant markers, n-C27 alkane, n-C28 alkanoic acid and ƒÖ-hydroxy n-C22 alkanoic acid; to algal derived compounds increase upward through the Funakawa Formation, indicating the rapid increase of land plant input associated with the increase of detrital matter during the deposition of the Funakawa Formation. Dinosteranes as specific compounds of dinoflagellates are more abundant in the lower part of the Onnagawa and the Funakawa Formations than in the middle and upper parts of the Onnagawa and the Tentokuji Formations. C25 highly branched isoprenoid (HBI) alkane as a specific compound of diatoms is abundant in the Onnagawa Formation, while less abundant in the Funakawa and Tentokuji Formations. The negative behavior of C25 HBI alkane/n-C21 alkane and dinosterane/4-desmethylsterane ratios through the Onnagawa Formation probably reflects the changes in primary producers likely due to the changes of nutrient silica concentration of surface water. The high dinosterane/4- desmethylsterane ratio in the Tentokuji Formation seems to reflect the increase of coastal dinoflagellates under the influence of riverine water inflow. An increase of hopane/sterane ratio in the Funakawa Formation probably reflects the increase of aerobic bacterial activity during early diagenesis resulted from bottom water oxygenation in this period. -
The Geological Succession of Primary Producers in the Oceans
CHAPTER 8 The Geological Succession of Primary Producers in the Oceans ANDREW H. KNOLL, ROGER E. SUMMONS, JACOB R. WALDBAUER, AND JOHN E. ZUMBERGE I. Records of Primary Producers in Ancient Oceans A. Microfossils B. Molecular Biomarkers II. The Rise of Modern Phytoplankton A. Fossils and Phylogeny B. Biomarkers and the Rise of Modern Phytoplankton C. Summary of the Rise of Modern Phytoplankton III. Paleozoic Primary Production A. Microfossils B. Paleozoic Molecular Biomarkers C. Paleozoic Summary IV. Proterozoic Primary Production A. Prokaryotic Fossils B. Eukaryotic Fossils C. Proterozoic Molecular Biomarkers D. Summary of the Proterozoic Record V. Archean Oceans VI. Conclusions A. Directions for Continuing Research References In the modern oceans, diatoms, dinoflagel- geobiological prominence only in the Mesozoic lates, and coccolithophorids play prominent Era also requires that other primary producers roles in primary production (Falkowski et al. fueled marine ecosystems for most of Earth 2004). The biological observation that these history. The question, then, is What did pri- groups acquired photosynthesis via endo- mary production in the oceans look like before symbiosis requires that they were preceded in the rise of modern phytoplankton groups? time by other photoautotrophs. The geologi- In this chapter, we explore two records cal observation that the three groups rose to of past primary producers: morphological 133 CCh08-P370518.inddh08-P370518.indd 113333 55/2/2007/2/2007 11:16:46:16:46 PPMM 134 8. THE GEOLOGICAL SUCCESSION OF PRIMARY PRODUCERS IN THE OCEANS fossils and molecular biomarkers. Because without well developed frustules might these two windows on ancient biology are well leave no morphologic record at all in framed by such different patterns of pres- sediments. -
The Age of the Source Rock and Its Source Facies for the Migrated Oil in Rock Samples from Novaya Zemlya
Master Thesis in Geosciences The age of the source rock and its source facies for the migrated oil in rock samples from Novaya Zemlya Ingi Thór Hallgrimson Kúld The age of the source rock and its source facies for the migrated oil in rock samples from Novaya Zemlya Ingi Thór Hallgrimson Kúld Master Thesis in Geosciences Discipline: Petroleum Geology and Geophysics (PEGG) Department of Geosciences Faculty of Mathematics and Natural Sciences UNIVERSITY OF OSLO June 2009 © Ingi Thór Hallgrimsson Kúld, 2009 Tutor(s): Dr. Dag A. Karlsen This work is published digitally through DUO – Digitale Utgivelser ved UiO http://www.duo.uio.no It is also catalogued in BIBSYS (http://www.bibsys.no/english ) All rights reserved. No part of this publication may be reproduced or transmitted, in any form or by any means, without permission . Acknowledgements I would like to thank my tutor Dr. Dag A. Karlsen for all his guidance, help, support and useful discussions during the work of this study. I would also like to thank Kristian Backer– Owe and Jan Hendrik van Koeverden at the Department of Geosciences for all their technical help and guidance in the geochemistry laboratory, for all the useful discussions we had concerning the topics of the study and for guidance into the literature. I would like to thank the Natural History Museum of the University of Oslo and in particular Hans Arne Nakrem for providing the samples from Novaya Zemlya. Lundin Petroleum AS is acknowledged for the funds which allowed me to perform extensive studies of age-specific biomarkers on the entire sample set. -
Ancient DNA Archives in Marine Sediments
