Part IV Elasticity and Thermodynamics of Reversible Processes
175 Chapter 5
Elasticity: An Energy Approach
Matter deforms when subjected to stresses. The English experimental physi- cist and inventor Robert Hooke (1635—1703), a contemporary of Isaac New- ton, rst stated formally this observation as an empirical relation, ‘ut tensio, sic vis’, which translates into our language as ‘extension is directly propor- tional to force’. In Engineering Mechanics, this observation translates into the theory of linear elasticity. Elasticity describes reversible material be- havior, and the notion of reversibility is a hallmark of another engineering science discipline: Thermodynamics. Thermodynamics is the study of en- ergy and energy transformations. Energy, which exists in many forms, such as heat, light, chemical energy, and electrical energy, is the ability to bring about change or to do work. Hence, an elastic, ie. reversible, behavior is readily recognized to be one where the energy provided to a material or structural system from the outside in form of work by forces and stresses, is stored as internal energy, which can be completely recovered at any time. Thermodynamics, therefore, provides a means to connect an observation to a fundamental physics law. The focus of this Chapter is to employ the laws of thermodynamics as a backbone for the engineering investigation of linear elastic behavior of materials and structures.
176 5.1. 1-D ENERGY APPROACH 177
0.4 d F0.35
0.3
0.25
0.2 KS 0.15 (x) 0.1
0.05 K x S 0 1 0 0.1 0.2x 0.3 0.4 0.5 F d
Figure 5.1: Elasticity: 1-D Thought Model of Elasticity (left), and force— displacement curve with free energy (right).
5.1 1-D Energy Approach
The 1-D spring system subjected to a force ononesideisthesimplest representation of an elastic behavior (Fig. 5.1). While equilibrium tells us that the externally supplied force is equal to the force in the spring, that is, = , Hooke’s observational law links to the extension at the point of load application through the proportionality constant (of dimension 1 2 []= [ ]= ):
= = (5.1)
Note that the elastic behavior of the spring may also be non-linear (Fig. 5.1). However, in all what follows we will restrict ourselves to linear elasticity. Let us now take another route to the problem, by evoking the First Law and the Second Law of Thermodynamics.
5.1.1 The First Law The First Law of Thermodynamics states that energy can be changed from one form to another, but that it cannot be created or destroyed. Energy is conserved. This is expressed by the internal energy U of a system (of dimension [U]=2 2). Speci cally the First Law informs us that the 178 CHAPTER 5. ELASTICITY: AN ENERGY APPROACH change in internal energy U of a system is due to work W and heat Q provided from the outside. Formally we write: U W Q (5.2) = + where we employ the symbol ‘ ( )’ to specify that the rate is not necessarily the time derivative of a function . For instance, the work rate W is generally not the total time derivative of the work W, ie. W =6 W .For instance, in the case of our 1-D spring system, the total work is W = , and the time derivative is W = + . In contrast, the work rate W is what the force realizes along the velocity = 0 at the point of load application, that is, W = .
5.1.2 The Second Law The Second Law of Thermodynamics speci es the direction of spontaneous change of energy, which is expressed by another physics quantity, the internal entropy S (of dimension [S]=2 2 1). The entropy is a measure of the quality of the energy. Speci cally, the Second Law informs us that the change of the internal entropy is always greater or equal to the entropy supplied to a system in heat form; that is: S Q (5.3) 0 where 0 0 stands for the absolute temperature, which is assumed to be constant in what follows. The di erence between the left and the right hand side is recognized as the fraction of entropy which is produced internally in aspontaneous(ie. uncontrolled) fashion, and which manifests itself as an internal heat source, D S Q = 0 0 (5.4) This internal heat source is called dissipation. More speci cally, if we substi- tute the First Law (5.2) into (5.4), we obtain: D W U S = ( 0 ) 0 (5.5) In this form, the Second Law appears as a balance law between the external work rate W and some form of recoverable energy (U 0S). This energy 5.1. 1-D ENERGY APPROACH 179 is called the free energy or Helmholtz Energy, which we denote by ,and which expresses the maximum internal capacity of a system to do work: