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Quartz Grainsize Evolution During Dynamic Recrystallization Across a Natural Shear Zone Boundary
Journal of Structural Geology 109 (2018) 120–126 Contents lists available at ScienceDirect Journal of Structural Geology journal homepage: www.elsevier.com/locate/jsg Quartz grainsize evolution during dynamic recrystallization across a natural T shear zone boundary ∗ Haoran Xia , John P. Platt Department of Earth Sciences, University of Southern California, Los Angeles, CA 90089-0740, USA ARTICLE INFO ABSTRACT Keywords: Although it is widely accepted that grainsize reduction by dynamic recrystallization can lead to strain locali- Dynamic recrystallization zation, the details of the grainsize evolution during dynamic recrystallization remain unclear. We investigated Bulge the bulge size and grainsizes of quartz at approximately the initiation and the completion stages of bulging Subgrain recrystallization across the upper boundary of a 500 m thick mylonite zone above the Vincent fault in the San Grainsize evolution Gabriel Mountains, southern California. Within uncertainty, the average bulge size of quartz, 4.7 ± 1.5 μm, is Vincent fault the same as the recrystallized grainsize, 4.5 ± 1.5 μm, at the incipient stage of dynamic recrystallization, and also the same within uncertainties as the recrystallized grainsize when dynamic recrystallization is largely complete, 4.7 ± 1.3 μm. These observations indicate that the recrystallized grainsize is controlled by the nu- cleation process and does not change afterwards. It is also consistent with the experimental finding that the quartz recrystallized grainsize paleopiezometer is independent of -
Niobium Doped BGO Glasses: Physical, Thermal and Optical Properties
IOSR Journal of Applied Physics (IOSR-JAP) e-ISSN: 2278-4861. Volume 3, Issue 5 (Mar. - Apr. 2013), PP 80-87 www.iosrjournals.org Niobium doped BGO glasses: Physical, Thermal and Optical Properties Khair-u-Nisa1, Ejaz Ahmed2, M. Ashraf Chaudhry3 1,2,3Department of Physics, Bahauddin Zakariya University, Multan (60800), Pakistan. Abstract: IR- transparent niobium substituted heavy metal oxide glass system in formula composition (100-x) BGO75- xNb2O5; 5 ≤ x ≤ 25 was fabricated by quenching and press molding technique. Glassy state was confirmed by XRD. Density ρexp varied 6.381 g/cc-7.028 g/cc ±0.06%. Modifying behavior of Nb2O5 was corroborated by rate of increase in theoretical volume Vth, measured volume Vexp and oxygen molar volume -2 5+ 4+ VMO . Nb had larger cation radius and greater polarizing strength as compared to Ge ions. It replaced 4+ o Ge sites introducing more NBOs in the network. Transformation temperatures Tg, Tx and Tp1 were 456 -469 C ±2 oC, 516 -537 oC ±2 oC and 589 -624 oC ±2 oC respectively. In the range from room temperature to 400 oC -6 -1 -6 -1 the coefficient of linear thermal expansion α was 5.431±0.001*10 K to 7.333±0.001*10 K . ΔT = Tx-Tg and ΔTP1 = TP1-Tg varied collinearly with increase in niobium concentration and revealed thermal stability against devitrification. The direct bandgap Eg values lay in 3.24 -2.63 eV ±0.01 eV range and decreased due to impurity states of Nb5+ within the forbidden band. Mobility edges obeyed Urbach law verifying amorphousness of the compositions. -
Using Grain Boundary Irregularity to Quantify Dynamic Recrystallization in Ice
Acta Materialia 209 (2021) 116810 Contents lists available at ScienceDirect Acta Materialia journal homepage: www.elsevier.com/locate/actamat Using grain boundary irregularity to quantify dynamic recrystallization in ice ∗ Sheng Fan a, , David J. Prior a, Andrew J. Cross b,c, David L. Goldsby b, Travis F. Hager b, Marianne Negrini a, Chao Qi d a Department of Geology, University of Otago, Dunedin, New Zealand b Department of Earth and Environmental Science, University of Pennsylvania, Philadelphia, PA, United States c Department of Geology and Geophysics, Woods Hole Oceanographic Institution, Woods Hole, MA, United States d Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing, China a r t i c l e i n f o a b s t r a c t Article history: Dynamic recrystallization is an important mechanical weakening mechanism during the deformation of Received 24 December 2020 ice, yet we currently lack robust quantitative tools for identifying recrystallized grains in the “migration” Revised 7 March 2021 