2/853 – Hydride Generation Atomic Absorption Spectrometry
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Inventory Size (Ml Or G) 103220 Dimethyl Sulfate 77-78-1 500 Ml
Inventory Bottle Size Number Name CAS# (mL or g) Room # Location 103220 Dimethyl sulfate 77-78-1 500 ml 3222 A-1 Benzonitrile 100-47-0 100ml 3222 A-1 Tin(IV)chloride 1.0 M in DCM 7676-78-8 100ml 3222 A-1 103713 Acetic Anhydride 108-24-7 500ml 3222 A2 103714 Sulfuric acid, fuming 9014-95-7 500g 3222 A2 103723 Phosphorus tribromide 7789-60-8 100g 3222 A2 103724 Trifluoroacetic acid 76-05-1 100g 3222 A2 101342 Succinyl chloride 543-20-4 3222 A2 100069 Chloroacetyl chloride 79-04-9 100ml 3222 A2 10002 Chloroacetyl chloride 79-04-9 100ml 3222 A2 101134 Acetyl chloride 75-36-5 500g 3222 A2 103721 Ethyl chlorooxoacetate 4755-77-5 100g 3222 A2 100423 Titanium(IV) chloride solution 7550-45-0 100ml 3222 A2 103877 Acetic Anhydride 108-24-7 1L 3222 A3 103874 Polyphosphoric acid 8017-16-1 1kg 3222 A3 103695 Chlorosulfonic acid 7790-94-5 100g 3222 A3 103694 Chlorosulfonic acid 7790-94-5 100g 3222 A3 103880 Methanesulfonic acid 75-75-2 500ml 3222 A3 103883 Oxalyl chloride 79-37-8 100ml 3222 A3 103889 Thiodiglycolic acid 123-93-3 500g 3222 A3 103888 Tetrafluoroboric acid 50% 16872-11-0 1L 3222 A3 103886 Tetrafluoroboric acid 50% 16872-11-0 1L 3222 A3 102969 sulfuric acid 7664-93-9 500 mL 2428 A7 102970 hydrochloric acid (37%) 7647-01-0 500 mL 2428 A7 102971 hydrochloric acid (37%) 7647-01-0 500 mL 2428 A7 102973 formic acid (88%) 64-18-6 500 mL 2428 A7 102974 hydrofloric acid (49%) 7664-39-3 500 mL 2428 A7 103320 Ammonium Hydroxide conc. -
Enhancing the Efficacy of Antimicrobial Peptide BM2, Against Mono-Species Biofilms, with Detergents
Enhancing the efficacy of Antimicrobial peptide BM2, against mono-species biofilms, by combining with detergents A thesis submitted for the degree of Doctor of Clinical Dentistry (Endodontics) Arpana Arthi Devi Department of Oral Rehabilitation, School of Dentistry, University of Otago, Dunedin, New Zealand 2016 Abstract Title Enhancing the efficacy of antimicrobial peptide BM2, against mono-species biofilms, by combining with detergents. Aim To investigate if a detergent regime could enhance the antimicrobial ability of BM2. Method Strains of Enterococcus faecalis, Streptococcus gordonii, Streptococcus mutans, and Candida albicans were grown from glycerol stocks after confirmation of the strains. After subculturing single colonies were cultured in TSB and CSM liquid media for 24hr to obtain a microbial suspension which was adjusted to OD600nm = 0.5. Dilution series of the peptidomimetic BM2 and detergents were prepared in aqueous solution and minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) were determined using a broth micro-dilution method. Further on planktonic cells and monospecies biofilms were exposed to the detergent and BM2 combinations. The efficacy of BM2 and detergents at causing biofilm detachment was measured using a crystal violet based assay. Results Planktonic cells were easier to kill with some of the detergents in isolation or in combination with BM2. SDS and CTAB in combination with BM2 increased the efficacy of BM2 against the test organisms. Tween 20 did not kill any of the test organisms alone or in combination. Biofilms were harder to eradicate and detergent, BM2 combinations gave varied results for the different species tested. Detergents in combination with BM2 did not increase the efficacy of the antimicrobial peptide in disrupting S. -
