Process Descriptions: an Introductory Library Research Assignment on Chemical Processes for First Year Students
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Metallurgical Engineering
ENSURING THE EXPERTISE TO GROW SOUTH AFRICA Discipline-specific Training Guideline for Candidate Engineers in Metallurgical Engineering R-05-MET-PE Revision No.: 2: 25 July 2019 ENGINEERING COUNCIL OF SOUTH AFRICA Tel: 011 6079500 | Fax: 011 6229295 Email: [email protected] | Website: www.ecsa.co.za ENSURING THE Document No.: Effective Date: Revision No.: 2 R-05-MET-PE 25/07/2019 Subject: Discipline-specific Training Guideline for Candidate Engineers in Metallurgical Engineering Compiler: Approving Officer: Next Review Date: Page 2 of 46 MB Mtshali EL Nxumalo 25/07/2023 TABLE OF CONTENTS DEFINITIONS ............................................................................................................................ 3 BACKGROUND ......................................................................................................................... 5 1. PURPOSE OF THIS DOCUMENT ......................................................................................... 5 2. AUDIENCE............................................................................................................................. 6 3. PERSONS NOT REGISTERED AS CANDIDATES OR NOT BEING TRAINED UNDER COMMITMENT AND UNDERTAKING (C&U) ..................................................... 7 4. ORGANISING FRAMEWORK FOR OCCUPATIONS ............................................................. 7 4.1 Extractive Metallurgical Engineering ..................................................................................... 8 4.2 Mineral Processing Engineering .......................................................................................... -
Opportunities for Catalysis in the 21St Century
Opportunities for Catalysis in The 21st Century A Report from the Basic Energy Sciences Advisory Committee BASIC ENERGY SCIENCES ADVISORY COMMITTEE SUBPANEL WORKSHOP REPORT Opportunities for Catalysis in the 21st Century May 14-16, 2002 Workshop Chair Professor J. M. White University of Texas Writing Group Chair Professor John Bercaw California Institute of Technology This page is intentionally left blank. Contents Executive Summary........................................................................................... v A Grand Challenge....................................................................................................... v The Present Opportunity .............................................................................................. v The Importance of Catalysis Science to DOE.............................................................. vi A Recommendation for Increased Federal Investment in Catalysis Research............. vi I. Introduction................................................................................................ 1 A. Background, Structure, and Organization of the Workshop .................................. 1 B. Recent Advances in Experimental and Theoretical Methods ................................ 1 C. The Grand Challenge ............................................................................................. 2 D. Enabling Approaches for Progress in Catalysis ..................................................... 3 E. Consensus Observations and Recommendations.................................................. -
Process Intensification in the Synthesis of Organic Esters : Kinetics
PROCESS INTENSIFICATION IN THE SYNTHESIS OF ORGANIC ESTERS: KINETICS, SIMULATIONS AND PILOT PLANT EXPERIMENTS By Venkata Krishna Sai Pappu A DISSERTATION Submitted to Michigan State University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Chemical Engineering 2012 ABSTRACT PROCESS INTENSIFICATION IN THE SYNTHESIS OF ORGANIC ESTERS: KINETICS, SIMULATIONS AND PILOT PLANT EXPERIMENTS By Venkata Krishna Sai Pappu Organic esters are commercially important bulk chemicals used in a gamut of industrial applications. Traditional routes for the synthesis of esters are energy intensive, involving repeated steps of reaction typically followed by distillation, signifying the need for process intensification (PI). This study focuses on the evaluation of PI concepts such as reactive distillation (RD) and distillation with external side reactors in the production of organic acid ester via esterification or transesterification reactions catalyzed by solid acid catalysts. Integration of reaction and separation in one column using RD is a classic example of PI in chemical process development. Indirect hydration of cyclohexene to produce cyclohexanol via esterification with acetic acid was chosen to demonstrate the benefits of applying PI principles in RD. In this work, chemical equilibrium and reaction kinetics were measured using batch reactors for Amberlyst 70 catalyzed esterification of acetic acid with cyclohexene to give cyclohexyl acetate. A kinetic model that can be used in modeling reactive distillation processes was developed. The kinetic equations are written in terms of activities, with activity coefficients calculated using the NRTL model. Heat of reaction obtained from experiments is compared to predicted heat which is calculated using standard thermodynamic data. The effect of cyclohexene dimerization and initial water concentration on the activity of heterogeneous catalyst is also discussed. -
Chemical Process Modeling in Modelica