recrystallization regime that dominates ice deformation at temperatures close to the ice melting point. Accepted 10 March 2021 Here, we propose grain boundary irregularity as a quantitative means for discriminating between recrys- Available online 15 March 2021 tallized (high sphericity, low irregularity) and remnant (low sphericity, high irregularity) grains. To this Keywords: end, we analysed cryogenic electron backscatter diffraction (cryo-EBSD) data of deformed polycrystalline High-temperature deformation ice, to quantify dynamic recrystallization using grain boundary irregularity statistics. Grain boundary ir- Grain boundary irregularity regularity has an inverse relationship with a sphericity parameter, , defined as the ratio of grain area Dynamic recrystallization and grain perimeter, divided by grain radius in 2-D so that the measurement is grain size independent. -
Grain Boundary Loops in Graphene
Grain Boundary Loops in Graphene Eric Cockayne,1§ Gregory M. Rutter,2,3 Nathan P. Guisinger,3* Jason N. Crain,3 Phillip N. First,2 and Joseph A. Stroscio3§ 1Ceramics Division, NIST, Gaithersburg, MD 20899 2School of Physics, Georgia Institute of Technology, Atlanta, GA 30332 3Center for Nanoscale Science and Technology, NIST, Gaithersburg, MD 20899 Topological defects can affect the physical properties of graphene in unexpected ways. Harnessing their influence may lead to enhanced control of both material strength and electrical properties. Here we present a new class of topological defects in graphene composed of a rotating sequence of dislocations that close on themselves, forming grain boundary loops that either conserve the number of atoms in the hexagonal lattice or accommodate vacancy/interstitial reconstruction, while leaving no unsatisfied bonds. One grain boundary loop is observed as a “flower” pattern in scanning tunneling microscopy (STM) studies of epitaxial graphene grown on SiC(0001). We show that the flower defect has the lowest energy per dislocation core of any known topological defect in graphene, providing a natural explanation for its growth via the coalescence of mobile dislocations. §Authors to whom correspondence should be addressed:[email protected], [email protected] * Present address: Argonne National Laboratory, Argonne, IL 1 I. Introduction The symmetry of the graphene honeycomb lattice is a key element for determining many of graphene's unique electronic properties. The sub-lattice symmetry of graphene gives rise to its low energy electronic structure, which is characterized by linear energy-momentum dispersion.1 The spinor-like eigenstates of graphene lead to one of its celebrated properties, reduced backscattering (i.e., high carrier mobility), which results from pseudo-spin conservation in scattering within a smooth disorder potential.2,3 Topological lattice defects break the sublattice symmetry, allowing insight into the fundamental quantum properties of graphene. -
Grain Boundary Phases in Bcc Metals
Nanoscale Grain boundary phases in bcc metals Journal: Nanoscale Manuscript ID NR-ART-01-2018-000271.R1 Article Type: Paper Date Submitted by the Author: 06-Mar-2018 Complete List of Authors: Frolov, Timofey; Lawrence Livermore National Laboratory, Setyawan, Wahyu; Pacific Northwest National Laboratory, Kurtz, Richard; Pacific Northwest National Laboratory Marian, Jaime ; University of California Los Angeles Oganov, Artem; Stony Brook University Rudd, Robert; Lawrence Livermore National Laboratory Zhu, Qiang; University of Nevada Las Vegas Page 1 of 34 Nanoscale Grain boundary phases in bcc metals T. Frolov,1 W. Setyawan,2 R. J. Kurtz,2 J. Marian,3 A. R. Oganov,4, ∗ R. E. Rudd,1 and Q. Zhu5 1Lawrence Livermore National Laboratory, Livermore, California 94550, USA 2Pacific Northwest National Laboratory, P. O. Box 999, Richland, Washington 99352, USA 3Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, California 90095, USA 4Stony Brook University, Stony Brook, New York 11794, USA 5Department of Physics and Astronomy, High Pressure Science and Engineering Center, University of Nevada, Las Vegas, Nevada 89154, USA Abstract We report a computational discovery of novel grain boundary structures and multiple grain boundary phases in elemental body-centered cubic (bcc) metals represented by tungsten, tantalum and molybde- num. While grain boundary structures created by the γ-surface method as a union of two perfect half crystals have been studied extensively, it is known that the method has limitations and does not always predict the correct ground states. Here, we use a newly developed computational tool, based on evolu- tionary algorithms, to perform a grand-canonical search of a high-angle symmetric tilt and twist bound- aries in tungsten, and we find new ground states and multiple phases that cannot be described using the conventional structural unit model. -
