i i WATER QUALITY MONITORINGPROGRAM OF THE METROPOLITANAREA PLANNING COUNCl~S 208 MANAGEMENTAREA 1977 DATA REPORT

ij

I '

WATER QUALITY AND RESEARCH SECTION ' DIVISION OF WATER POLLUTION CONTROL ij DEPARTMENT OF ENVIRONMENTAL QUALITY ENGINEERING WATERQUALITY MONITORING PROGRAM

OF THE

METROPOLITANAREA PLANNING COUNCIL'S

208 MANAGEMENTAREA

1977

DATAREPORT

PREPAREDBY WATERQUALITY AND RESEARCH SECTION MASSACHUSETTSDIVISION OF WATERPOLLUTION CONTROL DEPARTMENTOF ENVIRONMENTALQUALITY ENGINEERING

WESTBOROUGH,MASSACHUSETTS

NOVEMBER1977

Publication Number: Approved By: #12769-226-25-4-82-CR John J. Manton, State Purchasing Agent TABLE OF CONTENTS

ITEM PAGE

Introduction 3

List of Tables 4

List of Figures 11

Water Quality Sampling Data 12

Ipswich River Basin 13

Aberjona River Basin 37

Neponset River Basin 60

North and South River Basins 84

Charles River Basin 108

SUASCORiver Basin 133

Sediment Sampling Data 158

Ipswich River 159

Neponset River 163

Charles River 167

Assabet & Sudbury Rivers & Hop Brook 171

Benthic Invertebrate Sampling Data 175

Assabet River 181

Neponset River 194

Ispwich River 206

Marblehead Harbor Survey Data 213

Measures of Water Pollution 220

2 INTRODUCTION

The Massachusetts Division of Water Pollution Control, in cooperation with the Metropolitan Area Planning Council (MAPC), undertook during 1977 an extensive water quality monitoring program in the major river basins of the MAPC 208 management area. This program was multi-faceted with water quality sampling of surface waters, sampling of stream sediments, and sampling of benthic invertebrates. In addition, a special survey was conducted in Marblehead Harbor to assess the impact of vessel discharges and to determine the overall water quality of this popular and extensively used harbor.

This report presents the results of the analyses performed on the hundreds of samples collected during the duration of this project. Chemical analyses were performed at the Lawrence Experiment Station of the Department of Environmental Quality Engineering, according to procedures described in the American Public Health Association's document Standard Methods for the Examination of Water and Wastewater (14th Edition, 1976, New York). The benthic invertebrate samples were analyzed by biological staff personnel of the Division's Water Quality Section, according to methods recommended by the United States Environ­ mental Protection Agency. The data was recorded and placed in tabular form by personnel of Division's Water Quality Section.

3 LIST OF TABLES

NUMBERAND DESCRIPTION PAGE

I. Water Quality Monitoring Program A. Ipswich River Basin 1. Location of Monitoring Stations 13 2. Time - Temperature - Dissolved Oxygen 15 3. Chemical Oxygen Demand Data 17 4. 5-Day Biochemical Oxygen Demand Data 18 5. pH Data 19 6. Total Alkalinity Data 20 7. Hardness Data 21 8. Turbidity Data 22 9. Suspended Solids Data 23 10. Dissolved Solids Data 24 11. Total Solids Data 25 12. Total Kjeldahl-Nitrogen Data 26 13. Ammonia-Nitrogen Data 27 14. Nitrate-Nitrogen Data 28 15. Total Phosphorus Data 29 16. Total Coliform Data 30 17. Fecal Coliform Data 31 18. Cadmium Data 32 19. Iron Data 33 20. Lead Data 34 21. Manganese Data 35 22. Zinc Data 36 B. Basin 1. Location of Monitoring Stations 37 2. Time - Temperature - Dissolved Oxygen 39 3. Chemical Oxygen Demand Data 40 4. 5-Day Biochemical Oxygen Demand Data 41 5. pH Data 42 6. Total Alkalinity Data 43

4 LIST OF TABLES (CONTINUED)

NUMBERAND DESCRIPTION PAGE B. Aberjona River Basin (Continued) 7. Hardness Data 44 8. Turbidity Data 45 9. Suspended Solids Data 46 10. Dissolved Solids Data 47 11. Total Solids Data 48 12. Total Kjeldahl-Nitrogen Data 49 13. Ammonia-Nitrogen Data 50 14. Nitrate-Nitrogen Data 51 15. Total Phosphorus Data 52 16. Total Coliform Data 53 17. Fecal Coliform Data 54 18. Cadmium Data 55 19. Iron Data 56 20. Lead Data 57 21. Manganese Data 58 22. Zinc Data 59 C. Neponset River Basin 1. Location of Monitoring Stations 60 2. Time - Temperature - Dissolved Oxygen 62 3. Chemical Oxygen Demand Data 64 4. 5-Day Biochemical Oxygen Demand Data 65 5. pH Data 66 6. Total Alkalinity Data 67 7. Hardness Data 68 8. Turbidity Data 69 9. Suspended Solids Data 70 10. Dissolved Solids Data 71 11. Total Solids Data 72 12. Total Kjeldahl-Nitrogen Data 73 13. Ammonia-Nitrogen Data 74 14. Nitrate-Nitrogen Data 75

5 LIST OF TABLES (CONTINUED)

NUMBERAND DESCRIPTION PAGE C. Neponset River Basin (Continued) 15. Total Phosphorus Data 76 16. Total Coliform Data 77 17. Fecal Coliform Data 78 18. Cadmium Data 79 19. Iron Data 80 20. Lead Data 81 21. Manganese Data 82 22. Zinc Data 83 D. North and South River Basins 1. Location of Monitoring Stations 84 2. Time - Temperature - Dissolved Oyxgen 86 3. Chemical Oyxgen Demand Data 88 4. 5-Day Biochemical Oxygen Demand Data 89 5. pH Data 90 6. Total Alkalinity Data 91 7. Hardness Data 92 8. Turbidity Data 93 9. Suspended Solids Data 94 10. Dissolved Solids Data 95 11. Total Solids Data 96 12. Total Kjeldahl-Nitrogen Data 97 13. Ammonia-Nitrogen Data 98 14. Nitrate-Nitrogen Data 99 15. Total Phosphorus Data 100 16. Total Coliform Data 101 17. Fecal Coliform Data 102 18. Cadmium Data 103 19. Iron Data 104 20. Lead Data 105 21. Manganese Data 106 22. Zinc Data 107

6 LIST OF TABLES (CONTINUED)

NUMBERAND DESCRIPTION PAGE E. Charles River Basin 1. Location of Monitoring Stations 108 2. Time - Temperature - Dissolved Oxygen 110 3. Chemical Oxygen Demand Data 113 4. 5-Day Biochemical Oxygen Demand Data 114 s. pH Data 115 6. Total Alkalinity Data 116 7. Hardness Data 117 8. Turbidity Data 118 9. Suspended Solids Data 119 10. Dissolved Solids Data 120 11. Total Solids Data 121 12. Total Kjeldahl-Nitrogen Data 122 13. Ammonia-Nitrogen Data 123 14. Nitrate-Nitrogen Data 124 15. Total Phosphorus Data 125 16. Total Coliform Data 126 17. Fecal Coliform Data 127 18. Cadmium Data 128 19. Iron Data 129 20. Lead Data 130 21. Manganese Data 131 22. Zinc Data 132 F. SUASCORiver Basin 1. Location of Monitoring Stations 133 2. Time - Temperature - Dissolved Oxygen 135 3. Chemical Oxygen Demand Data 138 4. 5-Day Biochemical Oxygen Demand Data 139 5. pH Data 140 6. Total Alkalinity Data 141 7. Hardness Data 142

7 LIST OF TABLES (CONTINUED)

NUMBERAND DESCRIPTION PAGE F. SUASCORiver Basin (Continued) 8. Turbidity Data 143 9. Suspended Solids Data 144 10. Dissolved Solids Data 145 11. Total Solids Data 146 12. Total Kjeldahl-Nitrogen Data 147 13. A!lllllonia-Nitrogen Data 148 14. Nitrate-Nitrogen Data 149 15. Total Phosphorus Data 150 16. Total Coliform Data 151 17. Fecal Coliform Data 152 18. Cadmium Data 153 19. Iron Data 154 20. Lead Data 155 21. Manganese Data 156 22. Zinc Data 157 II. Sediment Sampling Program A. Ipswich River 1. Sediment Sampling Locations 159 2. Sediment Sampling Data 161 B. Neponset River 1. Sediment Sampling Locations 163 2. Sediment Sampling Data 165 c. Charles River 1. Sediment Sampling Locations 167 2. Sediment Sampling Data 169 D. Assabet & Sudbury Rivers & Hop Brook 1. Sediment Sampling Locations 171 2. Sediment Sampling Data 173

8 LIST OF TABLES (CONTINUED)

NUMBERAND DESCRIPTION PAGE III. Benthic Invertebrate Sampling Program A. Location of Sampling Stations 176 B. 1. Station AS02 Data 181 2. Station AS06 Data 183 3. Station AS14 Data 184 4. Station AS15 Data 186 5. Station AS17 Data 188 6. Station AS19 Data 190 7. Station AS22 Data 192 c. Neponset River 1. Station NEOl Data 194 2. Station NE02 Data 196 3. Station NE04 Data 198 4. Station NE05 Data 200 5. Station NE07 Data 202 6. Station NE08 Data 204 D, Ipswich River 1. Station IP03 Data 206 2. Station IP05 Data 208 3. Station IP13 Data 210 4. Station IP14 Data 211 IV. Marblehead Harbor Sampling Program A. Marblehead Harbor Survey 1. Location of Sampling Stations 214 2. Total and Fecal Coliform Bacteria 216 Data - Station 1 3. Total and Fecal Coliform Bacteria 218 Data - Stations 2 - 5 4. Chemical Data 219

9 LIST OF TABLES (CONTINUED)

NUMBERAND DESCRIPTION PAGE V. Measures of Water Pollution A. Specified Levels of Certain Parameters - Massachusetts 224 Water Quality Standards Revised 1974 B. Selected Analyses of Unpolluted Waters 226

10 LIST OF FIGURES

FIGURE DESCRIPTION PAGE A Location of Water Quality Monitoring Stations - 14 Ipswich River Basin

B Location of Water Quality Monitoring Stations - 38 Aberjona River Basin

C Location of Water Quality Monitoring Stations - 61 Neponset River Basin

D Location of Water Quality Monitoring Stations - 85 North and South River Basins

E Location of Water Quality Monitoring Stations - 109 Charles River Basin

F Location of Water Quality Monitoring Stations - 134 SUASCORiver Basin

G Sediment Sampling Locations - Ipswich River 160

H Sediment Sampling Locations - Neponset River 164

I Sediment Sampling Locations - Charles River 168

J Sediment Sampling Locations - Assabet and Sudbury 172 Rivers and Hop Brook

K Location of Benthic Invertebrate Samples - 177 Assabet River

L Location of Benthic Invertebrate Samples - 178 Neponset River

M Location of Benthic Invertebrate Samples - 179 Ipswich River

N Location of Sampling Stations - Marblehead Harbor 215 Survey

11 WATERQUALITY SAMPLING DATA

12 TABLE I-A-1

DWPC- MAPC208 MONITORINGPROGRAM

IPSWICH RIVER BASIN

LOCATIONOF MONITORINGSTATIONS

NUMBER STREAM LOCATION MUNICIPALITY

01 Ipswich River Wildwood Street Wilmington

02 Ipswich River Woburn Street Wilmington

03 Ipswich River Haverhill Road North Reading

04 Ipswich River Russell Street Peabody

05 Ipswich River Route 62 Middleton

06 Ipswich River Route 97 Topsfield

07 Ipswich River Willowdale Dam Topsfield

08 Ipswich River Sylvania Dam Ipswich

09 Lubber Brook Concord Street Wilmington

10 Martin's Brook Park Street West North Reading

11 Boston Brook Peabody Street Middleton

12 Fish Brook Endicott Road Topsfield

13 Howlett Brook Ipswich Road Topsfield

14 Miles River Route lA Ipswich

15 Miles River Bridge Street Hamilton

16 Miles River Larch Row Wenham

13 LOCATIONOF MONITORINGSTATIONS

IPSWICH RIVER BASIN

is"-a,...... _ DY

0 I 2 3 4

MILES

FIGURE A 14 TABLEI-A-2 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN TIME - TEMPERATURE- DISSOLVEDOXYGEN

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 01 * 0925 0930 0920 0955 ** 37 58 69 65 *** 7.0 3.8 0.9 1.4 02 0915 0925 0910 0945 37 58 69 69 7.7 3.3 2.8 4.3

03 1000 0955 0950 1020 37 59 72 69 8.7 4.2 5.4 4.5

04 Above 1015 1010 1005 1030 38 59 74 72 9.4 5.8 3.1 5.9

04 Below 1015 1010 38 74 10.5 5.4

05 1050 1025 1015 1040 38 58 72 69 9.9 7.2 4.8 3.5

06 1125 1055 1050 1115 37 59 72 70 10.8 5.6 4.9 6.8

07 Above 1155 1110 1110 1135 39 60 74 73 9.1 5.8 3.0 6.2

07 Below 1200 1110 1110 40 60 74 10.3 6.4 5.1

08 Above 1240 1120 1120 1140 39 60 77 73 10.1 7.2 6.4 5.6

* Time ** Temperature (OF) *** Dissolved Oxygen (mg/1)

15 TABLEI-A-2 (CONTINUED)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

08 Below 1245 1120 1125 40 60 76 11. 0 8.0 6.3

09 0935 0940 0925 1000 37 58 70 68 8.5 4.0 3.3 2.2

10 0950 0945 0940 1010 38 59 71 68 8.9 5.1 2.4 2.4

11 1100 1130 1025 1050 36 59 73 70 12.0 8.8 6.2 4.4

12 1110 1040 1035 1100 36 58 68 65 11.4 8.2 6.5 7.3

13 1140 1105 1100 1125 38 59 73 73 11.2 7.8 7.1 7.0

14 1250 1225 1130 1210 40 60 72 72 8.9 5.3 3.0 4.2

15 1305 1235 1140 1220 42 62 72 70 10.7 4.6 0.3 2.0

16 1320 1245 1155 1225 42 60 72 70 6.6 5.6 1.0 5.4

16 TABLE I-A-3 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN CHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH22 MAY2 JULY 5 SEPTEMBER6

01 30 21 41 55

02 45 31 51 55

03 50 47 77 40

04 50 58 67 45

05 50 54 51 30

06 35 52 51 45

07 30 47 66* 40

08 45 31 56 50

09 60 54 51 65

10 45 47 61 70

11 40 42 51 30

12 35 47 51 25

13 35 21 20 25

14 25 26 51 35

15 30 21 31 25

16 20 26 51 30

* July 7

17 TABLEI-A-4

DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN 5-DAY BIOCHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 2. 1 3.6 1.5 0.9

02 2.4 3.9 0.9 0.6

03 2.1 3.6 2.1 1.2

04 0.9 3.6 1. 2 2. 1

05 1.8 2.1 1.8 0.6

06 4.2 3.9 1.2 0.3

07 1.2 3.3 1.8* 2.1

08 2.1 3.3 1.5 0.9

09 2. 1 1.8 1.2 3.0

10 0.6 3.3 2.7 1. 2

11 2.4 3.3 1.8 0.9

12 1. 2 3.0 1.5 0.0

13 1. 2 3.3 1.8 0.0

14 1.8 3.9 2.1 1. 2

15 0.9 4.2 2. 7 0.3

16 1. 2 3.3 2.7 0.0

* July 7

18 TABLEl-A-5 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN pH DATA (Standard Units)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 6.7 7.0 6.8 6.8

02 6.4 6.9 6.8 7.0

03 6.3 6.7 6.8 6.8

04 6.4 6.6 6.7 7.1

05 6.6 6.8 6.9 7.2

06 6.6 6.7 7.0 7.5

07 6.5 6.7 6.6* 7.4

08 6.6 6.8 7.1 7.4

09 6.1 6.5 6.7 6.8

10 6.3 6.6 6.7 6.4

11 6.5 6.8 6.9 6.7

12 6.5 6.9 7.3 7.4

13 6.8 7.1 7.3 7.7

14 6.6 6.8 6.9 7.3

15 6.6 6.7 6.6 6.8

16 6.4 6.7 6.8 7.1

* July 7

19 TABLEI-A-6 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN TOTALALKALINITY DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 21 31 48 47

02 12 22 40 39

03 9.0 15 28 22

04 9.0 14 27 31

05 14 22 35 49

06 11 17 34 44

07 10 18 26* 43

08 11 17 35 42

09 7.0 13 28 38

10 8.0 14 25 14

11 7.0 11 23 25

12 8.0 14 24 32

13 17 29 41 54

14 13 21 46 52

15 12 21 41 49

16 11 20 52 41

* July 7

20 TABLEI-A-7 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN HARDNESSDATA (mg/1)

STATION MARCH21 MAY 2 JULY 5 SEPTEMBER6

01 35 48 58 67

02 33 44 50 44

03 28 30 44 50

04 27 28 41 55

05 33 39 53 71

06 29 33 53 71

07 27 32 54* 70

08 27 31 49 64

09 27 28 38 52

10 24 26 40 40

11 20 23 32 43

12 24 29 49 59

13 32 42 53 79

14 25 32 53 75

15 25 33 43 54

16 21 28 52 53

* July 7

21 TABLEI-A-8 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN TURBIDITYDATA (NTU)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 0.7 1.3 2.0 5.3

02 0.4 0.8 1. 7 2.8

03 0.3 0.8 2.5 4.9

04 0.3 1.0 2.7 2.1

05 0.4 0.4 3.4 1.2

06 0.5 0.9 3.2 1. 9

07 0.3 0.9 3.4* 3.9

08 0.3 0.9 3.2 1.2

09 0.4 0.4 2.2 2.6

10 0.4 1.1 1.7 1.2

11 0.3 1.0 2.3 1.6

12 0.5 1.4 3.5 1. 7

13 0.6 1.5 7.7 3.1

14 0.8 1.1 2.5 2.9

15 0.5 1.2 4.0 4.9

16 0.5 1. 6 3.5 2.9

* July 7

22 TABLEI-A-9 DPWC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN SUSPENDEDSOLIDS DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 1.0 0.0 0.5 6.5

02 1.0 0.0 0.5 7.0

03 1.0 0.0 3.0 6.0

04 1.0 0.0 1.0 7.5

05 1.0 0.0 0.5 2.0

06 1.0 0.0 1.0 8.0

07 1.0 0.0 2.0* 4.0

08 1.0 o.o 0.5 4.0

09 1.0 0.0 1.0 19

10 1.0 o.o 4.5 15

11 1.0 o.o 0.5 4.5

12 1.0 0.0 1.5 2.5

13 2.0 0.0 1.0 6.0

14 3.0 0.0 1.5 8.5

15 2.0 0.0 3.5 5.5

16 1.0 0.0 7.0 4.5

* July 7

23 TABLEI-A-10 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN DISSOLVEDSOLIDS DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 157 124 207 193

02 119 110 199 175

03 109 90 169 166

04 89 86 161 150

05 105 128 167 166

06 87 70 159 152

07 73 68 176* 132

08 75 70 145 122

09 107 114 161 153

10 79 76 167 141

11 51 46 103 75

12 63 54 150 109

13 74 72 129 122

14 59 72 158 127

15 48 66 116 120

16 49 52 137 107

* July 7

24 TABLEI-A-11 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN TOTALSOLIDS DATA (mg/1)

STATION MARCH21 MAY 2 JULY 5 SEPTEMBER6

01 158 124 208 200

02 120 110 200 182

03 110 90 172 172

04 90 86 162 158

05 106 128 168 168

06 88 70 160 160

07 74 68 178* 136

08 76 70 146 126

09 108 114 162 172

10 80 76 172 156

11 52 46 104 80

12 64 54 152 112

13 76 72 130 128

14 62 72 160 136

15 50 66 120 126

16 so 52 144 112

* July 7

25 TABLEI-A-12

DWPC- MA.PC208 MONITORINGPROGRAM IPSWICH RIVER BASIN TOTALKJELDAHL-NITROGEN DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 0.59 1.1 1.4 1.3

02 1.2 0.75 1.1 0.90

03 0.62 0.90 1.0 1.2

04 0.65 1.2 1.0 1.2

05 0.68 0.80 0.85 0.85

06 0.60 0.80 0.65 1.0

07 0.57 o. 70 0. 72* 0.90

08 0.69 1.3 0.82 1.1

09 0.80 0.82 0.75 1.8

10 0.63 0.75 1. 6 1.6

11 0.72 0.75 0.60 1.3

12 0.46 0.88 0.85 o.78

13 0.58 0.62 0.70 0.83

14 0.57 0.80 1. 2 1.0

15 0.66 0.70 1.1 0.95

16 0.62 0.50 0.78 0.83

* July 7

26 TABLE I-A-13 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN AMMONIA-NITROGENDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 0.03 o.oo 0.07 0.17 02 o.oo o.oo 0.01 0.08

03 0,01 0.00 0.09 0.10

04 0.00 o.oo 0.03 0.01

05 0,00 0.06 0.01 0,02

06 0.01 0.00 0.03 0.04

07 0.00 0.00 0.05* 0.02

08 0,00 0.00 0.03 0.04

09 0.01 0.15 0.01 0.04

10 o.oo 0.00 0.13 0.08

11 0.01 o.oo o. 03 0.07

12 0.00 0.00 0.04 0.02

13 0.01 0.13 0.03 0.09

14 0.00 0.00 0.01 o. 08 15 0.00 o.oo 0.00 0.09

16 0.00 0.00 0.01 0.03

* July 7

27 TABLEI-A-14 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN NITRATE-NITROGENDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 0.5 0.00 0.1 0,5

02 0.5 0.00 0.1 0.2

03 0.3 0.00 0.2 0.2

04 0.3 0.1 0.2 0.1

05 0.5 0.1 0.3 0.2

06 0.3 0.1 0.3 o. 1

07 0.2 0.0 0.2* o.o

08 0.2 0,0 0.1 0.1

09 0.5 0.0 o.o 0.2

10 0.3 0.0 0.1 0.1

11 0.2 0.0 o.o 0.1

12 0.1 0.3 0.3 0.3

13 0.3 0.1 0.2 0.2 14 0.1 o.o 0.0 0.2 15 0.3 o.o o.o 0.0

16 0.3 0.0 0.0 0.1

* July 7

28 TABLEI-A-15 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN TOTALPHOSPHORUS DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 0.11 0.07 0.05 0.22

02 0.12 0.04 0.08 0.14

03 0.07 0.06 0.07 0.10

04 0.16 0.08 0.08 0.09

05 0.12 0.05 0.09 0.07

06 0.11 0.04 0.07 0.10

07 0.09 0.04 0.08* 0.08

08 0.10 0.07 0.07 0.07

09 o. 19 0.04 o. 06 0.11 10 o. 08 0.05 0.13 0.14

11 0.10 0.05 0.04 0.06

12 0.10 0.47 o. 04 0.03

13 0.08 o. 04 0.04 0. 05

14 0.09 0.05 0.06 0.10

15 0.12 0.06 0.07 0.14

16 0.12 0.03 0.05 0.06

* July 7

29 TABLE I-A-16

DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN TOTALCOLIFORM DATA (per 100 ml)

