The Future of Petrochemicals
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1 Refinery and Petrochemical Processes
3 1 Refinery and Petrochemical Processes 1.1 Introduction The combination of high demand for electric cars and higher automobile engine effi- ciency in the future will mean less conversion of petroleum into fuels. However, the demand for petrochemicals is forecast to rise due to the increase in world popula- tion. With this, it is expected that modern and more innovative technologies will be developed to serve the growth of the petrochemical market. In a refinery process, petroleum is converted into petroleum intermediate prod- ucts, including gases, light/heavy naphtha, kerosene, diesel, light gas oil, heavy gas oil, and residue. From these intermediate refinery product streams, several fuels such as fuel gas, liquefied petroleum gas, gasoline, jet fuel, kerosene, auto diesel, and other heavy products such as lubricants, bunker oil, asphalt, and coke are obtained. In addition, these petroleum intermediates can be further processed and separated into products for petrochemical applications. In this chapter, petroleum will be introduced first. Petrochemicals will be intro- duced in the second part of the chapter. Petrochemicals – the main subject of this book – will address three major areas, (i) the production of the seven cornerstone petrochemicals: methane and synthesis gas, ethylene, propylene, butene, benzene, toluene, and xylenes; (ii) the uses of the seven cornerstone petrochemicals, and (iii) the technology to separate petrochemicals into individual components. 1.2 Petroleum Petroleum is derived from the Latin words “petra” and “oleum,” which means “rock” and “oil,” respectively. Petroleum also is known as crude oil or fossil fuel. It is a thick, flammable, yellow-to-black mixture of gaseous, liquid, and solid hydrocarbons formed from the remains of plants and animals. -
Olive Oil Jars Left Behind By
live oil jars left behind by the ancient Greeks are testament to our centuries- old use of cooking oil. Along with salt and pepper, oil Oremains one of the most important and versatile tools in your kitchen. It keeps food from sticking to pans, adds flavor and moisture, and conducts the heat that turns a humble stick of potato into a glorious french fry. Like butter and other fats, cooking oil also acts as a powerful solvent, unleashing fat-soluble nutrients and flavor compounds in everything from tomatoes and onions to spices and herbs. It’s why so many strike recipes begin with heating garlic in oil rather than, say, simmering it in water. The ancient Greeks didn’t tap many cooking oils. (Let’s see: olive oil, olive oil, or—ooh, this is exciting!—how about olive oil?) But you certainly can. From canola to safflower to grapeseed to walnut, each oil has its own unique flavor (or lack thereof), aroma, and optimal cooking temperature. Choosing the right kind for the task at hand can save you money, boost your health, and improve your cooking. OK, so you probably don’t stop to consider your cooking oil very often. But there’s a surprising amount to learn about What’s this? this liquid gold. BY VIRGINIAWILLIS Pumpkin seed oil suspended in corn oil—it looks like a homemade Lava Lamp! 84 allrecipes.com PHOTOS BY KATE SEARS WHERE TO store CANOLA OIL GRAPESEED OIL are more likely to exhibit the characteristic YOUR OIL flavor and aroma of their base nut or seed. -
Secure Fuels from Domestic Resources ______Profiles of Companies Engaged in Domestic Oil Shale and Tar Sands Resource and Technology Development
5th Edition Secure Fuels from Domestic Resources ______________________________________________________________________________ Profiles of Companies Engaged in Domestic Oil Shale and Tar Sands Resource and Technology Development Prepared by INTEK, Inc. For the U.S. Department of Energy • Office of Petroleum Reserves Naval Petroleum and Oil Shale Reserves Fifth Edition: September 2011 Note to Readers Regarding the Revised Edition (September 2011) This report was originally prepared for the U.S. Department of Energy in June 2007. The report and its contents have since been revised and updated to reflect changes and progress that have occurred in the domestic oil shale and tar sands industries since the first release and to include profiles of additional companies engaged in oil shale and tar sands resource and technology development. Each of the companies profiled in the original report has been extended the opportunity to update its profile to reflect progress, current activities and future plans. Acknowledgements This report was prepared by INTEK, Inc. for the U.S. Department of Energy, Office of Petroleum Reserves, Naval Petroleum and Oil Shale Reserves (DOE/NPOSR) as a part of the AOC Petroleum Support Services, LLC (AOC- PSS) Contract Number DE-FE0000175 (Task 30). Mr. Khosrow Biglarbigi of INTEK, Inc. served as the Project Manager. AOC-PSS and INTEK, Inc. wish to acknowledge the efforts of representatives of the companies that provided information, drafted revised or reviewed company profiles, or addressed technical issues associated with their companies, technologies, and project efforts. Special recognition is also due to those who directly performed the work on this report. Mr. Peter M. Crawford, Director at INTEK, Inc., served as the principal author of the report. -