Ethoxylation Reactor Modelling and Design
Ethoxylation Reactor Modelling and Design by Yen-ni Chiu Bachelor of Engineering (Chemical) UNSW A thesis submitted in fulfillment of the requirements for the degree of Doctor of Philosophy Facaulty of Engineering and Industrial Sciences Swinburne University of Technology Melbourne, Australia To Mum, Dad, Jess and Ted Abstract The manufacture of nonionic surfactants generally involves ethoxylation via ethylene oxide condensation onto a hydrophobe substrate, mostly in the presence of an alkaline catalyst. Nonionic surfactants are used widely in industrial applications, such as detergents, health and personal care, coatings, and polymers. In Australia, approximately one-third of the annual consumption of nonionic surfactants is imported from offshore manufacturers; the market is highly competitive with the local manufacturer facing increasing competition from imports. Optimisation is a pressing need for the current manufacturing plant of the industrial partner for this research project, Huntsman Corporation Australia Pty Limited, the sole domestic manufacturer of nonionic surfactants in Australia. Therefore, the objectives of this research project were • to gain a better understanding of the various chemical and physical processes occurring simultaneously in an ethoxylation process; • to identify the process limitation in an existing production plant operated by Huntsman Corporation Australia, and • to explore measures for enhancing the asset productivity of the production plant. An ethoxylation process working model, describing the chemical kinetics and the physical transport processes involved, was developed to aid the exploration of optimisation opportunities, which would otherwise be empirical. Accordingly, this research project was structured into a two-stage program. The first stage determined the ethoxylation kinetics experimentally. The second stage investigated the interactions of physical transport processes numerically using a computational fluid dynamics (CFD) technique. -
1 Abietic Acid R Abrasive Silica for Polishing DR Acenaphthene M (LC
1 abietic acid R abrasive silica for polishing DR acenaphthene M (LC) acenaphthene quinone R acenaphthylene R acetal (see 1,1-diethoxyethane) acetaldehyde M (FC) acetaldehyde-d (CH3CDO) R acetaldehyde dimethyl acetal CH acetaldoxime R acetamide M (LC) acetamidinium chloride R acetamidoacrylic acid 2- NB acetamidobenzaldehyde p- R acetamidobenzenesulfonyl chloride 4- R acetamidodeoxythioglucopyranose triacetate 2- -2- -1- -β-D- 3,4,6- AB acetamidomethylthiazole 2- -4- PB acetanilide M (LC) acetazolamide R acetdimethylamide see dimethylacetamide, N,N- acethydrazide R acetic acid M (solv) acetic anhydride M (FC) acetmethylamide see methylacetamide, N- acetoacetamide R acetoacetanilide R acetoacetic acid, lithium salt R acetobromoglucose -α-D- NB acetohydroxamic acid R acetoin R acetol (hydroxyacetone) R acetonaphthalide (α)R acetone M (solv) acetone ,A.R. M (solv) acetone-d6 RM acetone cyanohydrin R acetonedicarboxylic acid ,dimethyl ester R acetonedicarboxylic acid -1,3- R acetone dimethyl acetal see dimethoxypropane 2,2- acetonitrile M (solv) acetonitrile-d3 RM acetonylacetone see hexanedione 2,5- acetonylbenzylhydroxycoumarin (3-(α- -4- R acetophenone M (LC) acetophenone oxime R acetophenone trimethylsilyl enol ether see phenyltrimethylsilyl... acetoxyacetone (oxopropyl acetate 2-) R acetoxybenzoic acid 4- DS acetoxynaphthoic acid 6- -2- R 2 acetylacetaldehyde dimethylacetal R acetylacetone (pentanedione -2,4-) M (C) acetylbenzonitrile p- R acetylbiphenyl 4- see phenylacetophenone, p- acetyl bromide M (FC) acetylbromothiophene 2- -5- -