STATION MARCH 21 MAY2 JULY 5 SEPTEMBER6

01 100 440 8,000 2,200

02 220 500 700 3,800

03 120 1,000 140 600

04 340 350 300 200

05 80 280 60 100

06 10 400 120 200

07 20 480 220 100

08 100 400 1,500 500

09 120 1,000 1,900 9,000

10 20 2,000 100 6,200

11 80 800 200 500

12 140 380 1,240 2,300

13 20 280 150 400

14 10 300 350 600

15 20 600 2,000 900

16 40 200 800 300

30 TABLEI-A-17 PWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN FECALCOLIFORM DATA (per 100 ml)

STATION MARCH 21 MAY2 JULY 5 SEPTEMBER 6

01 10 40 20 200

02 <10 <5 80 20

03 <5 60 20 220

04 <5 30 60 <20

05 <5 30 10 40

06 <5 10 70 20

07 <5 10 50 20

08 <5 10 150 <20

09 <5 140 10 40

10 <5 80 10 360

11 30 40 <5 60

12 30 30 200 280

13 5 40 40 20

14 <5 15 90 140

15 <5 10 60 80

16 <5 5 20 60

31 TABLEI-A-18 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN CADMIUMDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 0.00 0.00 0.00 0.00

02 0.00 o.oo 0.00 0.00 03 0.00 o.oo 0.00 o.oo

04 0.00 0.00 0.00 0.00

05 0.00 0.00 0.00 0.00

06 0.00 0.00 0.00 0.00

07 0.00 0.00 o.oo 0.00

08 0.00 0.00 0.00 0.00

09 0.00 0.00 0.00 0.00

10 0.00 0.00 0.00 0.00

11 0.00 0.00 0.00 0.00

12 0.00 0.00 0.00 0.00

13 0.00 0.00 0.00 o.oo

14 0.00 0.00 0.00 0.00

15 0.00 0.00 o.oo 0.00

16 o.oo 0.00 0.00 0.00

32 TABLEI-A-19 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN IRON DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 0.25 0.45 1.0 2.2

02 0.25 0.49 1.0 9.0

03 0.27 0.48 1. 7 1. 2

04 0.25 0.50 1.8 0.75

05 o. 20 0.40 1. 2 0.25

06 0.17 0.44 1.2 0.45

07 0.15 0.30 1.3 0.30

08 0.15 0.30 1.4 1.3

09 0.37 0.80 1.8 2.7

10 0.27 0.30 2.4 1.5

11 0.15 0.30 1.0 0.50

12 0.19 0.48 0.93 0.35

13 0.07 0.20 1.3 0.17

14 0.44 0.33 3.6 1.5

15 0.25 0.25 2.5 0.65

16 0.32 0.25 4.2 0.30

33 TABLE I-A-20 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN LEAD DATA (mg/1)

STATION MARCH21 MAY 2 JULY 5 SEPTEMBER6

01 0.00 0.00 0.00 0.00

02 0.00 0.00 0.00 0.00

03 0.00 0.00 0.00 0.00

04 0.00 0.00 0.00 0.00

05 0.00 o.oo 0.00 o.oo

06 0.00 0.00 0.00 o.oo

07 0.00 0.00 0.00 0.00

09 0.00 o.oo 0.00 0.00

10 0.00 0.00 0.00 0.00

11 0.00 0.00 0.00 0.00

12 0.00 0.00 0.00 0.00

13 0.00 0.00 0.00 0.00

14 0.00 0.00 0.00 0.00

15 0.00 0.00 0.00 0.00

16 0.00 0.00 0.00 0.00

34 TABLEI-A-21 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN MANGANESEDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 0.05 0.08 0.25 1.6

02 0.06 0.05 0.10 1.0

03 0.04 o. 03 o.22 0.25

04 0.05 0.05 0.18 0.10

05 0.02 0.05 0.07 0.06

06 0.01 0. 04 0.10 0.10

07 0.01 0.02 0.10 0.07

08 0.02 0.02 0.20 0.10

09 0.09 0.04 0.15 0.50

10 0.04 0. 03 0.33 0.17

11 0.02 o. 04 0.22 0.30

12 0.03 0.04 0.05 0.04

13 0.02 0.02 0.18 0.00

14 0.05 0.04 0.60 0.25

15 0.02 0.02 0.45 0.60

16 0.09 0.03 2.3 0.00

35 TABLEI-A-22 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER BASIN ZINC DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

01 0.06 0.03 o.oo 0.07

02 0.20 0.04 0.00 0.04

03 0.05 0.04 0.00 0.00

04 0.04 0.05 o.oo o. 00

05 0.03 0.06 0.00 0.00

06 0.04 0.06 0.00 0.00

07 0.02 0.06 0.00 0.00

08 0.02 0.02 0.00 0.00

09 0.05 0. 02 o.oo 0.00

10 0.02 0.02 0.00 0.00

11 0.02 0.02 0.00 0.00

12 0.02 0.04 o.oo 0.00

13 0.01 0.02 0.00 0.00

14 0.01 0.02 0.00 o. 00

15 0. 02 0.00 0.00 0.00

16 0.01 0.00 0.00 0.00

36 TABLE I-B-1

DWPC- MAPC208 MONITORINGPROGRAM

ABER.JONARIVER BASIN

LOCATIONOF MONITORINGSTATIONS

STATION STREAM LOCATION MUNICIPALITY

17 Aberjona River Salem Street Woburn

18 Aberjona River Washington Street Winchester

19 Aberjona River USGS Gage Winchester

20 Horn Pond Brook Route 38 Winchester

21 Sweetwater Brook Maple Street Woburn

22 Hall's Brook New Boston Road Woburn

37 LOCATIONOF MONITORINGSTATIONS

ABERJONA:_

/ BASIN / (

Surfing/on BK. \ ' \ \__ 0 2 3 MILES

Lexington

___/ '

, ~( I ~omL>ridge

Watertown'--~--✓

Boston

FIGURE B 38 TABLEI-B-2 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN TIME - TEllPERATURE- DISSOLVEDOXYGEN

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 17 * 1415 1350 1315 1330 ** 46 61 81 73 *** 9.7 7.6 10.4 4.2 18 1435 1400 1330 1345 45 58 75 70 10.4 9.9 5.2 4.9

19 1500 1415 1345 1400 42 59 75 67 11. 5 8.9 6. 1 7.5

20 1445 1405 1340 1355 42 59 79 73 11. 7 11. 0 8.9 4.4

21 1430 1425 1320 1335 46 57 73 69 11. 0 11. 7 2.4 1.3

22 1400 1335 1300 1315 47 60 77 66 7.7 8.0 4.0 5.3

* Time 0 ** Temperature ( F) *** Dissolved Oxygen (mg/1)

39 TABLE I-B-3 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN CHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 55 52 61 50

18 66 58 51 45

19 25 47 67 55

20 45 58 56 45

21 86 58 82 75

22 60 37 41 40

40 TABLEI-B-4 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN 5-DAY BIOCHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 7.8 9.0 3.0 1. 2

18 10.0 8.7 2.7 3.3

19 6.0 8.7 3.0 0.0

20 1.8 6.0 2.4 1.2

21 4.2 3.6 40 38

22 1.8 2.4 1.5 1.8

41 TABLEI-B-5 DWPC- MAPC208 MONITORINGPROGRAM ABER.JONARIVER BASIN pH DATA (Standard Urtits)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 7.2 7.4 7.4 7.3

18 8.8 7.6 7.3 7.4

19 7.3 7.5 7.2 7.4

20 7.2 7.8 8.4 7.3

21 7.1 8.0 7.1 7.3

22 6.8 7.2 6.8 7.5

42 TABLEI-B-6 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN TOTALALKALINITY DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 45 54 64 57

18 57 50 51 44

19 38 44 48 63

20 34 32 43 38

21 27 42 66 74

22 28 39 62 51

43 TABLEI-B-7 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN HARDNESSDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 95 96 124 137

18 95 102 111 141

19 88 95 118 175

20 70 68 73 60

21 76 105 83 76

22 71 72 77 61

44 TABLEI-B-8 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN TURBIDITYDATA (NTU)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 3.5 4. 1 4.2 2.2

18 6.2 3.5 2.8 3.6

19 3.1 3.3 2.3 1.0

20 1. 9 3.8 1.6 3.2

21 17 3.5 11 5.6

22 1.2 1.8 17 3.2

45 TABLEI-B-9 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN SUSPENDEDSOLIDS DATA(mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 1.0 o.o 1.0 3.5

18 10.0 0.0 2.0 9.0

19 5.0 0.0 4.0 3.5

20 4.0 2.0 0.5 5.5

21 35.0 0.0 38 15

22 3.0 0.0 6.0 14

46 TABLEI-B-10 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN DISSOLVEDSOLIDS DATA(mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 291 306 353 480

18 332 322 350 401

19 289 306 388 598

20 208 238 259 260

21 359 350 282 283

22 267 202 212 220

47 TABLEI-B-11 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN TOTALSOLIDS DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 292 306 354 484

18 342 322 352 410

19 294 306 392 602

20 212 240 260 266

21 394 350 320 298

22 270 202 218 234

48 TABLEl-B-12 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN TOTALKJELDAHL-NITROGEN DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 8.5 9.0 5.3 7.9

18 4.3 7.0 2.0 3.4

19 3.1 4.1 1.4 1.2

20 o. 92 0.70 0.82 1.4

21 1.7 1.0 6.8 6.0

22 0.93 0.75 1.1 0.95

49 TABLEI-B-13 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN AMMONIA-NITROGENDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 8,0 8.6 4.9 6.8

18 4.0 6.5 1.7 3.1

19 2.4 3.5 0.48 0.10

20 0.09 0.02 0.15 0.18

21 0.05 o. 12 2.2 5.9

22 0.09 0.00 0.24 o. 07

50 TABLEI-B-14 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN NITRATE-NITROGENDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 1. 6 5.0 3.5 4.8

18 2.2 4.3 2.8 4.8

19 1.4 3.7 2.4 1.4

20 0.6 1.0 0.1 0.1

21 1.7 2.7 1.0 0.0

22 1.0 0.2 0.3 0.4

51 TABLEI-B-15 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN TOTAI PHOSPHORUSDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 0.08 0.04 o. 02 0.05

18 0.10 0.06 0.06 0.09

19 0.10 0.07 o. 04 0.05 20 0.24 0.08 o. 03 0.09 21 0.48 o.21 1.8 2.0

22 0.08 0.07 0.11 0.12

52 TABLEI-B-16 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN TOTALCOLIFORM DATA (per 100 ml)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 100 820 500 1,400

18 2,000 3,000 21,000 6,800

19 680 1,600 2,000 1,800

20 300 1,500 1,000 700

21 36,000 42,000 200,000 4,500,000

22 220 900 1,400 1,100

53 TABLE I-B-17 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN FECAL COLIFORMDATA (per 100 ml)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 10 30 240 40

18 60 400 1,200 145

19 10 300 240 140

20 60 100 90 20

21 4,300 7,200 25,000 700,000

22 <5 5 130 180

54 TABLEI-B-18 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN CADMIUMDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 0.00 0.00 0.00 0.00

18 0.00 0.00 0.00 0.00

19 0.00 0.00 0.00 0.00

20 0.00 0.00 o.oo 0.00

21 0.00 0.00 0.00 0.00

22 0.00 0.00 0.00 0.00

55 TABLEI-B-19 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN IRON DATA (mg/1)

STATION MARCH21 MAY 2 JULY 5 SEPTEMBER6

17 1.1 0.60 0.80 0.65

18 1.2 0.53 0.55 0.25

19 0.70 0.57 0.70 0.25

20 0.30 0. 20 0.50 0.65

21 1.2 0.45 1.0 0.60

22 0.42 0.30 3. 1 2.1

56 TABLEI-B-20 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN LEADDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 0.00 0.00 0.00 0.00

18 0.03 0.00 0.00 0.00

19 0.00 0.00 0.00 0.00

20 0.00 0.00 0.00 0.00

21 0.12 0.00 0.00 0.00

22 0.00 0.00 0.00 0.00

57 TABLEI-B-21 DWPC- MAPC208 MONITORINGPROGRAM ABERJONARIVER BASIN MANGANESEDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 0.20 0.03 0.05 o.22

18 0.18 0.07 0.15 0.16

19 0.16 0.10 0.15 0.08

20 0.12 0.05 0.05 0.23

21 0.15 0.11 0.07 0.14

22 0.08 0.04 0.40 0.35

58 TABLEI-B-22 DWPC- MAPC208 MONITORINGPROGRAM ABER.JONARIVER BASIN ZINC DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

17 0.24 0.12 0. 05 0.05

18 0.18 0.12 o. 03 0.01

19 0.13 0.10 0.00 0.00

20 0.03 0.02 0.00 0.00

21 0.13 0.03 0.00 0.00

22 0.05 0.04 0.00 0.00

59 TABLE I-C-1 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN LOCATIONOF MONITORINGSTATIONS

NUMBER STREAM LOCATION MUNICIPALITY

23 Neponset River Summer Street Dam Walpole

24 Neponset River Hollingsworth & Vose Dam East Wapole

24A Neponset River Neponset Street Canton

25 Neponset River - Neponset Street Canton East Branch

26 Neponset River Truman Highway Bridge Milton

27 Neponset River Adams Street Bridge Milton-Boston

28 Neponset River Main Street - Rte. lA Walpole

29 School Meadow Brook Washington Street Walpole

30 Hawes Brook Washington Street Norwood

31 Traphole Brook Summer Street Walpole

32 Massapoag Brook Bolivar Street Canton

33 Purgatory Brook Rte. 1 Norwood

33A Plantingfield Brook Rte. 1 Norwood

34 Ponkapoag Brook Elm Street Canton

35 Pine Tree Brook Eliot Street Milton

60 LOCATIONOF MONITORINGSTATIONS

NEPONSETRIVER BASIN

BOSTON

_ QUI

Mother --unfquity Brook -...... -- Pine Tree ~ok \ MILTON )

- Neponset River,

,,,,-- j------Ponkopog Pond RANDOLPH

CANTON ' MED East ' ' Bronc '--.... .

Res:s7-·Pond

~ phole Br. -· ----- ""' l Lr, North \ Bk. \ J 0 ----2 3 4 5 MILES Neponset Reservoir FOXBOROUGH"'--' FIGURE C 61 TABLEI-C-2 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN TIME - TEMPERATURE- DISSOLVEDOXYGEN

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 23 * 0918 0930 0950 1005 ** 39 53 72 73 *** 11.1 8.9 4.8 6.6 24 1035 1050 1055 1125 40 60 78 76 11.8 9.5 6.6 9.0

24A 1120 1140 1150 1215 40 57 76 64 10.8 9.3 6.4 8.3

25 Above 1107 1130 1140 1205 40 59 76 75 12.0 9.3 5.9 6.1

25 Below 1107 1130 1140 1205 40 59 76 75 12.5 9.8 7.6 7.8

26 1235 1230 1250 1315 40 60 75 73 9.7 8.3 7.5 8.6

27 1300 1300 1312 1340 41 62 76 72 11. 6 10.7 7.8 7.6

28 0945 1000 1017 1025 39 57 70 68 11.0 9.4 7.5 7.7

29 0925 0945 1000 1010 37 56 66 66 8.3 5.5 3.7 6.7

30 1000 1030 1031 1100 40 58 76 62 12.1 10.2 8.4 9.0

Time * 0 ** Temperature ( F) *** Dissolved Oxygen (mg/1)

62 TABLEI-C-2 (CONTINUED)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

31 1020 llOO 1103 ll30 38 60 62 64 12.3 11.0 9.1 9.5

32 1050 lll5 1118 ll45 40 58 72 68 11.8 10.0 7.2 8.0

33 ll50 1157 1207 1235 41 59 72 70 11.8 11. 1 9.9 11. 8

33A ll40 ll50 1200 1225 40 57 70 64 10.5 11.4 7.8 5.4

34 1205 1210 1230 1255 38 56 68 63 9.9 9.4 6. 1 6.2

35 1250 1250 1305 1330 40 62 70 68 10.9 10.3 8.6 8.6

63 TABLEI-C-3

DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN CHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 37 61 52

24 43 48 31 42

24A 21 37 41 31

25 32 48 15 26

26 21 43 46 36

27 21 32 46 36

28 32 43 20 31

29 21 32 20 21

30 38 37 36 21

31 32 37 41 31

32 32 16 31 16

33 38 54 72 99

33A 32 21 56 31

34 32 27 41 26

35 43 16 21 36

64 TABLEI-C-4 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN 5-DAY BIOCHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 3.6 5.1 3.9

24 3.6 3.6 2.7 2.4

24A 2.7 2.7 3.6 2. 1

25 2.1 6.9 3.0 2.7

26 2.1 3.9 3.0 2.4

27 2.4 3.0 3.3 3.9

28 2.1 3.3 3.6 2.1

29 3.0 4.2 2.4 0.6

30 2.1 3.6 3.3 2.1

31 1.8 2.7 2.7 0.3

32 2.4 3.3 2.4 1.5

33 2.1 3.3 3.0 0.6

33A 2.1 2.7 2.4 3.3

34 2.1 3.0 2.4 0.9

35 2.4 4.2 2.4 2.1

65 TABLEI-C-5 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN pH DATA (Standard Units)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 7.0 6.9 7.1

24 6.7 7.0 7.2 7.6

24A 6.7 6.9 7.1 7.3

25 6.7 6.6 7.1 7.1

26 6.6 6.6 7.1 7.3

27 6.7 7.2 7.2 7.5

28 6.5 6.9 7.1 7.3

29 6.2 6.4 6.9 7.8

30 7.0 7.2 7.2 7. 4

31 6.9 7.2 7.1 7.3

32 6.6 7.2 7.3 7.3

33 6.6 7. 3 7.2 7.6

33A 7.3 7.1 7.1 7.6

34 6.6 6.8 6.9 7.2

35 6.5 6.9 7.1 7.5

66 TABLEI-C-6 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN TOTALALKALINITY DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 25 25 30

24 10 15 20 28

24A 15 18 25 30

25 15 15 24 30

26 14 16 25 30

27 15 18 27 33

28 10 15 21 32

29 8.0 12 17 19

30 19 17 21 24

31 17 19 15 20

32 12 16 20 24

33 19 22 29 44

33A 22 24 33 57

34 9.0 17 18 21

35 10 15 21 28

67 TABLEI-C-7 DPWC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN HARDNESSDATA (mg/1)

STATION MARCH22 MAY 3 JULY 6 SEPTEMBER7

23 46 52 44

24 26 30 47 52

24A 35 49 48

25 31 35 44 48

26 33 41 50 55

27 32 40 55 65

28 25 30 53 55

29 31 27 41 37

30 35 43 45 37

31 55 67 73

32 27 30 43 39

33 46 15 95 125

33A 61 47 63 77

34 33 41 41 49

35 31 34 50 52

68 TABLEI-C-8 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN TURBIDITYDATA (NTU)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 4.5 6.7 13

24 1.5 1.6 3.5 2.7

24A 1.0 1.8 2.8 3.4

25 0.8 2.1 2.4 2.9

26 0.9 2.1 3.3 2.6

27 1.1 1.9 2.9 4.1

28 1.3 2.4 6.0 3.1

29 0.4 0.8 6.1 7.6

30 0.5 1.0 1.7 1. 4

31 0.7 0.5 1.3 0.9

32 0.5 1.1 1. 6 1.3

33 0.4 0.5 2.0 2.1

33A 0.5 0.5 6.1 7.7

34 0.4 0.6 2.0 1.1

35 0.4 0.8 1.3 1. 2

69 TABLEI-C-9 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN SUSPENDEDSOLIDS DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 2.0 8.0 12

24 1.0 3.0 3.5 4.5

24A 1.0 4.0 2.0 3.5

25 2.0 4.0 3.0 4.0

26 3.0 3.0 3.0 5.0

27 4.0 6.0 9.0 13

28 1.0 4.0 9.5 4.0

29 1.0 o.o 5.0 2.0

30 1.0 0.0 3.0 2.0

31 1.0 o.o 5.0 2.5

32 1.0 0.0 2.5 2.5

33 1.0 0.0 0.5 5.0

33A 1.0 0.0 30 8.5

34 1.0 0.0 3.0 2.0

35 1.0 2.0 2.0 2.5

70 TABLEI-C-10 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN DISSOLVEDSOLIDS DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 178 220 154

24 113 103 168 161

24A 119 92 146 130

25 104 100 125 128

26 121 119 171 175

27 112 126 183 197

28 103 110 206 182

29 61 72 145 136

30 113 114 145 124

31 143 168 263 281

32 79 78 103 267

33 137 342 543 791

33A 279 162 220 225

34 127 98 151 228

35 101 132 148 145

71 TABLEI-C-11 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN TOTALSOLIDS DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 180 228 166

24 114 106 172 166

24A 120 96 148 134

25 106 104 128 132

26 124 122 174 180

27 116 132 192 210

28 104 114 216 186

29 62 72 150 138

30 114 114 148 126

31 144 168 268 284

32 80 78 106 270

33 138 342 544 796

33A 280 162 250 234

34 128 98 154 230

35 102 134 150 148

72 TABLEI-C-12 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN TOTALKJELDAHL-NITROGEN (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 1.0 1.2 1.5

24 0.87 0.73 0.95 1.0

24A 1.0 0.80 0.50 0.80

25 1.1 1.0 0.63 0.88

26 0.93 0.75 0.58 o. 95

27 o. 79 0. 70 0.70 1.2

28 0.86 0.75 0.72 0.88

29 0.95 0.85 0.55 0.95

30 0.80 0.68 0.58 0.90

31 0.55 0.62 0.55 0.42

32 0.79 0.60 0.70 0.75

33 1.1 0.58 1.0 1.2

33A 0.78 0.65 0.55 1.2

34 0.98 0.88 0.65 0.58

35 0.76 o. 72 0.52 0.70

73 TABLEl -C-13 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN AMMONIA-NITROGENDATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 0.11 0.14 0.04

24 0.00 0.11 0.04 0.01

24A 0.00 0.03 0.06 0.04

25 0.01 0.10 0.00 0.04

26 0.00 0.04 0,00 0.01

27 0.00 0.02 o.oo 0.09

28 0.00 0.00 0,06 0.05

29 0.04 0.00 0.06 0.02

30 0.04 0.01 0.00 0.01

31 0.00 0.00 0.02 0.10

32 0.00 0.00 0.05 0.04

33 0.07 0.00 0.01 0.08

33A 0.00 0.01 0.07 0.26

34 0.00 0.01 0.03 0.03

35 0.00 0.00 0.01 0.03

74 TABLEI-C-14 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN NITRATE-NITROGENDATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 0.8 0.4 0.3

