De Broglie and Schrödinger's External and Internal Wave Functions
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Lecture 32 Relevant Sections in Text: §3.7, 3.9 Total Angular Momentum
Physics 6210/Spring 2008/Lecture 32 Lecture 32 Relevant sections in text: x3.7, 3.9 Total Angular Momentum Eigenvectors How are the total angular momentum eigenvectors related to the original product eigenvectors (eigenvectors of Lz and Sz)? We will sketch the construction and give the results. Keep in mind that the general theory of angular momentum tells us that, for a 1 given l, there are only two values for j, namely, j = l ± 2. Begin with the eigenvectors of total angular momentum with the maximum value of angular momentum: 1 1 1 jj = l; j = ; j = l + ; m = l + i: 1 2 2 2 j 2 Given j1 and j2, there is only one linearly independent eigenvector which has the appro- priate eigenvalue for Jz, namely 1 1 jj = l; j = ; m = l; m = i; 1 2 2 1 2 2 so we have 1 1 1 1 1 jj = l; j = ; j = l + ; m = l + i = jj = l; j = ; m = l; m = i: 1 2 2 2 2 1 2 2 1 2 2 To get the eigenvectors with lower eigenvalues of Jz we can apply the ladder operator J− = L− + S− to this ket and normalize it. In this way we get expressions for all the kets 1 1 1 1 1 jj = l; j = 1=2; j = l + ; m i; m = −l − ; −l + ; : : : ; l − ; l + : 1 2 2 j j 2 2 2 2 The details can be found in the text. 1 1 Next, we consider j = l − 2 for which the maximum mj value is mj = l − 2. -
Path Integrals in Quantum Mechanics
Path Integrals in Quantum Mechanics Dennis V. Perepelitsa MIT Department of Physics 70 Amherst Ave. Cambridge, MA 02142 Abstract We present the path integral formulation of quantum mechanics and demon- strate its equivalence to the Schr¨odinger picture. We apply the method to the free particle and quantum harmonic oscillator, investigate the Euclidean path integral, and discuss other applications. 1 Introduction A fundamental question in quantum mechanics is how does the state of a particle evolve with time? That is, the determination the time-evolution ψ(t) of some initial | i state ψ(t ) . Quantum mechanics is fully predictive [3] in the sense that initial | 0 i conditions and knowledge of the potential occupied by the particle is enough to fully specify the state of the particle for all future times.1 In the early twentieth century, Erwin Schr¨odinger derived an equation specifies how the instantaneous change in the wavefunction d ψ(t) depends on the system dt | i inhabited by the state in the form of the Hamiltonian. In this formulation, the eigenstates of the Hamiltonian play an important role, since their time-evolution is easy to calculate (i.e. they are stationary). A well-established method of solution, after the entire eigenspectrum of Hˆ is known, is to decompose the initial state into this eigenbasis, apply time evolution to each and then reassemble the eigenstates. That is, 1In the analysis below, we consider only the position of a particle, and not any other quantum property such as spin. 2 D.V. Perepelitsa n=∞ ψ(t) = exp [ iE t/~] n ψ(t ) n (1) | i − n h | 0 i| i n=0 X This (Hamiltonian) formulation works in many cases. -
Gaussian Wave Packets
The Free Particle Gaussian Wave Packets The Gaussian wave packet initial state is one of the few states for which both the {|x i} and {|p i} basis representations are simple analytic functions and for which the time evolution in either representation can be calculated in closed analytic form. It thus serves as an excellent example to get some intuition about the Schr¨odinger equation. We define the {|x i} representation of the initial state to be 2 „ «1/4 − x 1 i p x 2 ψ (x, t = 0) = hx |ψ(0) i = e 0 e 4 σx (5.10) x 2 ~ 2 π σx √ The relation between our σx and Shankar’s ∆x is ∆x = σx 2. As we shall see, we 2 2 choose to write in terms of σx because h(∆X ) i = σx . Section 5.1 Simple One-Dimensional Problems: The Free Particle Page 292 The Free Particle (cont.) Before