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International Review of Chemical Engineering (I.RE.CH.E.), Vol. 4, N. 5 ISSN 2035-1755 September 2012 Special Section on Open Door Initiative (ODI) – 3rd edition An Exercise with the He’s Variation Iteration Method to a Fractional Bernoulli Arising in Transient Conduction with Non-Linear Heat Flux at the Boundary

Jordan Hristov

Abstract – Surface temperature evolution of a body subjected to a nonlinear heat flux involving counteracting convection heating and radiation cooling has been solved by the variations iteration method (VIM) of He. The surface temperature comes as a combination of the time-fractional (half-time) subdiffusion model of the heat conduction and the boundary condition relating the temperature field at the surface through the Riemann-Liouville fractional . The result of this equation is a Bernoulli-type ordinary fractional equation with a non- linear term of 4th order. Two approaches in the identification of the general Lagrange multiplier and a consequent application of VIM have been applied. The common method replaces the fractional integral (in the Riemann-Liouville sense) by an integer order integral. The more exact method of Wu uses an initial Laplace transform of the fractional integral in the iteration formula to find correctly the Lagrange multiplier. Both approaches yield different Lagrange multipliers which results in different numerical results.The article discusses the origin of these differences in the light of correct application of VIM. The developed approximate solutions have been used in numerical simulation showing the effect of Biot number and the radiation-conduction number on the surface temperature evolution. Copyright © 2012 Praise Worthy Prize S.r.l. - All rights reserved.

Keywords: Variational Iteration Method, Bernoulli-Like Fractional Equation, Lagrange Multiplier, Surface Temperature Evolution

Nomenclature Greek Letters α Fractional order, dimensionless a Thermal diffusivity, ms2 ε Emissivity of cooled surface, b Sample (slab) thickness, m dimensionless General Lagrange multiplier h Heat transfer coefficient, WmK2 λ (τ ) k Thermal conductivity, WmK λH Lagrange multiplier defined by the method of He (see also the articles 2 qts′′ () Surface flux density, Wm of S. Momani et al.) t Time, s λW Lagrange multiplier defined by the tba* = 2 Time scale (heat diffusion), s method of G. C. Wu [24], [25] (see Eq.(13c)) Ambient temperature, K Ta σ Stefan Boltzmann constant Reference temperature, K Tref Γ(•) Gamma T Surface temperature, K s θ = TTs a Dimensionless temperature Initial temperature of the body, K T∞ θ (s) Laplace transform of the x Space co- ordinate, m dimensionless temperature θ y ()t Casual function ξ = x b Dimensionless space co-ordinate τ Dummy in the fractional Dimensionless Numbers and Bi= bh k Biot number Subscripts *2Fourier number Fotttab== n Number of iteration 3 Radiation conduction number NbTk= σε a

Manuscript received and revised August 2012, accepted September 2012 Copyright © 2012 Praise Worthy Prize S.r.l. - All rights reserved

