List of Publications Nicolas Le Poul 01/10/2016

List of Publications – Nicolas Le Poul – 01/10/2016.

37. "Immobilization of monolayers incorporating Cu funnel complexes onto gold electrodes. Application to the selective electrochemical recognition of primary alkylamines in water", G. De Leener, F. Evoung−Evoung, A. Lascaux, J. Mertens, A. G. Porras−Gutierrez, N. Le Poul, C. Lagrost, D. Over, Y. R. Leroux, F. Reniers, P. Hapiot, Y. Le Mest, I. Jabin, O. Reinaud, J. Am. Chem. Soc. 2016, 138, 12841−12853.

36. "Room−temperature characterization of a mixed−valent µ−hydroxodicopper(II,III)”, J. A. Isaac, F. Gennarini, I. Lopez, A. Thibon−Pourret, R. David, G. Gellon, B. Gennaro, C. Philouze, F. Meyer, S. Demeshko, Y. Le Mest, M. Reglier, H. Jamet, N. Le Poul, C. Belle, Inorg. Chem. 2016, 55, 8263−8266.

35. "Cyclams with ambidentate methylthiazolyl pendants for stable, inert, and selective Cu(II) coordination", A. Rodriguez−Rodriguez, Z. Halime, L. M. P. Lima, M. Beyler, D. Deniaud, N. Le Poul, R. Delgado, C. Platas−Iglesias, V. Patinec, R. Tripier, Inorg. Chem. 2016, 55, 619−632.

34. "Improving the stability and inertness of Cu(II) and Cu(I) complexes with methylthiazolyl ligands by tuning the macrocyclic structure", M. Le Fur, M. Beyler, N. Le Poul, L. M. P. Lima, Y. Le Mest, R. Delgado, C. Platas−Iglesias, V. Patinec, R. Tripier. Dalton Trans. 2016, 45, 7406−7420.

33. “The synthesis of flexible tetrapyridylethanes from pyridylpyrylium dications", P. Le Poul, N. Le Poul, S. Golhen, F. Robin−Le Guen, B. Caro ", New J. Chem. 2016, 40, 5666−5669.

32. “Supramolecular modeling of mono-copper enzyme active sites with calix[6]arene-based funnel complexes", N. Le Poul, Y. Le Mest, I. Jabin, O. Reinaud, Acc. Chem. Res. 2015, 48, 2097-2106.

31. "Electrochemically and chemically induced redox processes in molecular machines", N. Le Poul, B. Colasson , ChemElectrochem 2015, 2, 475-496.

30. "Supramolecular control of a mononuclear biomimetic copper(II) center: Bowl complexes vs funnel complexes", J. Gout, A. Visnjevac, S. Rat, A. Parrot, A. Hessani, O. Bistri, N. Le Poul, Y. Le Mest, O. Reinaud , Inorg. Chem. 2014, 53, 6224-6234.

29. "Synthesis, photovoltaic performances and TD-DFT modeling of push-pull diacetylide platinum complexes in TiO2 based dye-sensitized solar cells", S. Gauthier, B. Caro, F. Robin-Le Guen, N. Bhuvanesh, J. A. Gladysz, L. Wojcik, N. Le Poul, A. Planchat, Y. Pellegrin, E. Blart, D. Jacquemin, F. Odobel, Dalton Trans. 2014, 43, 11233-11242.

28. "Locally induced and self-induced “electro-click” onto self-assembled monolayer: writing and reading with SECM under unbiased condition”, S. Lhenry, Y. R. Leroux, C. Orain, F. Conan, N. Cosquer, N. Le Poul, O. Reinaud, Y. Le Mest, P. Hapiot, Langmuir 2014, 30, 4501-4508.

27. "Insights into water coordination associated with the Cu(II)/Cu(I) electron transfer at a biomimetic Cu centre”, A. G. Porras Gutiérrez, J. Zeitouny, A. Gomila, B. Douziech, N. Cosquer, F. Conan, O. Reinaud, P. Hapiot, Y. Le Mest, C. Lagrost, N. Le Poul, Dalton Trans. 2014, 43, 6436-6445.

26. "Synthesis of an unsymmetrical N-functionalized triazacyclononane ligand and its Cu(II) complex", M. Roger, V. Patinec, R. Tripier, S. Triki, N. Le Poul, Y. Le Mest, Inorg. Chim. Acta 2014, 417, 201-207.

