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Quality Assurance Project Plan Quality Assurance Project Plan for the Maryland Department of Natural Resources Chesapeake Bay Shallow Water Quality Monitoring Program for the period July 1, 2019 - June 30, 2020 1 July, 2019 DRAFT Quality Assurance Project Plan for the Maryland Department of Natural Resources Chesapeake Bay Shallow Water Quality Monitoring Program for the period July 1, 2019 – June 30, 2020 Prepared by: Tom Parham, Mark Trice, Brian Smith, Diana Domotor, and Ben Cole Resource Assessment Service/Tidewater Ecosystem Assessment Maryland Department of Natural Resources Tawes Building, D-2 580 Taylor Avenue Annapolis, MD 21401 Website Address: http://dnr.maryland.gov Toll Free in Maryland: 1-877-620-8DNR, ext: 8630 Out of state call: 410-260-8630 TTY users call via the MD Relay: 711 (within MD) Out of state call: 1-800-735-2258 © 2019 Maryland Department of Natural Resources The facilities and services of the Maryland Department of Natural Resources are available to all without regard to race, color, religion, sex, sexual orientation, age, national origin or physical or mental disability. This document is available in alternative format upon request from a qualified individual. Larry Hogan, Governor Boyd Rutherford, Lt. Governor Printed on Recycled Paper Quality Assurance Project Plan for the Maryland Department of Natural Resources Chesapeake Bay Shallow Water Quality Monitoring Program for the period July 1, 2019 - June 30, 2020 1 July, 2019 _______________________________ Thomas Parham, Principal Investigator Director, Tidewater Ecosystem Assessment Division Maryland Department of Natural Resources _______________________________ Bruce Michael Director, Resource Assessment Services Maryland Department of Natural Resources _______________________________ Christine Conn, Ph.D., Quality Assurance Officer Director, Office of Science and Stewardship Maryland Department of Natural Resources _______________________________ Jerry Frank, Manager of Analytical Services/Senior Faculty Research Assistant Chesapeake Biological Laboratory University of Maryland, Center for Environmental Science _______________________________ Carin Bisland, Acting Quality Assurance Officer Chesapeake Bay Program Office U.S. Environmental Protection Agency ______________________________ James Hargett, Project Officer Chesapeake Bay Program Office U.S. Environmental Protection Agency TABLE OF CONTENTS 1. INTRODUCTION AND PROJECT DESCRIPTION ......................................................... 1 2. METHODS AND PERFORMANCE MEASURES ............................................................ 11 3. FIELD MEASUREMENTS AND SAMPLING ................................................................... 19 4. LABORATORY ANALYSIS ................................................................................................ 21 5. DATA MANAGEMENT, VERIFICATION AND DOCUMENTATION ....................... 23 6. PROJECT QUALITY ASSURANCE/QUALITY CONTROL ......................................... 27 7. DATA ANALYSIS AND REPORTING .............................................................................. 29 8. PROJECT ORGANIZATION AND RESPONSIBILITY ................................................. 30 9. REFERENCES ....................................................................................................................... 32 10. APPENDICIES .................................................................................................................... 33 LIST OF TABLES Table 1 Shallow-water monitoring for 2019: Bay segment, sample type(s) and Designated Uses for which the collected data will be used to assess water quality criteria ............................... 4 Table 2. Water Quality Mapping Cruise Schedule (April through October 2019) ........................ 5 Table 3. 2019 Continuous monitoring stations .............................................................................. 8 Table 4. 2019 Water quality mapping calibration stations ............................................................ 9 Table 5. In situ monitor performance checks and acceptance criteria ......................................... 11 Table 6. Discrete sample performance checks and acceptance criteria ....................................... 11 Table 7. Continuous monitoring in situ water column parameters .............................................. 12 Table 8. Water Quality Mapping in situ water column parameters ............................................. 14 Table 9. Shallow Water Monitoring Program Grab Sample Water Column Parameters, Detection Limits, Methods, References, and Holding Times and Conditions ...................................... 16 Table 10. NASL methods ............................................................................................................ 21 Maryland Department of Natural Resources, 580 Taylor Avenue, D-2, Annapolis, MD 21401 QAPP: Shallow Water Monitoring Program - 1 July, 2019 DRAFT Page i Table 11. Acceptable drift tolerances for YSI 6600EDS/V2/EXO2 sondes following post- calibration check ................................................................................................................... 23 Table 12. Deployment dates for Maryland DNR Continuous Monitoring Sites ......................... 91 Table 13. Sampling Matrix for Maryland DNR Water Quality Mapping Systems ..................... 95 LIST OF FIGURES Figure 1. Map of 2019 continuous monitoring stations and water quality mapping systems, with progress of assessment ................................................................................................. 10 Figure 2. Conceptual diagram of continuous monitoring data management components, including automated data submission from DNR to the Bay Program ........................ 26 Figure 3. Conceptual diagram of water quality mapping data management components, including automated data submission from DNR to the Bay Program ........................ 26 Figure 4: Continuous Monitoring Field Sheet .............................................................................. 42 Figure 5: Continuous Monitoring Calibration Sheet .................................................................... 59 Figure 6: Water Quality Mapping Calibration Sheet .................................................................... 67 Maryland Department of Natural Resources, 580 Taylor Avenue, D-2, Annapolis, MD 21401 QAPP: Shallow Water Monitoring Program - 1 July, 2019 DRAFT Page ii ACRONYMS AND ABBREVIATIONS AA - Autoanalyzer AMQAW - Analytical Methods and Quality Assurance Workgroup (a workgroup of the Chesapeake Bay Program’s Monitoring Subcommittee) BGA - Blue-Green Algae C - Carbon CBP - EPA’s Chesapeake Bay Program CBPO - EPA’s Chesapeake Bay Program Office CBL - University of Maryland’s Chesapeake Biological Laboratory CDMA - Code Division Multiple Access Chl - Chlorophyll CIMS - Chesapeake Information Management System cm - Centimeter CSSP - Coordinated Split Sample Program d - Day DI - Deionized DIWG - Data Integrity Workgroup (a workgroup of the Chesapeake Bay Program, formerly AMQAW) DNR - Maryland Department of Natural Resources DO - Dissolved Oxygen DU - Designated Use EM - Emission EPA - U.S. Environmental Protection Agency EST - Eastern Standard Time EX - Excitation FGDC - Federal Geographic Data Commission FNU - Formazin Nephelometric Units FS - Full Scale g - Gram h - Hour ITAT - Integrated Trends Analysis Team Kd - Diffuse Attenuation Coefficient for Downward Irradiance L - Liter m - Meter MDE - Maryland Department of the Environment MDH - Maryland Department of Health min. - Minute mg - Milligram ml or mL - Milliliter mm - Millimeter mS - Millisiemens mV - Millivolts N - Nitrogen NASL - Nutrient Analytical Services Laboratory NERR - National Estuarine Research Reserve NH4 - Ammonium NIST - National Institute of Science and Technology nm - Nanometer no. - Number NO2 - Nitrite Maryland Department of Natural Resources, 580 Taylor Avenue, D-2, Annapolis, MD 21401 QAPP: Shallow Water Monitoring Program - 1 July, 2019 DRAFT Page iii NO23 - Nitrate + Nitrite NO3 - Nitrate NOAA - National Oceanic and Atmospheric Administration NTU - Nephelometric Turbidity Units OD - Optical Density ODO - Optical Dissolved Oxygen P - Phosphorus PAR - Photosynthetic Active Radiation PC - Particulate Carbon (Organic) PC - Personal Computer PE - Phycoerythrin PIP - Particulate Inorganic Phosphorus PN - Particulate Nitrogen PO4 - Phosphate PP - Particulate Phosphorus ppt - Parts Per Thousand QA - Quality Assurance QAO - Quality Assurance Officer (Unless otherwise noted, this refers to the DNR QAO) QAPP - Quality Assurance Project Plan QA/QC - Quality Assurance/Quality Control QC - Quality Control R/V - Research Vessel RFU - Relative Fluorescence Units SAS - Statistical Analysis System Sat% - Percent Saturation SAV - Submerged Aquatic Vegetation SpCond - Specific Conductance STAR - Scientific, Technical Assessment and Reporting Team TCP/IP - Transmission Control Protocol/Internet Protocol TDN - Total Dissolved Nitrogen TDP - Total Dissolved Phosphorus TMAW - Tidal Monitoring and Analysis Workgroup TMDL - Total Maximum Daily Load TN - Total Nitrogen TP - Total Phosphorus TPP - Total Particulate Phosphorus trib - Bay Tributary TSS - Total Suspended Solids TVS - Total Volatile Solids µg - Microgram USDI - U.S. Department of the Interior USGS - U.S. Geological Survey VIMS - Virginia Institute of Marine Science VSS - Volatile Suspended Solids YSI - Yellow Springs Instruments C - Degrees Celsius Maryland Department of Natural Resources, 580 Taylor
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