Small Refineries and Oil Field Processors: Opportunities and Challenges
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1 Refinery and Petrochemical Processes
3 1 Refinery and Petrochemical Processes 1.1 Introduction The combination of high demand for electric cars and higher automobile engine effi- ciency in the future will mean less conversion of petroleum into fuels. However, the demand for petrochemicals is forecast to rise due to the increase in world popula- tion. With this, it is expected that modern and more innovative technologies will be developed to serve the growth of the petrochemical market. In a refinery process, petroleum is converted into petroleum intermediate prod- ucts, including gases, light/heavy naphtha, kerosene, diesel, light gas oil, heavy gas oil, and residue. From these intermediate refinery product streams, several fuels such as fuel gas, liquefied petroleum gas, gasoline, jet fuel, kerosene, auto diesel, and other heavy products such as lubricants, bunker oil, asphalt, and coke are obtained. In addition, these petroleum intermediates can be further processed and separated into products for petrochemical applications. In this chapter, petroleum will be introduced first. Petrochemicals will be intro- duced in the second part of the chapter. Petrochemicals – the main subject of this book – will address three major areas, (i) the production of the seven cornerstone petrochemicals: methane and synthesis gas, ethylene, propylene, butene, benzene, toluene, and xylenes; (ii) the uses of the seven cornerstone petrochemicals, and (iii) the technology to separate petrochemicals into individual components. 1.2 Petroleum Petroleum is derived from the Latin words “petra” and “oleum,” which means “rock” and “oil,” respectively. Petroleum also is known as crude oil or fossil fuel. It is a thick, flammable, yellow-to-black mixture of gaseous, liquid, and solid hydrocarbons formed from the remains of plants and animals. -
The Chemistry of Refining Crude Oil SPN#12
The Chemistry of Refining Crude Oil SPN LESSON #12 LEARNING OUTCOME: Students come to view energy from several viewpoints. They work with the processes of • Phase changes and the many energy transformations and transfers involved in that physical change; • chemical change and the energy it releases. LESSON OVERVIEW: The fractional distillation of crude oil is featured. This major fossil fuel of the modern age is viewed as an example of stored chemical energy. Alcohol and water are separated and recaptured by taking advantage of the differences in the two substances’ boiling points. The many components of crude oil are explored and students are introduced to organic chemical formulas, characteristics of changes in phases, and laboratory distillation procedures. GRADE-LEVEL APPROPRIATENESS: This Level II Physical Setting, technology education lesson is intended for students in grades 5–8. MATERIALS (per group) Safety goggles (per person) Lab apron (per person) Bunsen burner Ring stand with utility clamp Metal pan 3 medium test tubes Test tube rack Boiling chip 2-hole stopper 10 cm glass tubing with 90o bend Thermometer 15 mL of isopropyl alcohol–water mixture nyserda.ny.gov/School-Power-Naturally Stirring rod Graduated cylinder Grease pencil or marker 4 paper strips, 10 cm x 1 cm 60 cm rubber tubing SAFETY Students should be made familiar with proper laboratory safety procedures including the location of fire extinguishers, fire blankets, and safety showers (where available). Instruct students regarding the proper and safe use of Bunsen burners and matches, and stress the importance of keeping the volatile components of the fractional distillation away from the flame during the collection of distillates. -
Concept Papers for Changes to Rule 9-1 -- Refinery Fuel Gas Sulfur
