Organometallics and Catalysis ORGANOMETALLICS AND CATALYSIS: CH 390K (51420) & CH 368 (51300)

Spring 2015 Room: WEL 2.304 Tues/Thurs 5:00-6:30

Instructor: Prof Michael J Rose WEL 4.420, [email protected]

Office Hours: Tues 1-2p, and by appointment

TA: Ryan Pekarek, [email protected] UG Pre-presentation: Friday 4-5p, or by appointment TA Office Hours: TBA

Reference: Organometallics 1: Bochmann (Mallet/Welch Library Reserves) Textbooks Complexes with Transition Metal-Carbon -bonds Organometallics 2: Bochmann (Mallet/Welch Library Reserves) Complexes with Transition Metal-Carbon -Bonds Organometallic Chemistry Spessand and Miessler

I. Rationale:

Overstating the commercial importance of catalysis is virtually impossible. Catalysts transform vast reservoirs of cheap and readily available chemical feedstocks into products like nylon and polyethylene polymers. They also provide efficient routes towards the synthesis of fine chemicals for use in pharmaceuticals, perfumes and foods. The development of catalysts can also play a vital role in protecting the environment by simplifying the reagents and conditions used for industrial chemistry. The worldwide market for catalysts (both homogeneous and heterogeneous) rose above the $11 billion mark in 2000.

II. Course Objectives:

The goal of the course is to give students a broad understanding of the important roles that metals play in modern catalysis. Students will be exposed to a wide range of metal-catalyzed reactions that are relevant to the modern chemical enterprise – especially industrial chemistry, the synthesis of pharmaceuticals, and the preparation of base organic compounds and polymers. As a benchmark, the successful student would be able to attend graduate level seminars in catalysis and be able to understand the background and experimental approaches in the field.

III. The Course Format is Unique

The format of this graduate level class is unique: The class will be organized in a seminar format, with a critical foundation in student participation. This class will most likely be unlike any course you have had as an undergraduate, and represents a new (somewhat experimental) approach in student-centered learning.

While the instructor will provide an introduction to the concepts and basic framework of each example of catalysis, students in the class will bring the example into the ‘real world’, by presenting literature publications, patents or up-and-coming textbook material in seminar format to the rest of the class. Therefore, a significant portion of your grade (~30%) will be based on your presentation to the class as well as your active responses to other classmates’ and the instructor’s presentations.

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IV. Prerequisite Knowledge

This course requires a solid grasp of basic inorganic chemistry including participation of d-orbitals in bonding, crystal field theory, electron counting, coordination chemistry and redox reactions. A brief re-cap of this information will be given at the beginning of the course, supplemental by frequent review of these concepts in conjunction with the more advanced material covered throughout the course.

V. Textbook and Course Notes

(a) Course Notes: Course notes and student presentations will be made available via UT Canvas.

(b) Textbook: There is no specific textbook required for this course. However, there are many texts available that directly relate to the topics covered in this course. A few useful ones are listed above, and have been made available on Reserve at the Welch Hall, Mallet Chemistry Library.

(c) Publications and Literature: Student presentations will be guided largely by recent publications that will be provided to the student presenter by the instructor. These publications will be posted on UT Canvas, and are also available free of charge from within the UT Network.

IV. Grading Procedures: Grades will be approximately based on:

(a) ~25% Student Presentation

(b) ~25% Mid-Term #1

(c) ~25% Final

(d) ~10% Problem Set #1

(e) ~10% Problem Set #2

(f) ~5% Participation

Grades will be assigned per the following scale

70-100% A 60-70% B 50-60% C 40-50% D <40% F

Note: The two homework assignments are intended to prepare you for the Mid-Term and the Final. HW assignments may be performed in groups of 1-3 and will be graded.

2 Organometallics and Catalysis V. Course Schedule:

COURSE PART I COURSE PART II

Jan 20 Intro / Inorg Principles March 24 No class (Spring ACS)

Jan 22 Suzuki / Heck Lecture March 26 , Unsat Aldehyde Hydrog

Jan 27 Online Search Tools March 31 Special Topics (Student)

Jan 29 Hydroformylation Lecture April 2 Olefin Epoxidation

Feb 3 Student Suzuki April 7 Student Aldehyde Hydrog

Feb 5 Monsanto / BP Cativa Lecture April 9 Single-site MOF / Zeolites

Feb 10 Student Hydroformylation April 14 Student Olefin Epox

Feb 12 Olefin Polymrzn (Early Metals) April 16 Metal-Ligand Cooperativity

Feb 17 Student Monsanto / BP April 21 Student MOF / Zeolite

Feb 19 Olefin Polymrzn (Late Metals) April 23 Electrocatalysis

Feb 24 Student Olfn Polmrzn, Early April 28 Student M-L Cooperativity

Feb 26 Olefin Metathesis I April 30 Student Special Topics

March 3 Student Olfn Polmrzn, Late May 5 Student Electrocatalysis

March 5 Olefin Metathesis II May 7 Student Special Topics

March 10 Student Olefin Metathesis Finals Week: Final

March 12 Mid-Term I March 17,19 Spring Break 3 Organometallics and Catalysis

VI. Use of UT Canvas in class UT Canvas—a Web-based course management system with password-protected access at http://courses.utexas.edu — will be used to distribute course materials, to communicate and collaborate online, to post grades, to submit assignments, and to give you online quizzes and surveys. You can find support in using Blackboard at the ITS Help Desk at 475-9400, Monday through Friday, 8 a.m. to 6 p.m., so plan accordingly. ______