489

Jordan Hristov

Superscripts equation with zero initial condition. Now, we stress the C Cooling attention on a fractional-time equation arising in transient H Heating heating of bodies where (1a) is related to the time- R Radiative evolution of surface temperature and the solution is developed without the temperature field in the depth of the body. I. Introduction The heat transfer problems are among those with II. Problem Formulation and Model intensive applications of new analytical and numerical methods for solving new emerging practical situations. The flash heating of powder for example is a The present article addresses two principle issues. technique widely applied for de-hydroxylation of First of all, a problem of surface heating of body kaolinite. This mineral ( Al23 Oii 2SiO 2 2H 2 O ) undergoes subjected to a non-linear heat flux compromising a an endothermic reduction (loss) of the amount of the convective heating and a counteracting radiation cooling hydroxyl water at about 600°C resulting in meta-kaolin. is formulated. The problem formulation uses half-time This final form is strongly dependent on the rate of fractional model (in the Riemann-Liouville sense) to heating during the flash process. The kaolinite particles create an ordinary fractional are in the micro-size range but form aggregates that get (OFDE). forms of flakes which to some extent can be accepted as This allows elimination of cumbersome solutions of plates when the thermal treatment process has to be the temperature file in the depth of the thermally treated modelled. In accordance with the model of Davies [11] body. Second, the fractional model of surface the kaolinite aggregates are assumed as plates of temperature evolution is of Bernoulli type OFDE which thickness b heated by convection passing rapidly is solved by the variational iteration method (VIM) of through a furnace and cooled be thermal radiation. It is He. The main problem is the correct identification of the well-known that such models have no analytical general Lagrange multiplier. All these problems are solutions due to the non-linearity of the boundary consequently developed in the article. conditions at the interface. The process of flash heating of plate relevant to I.1. Non-Linear Boundary Condition due to thermal treatment of kaolinite has been modelled by Convection and Thermal Radiation Davies [11] and solved approximately by the heat- balance integral method of Goodman [12]. The transient heating of flat surfaces is a common The same method has been applied to radiation thermal problem solved by many methods and under cooling of finite solids [13] and plates by convention- various boundary conditions. radiation [14]. The heat balance integral solution allows It is impossible to encompass all of them, relevant the surface temperature to be estimated by developing an especially to the flash heating of bodies used in the approximated temperature profile in the depth of body, chemical, metallurgical and mineral industries. We stress then defining the temperature gradient required to solve the attention to 1-D transient heat conduction with a (1a) with respect to T . The main drawback of this nonlinear boundary condition in the form: s solution is that the temperature gradient at the interface depends on the choice of the approximate profile [12] ∂T −=−±−khTTTTs CRσε 4 (1a) and its calibration [15],[16]. ()()ssref ref ∂x x=0 The present work considers the transient heat conduction in a plate of thickness b which is heated by In (1a) the reference temperature is [1],[2] is defined convection and cooled by thermal radiation. This is, in in accordance with the direction of heat fluxes fact, the problem considered by Davies [11], namely towards/from the interface, namely: for cooling: ∂∂TT2 k C R = a,a,xb=≤≤0 (2a) TT= a and TT= a (1b) 2 ref ref ∂tC∂x ρ p for heating: with: H R TT= a and TT= R (1c) ∂T ref ref = 0atx = b (2b) ∂x In the light of application of the He’s VIM (see refs [3]-[8]) to solve nonlinear conduction equations this and: boundary condition has been recently used for solving convective–radiative cooling of lumped system (fin ∂Ts 44 conduction problem) [9],[10]; as an independent −khTTTTx=−−()saσε () s − aat = 0 (2c) ∂x x=0

Copyright © 2012 Praise Worthy Prize S.r.l. - All rights reserved International Review of Chemical Engineering, Vol. 4, N. 5 Special Section on Open Door Initiative (ODI) – 3rd edition

490

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The problem of interest is the time evolution of the problem at issue. surface temperature Ts which to some extent could be ¾ Note: In order to be correct, a variable uT= ∞ − T transforms the initial condition of Eq. (2a) to zero accepted with an initial condition Tts ()==00 for one, which simplifies the problem with application simplicity of the solution. It can be solved by either of the RL . Similar problem, with only approximate analytical methods as those mentioned radiative cooling, i.e., qTxT4 above or numerically. However, with all these methods s =−∂∂()∂=x 0 =µ s the main errors come from the approximate and the variable uT= ∞ − T through the relationship determination of the space derivative Tx [12], ()∂∂x=0 ∗ −∗12 4 ∗ (4b) yields TTDTss(τµ) =−∞ ()τ , where τ [15],[16]. In order to find an effective solution of the is dimensionless time. The variable uT= − T problem where only the surface temperature Ts is of ∞ interest (it is the upper to which the body should be means only a shift of the origin of the co-ordinate heated; determined by technological conditions, for systems, that is equivalent to the assumption that example) we refer to the possibility to split (2a) into a T∞ = 0 at t = 0 : fractional (half-time) heat conduction equation, namely: k ∂12T 1 −=−−−s hT Tσε T44 T (5b) 12 ()s asa() ∂∂2Tx,t() Tx,t() α ∂t =− a (3a) 1 ∂x ∂t 2 Equation (5a) is expressed in a dimensional form but after non-dimensialization of the basic model (2a,b,c) with a fractional half-time derivative in the Riemann- * * 2 with θ = TTs a , ξ = x b and Fott= ( tba= ), we Liouville sense: get:

