DOCSLIB.ORG

Lication in the Following Source

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Lication in the Following Source This is the author’s version of a work that was submitted/accepted for pub- lication in the following source: Frost, Ray L., Xi, Yunfei, Scholz, Ricardo, López, Andrés, Lima, Rosa Malena Fernandes, & Ferreira, Claudiane Moraes (2013) Vibra- tional spectroscopic characterization of the phosphate mineral series eosphorite–childrenite–(Mn,Fe)Al(PO4)(OH)2·(H2O). Vibrational Spec- troscopy, 67, pp. 14-21. This file was downloaded from: http://eprints.qut.edu.au/60932/ c c 2013 Elsevier B.V. Notice: Changes introduced as a result of publishing processes such as copy-editing and formatting may not be reflected in this document. For a definitive version of this work, please refer to the published source: http://dx.doi.org/10.1016/j.vibspec.2013.03.005 Vibrational spectroscopic characterization of the phosphate mineral series eosphorite- childrenite – (Mn,Fe)Al(PO4)(OH)2·(H2O) Ray L. Frosta, Yunfei Xia, Ricardo Scholzb, Claudiane Moraes Ferreirab a School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane Queensland 4001, Australia. b Geology Department, School of Mines, Federal University of Ouro Preto, Campus Morro do Cruzeiro, Ouro Preto, MG, 35,400-00, Brazil Abstract: The phosphate mineral series eosphorite-childrenite – (Mn,Fe)Al(PO4)(OH)2·(H2O) has been studied using a combination of electron probe analysis and vibrational spectroscopy. Eosphorite is the manganese rich mineral with lower iron content in comparison with the childrenite which has higher iron and lower manganese content. The determined formula of the minerals are (Mn0.71,Fe0.13,Ca0.01)(Al)1.03(PO4)1.07(OH1.85,F0.02)·2(H2O) and (Fe0.49,Mn0.35,Mg0.06,Ca0.04)(Al)1.03(PO4)1.05(OH)1.80·2(H2O). Raman spectroscopy enabled the observation of bands at 969, 978 and 1011 cm-1 assigned to monohydrogen phosphate, phosphate and dihydrogen phosphate units. Differences are observed in the area of the peaks between the two eosphorite minerals. -1 Raman bands at 562, 595, and 608 cm are assigned to the ν4 out of plane bending modes of -1 the PO4, HPO4 and H2PO4 units; Raman bands at 405, 427 and 466 cm are attributed to the ν2 modes of these units. Raman bands of the hydroxyl and water stretching modes are observed. Key words: eosphorite, childrenite, phosphate, pegmatite, Raman spectroscopy, infrared spectroscopy Author to whom correspondence should be addressed ([email protected]) P +61 7 3138 2407 F: +61 7 3138 1804 1 Introduction Eosphorite is a pink manganese mineral with formula MnAl(PO4)(OH)2·(H2O) which crystallises in a monoclinic crystal system [1] and forms prismatic crystals which form radiating clusters. The mineral shows pseudo-orthrhombic morphology due to twinning. The mineral ocurs worldwide in pegamatites [2-7] and is always associated with other phosphate minerals [8]. Eosphorite forms a solid solution series with the mineral childrenite [9-11]. Childrenite's formula is (Fe, Mn)AlPO4(OH)2·H2O and differs from eosphorite by being rich in iron instead of manganese. The structures of the two minerals are the same and therefore it would be expected that their differences in physical properties between the two would be related to the iron/manganese content. Eosphorite is less dense and is generally pinkish to rose-red in color whereas childrenite's colors tends towards various shades of brown. In terms of crystal habits the two also differ. Eosphorite forms prismatic, slender crystals and rosettes. Childrenite forms tabular or bladed individuals or lamellar aggregates. It has been said that the two different habits belie their solid solution relationship. In this work, samples of the mineral series eosphorite and childrenite from different pegmatites from Minas Gerais were studied. Characterization include chemistry via Electron Probe Microanalysis in the WDS mode (EPMA) and spectroscopic characterization of the structure with infrared and Raman. Experimental Samples description and preparation The eosphorite and childrenite samples studied in this work were