24 0.3 0.3 0.2 o.o

24A 0.6 0.5 0.2 0.3

25 0.7 2.0 0.1 0.3

26 0.5 0.8 0.2 0.2

27 0.5 0.4 0.2 0.2

28 0.4 0.2 0.2 0.3

29 0.2 0.1 0.0 0.1

30 0.6 0.7 0.2 0.1

31 0.5 0.9 0.8 0.8

32 0.7 0.5 0.3 0.2

33 0.6 1.5 1.5 1.3

33A 1.0 0.8 1.0 0.9

34 0.7 0.9 0.5 1.5

35 0.3 0.3 0.3 0.5

75 TABLEl-C-15 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN TOTALPHOSPHORUS DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 0.06 0.10 0.13

24 0.13 0.05 0.05 0.05

24A 0.09 0.05 0.06 0.06

25 0.10 0.05 0.05 o. 04

26 0.08 0.05 0.05 0.05

27 0.08 0.30 0.08 0.11

28 0.13 0.07 0.06 0.09

29 0.09 0.04 0.04 0.05

30 0.08 0.04 0.04 0. 04

31 0.10 0.04 0.04 o. 04

32 0.08 0.04 0.03 0.06

33 0.10 o. 04 0.04 0.05

33A 0.10 0.04 0.08 0.12

34 0.12 0.05 0.06 0.04

35 0.07 0.04 0.04 0.11

76 TABLEI-C-16 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN TOTALCOLIFORll DATA (per 100 ml)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 150 1,300 7,200 10,000

24 200 400 120 100

24A 500 850 6,000 1,300

25 1,200 6,000 18,000 2,600

26 300 1,100 300 800

27 2,800 4,400 120,000 4,300

28 60 360 11,000 1,200

29 60 140 230 200

30 180 180 1,600 3,400

31 480 170 560 1,800

32 1,000 230 10,000 1,600

33 560 8,000 74,000 1,600

33A 360 12,000 13,000

34 320 60 480 300

35 220 1,200 63,000 120,000

77 TABLEI-C-17 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN FECAL COLIFORMDATA (per 100 ml)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 80 150 380 900

24 30 15 30 <50

24A 90 60 700 180

25 10 400 600 1,000

26 40 60 40 80

27 200 200 4,400 760

28 10 10 5,000 100

29 < 5 20 60 40

30 10 35 400 280

31 20 20 250 360

32 <10 15 900 120

33 20 80 1,400 160

33A 70 560 800

34 <5 5 60 <5

35 10 70 4,300 8,000

78 TABLEI-C-18 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN CADMIUMDATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 0.00 0.00 o.oo 0.00 24 0.00 0.00 o.oo 0.00

24A o.oo 0.00 0.00 0.00 25 0.00 0.00 o.oo 0.00 26 o.oo o.oo o.oo 0.00

27 0.00 0.00 0.00 0.00

28 o.oo 0.00 0.00 0.00

29 0.00 0.00 0.00 0.00

30 o.oo 0.00 o.oo 0.00 31 o.oo 0.00 0.00 0.00

32 0.00 0.00 0.00 0.00

33 0.00 0.00 o.oo 0.00

33A o.oo 0.00 0.00 0.00 34 o.oo 0.00 0.00 0.00 35 0.00 0.00 o.oo 0.00

79 TABLEI-C-19 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN IRON DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 1.2 1.4 2.3 2.2

24 0.40 0.65 1.3 0.30

24A 0.40 0.70 1.1 1.0

25 0.50 0.67 0.90 1.1

26 0.46 1.0 1.8 0.65

27 0.40 0.89 1.0 0.85

28 0.40 0.70 1.4 0.85

29 0.20 0.30 1.2 1.0

30 0.30 0.45 0.85 o. 40

31 0.25 0.33 0.50 0.25

32 0.20 0.40 o. 77 0.50

33 0.39 0.50 0. 75 0.66

33A 30.0 0.35 5.0 2.4

34 0.25 0.31 0.82 o. 20

35 0.30 0.47 0.45 0.35

80 TABLEI-C-20 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN LEADDATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 0.00 0.00 o.oo 0.00

24 0.00 0.00 0.00 o.oo

24A 0.00 0.00 0.00 o.oo

25 0.00 0.00 0.00 o.oo

26 0.00 0.00 0.00 0.00

27 0.00 0.00 o.oo 0.00

28 0.00 0.00 o.oo 0.00

29 0.00 0.00 0.00 o.oo

30 0.00 o.oo o.oo o.oo

31 0.00 0.00 0.00 0.00

32 0.00 0.00 0.00 o.oo

33 0.00 0.00 0.00 0.00

33A 0.09 0.00 0.00 0.00

34 0.00 0.00 0.00 0.00

35 0.00 0.00 0.00 0,00

81 TABLEl-C-21 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER BASIN MANGANESEDATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 0.55 0.52 0.55 0.45

24 0.09 0.11 0.25 0.12

24A 0.10 0.15 0.13 0.10

25 0.10 0.16 0.22 0.20

26 0.08 0.19 0.30 0.11

27 0.10 0.18 0.20 0.35

28 0.25 0.16 0.35 0.22

29 0.02 0.07 0.40 0.12

30 0.12 0.21 0.13 0.05

31 0.08 0.09 0.07 0.05

32 0.79 0.08 0.11 0.10

33 0.16 0.14 0.22 0.23

33A 5.0 0.14 0.50 0.70

34 0.05 0.09 0.30 0.09

35 0.07 0.10 0.07 0.05

82 TABLE I-C-22 DWPC- Mt\PC 208 MONITORINGPROGRAM NEPONSETRIVER BASIN ZINC DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

23 o. 03 0.03 0. 03 0.03

24 0.02 0.02 0.03 0.06

24A 0.02 0.02 o.oo 0.12

25 0.00 0.02 0.00 0.02

26 0.00 0.02 0.10 0.00

27 0.02 0.03 0.03 0.10

28 0.00 0.02 0.00 0.01

29 0.00 0.02 0.00 0.06

30 0.00 0.01 0.00 o.oo

31 0.03 0.01 o. 04 o. 05

32 0.00 0.02 0.01 0.02

33 0.02 0.02 0.01 0.02

33A o. 20 0.01 0.03 0.02

34 0.02 0.04 0.00 0.05

35 0.00 0.02 0.00 0.08

83 TABLE I-D-1 DWPC- MAPC208 MONITORINGPROGRAM NORTHAND SOUTHRIVER BASIN LOCATIONOF MONITORINGSTATIONS

NUMBER STREAM LOCATION MUNICIPALITY

36 Drinkwater River Route 139 Hanover

37 French Stream Center Avenue Rockland

38 Drinkwater River Inlet Forge Pond Hanover

39 Center Street Hanover-Hanson

40 Indian Head River Curtis Crossing Dam Hanover-Pembroke

41 South River Main Street Marshfield

42 Third Herring Brook River Street Hanover-Norwell

43 Second Herring Brook Route 123 Norwell

44 First Herring Brook Route 123 Scituate

45 Torrey Brook Off Winter Street Hanover

46 Iron Mine Brook Riverside Drive Hanover

47 Indian Head Brook Washington Street Hanson

48 Furnace Brook Parsons Road Marshfield

49 Littles Creek Summer Street Marshfield

50 H. Eames Brook Damon Point Road Marshfield

84 LOCATIONOF MONITORINGSTATIONS

NORTH8 SOUTH RIVER BASINS

North 1 scale

Norwel I

Udcof Crt.

itdcof 8t.

Hanover Iron Mine Bk.

Puddint1 Bk. ;- , I Hm1n, 7 Pembroke ,I

Hanson

FIGURE D 85 TABLEI-D-2 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN TIME - TEMPERATURE- DISSOLVEDOXYGEN

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8 36 * 1435 1436 0955 1035 ** 40 62 65 62 *** 10.3 12.4 6.8 6.7 37 1415 1310 0945 No Flow 40 62 68 10.9 14.9 10.0

38 1450 1440 1005 1050 40 62 65 67 10.3 9.5 5.9 2.1

39 1610 1505 1030 1115 40 64 74 70 10.7 8.7 5.0 1. 7

40 Above 1640 1530 1045 1135 40 63 73 70 11. 2 8.3 5.0 5.9

40 Below 1640 1530 1045 1135 40 63 73 70 10.8 17. 2 7.2 7.5

41 1730 1615 1126 1220 40 63 74 69 10.8 9.9 8.0 10.3

42 1705 1550 1100 1200 39 62 70 62 10.8 8.7 6.2 5.0

43 1830 1715 1230 1350 40 60 68 63 10.5 8.8 8.1 8.8

44 Above 1815 1710 1215 1335 40 62 80 72 10.8 10.3 5.6 8.0

Time * 0 ** Temperature ( F) *** Dissolved Oxygen (mg/1)

86 TABLEI-D-2 (CONTINUED)

STATION MARCH 22 MAY3 JULY 7 SEPTEMBER8

44 Below 1815 1710 1215 1335 40 62 80 72 10.9 10.4 6.3 7.7

45 1600 1455 1015 1105 40 62 60 58 9.8 9.3 8.3 8.8

46 1650 1540 1050 1150 40 64 66 62 10.3 10.1 8.1 5.4

47 1630 1520 1035 1125 40 63 66 59 9.7 10.0 6.7 8.7

48 1737 1605 1120 1215 40 65 76 71 10.0 10.3 10.7 6.8

49 1750 1645 1153 1310 41 62 74 70 11. 6 11.2 9.9 9.5

50 1800 1700 1201 1320 40 62 79 70 11.0 10.3 9.3 9.1

87 TABLEI-D-3 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN CHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 21 32 46 20

37 43 43 46 No Flow

38 32 38 61 67

39 38 72 45

40 38 32 66 30

41 38 46 30

42 38 102 25

43 27 61 30

44 38 54 61 35

45 27 32 46 15

46 48 43 41 25

47 32 38 61 20

48 27 11 46 30

49 21 5.4 5.0 5.0

so 32 21 36 2.0

88 TABLEI-D-4 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN 5-DAY BIOCHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH22 HAY 3 JULY 7 SEPTEMBER8

36 1.5 3.0 2.1 o.o

37 2.4 6.6 1.8 No Flow

38 3.0 4.2 2.1 9.3

39 3.9 2.7 1.8

40 1.8 3.9 2.4 1. 2

41 3.6 1.8 0.0

42 3.0 2.4 0.3

43 3.3 1.8 0.3

44 2.7 4.5 2.7 2.4

45 3.0 3.0 1.5 0.6

46 2.1 3.9 1.8 0.6

47 2.7 3.3 1.8 0.3

48 2.1 3.0 3.3 1.8

49 1.8 3,3 1.8 1.5

50 2.1 3.0 1.2 0.6

89 TABLEI-D-5 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN pH DATA (Standard Units)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 5.9 5.5 6.7 7.2

37 6.6 8.3 6.8 No Flow

38 6.3 6.7 6.6 7.8

39 6.9 6.7 7.4

40 6.5 6.8 6.6 7.3

41 6.4 6.8 7.0

42 6.3 6.4 7.2

43 5.2 6.3

44 6.2 6.6 6.5 6.9

45 6.3 6.7 6.6 6.9

46 6.2 7. 1 7.0 7.4

47 6.4 5.9 6.6 7.2

48 6.1 7.0 6.9 7.2

49 6.4 7.1 7.0 7 ..1

50 6.6 6.7 7.2 7.2

90 TABLEI-D-6 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN TOTALALKALINITY DATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 5.0 4.0 13 27

37 18 20 14 No Flow

38 9.0 1.3 13 110

39 14 16 28

40 9.0 11 9.0 21

41 5.0 8.0 9.0

42 5.0 10 19

43 3.0 4.0 8.0

44 7.0 7.0 10 9.0

45 8.0 10 12 14

46 9.0 14 22 32

47 9.0 5.0 8.0 14

48 5.0 15 16 20

49 10 11 12 13

50 10 6.0 10 16

91 TABLEI-D-7 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN HARDNESSDATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 12 24 35 46

37 38 32 50 No Flow

38 25 28 34 57

39 30 35 40

40 26 28 30 36

41 17 23 21

42 23 32 43

43 19 27 28

44 23 25 30 30

45 25 28 37 42

46 33 39 54 66

47 58 22 25 40

48 24 30 38 42

49 16 16 17 19

so 22 20 27 30

92 TABLEl-D--8 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN TURBIDITYDATA (NTU)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 0.3 0.8 3.0 1.9

37 2.8 6.2 5.2 No Flow

38 0.8 2.4 3.6 4.0

39 1.8 2.9 2.7

40 1.0 1.3 2.4 4.2

41 0.6 1.8 1.7

42 0.6 3.6 5.8

43 0.2 2.0 0.7

44 1.2 1.4 6.3 3.8

45 4.2 1.4 3.6 2.7

46 1.7 1.2 3.2 2.2

47 1.8 1.0 2.8 1.9

48 0.5 0.5 1.1 1.0

49 0.6 0.6 1. 6 1.3

50 0.8 0.7 0.6 1.3

93 TABLE I-D-9 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN SUSPENDEDSOLIDS DATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 1.0 2.0 2.5 2.0

37 5.0 5.0 5.0 No Flow

38 1.0 6.0 2.0 5.0

39 1.0 5.5 3.0

40 3.0 1.0 2.0 3.0

41 0.0 2.0 2.0

42 2.0 12 4.0

43 0.0 5.5 0.0

44 4.0 5.0 4.5 5.0

45 13 0.0 2.0 3.5

46 s.o 0.0 12 1.5 47 s.o 7.0 4.5 1.0

48 1.0 2.0 0.5 3.0

49 1.0 0.0 1.5 2.5

so 1.0 0.0 0.5 2.0

94 TABLEI-D-10 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN DISSOLVEDSOLIDS DATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 99 124 161 138

37 137 119 195 No Flow

38 115 132 182 287

39 119 178 153

40 121 139 160 147

41 70 116 84

42 140 254 340

43 116 196 130

44 102 133 175 141

45 123 136 166 146

46 141 172 256 216

47 105 105 159 143

48 95 120 191 71

49 63 52 82 59

50 123 108 141 118

95 TABLE I-D-11 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN TOTALSOLIDS DATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 100 126 164 140

37 142 124 200 No Flow

38 116 138 184 292

39 120 184 156

40 124 140 162 150

41 70 118 86

42 142 266 344

43 116 202 130

44 106 138 180 146

45 136 136 168 150

46 146 172 268 218

47 110 112 164 144

48 96 122 192 74

49 64 52 84 62

50 124 108 142 120

96 TABLEI-D-12 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN TOTALKJELDAHL-NITROGEN DATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 0.90 o. 77 0.58 0.70

37 1.2 1.0 0.40 No Flow

38 1.1 1.5 0.95 18

39 1.4 1. 3 1. 9

40 1.3 1.1 0.80 1.1

41 0.90 0.57 0.77

42 0.80 1.3 1.0

43 0.88 0.78 0.82

44 1.0 1.0 0.90 1. 3

45 1.1 0.82 0.42 0.62

46 1.2 1.1 0. 50 0.65

47 1.1 0.78 0.80 0.55

48 0.82 0.78 0.65 o. 70

49 0.72 0.45 0.40 0.68

50 0.83 0.52 0.32 1.0

97 TABLEI-D-13 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN AMMONIA-NITROGENDATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 0.00 0.00 o.oo 0,00

37 0.22 0.01 0.04 No Flow

38 0.26 o. 49 0.08 17

39 0.43 0.55 0.61

40 0.23 0.23 0.20 0.12

41 0.00 0.05 0.01

42 o.oo 0.08 0.05

43 0.01 0.03 0,01

44 0.00 0.01 0.18 0.01

45 0.12 0.02 0.01 0.05

46 0.03 0.00 0.04 0.01

47 0.00 0.00 0.13 o. 02

48 0.00 0.00 0.02 0.00

49 0.00 0.00 0.02 0.02

50 0.00 0.00 0.01 0.00

9B TABLEI-D-14 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN NITRATE-NITROGENDATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 0.3 0.3 0.2 0.0

37 0.09 0.8 0.8 No Flow

38 0.4 0.4 0.2 0.02 39 0.6 0.4 0.1

40 0.4 0.6 0.5 0.3

41 0.0 o. 1 0.1

42 0.0 0.1 0.5

43 0.2 0.2 0.2

44 0.2 0.3 0.1 0.0

45 0.6 1.0 1.5 1.8

46 0.4 0.4 0.6 0.1

47 0.2 0.2 0.4 1.0

48 0.4 0.3 0.1 o.o

49 0.1 0.0 0.0 0.0

50 0.2 0.1 0.0 0.0

99 TABLEI-D-15 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN TOTALPHOSPHORUS DATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 0.08 0.04 0.06 o. 04

37 0.16 0.20 0.09 No Flow

38 0.17 0.27 0.16 6.8

39 0.28 0.57 0.63

40 0.18 0.19 0.33 o. 41

41 0. 06 0.08 0. 07

42 0.05 0.13 0.06

43 o. 04 0.10 0.13

44 0.11 0.06 0.16 0.12

45 0.21 0.04 0.06 0.06

46 0.11 0.04 0.07 0.04

47 0.10 0.04 0.08 0.04

48 0.52 0.03 0.03 o. 04

49 0.15 0.03 0.06 0.06

50 0.10 0.03 0.03 0.02

100 TABLEl-D-16 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN TOTALCOLIFORM DATA (per 100 ml)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 220 220 390 700

37 32,000 1,200 3,800 No Flow

38 600 400 480 1,000

39 900 100 200 100

40 640 30 1,200 50

41 80 480 1,700 500

42 320 780 1,200 1,300

43 500 120 2,500 200

44 700 80 1,300 350

45 200 80 810 900

46 520 800 480 600

47 340 120 400 1,500

48 360 100 720 400

49 300 90 580 100

50 260 80 240 50

101 TABLEI-D-17 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN FECAL COLIFOR-~DATA (per 100 ml)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 20 60 80 20

37 3,500 800 400 No Flow

38 20 10 120 220

39 160 5 10 40

40 70 10 600 <5

41 <5 20 700 20

42 <5 50 40 280

43 100 25 600 20

44 30 5 580 20

45 80 <5 300 60

46 70 <10 200 10

47 20 30 100 100

48 150 <5 30 <5

49 60 <5 160 <5

50 <5 <5 40 <5

102 TABLEI-D-18 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN CADMIUMDATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 0.00 0.00 0.00 o.oo 37 o.oo 0.00 0.00 0.00

38 0.00 0.00 0.00 0.00

39 0.00 0.00 0.00 0.00

40 0.00 0.00 0.00 0.00

41 0.00 0.00 0.00 0.00

42 0.00 0.00 0.00 o.oo

43 0.00 0.00 0.00 o.oo

44 0.00 0.00 0.00 0.00

45 0.00 0.00 0.00 0.00

46 o.oo 0.00 0.00 o.oo 47 0.00 o.oo 0.00 0.00 48 0.00 0.00 0.00 o.oo

49 0.00 0.00 0.00 0.00

50 0.00 0.00 o.oo o.oo

103 TABLEI-D-19 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN IRON DATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 0.36 0.55 1.6 0.48

37 1.1 1.4 1.0 No Flow

38 0.55 1.3 2.3 1.5

39 0.63 1.3 2.9 1.5

40 0.60 1.1 2.0 1.5

41 0.50 0.68 1.6 0.90

42 0.45 1.0 7.0 1.3

43 o. 40 0.30 2.1 0.25

44 0.60 0.75 3.6 2.3

45 0.90 1.1 1. 2 o. 57

46 0.75 0.81 1.8 0.75

47 0.90 1.0 1.8 0.48

48 0.35 0.50 0.85 0.50

49 0.25 0.20 0.40 0.24

50 0.40 0.40 o. 60 o. 60

104 TABLEI-D-20 DWPC- MAf'C208 MONITORINGPROGRAM NORTHRIVER BASIN LEADDATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 0.00 0.00 o.oo o.oo

37 0.00 0.00 0.00 o.oo 38 0.00 0.00 0.00 o.oo

39 0.00 0.00 0.00 0.00

40 0.00 0.00 0.00 0.00

41 0.00 0.00 0.00 o.oo

42 0.00 o.oo 0.00 o.oo

43 0.00 0.00 0.00 o.oo

44 0.00 0.00 o.00 o.oo

45 0.00 0.00 0.00 0.00

46 0.00 0.00 0.00 0.00

47 0.00 0.00 0.00 0.00

48 0.00 0.00 0.00 o.oo

49 0.00 o.oo o.oo 0.00 so 0.00 0.00 o.oo 0.00

105 TABLEI-D-21 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN MANGANESEDATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 0.13 0. 05 0.05 0.04

37 0.40 0.20 0.48 No Flow

38 0.15 0.15 0.08 0.40 39 0.21 0.18 0.30 0.30

40 0.25 0.18 0.18 0.29

41 0.12 0.04 0.05 0.03

42 0.17 0.09 0.63 0.28

43 0.24 0.05 0.25 0.03

44 0.14 0.07 0.25 0.11

45 0.15 0.12 0.12 0.09

46 0.15 0.10 0.38 0.46

47 0.19 0.12 0.10 0.07

48 0.10 0.08 0.02 0.07

49 0.10 0.01 0.15 0.01

50 0.10 0.02 0.10 0.05

106 TABLEI-D-22 DWPC- MAPC208 MONITORINGPROGRAM NORTHRIVER BASIN ZINC DATA (mg/1)

STATION MARCH22 MAY3 JULY 7 SEPTEMBER8

36 0.00 0.01 0.00 0.01

37 0.14 0.3 0.03 No Flow

38 0.03 0.04 0.00 0.00

39 0.02 0.02 0.00 0.00

40 0.02 0.02 0.00 0.00

41 0.00 0.00 0.00 0.00

42 0.00 0.00 0.00 0.00

43 0.00 o.oo 0.00 0.00

44 0.09 0.02 0.02 0.00

45 0.00 0.01 0.00 0.06

46 0.11 o. 03 0.00 0.00

47 0.00 0.00 0.00 0.00

48 0.00 0.00 0.00 0.00

49 0.00 0.07 0.00 o.oo

50 0.06 0.03 o.oo 0.00

107 TABLE I-E-1 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN LOCATIONOF MONITORINGSTATIONS

NUMBER STREAM LOCATION MUNICIPALITY

51 Charles River Route 126 Bellingham 52 Charles River Walker Street Medway 53 Charles River Forest Road Millis-Medfield 54 Charles River South Natick Dam Natick 55 Charles River Charles River Village Dover Dam 56 Charles River Ames Street Dedham 57 Charles River Elliot Street Newton 58 Charles River Walnut Street Wellesley 59 Charles River Moody Street Waltham 60 Hopping Brook Route 126, Bellingham Hartford Avenue 61 Mine Brook Pond Street Franklin 62 Chicken Brook Village Street Medway 63 Shepards Brook Elm Street Franklin 64 Mill River River Road Norfolk 65 Stop River Causeway Street Medfield 66 Bogastow Brook Orchard Street Millis 67 Waban Brook Wellesley College Wellesley Golf Course 68 Fuller Brook Dover Road Wellesley 69 Powissett Brook Dedham Street Dover 70 Rosemary Brook Housing Project Wellesley 71 Stony Brook South Street Waltham 72 Stony Brook Church Street Weston 73 Hobbs Brook Route 117 Weston 74 Beaver Brook River Street Waltham