Grain Boundary Properties of Elemental Metals
Acta Materialia 186 (2020) 40–49 Contents lists available at ScienceDirect Acta Materialia journal homepage: www.elsevier.com/locate/actamat Full length article Grain boundary properties of elemental metals Hui Zheng a,1, Xiang-Guo Li a,1, Richard Tran a, Chi Chen a, Matthew Horton b, ∗ Donald Winston b, Kristin Aslaug Persson b,c, Shyue Ping Ong a, a Department of NanoEngineering, University of California San Diego, 9500 Gilman Dr, Mail Code 0448, La Jolla, CA 92093-0448, United States b Energy Technologies Area, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, United States c Department of Materials Science & Engineering, University of California Berkeley, Berkeley, CA 94720-1760, United States a r t i c l e i n f o a b s t r a c t Article history: The structure and energy of grain boundaries (GBs) are essential for predicting the properties of polycrys- Received 26 July 2019 talline materials. In this work, we use high-throughput density functional theory calculations workflow Revised 13 December 2019 to construct the Grain Boundary Database (GBDB), the largest database of DFT-computed grain boundary Accepted 14 December 2019 properties to date. The database currently encompasses 327 GBs of 58 elemental metals, including 10 Available online 19 December 2019 common twist or symmetric tilt GBs for body-centered cubic (bcc) and face-centered cubic (fcc) systems Keywords: and the 7 [0 0 01] twist GB for hexagonal close-packed (hcp) systems. In particular, we demonstrate a Grain boundary novel scaled-structural template approach for HT GB calculations, which reduces the computational cost DFT of converging GB structures by a factor of ~ 3–6. -
Lecture 4 (Pdf)
GFD 2006 Lecture 4: Interfacial instability in two-component melts Grae Worster; notes by Shane Keating and Takahide Okabe March 15, 2007 So far, we have looked at some of the fundamentals associated with solidification of pure melts. When we try to solidify a solution of two or more components, salt and water, for example, the character of the solidification changes considerably. In particular, the presence of salt can depress the temperature at which ice and salt water can coexist in thermal equilibrium. This has an important consequence for the growth of sea ice: unless there is some other mechanism for the transport of the salt field, such as convection, the growth of the ice is limited by the rate at which excess salt can diffuse away from the interface. Finally, we will discuss the morphological instability in two-component melts. We shall see that the solute field is destabilizing and can give rise to morphological instability even when the liquid phase is not initially supercooled. 1 Two-component melts 1.1 A simple demonstration We shall begin with a simple demonstration. Crushed ice at 0◦C is placed in a cup with a thermometer. We add a handful of salt at room temperature and stir briskly. The ice begins to melt, but what happens to the temperature? We notice that there is some melt water in the cup, which helps bring the ice and salt into contact, and see a fairly rapid decrease in the temperature measured by the thermometer: after a few minutes, it reads almost 10 C. -
Electronic Properties of Grains and Grain Boundaries in Graphene Grown by Chemical Vapor Deposition
