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Page 901 of 1156 Intestine-Give Milk, Milk of Magnesia, ENO 95 Toluene/ Hexane Flammable Foam 96 Ethanol Flammable Foam 97 Chlorine Toxic NA Oxygen 98 HF Toxic & Corrosive NA Calcium Gluconate Gel 99 Butene/LPG Flammable Water Spray 100 Hydrogen Flammable Water Spray 101 Aluminum Alkyl Pyrophoric Vermiculate powder/DCP * Hari Orgochem (p) Ltd. 102 Cumine Fire NA Milk of 103 Caustic SodaLye corrosive Magnesia/Soframycin CO type of fire ext., Dry 2 ointment sand. Milk of 104 Hydrochloric Acid corrosive Magnesia/Soframycin ointment Milk of 105 Nitric Acid corrosiive Magnesia/Soframycin ointment Milk of 106 Acetic Acid Fire/Corrosive CO2 type of fire ext., Dry Magnesia/Soframycin sand. ointment Milk of 107 Chlorine Gas Corrosive/Toxic Magnesia/Soframycin ointment/Oxygen Gas * HARI ORGOCHEM Pvt. Ltd Skin-Wash plenty of water 15 minutes apply Soframicyn tube or Sodium by carbonate. Eye-Wash plenty of water 15 minutes. put three drops of 108 Chlorine Toxic Non Flammable Zecip. Respiration-Apply pure oxygen. Intestine - give Milk, Milk of Magnesia, ENO. Consult a Physician Immediately. Skin-Wash plenty of water 15 minutes apply Soframicyn tube. Sulphur Mono Eye-Wash plenty of water 15 109 Toxic Non Flammable chloride (SMC) minutes. put three drops of Zecip. Respiration-Apply pure oxygen. DDMP VADODARA 2016 Page 521 Page 901 of 1156 Intestine-give Milk, Milk of Magnesia, ENO. Consult a Physician Immediately. Skin-Wash plenty of water 15 minutes apply Soframicyn tube. Eye-Wash plenty of water 15 minutes. put three drops of Hydrochloric Acid 110 Corrosive Non Flammable Zecip. 30% Respiration-Apply pure oxygen. Intestine - give Milk, Milk of Magnesia, ENO. Consult a Physician Immediately. Skin-Wash plenty of water 15 minutes apply Soframicyn tube. Eye-Wash plenty of water 15 minutes. put three drops of 111 Caustic Soda Lye 48% Corrosive Non Flammable Zecip. Respiration-Apply pure oxygen. Intestine - give Milk, Milk of Magnesia, ENO. Consult a Physician Immediately. Skin- Sodium bi Carbonate- Soframicyn tube - Eye- Zecip Eye Drops- Mother liquor of Throat & Respiration - 1. 112 Mono chloro acetic Corrosive Non Flammable Milk of Magnesia- acid 2. Milk- 3. ENO - Oxygen Cylinder in OHC Room - Skin- Sodium bi Carbonate- Soframicyn tube - Eye- Zecip Eye Drops- Tri chloro acetyl Throat & Respiration - 1. 113 Corrosive Non Flammable chloride Milk of Magnesia- 2. Milk- 3. ENO - Oxygen Cylinder in OHC Room - Skin- Soframicyn tube 114 Ammonia Corrosive Non Flammable Eye- Zecip Eye Drops- DDMP VADODARA 2016 Page 522 Page 902 of 1156 Throat- 1. Milk of Magnesia- 2.Milk- 3.ENO- 4.Smelling Ethanol * Huntsman International (India) Pvt Ltd Fire Tender (Cap : 2000 Furnace Oil (150 KL), Lts, Foam : 500 Lts), Combustible / 115 High Speed Diesel (15 Extinguishers of CO2, 10 First Aid Boxes Flammable Liquid kl ), LDO (50 Kl) DCP, ABC and Foam type * M/s. I. S. Dyestuff Industries Ltd Toxic DCP 116 Ethylene Odixe Fire ABC Explosion Foam * Gujarat Refinery Indian Oil Corporation Ltd No specific Antidote First Aid Measures Dry Chemical Eye Exposure: Irrigate eyes 117 NIL Dry Chemical Powder Powder with water and repeat until pain free. Seek medical attention if irritation develops or if vision changes occur. DDMP VADODARA 2016 Page 523 Page 903 of 1156 Skin Exposure: In case of contact, wash with plenty of soap and water. Seek medical attention if irritation