obtained from the collection of the Geology Department of the Federal University of Ouro Preto, Minas Gerais, Brazil, with sample code SAA-090 and SAA-072 respectively. The samples are from two different granitic pegmatites from Minas Gerais, Brazil. Sample SAA-072 was collected from the Ponte do Piauí mine, located in the Piauí valley, municipality of Itinga. The region is well-known as an important source of rare phosphates 2 and gemological minerals. The pegmatite is located in the Araçuaí pegmatite district, one of the subdivisions of the Eastern Brazilian Pegmatite province [12]. The pegmatite is mined for gemstones and samples for the collectors market. It is heterogeneous with well-developed mineralogical and textural zoning. The primary mineral association is represented by quartz, muscovite, microcline, schorl and almandine-spessartine. The secondary association is mainly composed by albite, Li bearing micas, cassiterite, elbaite and hydrothermal rose quartz. In the Ponte do Piauí pegmatite, secondary phosphates, namely childrenite, eosphorite, fluorapatite, zanazziite, occur in miarolitic cavities in association with albite, quartz and muscovite. Childrenite grows usually along the surface of quartz crystals and in albite agregates. Sample SAA-090 was collected from Roberto mine, a granitic pegmatite located in Divino das Laranjeiras east of Minas Gerais. The region is situated 65 km ENE of Governador Valadares. The region is well-known as an important source of rare minerals such as brazilianite. The pegmatite is located in the Conselheiro Pena pegmatite district, also one of the subdivisions of the Eastern Brazilian Pegmatite province (EBP). The pegmatite is mined for rare minerals for the collectors market. It is heterogeneous with well-developed mineralogical and textural zoning. The primary mineral association is represented by quartz, muscovite, microcline, schorl, almandine-spessartine and triphylite. The secondary association is mainly composed by albite, quartz crystals and a number of secondary phosphates, namely eosphorite, fluorapatite, zanazziite and brazilianite. The phosphates occur in miarolitic cavities. The sample was gently crushed and the associated minerals were removed under a stereomicroscope Leica MZ4. The eosphorite and childrenite samples were phase analyzed by X-ray diffraction. Scanning electron microscopy (SEM) was applied to support the mineralogical chemical Scanning electron microscopy (SEM) Experiments and analyses involving electron microscopy were performed in the Center of Microscopy of the Universidade Federal de Minas Gerais, Belo Horizonte, Minas Gerais, Brazil (http://www.microscopia.ufmg.br). Eosphorite and childrenite single crystals were coated with a 5 nm layer of evaporated Au. Secondary Electron and Backscattering Electron images were obtained using a JEOL JSM- 3 6360LV equipment. Qualitative and semi-quantitative chemical analysis in the EDS mode were performed with a ThermoNORAN spectrometer model Quest and was applied to support the mineral characterization and to determine the major elements to be measured by Electron probe micro-analysis. Electron probe micro-analysis (EPMA) The quantitative chemical analysis of eosphorite and childrenite single crystals was carried via EPMA. The chemical analysis was carried out with a Jeol JXA8900R spectrometer from the Physics Department of the Federal University of Minas Gerais, Belo Horizonte. For each selected element was used the following standards: Fe and Mg – olivin, Mn – rodhonite, P and Ca - Apatite Artimex, Al - Corundum and F - Fluorite. The epoxy embedded eosphorite and childrenite crystals was polished in the sequence of 9μm, 6μm and 1μm diamond paste MetaDI® II Diamond Paste – Buhler, using water as a lubricant, with a semi-automatic MiniMet® 1000 Grinder-Polisher – Buehler. Finally, the epoxy embedded samples was coated with a thin layer of evaporated carbon. The electron probe microanalysis in the WDS (wavelength dispersive spectrometer) mode was obtained at 15 kV accelerating voltage and beam current of 10 nA. Chemical formula was calculated