Chemical Process Modeling in Modelica Ali Baharev Arnold Neumaier Fakultät für Mathematik, Universität Wien Nordbergstraße 15, A-1090 Wien, Austria Abstract model creation involves only high-level operations on a GUI; low-level coding is not required. This is the Chemical process models are highly structured. Infor- desired way of input. Not surprisingly, this is also mation on how the hierarchical components are con- how it is implemented in commercial chemical process nected helps to solve the model efficiently. Our ulti- simulators such as Aspen PlusR , Aspen HYSYSR or mate goal is to develop structure-driven optimization CHEMCAD R . methods for solving nonlinear programming problems Nonlinear system of equations are generally solved (NLP). The structural information retrieved from the using optimization techniques. AMPL (FOURER et al. JModelica environment will play an important role in [12]) is the de facto standard for model representation the development of our novel optimization methods. and exchange in the optimization community. Many Foundations of a Modelica library for general-purpose solvers for solving nonlinear programming (NLP) chemical process modeling have been built. Multi- problems are interfaced with the AMPL environment. ple steady-states in ideal two-product distillation were We are aiming to create a ‘Modelica to AMPL’ con- computed as a proof of concept. The Modelica source verter. One could use the Modelica toolchain to create code is available at the project homepage. The issues the models conveniently on a GUI. After exporting the encountered during modeling may be valuable to the Modelica model in AMPL format, the already existing Modelica language designers. software environments (solvers with AMPL interface, Keywords: separation, distillation column, tearing AMPL scripts) can be used. -
Taking Reactive Distillation to the Next Level of Process Intensification, Chemical Engineering Transactions, 69, 553-558 DOI: 10.3303/CET1869093 554
553 A publication of CHEMICAL ENGINEERING TRANSACTIONS VOL. 69, 2018 The Italian Association of Chemical Engineering Online at www.aidic.it/cet Guest Editors: Elisabetta Brunazzi, Eva Sorensen Copyright © 2018, AIDIC Servizi S.r.l. ISBN 978-88-95608-66-2; ISSN 2283-9216 DOI: 10.3303/CET1869093 Taking Reactive Distillation to the Next Level of Process Intensification Anton A. Kissa,b,*, Megan Jobsona a The University of Manchester, School of Chemical Engineering and Analytical Science, Centre for Process Integration, Sackville Street, The Mill, Manchester M13 9PL, United Kingdom b University of Twente, Sustainable Process Technology, PO Box 217, 7500 AE Enschede, The Netherlands [email protected] Reactive distillation (RD) is an efficient process intensification technique that integrates catalytic chemical reaction and distillation in a single apparatus. The process is also known as catalytic distillation when a solid catalyst is used. RD technology has many key advantages such as reduced capital investment and significant energy savings, as it can surpass equilibrium limitations, simplify complex processes, increase product selectivity and improve the separation efficiency. But RD is also constrained by thermodynamic requirements (related to volatility differences and heat of reaction), overlapping of the reaction and distillation operating conditions, and the availability of catalysts that are active, selective and with sufficient longevity. This paper is the first to provide insights into novel reactive distillation technologies that combine RD principles with other intensified distillation technologies – e.g. dividing-wall columns, cyclic distillation, HiGee distillation, and heat integrated distillation column – potentially leading to new processes and applications. 1. Introduction Reactive distillation (RD) is one of the best success stories of process intensification technology – developed since the early 1920s – that made a strong positive impact in the chemical process industry (CPI). -
CHEMICAL REACTION ENGINEERING* Current Status and Future Directions
[eJij9iviews and opinions CHEMICAL REACTION ENGINEERING* Current Status and Future Directions M. P. DUDUKOVIC and petrochemical industry provided a fertile ground Washington University for further development of reaction engineering con St. Louis, MO 63130 cepts. The final cornerstone of this new discipline was laid in 1957 by the First Symposium on Chemical HEMICAL REACTIONS have been used by man Reaction Engineering [3] which brought together and C kind since time immemorial to produce useful synthesized the European point of view. The Amer products such as wine, metals, etc. Nevertheless, the ican and European schools of thought were not identi unifying principles that today we call chemical reac cal, but in time they converged into the subject matter tion engineering were not developed until relatively a that we know today as chemical reaction engineering, short time ago. During the decade of the 1940's (not or CRE. The above chronology led to the establish even half a century ago!) a transition was made from ment of CRE as an accepted discipline over the span descriptive industrial chemistry to the conceptual un of a decade and a half. This does not imply that all the ification of reaction processes and reactor types. The principles important in CRE were discovered then. pioneering work in this area of industrial practice was The foundation for CRE had already been established done by Denbigh [1] in England. Then in 1947, by the early work of Frank-Kamenteski, Damkohler, Hougen and Watson [2] published the first textbook Zeldovitch, etc., but at that time they represented in the U.S. -