Draft: 05‐14‐15 Appendix C: Concept Paper for Changes to Rule 9‐1: Refinery Fuel Gas Sulfur Limits Rules to Be Amended or Drafted Regulation of refinery fuel gas (RFG) requires amendments to Air District Regulation 9, Rule 1, Sulfur Dioxide. Goals The goal of this rulemaking is to achieve technically feasible and cost‐effective sulfur dioxide (SO2) emission reductions from RFG systems at Bay Area refineries. Background The lightest components of crude oil separated by a refinery’s atmospheric fractionator are methane and ethane, which are also the primary components of natural gas. At petroleum refineries, these products are not produced in marketable quantities, but are used as fuel in the numerous onsite steam generators and process heaters. When produced at a refinery, this product is called refinery fuel gas (RFG). Pipeline natural gas may be used as a supplemental fuel when needed to enhance the quality of RFG or when there is not enough RFG available. Unlike, pipeline natural gas, refinery fuel gas often contains significant quantities of sulfur that occur naturally in crude oil. When burned, these sulfur compounds are converted to SO2. Process and Source Description RFG can contain between a few hundred and a few thousand parts per million‐volume (ppmv) sulfur in the form of hydrogen sulfide (H2S), carbonyl sulfide (COS), and organic sulfur compounds, such as mercaptans. During combustion, the sulfur in all of these compounds will oxidize to form SO2, which is a criteria air pollutant and a precursor to particulate matter. Scrubbing with an amine or caustic solution can be effective at removing H2S and some acidic sulfur containing compounds, but is generally ineffective at removing nonacidic sulfur compounds. -
Olive Oil Jars Left Behind By
live oil jars left behind by the ancient Greeks are testament to our centuries- old use of cooking oil. Along with salt and pepper, oil Oremains one of the most important and versatile tools in your kitchen. It keeps food from sticking to pans, adds flavor and moisture, and conducts the heat that turns a humble stick of potato into a glorious french fry. Like butter and other fats, cooking oil also acts as a powerful solvent, unleashing fat-soluble nutrients and flavor compounds in everything from tomatoes and onions to spices and herbs. It’s why so many strike recipes begin with heating garlic in oil rather than, say, simmering it in water. The ancient Greeks didn’t tap many cooking oils. (Let’s see: olive oil, olive oil, or—ooh, this is exciting!—how about olive oil?) But you certainly can. From canola to safflower to grapeseed to walnut, each oil has its own unique flavor (or lack thereof), aroma, and optimal cooking temperature. Choosing the right kind for the task at hand can save you money, boost your health, and improve your cooking. OK, so you probably don’t stop to consider your cooking oil very often. But there’s a surprising amount to learn about What’s this? this liquid gold. BY VIRGINIAWILLIS Pumpkin seed oil suspended in corn oil—it looks like a homemade Lava Lamp! 84 allrecipes.com PHOTOS BY KATE SEARS WHERE TO store CANOLA OIL GRAPESEED OIL are more likely to exhibit the characteristic YOUR OIL flavor and aroma of their base nut or seed. -
Liquefied Petroleum Gas (LPG)
Liquefied Petroleum Gas (LPG) Demand, Supply and Future Perspectives for Sudan Synthesis report of a workshop held in Khartoum, 12-13 December 2010 The workshop was funded by UKaid from the Department for International Development Cover image: © UNAMID / Albert Gonzalez Farran This report is available online at: www.unep.org/sudan Disclaimer The material in this report does not necessarily represent the views of any of the organisations involved in the preparation and hosting of the workshop. It must be noted that some time has passed between the workshop and the dissemination of this report, during which some important changes have taken place, not least of which is the independence of South Sudan, a fact which greatly affects the national energy context. Critically, following the independence, the rate of deforestation in the Republic of Sudan has risen from 0.7% per year to 2.2% per year, making many of the discussions within this document all the more relevant. Whilst not directly affecting the production of LPG, which is largely derived from oil supplies north of the border with South Sudan, the wider context of the economics of the energy sector, and the economy as a whole, have changed. These changes are not reflected in this document. This being said, it is strongly asserted that this document still represents a useful contribution to the energy sector, particularly given its contribution to charting the breadth of perspectives on LPG in the Republic of Sudan. Liquefied Petroleum Gas (LPG) Demand, Supply and Future Perspectives for Sudan Synthesis report of a workshop held in Khartoum, 12-13 December 2010 A joint publication by: Ministry of Environment, Forestry and Physical Development – Sudan, Ministry of Petroleum – Sudan, United Kingdom Department for International Development, United Nations Development Programme and United Nations Environment Programme Table of contents Acronyms and abbreviations . -