doing the time evolution, let’s better understand the initial state. First, the symmetry of hx |ψ(0) i in x implies hX it=0 = 0, as follows: Z ∞ hX it=0 = hψ(0) |X |ψ(0) i = dx hψ(0) |X |x ihx |ψ(0) i −∞ Z ∞ = dx hψ(0) |x i x hx |ψ(0) i −∞ Z ∞ „ «1/2 x2 1 − 2 = dx x e 2 σx = 0 (5.11) 2 −∞ 2 π σx because the integrand is odd. 2 Second, we can calculate the initial variance h(∆X ) it=0: 2 Z ∞ „ «1/2 − x 2 2 2 1 2 2 h(∆X ) i = dx `x − hX i ´ e 2 σx = σ (5.12) t=0 t=0 2 x −∞ 2 π σx where we have skipped a few steps that are similar to what we did above for hX it=0 and we did the final step using the Gaussian integral formulae from Shankar and the fact that hX it=0 = 0. -
Lecture 4 – Wave Packets
LECTURE 4 – WAVE PACKETS 1.2 Comparison between QM and Classical Electrons Classical physics (particle) Quantum mechanics (wave) electron is a point particle electron is wavelike * * motion described by F =ma for energy E, motion described by wavefunction & F = -∇ V (r) * − jωt Ψ()r,t = Ψ ()r e !ω = E * !2 & where V()r − potential energy - ∇2Ψ+V()rΨ=EΨ & 2m typically F due to electric fields from other - differential equation governing Ψ charges & V()r - (potential energy) - this is where the forces acting on the electron are taken into account probability density of finding electron at position & & Ψ()r ⋅ Ψ * ()r 1 p = mv,E = mv2 E = !ω, p = !k 2 & & & We shall now consider "free" electrons : F = 0 ∴ V()r = const. (for simplicity, take V ()r = 0) Lecture 4: Wave Packets September, 2000 1 Wavepackets and localized electrons For free electrons we have to solve Schrodinger equation for V(r) = 0 and previously found: & & * ()⋅ −ω Ψ()r,t = Ce j k r t - travelling plane wave ∴Ψ ⋅ Ψ* = C2 everywhere. We can’t conclude anything about the location of the electron! However, when dealing with real electrons, we usually have some idea where they are located! How can we reconcile this with the Schrodinger equation? Can it be correct? We will try to represent a localized electron as a wave pulse or wavepacket. A pulse (or packet) of probability of the electron existing at a given location. In other words, we need a wave function which is finite in space at a given time (i.e. t=0). -
Wave Nature of Matter: Made Easy (Lesson 3) Matter Behaving As a Wave? Ridiculous!
Wave Nature of Matter: Made Easy (Lesson 3) Matter behaving as a wave? Ridiculous! Compiled by Dr. SuchandraChatterjee Associate Professor Department of Chemistry Surendranath College Remember? I showed you earlier how Einstein (in 1905) showed that the photoelectric effect could be understood if light were thought of as a stream of particles (photons) with energy equal to hν. I got my Nobel prize for that. Louis de Broglie (in 1923) If light can behave both as a wave and a particle, I wonder if a particle can also behave as a wave? Louis de Broglie I’ll try messing around with some of Einstein’s formulae and see what I can come up with. I can imagine a photon of light. If it had a “mass” of mp, then its momentum would be given by p = mpc where c is the speed of light. Now Einstein has a lovely formula that he discovered linking mass with energy (E = mc2) and he also used Planck’s formula E = hf. What if I put them equal to each other? mc2 = hf mc2 = hf So for my photon 2 mp = hfhf/c/c So if p = mpc = hfhf/c/c p = mpc = hf/chf/c Now using the wave equation, c = fλ (f = c/λ) So mpc = hc /λc /λc= h/λ λ = hp So you’re saying that a particle of momentum p has a wavelength equal to Planck’s constant divided by p?! Yes! λ = h/p It will be known as the de Broglie wavelength of the particle Confirmation of de Broglie’s ideas De Broglie didn’t have to wait long for his idea to be shown to be correct. -
Quantum Field Theory*