on the basis of seven oxygen atoms (O, F, OH, H2O). Raman microprobe spectroscopy Crystals of eosphorite were placed on a polished metal surface on the stage of an Olympus BHSM microscope, which is equipped with 10x, 20x, and 50x objectives. The microscope is part of a Renishaw 1000 Raman microscope system, which also includes a monochromator, a filter system and a CCD detector (1024 pixels). The Raman spectra were excited by a Spectra-Physics model 127 He-Ne laser producing highly polarised light at 633 nm and collected at a nominal resolution of 2 cm-1 and a precision of ± 1 cm-1 in the range between 200 and 4000 cm-1. Repeated acquisitions on the crystals using the highest magnification (50x) were accumulated to improve the signal to noise ratio of the spectra. Raman Spectra were calibrated using the 520.5 cm-1 line of a silicon wafer. The Raman spectrum of at least 10 crystals was collected to ensure the consistency of the spectra. Infrared spectroscopy Infrared spectra were obtained using a Nicolet Nexus 870 FTIR spectrometer with a smart endurance single bounce diamond ATR cell. Spectra over the 4000525 cm-1 range were 4 obtained by the co-addition of 128 scans with a resolution of 4 cm-1 and a mirror velocity of 0.6329 cm/s. Spectra were co-added to improve the signal to noise ratio. Spectral manipulation such as baseline correction/adjustment and smoothing were performed using the Spectracalc software package GRAMS (Galactic Industries Corporation, NH, USA). Band component analysis was undertaken using the Jandel ‘Peakfit’ software package that enabled the type of fitting function to be selected and allows specific parameters to be fixed or varied accordingly. Band fitting was done using a Lorentzian-Gaussian cross-product function with the minimum number of component bands used for the fitting process. The Gaussian-Lorentzian ratio was maintained at values greater than 0.7 and fitting was undertaken until reproducible results were obtained with squared correlations of r2 greater than 0.995.
Load more

Recommended publications
  • L. Jahnsite, Segelerite, and Robertsite, Three New Transition Metal Phosphate Species Ll. Redefinition of Overite, an Lsotype Of
    American Mineralogist, Volume 59, pages 48-59, 1974 l. Jahnsite,Segelerite, and Robertsite,Three New TransitionMetal PhosphateSpecies ll. Redefinitionof Overite,an lsotypeof Segelerite Pnur BnnN Moone Thc Departmcntof the GeophysicalSciences, The Uniuersityof Chicago, Chicago,Illinois 60637 ilt. lsotypyof Robertsite,Mitridatite, and Arseniosiderite Peur BmaN Moonp With Two Chemical Analvsesbv JUN Iro Deryrtrnent of GeologicalSciences, Haraard Uniuersity, Cambridge, Massrchusetts 02 I 38 Abstract Three new species,-jahnsite, segelerite, and robertsite,-occur in moderate abundance as late stage products in corroded triphylite-heterosite-ferrisicklerite-rockbridgeite masses, associated with leucophosphite,hureaulite, collinsite, laueite, etc.Type specimensare from the Tip Top pegmatite, near Custer, South Dakota. Jahnsite, caMn2+Mgr(Hro)aFe3+z(oH)rlPC)oln,a 14.94(2),b 7.14(l), c 9.93(1)A, p 110.16(8)", P2/a, Z : 2, specific gavity 2.71, biaxial (-), 2V large, e 1.640,p 1.658,t l.6lo, occurs abundantly as striated short to long prismatic crystals, nut brown, yellow, yellow-orange to greenish-yellowin color.Formsarec{001},a{100},il2oll, jl2}ll,ft[iol],/tolll,nt110],andz{itt}. Segeierite,CaMg(HrO)rFes+(OH)[POdz, a 14.826{5),b 18.751(4),c7.30(1)A, Pcca, Z : 8, specific gaavity2.67, biaxial (-), 2Ylarge,a 1.618,p 1.6t5, z 1.650,occurs sparingly as striated yellow'green prismaticcrystals, with c[00], r{010}, nlll0l and qll2l } with perfect {010} cleavage'It is the Feg+-analogueofoverite; a restudy on type overite revealsthe spacegroup Pcca and the ideal formula CaMg(HrO)dl(OH)[POr]r. Robertsite,carMna+r(oH)o(Hro){Ponlr, a 17.36,b lg.53,c 11.30A,p 96.0o,A2/a, Z: 8, specific gravity3.l,T,cleavage[l00] good,biaxial(-) a1.775,8 *t - 1.82,2V-8o,pleochroismextreme (Y, Z = deep reddish brown; 17 : pale reddish-pink), @curs as fibrous massesand small wedge- shapedcrystals showing c[001 f , a{1@}, qt031}.