12 t RL 12 ∂ Tx,t() 1 d Tx,u() ∂∂θθ2 0 Ddut == (3b) = , 01≤≤ξ (6a) 12 Γ 12 dt ∫ 2 ∂−+ttu()0 ∂Fo ∂ξ

The surface flux and the temperature at the interface with: are interrelated by (3a) setting x = 0 : ∂θ = 0atξ ==xb 1 (6b) ∂ξ k ⎡⎤∂12T,t()0 T q,t′′ 0 =−∞ (4a) s () ⎢⎥12 α ⎣⎦⎢⎥∂ttπ and: ∂θ − s =−−−Bi()θθ11at0 N4 x = (6c) ∂ξ ss() with TT()x=0 = s x=0

−12 bh α ∂ ⎣⎦⎡⎤q,ts′′ ()0 Bi =−Biot Number (7a) T,t()0 =+ T (4b) k k −12 ∞ ∂t

bTσε 3 with: N =−a Radiation-conduction number (7b) ∂T k −=kqt′′ () ∂x s x=0 Now, using the relationship (4a) in a dimensionless form we get: T∞ in (4a),(4b) is the initial temperature of the body. Therefore, expressing the surface flux by (4a) and the 1 RL DBiN2θθ= −−11 θθ4 − , = 0 (8a) boundary condition (2c) we get: 0 Fo ss()() ss()Fo=0

After rearranging the RHS of (8a) we get a fractional k ⎡⎤∂12T T −−=−−−s ∞ hT Tσε T44 T (5a) (half –time) Bernoulli equation, namely: ⎢⎥12 ()s asa() απ⎣⎦⎢⎥∂tt 1 RL DABC2θ =+θθ + 4 (8b) at x = 0 . 0 Fo s ss

In accordance with the assumption that Tt= 00= s () A = NBi,BBi−=and C =− N (8c) we may suggest T∞ = 0 in (4a),(4b) that simplifies the

Copyright © 2012 Praise Worthy Prize S.r.l. - All rights reserved International Review of Chemical Engineering, Vol. 4, N. 5 Special Section on Open Door Initiative (ODI) – 3rd edition

491

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This fractional-time Bernoulli equation was not resulting in λ = −1. The result is the same as for the encountered in the literature so far, even with arbitrary fractional Riccati equations [17],[18] because both the fractional order 01<<α similar to the fractional Riccati linear and the non-linear terms in the RHS of (11b) are equation; expressed through the Caputo derivatives [16] restricted variations. Therefore, the correctional or modified Riemann-Liouville (Jumarie’s) derivatives functional (10a) for 01< α < (omitting the subscript Fo ) [17], namely: should be:

C α 2 0111Dytt ()=+ At () Bty () + C () ty,01 <<α (9) θ =−θθθθRLIDαα⎡ RL −− ABC − 4 ⎤ (11c) nnt+100 ⎣ n nn⎦