Chemical Engineering (CHE) 1
Chemical Engineering (CHE) 1 CHE 3113 Rate Operations II CHEMICAL ENGINEERING Prerequisites: CHE 3013, CHE 3333, and CHE 3473 with grades of "C" or better. (CHE) Description: Development and application of phenomenological and empirical models to the design and analysis of mass transfer and CHE 1112 Introduction to the Engineering of Coffee (LN) separations unit operations. Description: A non-mathematical introduction to the engineering aspects Credit hours: 3 of roasting and brewing coffee. Simple engineering concepts are used Contact hours: Lecture: 3 Contact: 3 to study methods for roasting and processing of coffee. The course will Levels: Undergraduate investigate techniques for brewing coffee such as a drip coffee, pour-over, Schedule types: Lecture French press, AeroPress, and espresso. Laboratory experiences focus on Department/School: Chemical Engineering roasting and brewing coffee to teach introductory engineering concepts CHE 3123 Chemical Reaction Engineering to both engineers and non-engineers. Prerequisites: CHE 3013, CHE 3333, and CHE 3473 with grades of "C" or Credit hours: 2 better. Contact hours: Lecture: 1 Lab: 2 Contact: 3 Description: Principles of chemical kinetics rate concepts and data Levels: Undergraduate treatment. Elements of reactor design principles for homogeneous Schedule types: Lab, Lecture, Combined lecture and lab systems; introduction to heterogeneous systems. Course previously Department/School: Chemical Engineering offered as CHE 4473. General Education and other Course Attributes: Scientific Investigation, Credit hours: 3 Natural Sciences Contact hours: Lecture: 3 Contact: 3 CHE 2033 Introduction to Chemical Process Engineering Levels: Undergraduate Prerequisites: CHEM 1515, ENSC 2213, and ENGR 1412 with grades of "C" Schedule types: Lecture or better and concurrent enrollment in MATH 2233 or MATH 3263. -
Chemical & Biological Engineering Department History (PDF)
Chemical & Biological Engineering The University of Alabama A Century of Excellence and Quality A Legacy of Leadership 1910 – 2010 By Gary C. April University Research Professor & Head (Emeritus) A Century of Excellence and Quality A Legacy of Leadership 1910-2010 Gary C. April University Research Professor & Head Emeritus Chemical & Biological Engineering The University of Alabama October 2010 ii Dedication The author would like to dedicate this brief history of the Chemical Engineering Department at The University of Alabama to Lynne, his wife, partner and soul mate of 48 years, to his children, Andrew, Brian and Elizabeth, who lived most of their lives while he was a professor there, and to his granddaughters, Andrea, Abigail, Caroline and Olivia who continue to provide him with encouragement by sharing a vision for the future that is filled with hope and opportunities. iii Table of Contents Preface ..................................................................................................................... v 1. The Beginning of Engineering Education at The University of Alabama 1 ................................................................................................................. 1 2. The Emergence of the Chemical Engineering Profession ........................... 7 3. Chemical Engineering at the University of Alabama – A Century of Excellence and Quality – A Legacy of Leadership 5 ....................................... 11 4. The Significance of Who We Are ................................................................. -
Business Process Engineering Release 3.0 E20216-03
Oracle® Practitioner Guide Business Process Engineering Release 3.0 E20216-03 December 2010 Business Process Engineering, Release 3.0 E20216-03 Copyright © 2010, Oracle and/or its affiliates. All rights reserved. Primary Author: Mark Wilkins Contributing Author: Dave Chappelle, Bob Hensle, Stephen Bennett, Anbu Krishnaswamy, Cliff Booth, Jeff McDaniel Contributor: Meera Srinivasan, Barry O’Reilly Warranty Disclaimer THIS DOCUMENT AND ALL INFORMATION PROVIDED HEREIN (THE "INFORMATION") IS PROVIDED ON AN "AS IS" BASIS AND FOR GENERAL INFORMATION PURPOSES ONLY. ORACLE EXPRESSLY DISCLAIMS ALL WARRANTIES OF ANY KIND, WHETHER EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE AND NON-INFRINGEMENT. ORACLE MAKES NO WARRANTY THAT THE INFORMATION IS ERROR-FREE, ACCURATE OR RELIABLE. ORACLE RESERVES THE RIGHT TO MAKE CHANGES OR UPDATES AT ANY TIME WITHOUT NOTICE. As individual requirements are dependent upon a number of factors and may vary significantly, you should perform your own tests and evaluations when making technology infrastructure decisions. This document is not part of your license agreement nor can it be incorporated into any contractual agreement with Oracle Corporation or its affiliates. If you find any errors, please report them to us in writing. Third Party Content, Products, and Services Disclaimer This document may provide information on content, products, and services from third parties. Oracle is not responsible for and expressly disclaim all warranties of any kind with respect to third-party content, products, and services. Oracle will not be responsible for any loss, costs, or damages incurred due to your access to or use of third-party content, products, or services. -
