SDS EU (Reach Annex II)

ONA MIST Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Date of issue: 1. 2. 2016 Revision date: 23. 9. 2016 Supersedes: 11. 7. 2016 Version: 2.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : ONA MIST Vaporizer : Aerosol

1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Main use category : Industrial use, Professional use, Consumer use Use of the substance/mixture : Odour Neutralizer

1.2.2. Uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet Supplier Distributor Odorchem Manufacturing Corp. Mariner Packaging Co. Ltd. Unit #1 – 9790 190th St. Unit 2 Omega Buisiness Park, Estate Road 6, South Humberside Surrey, BC V4N 3M9 Industrial Estate T +1 604 942 7880, +1 877 386 5000 - F +1 604 608 2980 DN31 2TG Grimsby - United Kingdom [email protected] - http://www.odorchem.com/ T 44 1472 242 244 www.easy-grow.co.uk

1.4. Emergency telephone number Country Organisation/Company Address Emergency number Comment United Kingdom National Poisons Information Grosvenor Road 0844 892 0111 (UK Service (Belfast Centre) BT12 6BA Belfast only, Monday to Friday, Royal Victoria Hospital 08.00 to 18.00 hours) United Kingdom National Poisons Information Dudley Road 0844 892 0111 (UK Service (Birmingham Centre) B18 7QH Birmingham only, Monday to Friday, City Hospital, Guy's & St Thomas' 08.00 to 18.00 hours) Hospital Trust United Kingdom National Poisons Information Penarth 0844 892 0111 (UK Service (Cardiff Centre) CF64 2XX Cardiff only, Monday to Friday, Gwenwyn Ward, Wolfson Unit 08.00 to 18.00 hours) United Kingdom National Poisons Information Claremont Place 0844 892 0111 (UK Newcastle-upon-Tyne Service (Newcastle Centre) NE1 4LP Newcastle only, Monday to Friday, Regional Drugs and Therapeutics Centre 08.00 to 18.00 hours)

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Aerosol, Category 1 H222;H229 Full text of H statements : see section 16

Adverse physicochemical, human health and environmental effects Extremely flammable aerosol.

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) :

GHS02 Signal word (CLP) : Danger Hazard statements (CLP) : H222 - Extremely flammable aerosol H229 - Pressurised container: May burst if heated Precautionary statements (CLP) : P102 - Keep out of reach of children

28. 9. 2016 EN (English) 1/9 ONA MIST Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P211 - Do not spray on an open flame or other ignition source P251 - Do not pierce or burn, even after use P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F EUH-statements : EUH208 - Contains Terpens and terpenoids(65996-98-7), Citrus aurantium dulcis (orange) peel oil(8008-57-9), Pinus palustris leaf extract (oil)(8002-09-3). May produce an allergic reaction

2.3. Other hazards Other hazards not contributing to the : May cause sensitization by skin contact. classification PBT: not yet assessed vPvB: not yet assessed

SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable

3.2. Mixture

Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] isobutane (CAS No) 75-28-5 60 - 100 Flam. Gas 1, H220 (EC no) 200-857-2 Press. Gas (EC index no) 601-004-00-0 propane (CAS No) 74-98-6 5 - 10 Flam. Gas 1, H220 (EC no) 200-827-9 Press. Gas (EC index no) 601-003-00-5 ethanol, ethyl alcohol (CAS No) 64-17-5 3 - 7 Flam. Liq. 2, H225 (EC no) 200-578-6 (EC index no) 603-002-00-5 Terpens and terpenoids (CAS No) 65996-98-7 < 1 Skin Irrit. 2, H315 (EC no) 266-034-5 Skin Sens. 1, H317 Citrus aurantium dulcis (orange) peel oil (CAS No) 8008-57-9 < 1 Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Pinus palustris leaf extract (oil) (CAS No) 8002-09-3 < 1 Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317

Full text of H-statements: see section 16

SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : If you feel unwell, seek medical advice (show the label where possible). Never give anything by mouth to an unconscious person. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. If you feel unwell, seek medical advice. First-aid measures after skin contact : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : May cause an allergic skin reaction. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Dry powder. Water spray. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Extremely flammable aerosol.