    [Show full text]
  • Kosnarite Kzr2(PO4)3 C 2001-2005 Mineral Data Publishing, Version 1
    Kosnarite KZr2(PO4)3 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Hexagonal, pseudocubic. Point Group: 32/m. As rhombohedral pseudocubic crystals, to 0.9 mm, with {1012} and tiny {0001}. Physical Properties: Cleavage: Perfect on {1012}. Fracture: Conchoidal. Tenacity: Brittle. Hardness = 4.5 D(meas.) = 3.194(2) D(calc.) = 3.206 Optical Properties: Transparent to translucent. Color: Pale blue to blue-green, bluish gray, nearly colorless. Streak: White. Luster: Vitreous. Optical Class: Uniaxial (+). ω = 1.656(2) = 1.682(2) Cell Data: Space Group: R3c. a = 8.687(2) c = 23.877(7) Z = 6 X-ray Powder Pattern: Mt. Mica, Maine, USA. 4.329 (100), 3.806 (90), 2.928 (90), 6.41 (50), 4.679 (50), 2.502 (50), 1.903 (45) Chemistry: (1) (2) (3) P2O5 43.3 42.2 42.04 ZrO2 44.5 47.9 48.66 HfO2 0.5 0.9 FeO 0.2 < 0.1 MnO 1.0 < 0.1 Na2O 1.4 < 0.1 K2O 8.7 9.25 9.30 Rb2O 0.25 0.2 F 0.20 0.2 −O=F2 0.08 0.08 Total 99.97 100.57 100.00 (1) Mt. Mica, Maine, USA; by electron microprobe, total Fe as FeO, total Mn as MnO; corresponds to (K0.93Na0.08Rb0.01)Σ=1.02(Zr1.81Na0.15Mn0.07Fe0.01Hf0.01)Σ=2.05 [P1.02(O3.98F0.02)Σ=4.00]3. (2) Black Mountain, Maine, USA; by electron microprobe, total Fe as FeO, total Mn as MnO; corresponds to (K0.99Rb0.01)Σ=1.00(Zr1.96Hf0.02)Σ=1.98 [P1.00(O3.98F0.02)Σ=4.00]3.
    [Show full text]
  • Mineral Processing
    Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19
    [Show full text]
  • The Secondary Phosphate Minerals from Conselheiro Pena Pegmatite District (Minas Gerais, Brazil): Substitutions of Triphylite and Montebrasite Scholz, R.; Chaves, M
    The secondary phosphate minerals from Conselheiro Pena Pegmatite District (Minas Gerais, Brazil): substitutions of triphylite and montebrasite Scholz, R.; Chaves, M. L. S. C.; Belotti, F. M.; Filho, M. Cândido; Filho, L. Autor(es): A. D. Menezes; Silveira, C. Publicado por: Imprensa da Universidade de Coimbra URL persistente: URI:http://hdl.handle.net/10316.2/31441 DOI: DOI:http://dx.doi.org/10.14195/978-989-26-0534-0_27 Accessed : 2-Oct-2021 20:21:49 A navegação consulta e descarregamento dos títulos inseridos nas Bibliotecas Digitais UC Digitalis, UC Pombalina e UC Impactum, pressupõem a aceitação plena e sem reservas dos Termos e Condições de Uso destas Bibliotecas Digitais, disponíveis em https://digitalis.uc.pt/pt-pt/termos. Conforme exposto nos referidos Termos e Condições de Uso, o descarregamento de títulos de acesso restrito requer uma licença válida de autorização devendo o utilizador aceder ao(s) documento(s) a partir de um endereço de IP da instituição detentora da supramencionada licença. Ao utilizador é apenas permitido o descarregamento para uso pessoal, pelo que o emprego do(s) título(s) descarregado(s) para outro fim, designadamente comercial, carece de autorização do respetivo autor ou editor da obra. Na medida em que todas as obras da UC Digitalis se encontram protegidas pelo Código do Direito de Autor e Direitos Conexos e demais legislação aplicável, toda a cópia, parcial ou total, deste documento, nos casos em que é legalmente admitida, deverá conter ou fazer-se acompanhar por este aviso. pombalina.uc.pt digitalis.uc.pt 9 789892 605111 Série Documentos A presente obra reúne um conjunto de contribuições apresentadas no I Congresso Imprensa da Universidade de Coimbra Internacional de Geociências na CPLP, que decorreu de 14 a 16 de maio de 2012 no Coimbra University Press Auditório da Reitoria da Universidade de Coimbra.