Master's Program in Chemical and Biochemical Engineering
Chemical and Biochemical Engineering Kemisk og Biokemisk Teknologi Master of Science (Kandidat) 2 years Master’s Program in Chemical and Biochemical Engineering Why get a master’s degree in chemical and bio- Holding a master’s degree in Chemical and Biochemical chemical engineering? Engineering from DTU you will be one of those engineers You have got a bachelor degree in a related field, you are with the scientific and technological capabilities needed to interested in commercial and sustainable chemical or bio- bring new chemical and biochemical products from incep- chemical transformation of raw materials to products, but tion to safe and economically viable production. You will be you are first and foremost interested in the research and at the forefront of chemical and biochemical engineering, development of methods and processes: Then DTU’s MSc in and you will be on your way to a rewarding career based on Chemical and Biochemical Engineering is the right two-year research and development. master’s program for you. Program Content The program is a research based four semester education, where three semesters are taken up by courses in different disciplines, giving you a basis and specialized knowledge lea- ding up to the semester-long MSc research project. You will set up your own individualized study plan, covering key aspects of chemical process technology and process-oriented aspects of biotechnology and biochemistry, chemical and biochemical pro- duct design, or the cross-disciplinary application of chemical engineering principles in energy and environmental engine- ering. These are the three focus areas of the program. Your MSc project, carried out at leading research centers of DTU, especially at DTU Chemical Engineering, often in col- laboration with major Danish companies, prepares you for research and development in academic or industrial contexts. -
Biochemical Thermodynamics
© Jones & Bartlett Learning, LLC. NOT FOR SALE OR DISTRIBUTION CHAPTER 1 Biochemical Thermodynamics Learning Objectives 1. Defi ne and use correctly the terms system, closed, open, surroundings, state, energy, temperature, thermal energy, irreversible process, entropy, free energy, electromotive force (emf), Faraday constant, equilibrium constant, acid dissociation constant, standard state, and biochemical standard state. 2. State and appropriately use equations relating the free energy change of reactions, the standard-state free energy change, the equilibrium constant, and the concentrations of reactants and products. 3. Explain qualitatively and quantitatively how unfavorable reactions may occur at the expense of a favorable reaction. 4. Apply the concept of coupled reactions and the thermodynamic additivity of free energy changes to calculate overall free energy changes and shifts in the concentrations of reactants and products. 5. Construct balanced reduction–oxidation reactions, using half-reactions, and calculate the resulting changes in free energy and emf. 6. Explain differences between the standard-state convention used by chemists and that used by biochemists, and give reasons for the differences. 7. Recognize and apply correctly common biochemical conventions in writing biochemical reactions. Basic Quantities and Concepts Thermodynamics is a system of thinking about interconnections of heat, work, and matter in natural processes like heating and cooling materials, mixing and separation of materials, and— of particular interest here—chemical reactions. Thermodynamic concepts are freely used throughout biochemistry to explain or rationalize chains of chemical transformations, as well as their connections to physical and biological processes such as locomotion or reproduction, the generation of fever, the effects of starvation or malnutrition, and more. -
Mixing, Crystallization and Separation
CRYSTALLIZATION AND PRECIPITATION ENGINEERING Alan Jones, Rudi Zauner and Stelios Rigopoulos Department of Chemical Engineering University College London, UK www.chemeng.ucl.ac.uk Acknowledgements to: Mohsen Al-Rashed, Andreas Schreiner and Terry Kougoulos; EPSRC, EU and GSK Outline of talk ! Introduction to crystals and crystallization ! The ideal well-mixed crystallizer ! Prediction of Crystal Size Distribution ! Mixing effects in real crystallizers ! Precipitation processes ! Crystallization processes ! Scale up ! Scale out ! Conclusions Crystallization Processes ! Crystallization is a core technology of many sectors in the chemical process and allied industries ! Involves a variety of business sectors, e.g. – Agrochemicals, catalysts, dyes/pigments, electronics, food/confectionery, health products, nano-materials, nuclear fuel, personal products & pharmaceuticals ! Processes can involve complex process chemistry together with non-ideal reactor hydrodynamics – Hence can be difficult to understand and scale-up from laboratory to production scale operation ! Crystallization also forms part of a wider process system Crystallization Process Systems Water Feed ‘Clean’ air Liquor Recycle to recycle Liquor to recycle Slurry Convey Liquor to recycle Screen Mill Hot air oversize PRODUCT CRYSTALS Mix, convey, etc. Jones, A.G. Crystallization Process Systems, Butterworth-Heinemann, 2002 CRYSTAL CHARACTERISTICS Crystals appear in many: ! sizes, ! shapes and ! forms, Which affect both: ! performance during processing, and ! quality in application