25. "Aza and cyanobridged tripodal dinuclear copper(II) complexes: Electrochemical studies and structural evidence for an original azacyanocarbanion", A. Gomila, B. Douziech, N. Cosquer, N. Le Poul, F. Michaud, C. J. Gomez-Garcia, Y. Le Mest, F. Conan, Inorg. Chim. Acta 2014, 411, 67-76.

24. "Electrocatalytic reduction of nitrite ions by a copper complex attached as SAMs on gold by “self-induced electroclick”: Enhancement of the catalytic rate by surface coverage decrease “, C. Orain, A. G. Porras-Gutiérrez, F. Evoung Evoung, C. Charles, N. Cosquer, A. Gomila, F. Conan, Y. Le Mest, N. Le Poul, Electrochem. Commun. 2013, 34, 204-207.

23. "Bowl vs. funnel supramolecular concept for Cu(I) Complexes within the biomimetic tris- imidazole core", J. Gout, A. Višnjevac, S. Rat, O. Bistri, N. Le Poul, Y. Le Mest, O. Reinaud, Eur. J. Inorg. Chem. 2013, 29, 5171-5180.

22. "Electrochemically-driven cup-and-ball Cu(I) and Cu(II) complexes", N. Menard, Y. Hériot, Y. Le Mest, O. Reinaud, N. Le Poul, B. Colasson, Chem. Eur. J. 2013, 19, 10611-106618.

21. "Electron transfer properties of mono- and diferrocenyl based Cu complexes attached as self-assembled monolayers on gold electrodes by “self-induced” electroclick", C. Orain, P. Le Poul,Y. Le Mest, N. Le Poul, J. Electroanal. Chem. 2013, 170, 48-58. 20. "Diferrocenylpyrylium salts and electron rich bispyran from oxidative coupling of ferrocenylpyran. Example of redox systems switched by proton transfer", F. Ba, N. Cabon, P. Le Poul, S. Kahlal, J.-Y. Saillard, N. Le Poul, S. Golhen, B. Caro and F. Robin-Le Guen, New J. Chem. 2013, 37, 2066-2081.

19. "Electrochemical behavior and dioxygen reactivity of tripodal dinuclear copper complexes linked by unsaturated rigid spacers", A. Gomila , N. Le Poul , J.-M. Kerbaol , N. Cosquer, S. Triki , B. Douziech , F. Conan, Y. Le Mest, Dalton Trans. 2013, 42, 2238-2253.

18. "Rate enhancement of the catechol oxidase activity of a series of biomimetic monocopper(II) complexes by introduction of non-coordinating groups in N-tripodal ligands", R. Marion, N. M. Saleh, N. Le Poul, D. Floner, O. Lavastre, F. Geneste, New J. Chem. 2012, 36, 1828-1835.

17. "Synthesis and studies of a water-soluble and air-stable Cu(I)/Cu(II) open-shell funnel complex", G. Thiabaud, A. Brugnara, M. Carboni, N. Le Poul, B. Colasson, Y. Le Mest, O. Reinaud, Org. Lett. 2012, 14, 2500-2503.

16. "A generic platform for the addressable functionalisation of electrode surfaces through self-induced “electroclick”", C. Orain, N. Le Poul, A. Gomila, N. Cosquer, O. Reinaud, F. Conan, Y. Le Mest, Chem. Eur. J. 2012, 18, 594-602.

15. "Tris(triazolyl) calix[6]arene-based zinc and copper funnel complexes: imidazole-like or pyridine-like? A comparative study", B. Colasson, N. Le Poul, Y. Le Mest, O. Reinaud, B. Colasson, N. Le Poul, Y. Le Mest, O. Reinaud, Inorg. Chem. 2011, 50, 10985–10993.

14. "Self-induced “electroclick” immobilization of a copper complex onto self-assembled monolayers on a gold electrode", A. Gomila, N. Le Poul, N. Cosquer, J.-M. Kerbaol, J.- M. Noël, M. T. Reddy, I. Jabin, O. Reinaud, F. Conan, Y. Le Mest, Dalton Trans. 2010, 39, 11516-11518.

