Speaking About the Other Ones: Swedish Chemists on Alchemy, C
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Determination of D003 by Capillary Gas Chromatography
Rev. CENIC Cienc. Quím.; vol. 51. (no.2): 325-368. Año. 2020. e-ISSN: 2221-2442. BIBLIOGRAPHIC REWIEW THE FAMOUS FINNISH CHEMIST JOHAN GADOLIN (1760-1852) IN THE LITERATURE BETWEEN THE 19TH AND 21TH CENTURIES El famoso químico finlandés Johan Gadolin (1760-1852) en la literatura entre los siglos XIX y XXI Aleksander Sztejnberga,* a,* Professor Emeritus, University of Opole, Oleska 48, 45-052 Opole, Poland [email protected] Recibido: 19 de octubre de 2020. Aceptado: 10 de diciembre de 2020. ABSTRACT Johan Gadolin (1760-1852), considered the father of Finnish chemistry, was one of the leading chemists of the second half of the 18th century and the first half of the 19th century. His life and scientific achievements were described in the literature published between the 19th and 21st centuries. The purpose of this paper is to familiarize readers with the important events in the life of Gadolin and his research activities, in particular some of his research results, as well as his selected publications. In addition, the names of authors of biographical notes or biographies about Gadolin, published in 1839-2017 are presented. Keywords: J. Gadolin; Analytical chemistry; Yttrium; Chemical elements; Finnland & Sverige – XVIII-XIX centuries RESUMEN Johan Gadolin (1760-1852), considerado el padre de la química finlandesa, fue uno de los principales químicos de la segunda mitad del siglo XVIII y la primera mitad del XIX. Su vida y sus logros científicos fueron descritos en la literatura publicada entre los siglos XIX y XXI. El propósito de este artículo es familiarizar a los lectores con los acontecimientos importantes en la vida de Gadolin y sus actividades de investigación, en particular algunos de sus resultados de investigación, así como sus publicaciones seleccionadas. -
Hjalmar Fors, the Limits of Matter—Chemistry, Mining & Enlightenment
Miner Econ (2015) 28:131–132 DOI 10.1007/s13563-015-0071-2 BOOK REVIEW Hjalmar Fors, The Limits of Matter—Chemistry, mining & enlightenment The University of Chicago Press Chicago USA 2015 Magnus Ericsson1 Published online: 15 September 2015 # Springer-Verlag Berlin Heidelberg 2015 Swedish chemists have discovered more elements than scien- though at that time not united into one yet), France and tists from any other nation. Over more than 100 years, from England? Part of the answer is surprisingly bureaucratisation the early 18th century to the end of the 19th century, 20 ele- or the creation of an administrative institution called ments of which 18 metals or non-metals and 2 gases, nitrogen Bergskollegium in Swedish or English Bureau of Mines as and chlorine were independently isolated and described. Some Hjalmar Fors calls it in his new and path-breaking study of these are as follows: The Limits of Matter—Chemistry, mining & enlightenment. Another part is the need of improved processes and better Element Name Year of discovery yields in Swedish mines, which played such a vital role in Cobalt Brandt 1735 the Swedish economy during this period. The Swedish ruling Nickel Cronstedt 1751 groups saw these demands and founded the Bureau of Mines, Manganese Gahn 1774 which acted in several ways to solve problems, that had arisen in the mining industry. R&D in those days was highly Molybdenum Hjelm 1781 applied but nevertheless led to important purely scientific Yttrium Gadolin 1794 results. Tantalum Ekeberg 1802 The Bureau was set up in 1634 based on a predecessor, Cerium Berzelius 1803 which was started already in 1630. -
RBRC-32 BNL-6835.4 PARITY ODD BUBBLES in HOT QCD D. KHARZEEV in This ~A~Er We Give a Pedawwicalintroduction~0 Recent Work Of
RBRC-32 BNL-6835.4 PARITY ODD BUBBLES IN HOT QCD D. KHARZEEV RIKEN BNL Research Center, Br$ookhauenNational Laboratory, . Upton, New York 11973-5000, USA R.D. PISARSKI Department of Physics, Brookhaven National Laboratoy, Upton, New York 11973-5000, USA M.H.G. TYTGAT Seruice de Physique Th&orique, (7P 225, Uniuersitc4Libre de Bruzelles, B[ud. du !t%iomphe, 1050 Bruxelles, Belgium We consider the topological susceptibility for an SU(N) gauge theory in the limit of a large number of colors, N + m. At nonzero temperature, the behavior of the topological susceptibility depends upon the order of the reconfining phrrse transition. The meet interesting possibility is if the reconfining transition, at T = Td, is of second order. Then we argue that Witten’s relation implies that the topological suscepti~lfity vanishes in a calculable fdion at Td. Ae noted by Witten, this implies that for sufficiently light quark messes, metaetable etates which act like regions of nonzero O — parity odd bubbles — can arise at temperatures just below Td. Experimentally, parity odd bubbles have dramatic signature% the rI’ meson, and especially the q meson, become light, and are copiously produced. Further, in parity odd bubbles, processes which are normally forbidden, such as q + rr”ro, are allowed. The most direct way to detect parity violation is by measuring a parity odd global seymmetry for charged pions, which we define. 1 Introduction In this .-~a~er we give a Pedawwicalintroduction~0 recent work of ours? We I consider an SU(IV) gau”ge t~e~ry in the limit of a large number of colors, N + co, This is, of course, a familiar limit? We use the large N expansion I to investigate the behavior of the theory at nonzero temperature, especially for the topological susceptibility. -
Hexagon Fall
Redis co very of the Elements The Rare Earth s–The Beginnings I I I James L. Marshall, Beta Eta 1971 , and Virginia R. Marshall, Beta Eta 2003 , Department of Chemistry, University of North Texas, Denton, TX 76203-5070, [email protected] 1 Rare earths —introduction. The rare earths Figure 1. The “rare earths” are defined by IUPAC as the 15 lanthanides (green) and the upper two elements include the 17 chemically similar elements of the Group III family (yellow). These elements have similar chemical properties and all can exhibit the +3 occupying the f-block of the Periodic Table as oxidation state by the loss of the highest three electrons (two s electrons and either a d or an f electron, well as the Group III chemical family (Figure 1). depending upon the particular element). A few rare earths can exhibit other oxidation states as well; for These elements include the 15 lanthanides example, cerium can lose four electrons —4f15d 16s 2—to attain the Ce +4 oxidation state. (atomic numbers 57 through 71, lanthanum through lutetium), as well as scandium (atomic number 21) and yttrium (atomic number 39). The chemical similarity of the rare earths arises from a common ionic configuration of their valence electrons, as the filling f-orbitals are buried in an inner core and generally do not engage in bonding. The term “rare earths” is a misnome r—these elements are not rare (except for radioactive promethium). They were named as such because they were found in unusual minerals, and because they were difficult to separate from one another by ordinary chemical manipula - tions. -
Kemivandring ‐ Uppsala]
Uppsala Universitet [KEMIVANDRING ‐ UPPSALA] En idéhistorisk vandring med nedslag i kemins Uppsala och historiska omvärld i urval. Karta: 1. Academia Carolina, Riddartorget 2. Gustavianum 3. Skytteanum 4. Fängelset vid domtrappan 5. Kungliga vetenskaps‐societeten 6. St. Eriks källa, akademikvarnen 7. Starten för branden 1702 8. Celsiushuset 9. Scheeles apotek (revs 1960) 10. Gamla kemikum, Wallerius/Bergman 11. Carolina Rediviva 12. Nya Kemikum/Engelska parken 13. The Svedberg laboratoriet 14. BMC, Uppsala Biomedicinska centrum 15. Ångströmlaboratoriet Uppsala Universitet [KEMIVANDRING ‐ UPPSALA] Uppsala universitet: kort historik[Karta: 1‐4] Uppsala universitet grundades 1477 av katolska kyrkan som utbildningsinstitution för präster och teologer. Det är nordens äldsta universitet och var vid tidpunkten världens nordligaste universitet. Domkyrkorna utbildade präster men för högre utbildningar var svenskar från 1200‐ talet och framåt tvungna att studera vid utländska universitet i till exempel Paris eller Rostock. Den starkast drivande kraften för bildandet av Uppsala universitet var Jakob Ulvsson som var Sveriges ärkebiskop mellan år 1469‐1515 och därmed den som innehaft ämbetet längst (46 år). Vid domkyrkan mot riddartorget finns en staty av Jakob Ulvsson av konstnären och skulptören Christian Eriksson. Statyns porträttlikhet med Ulvsson är förstås tvivelaktig eftersom man inte vet hur Jakob Ulvsson såg ut. Konstnären studerade i Paris tillsammans med Nathan Söderblom och det sägs att Eriksson hade honom som förebild för Ulvsson statyn och som därmed fick mycket lika ansiktsdrag som Söderblom. (Nathan Söderblom var ärkebiskop i Uppsala 1914‐ 1931, grundade den Ekumeniska rörelsen och fick Nobels fredspris 1930). Till en början bestod undervisningen vid Uppsala universitet främst av filosofi, juridik och teologi. Någon teknisk eller naturvetenskap utbildning fanns inte vid denna tidpunkt. -