United States Patent (19) 11 Patent Number: 6,013,801 Köll, Deceased Et Al
US00601 3801A United States Patent (19) 11 Patent Number: 6,013,801 Köll, deceased et al. (45) Date of Patent: Jan. 11, 2000 54 METHOD FOR PRODUCING 4,590,223 5/1986 Arai et al. ........................... 544/401 X AMINOETHYLETHANOLAMINE AND/OR 5,455,352 10/1995 Huellmann et al. .................... 544/401 HYDROXYETHYL PPERAZINE FOREIGN PATENT DOCUMENTS 75 Inventors: Juhan Köll, deceased, late of Stenungsund, by Mall Koll, legal 0 354993 2/1990 European Pat. Off. ...... CO7C 213/06 representative; Magnus Frank, 2013 676 1/1972 Germany ....................... CO7D 51/64 Göteborg, both of Sweden 27 16946 10/1978 Germany ....................... CO7C 89/02 206670 2/1984 Germany. 73 Assignee: Akzo Nobel N.V., Arnhem, Netherlands 1512967 10/1989 Russian Federation ........ CO7C 91/12 21 Appl. No.: 08/875,871 OTHER PUBLICATIONS 22 PCT Filed: Jan. 11, 1996 86 PCT No.: PCT/EP96/00207 Ludwig Knorr und Henry W. Brownadon: Ueber Alkohol basen aus Aethylendiamin und uber das Aethylenbismor S371 Date: Oct. 30, 1998 pholin, Dec. 11, 1902 pp. 4470–4473. S 102(e) Date: Oct. 30, 1998 87 PCT Pub. No.: WO96/24576 Primary Examiner Michael G. Ambrose PCT Pub. Date: Aug. 15, 1996 Attorney, Agent, or Firm-Ralph J. Mancini 30 Foreign Application Priority Data 57 ABSTRACT Feb. 8, 1995 (SE) Sweden .................................. 9500444 A method for preparing aminoethylethanolamine, and/or hydroxyethylpiperazine is described. Reaction of ethylene 51) Int. Cl." ........................ C07D 295/88; CO7C 213/04 oxide with ethylendiamine, piperazine, or a mixture of both 52 U.S. Cl. ............................................. 544/401; 564/503 produces these compounds. The process is integrated into a 58 Field of Search ............................. -
Evaluation of Health Hazards by Exposure to N,N-Dimethyl-1,3-Propanediamine and Proposal of a Health Based Quality Criterion for Ambient Air
Evaluation of health hazards by exposure to N,N-Dimethyl-1,3-propanediamine and proposal of a health-based quality criterion for ambient air. Environmental Project No. 1493, 2013 Title: Editing: Evaluation of health hazards by exposure to N,N- Elsa Nielsen, Ole Ladefoged Dimethyl-1,3-propanediamine and proposal of a Division of Toxicology and Risk Assessment. health-based quality criterion for ambient air National Food Institute, Technical University of Denmark. Published by: The Danish Environmental Protection Agency Strandgade 29 1401 Copenhagen K Denmark www.mst.dk/english Year: ISBN no. 2013 978-87-93026-30-8 Disclaimer: When the occasion arises, the Danish Environmental Protection Agency will publish reports and papers concerning research and development projects within the environmental sector, financed by study grants provided by the Danish Environmental Protection Agency. It should be noted that such publications do not necessarily reflect the position or opinion of the Danish Environmental Protection Agency. However, publication does indicate that, in the opinion of the Danish Environmental Protection Agency, the content represents an important contribution to the debate surrounding Danish environmental policy. Sources must be acknowledged. 2 Fejl! Ingen tekst med den anførte typografi i dokumentet. Content CONTENT 3 PREFACE 5 1 GENERAL DESCRIPTION 6 1.1 IDENTITY 6 1.2 PHYSICAL / CHEMICAL PROPERTIES 6 1.3 PRODUCTION AND USE 7 1.4 ENVIRONMENTAL OCCURRENCE 7 1.5 ENVIRONMENTAL FATE 7 1.5.1 Air 7 1.5.2 Water 8 1.5.3 Soil 8 1.5.4 -
