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Act-C 先導的物質変換領域 2016-2017

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Act-C 先導的物質変換領域 2016-2017 Creation of Advanced Catalytic Transformation for the Sustainable Manufacturing at Low Energy, Low Environmental Load Advanced Catalytic Transformation program for Carbon utilization 2016-2017 Creation of Advanced Catalytic Transformation for the Sustainable Manufacturing at Low Energy, Low Environmental Load Outline of the Research Area This research area aims to create an advanced catalytic transformation that can contribute to solving various challenges by realizing a low-carbon society, and producing sustainable and advanced drugs and functional materials. Specifically, the following studies are addressed: 1) Studies of reactions (such as CO2 reduction) to utilize small molecules as a resource instead of fossil resources and efficiently convert the CO2 into useful C1, C2 and C3 compounds; 2) Studies of reactions such as asymmetric carbon-carbon bond formation, which will lead to industrial applications; 3) Studies of the creation of π(pi)-electron molecules having superior properties and functions by innovative bond formation, cleavage and recombination; and the creation of new features by introducing functional groups to the pi-electron molecules. As such molecular conversion methods aim to be safe, with high atom efficiency, high yield and high selectivity, ACT-C promotes challenging research beyond the boundaries of the field of chemistry, physics, mathematics and engineering. In addition, cooperation with research related to measurement and analysis as well as theoretical chemistry, for the elucidation of reaction mechanism is encouraged. Objectives of the Research Area • Creation of a reduction method for transforming and applying CO2 as a useful substance • Creation of a catalytic substance transformation technology that directly generates asymmetric carbon-carbon bonds, and does so with high yield, effectiveness, selectivity, economy, and safety • Chemosynthesis of π-electron molecules and creation of new function generation approaches for devices Features of Research Area Management 1. Research Progress Monitoring The Research Supervisor and Advisors review research progress every quarter and provide various types of advice for each project. In addition, the research framework and resources are re-examined and flexibly revised depending on research progress. 2. Networking and Exchange of Research Progress Research progress is presented and discussed at ACT-C meetings every year, where all PIs, the Research Supervisor, Principal Program Director, and Advisors participate, to share ideas and to build inter-disciplinary research networks. 3. Promoting Synergistic Collaboration Through ad hoc workshops and symposium on specific themes, intra- and inter- research collaborations are promoted to enhance synergistic effects. 2 ACT-C ACT-C_pamph_e.indd 2 2016/06/30 9:29 Advanced Catalytic Transformation program for Carbon utilization Summary The Strategic Sector Creation of advanced catalytic transformation techniques/technologies for addressing the priority issues such as environment, energy, drug discovery and others Research Period 5 years Budget 40~300 million JPYen/Project Research Projects 51 projects Research Framework JST Research agreement Research Team Japanese Government (MEXT) Solicitation and selection Strategic Sector Research Principal Program of research proposals Supervisor Director Principal investigator, researchers Universities, independent administrative agencies, national and public testing and research institutions, companies, etc. Advisors Participation Participation Research Area Meeting Research Area (Research results) Research Supervisor Principal Program Director Toyoki KUNITAKE Ei-ichi NEGISHI President, Kitakyushu Foundation for Advancement of H.C. Brown Distinguished Professor of Chemistry, Industry Science and Technology PURDUE University Advisors | Takao IKARIYA | Masahiro HIRAMOTO Professor Emeritus, Tokyo Institute of Technology Professor, NINS, Institute for Molecular Science | Keisuke SUZUKI | Terunori FUJITA Professor, School of Science, Tokyo Institute of Technology Senior Research Fellow/ General Manager, Fujita Special Laboratory, MITSUI CHEMICALS,INC. | Kohei TAMAO | Shin-ji MURAI Science Advisor/ Director, Global Research Cluster, RIKEN Specially Appointed Professor, Nara Institute of Science and Technology | Tetsuo TSUTSUI | Shun-ichi MURAHASHI Professor Emeritus, Kyushu University Professor Emeritus, Osaka University | Kazunari DOUMEN | Miwako MORI Professor, School of Engineering, The University of Tokyo Affiliate Professor, Health Sciences University of Hokkaido ACT-C 3 ACT-C_pamph_e.indd 3 2016/06/30 9:29 INDEX 01 Shinji INAGAKI A Study on Bio-Mimetic Catalysis Using Mesoporous Organosilica ---------------------------------------------------------------- 5 02 Kei INUMARU Materials Design of Composite Structure in Nano-Scale and its Application to CO2 Utilization ---------------------------- 6 03 Nobuharu IWASAWA Synthesis of Acrylic Acid from Ethylene or Acetylene Based on the Innovative Transition Metal Catalysis -------------- 7 04 Minoru UMEDA Alcohol Synthesis Based on CO2 Reduction at Polymer Electrolyte Fuel Cell Cathode ---------------------------------------- 8 05 Teruhisa OHNO Development of Interfacial-Morphology Controlled Photocatalytic Electrode toward CO2 Conversion ----------------- 9 06 Sensuke OGOSHI Asymmetric Cycloaddition via Nickelacycles --------------------------------------------------------------------------------------------- 10 07 Fumiyuki OZAWA Development of Highly Effi cient Catalysts for Synthesizing π-Conjugated Polymers via Direct Arylation -------------- 11 08 Fumitoshi KAKIUCHI Developments of Innovative Synthetic Methods of n-type Organic Semiconductor Materials Using Unreactive Carbon Bonds and Organic Field-Eff ect Transistor Fabrication Methods ------------------------------------------ 12 09 Hiroyuki KAWAGUCHI Activation of Stable Small Molecules by Inorganic Metal Clusters ----------------------------------------------------------------- 13 10 Susumu KITAGAWA Methanol Synthesis in Porous Coordination Polymers as Reaction Field --------------------------------------------------------- 14 11 Masato KITAMURA Development of High Performance Transition Metal Catalysts for Dehydrative Asymmetric α-Allylation of Carbonyl Compounds -------------------------------------------------------------------------------------------------------------------------- 15 12 Soichiro KYUSHIN Functions and Properties of Silyl-Substituted Aromatic Compounds ------------------------------------------------------------- 16 13 Takuya KURAHASHI Development of Novel Metalloporphyrin Catalyst toward Advanced Catalytic Transformation Program for Carbon Utilization ------------------------------------------------------------------------------------------------------------------------------- 17 14 Shū KOBAYASHI Development and Expansion of Innovative Asymmetric Carbon-Carbon Bond Forming Reactions Based on the Original Basic Sciences ---------------------------------------------------------------------------------------------------------------- 18 15 Mio KONDO Development of Supermolecular Catalyst toward CO2 Reduction System Using H2O as Electron Source --------------- 19 16 Hidehiro SAKURAI Novel Reactions Catalyzed by Metal Clusters Induced by the Ensemble Eff ect of Multi-Metal System ------------------- 20 17 Susumu SAITO Chemical Immobilization of CO2 through Molecular Manipulations of the Crossover and Interfaces between Molecular and Solid Catalyst ------------------------------------------------------------------------------------------------------------------ 21 18 Hiroaki SASAI Development of Practical Method for Molecular Transformation Based on Catalytic Asymmetric Domino Reactions ------------------------------------------------------------------------------------- 22 19 Tetsuya SATOH Development of Environmentally-Benign, Waste-Free Dehydrogenative Cross-Coupling Reactions -------------------- 23 20 Yoshihiro SATO Synthesis of Acrylic Acid Derivatives from Alkenes and CO2 Using Nickel Catalyst and Development of Novel Type of Immobilized Nickel Catalyst on Gold, SANi (Sulfur-modifi ed Au supported Ni material) ----------------- 24 21 Masaya SAWAMURA Development of Asymmetric C–H Bond Activation Catalysts Guided by Quantum Simulations -------------------------- 25 22 Masakatsu SHIBASAKI Development of Advanced Practical Cooperative Asymmetric Catalysts and Their Application to Streamlining Enantioselective Synthesis of Therapeutics ----------------------------------------------------------------------------- 26 23 Takanori SHIBATA Construction of Chiral p Space by Using Transition Metal-Catalyzed Asymmetric Reactions and its Application to the Functional Materials ------------------------------------------------------------------------------------------------ 27 24 Toshikazu TAKATA Highly Selective Effi cient Transformation of Polymers Exploiting Interlocked Catalyst --------------------------------------- 28 25 Ken TANAKA Advancement and Application of Catalytic Ring Construction by Asymmetric Carbon–Carbon Bond Forming Reactions ------------------------------------------------------------------------------------------------------------------------------- 29 26 Naoto CHATANI Development of New Methodology for Environmentally Friendly Transformation -------------------------------------------- 30 27 Noritatsu TSUBAKI Novel C1 Chemistry Process to Convert Carbon Dioxide ----------------------------------------------------------------------------- 31
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