Newsletter O U R S E L E C T I O N a T T H E L O N D O N International Antiquarian B O O K F a I R O L Y M P I a 24–26 M a Y 2012
11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE 11 20 BOHMAN RICE AT BE SWEDEN SVERIGE LA SUÈDE SAINT BRIDGET 1303–1373 LINNAEUS 1707–1778 STRINDBERG 1849–1912 Newsletter OUR SELECTION AT THE LONDON INTERNATIONAL ANTIQUARIAN BOOK FAIR OLYMPIA 24–26 MAY 2012 jakobsgatan 27b / p.o box 16394 / se-103 27 stockholm, sweden MATS REHNSTRÖM Rare books tel. +46 8 411 92 24 / fax: +46 8 411 94 61 / e-mail: [email protected] 4. Science, Medicine & The books offered below are subject to prior sale. 1. AGARDH, C. A. Icones algarum europae- arum. Représentation d’algues européennes Technology suivie de celle d’espèces exotiques les plus re- marquables recemment découvertes. Avec 40 planches coloriées. Leipzig, L. Voss, 1828-35. 8:o. (90) pp. & 40 handcoloured litographed plates. + AGARDH, JACOB A. Algæ maris Mediterranei et Adriatici, observationes in di- agnosin specierumet dispositionem generum. Paris, A. Saintin, 1842. 8:o (2),X,164 pp. Slightly worn contemporary full calf with broad raised 25. bands, gilt and blind tooled spine and green mo- rocco spine labels (bound by Taylor & Walton). Marbled edges. Boards with narrow gilt and blind tooled borders and extremities. Slightly faded on upper part of the boards. Spine in part slightly miscoloured. -
Carl Wilhelm Scheele (1742–1786)
a TRibuTe To The memoRy of caRl wilhelm Scheele (1742–1786) 1 by PRofessoR gunnaR SVedbeRg Royal SwediSh academy of engineeRing ScienceS (iVa) 2 A TribuTe To The MeMory of Carl Wilhelm SCheele (1742–1786) 3 P resenTed at The 2012 A nnuA l MeeTing of The royA l swedish AcA deM y of engineering sciences by P rofessor gunnA r svedberg The Royal Swedish Academy of Engineering Sciences (IVA) is an independent, learned society that promotes the engineering and economic sciences and the development of industry for the benefit of Swedish society. In cooperation with the business and academic communities, the Academy initiates and proposes measures designed to strengthen Sweden’s industrial skills base and competitiveness. For further information, please visit IVA’s website at www.iva.se. Published by the Royal Swedish Academy of Engineering Sciences (IVA), Professor Gunnar Svedberg Cover Photo: Statue of Scheele on Flora’s Hill in Humlegården, Stockholm Photo by Hans Melcherson. 4 IVA, P.O. Box 5073, SE-102 42 Stockholm, Sweden Phone: +46 8 791 29 00 Fax: +46 8 611 56 23 E-mail: [email protected] Website: www.iva.se IVA-M 431 • ISSN 1102-8254 • ISBN 978-91-7082-853-9 Editor: Anna Lindberg, IVA Layout and production: Hans Melcherson, Tryckfaktorn AB, Stockholm, Sweden Printed by Kaigan AB, Stockholm, Sweden, 2012 ForeWord Every year the Royal Swedish Academy of Engineering Sciences (IVA) produces a booklet commemorating a person who was active in Sweden and whose scientific, engineering, economic or indus- trial achievements were of significant benefit to the society of his or her day. -
Carl Wilhelm Scheele (1742-1786) in the Literature Between the 19Th and 21Th Centuries