III. Solution by VIM However, following the rules defined by (11a),(11b) we may write the correction functional also as: In accordance with the VIM methodology, we have to construct a correction functional for (8b) in the form: Fo ⎡ RL α 4 ⎤ θnn+10=−θθθθτ∫ ⎣ DABCd Fonnn −− − ⎦ (11d) ⎡⎤⎛⎞RL α 0 RL α 0 DAFoθ n −+ θθnnt+1 =+I ⎢⎥ λτ()⎜⎟ (10a) 0 ⎢⎥⎜⎟4 ⎣⎦⎝⎠−−BCθθnn i.e. the Riemann-Liouville integral is replaced by an integer-order Riemann integral where: Therefore, there are two options in the successive iterations after determination of the Lagrange multiplier, Fo RL α 1 α −1 namely: It θ ()Fo=−()() Foτθ Fo d τ (10b) 0 Γ α ∫ 1) Approach 1 - Option 1 (A1-O1), λH = −1 and ()0 Riemann integration by (11d) is a fractional integral in the Riemann-Liouville sense. 2) Approach 1 - Option 2 (A1-O2), λH = −1 and The crucial step defining the successful application of Riemann-Liouville integration by (11c) VIM is the determination of the general Langrage • The subscript "H"indicate that this multiplier is multiplier λ (τ ) . The problems existing in its identified by rules drawn by J.H-He (see III.3 for detailed comments) determination are discussed next. These two options will be commented and numerically exemplified further in this article. III.1. Lagrange Multiplier Determination Approach 2: The main problem emerging through the identification Avoiding the problem with the impossible integration of the general Lagrange multiplier in case of fractional by parts with the integral Iα in (10a), we apply the equations is the fact that with the integral Iα in the approach of Wu [24], [25] which has two principle steps: correctional functional the cannot be a) By an initial Laplace transform to (10a) we get: applied [3],[4]. We will discuss two approaches existing in the literature and providing different Lagrange ⎡ t RL α ⎤ multipliers. ⎛⎞0 DAθn −+ θθnn+1 ()ssLt,=+()⎢ λτ ( )⎜⎟⎥ (12a) ⎢∫ ⎜⎟−−BCθθ4 ⎥ Approach 1: ⎣ 0 ⎝⎠nn⎦ Following Momani and Odibat [19]-[21] and other articles devoted to similar problems [17], [18], [22], [23] The Lagrange multiplier is assumed in the form the iteration formula (10a) is replaced by: λ (t,τλτ) = ( t − ) allowing:

Fo RL α 4 ⎡ t ⎤ θnn+10=+θλτθ()⎡⎤DABCd Fonnn −− θθτ − (11a) RL α 4 ∫ ⎣⎦ Lt,D⎢ λτ()()0 θnnn−− ABC θ − θ⎥ (12b) 0 ∫ ⎣⎢ 0 ⎦⎥

The stationary condition of the functional leads too: to be considered as convolution of λ ()t and: Fo dθn δθ=+ δθ δ λ() τd τ =0 (11b) RL α 4 nn+1 ∫ dτ DABCθ −−θθ − 0 ( 0 nnn)

4 Because θn is a restricted variation, i.e. δθn = 0 , the Then, if θn and θn are restricted variations (similar condition (11b) yields: λτ′( ) = 0 and 10+=λτ( ) to Approach 1), we get:

Copyright © 2012 Praise Worthy Prize S.r.l. - All rights reserved International Review of Chemical Engineering, Vol. 4, N. 5 Special Section on Open Door Initiative (ODI) – 3rd edition

492

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⎡ ααRL ⎤ integration by (11c), yield. δθnn+100()ssLID=+ δθ() δ t λ() θ n = ⎣ ⎦ (12c) Moreover, taking into account (see (8c)) that the α coefficients in the Bernoulli equations are A = NBi− , =+()1 λδθ()ssn () s BBi= and CN= − , and with α = 12 we get:

The stationary conditions implies the coefficient of Fo12 Fo δθ s to be equal to zero, that results in: AO12− n () θ = ()NBi−++ Bi ΓΓ()32() 2 1 52 (15) λ s =− (13a) Fo Γ()3 () α − N s Γ()72 4 ⎣⎦⎡⎤Γ()32 b) The inverse Laplace transform of (13a) gives the Wu’s multiplier [24], [25], (denoted as λW ): The experiment just performed, was done by intuition, i.e. a mechanistic combination of λH =−1 with the ()tt−−−ττααα−−11()(1 ) Riemann-Liouville integration. However, as it is λτ()t, =− = (13b) demonstrated further in this article (see sec. V) this is a W ΓΓαα () () route equivalent to a combination of the Wu’s multiplier and the Riemann integration. More detailed analyses about this approach and the Lagrange multiplier (13b) are available in [24], [25]. ()Fo −τ α −1 Thus, with the Lagrange multiplier (13b) and taking Approach 2 (with λ =− ) and integration into account that tFo≡ (and omitting the subscript Fo ), W Γ()α the correctional functional (10a), for 01<<α , is: by (13d)