108 LOCATIONOF MONITORINGSTATIONS

CHARLESRIVER BASIN

0 2 3 4 5

MILES

NATICK I Wobon Lt.-~i.'.. Wobu Bt. ( ''!'Ill Pd~\

WESTWOOD HOPKINTON, Cello Lok•

( HOLLISTO

_,,.,t:Mlw ___

MILFORD WALPOLE

HOP~E

WRENTHAM ~ FIGURE E 109 TABLEI-E-2 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN TIME - TEMPERATURE- DISSOLVEDOXYGEN

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 * 0905 0910 0850 0925 ** 39 56 74 72 *** 10.2 8. 1 1.8 1.8 52 1000 1010 1002 1025 40 56 74 71 12.6 9.4 7.9 8.5

53 1040 1040 1035 1100 38 56 76 72 11. 6 8.4 7.5 6.9

54 Above 1210 1210 1145 1220 40 58 78 79 9.7 7.7 5.8 5.9

54 Below 1210 1210 1145 1220 40 58 78 79 10.8 8.1 6.7 7.5

55 Above 1230 1250 1225 1310 41 57 78 73 10.5 7.6 5.5 7.4

55 Below 1230 1250 1225 1310 41 57 78 73 11.4 9.2 6.7 7.9

56 1350 1325 1255 1355 42 58 78 78 11.5 8.8 8.9 9.6

57 ll,45 1350 1315 1415 43 57 80 78 11. 0 8.5 12.4 10.3

58 1325 1420 1330 1430 41 57 80 76 9.0 9.5 8.0 7.1

* Time ** Temperature (°F) *** Dissolved Oxygen (mg/1) 110 TABLEI-E-2 (CONTINUED)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

59 1515 1450 1410 1500 43 57 80 77 11.7 8.9 7.3 11. 4

60 0915 0925 0905 0935 38 55 68 67 11. 9 8.5 6.6 5.0

61 0925 0935 0915 0950 39 56 70 66 8. 1 3.8 2.2 2.5

62 0940 0955 0937 1005 39 57 70 67 12.4 10.2 5.3 6.5

63 0950 0945 0930 1000 37 55 70 67 11. 2 7.2 4.6 4.3

64 1015 1020 1020 1040 40 56 74 73 10.8 8.6 8.8 7.4

65 1055 1055 1055 1110 39 58 74 72 8.2 3.2 2.2 2.0

66 Above 1110 1110 1110 1140 40 58 75 79 10.3 7.8 5.3 12.6

66 Below 1110 1110 1110 1140 40 58 75 79 10. 6 8.4 10.1 9.5

67 1305 1225 1205 1240 41 57 76 72 10.1 9.6 7.8 7.1

68 1255 1230 1215 1300 44 55 72 67 10. 4 8.6 11.5 12.7

69 1405 1305 1240 No Flow 44 58 76 11. 9 8.1 7.0

111 TABLEI-E-2 (CONTINUED)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

70 1430 1405 1350 1425 48 58 69 64 12.3 8.5 9.4 4.8

71 1500 1435 1355 1445 42 57 80 78 11.4 10.2 8.9 8.5

72 1445 1600 75 68 10.4 6.3 8.2

73 1520 1458 1610 57 76 75 11. 0 10.0 6.7 7.8

74 1500 1420 1510 56 70 65 9.1 6.3 8.1

112 TABLE I-E-3 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN CHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH22 MAY2 JULY 5 SEPTEMBER6 51 50 21 51 65 52 27 47 56 50 53 16 26 31 30 54 21 47 36 30 55 32 26 31 45 56 27 26 31 50 57 16 37 46 45 58 27 26 41 47 59 21 47 46 62 60 27 26 46 31 61 47 36 68 62 21 26 46 36 63 5.4 11 10 42 64 27 32 20 26 65 32 20 31 66 43 41 31 67 21 32 41 36 68 32 46 31 69 11 11 10 No Flow 70 32 37 51 31 71 16 32 26 26 72 21 27 31 26 73 32 37 46 36 74 32 38 41 31

113 TABLEI-E-4 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN 5-DAY BIOCHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 5.1 6.9 4.5 5.1 52 1.8 3.9 3.0 1.2 53 3.0 4.5 3.0 1.5 54 1.5 3.6 2.7 1.2 55 1.2 3.0 2.7 2.7 56 1.8 3.9 4.8 3.3 57 2.1 3.9 8. 7 3.6 58 2.4 3.9 6.0 4.2 59 2.7 4.5 3.6 8.7 60 1.5 2.7 3.3 0.6 61 4.8 2.7 2.1 62 2.4 3.3 4.2 1. 2 63 0.9 4.2 2.1 1.2 64 0.9 3.9 1.8 0.3 65 6.0 1. 2 1. 5 66 3.6 2.7 2.1 67 2.1 3.9 2.1 0.6 68 3.9 2. 1 1.5 69 1.2 2.1 1.2 No Flow 70 2.4 3.3 3.0 0.6 71 2.7 3.3 2.4 0.9 72 1.8 2.1 2.7 1.5 73 6.9 5.7 3.3 0.0 74 3.0 4.8 3.6 3.0

114 TABLEI-E-5 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN pH DATA (Standard Units)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 6.8 6.9 6.8 7 .5 52 6.8 7.0 7.3 7.6 53 6.6 6.8 7.2 7.5 54 6.4 6.7 6.9 7.5 55 6.4 6.8 7.0 7.5 56 6.6 6.9 7.1 7.5 57 6.6 6.9 7.3 7.7 58 6.7 7.0 7.4 7.6 59 6.8 7.0 7.2 7.9 60 5.9 6.1 6.9 7.3 61 6.6 6.6 7.4 62 6.1 6.9 6.9 7.5 63 6.6 6.7 6.7 7.2 64 6.8 6.9 6.8 7. 4 65 6.0 6.7 7.2 66 6.8 6.9 8.6 67 6.9 7.1 6.5 7.3 68 7.3 7.4 8.3 69 6.2 6.5 6.7 No Flow 70 7. 0 7.1 7.2 7.0 71 7.1 7.3 7.3 7.6 72 6.9 6.9 7.0 7.4 73 7.3 7.4 7.4 7.4 74 7.3 7.3 7.3 7.4

115 TABLEI-E-6 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN TOTALALKALINITY DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6

51 20 25 38 47 52 12 13 32 33 53 12 12 26 27 54 11 15 26 32 55 12 15 28 30 56 15 15 27 31 57 14 16 29 34 58 17 17 27 35 59 17 17 37 34 60 7.0 5.0 12 26 61 16 27 39 62 10 13 25 37 63 11 13 17 26 64 13 15 17 23 65 9.0 19 23 66 17 22 32 67 27 22 15 27 68 43 47 43 69 4.0 5.0 6.0 No Flow 70 24 29 40 53 71 18 22 30 31 72 15 20 31 30 73 37 32 28 21 74 34 40 45 49

116 TABLEI-E-7 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN HARDNESSDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 32 32 35 43 52 25 27 35 54 53 26 27 36 46 54 24 27 38 49 55 26 29 38 47 56 26 28 39 49 57 28 31 43 54 58 28 32 43 58 59 30 29 49 60 60 23 15 21 42 61 32 45 52 62 28 30 54 68 63 26 28 37 41 64 30 33 31 43 65 27 37 44 66 31 37 58 67 53 50 64 60 68 75 85 84 69 12 13 13 No Flow 70 54 54 89 97 71 44 45 51 58 72 31 38 47 59 73 63 18 49 51 74 70 82 77 74

117 TABLEI-E-8 PWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN TURBIDITYDATA (NTU)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 2.5 3.2 2.6 3.1 52 0.6 6.3 2.6 1.5 53 0.6 2.8 1.7 1.0 54 0.4 2.8 1.6 1.5 55 0.4 2.5 1.8 2.0 56 0.6 3.5 2.5 3.0 57 1.1 3.8 3.0 7. 8 58 0.9 3.8 2.8 5.5 59 1.4 3.7 2.5 13 60 0.3 1.6 1. 9 4.8 61 2.3 4.5 2.9 62 0.6 2.8 2.7 2.4 63 0.4 2.2 12 1. 8 64 0.3 1. 9 1.1 0.7 65 0.8 1.8 0.9 66 1.5 4.5 3.6 67 1.0 1.8 0.7 0.5 68 3.0 2.4 1.1 69 0.6 0.9 1.4 No Flow 70 1.4 2.6 2.1 2.2 71 1.1 1.6 1. 3 0.8 72 0.3 0.4 1.7 0.7 73 2.4 2.5 2.5 1.1 74 2.2 4.2 3.0 3.8

118 TABLEI-E-9 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN SUSPENDEDSOLIDS DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 3.0 4.0 6.0 17 52 2.0 11 8.0 4.0 53 3.0 5.0 7.0 4.5 54 3.0 4.0 10 8.0 55 4.0 4.0 11 13 56 2.0 7.0 27 18 57 5.0 13 27 17 58 2.0 17 49 22 59 2.0 12 13 20 60 1.0 1.0 7.0 5.0 61 3.0 4.0 7.5 62 3.0 4.0 1.5 21 63 1.0 2.0 10 7.0 64 1.0 4.0 2.5 4.5 65 1.0 2.5 9.5 66 2.0 4.5 12 67 1.0 1.0 5.0 5.5 68 6.0 8.5 8.0 69 1.0 1.5 6.0 No Flow 70 3.0 2.0 45 4.5 71 2.0 0.0 2.0 6.0 72 1.0 0.0 0.5 20 73 5.0 4.0 68 4.0 74 5.0 11 10 7.0

119 TABLEI-E-10 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN DISSOLVEDSOLIDS DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 105 136 178 211 52 78 111 156 222 53 77 93 125 155 54 61 94 122 140 55 58 104 119 155 56 68 99 123 170 57 79 107 135 205 58 78 105 133 182 59 100 86 139 194 60 49 61 111 117 61 125 198 226 62 85 88 188 193 63 57 74 110 131 64 71 96 99 111 65 111 113 128 66 98 133 152 67 163 147 189 180 68 171 231 280 69 25 25 24 No Flow 70 161 138 275 359 71 102 102 136 184 72 75 84 301 114 73 161 156 204 186 74 259 225 234 195

120 TABLE I-E-11 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN TOTALSOLIDS DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 108 140 184 228 52 80 122 164 226 53 70 98 132 160 54 64 98 132 148 55 62 108 130 168 56 70 106 150 188 57 84 120 162 222 58 80 122 182 204 59 102 98 152 214 60 50 62 118 122 61 128 202 234 62 88 92 190 214 63 58 76 120 138 64 72 100 102 116 65 112 116 138 66 100 138 164 67 164 148 194 186 68 178 240 288 69 26 26 30 No Flow 70 164 140 320 364 71 104 102 138 190 72 76 84 302 134 73 166 160 272 190 74 264 236 244 202

121 TABLEI-E-12 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN TOTALKJELDAHL-NITROGEN DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 1.7 2.2 1.5 2.8 52 1. 2 0.85 1.3 1. 2 53 0.92 0.88 1.4 1.0 54 o. 71 0.88 1.7 1.1 55 0.56 0.70 2.2 1.4 56 0.75 0.75 0.90 1.3 57 0.85 0.82 1.0 1.7 58 0. 71 0.85 1. 2 1.8 59 0.73 1.1 1.4 1.4 60 0.62 0.80 1.1 0.90 61 1.4 1. 2 4.3 62 1.0 0.75 0.72 1.1 63 0.63 0.72 0.75 1.2 64 0.42 0.55 1.2 0.60 65 o. 77 0.55 0.95 66 0.90 1.0 0.90 67 o. 72 0.60 0.20 0.62 68 0.75 0. 72 0.87 69 0.46 0.38 0.60 No Flow 70 o. 71 0.62 1. 2 0.38 71 0.74 0.65 0.80 0.73 72 0.65 0.65 0.48 0.90 73 2.2 1. 2 1. 6 0. 75 74 1.5 1.0 1.4 1.2

122 TABLEI-E-13 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN AMMONIA-NITROGENDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 0.94 1.4 0.85 0.81 52 0.29 0.08 0.01 0.10 53 0.22 0.01 0.02 0.04 54 0.00 0.00 o.oo 0.06 55 0.01 0.00 0.00 0.03 56 0.00 0.00 0.02 0.01 57 0.06 0.08 0.00 0.08 58 0.06 0.08 0.00 0.18 59 0.09 0.04 0.07 0.01 60 o.oo 0.04 0.01 0.05 61 0.40 0.23 4.3 62 0.19 0. 03 0.18 0.07 63 0.00 0.02 0.08 0.01 64 0.00 0.01 0.01 0.01 65 0.00 0.01 0.06 66 o.oo 0.04 0.06 67 o. 14 0.01 0,05 0.01 68 0.02 0.03 0.00 69 0.00 0.00 0.00 No Flow 70 0.04 0.01 0.01 0.01 71 0.07 0.05 0.03 0.01 72 0.00 0.04 0.00 0.01 73 1.1 0.25 0. 06 0.02 74 0.05 0.08 0.20 o. 12

123 TABLEl-E-14 DWPC- MAPC208 MONlTORINGPROGRAM CHARLESRlVER BASIN NITRATE-NITROGENDATA (mg/1)

STATION MARCH21 MAY 2 JULY 5 SEPTEMBER6 51 0.6 0.9 1.3 1.0 52 0.6 0.8 0.2 1.6 53 0.6 0.8 0.0 0.5 54 0.4 0.2 o.o 0.1 55 0.5 0.2 o.o 0.0 56 0.7 0.2 o.o o.o 57 0.4 0.3 o.o 0.1 58 0.5 0.3 o.o 0.2 59 0.5 0.3 0.0 0.0 60 0.3 0.2 0.2 0.2 61 0.8 0.9 0.3 62 1.3 0.6 0.9 1.0 63 0.9 0.5 0.7 0.4 64 0.5 0.3 o. 1 0.1 65 0.2 0.2 0.8 66 0.2 0.0 0.1 67 1.1 0.5 0.1 0.1 68 1.1 1. 2 1.5 69 0.2 0.0 0.1 No Flow 70 0.8 0.3 1.5 1.4 71 0.8 0.6 0.1 0.1 72 0.8 0.3 0.7 0.8 73 1.2 0.9 0.4 0.2 74 1.4 1.0 1.2 1.5

124 TABLEI-E-15 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN TOTALPHOSPHORUS DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 0.35 0.42 1.8 3.3 52 0.16 0.35 1.0 1.6 53 0.15 0.27 0.38 0.65 54 0.16 0.20 0. 72 0.53 55 0.14 0.18 0.27 0.57 56 0.14 0.18 0.28 0.28 57 0.15 0.18 0.23 0.19 58 0.12 0.20 0.24 0.26 59 0.11 0.18 0.17 0.31 60 0.09 0.06 0.07 0.06 61 0.68 1.1 1.5 62 0.23 0.12 0.16 0.15 63 0.07 0.06 0.12 0.07 64 0.06 0.04 0.05 0.02 65 0.08 0.21 o. 21 66 0.08 0.14 0.11 67 0.07 0.04 0.04 0.03 68 0.06 0.08 0.09 69 0. 04 0.03 0.05 No Flow 70 0.08 0.05 0.15 O. 05 71 0. 06 0.03 0.03 0.97 72 0.11 0.03 0.03 0.09 73 0.12 0.07 0.15 o. 05 74 0.31 0.14 0.16 0.16

125 TABLEl-E-16 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN TOTALCOLIFORM DATA (per 100 ml)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 5,000 1,800 1,200 1,900 52 30 500 1,200 500 53 180 330 180 600 54 1,000 580 200 100 55 300 850 400 1,000 56 320 600 140 300 57 1,200 11,000 800 400 58 8,000 15,000 1,000 1,200 59 2,400 2,800 400 400 60 240 620 9,000 1,500 61 40 50 500 1,000 62 1,400 1,200 700 3,600 63 240 1,000 1,800 1,500 64 40 160 220 400 65 60 80 400 66 80 300 900 1,000 67 240 100 20,000 5,000 68 600 850 2,400 4,300 69 80 250 280 No Flow 70 20 40 280 1,800 71 40 300 100 800 72 140 700 440 900 73 900 180 200 700 74 10,000 26,000 38,000 20,000

126 TABLEI-E-17 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN FECAL COLIFORMDATA (per 100 ml)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 420 20 40 380 52 <5 40 150 180 53 30 30 60 60 54 <10 40 15 <20 55 <10 35 200 340 56 20 20 40 <20 57 70 80 <5 200 58 1,500 2,800 120 300 59 300 480 80 40 60 10 60 400 20 61 5 10 80 80 62 100 120 100 400 63 40 70 190 40 64 <5 60 10 <20 65 <5 30 40 66 <5 25 80 20 67 <10 10 250 200 68 200 200 1,000 1,200 69 <5 10 90 No Flow 70 5 5 150 60 71 <5 140 10 <20 72 <5 40 150 520 73 <10 20 150 60 74 1,800 600 5,000 4,800

127 TABLEI-E-18 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN CADMIUMDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 0.00 0.00 0.00 0.00 52 0.00 0.00 0.00 0.00 53 0.00 0.00 0.00 0.00 54 0.00 0.00 0.00 0.00 55 0.00 0.00 0.00 0.00 56 0.00 0.00 o.oo 0.00 57 0.00 0.00 0.00 0.00 58 0.00 0.00 0.00 0.00 59 0.00 0.00 o.oo 0.00 60 0.00 0.00 0.00 0.00 61 0.00 0.00 0.00 0.00 62 o.oo 0.00 0.00 0.00 63 0.00 0.00 0.00 0.00 64 0.00 0.00 0.00 0.00 65 0.00 0.00 0.00 0.00 66 0.00 0.00 0.00 0.00 67 0.00 o.oo 0.00 0.00 68 0.00 0.00 0.00 0.00 69 0.00 0.00 o. 00 No Flow 70 0.00 0.00 o.oo 0.00 71 0.00 0.00 0.00 0.00 72 0.00 0.00 0.00 0.00 73 0.00 0.00 o. 00 0.00 74 0.00 0.00 0.00 0.00

128 TABLEI-E-19 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN IRON DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 0.60 0.80 1.2 1.5 52 0.25 0.70 1.5 0.40 53 0.22 o. 50 0.85 0.25 54 0.20 0.45 0.67 0.28 55 0.22 0.47 0.67 0.38 56 0.25 0.42 0.90 0.43 57 0.30 0.58 0.90 0.58 58 0.30 0.62 1.3 0.68 59 0.38 0.60 1.0 1.2 60 0.25 0.45 1.8 2.2 61 0. 21 0.68 2.0 1.2 62 0.21 0.52 1.0 1.4 63 0.05 0.35 1.3 0.60 64 0.13 0.32 0.53 0.20 65 0.15 0.25 0.50 0.58 66 0.20 0.60 1.4 o. 70 67 0.25 0.15 0.12 0.40 68 o. 75 o. 75 1.0 0.35 69 0.30 0.34 0.85 No Flow 70 0.55 0.60 1.9 0.52 71 0. 20 0.25 0.35 0.20 72 0.15 0.30 0.53 0.85 73 0.55 0.60 6.5 0.25 74 0.65 1. 2 0.70 1.0

129 TABLEI-E-20 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN LEADDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 0.00 0.00 0.00 0.00 52 0.00 0.00 0.00 o.oo 53 0.00 0.00 0.00 o.oo 54 0.00 0.00 0.00 o.oo 55 0.00 0.00 0.00 o.oo 56 0.00 0.00 0.00 o.oo 57 0.00 0.00 0.00 0.00 58 0.00 0.00 0.00 o.oo 59 0.00 0.00 0.00 o.oo 60 0.00 0.00 o.oo 0.00 61 0.00 0.00 0.00 0.00 62 0.00 0.00 0.00 o.oo 63 0.00 o.oo 0.00 0.00 64 0.00 o.oo 0.00 0.00 65 0.00 0.00 0.00 o.oo 66 0.00 o.oo 0.00 0.00 67 0.00 0.00 0.00 0.00 68 0.00 0.02 0.00 0.00 69 0.00 0. 00 0.00 No Flow 70 0.00 0.00 0.00 0.00 71 0.00 0.00 0.00 0.00 72 0.00 0.00 0.00 0.00 73 0.00 0.00 0.00 0.00 74 o.oo 0.00 o.oo o.oo

130 TABLE I-E-21 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN MANGANESEDATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 0.13 0.12 0.20 0.35 52 0.11 0.10 0.08 0.04 53 0.04 0. 07 0.15 0.05 54 0.10 0.06 0.25 0.09 55 0.04 0.06 0.13 0.11 56 0.07 0.10 0.15 0.12 57 0.11 0.10 0.20 0.17 58 0. 07 0.12 0.23 0.15 59 0.50 0.10 o. 15 0.24 60 o. 05 0.03 0.07 0.22 61 0.04 0.15 0.15 0.25 62 0.07 0.15 0.29 0.25 63 0,03 0.06 0.20 0.40 64 0.01 0.04 0.02 0.07 65 0.02 0.03 0.05 0.15 66 0.03 0.05 0.18 0.15 67 0.25 0.36 0.07 0.25 68 0.13 0.07 0.09 0.05 69 0.02 0.04 0.13 No Flow 70 0.08 0.07 0.10 0.05 71 0.12 o. 07 0.15 0.09 72 0.06 0.02 0.13 0.12 73 0.40 0.42 2.0 0.15 74 0.11 0.16 0.15 0.09

131 TABLEI-E-22 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER BASIN ZINC DATA (mg/1)

STATION MARCH21 MAY2 JULY 5 SEPTEMBER6 51 0.05 0.02 0.00 0.00 52 0.01 0.02 0.00 0.02 53 0.01 0.06 0.00 0.05 54 0.00 0.03 0.00 0.00 55 0.10 0.09 0.00 0.03 56 0.03 0.02 0.00 0.00 57 o. 02 0.02 0.00 0.03 58 0.02 0.05 0.00 0.04 59 0.06 0.01 0.00 o. 03 60 0.01 0.01 0.00 0.04 61 0.05 0.03 0.00 0.02 62 0.05 0.01 0.00 0.00 63 0.00 0.05 0.00 0.00 64 0.12 0.00 0.00 0.10 65 0.00 0.01 0.00 0.02 66 0.01 0.10 0.00 0.00 67 0.02 0.01 0.00 o.oo 68 0.03 0.00 0.00 0.00 69 0.00 0.00 0.00 No Flow 70 0.01 0.00 0.00 0.00 71 0.00 o.oo 0.00 0.02 72 0.01 o.oo 0.00 0.00 73 0.01 0.02 0.10 0.02 74 0.02 0.02 0.00 0.00