Electronic properties of grains and grain boundaries in graphene grown by chemical vapor deposition Luis A. Jaureguia,b, Helin Caoa,c, Wei Wud,e, Qingkai Yud,e,f, Yong P. Chenc,a,b,* a Birck Nanotechnology Center, Purdue University, West Lafayette, IN 47907, USA b School of Electrical and Computer Engineering, Purdue University, West Lafayette, IN 47907, USA c Department of Physics, Purdue University, West Lafayette, IN 47907, USA d Center for Advanced Materials, University of Houston, Houston, TX 77204, USA e Department of Electrical and Computer Engineering, University of Houston, Houston, TX 77204, USA f Ingram School of Engineering and Materials Science, Engineering and Commercialization Program, Texas State University, San Marcos, TX 78666, USA ABSTRACT We synthesize hexagonal shaped single-crystal graphene, with edges parallel to the zig-zag orientations, by ambient pressure CVD on polycrystalline Cu foils. We measure the electronic properties of such grains as well as of individual graphene grain boundaries, formed when two grains merged during the growth. The grain boundaries are visualized using Raman mapping of the D band intensity, and we show that individual boundaries between coalesced grains impede electrical transport in graphene and induce prominent weak localization, indicative of intervalley scattering in graphene. * Corresponding author. Tel.: +1 765 494 0947; Fax: +1 765 494 0706 E-mail address: [email protected] (Y. P. Chen) 1. Introduction Since its discovery, graphene has attracted a lot of attention in many fields. Graphene’s potential applications have motivated the development of large-scale synthesis of graphene grown by several methods, including graphitization of SiC surfaces [1, 2] and chemical vapor deposition (CVD) on transition metals such as Ni [3-5] and Cu [6]. -
Fluidized Bed Chemical Vapor Deposition of Zirconium Nitride Films
INL/JOU-17-42260-Revision-0 Fluidized Bed Chemical Vapor Deposition of Zirconium Nitride Films Dennis D. Keiser, Jr, Delia Perez-Nunez, Sean M. McDeavitt, Marie Y. Arrieta July 2017 The INL is a U.S. Department of Energy National Laboratory operated by Battelle Energy Alliance INL/JOU-17-42260-Revision-0 Fluidized Bed Chemical Vapor Deposition of Zirconium Nitride Films Dennis D. Keiser, Jr, Delia Perez-Nunez, Sean M. McDeavitt, Marie Y. Arrieta July 2017 Idaho National Laboratory Idaho Falls, Idaho 83415 http://www.inl.gov Prepared for the U.S. Department of Energy Under DOE Idaho Operations Office Contract DE-AC07-05ID14517 Fluidized Bed Chemical Vapor Deposition of Zirconium Nitride Films a b c c Marie Y. Arrieta, Dennis D. Keiser Jr., Delia Perez-Nunez, * and Sean M. McDeavitt a Sandia National Laboratories, Albuquerque, New Mexico 87185 b Idaho National Laboratory, Idaho Falls, Idaho 83401 c Texas A&M University, Department of Nuclear Engineering, College Station, Texas 77840 Received November 11, 2016 Accepted for Publication May 23, 2017 Abstract — – A fluidized bed chemical vapor deposition (FB-CVD) process was designed and established in a two-part experiment to produce zirconium nitride barrier coatings on uranium-molybdenum particles for a reduced enrichment dispersion fuel concept. A hot-wall, inverted fluidized bed reaction vessel was developed for this process, and coatings were produced from thermal decomposition of the metallo-organic precursor tetrakis(dimethylamino)zirconium (TDMAZ) in high- purity argon gas. Experiments were executed at atmospheric pressure and low substrate temperatures (i.e., 500 to 550 K). Deposited coatings were characterized using scanning electron microscopy, energy dispersive spectroscopy, and wavelength dis-persive spectroscopy. -
Emission of Dislocations from Grain Boundaries and Its Role in Nanomaterials
crystals Review Emission of Dislocations from Grain Boundaries and Its Role in Nanomaterials James C. M. Li 1,*, C. R. Feng 2 and Bhakta B. Rath 2 1 Department of Mechanical Engineering, University of Rochester, Rochester, NY 14627, USA 2 U.S. Naval Research Laboratory, 4555 Overlook Ave SW, Washington, DC 20375, USA; [email protected] (C.R.F.); [email protected] (B.B.R.) * Correspondence: [email protected] Abstract: The Frank-Read model, as a way of generating dislocations in metals and alloys, is widely accepted. In the early 1960s, Li proposed an alternate mechanism. Namely, grain boundary sources for dislocations, with the aim of providing a different model for the Hall-Petch relation without the need of dislocation pile-ups at grain boundaries, or Frank-Read sources inside the grain. This article provides a review of his model, and supporting evidence for grain boundaries or interfacial sources of dislocations, including direct observations using transmission electron microscopy. The Li model has acquired new interest with the recent development of nanomaterial and multilayers. It is now known that nanocrystalline metals/alloys show a behavior different from conventional polycrystalline materials. The role of grain boundary sources in nanomaterials is reviewed briefly. Keywords: dislocation emission; grain boundaries; nanomaterials; Hall-Petch relation; metals and alloys 1. Introduction To explain the properties of crystalline aggregates, such as crystal plasticity, Taylor [1,2] provided a theoretical construct of line defects in the atomic scale of the crystal lattice. Citation: Li, J.C.M.; Feng, C.R.; With the use of the electron microscope, the sample presence of dislocations validated Rath, B.B. -