    [Show full text]
  • Alphab Etical Index
    ALPHAB ETICAL INDEX Names of authors are printed in SMALLCAPITALS, subjects in lower-case roman, and localities in italics; book reviews are placed at the end. ABDUL-SAMAD, F. A., THOMAS, J. H., WILLIAMS, P. A., BLASI, A., tetrahedral A1 in alkali feldspar, 465 and SYMES, R. F., lanarkite, 499 BORTNIKOV, N. S., see BRESKOVSKA, V. V., 357 AEGEAN SEA, Santorini I., iron oxide mineralogy, 89 Boulangerite, 360 Aegirine, Scotland, in trachyte, 399 BRAITHWAITE, R. S. W., and COOPER, B. V., childrenite, /~kKERBLOM, G. V., see WILSON, M. R., 233 119 ALDERTON, D. H. M., see RANKIN, A. H., 179 Braunite, mineralogy and genesis, 506 Allanite, Scotland, 445 BRESKOVSKA, V. V., MOZGOVA, N. N., BORTNIKOV, N. S., Aluminosilicate-sodalites, X-ray study, 459 GORSHKOV, A. I., and TSEPIN, A. I., ardaite, 357 Amphibole, microstructures and phase transformations, BROOKS, R. R., see WATTERS, W. A., 510 395; Greenland, 283 BULGARIA, Madjarovo deposit, ardaite, 357 Andradite, in banded iron-formation assemblage, 127 ANGUS, N. S., AND KANARIS-SOTIRIOU, R., autometa- Calcite, atomic arrangement on twin boundaries, 265 somatic gneisses, 411 CANADA, SASKATCHEWAN, uranium occurrences in Cree Anthophyllite, asbestiform, morphology and alteration, Lake Zone, 163 77 CANTERFORD, J. H., see HILL, R. J., 453 Aragonite, atomic arrangements on twin boundaries, Carbonatite, evolution and nomenclature, 13 265 CARPENTER, M. A., amphibole microstructures, 395 Ardaite, Bulgaria, new mineral, 357 Cassiterite, SW England, U content, 211 Arfvedsonite, Scotland, in trachyte, 399 Cebollite, in kimberlite, correction, 274 ARVlN, M., pumpellyite in basic igneous rocks, 427 CHANNEL ISLANDS, Guernsey, meladiorite layers, 301; ASCENSION ISLAND, RE-rich eudialyte, 421 Jersey, wollastonite and epistilbite, 504; mineralization A TKINS, F.
    [Show full text]
  • 38Th RMS Program Notes
    E.fu\wsoil 'og PROGRAM Thursday Evening, April 14, 2011 PM 4:00-6:00 Cocktails and Snacks – Hospitality Suite 400 (4th Floor) 6:00-7:45 Dinner – Baxter’s 8:00-9:15 THE GUALTERONI COLLECTION: A TIME CAPSULE FROM A CENTURY AGO – Dr. Renato Pagano In 1950, the honorary curator of the Museum of Natural History in Genoa first introduced Dr. Renato Pagano to mineral collecting as a Boy Scout. He has never looked back. He holds a doctorate in electrical engineering and had a distinguished career as an Italian industrialist. His passion for minerals has produced a collection of more than 13,000 specimens, with both systematic and aesthetic subcollections. His wife Adriana shares his passion for minerals and is his partner in collecting and curating. An excellent profile of Renato, Adriana, and their many collections appeared earlier this year in Mineralogical Record (42:41-52). Tonight Dr. Pagano will talk about an historic mineral collection assembled between 1861 and 1908 and recently acquired intact by the Museum of Natural History of Milan. We most warmly welcome Dr. Renato Pagano back to the speakers’ podium. 9:15 Cocktails and snacks in the Hospitality Suite on the 4th floor will be available throughout the rest of the evening. Dealers’ rooms will be open at this time. All of the dealers are located on the 4th floor. Friday Morning, April 15, 2011 AM 9:00 Announcements 9:15-10:15 CRACKING THE CODE OF PHLOGOPITE DEPOSITS IN QUÉBEC (PARKER MINE), MADAGASCAR (AMPANDANDRAVA) AND RUSSIA (KOVDOR) – Dr. Robert F. Martin Robert François Martin is an emeritus professor of geology at McGill University in Montreal.
