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Acetic Anhydride Cyclodehydration Agent, 220 Acetoamides Synthesis

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Acetic Anhydride Cyclodehydration Agent, 220 Acetoamides Synthesis INDEX Acetic anhydride Acrylic acid cyclodehydration agent, 220 biomer polymer activity, 309 Acetoamides Acrylonitrile synthesis, 277 purification, 409 Acetone sodium naphthalene polymerized, polyanhydride solvent, 193 410 Acetone cyanohydrin N-Acryloyl-a-aminoisobutyrate azlactone raw material, 225 synthesis, 225 a-Acetoxypropionic acid N-Acryloylmethylalanine ring closure to lactone, 443 ethyl chloroformate reaction, 206 Acetyl acetone, 464 Activation energy manganese decarbonyl coordi­ styrene anoinic dispersion nating agent, 300 polymerization, 392, 296 Acetyl chloride a-Acylamino-a-aminopropionic acid coumalic acid reaction, 61 conversion to a-lactone, 445 polystyrene living particle N-Acylurea, 307 reaction, 400 Adhesives, hot melt Acetylene carbonyls synthesis concept, 480 amine condensations, 276 Adipic acid, 192 Acrolein Adipic acid, metal salts acetal formation, 62, 74 phosphorus acid chloride Acrylamide condensation, 195 hydrophilic grafts on polymers, Aldehydes 293 anionic polymerization, 322 functionalized oligomers, 205, Alkenes 211, 215-217 triazolinedione ene reaction, 2 ORTEP plots, 212 Alkenyl azalactone purification, 308 amine oligomer reaction, 208, telechelic oligomers, 203 210, 211 Acrylamides, bis type 2-Alkenyl-2-oxazoline-5-ones amine reaction, 215 amine reactions, 205, 211 Acrylamides, telechelic Alkoxides characterization, 208 catalyst for oxazolidone synthesis from azlactones, formation, 252 219, 221 Alkoxides, polymeric Acrylates, alkyl ethylene oxide polymerization, anionic polymerization, 327 330 alkali metal alkoxides Alkyl ketones polymerization, 327 cycloaddition reaction, 1 group transfer polymerization, Alkyllithium 327 anionic polymerization initiator, Acrylates, perfluoroalkyl 335 methacryloyl polystyrene Alkyllithium, anionic initiators macromer copolymerization, copolymerization reactivity 463 ratios, 335 517 Allyl chloride Azlactones N-(2-hydroxyethyl) amide alkenyl oligomers, 203 reaction, 240 amine oligomer reactions, 203 Allyltrimethylsilane triazoline­ amine reactions, 217, 219 dione reaction, 2 bis-thio reaction, 225 Aluminum chloride n-butylamine reaction, 231 benzene-sulfur reaction 2-cyanoethyl methylamine catalyst, 176 reaction, 231 Friedel-Crafts catalysts, mercaptan reactions, 219 159-162, 164, 166, 167 nucleophilic attack, 231 Aluminum trichloride ring-opening, zwitterionic S-propiolactone polymerization reaction, 205 catalyst, 450, 451 synthesis, 225 Amides, N-halo derivative Azlactones, alkenyl polymer halogenation agents, 295 amine oligomer reaction, 221 Amines 1, 2-ethanediol addition reaction, acetylene carbonyl reaction, 276 221, 222 1, 3-dicarbonyl reaction, 276 ethylene-bis (3-mercaptopro- Amines, primary pionate) reaction, 221 benzoxazine synthesis, 27, 28, Jeffamine reaction, 229, 230 48 Michael addition reaction, 229 Amines, titration Mercaptan reaction, 229 perchloric acid/glacial acetic Nucleophilic reactions, 219, 232 acid method, 206, 207, 208 polymerization reactions, 232 Amino acids polythiol reaction, 223, 224 alkaloids preparation, 425 synthesis procedure, 221 diacid chloride reaction, 220 Azalactones, isopropenyl substituted optically active enantiomers, nucleophilic reaction, 219 resolution, 425, 438 Azalactones, multifunctional Aminoalkylation applications, 232 phenols, 29, 48 characterization, 224 p-Aminobenzoic acid curing mechanism, 232 polyphosphonamide monomer, 190 expansion polymerization, 232 polyamino acid monomer, 190 Michael addition, 232 Antibiotics Nucleophilic addition, 219, 220, polypeptide containing, 419 232 Aromatic polymers ring opening polymerization, 231, interfacial polymerization 232 production procedure, 54, synthesis, 221, 223, 224 59 Azalactones, vinyl substituted Arrhenius equation amine reaction, 229, 230 benzoxazine polymerization, 41 bis-mercaptan reaction product Arrhenius plot identification, 226 methyl methacrylate radical characterization, 227, 228 polymerization, 511 mercaptan Michael addult, 226-229 styrene anionic dispersion nucleophilic reactions, 219 polymerization, 392, 396 Azobisisobutyromitrile Arsenic pentafluoride radical polymerization catalyst, PPS dopant, 182 507-511, 514 Arsenic trifluoride PPS dopant, 182 Benzene Arterial prosthesis iron trichloride catalyzed poly(ether-urethane) based, 309 sulfur monochloride (-)-Asparagine reaction, 177 conversion to optically active sulfur-aluminum chloride S-propiolactone, 445 polymerized, 160, 170 Aspergillus flavus, 277 sulfur reaction, 159-162, 164, Aspergillus niger, 277 170, 171 518 Benzenesulfonamide-a-propiolac­ Benzoyl peroxide tones, a-(p-substituted) radical polymerization optically active monomer initiator, 510, 511 synthesis, 445 Benzyl bromide Benzophenone N-(2-hydroxyetnyl) amide photosensitizer, 125 reaction, 240 Benzoxazines Bernoullian statistics amine containing phenolic poly (a-propiolactones), 453 resins, 48 poly (a-trichloromethyl antioxidant uses, 48 a-propiolactone), 447 applications, 47 a-substituted poly bulk polymerization, 29 (a-propiolactones), 447 C14 labeled, 48 Biomer carbon substrate grafting, 29, 48 bromination, 310-312 characteristics, 27, 29, 48 chlorination, 310-312 complexing agents, 48 REMA grafted, 313 2,4-dimethylphenol reaction, 32 REMA palmitate ester grafting, 2,6-dimethylphenol reaction, 32 313-315 2,4-ditert-butylphenol polymeri- methyl methacrylate grafted, 313 zation rate, 39-41, 43 prosthesis materials, 309-311 2,6-ditert-butylphenol reaction, vinyl monomer grafting, 315 31 Biopolymers epoxy resin crosslinker, 47 cellulosic type, 405 fiber reinforced laminate uses, protein type, 405 47 starch type, 405 oligomer applications, 47, 48 Biphenols oligomerization reactions, 47, 48 bisphenate complex, 115 ortho and para substituted, 48 bisphenate synthesis, 114, 115 phenol activation energy, 30-32 dihaloalkane polyetherification, phenol initiated polymerization, 143 33-37, 47, 48 etherification mechanism, 143 phenol reaction, 28-31, 33, 34, Schotten-Baumann reaction, 189 48 4,4'-Biphenol phenol reaction rate constants, polyether synthesis, 98, 99, 30, 31, 33 101, 105, 108, 109 phenolic resin uses, 47 purification, 97 polymerization activation Biphenols, sodium salts energy, 41 aryl halide reactions, 114-116 polymerization kinetics, 35-37, N,N'-Bis(acetacetyl)-1,4-piperazine 48 p-n-butylamine model compound, polymerization mechanism, 37-39 283, 