Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2017-628 Manuscript under review for journal Hydrol. Earth Syst. Sci. Discussion started: 2 November 2017 c Author(s) 2017. CC BY 4.0 License. Modelling biocide and herbicide concentrations in catchments of the Rhine basin Andreas Moser1, Devon Wemyss1#, Ruth Scheidegger1, Fabrizio Fenicia1, Mark Honti2, Christian 1 Stamm 5 1Eawag – Swiss Federal Institute of Aquatic Science and Technology, Dübendorf, 8600, Switzerland 2MTA-BME Water Research Group, Hungarian Academy of Sciences, Budapest, 1111, Hungary #current address: ZHAW School of Management and Law, Winterthur, 8400, Switzerland Correspondence to: Christian Stamm (
[email protected]) 10 Abstract. Impairment of water quality by organic micropollutants such as pesticides, pharmaceuticals or household chemicals is a problem in many catchments worldwide. These chemicals originate from different urban and agricultural usages and are transferred to surface waters from point or diffuse sources by a number of transport pathways. The quantification of this form of pollution in streams is challenging and especially demanding for diffuse pollution due to the high spatio-temporal concentration dynamics, which requires large sampling and analytical efforts to obtain representative 15 data on the actual water quality. Models can also be used to predict information to which degree streams are affected by these pollutants. However, spatially distributed modeling of water quality is challenging for a number of reasons. Key issues are the lack of such models that incorporate both urban and agricultural sources of organic micropollutants, the large number of parameters to be estimated 20 for many available water quality models, and the difficulty to transfer parameter estimates from calibration sites to areas where predictions are needed.