Saturated, Unsaturated, and Trans Fat
Lifestyle Coach Facilitation Guide: Post-Core Fats - Saturated, Unsaturated, and Trans Fat Content Overview This session answers the question “what is fat?” It explores the different types of fat, and shows which fats are healthy (monounsaturated and polyunsaturated) and which fats are unhealthy (saturated and trans fat). Participants learn tips for choosing foods with healthy fats and avoiding foods with unhealthy fats. More information on cholesterol appears in Post-Core Session: Heart Health. Lifestyle Coach Preparation Checklist Materials Post-core handouts: What is Fat? Healthy Fats: Omega-3, Monounsaturated and Polyunsaturated Fats to Avoid: Saturated and Trans Fat Identifying Healthier Alternatives Tips for Choosing the Best Types of Fat “Food and Activity Trackers” “Lifestyle Coach’s Log” Balance scale Post-Core: Fats – Saturated, Unsaturated, and Trans Fat Key messages to reinforce A completely fat-free diet would not be healthy, yet it is important that fat be consumed in moderation. The main types of “healthy” fats are monounsaturated and polyunsaturated. The main types of “unhealthy” fats are saturated and trans fat. Saturated fats are primarily found in foods that come from animals, such as meat and dairy. Try to switch to lower-fat versions of these foods. In order to avoid trans fat, look on nutrition labels for ingredients such as “partially hydrogenated” oils or shortening. In addition, look for trans fat in the nutritional information in products like commercially baked cookies, crackers, and pies, and fried foods. After the session At the completion of this session, do the following: Use the “Notes and Homework Page” for notes and follow-up tasks. -
Water-Based Lubricants: Development, Properties, and Performances
lubricants Review Water-Based Lubricants: Development, Properties, and Performances Md Hafizur Rahman 1, Haley Warneke 1, Haley Webbert 1, Joaquin Rodriguez 1, Ethan Austin 1, Keli Tokunaga 1, Dipen Kumar Rajak 2 and Pradeep L. Menezes 1,* 1 Department of Mechanical Engineering, University of Nevada-Reno, Reno, NV 89557, USA; mdhafi[email protected] (M.H.R.); [email protected] (H.W.); [email protected] (H.W.); [email protected] (J.R.); [email protected] (E.A.); [email protected] (K.T.) 2 Department of Mechanical Engineering, Sandip Institute of Technology & Research Centre, Nashik 422213, India; [email protected] * Correspondence: [email protected] Abstract: Water-based lubricants (WBLs) have been at the forefront of recent research, due to the abundant availability of water at a low cost. However, in metallic tribo-systems, WBLs often exhibit poor performance compared to petroleum-based lubricants. Research and development indicate that nano-additives improve the lubrication performance of water. Some of these additives could be categorized as solid nanoparticles, ionic liquids, and bio-based oils. These additives improve the tribological properties and help to reduce friction, wear, and corrosion. This review explored different water-based lubricant additives and summarized their properties and performances. Viscosity, density, wettability, and solubility are discussed to determine the viability of using water-based nano-lubricants compared to petroleum-based lubricants for reducing friction and wear in machining. Water-based liquid lubricants also have environmental benefits over petroleum-based lubricants. Further research is needed to understand and optimize water-based lubrication for tribological systems completely. -
CCS: Applications and Opportunities for the Oil and Gas Industry