Feedback Statement

During this course I may request feedback on your learning experience in informal as well as formal ways, including anonymous surveys about how the teaching strategies are helping or hindering your learning. I encourage you to respond to these surveys, ensuring an effective environment for teaching and learning. ______

VII. Academic Integrity

University of Texas Honor Code The core values of The University of Texas at Austin are learning, discovery, freedom, leadership, individual opportunity, and responsibility. Each member of the university is expected to uphold these values through integrity, honesty, trust, fairness, and respect toward peers and community.

Each student in this course is expected to abide by the University of Texas Honor Code. Any work submitted by a student in this course for academic credit will be the student's own work.

You are encouraged to study together and to discuss information and concepts covered in lecture and the sections with other students. You can give "consulting" help to or receive "consulting" help from such students. However, this permissible cooperation should never involve one student having possession of a copy of all or part of work done by someone else, in the form of an e-mail, an e-mail attachment file, a diskette, or a hard copy, unless specifically allowed in the format of a group project or group homework.

Should disallowed copying occur, both the student who copied work from another student and the student who gave material to be copied will both automatically receive a zero for the assignment. Penalty for violation of this Code can also be extended to include failure of the course and University disciplinary action.

During examinations, you must do your own work. Talking or discussion is not permitted during the examinations, nor may you compare papers, copy from others, or collaborate in any way. Any collaborative behavior during the examinations will result in failure of the exam, and may lead to failure of the course and University disciplinary action.

VII. Other University Notices and Policies

Religious Holy Days By UT Austin policy, you must notify the instructor of your pending absence at least fourteen days prior to the date of observance of a religious holy day. If you must miss a class, an examination, a work assignment, or a project in order to observe a religious holy day, the opportunity will be given to complete the missed work within a reasonable time after the absence.

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Use of E-mail for Official Correspondence to Students  All students should become familiar with the University's official e-mail student notification policy. It is the student's responsibility to keep the University informed as to changes in his or her e-mail address. Students are expected to check e-mail on a frequent and regular basis in order to stay current with University-related communications, recognizing that certain communications may be time-critical. It is recommended that e-mail be checked daily, but at a minimum, twice per week. The complete text of this policy and instructions for updating your e-mail address are available at http://www.utexas.edu/its/help/utmail/1564 .

Documented Disability Statement Any student with a documented disability who requires academic accommodations should contact Services for Students with Disabilities (SSD) at (512) 471-6259 (voice) or 1-866-329-3986 (video phone). Faculty are not required to provide accommodations without an official accommodation letter from SSD.

. Please notify me as quickly as possible if the material being presented in class is not accessible (e.g., instructional videos need captioning, course packets are not readable for proper alternative text conversion, etc.).

. Please notify me as early in the semester as possible if disability-related accommodations for field trips are required. Advanced notice will permit the arrangement of accommodations on the given day (e.g., transportation, site accessibility, etc.).

. Contact Services for Students with Disabilities at 471-6259 (voice) or 1-866-329-3986 (video phone) or reference SSD’s website for more disability-related information: http://www.utexas.edu/diversity/ddce/ssd/for_cstudents.php

Behavior Concerns Advice Line (BCAL) If you are worried about someone who is acting differently, you may use the Behavior Concerns Advice Line to discuss by phone your concerns about another individual’s behavior. This service is provided through a partnership among the Office of the Dean of Students, the Counseling and Mental Health Center (CMHC), the Employee Assistance Program (EAP), and The University of Texas Police Department (UTPD). Call 512-232-5050 or visit http://www.utexas.edu/safety/bcal.

Q drop Policy The State of Texas has enacted a law that limits the number of course drops for academic reasons to six (6). As stated in Senate Bill 1231: “Beginning with the fall 2007 academic term, an institution of higher education may not permit an undergraduate student a total of more than six dropped courses, including any course a transfer student has dropped at another institution of higher education, unless the student shows good cause for dropping more than that number.”

Emergency Evacuation Policy Occupants of buildings on the UT Austin campus are required to evacuate and assemble outside when a fire alarm is activated or an announcement is made. Please be aware of the following policies regarding evacuation: . Familiarize yourself with all exit doors of the classroom and the building. Remember that the nearest exit door may not be the one you used when you entered the building. . If you require assistance to evacuate, inform me in writing during the first week of class. . In the event of an evacuation, follow my instructions or those of class instructors. Do not re-enter a building unless you’re given instructions by the Austin Fire Department, the UT Austin Police Department, or the Fire Prevention Services office.

 ______

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