    [Show full text]
  • Crystal Morphology and Xrd Peculiarities of Brazilianite from Different Localities
    NAT. CROAT. VOL. 20 No 1 1¿18 ZAGREB June 30, 2011 original scientific paper / izvorni znanstveni rad CRYSTAL MORPHOLOGY AND XRD PECULIARITIES OF BRAZILIANITE FROM DIFFERENT LOCALITIES ANDREA ^OBI]*1,VLADIMIR ZEBEC2,RICARDO SCHOLZ3, VLADIMIR BERMANEC1 &SANDRA DE BRITO BARRETO4 ¹Faculty of Science, Institute of Mineralogy and Petrography, Horvatovac 95, Zagreb, Croatia 2Croatian Natural History Museum, Demetrova 1, Zagreb, Croatia 3Department of Geology, School of Mining, Federal University Ouro Preto, Ouro Preto, MG, Brazil 4Department of Geology, Federal University of Pernambuco, Av. Academico Hélio Ramos. S/N. 5 andar., Cidade Universitária, Recife, PE, Brasil ^obi}, A., Zebec, V., Scholz, R., Bermanec, V. & de Brito Barreto, S.: Crystal morphology and xrd peculiarities of brazilianite from different localities. Nat. Croat., Vol. 20, No. 1., 1–18, 2011, Zagreb. Forty four brazilianite crystals from several localities in Brazil, Rwanda and Canada were measured on a two-circle goniometer to determine brazilianite morphology. Twenty forms were recorded; six of them have not been recorded before. All faces in the [001] zone are striated along crystallographic axis c. All striated forms in the [001] zone exhibit multiple signals. Two of the signals observed on the form {110} are always very clear. There is an exception on one crystal where just one face, (110), exhibits only one clear signal. Five groups of habits were recorded, two of them new to this mineral species. Eleven samples were examined by X-ray diffraction for calculation of the unit cell parameters yield- ing a=11.201(1)–11.255(2) Å, b=10.1415(5)–10.155(1) Å, c=7.0885(7)–7.119(2) Å and b=97.431(7)–97.34(1) °.
    [Show full text]
  • NEW MINERALS It Is Proposed Hereafter to Indicate In.A General Way the Classification of All New Minerals Recoided in This Department
    JOURNAL MINERALOGICAL SOCIETY OF AMENICA 63 Dr. Kunz then spoke of the various city localities and the minerals found therein. He stated that the East Side, from 37 to 110 St., probably afforded the most specimens. The various tunnels and their minerals were spoken of. Capt. Miller called attention to the fine collection of Brooklyn Drift Minerals and Rocks in the collection of the Long Island Historical Society. Ife abo mentioned the occurrence of monazite and xenotime crystals, on the Speedway,Harlem River. Dr. Kunz emphasizedthe irnportance of complete records being kept of all finds. Tnou,q,s L Mrr,r,nn, SecretaryPro, Tem. NEW MINERALS It is proposed hereafter to indicate in.a general way the classification of all new minerals recoided in this department. Subdivision will be first into "families," of which nine may be recognized,as listed in the January number (Am. Min.6 (1), 12,1921). Eachfamilywillbe separatedinto "subfamilies " based on special features of composition. This arrangement is tentative and open to modification, and criticism of it will be welcome, [Eo.] FAMILY 2. SULFIDES, ETC. SosreMrr,v 3. Doust,u suLFrDEs oF METALSAND sEMr-METAr,s. I'LTRABASITE V. Rosrcxf and J. Srnnse-Btinu. Ultrabasit, ein neues Mineral aus Freiberg in Sachsen. (Ultrabasite, a new mineral from Freiberg, Saxony). Rozpr.Eeslcd Ako,il. Prag,25, No. 45, 1916;Z. Krgst. Min., 55,43H39, 1920, Neun: From its extremely basic chemical composition. Pnrsrcar, Pnopnnrrus Color black, somewhat grayish; luster metallic; streak black; cleavage none; fracture scaly, with somewhat greasy luster on the surface. H. : 5; sp. gr.