Brief CCS: Applications and Opportunities for the Oil and Gas Industry Guloren Turan, General Manager, Advocacy and Communications May 2020 Contents 1. Introduction ................................................................................................................................... 2 2. Applications of CCS in the oil and gas industry ............................................................................. 2 3. Conclusion ..................................................................................................................................... 4 Page | 1 1. Introduction Production and consumption of oil and gas currently account for over half of global greenhouse gas emissions associated with energy use1 and so it is imperative that the oil and gas industry reduces its emissions to meet the net-zero ambition. At the same time, the industry has also been the source and catalyst of the leading innovations in clean energy, which includes carbon capture and storage (CCS). Indeed, as oil and gas companies are evolving their business models in the context of the energy transition, CCS has started to feature more prominently in their strategies and investments. CCS is versatile technology that can support the oil and gas industry’s low-carbon transition in several ways. Firstly, CCS is a key enabler of emission reductions in the industries’ operations, whether for compliance reasons, to meet self-imposed performance targets or to benefit from CO2 markets. Secondly, spurred by investor and ESG community sentiment, the industry is looking to reduce the carbon footprint of its products when used in industry, since about 90% of emissions associated with oil and gas come from the ultimate combustion of hydrocarbons – their scope 3 emissions. Finally, CCS can be a driver of new business lines, such as clean power generation and clean hydrogen production. From the perspective of the Paris Agreement, however, the deployment of CCS globally remains off track. -
Facts About Alberta's Oil Sands and Its Industry
Facts about Alberta’s oil sands and its industry CONTENTS Oil Sands Discovery Centre Facts 1 Oil Sands Overview 3 Alberta’s Vast Resource The biggest known oil reserve in the world! 5 Geology Why does Alberta have oil sands? 7 Oil Sands 8 The Basics of Bitumen 10 Oil Sands Pioneers 12 Mighty Mining Machines 15 Cyrus the Bucketwheel Excavator 1303 20 Surface Mining Extraction 22 Upgrading 25 Pipelines 29 Environmental Protection 32 In situ Technology 36 Glossary 40 Oil Sands Projects in the Athabasca Oil Sands 44 Oil Sands Resources 48 OIL SANDS DISCOVERY CENTRE www.oilsandsdiscovery.com OIL SANDS DISCOVERY CENTRE FACTS Official Name Oil Sands Discovery Centre Vision Sharing the Oil Sands Experience Architects Wayne H. Wright Architects Ltd. Owner Government of Alberta Minister The Honourable Lindsay Blackett Minister of Culture and Community Spirit Location 7 hectares, at the corner of MacKenzie Boulevard and Highway 63 in Fort McMurray, Alberta Building Size Approximately 27,000 square feet, or 2,300 square metres Estimated Cost 9 million dollars Construction December 1983 – December 1984 Opening Date September 6, 1985 Updated Exhibit Gallery opened in September 2002 Facilities Dr. Karl A. Clark Exhibit Hall, administrative area, children’s activity/education centre, Robert Fitzsimmons Theatre, mini theatre, gift shop, meeting rooms, reference room, public washrooms, outdoor J. Howard Pew Industrial Equipment Garden, and Cyrus Bucketwheel Exhibit. Staffing Supervisor, Head of Marketing and Programs, Senior Interpreter, two full-time Interpreters, administrative support, receptionists/ cashiers, seasonal interpreters, and volunteers. Associated Projects Bitumount Historic Site Programs Oil Extraction demonstrations, Quest for Energy movie, Paydirt film, Historic Abasand Walking Tour (summer), special events, self-guided tours of the Exhibit Hall. -
Wastewater Treatment and Reuse in the Oil & Petrochem Industry
Engineering Conferences International ECI Digital Archives Wastewater and Biosolids Treatment and Reuse: Proceedings Bridging Modeling and Experimental Studies Spring 6-13-2014 Wastewater treatment and reuse in the oil & petrochem industry – a case study Alberto Girardi Dregemont Follow this and additional works at: http://dc.engconfintl.org/wbtr_i Part of the Environmental Engineering Commons Recommended Citation Alberto Girardi, "Wastewater treatment and reuse in the oil & petrochem industry – a case study" in "Wastewater and Biosolids Treatment and Reuse: Bridging Modeling and Experimental Studies", Dr. Domenico Santoro, Trojan Technologies and Western University Eds, ECI Symposium Series, (2014). http://dc.engconfintl.org/wbtr_i/46 This Conference Proceeding is brought to you for free and open access by the Proceedings at ECI Digital Archives. It has been accepted for inclusion in Wastewater and Biosolids Treatment and Reuse: Bridging Modeling and Experimental Studies by an authorized administrator of ECI Digital Archives. For more information, please