Specifications Guide Americas Petrochemicals Latest Update: July 2020
Specifications Guide Americas Petrochemicals Latest update: July 2020 Definitions of the trading locations for which Platts publishes daily indexes or assessments 2 Olefins 3 US aromatics 6 Latin American aromatics 8 US polymers 10 Latin American polymers 13 US intermediates 16 US hydrocarbon solvents 17 US chlor alkali 18 US oxygenated solvents 19 Liquid and gas chemical freight 21 Global petrochemical indices 22 Revision history 23 www.spglobal.com/platts Specifications Guide Americas Petrochemicals: July 2020 DEFINITIONS OF THE TRADING LOCATIONS FOR WHICH PLATTS PUBLISHES DAILY INDEXES OR ASSESSMENTS The following specifications guide contains the primary specifications for S&P Global Platts petrochemical assessments in the Americas. All the assessments listed here employ Platts Assessments Methodology, as published at https://www.spglobal.com/platts/plattscontent/_assets/_files/en/our-methodology/methodology-specifications/platts-assessments-methodology-guide.pdf. These guides are designed to give Platts subscribers as much information as possible about a wide range of methodology and specification questions. This guide is current at the time of publication. Platts may issue further updates and enhancements to this methodology and will announce these to subscribers through its usual publications of record. Such updates will be included in the next version of this guide. Platts editorial staff and managers are available to provide guidance when assessment issues require clarification. OLEFINS Assessment CURRENCY CODE Mavg Wavg TYPE -
Saturated, Unsaturated, and Trans Fat
Lifestyle Coach Facilitation Guide: Post-Core Fats - Saturated, Unsaturated, and Trans Fat Content Overview This session answers the question “what is fat?” It explores the different types of fat, and shows which fats are healthy (monounsaturated and polyunsaturated) and which fats are unhealthy (saturated and trans fat). Participants learn tips for choosing foods with healthy fats and avoiding foods with unhealthy fats. More information on cholesterol appears in Post-Core Session: Heart Health. Lifestyle Coach Preparation Checklist Materials Post-core handouts: What is Fat? Healthy Fats: Omega-3, Monounsaturated and Polyunsaturated Fats to Avoid: Saturated and Trans Fat Identifying Healthier Alternatives Tips for Choosing the Best Types of Fat “Food and Activity Trackers” “Lifestyle Coach’s Log” Balance scale Post-Core: Fats – Saturated, Unsaturated, and Trans Fat Key messages to reinforce A completely fat-free diet would not be healthy, yet it is important that fat be consumed in moderation. The main types of “healthy” fats are monounsaturated and polyunsaturated. The main types of “unhealthy” fats are saturated and trans fat. Saturated fats are primarily found in foods that come from animals, such as meat and dairy. Try to switch to lower-fat versions of these foods. In order to avoid trans fat, look on nutrition labels for ingredients such as “partially hydrogenated” oils or shortening. In addition, look for trans fat in the nutritional information in products like commercially baked cookies, crackers, and pies, and fried foods. After the session At the completion of this session, do the following: Use the “Notes and Homework Page” for notes and follow-up tasks. -
Water-Based Lubricants: Development, Properties, and Performances
lubricants Review Water-Based Lubricants: Development, Properties, and Performances Md Hafizur Rahman 1, Haley Warneke 1, Haley Webbert 1, Joaquin Rodriguez 1, Ethan Austin 1, Keli Tokunaga 1, Dipen Kumar Rajak 2 and Pradeep L. Menezes 1,* 1 Department of Mechanical Engineering, University of Nevada-Reno, Reno, NV 89557, USA; mdhafi[email protected] (M.H.R.); [email protected] (H.W.); [email protected] (H.W.); [email protected] (J.R.); [email protected] (E.A.); [email protected] (K.T.) 2 Department of Mechanical Engineering, Sandip Institute of Technology & Research Centre, Nashik 422213, India; [email protected] * Correspondence: [email protected] Abstract: Water-based lubricants (WBLs) have been at the forefront of recent research, due to the abundant availability of water at a low cost. However, in metallic tribo-systems, WBLs often exhibit poor performance compared to petroleum-based lubricants. Research and development indicate that nano-additives improve the lubrication performance of water. Some of these additives could be categorized as solid nanoparticles, ionic liquids, and bio-based oils. These additives improve the tribological properties and help to reduce friction, wear, and corrosion. This review explored different water-based lubricant additives and summarized their properties and performances. Viscosity, density, wettability, and solubility are discussed to determine the viability of using water-based nano-lubricants compared to petroleum-based lubricants for reducing friction and wear in machining. Water-based liquid lubricants also have environmental benefits over petroleum-based lubricants. Further research is needed to understand and optimize water-based lubrication for tribological systems completely. -
ABS Plant Migrates from CENTUM XL to Integrated CENTUM CS 3000 Solution