Revista CENIC. Ciencias Químicas ISSN: 1015-8553 ISSN: 2221-2442 [email protected] Centro Nacional de Investigaciones Científicas Cuba Immortal fame of the Swedish apothecary and chemist: Carl Wilhelm Scheele (1742-1786) in the literature between the 19th and 21th centuries Sztejnberg, Aleksander Immortal fame of the Swedish apothecary and chemist: Carl Wilhelm Scheele (1742-1786) in the literature between the 19th and 21th centuries Revista CENIC. Ciencias Químicas, vol. 49, no. 1, 2018 Centro Nacional de Investigaciones Científicas, Cuba Available in: https://www.redalyc.org/articulo.oa?id=181661081016 PDF generated from XML JATS4R by Redalyc Project academic non-profit, developed under the open access initiative Aleksander Sztejnberg. Immortal fame of the Swedish apothecary and chemist: Carl Wilhelm Scheele (... Articulos de Revision Immortal fame of the Swedish apothecary and chemist: Carl Wilhelm Scheele (1742-1786) in the literature between the 19th and 21th centuries Fama inmortal del boticario y químico sueco Carl Wilhelm Scheele (1742-1786) en los siglos XIX y XXI Aleksander Sztejnberg a Redalyc: https://www.redalyc.org/articulo.oa? University of Opole, Polonia id=181661081016 [email protected] Received: 02 August 2018 Accepted: 04 September 2018 Abstract: In this article the literature on Carl Wilhelm Scheele (1742-1786) is reviewed, including books on chemistry and the history of chemistry, published between the 18th and the 21st century in different countries in order to: 1) familiarize readers with the names of authors of biographies and biographical notes about Carl Wilhelm Scheele, published in books in 1833-2017, 2) discusse the priority problem for the discovery of oxygen by Joseph Priestley (1733-1804) and Scheele, 3) familiarize readers with literature sources regarding Scheele's letter to Antoine Laurent Lavoisier (1743-1794), written on September 30, 1774, 4) show the causes of Scheele’s premature death, 5) familiarize readers with opinions about Scheele expressed by chemists in 1819-1942. -
Columbium and Tantalum
Rediscovery of the Elements Columbium and Tantalum Figure 2. Hatchett’s coach-making business was located at 121 Long Acre III (N51° 30.76 W00° 07.52). Charles spent his youth in Belle Vue in Chelsea (owned by his father) and then repurchased the home for his final James L. Marshall, Beta Eta 1971, and years (91-92 Virginia R. Marshall, Beta Eta 2003, Cheyne Walk; N51° 28.92 W00° 10.45). Department of Chemistry, University of Charles Hatchett’s North Texas, Denton, TX 76203-5070, first home after his marriage was at the Lower Mall in Hammersmith at an address today unknown; this [email protected] area was bombed in World War II and is now occupied by Furnival Gardens (N51° 29.42 W00° 13.99); this is where he discovered columbium. Also in Hammersmith may be found today at Hop Poles Inn (17-19 Charles Hatchett (1765–1847), a prosperous King Street, N51° 29.56 W00° 13.55), a favorite haunt of Charles Hatchett. In mid-life his home was London coach-builder and avocational Mount Clare (1808–1819) at Minstead Gardens, Roehampton (N51° 27.11 W00° 15.04). chemist, discovered columbium (niobium) in 1801. The following year, Anders Gufstaf Charles Hatchett 1 (Figure 2) was born at his merit his election to the Royal Society. His work Ekeberg (1767–1813), professor of chemistry at father’s carriage manufactory on Long Acre with bones and shells3b first determined the dif- the University of Uppsala, Sweden, discovered (Figure 3). Charles, being the only son, had ferent compositions of bones and teeth (mostly tantalum. -
Experimental Investigation of Recycling Rare Earth Elements from Waste Fluorescent Lamp Phosphors
EXPERIMENTAL INVESTIGATION OF RECYCLING RARE EARTH ELEMENTS FROM WASTE FLUORESCENT LAMP PHOSPHORS by Patrick Max Eduafo A thesis submitted to the Faculty and the Board of Trustees of the Colorado School of Mines in partial fulfillment of the requirements for the degree of Master of Science (Metallurgical and Material Engineering). Golden, Colorado Date: Signed: Patrick Max Eduafo Signed: Dr. Brajendra Mishra Thesis Advisor Golden, Colorado Date: Signed: Dr. Michael Kaufman Professor and Head Department of Metallurgical & Material Engineering ii ABSTRACT Characterization techniques and experimental measurements were used to evaluate a process for recycling rare earth elements (REEs) from spent fluorescent lamp phosphors. QEMSCAN analysis revealed that 70% of the rare earth bearing minerals was less than 10 µm in size. Feeds of varying characteristic were received throughout the course of the experimental analysis. A representative sample of the as-received feed contained 5.8% total rare earth elements (TREE) and upon sieving to below 44 µm, the grade increased to 16.5% TREE. By sieving further to below 10 µm, the grade increased to 19.8% TREE. Hydrochloric acid was used as lixiviant in batch leach experiments on the phosphor powder. The maximum extraction obtained was 90% for europium and yttrium at the following conditions: 1.5 M HCl, 70˚C, 1 hr, 30 g/L and 200 rpm. However, the solubility of cerium, lanthanum and terbium remained low under these conditions. Multistage leaching and calcination followed by leaching processes also resulted in poor extraction of cerium, lanthanum and terbium. Based on experimental results a new process for extracting the chief REEs from end of life fluorescent lamps has been developed. -