Quantum Field Theory y Frank Wilczek Institute for Advanced Study, School of Natural Science, Olden Lane, Princeton, NJ 08540 I discuss the general principles underlying quantum eld theory, and attempt to identify its most profound consequences. The deep est of these consequences result from the in nite number of degrees of freedom invoked to implement lo cality.Imention a few of its most striking successes, b oth achieved and prosp ective. Possible limitation s of quantum eld theory are viewed in the light of its history. I. SURVEY Quantum eld theory is the framework in which the regnant theories of the electroweak and strong interactions, which together form the Standard Mo del, are formulated. Quantum electro dynamics (QED), b esides providing a com- plete foundation for atomic physics and chemistry, has supp orted calculations of physical quantities with unparalleled precision. The exp erimentally measured value of the magnetic dip ole moment of the muon, 11 (g 2) = 233 184 600 (1680) 10 ; (1) exp: for example, should b e compared with the theoretical prediction 11 (g 2) = 233 183 478 (308) 10 : (2) theor: In quantum chromo dynamics (QCD) we cannot, for the forseeable future, aspire to to comparable accuracy.Yet QCD provides di erent, and at least equally impressive, evidence for the validity of the basic principles of quantum eld theory. Indeed, b ecause in QCD the interactions are stronger, QCD manifests a wider variety of phenomena characteristic of quantum eld theory. These include esp ecially running of the e ective coupling with distance or energy scale and the phenomenon of con nement. -
Path Integrals, Matter Waves, and the Double Slit Eric R
University of Nebraska - Lincoln DigitalCommons@University of Nebraska - Lincoln Herman Batelaan Publications Research Papers in Physics and Astronomy 2015 Path integrals, matter waves, and the double slit Eric R. Jones University of Nebraska-Lincoln, [email protected] Roger Bach University of Nebraska-Lincoln, [email protected] Herman Batelaan University of Nebraska-Lincoln, [email protected] Follow this and additional works at: http://digitalcommons.unl.edu/physicsbatelaan Jones, Eric R.; Bach, Roger; and Batelaan, Herman, "Path integrals, matter waves, and the double slit" (2015). Herman Batelaan Publications. 2. http://digitalcommons.unl.edu/physicsbatelaan/2 This Article is brought to you for free and open access by the Research Papers in Physics and Astronomy at DigitalCommons@University of Nebraska - Lincoln. It has been accepted for inclusion in Herman Batelaan Publications by an authorized administrator of DigitalCommons@University of Nebraska - Lincoln. European Journal of Physics Eur. J. Phys. 36 (2015) 065048 (20pp) doi:10.1088/0143-0807/36/6/065048 Path integrals, matter waves, and the double slit Eric R Jones, Roger A Bach and Herman Batelaan Department of Physics and Astronomy, University of Nebraska–Lincoln, Theodore P. Jorgensen Hall, Lincoln, NE 68588, USA E-mail: [email protected] and [email protected] Received 16 June 2015, revised 8 September 2015 Accepted for publication 11 September 2015 Published 13 October 2015 Abstract Basic explanations of the double slit diffraction phenomenon include a description of waves that emanate from two slits and interfere. The locations of the interference minima and maxima are determined by the phase difference of the waves. -
Singlet NMR Methodology in Two-Spin-1/2 Systems
Singlet NMR Methodology in Two-Spin-1/2 Systems Giuseppe Pileio School of Chemistry, University of Southampton, SO17 1BJ, UK The author dedicates this work to Prof. Malcolm H. Levitt on the occasion of his 60th birthaday Abstract This paper discusses methodology developed over the past 12 years in order to access and manipulate singlet order in systems comprising two coupled spin- 1/2 nuclei in liquid-state nuclear magnetic resonance. Pulse sequences that are valid for different regimes are discussed, and fully analytical proofs are given using different spin dynamics techniques that include product operator methods, the single transition operator formalism, and average Hamiltonian theory. Methods used to filter singlet order from byproducts of pulse sequences are also listed and discussed analytically. The theoretical maximum amplitudes of the transformations achieved by these techniques are reported, together with the results of numerical simulations performed using custom-built simulation code. Keywords: Singlet States, Singlet Order, Field-Cycling, Singlet-Locking, M2S, SLIC, Singlet Order filtration Contents 1 Introduction 2 2 Nuclear Singlet States and Singlet Order 4 2.1 The spin Hamiltonian and its eigenstates . 