    [Show full text]
  • Minerals Named After Scientists
    Dr. John Andraos, http://www.careerchem.com/NAMED/Minerals.pdf 1 MINERALS NAMED AFTER PEOPLE AND PLACES © Dr. John Andraos, 2003-2011 Department of Chemistry, York University 4700 Keele Street, Toronto, ONTARIO M3J 1P3, CANADA For suggestions, corrections, additional information, and comments please send e-mails to [email protected] http://www.chem.yorku.ca/NAMED/ PEOPLE MINERAL PERSON OR PLACE DESCRIPTION Abelsonite ABELSON, Philip Hauge (1913 - ?) geochemist Abenakiite ABENAKI people, Quebec, Canada Abernathyite ABERNATHY, Jess Mine operator American, b. ? Abswurmbachite ABS-WURMBACH, IRMGARD (1938 - ) mineralogist German, b. ? Adamite ADAM, Gilbert Joseph Zn3(AsO3)2 H2O (1795 - 1881) mineralogist French, b. ? Aegirine AEGIR, Scandinavian god of the sea Afwillite WILLIAMS, Alpheus Fuller (1874 - ?) mine operator DeBeers Consolidated Mines, Kimberley, South Africa Agrellite AGRELL, Stuart O. (? - 1996) mineralogist British, b. ? Agrinierite AGRINIER, Henri (1928 - 1971) mineralogist French, b. ? Aguilarite AGUILAR, P. Superintendent of San Carlos mine, Guanajuato, Mexico Mexican, b. ? Aikenite 2 PbS Cu2S Bi2S5 Andersonite ANDERSON, Dr. John Andraos, http://www.careerchem.com/NAMED/Minerals.pdf 2 Andradite ANDRADA e Silva, Jose B. Ca3Fe2(SiO4)3 de (? - 1838) geologist Brazilian, b. ? Arfvedsonite ARFVEDSON, Johann August (1792 - 1841) Swedish, b. Skagerholms- Bruk, Skaraborgs-Län, Sweden Arrhenite ARRHENIUS, Svante Silico-tantalate of Y, Ce, Zr, (1859 - 1927) Al, Fe, Ca, Be Swedish, b. Wijk, near Uppsala, Sweden Avogardrite AVOGADRO, Lorenzo KBF4, CsBF4 Romano Amedeo Carlo (1776 - 1856) Italian, b. Turin, Italy Babingtonite (Ca, Fe, Mn)SiO3 Fe2(SiO3)3 Becquerelite BECQUEREL, Antoine 4 UO3 7 H2O Henri César (1852 - 1908) French b. Paris, France Berzelianite BERZELIUS, Jöns Jakob Cu2Se (1779 - 1848) Swedish, b.
    [Show full text]
  • Mineral Collecting Sites in North Carolina by W
    .'.' .., Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie RUTILE GUMMITE IN GARNET RUBY CORUNDUM GOLD TORBERNITE GARNET IN MICA ANATASE RUTILE AJTUNITE AND TORBERNITE THULITE AND PYRITE MONAZITE EMERALD CUPRITE SMOKY QUARTZ ZIRCON TORBERNITE ~/ UBRAR'l USE ONLV ,~O NOT REMOVE. fROM LIBRARY N. C. GEOLOGICAL SUHVEY Information Circular 24 Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie Raleigh 1978 Second Printing 1980. Additional copies of this publication may be obtained from: North CarOlina Department of Natural Resources and Community Development Geological Survey Section P. O. Box 27687 ~ Raleigh. N. C. 27611 1823 --~- GEOLOGICAL SURVEY SECTION The Geological Survey Section shall, by law"...make such exami­ nation, survey, and mapping of the geology, mineralogy, and topo­ graphy of the state, including their industrial and economic utilization as it may consider necessary." In carrying out its duties under this law, the section promotes the wise conservation and use of mineral resources by industry, commerce, agriculture, and other governmental agencies for the general welfare of the citizens of North Carolina. The Section conducts a number of basic and applied research projects in environmental resource planning, mineral resource explora­ tion, mineral statistics, and systematic geologic mapping. Services constitute a major portion ofthe Sections's activities and include identi­ fying rock and mineral samples submitted by the citizens of the state and providing consulting services and specially prepared reports to other agencies that require geological information. The Geological Survey Section publishes results of research in a series of Bulletins, Economic Papers, Information Circulars, Educa­ tional Series, Geologic Maps, and Special Publications.