132 TABLE I-F-1 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN LOCATIONOF MONITORINGSTATIONS

NUMBER STREAM LOCATION MUNICIPALITY 75 Cordaville Road Ashland 76 Sudbury River Route 135 Ashland 77 Sudbury River Winter Street Framingham 78 Sudbury River Central Street Framingham 79 Sudbury River Pelham Island Road Wayland 80 Sudbury River Route US 20 Wayland 81 Sudbury River Route 117 Concord/Lincoln 82 Sudbury River Nashawtuc Road Concord 83 Indian Brook Cross Street Ashland 84 Cold Spring Brook Chestnut Street Ashland 85 Dunsdell Brook Brook Street Framingham 86 Hop Brook Landham Road Sudbury 87 Hop Brook Peakham Road Sudbury 88 Assabet River Chapin Road Hudson 89 Assabet River Cox Street Hudson 90 Assabet River Gleasondale Dam Stow 91 Assabet River Routes 62 & 117 Maynard 92 Assabet River USGS Gage Maynard 93 Assabet River Route 62 Acton/Concord 94 Assabet River Route 62 Concord 95 Assabet River Route 2/2A Concord 96 Lowell Road Concord 97 Dansforth Brook Main Street/Route 62 Hudson 98 Fort Meadow Brook Main Street Hudson 99 Elizabeth Brook Near Gravel Pit Stow 100 Fort Pond Brook South Main Street South Acton 101 Nashoba Brook Route 2 Acton 102 Warner's Pond Commonwealth Avenue West Concord 103 Spencer Brook Barrett's Mill Road Concord 104 Dakins Brook Lowell Road Concord 105 Fort Pond Brook Central Street West Acton 106 Nagog Brook Main Street Acton 133 LOCATIONOF MONITORINGSTATIONS

SUASCO RIVER BASIN

BILLERICA

HARVARD ' Elizabelh Bk. ---1' . / I

:~ury Rlvar

BERLIN \WESTON BOYLSTON t--·- 5. -(~,., • Cochltua/11 SHREWS ' 8"'-'' SOUTHS OUGH' Sudbur

I Nor I h ! /1Grbor Bk -~ UPTON HOLLISTON 0 2 3 4 5

-----MILES FIGURE F 134 TABLEI-F-2 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN TIME - TEMPERATURE- DISSOLVEDOXYGEN

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 * 1015 0950 0850 0950 ** 37 54 70 68 *** 11. 5 9.0 4.9 7.3 76 1030 1005 0905 1010 38 56 70 68 12.3 9.5 5.6 6.4

77 Above 1040 1015 0915 38 57 77 12.0 9.3 7.1

77 Below 1020 0915 1020 57 76 74 9.9 7.3 8.1

78 Above ll05 1040 39 59 11.5 9.4

78 Below lllO 1042 1005 1035 39 58 74 71 12.2 9.7 7.8 8.5

79 ll25 1055 1020 1050 39 60 74 71 11.1 8.5 7.5 8.1

80 ll30 ll05 1030 1055 40 59 74 71 10.8 7.9 7.2 6.1

81 1205 ll45 ll05 1135 39 62 77 74 10.1 7.4 11. 1 9.5

82 1225 1225 ll20 1215 39 60 76 75 10.1 9.1 8.5 9.2

* Time ** Temperature (oF) *** Dissolved Oxygen (mg/1) 135 TABLEI-F-2 (CONTINUED)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

83 1005 0940 0835 0945 38 48 61 60 12.0 11. 0 7.0 6.9

84 1020 1000 0900 1000 39 56 69 64 11.7 9.2 5.0 9.1

85 1055 1030 0935 1030 40 54 62 62 12.0 11. 6 5.6 9.1

86 1140 1115 1035 1100 38 58 68 66 12.5 10.0 7.8 8. 1

87 1150 1130 1050 1120 40 59 69 67 11.5 10.0 8.0 7.9

88 1555 1520 1430 1455 38 60 72 72 9.9 9.5 9.0 5.8

89 1535 1505 1415 1440 39 62 72 71 11. l 10. 1 5.7 10. 2

90 1505 1450 1355 1425 39 60 75 73 10. 5 9.0 3.0 2.8

91 1440 1415 1330 1400 39 60 78 73 10.5 8.3 9.0 11.4

92 1425 1410 1320 1350 39 60 76 73 11. 2 9.5 7.9 8.1

93 1420 1400 1315 1345 38 61 76 75 11. 7 8.9 5.4 7.6

94 1405 1350 1305 1340 39 62 77 75 11. 7 9.6 10.5 12.1

136 TABLEI-F-2 (CONTINUED)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7

95 1255 1250 1150 1240 39 61 73 73 11.5 9.3 6.8 10.2

96 1235 1230 1135 1245 39 60 76 74 10.6 8.4 7.1 8.9

97 1545 1515 1425 1450 38 60 74 68 11. 9 9.1 6.2 5.4

98 1520 1500 1405 1435 39 63 62 63 11. 1 8.8 7.2 6.7

99 1445 1430 1345 1410 39 62 70 74 6.9 8.8 6.9 7.4

100 1345 1330 1245 1320 38 62 75 74 8.8 5.7 6.3 6.6

101 1305 1300 1200 1245 37 60 70 69 11.7 9.0 5.7 6.4

102 1400 1345 1300 1330 38 61 76 74 10.9 8.8 7.4 7.5

103 1250 1240 1145 1235 38 62 69 64 10.9 7.6 5.0 1.7

104 1240 1235 1140 1230 39 62 74 75 8.2 8.1 4.2 3.9

105 1335 1320 1225 1300 38 62 70 67 10.1 6.8 5.4 6.4

106 1320 1310 1210 No Flow 38 60 64 11.8 9.4 8.1

137 TABLEI-F-3 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN CHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 37 32 57 36 76 21 32 41 41 77 37 38 26 31 78 27 16 31 26 79 32 38 41 26 80 21 54 52 52 81 27 36 36 82 37 43 52 41 83 37 38 5.0 26 84 21 16 15 21 85 37 43 26 26 86 21 16 57 36 87 27 43 72 57 88 16 21 26 31 89 16 43 31 47 90 37 48 21 41 91 21 16 26 26 92 32 32 36 31 93 11 27 41 31 94 27 27 36 26 95 27 51 31 96 27 27 56 26 97 27 48 26 31 98 16 32 41 16 99 53 43 31 16 100 32 38 46 31 101 32 48 46 21 102 32 32 41 30 103 27 48 46 30 104 16 32 41 20 105 21 43 41 25 106 21 27 31 No Flow 138 TABLEI-F-4 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN 5-DAY BIOCHEMICALOXYGEN DEMAND DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 1.5 4.8 2.4 2.7 76 1.8 6.3 2.4 1.8 77 2.7 3.3 3.0 2.4 78 2.1 4.8 3.3 1.5 79 2.4 4.2 3.9 1.5 80 2.4 3.3 3.6 1.5 81 3.9 6.6 4.2 82 2.1 4.2 5.1 4.5 83 2.7 4.2 2.1 2.7 84 2.4 2.7 1.8 0.6 85 2.1 3.6 0.6 0.0 86 1.8 3.0 5.4 5.1 87 1.2 3.9 6.6 6.6 88 2.4 2.7 2.7 1. 2 89 2.1 2.7 9.0 0.9 90 2.1 2.4 4.8 4.8 91 2.4 2.7 3.0 1. 2 92 2.4 2.1 4.8 1.2 93 3.0 3.6 5.1 3.0 94 1.8 3.0 3.6 0.9 95 3.6 1.8 0.9 96 2.1 2.4 3.9 2.1 97 1.5 2.4 2.1 2.1 98 1.8 5.4 2.7 1.2 99 3.6 2.7 3.0 0.9 100 2.7 1.8 2.7 2.1 101 1.5 2.1 1.8 1.8 102 1.8 2.1 3.9 2.1 103 1.5 1.8 2.4 4.5 104 2.4 2.7 3.0 2.7 105 2.1 3.3 3.3 1.2 106 2.4 2.4 2.4 No Flow 139 TABLEI-F-5 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN pH DATA (Standard Units)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 6.3 7.1 7.1 7.4 76 6.5 6.7 7.1 7.4 77 6.6 6.8 7.2 7.3 78 6.6 6.7 7.2 7.4 79 6.7 6.9 7.5 7.6 80 6.7 6.9 7.1 7.6 81 6.9 7.3 7.6 82 6.8 6.9 7.2 7.6 83 6.7 6.4 6.6 6.6 84 6.6 6.7 6.7 6.6 85 6.7 7.2 6.9 7.1 86 6.7 7.2 7.2 7.5 87 6.8 7. 1 8.0 7.8 88 6.8 6.9 7.3 7.1 89 6.8 7.0 7.3 7.5 90 6.7 6.9 7.0 6.9 91 6.5 6.8 7.4 8.1 92 6.7 6.9 7.8 7.4 93 6.8 6.8 7.4 7.3 94 6.8 7.1 7.6 8.2 95 6.9 7.4 7.6 96 6.7 6.8 7.4 7.1 97 6.8 6.9 7.3 6.9 98 7.0 6.0 7.0 6.4 99 4.9 6.7 7.2 7. 0 100 6.1 6.5 6.8 7.0 101 6.4 6.7 6.8 7.1 102 6.4 6.7 7.1 7.1 103 6.2 6.4 6.6 6.7 104 6.1 6.6 6.7 6.5 105 6.3 6.6 6.8 6.5 106 6.6 6.8 7.0 No Flow

140 TABLEI-F-6 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN TOTALALKALINITY DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 5.0 12 20 25 76 5.0 10 19 23 77 8.0 11 14 18 78 10 12 18 24 79 11 17 26 32 80 14 18 25 36 81 19 27 37 82 15 18 25 32 83 12 6.0 9.0 15 84 7.0 11 17 32 85 9.0 26 19 33 86 21 25 31 34 87 14 20 30 51 88 14 17 28 30 89 13 17 32 38 90 13 16 29 40 91 10 15 24 34 92 11 14 23 30 93 11 14 24 29 94 10 16 21 27 95 15 22 31 96 11 15 24 31 97 9.0 13 19 27 98 14 7.0 12 17 99 3.0 12 14 20 100 6.0 13 18 25 101 7.0 12 19 28 102 8.0 14 21 27 103 5.0 7.0 10 28 104 7.0 8.0 14 17 105 9.0 13 15 15 106 8.0 12 21 No Flow

141 TABLEI-F-7 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN HARDNESSDATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 26 27 44 40 76 26 28 47 59 77 26 28 40 30 78 28 33 70 43 79 33 37 61 59 80 33 37 42 61 81 39 76 60 82 32 36 36 57 83 26 20 25 25 84 25 26 40 75 85 47 50 60 64 86 41 43 34 77 87 40 37 29 71 88 33 32 so 52 89 33 32 40 50 90 33 32 46 51 91 31 21 42 47 92 30 31 44 46 93 30 31 42 31 94 30 31 35 41 95 31 46 47 96 31 32 27 50 97 24 26 58 47 98 35 33 32 29 99 18 29 45 40 100 26 28 40 46 101 26 28 42 44 102 28 28 43 45 103 20 19 29 36 104 15 17 26 31 105 26 28 37 35 106 25 25 43 No Flow

142 TABLEI-F-8 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN TURBIDITYDATA (NTU)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 0.2 0.6 4.7 3.1 76 0.4 0.9 2.9 1. 9 77 0.7 0.9 1.5 1. 9 78 0.9 1.0 1.5 1.6 79 1.1 1. 2 2.0 1.6 80 0.6 1.0 4.6 3.1 81 0.6 8.0 7.4 82 0.8 0.6 5.7 5.9 83 0.2 0.3 1. 6 2.6 84 0.4 0.2 1.7 0.6 85 1.1 1.1 1.4 1. 9 86 0.3 1.0 18 14 87 0.3 1. 9 22 22 88 0.5 1.0 1. 6 1. 9 89 0.8 1.0 1.0 1.1 90 0.4 1.0 1.5 1.4 91 0.2 1.0 1.7 1.1 92 1.2 1.0 1.8 1.2 93 0.5 1.0 2.0 1. 1 94 0.5 2.9 1.7 0. 7 95 0.9 1.3 0.9 96 0.5 0.9 4.1 1. 9 97 2.3 1.3 4.3 11 98 1.1 0.7 1. 9 2.7 99 0.3 1.8 5.5 1.0 100 0.2 0.4 1.5 1.2 101 0.3 0.5 1.2 1.0 102 0.3 0.5 1.3 1.4 103 0.6 1.6 0.9 6.4 104 0.6 1.1 1.5 2.4 105 0.4 0.2 2.3 3.1 106 0.3 0.6 0.6 No Flow

143 TABLEI-F-9 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN SUSPENDEDSOLIDS DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 1.0 o.o 7.0 4.5 76 1.0 1.0 3.0 0.5 77 2.0 3.0 0.5 2.0 78 1.0 2.0 0.5 0.5 79 1.0 1.0 5.5 4.0 80 1.0 1.0 4.5 7.0 81 0.0 18 16 82 1.0 1.0 13 13 83 1.0 0.0 14 2.0 84 1.0 0.0 0.5 1.5 85 2.0 2.0 0.5 3.0 86 1.0 3.0 20 18 87 1.0 7.5 28 16 88 1.0 2.0 0.5 2.5 89 1.0 o.o 0.5 2.0 90 1.0 2.0 5.0 10 91 1.0 1.0 2.0 1.5 92 1.0 0.5 5.5 3.0 93 1.0 3.0 3.5 1.5 94 1.0 2.0 2.0 0.5 95 1.0 0.5 0.5 96 1.0 2.0 9.0 3.5 97 9.0 2.0 4.0 4.0 98 5.0 2.0 1.0 2.0 99 1.0 4.0 9.0 1.0 100 1.0 0.0 0.5 1.5 101 1.0 1.0 0.5 o.o 102 1.0 2.0 0.5 1.0 103 1.0 1.0 0.5 11 104 2.0 6.0 0.5 4.0 105 1.0 0.0 3.0 1.0 106 1.0 o.o 5.0 No Flow 144 TABLEI-F-10 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN DISSOLVEDSOLIDS (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 97 110 163 159 76 99 121 171 225 77 90 115 139 142 78 95 114 145 161 79 101 135 168 182 80 119 133 181 191 81 124 158 198 82 97 123 163 163 83 71 84 154 102 84 69 86 117 228 85 118 130 179 189 86 109 125 186 212 87 111 114 172 242 88 71 104 133 155 89 103 106 14 7 188 90 99 104 145 198 91 107 103 140 116 92 97 105 136 177 93 101 87 136 166 94 103 90 140 159 95 100 147 163 96 109 106 153 166 97 69 78 162 164 98 99 140 133 156 99 81 96 143 141 100 83 102 157 150 101 79 113 123 142 102 83 106 137 171 103 57 75 95 105 104 32 42 103 128 105 75 102 151 131 106 73 90 155 No Flow

145 TABLE I-F-11 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN TOTAL SOLIDS DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 98 110 170 164 76 100 122 174 226 77 92 118 140 144 78 96 116 146 162 79 102 136 174 186 80 120 134 186 198 81 124 186 214 82 98 124 176 176 83 72 84 168 104 84 70 86 118 230 85 120 132 180 192 86 110 128 206 230 87 112 122 200 258 88 72 106 134 158 89 104 106 148 190 90 100 106 150 208 91 108 104 142 118 92 98 106 142 180 93 102 90 140 168 94 104 92 142 160 95 101 148 164 96 110 108 162 170 97 78 80 166 168 98 104 142 134 158 99 82 100 152 142 100 84 102 158 152 101 80 114 124 142 102 84 108 138 172 103 58 76 96 116 104 34 48 104 132 105 76 102 154 132 106 74 90 160 No Flow

146 TABLE I-F-12 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN TOTALKJELDAHL-NITROGEN DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 0.85 0.60 0.98 0.75 76 0.70 1.0 0.38 1.0 77 0.66 0.88 0.70 0.82 78 0.76 0.95 0.40 0.88 79 0.86 0.90 o. 72 0.83 80 0.84 0.90 0.87 0.92 81 0.82 1. 2 1.3 82 0.97 0.80 0.92 1.2 83 0.94 0.52 0.50 1.1 84 0.70 0.52 0.38 0.57 85 0.89 0.62 0.45 o. 72 86 0.90 0.65 1.8 2.3 87 0.90 1.2 2.3 2.8 88 0.95 1. 3 0.55 1.1 89 2.4 0. 72 2.4 1.2 90 0.87 0.82 0.95 1.7 91 0.95 0.68 0.68 1.0 92 1.1 0.60 1.2 1.0 93 1. 3 1.0 1. 2 1.1 94 1.1 0.87 1.3 0.87 95 0.95 0.55 0.90 96 0.94 1.1 o. 72 1.0 97 1.0 o. 72 o. 72 1.0 98 0.85 1.1 0.60 0.80 99 o. 96 0.68 0.68 0.80 100 0. 72 0.75 a.so 0.85 101 0.83 o. 72 0.62 0.65 102 0.84 1.0 0.82 0.82 103 1.1 0.87 0.90 1.3 104 0.82 0.82 0.58 1. 3 105 0.76 0.90 0. 72 1.0 106 0.60 0.85 0.35 No Flow

147 TABLE I-F-13 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN AMMONIA-NITROGENDATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 0.00 0.00 0.05 0.03 76 0.00 0.03 o. 04 0.06 77 0.00 0.00 o. 02 0.05 78 0.01 0.02 0.02 0.05 79 0.00 0.00 0.04 0.04 80 0.00 0.00 0.05 0.05 81 0.01 0.01 0.01 82 0.00 0.00 0.01 0.01 83 0.00 0.01 0.05 0.10 84 0.00 0.00 0.02 0.01 85 0.01 o.oo o. 03 0.01 86 0.05 0.03 0.02 0.21 87 0.00 0. 04 0.04 0.33 88 0.11 0.10 0.04 0.06 89 0.10 0.04 1.3 0.01 90 0.23 0.14 0.22 0.29 91 0.15 0.20 0.04 0.01 92 0.10 0.20 0.54 0.12 93 0.13 0.56 0.56 0.26 94 0.15 0.34 0.06 0.03 95 0.43 0.03 0.11 96 0.01 0.21 0.02 0.01 97 0.00 0.07 0.09 0.27 98 0.00 0.21 0.11 0.12 99 0.01 0.08 0.09 0.01 100 0.00 0.05 0.03 0.07 101 0.00 0.05 0.03 0.04 102 o.oo o. 07 0.02 0.03 103 0.00 0.06 0.05 0.18 104 o.oo 0.06 0.01 0.01 105 0.00 0.21 0.08 0.07 106 0.38 0.31 0.01 No Flow

148 TABLE I-F-14 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN NITRATE-NITROGENDATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 0.1 0.2 0.2 0.2 76 0.1 0.3 0.2 0.4 77 0.2 0.2 0.1 0.1 78 0.3 0.2 0.1 0.1 79 0.4 0.2 0.2 0.1 80 0.5 0.2 0.2 0.1 81 0.1 o.o 0.0 82 0.5 0.0 o.o 0.0 83 0.4 0.3 0.1 0.1 84 0.5 0.3 0.4 1.9 85 1.1 0.7 0.8 0.7 86 1.5 0.7 0.4 0.5 87 1. 6 1.0 0.3 0.4 88 0.7 0.7 0.9 1.5 89 0.7 0.4 0.2 0.7 90 0.7 0.5 0.9 1.4 91 0.9 0.5 0.2 0.1 92 0.7 0.7 0.1 0.2 93 0.8 0.4 0.7 0.9 94 0.7 0.4 1.3 0.9 95 0.4 0.7 0.8 96 0.5 0.2 0.3 0.6 97 0.3 0.2 0.1 0.3 98 0.5 0.1 o. 7 1.6 99 0.4 0.1 0.4 0.3 100 0.3 0.0 0.1 0.1 101 0.7 0.4 0.5 0.5 102 0.6 0.2 0.1 0.0 103 0.2 0.0 0.4 0.0 104 0.3 0.0 o.o 0.0 105 0.3 1.0 0.2 0.3 106 1.0 1.0 2.5 No Flow

149 TABLEI-F-15 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN TOTALPHOSPHORUS DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 0.14 0.04 0.15 0.07 76 0.08 0.08 0. 06 77 0.09 0.03 0.04 0.03 78 0.25 0.03 0.04 0.04 79 0.17 0.04 0.07 0.06 80 0.15 0.04 0.13 0.09 81 0.06 0.08 0.14 82 0.11 0.06 0.06 0.09 83 0.15 0.04 0.03 0.03 84 0.10 0.04 0.02 0.02 85 0.12 0.06 0.02 0.04 86 0.18 0.14 0.34 0.25 87 0. 15 0.18 0.37 0.31 88 0.09 0.36 0.68 1.2 89 0.16 0.27 0.75 0.98 90 0.13 0.74 1.6 91 0.14 0.34 0.46 0.78 92 0.14 0.30 0.52 0.69 93 0.17 0.36 0.81 0.92 94 0.13 0.28 0.70 0.74 95 0.20 0.21 0.59 96 0.08 0.14 0.26 0.41 97 0.21 0.04 o. 06 0.07 98 0.15 0.05 0.03 0.05 99 0.16 0.04 0.07 0.04 100 0.13 0.03 0.06 0.07 101 0.14 0.03 0.03 0.04 102 0.14 0.06 0.04 103 0.16 0.06 0.09 0.11 104 0.12 0.05 0.05 0.06 105 0.08 0.04 0.06 0.05 106 0.08 0,05 o. 05 No Flow

150 TABLE I-F-16 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN TOTALCOLIFORM BACTERIA DATA (per 100 ml)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 120 520 16,000 5,000 76 860 700 120,000 900 77 170 130 11,000 200 78 300 640 42,000 100 79 320 140 73,000 200 80 160 280 12,000 800 81 5 130 15,000 1,000 82 10 150 7,500 3,000 83 5 200 220 800 84 100 120 1,200 600 85 280 1,000 9,500 1,700 86 150 90 54,000 2,000 87 160 120 800 2,000 88 550 3,000 9,000 800 89 680 1,200 51,000 900 90 1,400 540 22,000 600 91 300 380 9,000 900 92 520 600 10,000 4,500 93 280 520 13,000 500 94 120 500 31,000 300 95 330 700 9,100 4,800 96 110 540 5,300 900 97 800 700 7,800 18,000 98 400 1,400 5,900 500 99 10 180 24,000 600 100 280 80 37,000 200 101 140 400 4,000 900 102 140 1,200 9,000 500 103 250 260 37,000 3,000 104 80 120 5,500 600 105 30 130 85,000 800 106 120 170 1,800 No Flow

151 TABLE I-F-17 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN FECAL COLIFORMBACTERIA DATA (per 100 ml)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 <5 10 1,300 50 76 10 30 6,000 240 77 100 5 400 140 78 20 50 1,200 40 79 20 30 2,000 20 80 <5 15 800 100 81 <5 <5 500 200 82 <5 <5 600 300 83 <5 <5 60 <5 84 10 5 50 <5 85 20 150 2,000 480 86 20 10 1,800 500 87 <5 20 200 230 88 80 170 280 100 89 140 60 2,200 80 90 320 <5 1,500 20 91 10 15 650 20 92 100 220 150 800 93 20 20 700 220 94 10 15 1,250 40 95 30 40 900 460 96 10 20 800 180 97 60 10 700 30 98 50 30 500 20 99 <5 5 1,000 80 100 10 10 1,200 <10 101 20 60 300 180 102 10 15 600 120 103 20 30 1,300 800 104 <5 5 400 <10 105 <5 5 1,500 200 106 <5 25 520 No Flow