4 2.2 Population operators and spin order . 6 2.3 Maximum transformation amplitude . 7 2.4 Spin Hamiltonian in single transition operator formalism . 8 2.5 Relaxation properties of singlet order . 9 2.5.1 Coherent dynamics . 9 2.5.2 Incoherent dynamics . 9 2.5.3 Central relaxation property of singlet order . 10 2.6 Singlet order and magnetic equivalence . 11 3 Methods for manipulating singlet order in spin-1/2 pairs 13 3.1 Field Cycling . -
Bouncing Oil Droplets, De Broglie's Quantum Thermostat And
Preprints (www.preprints.org) | NOT PEER-REVIEWED | Posted: 28 August 2018 doi:10.20944/preprints201808.0475.v1 Peer-reviewed version available at Entropy 2018, 20, 780; doi:10.3390/e20100780 Article Bouncing oil droplets, de Broglie’s quantum thermostat and convergence to equilibrium Mohamed Hatifi 1, Ralph Willox 2, Samuel Colin 3 and Thomas Durt 4 1 Aix Marseille Université, CNRS, Centrale Marseille, Institut Fresnel UMR 7249,13013 Marseille, France; hatifi[email protected] 2 Graduate School of Mathematical Sciences, the University of Tokyo, 3-8-1 Komaba, Meguro-ku, 153-8914 Tokyo, Japan; [email protected] 3 Centro Brasileiro de Pesquisas Físicas, Rua Dr. Xavier Sigaud 150,22290-180, Rio de Janeiro – RJ, Brasil; [email protected] 4 Aix Marseille Université, CNRS, Centrale Marseille, Institut Fresnel UMR 7249,13013 Marseille, France; [email protected] Abstract: Recently, the properties of bouncing oil droplets, also known as ‘walkers’, have attracted much attention because they are thought to offer a gateway to a better understanding of quantum behaviour. They indeed constitute a macroscopic realization of wave-particle duality, in the sense that their trajectories are guided by a self-generated surrounding wave. The aim of this paper is to try to describe walker phenomenology in terms of de Broglie-Bohm dynamics and of a stochastic version thereof. In particular, we first study how a stochastic modification of the de Broglie pilot-wave theory, à la Nelson, affects the process of relaxation to quantum equilibrium, and we prove an H-theorem for the relaxation to quantum equilibrium under Nelson-type dynamics. -
Bringing out the Dead Alison Abbott Reviews the Story of How a DNA Forensics Team Cracked a Grisly Puzzle
BOOKS & ARTS COMMENT DADO RUVIC/REUTERS/CORBIS DADO A forensics specialist from the International Commission on Missing Persons examines human remains from a mass grave in Tomašica, Bosnia and Herzegovina. FORENSIC SCIENCE Bringing out the dead Alison Abbott reviews the story of how a DNA forensics team cracked a grisly puzzle. uring nine sweltering days in July Bosnia’s Million Bones tells the story of how locating, storing, pre- 1995, Bosnian Serb soldiers slaugh- innovative DNA forensic science solved the paring and analysing tered about 7,000 Muslim men and grisly conundrum of identifying each bone the million or more Dboys from Srebrenica in Bosnia. They took so that grieving families might find some bones. It was in large them to several different locations and shot closure. part possible because them, or blew them up with hand grenades. This is an important book: it illustrates the during those fate- They then scooped up the bodies with bull- unspeakable horrors of a complex war whose ful days in July 1995, dozers and heavy earth-moving equipment, causes have always been hard for outsiders to aerial reconnais- and dumped them into mass graves. comprehend. The author, a British journalist, sance missions by the Bosnia’s Million It was the single most inhuman massacre has the advantage of on-the-ground knowl- Bones: Solving the United States and the of the Bosnian war, which erupted after the edge of the war and of the International World’s Greatest North Atlantic Treaty break-up of Yugoslavia and lasted from 1992 Commission on Missing Persons (ICMP), an Forensic Puzzle Organization had to 1995, leaving some 100,000 dead. -