SUCCESS STORY ABS Plant Migrates from CENTUM XL to Integrated CENTUM CS 3000 Solution Location: Rayong, Thailand Order Date: December 2007 Completion: November 2008 Industry: Petrochemical Executive Summary The Integrated Refinery and Petrochemical Complex Public Co., Ltd. (IRPC) in Rayong, Thailand has a refinery (215,000 b/d) as well as several petrochemical plants that produce chemicals such as olefins (360,000 t/y) and aromatics that are used as feedstock at various types of plastics plants. One of these petrochemical plants produces 140,000 t/y of acrylonitrile butadiene styrene (ABS). Although this plant had experienced no major problems with its CENTUM XL process control system during the 19 years that it was in use, IRPC decided to upgrade to the latest technology when Yokogawa announced the end of service for CENTUM XL. To control complex production operations in a total of 17 batch reactors at this ABS plant, Yokogawa Thailand installed the CENTUM CS 3000 Integrated Production Control System together with CCTV equipment, a plant information management system (PIMS), the Exaplog Event Analysis Package, and the CS Batch 3000 package. Customer Satisfaction Wichian Art-ong, Instrument Supervisor, said, “We are very happy that we have been able to operate the ABS plant without any major problems. We have no complains with the Yokogawa systems.” He went on to say, “The entire integrated production system is functioning well. We are able to view video from the CCTV cameras as well as other production data on large screens positioned near the CENTUM human machine interface (HMI) stations. Plant information can also be viewed from any location using a standard web browser. -
Wastewater Treatment and Reuse in the Oil & Petrochem Industry
Engineering Conferences International ECI Digital Archives Wastewater and Biosolids Treatment and Reuse: Proceedings Bridging Modeling and Experimental Studies Spring 6-13-2014 Wastewater treatment and reuse in the oil & petrochem industry – a case study Alberto Girardi Dregemont Follow this and additional works at: http://dc.engconfintl.org/wbtr_i Part of the Environmental Engineering Commons Recommended Citation Alberto Girardi, "Wastewater treatment and reuse in the oil & petrochem industry – a case study" in "Wastewater and Biosolids Treatment and Reuse: Bridging Modeling and Experimental Studies", Dr. Domenico Santoro, Trojan Technologies and Western University Eds, ECI Symposium Series, (2014). http://dc.engconfintl.org/wbtr_i/46 This Conference Proceeding is brought to you for free and open access by the Proceedings at ECI Digital Archives. It has been accepted for inclusion in Wastewater and Biosolids Treatment and Reuse: Bridging Modeling and Experimental Studies by an authorized administrator of ECI Digital Archives. For more information, please contact [email protected]. Wastewater Treatment and Reuse In Oil & Petrochemical Industry Otranto, June 2014 COMPANY PROFILE DEGREMONT, THE WATER TREATMENT SPECIALISTS 4 areas of 5 areas of expertise: activities: . Drinking water production . Design & Build plants . Operation & . Reverse osmosis desalination Services plants . Urban wastewater treatment . Equipment and reuse plants . BOT / PPP . Biosolid treatment systems . Industrial water production and wastewater treatment units plants 2 Wastewater Treatment and Reuse COMPANY PROFILE DEGREMONT, THE WATER TREATMENT SPECIALISTS In over For industrials: For local authorities: 70 . Energy . Drinking water countries, . Upstream oil and gas Degrémont offers . Desalination . Refining and solutions to local . Urban wastewater authorities and petrochemicals . Sludge and biosolids industries . Chemicals . Pharmaceutical, cosmetics, fine chemicals . -
Chemical Sector Profile
Chemical Sector Profile The U.S. Chemical Sector converts raw materials into more than 70,000 diverse products essential to modern life and distributes those products to more than 750,000 end users throughout the Nation. Several hundred thousand U.S. chemical facilities—ranging from petrochemical manufacturers to chemical distributors—use, manufacture, store, transport, or deliver chemicals along a complex, global supply chain. End users include critical infrastructure sectors, making the uninterrupted production and transportation of chemicals essential for national and economic security. Impact on U.S. Economy The U.S. chemical industry is responsible for more than a quarter of the U.S. GDP, supports the production of almost all commercial and household goods, and is essential to economic growth. Generation of U.S. Employment From research and development to manufacturing, the U.S. chemical industry employs nearly 800,000 people, while creating jobs in the many other industries it touches. Contribution to U.S. Exports The business of chemistry is America’s largest exporting sector, supplying an eighth of the world’s chemical needs. Components of the Chemical Sector The U.S. Chemical Sector is made up of five distinct components: agricultural chemicals, basic chemicals, specialty chemicals, consumer products, and pharmaceuticals. Each component supports a specific and integral part of America’s chemical needs. The Chemical Sector: Integral to Everyday Life Nearly all goods in use every day in the U.S. are manufactured using Chemical Sector products. These goods are found in homes, offices, drug stores, and farms across the Nation. Page 1: American Chemistry Council (ACC), Elements of the Business of Chemistry, 2017; DHS, Chemical SSP, 2015; National Association of Chemical Distributors (NACD), 2019, NACD Responsible Distribution. -