152 TABLE I-F-18 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN CADMIUMDATA (mg/1)

STATION MARCH22 MAY3 JUIY 6 SEPTEMBER7 75 o.oo 0.00 0.00 0.00 76 0.00 0.00 o.oo 0.00 77 o.oo 0.00 0.00 0.00 78 0.00 0.00 0.00 0.00 79 0.00 0.00 0.00 o.oo 80 o.oo 0.00 0.00 0.00 81 o.oo 0.00 0.00 0.00 82 0.00 0.00 o.oo 0,00 83 0.00 0,00 0.00 0.00 84 0.00 0.00 0.00 0.00 85 0.00 o.oo 0.00 0.00 86 0.00 0.00 0.00 0.00 87 0.00 o.oo 0.00 0.00 88 o.oo 0.00 0.00 89 0.00 0.00 0.00 90 o.oo 0.00 0.00 0.00 91 0. 00 o.oo 0,00 0.00 92 0.00 0.00 0.00 0.00 93 0.00 0.00 0.00 0.00 94 0.00 0.00 0.00 0.00 95 o.oo 0.00 0.00 0,00 96 0.00 0.00 0.00 0.00 97 o.oo 0.00 0.00 98 0.00 0.00 0.00 99 o.oo 0.00 0.00 0.00 100 o.oo 0.00 0.00 0.00 101 0.00 0.00 0.00 0.00 102 0.00 0.00 o.oo 0.00 103 0.00 0.00 0.00 0.00 104 0.00 o.oo 0.00 0.00 105 0.00 0.00 o.oo 0.00 106 0.00 0.00 o.oo 0.00 153 TABLE I-F-19 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN IRON DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 0.22 0.45 1.7 1.3 76 0.30 0.55 1.3 0.65 77 0.25 0.28 0.72 0.65 78 0.25 o. 40 0.80 0.60 79 0.25 0.40 0.85 0.40 80 0.20 0.40 0.95 0.40 81 0.23 0.31 0.75 0.59 82 0.23 0.31 o. 77 0.40 83 0.25 0.20 0.74 1.3 84 0.40 0.20 0.35 0.13 85 0.65 0.62 0.35 0.27 86 0.15 0.35 1.0 0.46 87 0. 17 0.47 0.80 0.60 88 0.42 o. so 0.50 89 0.45 0.34 0.30 90 0.25 0.50 o. so 0.40 91 0.20 0.46 0.58 0.20 92 0.29 0.46 0.55 0.25 93 0.25 0.54 0.75 0.29 94 0.25 0.52 0.60 0.15 95 0.20 0.52 0.45 0.17 96 0.28 0.42 0.78 0.16 97 0.55 1. 6 3.0 98 0.35 0.84 1.0 99 0.65 0.45 1.3 0.45 100 0.25 0.46 1. 2 0.48 101 0.15 0.36 0.50 0.30 102 0.15 0.45 0.70 0.42 103 0.25 0.45 1.1 1.8 104 o. so 0.48 2.1 1.8 105 0.27 0.25 0.87 o. 60 106 0.25 0.45 0.35 No Flow

154 TABLE I-F-20 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN LEAD DATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 0.00 0.00 0.00 o.oo 76 0,00 0.00 0.00 o.oo 77 0,00 0.00 0.00 o.oo 78 0.00 0,00 0.00 0.00 79 0.00 0,00 0.00 0.00 80 0.00 0,00 0,00 o.oo 81 0.00 0.00 0.00 0.00 82 0.00 0.00 0.00 0.00 83 0.00 0.00 0.00 o.oo 84 0.00 0.00 0.00 o.oo 85 0.00 0.00 0.00 0.00 86 0.00 o.oo 0.00 0.00 87 0.00 0.00 0.00 0.00 88 0.00 o.oo 0.00 89 0.00 0.00 0.00 90 0.00 0.00 0.00 0.00 91 0.00 0.00 0.00 0.00 92 0.00 0.00 0.00 0.00 93 0.00 0.00 0.00 o.oo 94 0.00 0,00 0.00 0.00 95 0.00 0.• 00 0,00 0.00 96 0.00 0.00 0.00 o.oo 97 0.00 0.00 0.00 98 0.00 0.00 0.00 99 0.00 0.00 0.00 0.00 100 0.00 0.00 0,00 0.00 101 0.00 0.00 0,00 0.00 102 0.00 0.00 0.00 o.oo 103 0.00 0.00 0.00 0.00 104 0.00 0.00 0.00 o.oo 105 0.00 0,00 0.00 o.oo 106 0.00 0.00 0.00 No Flow

155 TABLEI-F-21 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN MANGANESEDATA (mg/1)

STATION MARCH22 MAY3 JULY 6 SEPTEMBER7 75 0.05 0.08 0.26 0.20 76 0.09 0.10 0.20 0.40 77 0.09 0.09 0.20 0.35 78 0.09 0.18 0.10 0.30 79 0.05 0.10 0.20 0.06 80 0.05 0.08 o. 15 0.10 81 0.04 0.05 0.18 0.17 82 0.05 0.03 0.40 0.13 83 0.07 0.04 0.10 0.24 84 0.07 0.08 0.05 0.06 85 0.12 0.09 0.08 0. 03 86 0.00 0.05 0.24 0.10 87 0.05 0.05 0.17 0.12 88 0.13 0.05 0.06 89 0.08 0.34 0.04 90 0.09 0.11 0.50 0.20 91 0.06 0.10 0.58 0.05 92 o. 06 0.08 0.55 0.05 93 0.08 0.10 0.05 0.04 94 0.08 0.09 0.05 0.10 95 0.08 0.10 0.03 0.02 96 0.08 0.07 0.14 o. 05 97 0.08 0.12 0.50 98 0.05 0.10 o. 10 99 0.08 0.08 0.11 0.06 100 0.03 0.03 0.05 0.05 101 0.03 0.06 o. 05 0.10 102 o. 03 0.13 0.12 0.15 103 0.05 0.05 0.08 1.4 104 o. 05 0.03 0. 08 0.12 105 0.03 0.03 0.23 0.22 106 0.18 0.17 0.16 No Flow

156 TABLE I-F-22 DWPC- MAPC208 MONITORINGPROGRAM SUASCORIVER BASIN ZINC DATA (mg/1)

STATION MARCH22 MAY3 JUIY 6 SEPTEMBER7 75 0.00 0.00 0.00 0.00 76 0.02 0.00 0.00 0.00 77 0.00 0.02 0.00 0.02 78 0.04 0.00 0.00 0.04 79 0.00 0.02 0.00 o.oo 80 0.00 0.02 0.00 0.03 81 0.00 0.03 o.oo o. 05 82 o.oo o.oo o.oo 0.02 83 0.00 o.oo 0.00 0.00 84 0.00 0.00 0.00 0.05 85 0.00 o.oo 0.00 0.00 86 0.00 0.02 0.00 0.00 87 0.00 0.02 o.oo 0.00 88 0.00 0.00 0.00 89 0.02 0.00 0.00 90 0.02 0.00 0.00 0.00 91 0.00 0.00 0.00 0.00 92 0.00 0.00 0.00 0.00 93 o. 02 0.01 0.00 0.00 94 0.02 0.01 0.00 0.00 95 0.01 0.00 0.00 o.oo 96 o. 02 0.00 0.00 0.00 97 0.00 0.00 0.00 98 0.02 0.00 0.00 99 0.02 0.00 0.00 o.oo 100 0.00 0.00 0.00 0.00 101 0.00 0.00 0.00 0.00 102 0.00 o. 02 o.oo 0.05 103 0.04 0.00 0. 00 0.00 104 0.00 o.oo 0.00 0.11 105 0.00 o.oo 0.00 0.02 106 0.00 0.00 o.oo No Flow

157 SEDIMENTSAMPLING DATA

158 TABLE II-A-1 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER SEDIMENTSAMPLING LOCATIONS MAY 1977

NUMBER LOCATION MUNICIPALITY

1-101 Wildwood Street Wilmington

2-103 Chestnut Street North Reading

3-105 Above Russell Street Dam Peabody

4-107 Route 62 Middleton

5-111 Route 97 Topsfield

6-Il3 Willowdale Dam Topsfield

7-114 Sylvania Dam Ipswich

159 SEDIMENTSAMPLING LOCATIONS

IPSWICH RIVER BASIN

ANDOVE

isBr- ..._._

DY

D 2 3 4 E::.3n ,t J MILES

FIGURE G 160 TABLEII-A-2 DWPC- MAPC208 MONITORINGPROGRAM IPSWICH RIVER SEDIMENTSAMPLING DATA (mg/1) MAY 1977

% VOLATILE TOTAL TOTAL STATION COD(%) MATTER KJELDAHL-N PHOSPHORUS ARSENIC

1 o. 75 0.75 120 210 11

2 0.46 o. 53 260 300 2.3

3 4.2 3.7 910 460 12

4 2.1 1. 5 110 220 5.6

5 0.23 0.61 110 140 1. 2

6 0.61 0.87 343 200 12

7 1. 7 1.8 560 311 12

161 TAllLE II-A-2 (CONTINUED)

STATION CADMIUM CHROMIUM LEAD MERCURY NICKEL ZINC

1 0.00 11 25 0.07 7.2 32

2 o.00 9.2 15 0.04 3.8 19 3 o.oo 18 35 0.21 9.9 65

4 0.00 13 15 0.03 6.0 34

5 0.00 4.6 9.0 0.02 2.7 37

6 o.oo 9.0 20 0,00 3.0 35

7 0.00 17 28 0.01 10 65

162 TABLE Il-B-1 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER SEDIMENTSAMPLING LOCATIONS

NUMBER LOCATION MUNICIPALITY

8-NEOl Above Outlet Neponset Reservoir Foxborough

9-NE02 Above Outlet Crackrock Pond Foxborough

10-NE03 Below Sulllliler Street Dam East Walpole ll-NE04 Above South Street Dam Walpole

12-NEOS Above West Street Dam Walpole

13-NE06 Route U.S. 1 Walpole

14-NE07 Above Bird Pond Dam Walpole

15-NElO At USGS Gage Norwood lSA-NElOA 500 1 Upstream USGS Gage Norwood

16-NEl lA Canton Street Canton

17-NE13A Brush Hill Road Milton

18-NElS Routes 28/138 Milton/ Mattapan

163 SEDIMENT SAMPLING LOCATIONS

NEPONSET RIVER BASIN

BOSTON ·. )-au1N·cy' Mother -- Unlquity Brook

Tree ~ok \ MILTON ) ' Riv Br,

NORWOOD RANDOLPH Brook

MED '----,,es;;voi/•'Po/ ------

North

0----- 2 3 4 5 Ml LES

FOXBOROUGH FIGURE H 164 TABLEII-B-2 DWPC- MAPC208 MONITORINGPROGRAM NEPONSETRIVER SEDIMENTSAMPLING DATA (mg/1) MAY1977

% VOLATILE TOTAL TOTAL STATION COD (%) MATTER KJELDAHL-N PHOSPHORUS ARSENIC

8 0.67 1.0 250 330 1.4

9 41. 7 30 12,000 2,900 6.0

10 UNABLETO SAMPLE

11 28.0 27.9 5,100 670 6.9

12 30.9 27.9 3,800 730 14

13 0.53 0.81 130 290 1.4

14 4.8 32.5 11,000 2,400 17

15 0.83 1.14 180 530 9.6

15A 1.4 0.94 170 340 13

16 0.91 o. 96 210 190 0.10

17 0.49 o. 72 190 280 1.1

18 0.31 0.69 220 390 0.96

165 TABLEII-B-2 (CONTINUED)

STATION CADMIUM CHROMIUM LEAD MERCURY NICKEL ZINC

8 0.00 15 15 0.05 12 25

9 20 31 80 2.1 37 638

10 UNABLETO SAMPLE

11 9.8 108 176 1.1 25 245

12 5.9 83 754 o. 77 39 441

13 0.00 9.7 44 0.13 7.7 38

14 5.9 69 587 2.6 29 490

15 0.00 24 33 0.51 89 89

15A 0.00 27 59 0.48 69 54

16 0.00 19 19 0.16 7.7 62

17 0.00 13 18 0.10 2.8 36

18 0.00 17 43 0.06 12 42

166 TABLE II-C-1 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER SEDIMENTSAMPLING LOCATIONS MAY1977

NUMBER LOCATION MUNICIPALITY

19-CHOS Hartford Avenue Bellingham

20-CHOS Pond Street Medway

21-CHlO Walker Street Medway

22-CH12 Forest Road Millis

23-CHlS Bridge Street Dover

24-CH16 South Natick Dam South Natick

25-CH17 Central Street Needham

26-CH18 Chestnut Street Needham

27-CH19 Ames Street Dedham

28-CHZl Elliot Street Newton

167 SEDIMENT SAMPLING LOCATIONS

CHARLES RIVER BASIN

0 2 3 4 5

MILES

); BROOKLINE WELLESLEY Sa• MIii St. •,ioo,rn,

HOPl(INTON, Ee/Jo Lak, ( CMlor Swt,mp Pd.-- MILFORO WALPOLE HOPEOALE"

WRENTHAM ~IGURE I 168 TABLEII-C-2 DWPC- MAPC208 MONITORINGPROGRAM CHARLESRIVER SEDIMENTSAMPLING DATA (mg/1) MAY1977

% VOLATILE TOTAL TOTAL STATION COD (%) MATTER KJELDAHL-N PHOSPHORUS ARSENIC

19 1. 7 0.66 210 97 1.4

20 0.36 0.49 130 110 0.36

21 0.32 0.65 160 150 0.75

22 7.7 8.9 1,100 270 1.7

23 0. 70 0.87 190 120 0.48

24 15.5 15.2 3,200 880 1.9

25 3.9 5.1 1,300 630 1. 3

26 UNABLETO SAMPLE

27 0.42 0.78 210 400 0.77

28 6.9 7.4 1,600 860 4.8

169 TABLEII-C-2 (CONTINUED)

STATION CADMIUM CHROMIUM LEAD MERCURY NICKEL ZINC

19 0.00 4.3 10 0.01 0.00 13

20 0.00 7.3 7.0 0.09 0.00 20

21 0.00 7.5 23 0.03 0.00 26

22 0.00 69 46 0.57 6.5 175

23 o.oo 9.1 9.0 0.00 2.4 27

24 0.00 4.9 74 0.30 0.00 14

25 0.00 30 64 0.25 8.6 73

26 UNABLETO SAMPLE

27 0.00 16 77 0.10 6.2 50

28 0.00 53 155 0.49 12 145

170 TABLE II-D-1 DWPC- MAPC208 MONITORINGPROGRAM ASSABET& SUDBURYRIVERS & HOP BROOK SEDIMENTSAMPLING LOCATIONS

NUMBER STREAM LOCATION MUNICIPALITY

29-AS02 Assabet River Maynard Street Westborough 30-AS06 Assabet River School Street Northborough 31-AS09 Assabet River Boundary Street Northborough 32-ASlJ Assabet River Above Rte. 85 Dam Hudson 33-AS14 Assabet River Cox Street Hudson 34-AS15 Assabet River Above Rte. 62 Dam Stow 35-AS15A Assabet River Boone Road Stow 36-AS17 Assabet River Above Rtes. 62 - 117 Dam Maynard 37-AS19 Assabet River Above High Street Dam Acton 38-AS20 Assabet River Rte. 62 West Concord 39-AS22 Assabet River Rte. 2 Concord

40-SU05 Sudbury River Above Central Street Dam Framingham 41-SU07 Sudbury River Pelham Island Road Wayland 42-SU09 Sudbury River Rte. 117 Lincoln 43-SUlO Sudbury River Nashawtuc Road Concord

44-HP02 Hop Brook Outlet Hager Pond Marlborough 45-HP02A Hop Brook Old Boston Post Road Sudbury 46-HP03 Hop Brook French Road Sudbury 47-HP03A Hop Brook Outlet Stearns Mill Pond Sudbury 48-HP04 Hop Brook Landham Road Sudbury

171 SEDIMENT SAMPLING LOCATIONS

SUASCO RIVER BASIN

BILLERICA

Concord Rivar' LITTLETO~~-- ·--f- ---~ __/- [)J-eCTON80.XB~ROUGH/-- HARVARD

·---j ~6 37 STOW SOL TON ___J____ . / I Assobet {ry Rlvsr

BERLIN \WESTON BOYLSTON r·- 5. -(\~• I Coc//lfuafs , TICK SHREWS Y: SOUTHBOROUGH UGH'- / Sudbur~Rlvar~

I Nor I h !

-~ UPTON HOLLISTON 0 2 3 4 5

FIGURE J MILES 172 TABLEII-D-2 DWPC- MAPC208 MONITORINGPROGRAM ASSABET& SUDBURYRIVERS & HOP BROOK SEDIMENTSAMPLING DATA (mg/1) MAY1977

% VOLATILE TOTAL TOTAL STATION COD (%) MATTER KJELDAHL-N PHOSPHORUS ARSENIC 29 1.1 1.0 500 340 2.2 30 2.6 2.9 730 360 2.8 31 2.8 0.43 620 600 5.3 32 21. 7 22.3 7,900 2,200 14 33 0.40 0.53 120 140 2.6 34 31.6 31.9 4,800 3,000 26 35 2.8 8.8 700 300 2.1 36 32.1 45.6 8,200 1,500 20 37 26.6 33.5 4,900 2,000 16 38 6.2 16.1 290 620 21 39 0.70 1.8 290 430 2.0 40 15.9 13.0 4,000 1,200 16 41 7.8 12.7 1,200 390 14 42 28.4 29.4 2,400 1,600 11 43 6.8 10.7 960 290 6.8 44 0.93 0.86 290 190 5.4 45 1.8 0.67 190 130 0. 83 46 1.0 0.83 240 160 1. 9 47 39.9 38.6 7,600 3,300 22 48 1. 7 3.7 410 170 1.3

173 TABLEII-D-2 (CONTINUED)

STATION CADMIUM CHROMIUM LEAD MERCURY NICKEL ZINC 29 0.00 11 39 0.00 8.3 42 30 0.00 17 14 0.24 9.0 54 31 0.00 25 43 0.28 12 86 32 2.0 63 146 1.4 24 253 33 0.00 7.2 9.4 0.02 5.0 20 34 14 97 368 0.71 47 766 35 0.00 13 14 0.00 7.0 44 36 4.9 49 118 0.71 39 294 37 4. 7 678 754 1.9 38 707 38 0.00 219 95 3.7 19 67 39 0.00 25 18 0.14 8.0 35 40 14 106 389 6.9 48 387 41 0.00 24 43 0.59 10 67 42 7.0 70 129 2.6 25 348 43 0.00 19 30 0.37 7.5 57 44 0.00 12 17 0.08 20 61 45 0.00 6.0 13 0.03 6.0 45 46 0.00 13 14 0.02 11 47 47 2.9 19 106 0.35 19 241 48 0.00 6.0 12 0.03 4.5 34

174 BENTHICINVERTEBRATE SAMPLING DATA

175 MAPCWATER QUALITY SURVEY

During May 1977 a qualitative biological survey was conducted on the Assabet, Neponset, and Ipswich Rivers, The following stations were chosen for biological analysis: TABLEIII-A Assabet River

AS02 Maynard Street Westboro AS06 School Street Northboro AS14 Cox Street Hudson ASlS Route 62 Dam Gleasondale AS17 Routes 62 & 117 Dam Maynard AS19 Route 62 Acton/West Concord AS22 Route 2 West Concord

Neponset River

NEOl Neponset Reservoir Dam Foxboro NE02 Crackrock Pond Foxboro NE04 South Street Dam Walpole NEOS West Street Dam Walpole NE07 Bird Pond Dam Walpole NE08 Route 128 Norwood/Canton

Ipswich River

IP03 Park Street North Reading (Martin's Brook) IPOS B.B. Chemical Dam Middleton IP13 Willowdale Dam Topsfield IP14 Sylvania Dam Ipswich

At each station surface observations were made and the aquatic macrophyton, stream width and depth, and substrate types were recorded, Each substrate tYPe was sampled for its resident benthic macroinvertebrate community by employing the most appropriate piece of sampling gear.

This survey was~ designed for quantification buewas rather a qualita­ tive, or habitat, reconnaissance. For each station, a brief description of the sampling site and a list of invertebrates collected is given. A brief analysis of organisms response to existing water quality is also given.

It should be kept in mind that this survey was not conducted on an intensive basis and, therefore, the results should not be---;;;ed for anything other than a baseline approach.

176 LOCATION-OF BENTHIC INVERTEBRATESAMPLES·

'--, --­ ASSABET RIVER \CHELMSFORD ;•

BASIN BILLERICA

-Concord River

HARVARD

LINCOLN c&,.q~ --...__r WATERSHED LOCATION

-;:--_Sudburyr-1 River ' WAYLANb BERLIN \w·ESTON \ Lala _ Cochltuafs

\. , / - .., (' B.NATICK SOUTHBOROUGH------"' ' ~ WESTBOROUGH'\._ / ,_ I - Sudbur Rivu.J,,. -~-----

North ~-__J SHERBORN HOPKINTON \ ,.> -~ / •• HOLLISTON 0 2 3- 4 5 --MILES- -

FIGURE K 177 LOCATIONOF BENTHlCINVERTEBRATE SAMPLES

NEPONSET RIVER BASIN

BOSTON

>QUIN·cy Mother --l!niquity Brook

Tree ~ok \ MILTON ) - Neponset River,.

NORWOOD RANDOLPH Brook

MED

'-----Res:;voi r// Po~- --' 7 ··-- North \ _l

0 2. 3 4 5

MILES

FOXBOROUGH FIGURE L 178 LOCATIONOF BENTHICINVERTEBRATE SAMPLES

IPSWICH RIVER BASIN

NORTH AN !5ci'vE R

' ANDOVE '

isBr-----­ DY

0 2 3 4

MILES

FIGURE M 179 Each organism collected was assigned one of the three following organic pollution tolerance classifications based on a survey of the literature and upon field observations,

Tolerant (T) - organisms frequently associated with gross organic contamin­ ation and generally capable of thriving under partially anaerobic conditions.

Facultative (F) - organisms having a wide range of tolerance and frequently associated with moderate levels of organic contamination.

Intolerant (I) - organisms that are not found associated with even moderate levels of organic contaminates and generally intolerant of even mod­ erate reductions in dissolved oxygen.

*NOTE: At the request of MAPC, wherever possible sampling stations were located in impoundments. However, a few riffles were sampled, The differences between these two habitats are many; physical, chemical, and biological, Specific compari­ sons of benthic conmunities of the two habitats are very difficult. For this reason the physical description for each station should be kept in mind when the kinds and per­ centages of organisms are reported.

180 Station ASO2 was located on a stretch of the Assabet River approximately 15 feet wide with a maximwn depth of 6 inches. The substrate was mostly rubble, gravel, and sand the entire width. The stream flow was good with no visible signs of stress.