28. 9. 2016 EN (English) 2/9 ONA MIST Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Explosion hazard : Contains gas under pressure; may explode if heated. Reactivity in case of fire : Containers can build up pressure if exposed to heat (fire). May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products. Hazardous decomposition products in case of : Carbon dioxide. Carbon monoxide. fire 5.3. Advice for firefighters Precautionary measures fire : Fight fire remotely due to the risk of explosion. Firefighting instructions : Prevent fire fighting water from entering the environment. Use water spray or fog for cooling exposed containers. Protection during firefighting : Do not attempt to take action without suitable protective equipment. Complete protective clothing. Self-contained breathing apparatus.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Absorb spillage to prevent material damage. Eliminate every possible source of ignition. Isolate from fire, if possible, without unnecessary risk.

6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. Ventilate spillage area.

6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures : Stop leak if safe to do so. Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Notify authorities if product enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up : Take up liquid spill into absorbent material. This material and its container must be disposed of in a safe way, and as per local legislation. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections See Sections 8 and 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling : Avoid contact with skin, eyes and clothing. Do not breathe vapours. Do not spray on an open flame or other ignition source. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Provide local exhaust or general room ventilation. Use personal protective equipment as required. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Provide local exhaust or general room ventilation. Storage conditions : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep only in original container. Protect from sunlight. Store in a well-ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Incompatible materials : Sources of ignition. Heat sources. Direct sunlight. Storage area : Store away from heat. Store in a well-ventilated place. Special rules on packaging : Keep only in original container. Store in a closed container. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters ethanol, ethyl alcohol (64-17-5) United Kingdom Local name Ethanol United Kingdom WEL TWA (mg/m³) 1920 mg/m³ United Kingdom WEL TWA (ppm) 1000 ppm

28. 9. 2016 EN (English) 3/9 ONA MIST Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station.

Hand protection: Protective gloves

Eye protection: Chemical goggles or safety glasses

Skin and body protection: Wear suitable protective clothing

Respiratory protection: In case of inadequate ventilation wear respiratory protection

Other information: Do not eat, drink or smoke when using this product.

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid

Appearance : Colorless solutions or gas. Colour : clear.

Odour : No data available

Odour threshold : No data available

pH : 6 - 8

Relative evaporation rate (butylacetate=1) : < 1

Melting point : No data available

Freezing point : No data available

Boiling point : 80 °C

Flash point : 13 °C

Auto-ignition temperature : 460 °C (Propellant)

Decomposition temperature : No data available

Flammability (solid, gas) : Extremely flammable aerosol

Vapour pressure : No data available

Relative vapour density at 20 °C : No data available

Relative density : 0,81 - 0,85

Solubility : Soluble in water.

Log Pow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : No data available

Explosive limits : 1,8 19

9.2. Other information Internal Can Pressure : 40 - 60 psig

SECTION 10: Stability and reactivity 10.1. Reactivity The product is non-reactive under normal conditions of use, storage and transport.

10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions Refer to section 10.1 on Reactivity. 10.4. Conditions to avoid Direct sunlight. No flames, no sparks. Eliminate all sources of ignition. 10.5. Incompatible materials No additional information available 10.6. Hazardous decomposition products Containers can build up pressure if exposed to heat (fire). May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products. Thermal decomposition may produce : carbon oxides (CO and CO2).

SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified (Based on available data, the classification criteria are not met)

isobutane (75-28-5) LC50 inhalation rat (Vapours - mg/l/4h) 658 mg/l/4h propane (74-98-6) LC50 inhalation rat (ppm) > 800000 15min ethanol, ethyl alcohol (64-17-5) LD50 oral rat 12,6 g/kg LC50 inhalation rat (ppm) 20000 10 hrs Skin corrosion/irritation : Not classified (Based on available data, the classification criteria are not met) pH: 6 - 8 Serious eye damage/irritation : Not classified (Based on available data, the classification criteria are not met) pH: 6 - 8 Respiratory or skin sensitisation : Not classified (Conclusive but not sufficient for classification) Additional information : May cause an allergic skin reaction Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met) Carcinogenicity : Not classified (Based on available data, the classification criteria are not met) Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met) Specific target organ toxicity (single exposure) : Not classified (Based on available data, the classification criteria are not met) Specific target organ toxicity (repeated : Not classified (Based on available data, the classification criteria are not met) exposure) Aspiration hazard : Not classified (Based on available data, the classification criteria are not met) ONA MIST Vaporizer Aerosol

SECTION 12: Ecological information 12.1. Toxicity Ecology - general : Based on available data, the classification criteria are not met.

ethanol, ethyl alcohol (64-17-5) LC50 fish 1 14200 mg/l EC50 Daphnia 1 9300 mg/l

12.2. Persistence and degradability ONA MIST Persistence and degradability Not established. ethanol, ethyl alcohol (64-17-5) Persistence and degradability Readily biodegradable. 12.3. Bioaccumulative potential ONA MIST Bioaccumulative potential Not established.

12.4. Mobility in soil No additional information available 12.5. Results of PBT and vPvB assessment ONA MIST PBT: not yet assessed vPvB: not yet assessed Component Terpens and terpenoids (65996-98-7) PBT: not yet assessed vPvB: not yet assessed

12.6. Other adverse effects Additional information : Avoid release to the environment

SECTION 13: Disposal considerations 13.1. Waste treatment methods Regional legislation (waste) : Disposal must be done according to official regulations. Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions. Waste disposal recommendations : Avoid release to the environment. Container under pressure. Do not drill or burn even after use. Ecology - waste materials : Avoid release to the environment. HP Code : HP3 - “Flammable:” — other flammable waste: flammable aerosols, flammable self-heating waste, flammable organic peroxides and flammable self-reactive waste

SECTION 14: Transport information In accordance with ADN / ADR / IATA / IMDG / RID

14.1. UN number UN-No. (ADR) : 1950 UN-No. (IMDG) : 1950 UN-No. (IATA) : 1950 UN-No. (ADN) : 1950 UN-No. (RID) : 1950 14.2. UN proper shipping name Proper Shipping Name (ADR) : AEROSOLS Proper Shipping Name (IMDG) : AEROSOLS Proper Shipping Name (IATA) : Aerosols, flammable Proper Shipping Name (ADN) : AEROSOLS Proper Shipping Name (RID) : AEROSOLS Transport document description (ADR) : UN 1950 AEROSOLS (Isobutane, propane), 2.1, (D) Transport document description (IMDG) : UN 1950 AEROSOLS (Isobutane, propane), 2.1 Transport document description (IATA) : UN 1950 Aerosols, flammable (Isobutane, propane), 2.1 Transport document description (ADN) : UN 1950 AEROSOLS (Isobutane, propane), 2.1 Transport document description (RID) : UN 1950 AEROSOLS (Isobutane, propane), 2.1 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 2.1 Danger labels (ADR) : 2.1 :

IMDG Transport hazard class(es) (IMDG) : 2.1 Danger labels (IMDG) : 2.1

28. 9. 2016 EN (English) 6/9 ONA MIST Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 :

IATA Transport hazard class(es) (IATA) : 2.1 Hazard labels (IATA) : 2.1 :

ADN Transport hazard class(es) (ADN) : 2.1 Danger labels (ADN) : 2.1 :

RID Transport hazard class(es) (RID) : 2.1 Danger labels (RID) : 2.1 :

14.4. Packing group Packing group (ADR) : Not applicable Packing group (IMDG) : Not applicable Packing group (IATA) : Not applicable Packing group (ADN) : Not applicable Packing group (RID) : Not applicable 14.5. Environmental hazards Dangerous for the environment : No Marine pollutant : No Other information : No supplementary information available 14.6. Special precautions for user

- Overland transport Classification code (ADR) : 5F Special provisions (ADR) : 190, 327, 344, 625 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E0 Packing instructions (ADR) : P207, LP02 Special packing provisions (ADR) : PP87, RR6, L2 Mixed packing provisions (ADR) : MP9 Transport category (ADR) : 2 Special provisions for carriage - Packages : V14 (ADR) Special provisions for carriage - Loading, : CV9, CV12 unloading and handling (ADR) Special provisions for carriage - Operation : S2 (ADR) Tunnel restriction code (ADR) : D

- Transport by sea Special provisions (IMDG) : 63, 190, 277, 327, 344, 959 Limited quantities (IMDG) : SP277

28. 9. 2016 EN (English) 7/9 ONA MIST Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P207, LP02 Special packing provisions (IMDG) : PP87, L2 EmS-No. (Fire) : F-D EmS-No. (Spillage) : S-U Stowage category (IMDG) : None Stowage and handling (IMDG) : SW1, SW22 Segregation (IMDG) : SG69

- Air transport PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Y203 PCA limited quantity max net quantity (IATA) : 30kgG PCA packing instructions (IATA) : 203 PCA max net quantity (IATA) : 75kg CAO packing instructions (IATA) : 203 CAO max net quantity (IATA) : 150kg Special provisions (IATA) : A145, A167, A802 ERG code (IATA) : 10L

- Inland waterway transport Classification code (ADN) : 5F Special provisions (ADN) : 190, 327, 344, 625 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01, VE04 Number of blue cones/lights (ADN) : 1

- Rail transport Classification code (RID) : 5F Special provisions (RID) : 190, 327, 344, 625 Limited quantities (RID) : 1L Excepted quantities (RID) : E0 Packing instructions (RID) : P207, LP02 Special packing provisions (RID) : PP87, RR6, L2 Mixed packing provisions (RID) : MP9 Transport category (RID) : 2 Special provisions for carriage – Packages : W14 (RID) Special provisions for carriage - Loading, : CW9, CW12 unloading and handling (RID) Colis express (express parcels) (RID) : CE2 Hazard identification number (RID) : 23 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations

REGULATION (EC) No 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC. Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.

28. 9. 2016 EN (English) 8/9 ONA MIST Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 15.1.2. National regulations United Kingdom No additional information available

15.2. Chemical safety assessment No chemical safety assessment has been carried out

SECTION 16: Other information Indication of changes: Identification of the substance/mixture and of the company/undertaking. Hazards identification. Composition/information on ingredients. Exposure controls/personal protection. Toxicological information. Ecological information. Disposal considerations. Transport information. Abbreviations and acronyms: ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR European Agreement concerning the International Carriage of Dangerous Goods by Road CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 IATA International Air Transport Association IMDG International Maritime Dangerous Goods LC50 Median lethal concentration LD50 Median lethal dose PBT Persistent Bioaccumulative Toxic REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006 RID Regulations concerning the International Carriage of Dangerous Goods by Rail SDS Safety Data Sheet vPvB Very Persistent and Very Bioaccumulative Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. SDS ONA MIST, Version 1, February 2016 Dissemination portal ECHA Training advice : Normal use of this product shall imply use in accordance with the instructions on the packaging. Other information : None. Full text of H- and EUH-statements: Flam. Gas 1 Flammable gases, Category 1 Flam. Liq. 2 Flammable liquids, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Press. Gas Gases under pressure Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation — Skin, Category 1 H220 Extremely flammable gas H222 Extremely flammable aerosol H225 Highly flammable liquid and vapour H226 Flammable liquid and vapour H229 Pressurised container: May burst if heated H315 Causes skin irritation H317 May cause an allergic skin reaction EUH208 Contains . May produce an allergic reaction

Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]: Aerosol 1 H222;H229 On basis of test data

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

28. 9. 2016 EN (English) 9/9