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Glossary of Terms Used in Physical Organic Chemistry (IUPAC Recommendations 1994)

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Glossary of Terms Used in Physical Organic Chemistry (IUPAC Recommendations 1994) Article Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994) MULLER, Paul Abstract This glossary contains definitions and explanatory notes for terms used in the context of research and publications in physical organic chemistry. Its aim is to provide guidance on physical organic chemical terminology with a view to achieve a far-reaching consensus on the definitions of useful terms and on the abandonment of unsatisfactory ones. As a consequence of the development of physical organic chemistry, and of the increasing use of physical organic terminology in other fields of chemistry, the 1994 revision of the Glossary is much expanded in comparison to the previous edition, and it also includes terms from cognate fields. A few definitions have been refined, some others totally revised in the light of comments received from the scientific community. Reference MULLER, Paul. Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994). Pure and Applied Chemistry, 1994, vol. 66, no. 5, p. 1077-1184 DOI : 10.1351/pac199466051077 Available at: http://archive-ouverte.unige.ch/unige:151920 Disclaimer: layout of this document may differ from the published version. 1 / 1 Pure &Appl. Chem., Vol. 66, No. 5, pp. 1077-1184,1994. Printed in Great Britain. 0 1994 IUPAC INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY ORGANIC CHEMISTRY DIVISION COMMISSION ON PHYSICAL ORGANIC CHEMISTRY* GLOSSARY OF TERMS USED IN PHYSICAL ORGANIC CHEMISTRY (IUPAC Recommendations 1994) Prepared for publication by P. MULLER DCpartement de Chimie Organique, UniversitC de Genbve, CH-1211 Genbve 4, Suisse *Membership of the Commission during the period (1987-93) the report was drafted was as follows: Chairman: 1987-93 P. Muller (Switzerland); Secretary: 1987-91 M. P. Doyle (USA); 1991-93 W. Drenth (Netherlands). Titular Members: P. N. I. Ahlberg (Sweden, 1987-91); E. A. Halevi (Israel, 1987-89); J. M. McBride (USA, 1987-93); V. Minkin (USSR, 1991-93); 0. M. Nefedov (USSR, 1987-91); M. Oki (Japan, 1987-91); J. Shorter (UK, 1989-93); Y. Takeuchi (Japan, 1991-93); Z. Rappoport (Israel, 1991-93); Associate Members: P. N. I. Ahlberg (Sweden, 1991-93); T. A. Albright (USA, 1987-91); W. Drenth (Netherlands, 1987-91); E. A. Halevi (Israel, 1989-93); R. A. Y. Jones (UK, 1987-89); V. I. Minkin (USSR, 1987-91); 0. M. Nefedov (USSR, 1991-93); C. Pemn (USA, 1991-93); D. Raber (USA, 1991-93); K. Schwetlick (GDR, 1987-89); Y. Takeuchi (Japan, 1987-91); P. Van Brandt (Belgium, 1987-93); J. R. Zdysiewicz (Australia, 1989-93); National Representatives: J.-L. Abboud Mas (Spain, 1991-93); E. Baciocchi (Italy, 1989-93); M. V. Bhatt (India, 1989-91); X. Jiang (China, 1987-93); J. J. E. Humeres Allende (Brazil, 1991-93); P. Laszlo (Belgium, 1987-91); D. J. McLennan (New Zealand, 1987-91); Z. Rappoport (Israel, 1987-91); R. Sabbah (France, 1989-93); B. E. Smart (USA, 1987-91); J. A. Silva Cavaleiro (Portugal, 1991-93); J. Suh (Republic of Korea, 1989-93); 0. Tarhan (Turkey, 1989-93); T. T. Tidwell (Canada, 1991-93); M. Tisler (Yugoslavia, 1987-93); J. Zavada (Czechslovakia, 1987-89); J. Zdysiewicz (Australia, 1987-89). Membership of the Working Party 1987-93: Chairman: P. Muller (Switzerland); Members: P. N. I. Ahlberg (USA), M. P. Doyle (USA), W. Drenth (Netherlands), E. A. Halevi (Israel), R. A. Y. Jones (UK), J. M. McBride (USA), V. Minkin (USSR), M. Oki (Japan), Y. Takeuchi (Japan), J. R. Zdysiewicz (Australia). Republication of this report is permitted without the need for formal IUPAC permission on condition that an acknowledgement, with full reference together with IUPAC copyright symbol (0 1994 IUPAC), is printed. Publication of a translation into another language is subject to the additional condition of prior approval from the relevant IUPAC National Adhering Organization. 1078 GLOSSARY OF TERMS USED IN PHYSICAL ORGANIC CHEMISTRY List of General Symbols A pre-exponential factor in Arrhenius equation [see energy of actiuation). a order of reaction with respect to reactant A, or Bronsted coemcient (see order of reaction Br0nsted relation). P order of reaction with respect to reactant B or Bronsted coefficient (see order of reaction Brramted relation). CP heat capacity [at constant pressure). e base of natural logarithms (e = 2.718). energy of activation (see energy of actiuation). Ea G Gibbs energy. H enthalpy . h Planck constant. K Kelvin (unit of thermodynamic temperature). KD equilibrium constant. k rate constant (see order of reaction). Boltzmann constant. kB In natural logarithm. lg decadic logarithm. h wavelength. V frequency. 