207/2015 3 Lääkeluettelon Aineet, Liite 1. Ämnena I Läkemedelsförteckningen, Bilaga 1
207/2015 3 LÄÄKELUETTELON AINEET, LIITE 1. ÄMNENA I LÄKEMEDELSFÖRTECKNINGEN, BILAGA 1. Latinankielinen nimi, Suomenkielinen nimi, Ruotsinkielinen nimi, Englanninkielinen nimi, Latinskt namn Finskt namn Svenskt namn Engelskt namn (N)-Hydroxy- (N)-Hydroksietyyli- (N)-Hydroxietyl- (N)-Hydroxyethyl- aethylprometazinum prometatsiini prometazin promethazine 2,4-Dichlorbenzyl- 2,4-Diklooribentsyyli- 2,4-Diklorbensylalkohol 2,4-Dichlorobenzyl alcoholum alkoholi alcohol 2-Isopropoxyphenyl-N- 2-Isopropoksifenyyli-N- 2-Isopropoxifenyl-N- 2-Isopropoxyphenyl-N- methylcarbamas metyylikarbamaatti metylkarbamat methylcarbamate 4-Dimethyl- ami- 4-Dimetyyliaminofenoli 4-Dimetylaminofenol 4-Dimethylaminophenol nophenolum Abacavirum Abakaviiri Abakavir Abacavir Abarelixum Abareliksi Abarelix Abarelix Abataceptum Abatasepti Abatacept Abatacept Abciximabum Absiksimabi Absiximab Abciximab Abirateronum Abirateroni Abirateron Abiraterone Acamprosatum Akamprosaatti Acamprosat Acamprosate Acarbosum Akarboosi Akarbos Acarbose Acebutololum Asebutololi Acebutolol Acebutolol Aceclofenacum Aseklofenaakki Aceklofenak Aceclofenac Acediasulfonum natricum Asediasulfoni natrium Acediasulfon natrium Acediasulfone sodium Acenocoumarolum Asenokumaroli Acenokumarol Acenocumarol Acepromazinum Asepromatsiini Acepromazin Acepromazine Acetarsolum Asetarsoli Acetarsol Acetarsol Acetazolamidum Asetatsoliamidi Acetazolamid Acetazolamide Acetohexamidum Asetoheksamidi Acetohexamid Acetohexamide Acetophenazinum Asetofenatsiini Acetofenazin Acetophenazine Acetphenolisatinum Asetofenoli-isatiini -
Fatty Acids: Fatty Acid Is a Carboxylic Acid Often with a Long Aliphatic Chain, Which Is Either Saturated Or Unsaturated
Introduction 1 Fatty Acids: Fatty acid is a carboxylic acid often with a long aliphatic chain, which is either saturated or unsaturated. Fatty acids and their derivatives are consumed in a wide variety because they are used as raw materials for a wide variety of industrial products like, paints, surfactant, textiles, plastics, rubber, cosmetics, foods and pharmaceuticals. Industrially, fatty acids are produced by the hydrolysis of triglycerides, with the removal of glycerol moiety. As mentioned before, fatty acids can be classified into two classes, the first is unsaturated fatty acid with one or more double bonds in the alkyl chain and the other is saturated fatty acid. Long chain 3-alkenoic acids are a family of polyunsaturated fatty acids which have in common a carbon–carbon double bond in the position 3. They are used as key precursors for synthesis of many organic compounds. There are many methods for the synthesis of such acids; here we will mention two of these methods. Nucleophilic substitution of allylic substrates with organometallic reagents, treatment of β-vinyl-β-propiolactone with butylmagnesium bromide in the presence of copper(I) iodide in THF at –30 o C, gave 3-nonenoic acid as a major product and 3-butyl-4-pentenoic acid with the ratio 98:2 respectively(1). Knoevenagel condensation of an aldehyde with malonic acid in the presence of organic bases was considerable value for the synthesis of unsaturated fatty acids. This reaction is mainly related to its application for the synthesis of α-β-unsaturated fatty acids. For the synthesis of β-γ-unsaturated fatty acids the Linstead modification (2) of the Knoevenagel condensation, in which triethanolamine or other tertiary amines are used. -