5 the Dirac Equation and Spinors
5 The Dirac Equation and Spinors In this section we develop the appropriate wavefunctions for fundamental fermions and bosons. 5.1 Notation Review The three dimension differential operator is : ∂ ∂ ∂ = , , (5.1) ∂x ∂y ∂z We can generalise this to four dimensions ∂µ: 1 ∂ ∂ ∂ ∂ ∂ = , , , (5.2) µ c ∂t ∂x ∂y ∂z 5.2 The Schr¨odinger Equation First consider a classical non-relativistic particle of mass m in a potential U. The energy-momentum relationship is: p2 E = + U (5.3) 2m we can substitute the differential operators: ∂ Eˆ i pˆ i (5.4) → ∂t →− to obtain the non-relativistic Schr¨odinger Equation (with = 1): ∂ψ 1 i = 2 + U ψ (5.5) ∂t −2m For U = 0, the free particle solutions are: iEt ψ(x, t) e− ψ(x) (5.6) ∝ and the probability density ρ and current j are given by: 2 i ρ = ψ(x) j = ψ∗ ψ ψ ψ∗ (5.7) | | −2m − with conservation of probability giving the continuity equation: ∂ρ + j =0, (5.8) ∂t · Or in Covariant notation: µ µ ∂µj = 0 with j =(ρ,j) (5.9) The Schr¨odinger equation is 1st order in ∂/∂t but second order in ∂/∂x. However, as we are going to be dealing with relativistic particles, space and time should be treated equally. 25 5.3 The Klein-Gordon Equation For a relativistic particle the energy-momentum relationship is: p p = p pµ = E2 p 2 = m2 (5.10) · µ − | | Substituting the equation (5.4), leads to the relativistic Klein-Gordon equation: ∂2 + 2 ψ = m2ψ (5.11) −∂t2 The free particle solutions are plane waves: ip x i(Et p x) ψ e− · = e− − · (5.12) ∝ The Klein-Gordon equation successfully describes spin 0 particles in relativistic quan- tum field theory. -
The Statistical Interpretation of Entangled States B
The Statistical Interpretation of Entangled States B. C. Sanctuary Department of Chemistry, McGill University 801 Sherbrooke Street W Montreal, PQ, H3A 2K6, Canada Abstract Entangled EPR spin pairs can be treated using the statistical ensemble interpretation of quantum mechanics. As such the singlet state results from an ensemble of spin pairs each with an arbitrary axis of quantization. This axis acts as a quantum mechanical hidden variable. If the spins lose coherence they disentangle into a mixed state. Whether or not the EPR spin pairs retain entanglement or disentangle, however, the statistical ensemble interpretation resolves the EPR paradox and gives a mechanism for quantum “teleportation” without the need for instantaneous action-at-a-distance. Keywords: Statistical ensemble, entanglement, disentanglement, quantum correlations, EPR paradox, Bell’s inequalities, quantum non-locality and locality, coincidence detection 1. Introduction The fundamental questions of quantum mechanics (QM) are rooted in the philosophical interpretation of the wave function1. At the time these were first debated, covering the fifty or so years following the formulation of QM, the arguments were based primarily on gedanken experiments2. Today the situation has changed with numerous experiments now possible that can guide us in our search for the true nature of the microscopic world, and how The Infamous Boundary3 to the macroscopic world is breached. The current view is based upon pivotal experiments, performed by Aspect4 showing that quantum mechanics is correct and Bell’s inequalities5 are violated. From this the non-local nature of QM became firmly entrenched in physics leading to other experiments, notably those demonstrating that non-locally is fundamental to quantum “teleportation”.