Weekly Petroleum Status Report
Summary of Weekly Petroleum Data for the week ending September 17, 2021 U.S. crude oil refinery inputs averaged 15.3 million barrels per day during the week ending September 17, 2021 which was 1.0 million barrels per day more than the previous week’s average. Refineries operated at 87.5% of their operable capacity last week. Gasoline production increased last week, averaging 9.6 million barrels per day. Distillate fuel production increased last week, averaging 4.5 million barrels per day. U.S. crude oil imports averaged 6.5 million barrels per day last week, increased by 0.7 million barrels per day from the previous week. Over the past four weeks, crude oil imports averaged about 6.1 million barrels per day, 18.9% more than the same four-week period last year. Total motor gasoline imports (including both finished gasoline and gasoline blending components) last week averaged 1.1 million barrels per day, and distillate fuel imports averaged 184,000 barrels per day. U.S. commercial crude oil inventories (excluding those in the Strategic Petroleum Reserve) decreased by 3.5 million barrels from the previous week. At 414.0 million barrels, U.S. crude oil inventories are about 8% below the five year average for this time of year. Total motor gasoline inventories increased by 3.5 million barrels last week and are about 3% below the five year average for this time of year. Finished gasoline and blending components inventories both increased last week. Distillate fuel inventories decreased by 2.6 million barrels last week and are about 14% below the five year average for this time of year. -
Air Quality Impacts of Petroleum Refining and Petrochemical Industries
environments Review Air Quality Impacts of Petroleum Refining and Petrochemical Industries Aiswarya Ragothaman * and William A. Anderson ID Department of Chemical Engineering, University of Waterloo, Waterloo, ON N2L3G3, Canada; [email protected] * Correspondence: [email protected] Received: 29 June 2017; Accepted: 13 September 2017; Published: 19 September 2017 Abstract: Though refineries and petrochemical industries meet society’s energy demands and produce a range of useful chemicals, they can also affect air quality. The World Health Organization (WHO) has identified polluted air as the single largest environmental risk, and hence it is necessary to strive for and maintain good air quality. To manage potential health impacts, it is important to implement proper air quality management by understanding the link between specific pollutant sources and resulting population exposures. These industries release pollutants such as Volatile Organic Compounds, greenhouse gases and particulate matter, from various parts of their operations. Air quality should be monitored and controlled more meticulously in developing nations where increased energy demands, industrialization and overpopulation has led to more emissions and lower air quality. This paper presents a review of findings and highlights from various studies on air quality impacts of petroleum refining and petrochemical plants in many regions in the world. Keywords: air pollution; Air Quality Index; air quality management; refinery; petrochemical; emissions; exposure; particulate matter; Volatile Organic Compounds; greenhouse gases; ozone; carcinogenic; toxicity; Persistent Organic Pollutants; polychlorinated biphenyls; heavy metals; cancer; Chronic Obstructive Pulmonary Disease; lung cancer; air sampling; atmospheric lifetime; heat integration; emission control 1. Introduction Air pollution and air quality impacts have been studied for many years now, and there are significant concerns around the world to varying degrees. -
Physical and Chemical Properties of Oil
Physical and Chemical Properties of Oil 15th Annual OSC Readiness Training Program www.oscreadiness.org Physical and Chemical Properties of Oil Several physical and chemical properties useful to OSCs Determine what response technology works Terminology of the oil industry (jargon) . example: 1 Barrel of Oil is 42 gal . example: API Gravity 15th Annual OSC Readiness Training Program www.oscreadiness.org 2 Physical and Chemical Properties which affect cleanup and behavior on water Specific gravity Surface tension Viscosity Pour point Flash point Solubility in water And how these parameters change with time These parameters are measured at “standard temperature and atmospheric pressure Oil Spills are not at “standard temperatures and pressure” 15th Annual OSC Readiness Training Program www.oscreadiness.org 3 Physical properties of Oil Specific Gravity-The specific gravity of a substance is a comparison of its density to that of water. Less than SG 1.0 floats on water Greater than SG 1.0 sinks in water Majority of oils “float” Great spill cleanup significance In general, specific gravity of spilled oil will increase over time, as volatiles evaporate 15th Annual OSC Readiness Training Program www.oscreadiness.org 4 Physical properties of Oil API Gravity (American Petroleum Institute) Pure Water has arbitrary API Gravity of 10 Light crudes are generally those with an API gravity over 40. Gasoline ~ 60. Those with an API gravity below 40 are regarded as heavy There is an inverse relationship between API gravity