13. “Electrochemically triggered double translocation of two different metal ions with a ditopic calix[6]arene ligand”, B. Colasson, N. Le Poul, Y. Le Mest, O. Reinaud, J. Am. Chem. Soc. 2010, 132, 4393-4398.

12. “Ferrocenyl and pyridyl methylenepyrans as potential precursors of organometallic electron-rich extended bipyrans : synthesis, characterization and crystal structure”, F. Ba, F. Robin-Le Guen, N. Cabon, P. Le Poul, S. Golhen, N. Le Poul, B. Caro, J. Organomet. Chem. 2010, 695, 235-243.

11.“Mimicking the protein channel to a metal center: Effect of a funnel complex on dissociative vs associative copper redox chemistry”, N. Le Poul, B. Douziech, J. Zeitouny, G. Thiabaud, H. Colas, F. Conan, N. Cosquer, I. Jabin, C. Lagrost, P. Hapiot, O. Reinaud, Y. Le Mest, J. Am. Chem. Soc. 2009, 131, 17800-17807.

10."Diferrocenylbispyrylium salts and electron-rich diferrocenylbispyran from oxidative coupling of ferrocenylpyran. Induced electron transfer C-C bond making/breaking involving a metallocenyl radical intermediate”, F. Ba, N. Cabon, F. Robin-Le Guen, P. Le Poul, N. Le Poul, Y. Le Mest, S. Golhen, B. Caro, Organometallics 2008, 27, 6396-6399.

9. “Synthesis of bis 2H- and 4H-chalcogenapyrans and benzochalcogenapyrans via Pd° catalyzed dimerization of Fisher type carbene complexes. Redox properties and electronic structure of these new extended electron rich molecules”, N. Faux, F. Robin- Le Guen, P. Le Poul, B. Caro, N. Le Poul, Y. Le Mest, S.J. Green, S. Le Roux, S. Kahlal, J.-Y. Saillard, Tetrahedron 2007, 63, 7142-7153.

8. "Monocopper center embedded in a biomimetic cavity : from supramolecular control of copper coordination to redox regulation”, N. Le Poul, M. Campion, B. Douziech, Y. Rondelez, L. Le Clainche, O. Reinaud, Y. Le Mest, J. Am. Chem. Soc. 2007, 129, 8801- 8810.

7. "Determination of heterogeneous electron-transfer kinetics of decamethyferrocene at low temperatures (120 K < T < 200 K) by a.c. impedance”, N. Le Poul, S.J. Green, Y. Le Mest, J. Electroanal. Chem. 2006, 596, 47-56.

6. “Electrochemical behavior of the tris(pyridine)-Cu funnel complexes : an overall induced-fit process involving an entatic state through a supramolecular stress”, N. Le Poul, M. Campion, G. Izzet, B. Douziech, O. Reinaud, Y. Le Mest, J. Am. Chem. Soc. 2005, 127, 5280-5281.

5. “Sub-Tc electron transfer at the HTSC/polymer interface”, N. Le Poul, S.J. Green, J.P. Attfield, J. Chem. Soc. Chem. Commun. 2003, 638-639. 4. “Development of potentiometric ion sensors based on insertion materials as sensitive element”, N. Le Poul, E. Baudrin, M. Morcrette, S. Gwizdala, C. Masquelier, J.-M. Tarascon, Solid State Ionics 2003, 159,149-158.

3. “Sub-Tc electron transfer at the Hg-HTSC/liquid-electrolyte interface”, S.J. Green, N. Le Poul, P.P. Edwards, G. Peacock, J. Am. Chem. Soc. 2003, 13, 3686-3687.

2. “Synthesis of new highly conjugated bis-(4H-pyrans) involving electron rich polyene linkage, by Pd(0) catalytic coupling of g-methylenepyran Fischer type carbene complexes”, F. Robin-Le Guen, P. Le Poul, B. Caro, N. Faux, N. Le Poul, S.J. Green, Tetrahedron Letters 2002, 43, 3967-3970.

1. “Reactivity of carbanions of Fischer-type carbene complexes with pyrylium salts. Synthesis and characterisation of new g-methylenepyran carbene complexes via an addition – oxidation - deprotonation process”, B. Caro, P. Le Poul, F. Robin-Le Guen, J.-Y. Saillard, S. Kahlal, C. Moinet, N. Le Poul, J. Vaissermann, Tetrahedron 2002, 58, 7519-7530.