0 (superscript) relating to thermodynamic standard state. pressure. gas constant. entropy. second (unit of time). summation. thermodynamic temperature. time. rate of reaction (see rate of reaction). (superscript)relating to transition state. See &localization. amount concentration of X. See also IUPAC QUANTITIES (1988). Commission on Physical Organic Chemistry 1079 GLOSSARY OF TERMS USED IN PHYSICAL ORGANIC CHEMISTRY 2nd Edition, 1994 Synopsis. This glossary contains definitions and explanatory notes for terms used in the context of research and publications in physical organic chemistry. Its aim is to provide guidance on physical organic chemical terminology with a view to achieve a far-reaching consensus on the definitions of useful terms and on the abandonment of unsatisfactory ones. As a consequence of the development of physical organic chemistry, and of the increasing use of physical organic terminology in other fields of chemistry, the 1994 revision of the Glossary is much expanded in comparison to the previous edition, and it also includes terms from cognate fields. A few definitions have been refined, some others totally revised in the light of comments received from the scientific community. INTRODUCTION TO THE 1994 REVISION General Remarks The "Glossary of Terms Used In Physical Organic Chemistry" was published in provisional form in 1979 (IUPAC PHYSICAL. ORGANIC GLOSSARY (1979)) and in revised form in 1983. A historical account of procedure and progress up to that stage was outlined in the provisional publication. The 1983 revision incorporated modifications agreed by the IUPAC Commission 111.2 (Physical Organic Chemistry), partly in response to comments received since the provisional publication. The terms defined in the 1983 Glossary are incorporated in the IUPAC "COMPENDIUM OF CHEMICAL TERMINOLOGY (1987)(Victor Gold Book). The present revision was undertaken with the long-term objective of compiling a com- pendium of organic chemical terminology. For this reason the criteria for inclusion of terms were much expanded'. The criteria for the 1983 edition were that the meaning of a term was either not given in non-scientific dictionaries or standard textbooks or differed significantly from the deflnition in such reference works, or that the term was associated with some ambi- guity or uncertainty with respect to its meaning. The present compendium tries to be com- prehensive, but without including trivial terms and without redefining IUPAC approved terms. In particular, terms from cognate fields which are used by physical organic chemists, are included. The terminology for the various spectroscopic methods of interest to organic chemists is not treated in the present document, except for some terms from NMR spectroscopy, but may be the subject of a separate study. As a matter of policy, named reactions (such as Diels-Alder) and symbolic representation of reaction mechanisms (SN1.etc.) have been excluded with a few exceptions. These topics have been treated in separate reports of this Commission (IUPAC REACTION MECHANISMS (1989),IUPAC TERMINOLOGY FOR TRANSFORMATIONS (1989)). The work has been coordinated with that of other Commissions within the Division of Or- ganic Chemistry, which deal with terminology, (e.g., IUPAC PHOTOCHEMICAL GLOSSARY (1988), and its revision (1992), Commission 111.3; IUPAC TERMINOLOGY OF STEREOCHEMISI'RY (1993), joint project of Commissions 111.1 and 111.2, and IUPAC CLASS NAMES (1993).joint project of Commissions 111.1 and 111.2), and with that of Commission 1.5. Discrepancies in the views between the Commissions have been eliminated. Whenever there was overlap or disagreement between the 1983 glossary and one of the more recent ones, the best available definitions were incorporated in the present text with a reference to their origin. Otherwise this glossary was not expanded into areas where other Commissions or working parties are already active. It is hoped that a merged compendium will be published after approval of the various glossaries. The aim of the Glossary is to provide guidance on physical-organic chemical terminology with a view to achieving a far-reaching consensus on the definitions of useful terms and the abandonment of unsatisfactory ones. The Commission is anxious to emphasize that it cannot (and would not wish to) impose rules or restrictions which might hinder rather than help the precise formulation of new ideas. Generally speaking, operational definitions were preferred to definitions couched in terms of theoretical models. We have tried to avoid taking sides on issues of scientific, as distinct from semantic, disagreement. The Commission is pleased to acknowledge the generous contributions of many scientists who helped by proposing or defining new terms, or by criticizing existing ones. The following have contributed to this revision: 1080 GLOSSARY OF TERMS USED IN PHYSICAL ORGANIC CHEMISTRY I.P. Beletskaya N.J. Leonard T.W. Bentley R.M. Magid C.F. Bernasconi P.C. Maria E. Buncel RT. Myers C. Eabom C. Reichardt J.F. Gal J.D. Roberts S. Hoz M.F. Ruasse W.P. Jencks H. Zollinger N. Way The Commission thanks Mrs. M. Wyss and Dr. S. Motallebi for their help in the preparation of the manuscript of this Glossary. Arrangement, Abbreviations and Symbols The arrangement is simply alphabetical, terms beginning with Greek letters following those beginning with Latin ones. Italicized words in the body of a definition, as well as those cited at the end, point to relevant cross-references.
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