School of Molecular and Life Sciences Ancient DNA Archives In Marine Sediments Kuldeep Dilip More This thesis is presented for the Degree of Doctor of Philosophy of Curtin University December 2018 ABSTRACT Analysing the response of past ecosystems to paleoclimate variations will help us gauge the effects of ongoing and long-term climate change on similar ecosystem in long term. Marine sediments provide ideal settings for such studies as they form an archive of changing benthic and pelagic ecosystem in the form of a deposited biomass. Traditional approaches employed in paleoecological studies rely heavily on the ability of plankton to form microsopic or chemical fossils (i.e. biomarkers). However, most plankton fail to produce or preserve any diagnostic features and/or molecules upon burial and hence provide incomplete picture of the past. Therefore, a more reliable method is required to include the majority of planktonic and benthic taxa in paleoenvironmental studies, and to elucidate a more complete picture of climate-driven paleoecological changes. DNA has been shown to be well-preserved in marine and lake sediments covering at least the last glacial interglacial cycle, and can be analysed in correlation with geochemical proxies to reveal the species-specific ecosystem responses to past climate. This emerging field of analysing sedimentary ancient DNA is called “sedimentary paleogenomics” and was employed in this thesis to investigate paleo-ecology-climate dynamics in three different oceanic settings. In chapter 2, these techniques were employed to investigate how past protist communities responded to alternating strong and weak oxygen minimum zones (OMZs) that occurred in the north-eastern (NE) Arabian Sea during last glacial interglacial cycle. -
This Is the Author's Version of a Work That Was Accepted for Publication In
NOTICE: this is the author’s version of a work that was accepted for publication in Applied Geochemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Applied Geochemistry, 26, 9-10, 2011. DOI 10.1016/j.apgeochem.2011.04.026 Applied Geochemistry The significance of 24-norcholestanes, 4-methylsteranes and dinosteranes in oils and source-rocks from East Sirte Basin (Libya) S. Aboglila1*, K. Grice1*, K. Trinajstic1, C. Snape2 and K.H. Williford1 1 WA Organic and Isotope Geochemistry Centre, Department of Chemistry, Curtin University, GPO Box U1987, Perth WA 6845, Australia 2 Energy Technologies Research Institute, University of Nottingham, School of Chemical and Environmental Engineering, University Park, Nottingham NG7 2RD, UK. *Corresponding Authors. Fax: +61 8 9266 2300. E-mail address: [email protected]; [email protected]; [email protected] 1 Abstract The present paper involves a detailed evaluation of specific steroid biomarkers by gas chromatography- mass spectrometry (GC-MS) and GC- metastable reaction monitoring (MRM) analyses of several crude oils and source rocks from the East Sirte Basin. 24-nor -methyl-24- ethylcholestanes and triaromatic steroidscholestanes, have been dinosteranes, identified in 4α both source- rocks and crude oils of the East Sirte Basin. Diatoms, dinoflagellates, (including those potentially associated with corals) and/or their direct ancestors are amongst the proposed sources of these biomarkers. -
A Molecular Stable Carbon Isotope Study of Organic Matter in Immature Miocene Monterey Sediments, Pismo Basin
Geochimicaet CosmochimicaActa, Vol. 61, No. 10, pp. 2065-2082, 1997 Copyright0 1997 Elsevier Science Ltd printedin the USA. All rights reserved 0016-7037/97 $17.00 + .OO PII SOO16-7037(97)00062-8 A molecular stable carbon isotope study of organic matter in immature Miocene Monterey sediments, Pismo basin STEFAN SCHOUTEN,’ MARTIN SCHOELL,’ W. IRENE C. RIJPSTRA, ’ JAAP S. SINNINGHE DAMsT~, ’ and JAN W. DE LEEUW ’ ‘Department of Marine Biogeochemistry and Toxicology, Netherlands Institute for Sea Research (NIOZ), 1790 AB, Den Burg, Texel, The Netherlands *Chevron Petroleum Technology Company, 1300 Beach Boulevard, La Habra, California 90631, USA (Received August 8, 1996; accepted in revised form January 29, 1997) Abstract-The 300 m section of the Miocene Monterey Formation outcropping at Shell Beach (Pismo basin; ca. 15- 11 Ma) is composed of calcareous phosphatic ( 15.1- 14.5 Ma) and siliceous facies ( 14.5- 11 .O Ma). An objective of this paper is to document lateral paleoenvironmental changes in the Miocene Monterey Formation by comparing the Shell Beach (SB) profile with the Naples Beach (NB) section in the Santa Barbara-Ventura basin (Schouten et al., 1997) which is -80 km to the south. Eight samples (one sample representing, on average, a time period of ca. 2000 y ) from this section were analyzed for variations of extractable biomarkers and their carbon isotopic signatures as indicators for paleoenviron- mental change during the Miocene. Saturated hydrocarbons present include 28,30dinorhopane, phytane, n-alkanes (C,,-C3r), lycopane, and 17/?,21p(H)-homohopane. The biomarkers released after desulfur- ization of the polar fractions predominantly consist of phytane, 2,6,10,14-tetramethyl-7-( 3-methylpen- tyl)pentadecane, C,,-C3, n-alkanes, regular 5a- and SD-steranes, dinosteranes, and (22R)-17&21@(H)- pentakishomohopane.