    [Show full text]
  • Refinement of the Crystal Structure of Ushkovite from Nevados De Palermo, República Argentina
    929 The Canadian Mineralogist Vol. 40, pp. 929-937 (2002) REFINEMENT OF THE CRYSTAL STRUCTURE OF USHKOVITE FROM NEVADOS DE PALERMO, REPÚBLICA ARGENTINA MIGUEL A. GALLISKI§ AND FRANK C. HAWTHORNE¶ Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada ABSTRACT The crystal structure of ushkovite, triclinic, a 5.3468(4), b 10.592(1), c 7.2251(7) Å, ␣ 108.278(7), ␤ 111.739(7), ␥ 71.626(7)°, V 351.55(6) Å3, Z = 2, space group P¯1, has been refined to an R index of 2.3% for 1781 observed reflections measured with MoK␣ X-radiation. The crystal used to collect the X-ray-diffraction data was subsequently analyzed with an electron microprobe, 2+ 3+ to give the formula (Mg0.97 Mn 0.01) (H2O)4 [(Fe 1.99 Al0.03) (PO4) (OH) (H2O)2]2 (H2O)2, with the (OH) and (H2O) groups assigned from bond-valence analysis of the refined structure. Ushkovite is isostructural with laueite. Chains of corner-sharing 3+ 3+ {Fe O2 (OH)2 (H2O)2} octahedra extend along the c axis and are decorated by (PO4) tetrahedra to form [Fe 2 O4 (PO4)2 (OH)2 3+ (H2O)2] chains. These chains link via sharing between octahedron and tetrahedron corners to form slabs of composition [Fe 2 (PO4)2 (OH)2 (H2O)2] that are linked by {Mg O2 (H2O)4} octahedra. Keywords: ushkovite, crystal-structure refinement, electron-microprobe analysis. SOMMAIRE Nous avons affiné la structure cristaline de l’ushkovite, triclinique, a 5.3468(4), b 10.592(1), c 7.2251(7) Å, ␣ 108.278(7), ␤ 111.739(7), ␥ 71.626(7)°, V 351.55(6) Å3, Z = 2, groupe spatial P¯1, jusqu’à un résidu R de 2.3% en utilisant 1781 réflexions observées mesurées avec rayonnement MoK␣.
    [Show full text]
  • Brandãoite, [Beal2(PO4)2(OH)2(H2O
    Mineralogical Magazine (2019), 83, 261–267 doi:10.1180/mgm.2018.121 Article Brandãoite, [BeAl2(PO4)2(OH)2(H2O)4](H2O), a new Be–Al phosphate mineral from the João Firmino mine, Pomarolli farm region, Divino das Laranjeiras County, Minas Gerais State, Brazil: description and crystal structure † Luiz A. D. Menezes Filho1 , Mário L. S. C. Chaves1, Mark A. Cooper2, Neil A. Ball2, Yassir A. Abdu2,3, Ryan Sharpe2, Maxwell C. Day2 and Frank C. Hawthorne2* 1Federal University of Minas Gerais, Belo Horizonte, Minas Gerais, Brazil; 2Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada; and 3Department of Applied Physics and Astronomy, University of Sharjah, P.O. Box 27272, Sharjah, United Arab Emirates Abstract – Brandãoite, [BeAl2(PO4)2(OH)2(H2O)4](H2O), is a new Be Al phosphate mineral from the João Firmino mine, Pomarolli farm region, Divino das Laranjeiras County, Minas Gerais State, Brazil, where it occurs in an albite pocket with other secondary phosphates, including beryllonite, atencioite and zanazziite, in a granitic pegmatite. It occurs as colourless acicular crystals <10 µm wide and <100 µm long that form compact radiating spherical aggregates up to 1.0–1.5 mm across. It is colourless and transparent in single crystals and white in aggregates, has a white streak and a vitreous lustre, is brittle and has conchoidal fracture. Mohs hardness is 6, and the calculated density 3 α β γ is 2.353 g/cm . Brandãoite is biaxial (+), = 1.544, = 1.552 and = 1.568, all ± 0.002; 2Vobs = 69.7(10)° and 2Vcalc = 71.2°.
    [Show full text]