Predicting Distribution of Ethoxylation Homologues With
1 PREDICTING THE DISTRIBUTION OF ETHOXYLATION HOMOLOGUES WITH A PROCESS SIMULATOR Nathan Massey, Chemstations, Inc. Introduction Ethoxylates are generally obtained by additions of ethylene oxide (EO) to compounds containing dissociated protons. Substrates used for ethoxylation are primarily linear and branched C12-C18 alcohols, alkyl phenols, nonyl (propylene trimer) or decyl (propylene tetramer) groups, fatty acids and fatty acid derivatives. The addition of EO to a substrate containing acidic hydrogen is catalyzed by bases or Lewis acids. Amphoteric catalysts, as well as heterogeneous catalysts are also used. The degree of ethoxylation ( the moles of EO added per mole of substrate ) varies over wide ranges, in general between 3 and 40, and is chosen according to the intended use. As an illustration of how this distribution might be predicted using a process simulator, Chemcad was used to simulate the ethoxylation of Nonylphenols. Description of the Ethoxylation Chemistry The reaction mechanisms of base catalyzed and acid catalyzed ethoxylation differ, which affects the composition of the reaction products. In base catalyzed ethoxylation an alcoholate anion, formed initially by reaction with the catalyst ( alkali metal, alkali metal oxide, carbonate, hydroxide, or alkoxide ) nucleophilically attacks EO. The resulting union of the EO addition product can undergo an equilibrium reaction with the alcohol starting material or ethoxylated product, or can react further with EO: Figure 1 O RO- + H2CCH2 - - RO CH2CH2O O ROH H2CCH2 - - RO RO CH2CH2OH RO RO CH2CH2O 2 As Figure 1 illustrates, in alkaline catalyzed ethoxylations several reactions proceed in parallel. The addition of EO to an anion with the formation of an ether bond is irreversible. -
1 Zkoumadla ANGLICKO–ČESKÁ 2016 Acetic Acid, Dilute R1
7.4.2016 Zkoumadla ANGLICKO–ČESKÁ 2016 Vysvětlivky Times New Roman bold – název nového nebo změněného zkoumadla v ČL 2009 – Dopl. 2016, názvy označené N, jsou pro zkoumadla použitá v národních článcích Anglický název Český název Acacia Arabská klovatina R Acacia solution Arabská klovatina RS Acebutolol hydrochloride Acebutolol-hydrochlorid R Acetal Acetal R Acetaldehyde Acetaldehyd R Acetaldehyde ammonia trimer trihydrate Acetaldehyd-amoniak trimer trihydrát R Acetic acid, anhydrous Kyselina octová bezvodá R Acetic acid, glacial Kyselina octová ledová R Acetic acid Kyselina octová RS Acetic acid, dilute Kyselina octová zředěná RS Acetic acid, dilute R1 Kyselina octová zředěná RS1 Acetic anhydride Acetanhydrid R Acetic anhydride solution R1 Acetanhydrid RS1 Acetic anhydride-sulfuric acid solution Acetanhydrid v kyselině sírové RS Acetone Aceton R Acetonitrile Acetonitril R Acetonitrile for chromatography Acetonitril pro chromatografii R Acetonitrile R1 Acetonitril R1 Acetoxyvalerenic acid Kyselina acetoxyvalerenová R Acetylacetamide Acetylacetamid R Acetylacetone Acetylaceton R Acetylacetone reagent R1 Acetylaceton RS1 Acetylacetone reagent R2 Acetylaceton RS2 N-Acetyl-ε-caprolactam N-Acetyl-ε-kaprolaktam R Acetyl chloride Acetylchlorid R Acetylcholine chloride Acetylcholin-chlorid R Acetyleugenol Acetyleugenol R N-Acetylglucosamine N-Acetylglukosamin R Acetyl-11-keto-β-boswellic acid Kyselina acetyl-11-keto-β-boswellová R N-Acetylneuraminic acid Kyselina N-acetylneuraminová R N-Acetyltryptophan N-Acetyltryptofan Acetyltyrosine ethyl ester -