Technical Glasses
Technical Glasses Physical and Technical Properties 2 SCHOTT is an international technology group with 130 years of ex perience in the areas of specialty glasses and materials and advanced technologies. With our highquality products and intelligent solutions, we contribute to our customers’ success and make SCHOTT part of everyone’s life. For 130 years, SCHOTT has been shaping the future of glass technol ogy. The Otto Schott Research Center in Mainz is one of the world’s leading glass research institutions. With our development center in Duryea, Pennsylvania (USA), and technical support centers in Asia, North America and Europe, we are present in close proximity to our customers around the globe. 3 Foreword Apart from its application in optics, glass as a technical ma SCHOTT Technical Glasses offers pertinent information in terial has exerted a formative influence on the development concise form. It contains general information for the deter of important technological fields such as chemistry, pharma mination and evaluation of important glass properties and ceutics, automotive, optics, optoelectronics and information also informs about specific chemical and physical character technology. Traditional areas of technical application for istics and possible applications of the commercial technical glass, such as laboratory apparatuses, flat panel displays and glasses produced by SCHOTT. With this brochure, we hope light sources with their various requirements on chemical to assist scientists, engineers, and designers in making the physical properties, have led to the development of a great appropriate choice and make optimum use of SCHOTT variety of special glass types. Through new fields of appli products. cation, particularly in optoelectronics, this variety of glass types and their modes of application have been continually Users should keep in mind that the curves or sets of curves enhanced, and new forming processes have been devel shown in the diagrams are not based on precision measure oped. -
Development of Highly Transparent Zirconia Ceramics
11 Development of highly transparent zirconia ceramics Isao Yamashita *1 Masayuki Kudo *1 Koji Tsukuma *1 Highly transparent zirconia ceramics were developed and their optical and mechanical properties were comprehensively studied. A low optical haze value (H<1.0 %), defined as the diffuse transmission divided by the total forward transmission, was achieved by using high-purity powder and a novel sintering process. Theoretical in-line transmission (74 %) was observed from the ultraviolet–visible region up to the infra-red region; an absorption edge was found at 350 nm and 8 µm for the ultraviolet and infrared region, respectively. A colorless sintered body having a high refractive index (n d = 2.23) and a high Abbe’s number (νd = 27.8) was obtained. A remarkably large dielectric constant (ε = 32.7) with low dielectric loss (tanδ = 0.006) was found. Transparent zirconia ceramics are candidates for high-refractive index lenses, optoelectric devices and infrared windows. Transparent zirconia ceramics also possess excellent mechanical properties. Various colored transparent zirconia can be used as exterior components and for complex-shaped gemstones. fabricating transparent cubic zirconia ceramics.9,13-19 1.Introduction Transparent zirconia ceramics using titanium oxide as Transparent and translucent ceramics have been a sintering additive were firstly reported by Tsukuma.15 studied extensively ever since the seminal work on However, the sintered body had poor transparency translucent alumina polycrystal by Coble in the 1960s.1 and low mechanical strength. In this study, highly Subsequently, researchers have conducted many transparent zirconia ceramics of high strength were studies to develop transparent ceramics such as MgO,2 developed.