Foα θ =+θ With the same initial approximation θ = nn+1 0 Γ+()1 α Fo ⎡⎤()(−−1 ααFo τ )−1 ⎡⎤RLDAαθ −+ (13c) +×⎢⎥⎢⎥0 n dτ and taking into account that tFo≡ we get by iteration ∫ ⎢⎥Γ α 4 0 ⎣⎦() ⎣⎦⎢⎥−−BCθθnn Foαα Fo2 θ W = AB++ 1 Γ+()112αα Γ+() III.2 Iterations (16a) Fo5α Γ+()14α Approach 1 (with λ =−1 ) + C H 4 Γ+()15α ⎡⎤Γ+()1 α Option 1 (A1-O1 , λH =−1 and Riemann integration by ⎣⎦ (11d). This is common approach well-known from the with α = 12/ we have: literature (see refs.[17]-[22]). Assuming the initial α 12 52 Fo W Fo Fo Fo Γ()3 approximation as θ = we get by iteration: θ1 =++ABC (16b) 0 Γ+1 α ΓΓΓ32 2 72 4 () () () ()⎣⎦⎡⎤Γ()32

α AO− Fo The these results, i.e. (14b), (15) and (16b) are θ 11=−()AFo1 + + 1 Γ+()1 α presented graphically in a of plots (see Figs. 1-3) (14a) with various values of Bi and N numbers. Foαα++151 Fo ++BC 4 ()()11+Γ+αα15+Γ+αα⎡⎤ 1 ()()⎣⎦ III.3 Comments on the Lagrange Multipliers with α = 12, we get: The different results developed by both approaches need clarifications about the origin of these results. First of all it is clear that with the fractional integral and a Fo12 θ AO11− =−()AFo1 + + fractional derivative in the functional the differentiation 1 Γ()32 by parts does not hold. Browsing the literature on VIM, (14b) ⎛⎞22Fo32 ⎛⎞ Fo 72 several principle approximations have been done, among ++BC⎜⎟ ⎜⎟ them: ⎝⎠3327Γ ⎝⎠ 4 () ⎣⎦⎡⎤Γ()32 The first approximation in the identification of the general (example 2 in ref.[26]) provoked a simplification 3) Option 2 (A1-O2), λH =−1 and Riemann-Liouville by introducing restricted variations of high-order terms in the correction functional. This step, which, in fact,

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simplified the integration by parts, yields an approximate Lagrange multiplier. Now, this is a common step in all studies on VIM, but commonly the authors forget the reasons for this approach. The second approximation in application of VIM was done when fractional differential equations were at issue (see in detail part 5 in ref. [27]). Since the integration by parts does not hold with the Riemann-Liouville integral and the fractional derivative in the functional, He did two simplifications more a) Replaced the Riemann-Liouville integral by an integer Riemann Integral; b) The fractional derivative was replaced by an integer one of order m (minimal m=> ceil ()α α or maximal integer m=< floor ()α α ). In the case of 01<<α , and particularly with α = 12 we have m== floor ()α 1 . Combining Approx. 1 and Approx. 2, and the ideas of He [26], [27] the steps expressed by Eqs (11a), (11b) seems correct even though these are approximations avoiding principle obstacles in determination of the Lagrange multiplier. However, the consequent application of an integer (Riemann) integral in the development of the successive iteration (see again Chapter 5 in Ref. [2]) does not mean reasonable from a mathematical point of view. Nevertheless, from practical reasons, there is strong motivation this to be done. Simply, the increase in the order of iterations makes the calculations cumbersome which are hard to be handled manually, but easily carried out by Maple or Mathematica, where fractional integrals are not developed. Frequently, in the recent literature, this approach is referred to the works of Momani and collaborators [19]-[21] since they are easily accessible, but, in fact, the origin is the works of He [26], [27]. The Wu’s approach attacks the problem correctly, since it strictly follows the VIM’s rules without any approximation in the type of the integral in the correction functional. The only trace remaining from the He’s suggestions is the Approximation 1, with restricted variations of high order terms.