21 CFR Ch. I (4–1–09 Edition) § 173.25
§ 173.25 21 CFR Ch. I (4–1–09 Edition) ion exchange membranes intended for (2) Sulfonated anthracite coal meet- use in the treatment of bulk quantities ing the requirements of ASTM method of liquid food under the following pre- D388–38, Class I, Group 2, ‘‘Standard scribed conditions: Specifications for Classification of Coal (a) Identity. The membrane is a co- by Rank,’’ which is incorporated by polymer of ethanesulfonyl fluoride, 2- reference. Copies are available from [1-[difluoro-[(trifluoro- University Microfilms International, ethenyl)oxy]methyl]-1,2,2,2-tetrafluoro- 300 N. Zeeb Rd., Ann Arbor, MI 48106, or ethoxy]-1,1,2,2,-tetrafluoro-, with tetra- available for inspection at the National fluoroethylene that has been subse- Archives and Records Administration quently treated to hydrolyze the (NARA). For information on the avail- sulfonyl fluoride group to the sulfonic ability of this material at NARA, call acid. The Chemical Abstracts Service 202–741–6030, or go to: http:// name of this polymer is ethanesulfonic www.archives.gov/federallregister/ acid, 2-[1-[difluoro-[(trifluoro- codeloflfederallregulations/ ethenyl)oxy]methyl]-1,2,2,2-tetrafluoro- ibrllocations.html. ethoxy]-1,1,2,2,-tetrafluoro-, polymer (3) Sulfite-modified cross-linked phe- with tetrafluoroethane (CAS Reg. No. nol-formaldehyde, with modification 31175–20–9). resulting in sulfonic acid groups on (b) Optional adjuvant substances. The side chains. basic polymer identified in paragraph (4) Methacrylic acid-divinylbenzene (a) of this section may contain optional copolymer. adjuvant substances required in the (5) Cross-linked polystyrene, first production of such basic polymer. chloromethylated then aminated with These optional adjuvant substances trimethylamine, dimethylamine, di- may include substances used in accord- ethylenetriamine, or dimethylethanol- ance with § 174.5 of this chapter. -
EUROPEAN PHARMACOPOEIA 10.0 Index 1. General Notices
EUROPEAN PHARMACOPOEIA 10.0 Index 1. General notices......................................................................... 3 2.2.66. Detection and measurement of radioactivity........... 119 2.1. Apparatus ............................................................................. 15 2.2.7. Optical rotation................................................................ 26 2.1.1. Droppers ........................................................................... 15 2.2.8. Viscosity ............................................................................ 27 2.1.2. Comparative table of porosity of sintered-glass filters.. 15 2.2.9. Capillary viscometer method ......................................... 27 2.1.3. Ultraviolet ray lamps for analytical purposes............... 15 2.3. Identification...................................................................... 129 2.1.4. Sieves ................................................................................. 16 2.3.1. Identification reactions of ions and functional 2.1.5. Tubes for comparative tests ............................................ 17 groups ...................................................................................... 129 2.1.6. Gas detector tubes............................................................ 17 2.3.2. Identification of fatty oils by thin-layer 2.2. Physical and physico-chemical methods.......................... 21 chromatography...................................................................... 132 2.2.1. Clarity and degree of opalescence of