develops. Inhalation: If respiratory irritation or distress occurs remove victim to fresh air. Seek medical attention if irritation persists. Ingestion: If victim is conscious and alert, give 2-3 glasses of water to drink and do not induce vomiting. Seek immediate medical attention. Do not leave victim unattended. To prevent aspiration of swallowed product, lay victim on side with head lower than waist. If vomiting occurs and the victim is conscious, give water to further dilute the chemical. Medical conditions possibly aggravated by exposure: Inhalation of product may aggravate existing chronic respiratory problems such as asthma, emphysema, or bronchitis. Skin contact may aggravate existing skin disease. Chronic overexposure may cause pneumoconiosis (―dusty lung‖ disease). No specific Antidote First Aid Measures Eye Exposure: Irrigate eyes at 118 AFF Foam NIL AFF Foam eye wash station and repeat, retracting eyelids often, until pain free. Seek medical attention immediately. DDMP VADODARA 2016 Page 524 Page 904 of 1156 Skin Exposure: In case of contact, wash with plenty of soap and water. Launder clothing before reuse. Multiple minor exposures are worse than few large exposures. Inhalation: If respiratory irritation or distress occurs remove victim to fresh air. Provide oxygen if breathing is difficult. Seek medical attention if irritation develops or persists. Ingestion: Do not induce vomiting. Dilute with 4 – 6 cups of water or milk. Seek immediate medical attention. Do not leave victim unattended. To prevent aspiration of swallowed product, lay victim on side with head lower than waist. Medical conditions possibly aggravated by exposure: contact with product may aggravate existing skin or eye conditions. * INDO AMINES LTD FLUSHING WITH DCP,WATER EXCESS WATER, 119 ACN FLAMABLE SPRAY,FOAM (ANTIDOTS-CYANIDE SOLLUTION KIT) CO2,DCP, WATER NO SPECIFIC ANTIDOT, 120 H2 GAS FLAMABLE SPRAY, FOAM GET MEDICAL SOLLUTION ASSISTANCE CO2,DCP, WATER NO SPECIFIC ANTIDOT, 121 EO FLAMABLE SPRAY, FOAM GET MEDICAL SOLLUTION ASSISTANCE CO2,DCP, WATER NO SPECIFIC ANTIDOT, IRRITANT/ 122 NH3 SPRAY, FOAM GET MEDICAL CORROSIVE SOLLUTION ASSISTANCE DDMP VADODARA 2016 Page 525 Page 905 of 1156 CO2,DCP, WATER NO SPECIFIC ANTIDOT, 123 MCG FLAMABLE SPRAY, FOAM GET MEDICAL SOLLUTION ASSISTANCE * Indian Oil Corporation Limited Dry Chemical Powder Snake Venom AFFF First Aid 124 Hydrocarbon Fire ATC CO2 * Jubilant Life Sciences Limited . Purged with N2 Gas . High Level Alarm . High Temperature Alarm . High Pressure Alarm 125 Ethylene Oxide (E. O.) Fire, Explosion- Toxic . Remote operated control valves . Gas detection system at tank & on pumps . 2 Nos. water monitor & hydrants . Water Sprinkler system on tank . Separated fenced prohibited area . DCP & CO2 type extinguishers . Purged with N2 Gas . High Level Alarm . High Temperature Alarm . High Pressure Alarm Overhead underground / On Water . Remote operated control valves GRD Tank . 126 Trimethyl Amine Fire, Explosion, Toxic Emergency D. G. Set Gas detection system at tank & on Fire Pump Set pumps Fire Extinguishers , . Foam Trolley – 200 Liters 2 nos. safety valves . 2 Nos. water monitor & hydrants . Water Sprinkler system on tank . Separated fenced prohibited area . DCP & CO2 type extinguishers . High Level Alarm . High Temperature Alarm . High Pressure Alarm . Remote operated control valves . Gas detection system at tank & on 127 Butadiene Fire, Explosion pumps . 2 nos. safety valves . 2 Nos. water monitor & hydrants . Water Sprinkler system on tank . Separated fenced prohibited area . DCP & CO2 type extinguishers . Breather valve 128 E.D.C. Fire . Level gauge DDMP VADODARA 2016 Page 526 Page 906 of 1156 . Dyke wall . 2 nos. hydrants . DCP & CO2 type extinguishers * Kiri Industries LTD 1.Dry chemical powder 2. 3% AFFF Foam 3. 129 1. Methanol Sodium bicarbonate Carbon di oxide 4. ABC Type Extinguishers ANTIDOTE - 1 spoon 5. Fire hydrant water with KHANIJ OIL + 1 Glass of 130 2. Ethylene oxide hydrant system water + 1 spoon sodium / Toxic, corrosive Magnesium Sulphate . 3. Chloro Flammable 131 6. Foam for solvents Hot tea or coffee sulphonic Acid Explosive 132 4. Oleum 65% Vinegar (sirka) 133 5. Oleum 23% Methiline Blue 6. 6.Thionyl 134 chloride 135 7. Ammonia 136 8. Aniline Oil * LOVELY CHEMICALS UNIT - II DRY CHEMICALS FORMALDEHYDE POWDER/CO2 137 TOXIC DR. P.C. JAIN 37% BOTTLE/WATER SPRIT * M/s. Lubrizol Advance Material India Private Ltd. 1. Wash affected area in case of burns and seek Liquefied Petroleum Water, Dry Chemical medical advice. 138 Inflammable gas Gas Powder 2. Administrate Oxygen in case of breathing difficulties. * Mayur Dye chem Intermediate LLP 4-methyl pyrazole 15 mg Highly Inflammable Sprinkler system every 12 hrs. Flash point ; -17.8 DCP Extinguisher Thiamine/ pyridoxine ; 100 139 Ethylene Oxide Boiling point ; -10.7 Fire Monitor mg IV daily. LEL ; 3% UEL : 100 % TLV : 1 PPM DDMP VADODARA 2016 Page 527 Page 907 of 1156 Fomepizole: approved from Flash point : 10°C Fire hydrant system methanol poisoning in the USA. Folic Acid 1 mg/kg every 4 140 Methanol Boiling point : 54°C DCP/ Form Extinguisher hrs. LEL : 5.4 UEL : 100 TLV : 200 PPM. In case of spillage use of Flash point : 75.5 soda then neutralize Methylene blue 1% solution. aniline Boiling point ; 184.1 141 Aniline LEL: 1.3% UEL: 11% NFPA : 3 2 0 TLV : 2 PPM * Munjal Auto Industries Ltd 142 Sulphuric Acid Toxic Fumes - Emergency Shower 143 Chromic Acid Fire & Irritating - Emergency Shower 144 Hydrochloric Acid Toxic Fumes - Emergency Shower 145 Caustic Soda Toxic Fumes - Emergency Shower * Nirma Limited Remove victim to fresh air, Flush with water& give 146 Kerosene Flammable Foam, DCP, Water medical treatment at medical center. Remove victim to fresh air, Flush with water & give 147 Paraffin Flammable Foam, DCP, Water medical treatment at medical center. Remove victim to fresh air. F.O Wash with soap & water& 148 Flammable Foam, DCP, Water LDO give medical treatment at medical center. Remove victim to fresh air, Flush with water & give 149 Benzene Flammable Foam, DCP, Water medical treatment at medical center. Remove victim to fresh air, Flush with water & give 150 N-Pentane Flammable Foam, DCP, Water medical treatment at medical center. DDMP VADODARA 2016 Page 528 Page 908 of 1156 Remove victim to fresh air, Flush with water & give 151 Iso-Octane Flammable Foam, DCP, Water medical treatment at medical center. Remove victim to fresh air, Flush with water & give 152 Naphtha Flammable Foam, DCP, Water medical treatment at medical center. Remove victim to fresh air, Flush with water & give 153 Diesel Flammable Foam, DCP, Water medical treatment at medical center. Remove victim to fresh air, Flush with water & give 154 LAB Flammable Foam, DCP, Water medical treatment at medical center.
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