IV. Numerical Simulations and Comments Before performing cumbersome iterations resulting from the non-linear radiation term in the boundary condition, let us see what is the effect of Bi and N dimensionless numbers on the behaviour of the first iteration performed with the two distinct Lagrange multipliers and the suggested option in the integration in the correction functional. Initially, we start with Bi = 1 Figs. 1. Effect of the Lagrange multiplier on the first iteration in and N = 1 , following the work of Davies [11] and various case of convective heating and radiative cooling Crosbie and Viskanta [28]. The plots in Fig. 1(a) indicate The same behaviour is observed with N = 0.5 (see that the first iteration with λH =−1 goes far away from Fig. 1(b)), as well as when Bi = 0.1 and N = 0.1(Fig. the initial approximation, while with λ and W 1(c)). The case with extreme values of Bi = 10 and the lines are practically indistinguishable. λH ( A12− O ) (N = 10) does give adequate information which of the

Copyright © 2012 Praise Worthy Prize S.r.l. - All rights reserved International Review of Chemical Engineering, Vol. 4, N. 5 Special Section on Open Door Initiative (ODI) – 3rd edition

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first iterations is better (Fig. 1(d)). Physically, small Fo , means either small times for In case of only heating ( N = 0 ) (see Figs. 2(a), (b)); it materials with small thermal diffusivity time scale is possible to distinguish the behaviour of the lines, but ( ba2 ), or large times with large ba2 . In any case, the in all these the first iterations with λH ()A 12− O and the use of Fo as independent variable allows VIM to be Wu’s, multiplier and consequent Riemann-Liouville applied. integration practically merge (indistinguishable).

Figs. 2. Effect of the Lagrange multiplier on the first iteration in various case of convective heating only

The cases with small Bi numbers are small and the radiative cooling is dominating (see Fig. 3(a)) demonstrate distinguishable behaviour of the first iterations. In the other cases (Figs. 3(b), (c)) it is hard only on the basis of the first iteration to get right information which approximation is better, even though theoretically that of Wu with λW is the correct one. These are only first attempts to find what should be done further. The large varieties of values of the dimesionless numbers Bi and N do not allow to estimate, at this Figs. 3. Effect of the Lagrange multiplier on the first iteration in moment, the best performance of the approximation with various case of radiative cooling only either λH or λW . However, this can be simply estimated in a particular case strongly related to a practical The problems with successive approximation of high problem. order and their convergences when both Lagrange A special attempt in this work was done by non- multipliers are applied is open and its solution is a dimensalization of the governing equations and using the challenge, but beyond the scope of the present work. The Fourier number Fo as independent variable. This was better way, to elucidate this crucial for the VIM’s done, because, it is well-know that convergence of VIM applications problem is to solve well-known examples is better at small times, i.e. at small values of Fo in the available in the literature; this draws ideas for future present case. studies.

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V. Some Comments on the Options in the Moreover, we may expect that the correct approach in Integration and the Emerging Results the VIM integration and the Lagrange multiplier determination proposed by Wu would be briefly The previous point demonstrated what the numerical accepted and successful solutions of problems will be behaviour of the first iteration is when some published soon. combinations (option in iterations) between the Lagrange multiplier and the type of the integral were performed. First of all, starting with the dominating approach VI. Conclusion used by Momani et al. ([19]-[21]), we have: The present work formulated a time-fractional Bernoulli equation as a consequent splitting the heat- t C α ⎡⎤0 Duτ nn++ Ru[] conduction model into a subdiffusion one (half-time) uunn+1 =+λ () t,ττ⎢⎥ d (17a) with derivatives in the Riemann-Liouville sense and ∫ ⎢⎥+−Nu f()τ 0 ⎣⎦[]n application of a non-linear boundary flux condition involving both convective heating and radiative cooling. For the equation: The approach is general and can be applied to other