contact [email protected]. Wastewater Treatment and Reuse In Oil & Petrochemical Industry Otranto, June 2014 COMPANY PROFILE DEGREMONT, THE WATER TREATMENT SPECIALISTS 4 areas of 5 areas of expertise: activities: . Drinking water production . Design & Build plants . Operation & . Reverse osmosis desalination Services plants . Urban wastewater treatment . Equipment and reuse plants . BOT / PPP . Biosolid treatment systems . Industrial water production and wastewater treatment units plants 2 Wastewater Treatment and Reuse COMPANY PROFILE DEGREMONT, THE WATER TREATMENT SPECIALISTS In over For industrials: For local authorities: 70 . Energy . Drinking water countries, . Upstream oil and gas Degrémont offers . Desalination . Refining and solutions to local . Urban wastewater authorities and petrochemicals . Sludge and biosolids industries . Chemicals . Pharmaceutical, cosmetics, fine chemicals . -
Redalyc.BIODEGRADATION of CRUDE OIL by Pseudomonas
Tecnología Química ISSN: 0041-8420 [email protected] Universidad de Oriente Cuba Pérez Silva, Rosa M.; Ábalos Rodríguez, Arelis; Gómez Montes de Oca, José M.; Cantero Moreno, Domingo BIODEGRADATION OF CRUDE OIL BY Pseudomonas aeruginosa AT18 STRAIN Tecnología Química, vol. XXVI, núm. 1, enero-abril, 2006, pp. 70-77 Universidad de Oriente Santiago de Cuba, Cuba Available in: http://www.redalyc.org/articulo.oa?id=445543749010 How to cite Complete issue Scientific Information System More information about this article Network of Scientific Journals from Latin America, the Caribbean, Spain and Portugal Journal's homepage in redalyc.org Non-profit academic project, developed under the open access initiative BIODEGRADATION OF CRUDE OIL BY Pseudomonas aeruginosa AT18 STRAIN Rosa M. Pérez Silva1; Arelis Ábalos Rodríguez2*; José M. Gómez Montes de Oca1, Domingo Cantero Moreno1 1Department of Chemical Engineering Technology, Food Technology and Environmental Technologies, Faculty of Sciences, University of Cadiz, Campus Rio San Pedro, 11510 Puerto Real (Cadiz), Spain 2Centro de Estudios de Biotecnología Industrial. Facultad de Ciencias Naturales. Universidad de Oriente. Santiago de Cuba, Cuba The bioremediation of hydrocarbons in contaminated soils by Pseudomonas aeruginosa AT18 strain grow on crude oil, lubricant oil, naphthalene, toluene and, kerosene as unique carbon source and energy was isolated from samples soil contaminated with crude oil on Petroleum Refinery Hnos Díaz in Santiago de Cuba city. The biodegradative activity of the strain achieved 81% with the mixture Mesa 30/Puerto Escondido (8:2) crude oil. Key words: biodegradation, Pseudomonas aeruginosa. _____________________ Pseudomonas aeruginosa AT18, es capaz de usar hidrocarburos del petróleo como fuente de carbono y energía para su metabolismo. -
Weekly Petroleum Status Report
Summary of Weekly Petroleum Data for the week ending September 17, 2021 U.S. crude oil refinery inputs averaged 15.3 million barrels per day during the week ending September 17, 2021 which was 1.0 million barrels per day more than the previous week’s average. Refineries operated at 87.5% of their operable capacity last week. Gasoline production increased last week, averaging 9.6 million barrels per day. Distillate fuel production increased last week, averaging 4.5 million barrels per day. U.S. crude oil imports averaged 6.5 million barrels per day last week, increased by 0.7 million barrels per day from the previous week. Over the past four weeks, crude oil imports averaged about 6.1 million barrels per day, 18.9% more than the same four-week period last year. Total motor gasoline imports (including both finished gasoline and gasoline blending components) last week averaged 1.1 million barrels per day, and distillate fuel imports averaged 184,000 barrels per day. U.S. commercial crude oil inventories (excluding those in the Strategic Petroleum Reserve) decreased by 3.5 million barrels from the previous week. At 414.0 million barrels, U.S. crude oil inventories are about 8% below the five year average for this time of year. Total motor gasoline inventories increased by 3.5 million barrels last week and are about 3% below the five year average for this time of year. Finished gasoline and blending components inventories both increased last week. Distillate fuel inventories decreased by 2.6 million barrels last week and are about 14% below the five year average for this time of year.