285 polymerization rate constants, p-N-butylaniline reaction, 280 40, 41 1,10-decamethylenediamine polymerization rate equation, condensation, 282 37-39 diamine reaction product polymerization routes, 35 characterization 281, 284 polymer molecular weights, 37, Jeffamine polycondensation, 286 38, 47 p-phenylenediamine condensation, polymer structure, 35 282 ring opening polymerization, poly(amide enamine) monomer, 279 27-29, 33-36, 48 synthesis, 280 synthesis, 28, 48 m-xylxylenediamine condensation, thermal initiated 282 polymerization, 34, 42, 43 Bis(acetylacetone) ethylenediamine thermal polymerization kinetics, tautomeric forms, 276 43-47 Bis-acetylacetylarenes thermal polymerization diamine polycondensation, 278 mechanism, 45 thermal properties, 31, 34 519 2,2-Bis(4-amino cyclohexyl) propane Bis(methylurethane) polyamide monomer 59, 60, 65-70, epoxide reaction, 265 80-83, 85-88 Bisoxazoline purification, 72 dicarboxylic acid Bisazlactones copolymeriztion, 236 applications, 220, 221 ring opening polycondensations, diamine polymerization, 220 235 epoxy resin alternative, 231 Bis(phenylthio)benzene isocyanate resin alternative, 231 synthesis, 169 Michael-type reaction mechanism, Bis-triazolinediones 223 copolymerization, 19 oligomeric materials, 229 copolymer thermal properties, 23 polyamine reactions, 231, 232 B-dicarbonyl compound reactions, polymerization rates, 231 2 polyols reaction, 231 Diels-Alder Copolymerizations, 19 synthesis procedure, 220 Diels-Alder reaction, 1 1,4-Bis(3-p-n-butylanilino-2- Diene reactions, 2 butenoyl) piperzine identification, 18, 19 synthesis, 280 ene reaction, 1 1,2-Bis-(4-carboxyphenoxy) ethane synthesis, 18, 19 dibasic acid chloride Bisurethanes condensation, 188 diepoxides polymerization, 256 monomer for polyester, 188 Boron trifluoride, diethyl etherate 1,3-Bis(4-carboxyphenoxy) propane, oxazoline polymerization 192 catalyst, 238, 239 Bis(1,3-diketone) thiol-azlactone reaction diamine condensations, 278 catalyst, 229 Bis(dimethylamino benzophenone) B-Bromobutyric acid anionic living polystyrene D-(+)-B-butyrolactone reaction, 401 conversion, 445 1,8-Bis-(dimethylamino)naphthalene, 1-Bromopentane, 136 69, 87 polyether terminator, 145, 146 1,6-Bis-(3,5-dioxo-1,2,4- N-Bromosuccinimide triazoline-4-yl)hexane poly(aryl ether sulfone) synthesis, 8, 10, 18 bromination, 118 Bis-(p-3,5-dioxo-1,2,4-triazoline- 2-Bromoterephthalic acid, 192 4-yl-phenyl)methane 4-Bromothiophenol copolymerization reaction, 13 PPS intermediate, 175 synthesis, 10, 11, 18 copper salt/pyridine 2,2-Bis[p-(2,3-epoxypropyl)­ polymerized, 175 phenyl j propane Brucine 2,4-toluene diisocyanate amino acid resolving agent, 425, reaction, 252 427 2, 2-Bis (4-hydroxyphenyl) propane chiral base, 446 4,4'-dichlorodiphenyl sulfone Butadiene reaction, 239 anionic polymerization polyarylate monomer, 94, 95 polystyryl anion, 322, 347 polyether monomer, 94-96 s-butyllithium polymerization, polyester comonomer, 54, 59, 60, 333, 334 65-68, 70, 79-81, 83, 88 diphenylethylene dilithium purification, 72 polymerized, 325 tetramethyl derivative, 113 isoprene copolymerization, 336 Bis-ketoesters isoprene stereospecific diamine polycondensations, 276 copolymerization, 483 Bis-(methyl-4-N-phenylene polymerization
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