combinations of the heat fluxes acting at the solid-fluid C α 0 Duτ nn++ Ru[ ] Nu[ n] = f()τ (17b) interface. More interesting problem emerging in this work is the Here we use the common notations available in the correct performance of the successive iterations by the literature. proper identification of the general Lagrange multiplier. With the Lagrange multiplier λH =−1 commonly The steps done in the analysis of the problem stop at the used in the literature (Momani [19]-[21]), we get results first iterations only, because before cumbersome already demonstrated by integration with the Riemann calculations it is useful to elucidate which approach is integral, namely: promising. The numerical simulations illustrated by the plots indicate better performance of the Wu’s multiplier. t This is first estimation, but more information could be ⎡⎤C α taken from solutions of problems having exact closed- uunn+10=−∫ ⎣⎦ DuRuNufdτ n +[] n + [] n −()τ τ (18) 0 form or numerical solutions. The problem formulated in this work allows the However, with the Wu’s multiplier: surface temperature evolution of bodies to be calculated in a simpler way avoiding cumbersome solution of the α −1 temperature field in the depth of the medium. This would α ()τ − t be really a straightforward approach, but some essential λW =−()1 (19a) Γ()α steps in the application of VIM , especially the correct Lagrange multiplier identification and consequent which, in fact, is the kernel of the integration by the application of integration in the Riemann-Liouville since Riemann-Liouville integral , we get the Wu’s iteration (as it was done in this work) should be further formula, namely: thoroughly analyzed for particular problems.

uu=+ nn+1 Acknowledgements ⎧⎫⎡⎤α −1 α ()τ − t t ⎪⎪⎢⎥()−×1 This work was supported by University of Chemical ⎪⎪⎢⎥Γ()α ∫ ⎨⎬⎣⎦ dτ = (19b) Technology and Metallurgy, Sofia, Grant N10995/2012. 0 ⎪⎪The fruitful comments of Dr. G.-C Wu (College of ×++−⎡⎤C Duα Ru Nu fτ ⎩⎭⎪⎪⎣⎦0 τ nn[] [] n() Mathematics and Information Science, Neijiang Normal =−uIDuRuNufRLαα⎡⎤ C +[] + [] −()τ University, P.R. China) and his help in checking the nt00⎣⎦τ n n n calculations are highly appreciated.

Therefore, the Wu’s approach is equivalent to RL References integration with λH =−1 , as it was suggested mechanistically in this article, but from practical point of [1] J.L. Milton, W.P.Goss, On solving the transient conducting slab view it is more convenient since the Riemann integration with radiating and convecting surfaces, J. Heat Transfer, 96 (1974) 547-549. can be easily performed by Maple or Mathematica. [2] S. Liao J. Su, A.T. Chwang, Series solutions for a nonlinear We expect these brief explanations will elucidate the model of combined convective and cooling of a spherical body, behaviour of the first iterations demonstrated graphically Int. J. Heat Mass Transfer, 49 (2006) 2437–2445. in the previous point and while, in fact some of them [3] J.-H. He, Approximate analytical solution for seepage flow with were indistinguishable; in fact different combinations led fractional derivatives in porous media, Comput. Methods Appl. Mech. Eng. ,167 (1998) 57-68. to one and the same results.