CW Scheele, from Pharmacist's Apprentice to Man of Science
ambix, vol. 55, No. 1, March 2008, 29–49 Stepping through Science’s Door: C. W. Scheele, from Pharmacist’s Apprentice to Man of Science1 HJALMAR FORS Division of History of Science and Technology, Royal Institute of Technology, Stockholm This reinterpretation of Carl Wilhelm Scheele’s (1742–86) early life and career analyses the social interplay between Scheele and other chemists who were active in eighteenth-century Sweden. It is argued that Scheele, a rather lowly journeyman working in peripheral pharmacies, had to work hard and traverse several geographical and social boundaries to gain a foothold in the scientifi c community. Eventually, Scheele’s skilful analysis of the mineral magnesia nigra would establish him as one of the pivotal Swedish chemists. However, this happened only after Scheele had managed to prove himself as a knowledgeable chemist who did not threaten the authority of certain socially superior colleagues. When Scheele had gained a place in the scien- tifi c community, the exchange logic of the eighteenth-century republic of letters permitted him to trade experimental results for other kinds of resources. Hence, he gained in both social status, economic prosperity and scientifi c prominence in a relatively short time. Carl Wilhelm Scheele has been, and still is, the object of much admiration. In biographical texts he is often portrayed as the perfect scientifi c hero: humble begin- nings, miraculous discovery, worldwide fame, and an early death caused by long hours spent working over poisonous substances in a drafty chemical laboratory. The legacy of his short life is said to be the discovery of a great number of chemical 1 This paper is based on chapter 6 in the author’s doctoral thesis Mutual Favours: The Social and Scientifi c Practice of Eighteenth-century Swedish chemistry, Institutionen för idé- och lärdomshistoria: skrifter 30 (Uppsala: Uppsala University, 2003). -
THE MAJOR RARE-EARTH-ELEMENT DEPOSITS of AUSTRALIA: GEOLOGICAL SETTING, EXPLORATION, and RESOURCES Figure 1.1
CHAPTER ONE WHAT ARE RARE- EARTH ELEMENTS? 1.1. INTRODUCTION latter two elements are classified as REE because of their similar physical and chemical properties to the The rare-earth elements (REE) are a group of seventeen lanthanides, and they are commonly associated with speciality metals that form the largest chemically these elements in many ore deposits. Chemically, coherent group in the Periodic Table of the Elements1 yttrium resembles the lanthanide metals more closely (Haxel et al., 2005). The lanthanide series of inner- than its neighbor in the periodic table, scandium, and transition metals with atomic numbers ranging from if its physical properties were plotted against atomic 57 to 71 is located on the second bottom row of the number then it would have an apparent number periodic table (Fig. 1.1). The lanthanide series of of 64.5 to 67.5, placing it between the lanthanides elements are often displayed in an expanded field at gadolinium and erbium. Some investigators who want the base of the table directly above the actinide series to emphasise the lanthanide connection of the REE of elements. In order of increasing atomic number the group, use the prefix ‘lanthanide’ (e.g., lanthanide REE: REE are: lanthanum (La), cerium (Ce), praseodymium see Chapter 2). In some classifications, the second element of the actinide series, thorium (Th: Mernagh (Pr), neodymium (Nd), promethium (Pm), samarium 1 (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), and Miezitis, 2008), is also included in the REE dysprosium (Dy), holmium (Ho), erbium (Er), thulium group, while promethium (Pm), which is a radioactive (Tm), ytterbium (Yb), and lutetium (Lu).