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Jordan Hristov

[4] J.-H. He, Variational iteration method - a kind of non-linear Authors’ information analytical technique: some examples, Int. J. Non-Linear Mech., 34 (1999) 699-708. Jordan Hristov is associate professor in [5] J.-H. He, Variational iteration method for autonomous ordinary Department of Chemical Engineering University differential systems, Appl. Math.Comput., 114 (2000) 115–123. of Chemical Technology and Metallurgy [6] M.A. Abdou, A.A. Soliman, New applications of variational (UCTM) 1756 Sofia, 8 Kl. Ohridsky Blvd., iteration method, Physica D 211 (2005) 1–8. Bulgaria. [7] A.M. Wazwaz AM, The variational iteration method for analytic treatment for linear and nonlinear ODEs. Appl. Math Comput., 212 (2009) 120-134. [8] F.M. Fernandez, On some approximate methods for nonlinear models, Appl. Math.Comput., 215 (2009) 168–174. E-mails: [email protected] [9] D.D. Ganji , M.J. Hosseini, J. Shayegh, Some nonlinear heat [email protected] transfer equations solved by three approximate methods, Int. Website: http://hristov.com/jordan Comm. Heat Mass Transfer, 34 (2007) 1003–1016. [10] Mo. Miansari, D.D. Ganji, Me. Miansari, Application of He’s variational iteration method to nonlinear heat transfer equations , Physics Letters A, 372 (2008) 779–785. [11] T.W. Davies, Transient conduction in a plate with counteracting convection and thermal radiation at the boundaries, Appl. Math. Modelling, 9 (1985) 337-340. [12] T.R Goodman, The heat balance integral and its application to problems involving a change of phase, Transactions of ASME, 80 (1958) 335-342. [13] T.W. Davies, The radiant cooling of a finite solid, Int. Comm. Heat Mass Transfer, 11 (1984) 311-321. [14] T.W. Davies, The cooling of a plate by combined thermal radiation and convection, Int. Comm. Heat Mass Transfer, 12 (1985) 405-415. [15] J.Hristov, The heat-balance integral method by a parabolic profile with unspecified exponent: Analysis and benchmark exercises, Thermal Science, 13 (2009) 22-48. [16] Hristov, J. The Heat-Balance Integral: 1. How to Calibrate the Parabolic Profile?, CR Mechanique, 340 (2012) 485-492. [17] H. Jafari , H. Tajadodi, He’s Variational Iteration Method for Solving Fractional Riccati Differential Equation, Int. J.Diff. Eqs, 2010, Article ID 764738, doi:10.1155/2010/764738. [18] M. Merdan, On the Solutions Fractional Riccati Differential Equation with Modified Riemann-Liouville Derivative, Int. J. Diff. Eqs, (2010), Article ID 346089, doi:10.1155/2012/346089 [19] S.Momani, Z. Odibat, Analytical approach to linear fractional partial differential equations arising in fluid mechanics, Physics Letters A, 355 (2006) 271–279. [20] S.Momani, Z. Odibat, Numerical comparison of methods for solving linear differential equations of fractional orders, Chaos Soliton Fract., 31 (2007) 1248-1255. [21] Z.Odibat, S. Momani, Numerical methods for nonlinear partial differential equations of fractional order, Appl. Math. Mod., 33 (2008) 28-39. [22] F. Dal, Application of variational iteration method to fractional hyperbolic partial differential equations, Math. Probl. Eng. (2009), Article ID 824385, doi: 10.1155/2009/824385. [23] S. Das, Analytical solution of a fractional diffusion equation by variational iteration method, Comp. Math.Appl., 57 (2009) 483- 487. [24] G.-C.Wu, Variational iteration method for solving time-fractional diffusion in porous media medium, Chin Phys B, (2012) DOI:10.1088/1674-1056/21/12/12- in press. [25] M.B. Wei, G.C.Wu, Variational iteration method for the diffusion equations with the Riemann-Liouville derivatives, Heat. Trans. Res. (2012) -in press. [26] J.-H. He, A new approach to non-linear partial differential equations, Commun. Nonlinear Sci. Num Sim., 2 (1997) 230-235. [27] J.-H. He, Approximate analytical solution for seepage flow with fractional derivatives in porous media, Comp. Math. Appl. Mech. Eng., 167 (1998) 57-68. [28] A.I. Crosbie, R.Viskanta, Trasnient heating or cooling of a plate by combined convection and radiation, Int. J. Heat Mass Transfer, 11 (1968) 305-317.

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