The dominate macrophytes were pickerelweed and sedge. These were restricted to the west bank as the east bank was completely shaded.

A total of 19 kinds of organisms were collected: 43% intolerant, 31% facultative, and 26% tolerant. Black flies and caddisflies, both in• tolerant kinds, were the dominant organisms. The station as a whole exhibited good diversity with the percentage of intolerant kinds indi­ cating a healthy benthic conununity and good water quality.

A ssabet River Maynard Street, Westborough 17 May 1977 TABLEIII-B-1

ORGANISM TOLERANCE Hirudinea (leeches) Glossiphonia complanata T Helobdella stagnalis T Erpobdella punctata T Isopoda (sow bugs) Asellus sp. F Odonata (dragonflies & damselflies) Calopteryx sp. I Hemiptera (true bugs) Corixidae sp. T Coleoptera (beetles) Dineutes ciliatus F Trichoptera (caddisflies) Hydropsychidae sp. I Cheumatopsyche sp. F Hydropsyche sp. I H. betteni I Diptera (true flies) Conchapelopia/Arctopelopia F Endochironomus sp. F Paratendipes sp. I Polwedilwn sp. F Calopsectra sp. I Simuliidae sp. I

T I

181 ORGANISM TOLERANCE

Gastropoda (anails & limpets) Helisoma sp. T Amnicola sp. I Total# Kinds:

Percentages: Tolerant 26% Facultative 31% Intolerant 43%

182 Not quite three miles downstream Station AS06 exhibited a marked change in appearance. The river became murky and emitted a septic odor. The width ranged from 10 to 35 feet and the depth fran 6 inches to 3 feet.

The macrophytes observed were pickerelweed and Salix sp., a member of the willow family.

Almost s reversal in the percentage distribution £ran AS02 occurred at this station. Only 12 kinds of organisms were collected here with 50% being tolerant types. Oligochaetes were by far the dominant organisms although intolerant black fly larvae were present. (Black fly larvae - Simuliidae­ have been classified as intolerant but field observations indicate that they inhabit a wide variety of conditions.)

Other than midges and black flies no aquatic insects were found. Only isopods, leeches, and shellfish were present in addition to the worms. This drastic change would indicste a possible source of organic pollution somewhere between AS02 and AS06.

Assabet River School Street, Northboro 17 May 1977 TABLEIII-B-2

ORGANISM TOLERANCE

Oligochaeta (aquatic earthworms) Ophidonais serpentine F Tubificidae sp. T Limnodrilus sp. T Tubifex tubifex T Hirudinea (leeches) Helobdella stagnalis T Isopoda (sow bugs) Asellus communis F Diptera (true flies) Chironomus sp. T Cricotopus sp. I Orthocladius sp. I Simuliidae sp. I Gastropoda (snails & limpets) Physa sp. T PelecYPoda (clams & mussels) Sphaerilllll sp. F

Total# Kinds: 12 Percentages: Tolerant 50% Facultative 25% Intolerant 25%

183 Station AS14 was located at Cox Street in Hudson. The river was approxi­ mately 50 feet wide with the west bank flooded over another 40-50 feet, The depth was a uniform 2-3 feet. Sand and muck comprised most of the substrate with some gravel and detritus. Other than the water being slightly colored, no visible signs of gross pollution were evident.

The mscrophytes were more diverse than at stations AS02 and AS06. Pickerel­ weed and cattails were the dominate emergents and submerged vegetation in• eluded coontail, grasses, and Salix sp,

A total of 38 kinds of organisms were collected here with many intolerant mayflies, damselflies, and midges present which were absent at the above stream stations. Although the percentage of intolerant kinds did not change from AS06 (25%), the number of intolerant kinds more than tripled (10).

The percentages - 25% intolerant, 46% facultative, and 29% tolerant - along with the increase in the total number of kinds (38) indicates a shift toward recovery from the stressed condition at the previous station,

Assabet River• Station AS14 Cox Street, Hudson 17 May 1977 TABLEIII-B-3 ORGANISM TOLERANCE

Platyhelminthes (flatworms) Planaria sp, F Oligochaeta (aquatic earthworms) Stylaria fossularis F Hirudinea (leeches) Glossiphonia complanata T Helobdella stagnalis T Erpobdella sp. T Percymoorenis sp. T Amphipoda (scuds) Hyalella azteca F Ganmarus sp. F Ephemeropters (tl\llyflies} Baetis sp. I Stenonema rubrum I Ephemerellidae sp. I Ephemerella simplex I Caenis sp. F Odonata (dragonflies & damselflies) Perithemis sp. F Argia sp. I Enallagma sp. F Ischnura sp. F

184 ORGANISM TOLERANCE

Hemiptera (true bugs) Plea striola T Gerrie sp. T Coleoptera (beetles) Peltodytes edentulus F/T Bidessus sp. T Hydrochus sp. T Trichoptera (caddisflies) Cheumatopsyche sp. F Diptera (true flies) Chironcmus sp. T Dicrotendipes sp. F Rheotanytarsus sp. F Cricotopus sp. I Eukiefferiella sp. I Orthocladius sp. I Psectrocladius sp. I Simuliidae sp. I Odontomyia sp. F Gastropoda (snails & limpets) Physa sp. T Gyraulus sp • F Heliscma sp. T Campeloma sp. F Amnicola limosa I Pelecypoda (clams & mussels) Sphaerium securis/partumeium Total# Kinds: 38 Percentages: Tolerant 29% Facultative 46% Intolerant 25%

185 Station AS15 was located above the dam at Route 62 in Gleasondale. River width was 40 feet and maximum depth was 8 feet at mid-channel. The sub­ strate consisted of muck and detritus along both shorelines but the center channel had been scoured. No signs of gross pollution were observed but the water still retained some color,

Cattails, grasses, and sedge remained the dominant macrophytes. Duckweed lined both shorelines and has been noted as a problem in the past.

The percentages recorded here - 23% tolerant, 60 % facultative, and 17% intolerant - were very similar to the previous station (AS14) with a definite dominance of facultative kinds. The organisms collected showed little change in the response to the water quality, The intolerant may­ flies, midges, and black flies found here were the same kinds as at AS14.

Assabet River - Station AS15 Route 62 Dam, Gleasondale 17 May 1977

TABLEIII-B-4

ORGANISM TOLERANCE Oligochaeta (aquatic earthworms) Stylaria fossularis F S. lacustris F l{i:i7"udinea (leeches) Glossiphonia complanata T G. heteroclita T Erpobdellidae sp, T Dina sp • T Mooreobdella sp. T Isopoda (sow bugs) Asellus conmunis F Amphipods (scuds) F Ryalella azteca F Crangonyx obl~quus/richmondensis Ephemeroptera (mayflies) Stenonema rubrum I Ephemerella sp, .I/F Caenis sp. F Odonata (dragonflies & damselflies) Pachydiplax longipennis F Erythemis simplicicollis F Enallagma Sp. F Ischnura sp, F

186 ORGANISM TOLERANCE

Hemipetera (true bugs) Plea striola T Coleoptera {beetles) Peltodytes edentulus F/T Psephenus sp. I Diptera (true flies) CeratOl)ogonidae sp. F Guttipelopia sp. F Procladius sp. F Dicrotendipes sp. F Rheotanytarsus sp. F Orthocladiinae sp. I Cricotopus sp , I Simulliidae sp. I Gastropoda (snails & limpets) Physa sp. T Gyraulus sp. F Helisoma sp. T Pr0111enetus sp • F Amnicola limosa I Pelecypoda (clams & mussels) Pisidimn sp. F Sphaerimn partumeium F s. securis F

Total# Kinds: 35 Percentages: Tolerant 23% Facultative 60% Intolerant 17%

187 Above the dam at the intersection of Routes 62 and 117 in Maynard was the location of Station AS17. The river was approximately 150 feet wide but widened to a maximum of 300 feet about 50 feet above the dam before narrowing back to 150 feet again, Maximumdepth was 5 feet, Both banks consisted of muck and the center channel of sand and gravel, Surface observations revealed more water color than at Stations AS14 and AS15, Oil was observed on the surface and in the sediment. The macrophytes along the shoreline consisted of pickerelweed and sedge with milfoil the daninant submerged vegetation.

A total of 16 kinds of organisms were collected here, Of the 16 only one intolerant mayfly (Siphlonurus sp.) was found. There were, however, other mayflies and midges present but all of facultative tolerance.

Again, facultative organisms were daninate, accounting for 75% of the total. This increase of facultative types and the near absence of intolerant types indicated a slight drop in response to the water quality which would be expected in an impoundment of this type. Assabet River - Station AS17 Routes 62 & 117 Dam, Maynard 17 May 1977 TABLEIII•B-5 ORGANISM TOLERANCE Hirudinea (leeches) Helobdella stagnalis T Isopoda (sow bugs) Asellus connnunis F Amphipoda (scuds) Hyalella azteca F Ephemeroptera (mayflies) Siphlonurus sp. I Callibaetis sp. F Caenis sp. F Odonata (dragonflies & damselflies) Tetragoneuria sp. F Libellula luctosa F Pachydiplax longipennis F Lestes vigilax F Ischnura sp • F Diptera (true flies) Conchapelopia/Arctopelopia F Polypedilum sp. F

188 ORGANISM TOLERANCE

Gastropoda (snails & limpets) Physa sp. T Helisoma sp. T campeloma sp. F Total# Kinds: 16

Percentages:

Tolerant 19% Facultative 75% Intolerant 6%

189 Station AS19 was located at Route 62 on the Acton/West Concord line. The river was approximately 30 feet wide and the depth varied from one to two feet. The substrate consisted of sand, gravel, and rock with some muck on the shorelines. Riffle areas and overall good flm,1 characterized this station. No visible signs of gross pollution were evident.

Pickerelweed was the dominant emergent macnophyte on both shorelines. Sub­ merged vegetation included Elodea sp. and Crispus sp. along with some filamentous green algae.

A positive benthic response to the water quality here was indicated by the abundance of intolerant mayflies, midges, and black flies. While the tol­ erant and facultative kinds remained the same or declined in nU111bersand percentages, the intolerant kinds rose considerably from 6% to 30% of the total number collected. In the three river miles downstream from the previous station, the benthic conmunity showed a marked recovery frmm the stressed condition at AS17.

Assabet River - Station AS19 Route 62, Acton/West Concord 25 May 1977 TABLEIII-B-6

ORGANISM TOLERANCE Platyhelminthes (flatworms) Planaria sp. F Hirudinea {leeches) Erpobdella punctata T Mooreobdella sp. T Amphipoda (scuds) Crangonyx obliguus/richmondensis F Ephemeroptera (msyflies) Baetis sp. I Stenonema heterotarsale I §_. rubrum I Ephemerella attentuata I/F ~• simplex F Odonata (dragonflies & damselflies) Basiaeschna 1~ F Libellula luctosa F Pachydiplax longipennis F Argia sp. I Enallagma sp. F E. exsulans F !• hageni/ebrium group F Ischnura sp. F

190 ORGANISM TOLERANCE

Hemiptera (true bugs) Gerris sp. T Trichoptera (caddisflies) Che11111Stopsychesp. F Hydropsyche sp • I Diptera (true flies) Cardiocladius sp. I Simuliidae sp, I Gastropoda (snails & limpets) Campeloma sp. F

Total# Kinds: 23

Percentages: Tolerant 13% Facultative 57% Intolerant 30%

191 Station AS22 was located at the end of Assabet Avenue in West Concord. The river was 40 feet wide with a nearly uniform depth of four feet, The substrate consisted of sand and gravel the entire width. A moderate to good flow with no visible signs of gross pollution was obseived though the water was dark.

Other than low growing shrubs and grasses on the shorelines, no aquatic macrophytes were observed.

Again intolerant mayflies, midges, and blackflies were present and the n1.1111berof tolerant kinds was low (two). The only noticeable change was a rise in the n1.1111berof facultative kinds. Though the physical charac­ teristics of this and the previous station were very different (riffle areas opposed to channeled), a comparison of the two benthic communities would indicate very little change in the water quality. Assabet River - Station AS22 Assabet Avenue, West Concord 19 May 1977 TABLEIII-B-7

ORGANISM TOLERANCE Oligochaeta (aquatic earthworms) Stylaria fossularis F Amphipoda (scuds) Hyalella azteca F Crangonyx sp • F Ephemeroptera (mayflies) Siphlonurus sp. I Ephemerella temporalis I/F Odonata (dragonflies & damselflies) Coenagrionidae Sp. F Enallagma signat1.1111 F ] • ha genii ebrium group F Ischnura verticalis F Lestes sp. F Hemiptera (true bugs) Notonecta sp. T Plea striola T Coleoptera (beetles) Haliplus sp. F Trichoptera (caddisflies) Chemnatopsyche sp. J' Oecetis sp. F

192 ORGANISM TOLERANCE

Diptera (true flies) Tipuls sp. I Ceratopogonidae sp. F Ablabesmyia mallochi I Conchapelopia/Arctopelopia F Pentaneurinae sp. F Dicrotendipes sp. F Polzyedil\DII sp. F Psectrocladius sp. I Odontomyia sp. F S:&muliidae sp. I Hydracarina (water mites) I Gastropoda (snails & limpets) Lymnaea sp. F Gyraulus sp • F

T6tal # Kinds: 28

Percentages:

Tolerant 7% Facultative 71% Intolerant 22%

193 Station NEOl was located at a riffle area just below the Neponset Reservoir Dam. This small riffle, 15' long and 10' wide, fed a channel which wound its way through a large marsh. Sand and gravel comprised the substrate of the riffle. There was good flow through the riffle and the water level was high in the surrounding marsh. No signs of gross pollution were evident.

Cattail was definately the dominate emergent macrophyte with some pickerel­ weed along the shorelines. Submerged vegetation included coontail and milfoil. Duckweed and yellow water lilies were observed as the floating types present. All the vegetation present in the marsh area was at least moderate; most abundant.

The heavy population and good diversity at this station pointed to a healthy benthic cOlllllunity. Though facultative (52%) and tolerant (l'.J%) organisms together accounted for 82% of the kinds found, intolerant midges, elmid beetles (Stenelmis sp.), one csddisfly (Hydropsyche betteni), and one amnicolid snail found indicated that the water was able to support sensi­ tive organisms. However, no "clean water" mayflies or stoneflies were found. Generally, Station NEOl exhibited a good response to the water quality.

Neponset River - Station NEOl Outlet of Neponset Reservoir, Foxboro 18 May 1977 TABLE111-C-1 ORGANISM TOLERANCE

Platyhelminthes (flatworms) Planaria sp. F Hirudinea (leeches) Helobdella stagnalis T Isopoda (sow bugs) Asellus communis F Amphipoda (scuds) Hyalella azteca F Decapoda (crayfishes & shrimps) Orconectes sp. F Ephemeroptera (mayflies) Csenis sp. F Odonats (dragonflies & damselflies) Pachydiplax longipennis F Libellula sp. F Lestes rectangularis F lschnura verticalis F

194 ORGANISM TOLERANCE

Hemiptera (true bugs) Notonecta sp. T Gerridae sp. T Gerris sp, T Coleoptera (beetles) Hydrovatus sp. T Tropisternus sp. T Stenelmis sp. I Onychylis sp. T Trichoptera (caddisflies) Cheumatopsyche sp. F Hydropsyche betteni I Diptera (true flies) Ceratopogonidae sp. F Endochironomus sp. F GlYptotendipes sp. T PolYpedilum sp. F Cricotopus sp. I Psectrocladius sp. I Simuliidae sp. I Odontomyia sp. F Gastropoda (snails & limpets) Physa sp. T Lymnaea (Pseudosuccinea) sp. F Helisoma sp. T Ferriss is sp. F ilmnicola sp. I Pelecypoda (clsms & mussels) Pisidium sp. F

Tota 1 if Kinds: 33

Percentages:

Tolerant 30% Facultative 52% Intolerant 18%

195 Above the dam at Crackrock Pond was the location of Station NE02, This small pond was approximately 50 feet wide with a depth of four feet, The substrate was muck, from shoreline to shoreline, and was heavy with oil, Only moderate flow was noted.

A heavy growth of grasses lined the shorelines, with some pickerelweed and wild iria mixed in. The submerged vegetation was very abundant with coontail and filamentous green algae. Duckweed covered much of the peri­ meter of the pond.

A negative benthic response to the water quality occurred at Station NE02. Tolerant organisms became the dominant kinds accounting for 52% of the number of kinds found. Beetles, leeches, snails, and worms were the represen­ tative tolerant kinds. Only a few intolerant midges and amnicolid snails were found.

The lack of "clean water" ocganisms, the dominance of the tolerants, and the presence of oil in the sediment and on the shoreline indicated a con­ dition of stress. The benthic c0111Dunitydefinately showed an adverse response to the water quality at this station.

Neponset River - Station NE02 Crackrock Pond, Foxboro 26 May 1977 TABLE III·C-2

ORGANISM TOLERANCE

Oligochaeta (aquatic earthworms) Lumbriculidae sp. T Limnodrilus hoffmeisteri T Hirudinea (leeches) Helobdella stagnalis T Mooreobdella sp. T Isopoda (sow bugs) Asellus c0111Dunis F Amphipoda (scuds) Hyalella azteca F Ephemeroptera (mayflies) Caenis sp. F Odonata (dragonflies & damselflies) Pachydiplax longipennis F Lestes sp, F Hemiptera (true bugs) Plea Striola T Coleoptera (beetles) Agabus sp. T Celina sp. F

196 ORGANISM TOLERANCE

Coptotomue sp. T Or eodytee sp. T Hydroporus sp. T Scirtes ep. T Hydrophilidae sp. T Enochrus sp • T Tropistemus sp, T Onychylis sp. T Diptera (true flies) Ceratopogonidae sp. F Ablabesmyia sp. I ! . junta I Chironomus sp. T Crvptochironomus sp. T Endochironomus sp. F Glvptotendipes sp. T Polvpedilwn sp. F Cricotopus sp. I Psectrocladius sp. I Gastropoda (snails & limpets) Physa sp. T Gyraulus sp. F Amnicola sp. I Pelecypoda (clams & mussels) Pisidium sp. F Sphaerium partumeiwn F S, securis F

Total# Kinds: 36

Percentages:

Tolerant 53% Facultative 33% Intolerant 14%

197 Station NE04 was located above the dam at South Street in Walpole. The river was 30 feet wide and three feet deep. Muck and detritus comprised the substrate and banks. The flow was moderate and the water appeared dark.

Both banks were shaded but sunny spots were abundant with pickerelweed. Floating water lilies and duckweed were also observed.

A good recovery from the stressed conditions at NE02 was noted at this station. A marked increase in both the facultative and intolerant kinds coupled with a sharp drop in the tolerant kinds indicated a much better response to the water quality.

The diversity at this station was also encouraging. The whole range of macroinvertebrates was covered; from stoneflies and mayflies to snails and oligochaetes. The midge population characterized this diversity with eigh­ teen different genera collected. The tolerance distribution of the midges was not too different from the benthic couununity as a whole. overall, the benthic community exhibited a diverse, healthy response to the water quality.

Neponset River - Station NE04 South Street, Walpole 18 May 1977 TABLE III-C-3

ORGANISM TOLERANCE Nematoda (nematodes) F Oligochaeta (aquatic earthworms) Limnodrilus claparedianus T 1• hoffmeisteri T Isopoda (sow bugs) Asellus communis F Amphipoda (scuds) Hyalella azteca F Decapoda (crayfishes & shrimps) Astacidae sp. F Ephemeroptera (mayflies) Caenis sp. F Odonata (dragonflies & damselflies) Dromogomphus spinosus F Tetragoneuria sp. F Ischnura verticalis F Plecoptera (stoneflies) Perlesta placida I Hemiptera (true bugs) Corixidae sp. T Plea striola T Coleoptera (beetles) Peltodytes sp. F/T

lM ORGANISM TOLERANCE Trichoptera (caddisflies) Polycentropus sp. I Cheumatopsyche sp, F Hydropsyche sp. I Limnephilus sp. I Oecetis sp. F Diptera (true flies) Ceratopogonidae sp. F Clinotanvpus sp. F Conchapelopia/Arctopelopia Sp, F Guttipelopia sp. F Procladius sp, F Crvptochironomus T Dicrotendipes sp. F Cryptotendipes sp. Endochironomus sp. F Glyptotendipes sp. T Polypedilum sp. F P. fallax F Calopsectra sp. T Cladotanytarsus sp. F Potthastia sp, I Cricotopus sp. I Eukiefferiella sp. I Orthocladius sp. I Psectrocladius sp. I Hydracarina (water mites) I Gastropoda (snails & limpets) Physa sp. T Stagnicola sp. F Gyraulus sp. F Helisoma sp. T Campeloma sp. F PelecYPoda (clams & mussels) Sphaerium partumeium F

Total /f Kinds: 45

Percentages:

Tolerant 23% Facultative 54$, Intolerant 23%

199 Above the dam on West Street in Walpole was the site of Station NE05. The river was approximately 35 to 40 feet wide and three feet deep. The sub­ strate consisted of muck and detritus which was heavy with oil and a strong hydrogen sulfide (H2S) smell. Oil was observed floating on the surface as well. (A large parking lot was situated on the west bank.) The flow was slow to moderate.

Pickerelweed was moderate along the east bank. A few water lilies were observed amidst an abundance of filamentous green algae.

A sparce benthic population was recorded at this station. Only 16 kinds were collected here as opposed to 33, 36, and 45 at the previous three stations respectively. Of the 16 kinds collected, oaly one intolerant midge was found. A drop in the percentage of intolerant organisms (6%) and a rise in both the facultative (69%) and tolerant (25%) kinds further indicated a decline in the benthic response to the water quality.

Neponset River - Station NE05 West Street, Walpole 18 May 1977 TABLEIII-C-4

ORGANISM TOLERANCE

Oligochaeta (aquatic earthworms) Tubificidae sp. T Isopoda (sow bugs) Asellus conmunis F Amphipoda (scuds) Hyalella azteca F Odonata (dragonflies & damselflies) Plathemis sp. F Coenagrionidae sp. F Ischnura sp. F Coleoptera (beetles) Haliplus sp. F Peltodytes endentulus F/T Hydroporus sp, T Dactylosternum sp, T Diptera (true flies) Ceratopogonidae sp. F PolYpedilum sp. F Cladotanytarsus sp. F Cricotopus sp. I

200 ORGANISM TOLERANCE

Gastropoda (snails & limpets) Gyraulus sp. F Pelecypoda (clams & mussels) Piaidium sp. F

Total# Kinds: 16

Percentages:

Tolerant 25% Facultative 69% Intolerant 6%

201 Station NE07 was located above the Bird Pond Dam in Walpole. The pond was approximately 300 feet wide with a depth of three to eight feet. The sub­ strate was mostly muck with sand along the shorelines, Again the water appeared dark and oil was observed on the surface, The flow was slow to moderate,

Pickerelweed and Wild Iris growing on the shorelines were the only macro­ phytes observed.

As at NE05, only 16 kinds of organisms were collected here. However, the percentage distribution improved slightly. Intolerant kinds accounted for 25% of the total with both the facultative (56%) and tolerant (19%) kinds declining. The relatively low number of kinds and the more favorable percentages indicated a slight improvement in the benthic response to the water quality.

Neponset River - Station NE07 Bird Pond Dam, Walpole 18 May 1977 TABLE III-C-5

ORGANISM TOLERANCE

Oligochaeta (aquatic earthworms) Tubificidae sp. T Hirudinea (leeches) Helobdella stagnalis T Mooreobdella sp, T Isopoda (sow bugs) Asellus sp. F Ephemeroptera (mayflies) Caenis sp, F Odonata (dragonflies & damselflies) Coenagrionidae sp. F Argia sp, I Ischnura sp. F Diptera (true flies) Ceratopogonidae sp. F PolYpedilum sp, F Cricotopus sp. I Psectrocladius sp. I Gastropoda (snails & limpets) Ferrissia sp. F Amnicola sp. I

20:l! ORGANISM TOLERANCE

Pelecypoda (clams & mussels) Pisidium sp , F Sphaerium sp, F Total# Kinds: 16

Percentages:

Tolerant 19% Facultative 56% Intolerant 25%

203 Station NE08 was located off Canton Street near Route 128 on the Norwood, Dedham, Canton line, The river was 30 feet wide with a depth of four feet. The substrate was primarily detritus with some sand. Again the substrate contained a large amount of oil and the flow was slow to moderate.

Only a few sedges were observed along the shorelines.

What little benthic improvement was noted at NE07, disappeared at NE08. Percentages of both intolerant (15%) and facultative (39o/J kinds declined while the tolerant kinds rose to 40% of the total. The total ntanber of kinds collected dropped to 15, the lowest of any of the stations. overall, this station exhibited a poor response to the water quality.

Neponset Rfver - Station NE08 Canton Street (near Route 128), Canton/Norwood 18 May 1977 TABLEIII-C-6

ORGANISM TOLERANCE

Hirudinea (leeches) Helobdella elongata T Amphipoda (scuds) Gamnarus sp. F Ephemeroptera (mayflies) Ephemerella temporalis I/F Odonata (dragonflies & damselflies) Basiaeschna sp. F Boyeria sp, F Ischnura sp. F Calopteryx sp. I Hemiptera (true bugs) Corixidae sp. T Coleoptera (beetles) Peltodytes endentulus F/T Berosus sp, T Diptera (true flies) Cricotopus sp. I Gastropoda (snails & limpets) Physa sp, T Lymnaea (Pseudosuccinea) sp. F Helisoma sp. T

204 ORISIINISM TOLERANCE

Pelecypoda (clams & mussels) Sphaeritllll sp, F

Total #ft Kinds: 15

Percentages:

Tolerant 40% Facultative 47% Intolerant 13%

205 Station Ip03 was located on Martin's Brook at Park Street in North Reading. The brook was 10 feet wide and approximately two feet deep. The substrate consisted of sand, gravel, and rock. The water exhibited a very dark color. The flow was moderate to fast. Pickerelweed was the dominant emergent macrophyte. The submerged vegetation included coontail and mosses.

A very diverse benthic c00Dllunity was found at this station. The snail population reflected this condition as representatives of all three tol­ erance groups were collected. Intolerant mayflies, stoneflies, midges, caddisflies, and black flies were also collected. In addition, the per­ centages of kinds collected (25% Tolerant, 40% Facultative, and 35% In­ tolerant) furoher indicated a healthy comnunity and a very good response to the water quality.

Ipswich River - Ip03 Park Street, North Reading 20 May 1977 TABLEIll-D-1

ORGANISM TOLERANCE

Oligochaeta (aquatic earthworms) Tubificidae sp. T Hirudinea (leeches) Helobdella stagnalis T Placobdella ornata T Isopoda (sow bugs) Asellus sp, F Amphipoda (scuds) GallllllSrus sp. F Ephemeroptera (mayflies) Baetis sp. I Plecoptera (stoneflies) Perlesta placida I Trichoptera (caddisflies) Limnephilus sp. I Diptera (true flies) Conchapelopia/Arctopelopia sp. F Cryptochironomus sp. T Orthocladiinae sp. I Cricotopus sp. I Simuliidae sp. I

206 ORGANISM TOLERANCE

Gastropoda (snails & limpets) Physa sp. T Lymnaea sp. F Gyraulus sp • F Amnic.,la sp. I

Pelecypoda (clams) Pisidium Sp. F Sphaerium sp. F §.. partumeium

Total# Kinds: 20

Percentages:

Tolerant 25% Facultative 40% Intolerant 35%

207 Station Ip05 was located just above the dam at the B,B. Chemical Company in Middleton. The river was approximately 30 feet wide with a maximlllll depth of five feet. The substrate was sand, gravel, and rock, Other than the same dark color of the water, no visible signs of pollution were observed, The flow was good.

Again pickerelweed was the dominate emergent and milfoil, starwort, and grasses comprised most of the submerged vegetation.

Much less diversity and a lack of clean water mayflies, stoneflies, and black flies indicated a condition of stress at this station. Snails, leeches (which feed on snails), odonates, and amphipods were the dominate organ:sms; all tolerant or facultative kinds. The only intolerants found were one genus of snails and three genera of midges living in the vegeta­ tion,

Ipswich River - Ip05 B.B, Chemical Company Dam, Middleton 20 May 1977 TABLEIII-D-2 ORGANISM TOLERANCE Platyhelminthes (flatworms) Planaria sp, F Oligochaeta (aquatic earthworms) Stylaria la custris F Hirudinea (leeches) Glossiphoniidae sp. T Glossiphonia heteroclita T Helobdella sp. T Isopoda (sow bugs) Asellus camnunis F Amphipoda (scuds) Hyalella azteca F Gsmmarus sp. F Ephemeroptera (mayflies) caenis sp. F Odonata (dragonflies & damselflies) Libellulidae sp. F Coenagrionidae sp, F Enallagma signatum F Diptera (true flies) Chironomus sp. T CrYPtochironomus sp. T GlyPtotendipes sp. T Parachironomus sp. F Calopsectra sp. I Paratanytarsus sp. y. Cricotopus sp. I Psectrocladius sp. I 208 ORGANISM TOLERANCE

Gastropoda (snails & limpets) Physa sp. T Lymnaea sp. F Gyraulus sp • F Helisoma sp. T Amnicola sp. I Pelecypoda (clams & mussels) Pisidi1m1 sp. F

Total# Kinds: 26

Percentages:

Tolerant 27% Facultative 54% Intolerant 19%

209 Station Ipl3 was located abOV!ethe Willowdale Dam in Topsfield. The river was approximately 50 feet wide with a msximum depth of five feet, The substrste was mostly sand and gravel covered with vegetation, Again there was good flow and the water appeared very dark,

Thick vegetation lined both shorelines and submerged vegetation extended across the entire width of the river. Pickerelweed was again the dominant emergent. Submerged vegetation included pondweed, Elodea sp., milfoil, and filamentous green algae. Floating watershield, water lilies, and duckweed were abundant also,

Only six kinds of organisms were collected st this station, which is too few to draw any valid conclusions.

The thick vegetation in the river made it very difficult to get a good dredge sample, The few organisms collected were picked from the vegetation not the sediment, Many tolerant adult water striders (Gerris sp,) and whirligig beetles (Gyrinidae sp.) along with facultative adult damselflies (Aeshnidae sp,) were observed on the surface, Generally, the water quality appeared unchanged from the previous station and the lack of benthic or­ ganisms found cannot be readily explained.

Ipswich River - Ipl3 Willowdale Dam, Topsfield 20 May 1977 TABLEIII-D-3 ORGANISM TOLERANCE

Isopoda (sow bugs) Asellus communis F Amphipoda (scuds) Gammarus sp • F Neuroptera (spongilla flies) Climscia Sp. I Gastropoda (snails & limpets) Amnicola sp. I Pelecypoda (clams & mussels) Pisidium sp, F Sphaerium sp. F

Total# Kinds: 6

Percentages:

Facultative 67% Intolerant 33%

210 Station Ipl4 was located above Sylvania Dam in Ipswich. The river was 40 feet wide with a maximum depth of seven feet. The substrate consisted of muck and sand. The water was still very dark with good flow.

Pickerelweed was still the dominant emergent macrophyte with some water willow along both shorelines. The submerged vegetation consisted of pond­ weed, Elodea sp., and filamentous green algae.

The benthic community at this station was vecy similar to that at station Ip03. A repopulation of intolerant mayflies, damselflies, and black flies was observed which had been absent at the two previous stations {Ip05 & Ipl3). This would indicate a slight improvement in the response.to the water quality.

Overall, the benthic response was good at station Ip03 but quickly showed a downward shift at stations 1p05 and 1pl3. Station 1pl4 revealed a slight benthic recovery, possibly indicating a better response to the water quality than at 1p05 or Ip13.

Ipswich River - Station Ipl4 Sylvania Dam, Ipswich 20 May 1977 TABLEIII-D-4 ORGANISM TOLERANCE

Hirudinea (leeches) Glossiphonia heteroclita T Isopoda (sow bugs) Asellus cmmnunis F Amphipoda (scuds) Hyalella azteca F Gammarus sp. F Ephemeroptera (mayflies) Baetis sp. 1 B. fro111dalis I Od-;;°nata (dragonflies & damselflies) Calopteryx sp. I Enallagma sp • F E. signatum F ]• hageni/ebritm group F Hemiptera (true bugs) Palmacorixa sp. T Diptera (true flies) Conchapelopia/Arctopelopia sp. F Cryptochironomus sp. T Polypedilum sp. F Cricotopus sp. I Simuliidae sp. 1

211 ORGANISM TOLERANCE

Gastropoda (snails & limpets) Gyraulus sp, F Amnicola sp. I

Total# Kinds: 18

Percentages:

Tolerant 17% Facultative 50% Intolerant 33%

212 MARBLEHEADHARBOR SURVEY DATA

213 TABLEIV-A-1 MARBLEHEADHARBOR SURVEY LOCATIONOF SAMPLINGSTATIONS AUGUST14 - 15, 1977

STATION LOCATIONDESCRIPTION

1 Mid-channel between Fort Sewell and the Corinthian Yacht Club

2 100' offshore from Crocker Park

3 Inner Harbor at buoy X315

214 LOCATIONOF SAMPLING STATIONS MARBLEHEAD HARBOR SURVEY

SALEM HARBOR

t7 0 o MARBLEHEAD G)

MARBLEHEAD () 0 HARBOR ✓~ MARBLEHEAD NECK G)

DEVEREUX ~~ 'I\ Storm Water / Dverllow

FLYING POINT

FIGURE N 215 TABLE IV-A--2 MARBLEHEADHARBOR SURVEY TOTALAND FECAL COLIFORMBACTERIA DATA (per 100 ml) AUGUST14 - 15, 1977

Station 1

SURFACE BOTTOM DATE/TIME TOTAL FECAL TOTAL FECAL 14 Aug/1000 <10 <10 < 10 < 10 14 Aug/llOO <10 <10 200 <10 14 Aug/1200 200 <10 200 <10 14 Aug/1300 <10 <10 <10 < 10 14 Aug/1400 <10 <10 <10 <10 14 Aug/1500 100 <10 <10 <10 14 Aug/1600 20 <10 120 10 14 Aug/1700 10 10 30 <10 14 Aug/1800 40 <10 320 10 14 Aug/1900 40 <10 80 20 14 Aug/2000 20 <10 40 10 14 Aug/2100 10 <10 30 <10 14 Aug/2200 20 <10 150 <10 14 Aug/2300 10 <10 llO <10 14 Aug/2400 20 <10 10 <10

15 Aug/0100 20 <10 50 <10 15 Aug/0200 30 <10 20 <10

216 TABLE IV-A-2 (CONTINUED)

Station 1 (Continued)

SURFACE BOTTOM DATE/TIME TOTAL FECAL TOTAL FECAL 15 Aug/0300 40 10 <10 <5 15 Aug/0400 40 10 60 5 15 Aug/0500 70 5 60 <5 15 Aug/0600 40 5 <10 <5 15 Aug/0700 120 20 10 5 15 Aug/0800 40 10 90 50 15 Aug/0900 30 5 60 20 15 Aug/1000 20 <5 170 <5 15 Aug/llOO 300 30 70 5 15 Aug/1200 160 30 200 <5 15 Aug/1300 400 5 130 5 15 Aug/1400 50 10 120 20

217 TABLE IV-A-3 MARLBEHEADHARBOR SURVEY TOTALAND FECAL COLIFORMBACTERIA DATA (per 100 ml) AUGUST14 - 15, 1977

Station 2

SURFACE BOTTOM DATE/TIME TOTAL FECAL TOTAL FECAL 14 Aug/1000 50 <10 40 <10 14 Aug/1400 100 <10 100 <10 14 Aug/2000 240 30 20 <10 15 Aug/0200 120 10 60 10 15 Aug/0800 60 10 110 <5

15 Aug/1400 <10 <. 5 80 <5

Station 3

14 Aug/1000 20 10 <10 <10 14 Aug/1400 <10 <10 300 120 14 Aug/2000 40 20 80 40 15 Aug/0200 100 <10 70 10 15 Aug/0800 30 5 60 5 15 Aug/1400 10 <5 10 <5

Stormwater Effluent

14 Aug/1500 30,000 8,000

SESD Effluent Area

14 Aug/1500 2,000,000 200,000

218 TABLE IV-A-4 MARBLEHEADHARBOR SURVEY CHEMICALDATA (mg/1) AUGUST14 - 15, 1977

Station 1

AMMONIA NITRATE TOTALPHOSPHORUS MERCURY OIL & GREASE DATE/TIME SURFACE BOTTOM SURFACE BOTTOM SURFACE BOTTOM SURFACE BOTTOM SURFACE 14 Aug/1400 0.00 0.02 0.0 0.0 0.16 0.17 0.0001 0.0001 0.30 14 Aug/2000 0.00 0.01 0.0 0.0 0.13 0.12 0,0003 0,00 15 Aug/0200 0.00 0.01 0.0 0.0 0.12 0.16 0.0000 0.0010 0.50 15 Aug/0800 0.00 0.04 0.0 0.0 0.15 0.18 0.0000 0.0000 0.00 15 Aug/1400 0.09 0.11 0.0 0.0 0.09 0.21 0.0000 0,0000 0.60 ,...N '° Station 2

15 Aug/0200 0.01 0.02 0.0 0.0 0.21 0.19 0.0000 0.0000 0.10

Station 3

15 Aug/0200 0,00 0.08 0.0 0.0 0.14 o. 18 0.0000 0.0000 0.30

Storm Water Effluent

14 Aug/ 1500 0.35 0.6 0.43 0.0032

SESD Effluent Area

14 Aug/1500 1.8 0.0 1.4 0.0000 MEASURESOF WATERPOLLUTION

The term 'water pollution' has acquired many connotations. Literally, the word 'pollute' means 'render impure'; thus, in this sense, any water con­ taining matter other than its chemical constituents of two parts hydrogen to one part oxygen would be considered polluted. Such 'pure' water, however, is never found in natural bodies; the ecological balance in a waterbody is dependent upon the presence of other material. In this report, water pollution refers to a condition which is in contravention of the Water Quality Standards. Pollution degrades the physical, chemical and bacterial quality of a waterbody and can make it unsightly, malodorous, and a health hazard. Pollu­ tion occurs mainly through the discharge of wastes from homes and industries. The various types of pol ution are: 1) oxygen-demanding, such as originates from domestic sewage and certain industrial wastes; 2) toxic materials as in some industrial wastes; 3) radioactive wastes; 4) thermal; 5) bacterial; 6) oil; and 7) physical. Stormwater runoff from both urban and rural areas can also add pollutants to a waterbody.

The extent of pollution in a particular waterbody is determined by measuring certain chemical and biological constituents and properties. Chemical con­ stituents, such as dissolved oxygen, phosphates and metals, are generally measured in milligrams per liter (mg/1); since the unit weight of water,is 1.0 grams per milliliter, milligrams per liter are roughly equivalent to parts per million for a solution which is mostly water.

Dissolved Oxygen (D.O.) refers to the uncombined oxygen in water which is available to aquatic life. Since this oxygen is consumed more rapidly in the decomposition of wastes, the D.O. gives an instantaneous picture of the condition of a waterbody. Time of day and temperature of the water are important in interpreting D.O, levels. Temperature affects the amount of oxygen which water can contain. Time of day is related to the effeats of algae. Algae consume oxygen through respiration throughout the day and night. During daylight hours, they add oxygen through photosynthesis. D.O. levels are therefore generally highest during the afternoon and lowest just before sunrise.

Biochemical Oxygen Demand (BOD) measures the amount of oxygen required by bacteria to decompose organic matter. The BOD is gradually exerted in two stages. In the first stage, carbonaceous matter is stabilized, while nit­ rogenous substances are broken down in the second stage. The second stage (nitrification) usually begins after seven days. The ultimate, or total BOD from both stages may require an incubation period of 30 days or more. Through recurrent use, the 5-day BOD has become the standard test used in water quality analysis,

Chemical Oxygen Demand {COD) refers to the amount of oxygen required to chemically oxidize waste material. Since some of the organic matter in a waste cannot be decomposed by microorgRnisms but can be broken down by chemical oxidation, the COD is generally greater than the BOD. The COD is especially useful in analyzing a waste that contains a great deal of non-biodegradable matter.

220 Total Solids measures all solids in water including suspended snd dissolved, organic and inorganic. They are measured by evaporating. the water from a sample of known volume and measuring the residue remaining. The residue can then be ignited in a laboratory furnace to determine the organic portion The loss on ignition is considered organic and the remaining residue, known as fixed solids, is considered to be inorganic.

Suspended Solids are those which can be removed by passing the water through a filter. The remaining solids are called dissolved solids. Suspended solids provide a good measure of the efficiency of a sewage treatment plant: primary treatment should remove about 50 percent of the suspended solids, while secondary treatment should remove about 90 percent.

Coliform Bacteria are found in abundance in the intestinal tract of warm­ blooded animals. They are not harmful in themselves, but their presence indicate& that pathogenic bacteria may also be present. Since they can be detected by relatively simple test procedures, coliforms are used to indi­ cate the extent of bacterial pollution from sewage. Bacterial tests usually measure the fecal and total coliforms. Fecal coliforms make up about 90 percent of the coliforms discharged in fecal matter. Non-fecal coliforms may originate in soil, grain, or decaying vegetation.

£!! measures the hydrogen ion concentration on an inverse logarithmic scale ranging from Oto 14, pH values under 7 indicate more hydrogen ions and, therefore, more acidic solutions; pH values over 7 indicate fewer hydrogen ions and, therefore, more alkaline solutions. A pH of 7.0 indicates a neutral solution, Alkalinity is a quantitative measure of the alkaline materials present, while acidity is a quantitative measure of acidic materials.

Nutrients are compounds which act as fertilizers for aquatic organisms. Small amounts are necessary to the ecological balance of a waterbody, but · excessive amounts can upset the balance by causing excessive growths of algae· and other aquatic plants. Sewage discharged to a waterbody usually contains large amounts of carbon, nitrogen, and phosphorus. The concentra- . tion of carbonaceous matter is reflected in the BOD test. Additional tests are run to determine the concentrations of nitrogen and phosphorus.

Phosphorus appears in waterbodies in canbined forms known as ortho- and poly­ phosphates and organic phosphorus. The majority of the phosphorus contained in domestic sewage and industrial wastes comes from detergents. Additional phosphorus may enter a waterbody in agricultural runoff where fertilizers are used,

Nitrogen in the form of organic nitrogen normally decomposes into ammonia­ nitrogen, nitrite-nitrogen, and nitrate-nitrogen. Since each decomposition reaction is dependent on the preceding one, the progress of decomposition can be determined in terms of the relative amounts of these four forms of nitrogen,

221 Ammonia-Nitrogen (NH3-N) is present in sewage and is also.generated from the decomposition of organic nitrogen. In can also be formed when nitrites and nitrates are reduced. Ammonia is particularly important since it has high oxygen and chemical demands and is also toxic to fish.

Nitrite-Nitrogen (No2-N) is the oxidation product of ammonia. It has a fairly low oxygen demand and is rapidly converted to nitrate. The presence of nitrite­ nitrogen usually indicates that active decomposition is taking place.

Nitrate-Nitrogen {N03-N) is important since it is the end product in the aerobic decomposition of nitrogenous matter. Nitrogen in this form is readily available to plants.

Total Kjeldahl Nitrogen (TKN) includes ammonia and organic nitrogen but does not include nitrite and nitrate qitrogen. Thus it is a measure of the po­ tential for oxygen consumption of the nitrogenous matter in the water.

Turbidity is the measure of the clarity of a water sample. It is expressed in Nephelometric Turbidity Units (NTU) which are related to the scattering and absorption of light by the water sample.

Color is determined by visual comparison of a sample with known concentrations of colored solution and is expressed in standard units of color. Certain waste discharges may turn water to colors which cannot be defined by this method; in such cases, the color is expressed qualitatively rather than numerically.

Chloride (Cl-) is one of the major anions in water and sewage. A high chloride content can exert a deleterious effect on pipes and structues, as well as on plant life. The use of road salts is a major source of excessive chlorides in surface and groundwaters.

Specific Conductance yields a measure of a water sample's capacity to convey an electric current. It is dependent upon temperature and the concentration of ionized substances in the water. Distilled water exhibits specific con­ ductance of 0.5 to 2.0 micromhos per centimeter (µmhos/cm), while natural waters show values from 50 to 500 µmhos/cm.

The above parameters are measured in most water quality surveys. Other con­ stituents such as metals or oil and grease are measured in areas where parti­ cular problems are known to exist. Microscopic examinations are conducted on mott surveys to determine the number of algae and other microorganisms present. Additional samples of the river bottom sre usually collected in order to deter­ mine the types of deposits present. Decomposition of orgsnic suspended matter which settles to the bottom will exert an oxygen demand on the water.

222 Two types of samples are collected for analysis: grab and composite. A grab sample is an instantaneous sample collected to show conditions at a particular time. Composite samples are collected over a period of time at specific in­ tervals, giving a better picture of the overall water quality situation for the time covered.

Certain levels of the shove parameters occur naturally in waterbodies. Since these levels vary among the different ponds, streams, and coastal waters, the following tables are presented for the sake of reference. Table sum­ marizes the numerical limits for certain parameters as specified by the Massachusetts Water Quality Standards. Table lists levels found in unpol­ luted reaches of various Massachusetts waters.

223 ,.

XABLEV-A

SPECIFIED LEVELSOF CERTAINPARAMETERS

MASSACHUSETTSWATER QUALITY STANDARDS REVISED 1974*

DISSOLVEDOXYGEN pH COLIFORMBACTERIA CHEMICALCONSTITUENTS Class A Not less than 75% of saturation As naturally Not to exceed an average None in concentrations or for 16 hours of any 24 hour occurs of 50 per 100 ml for any combinations which would be pe,iod and never less than 5 mg/1, monthly period, harmful or offensive to For cold water streams the D,O, humans, or harmful to animal shall not be less than 6 mg/1, or aquatic life, For seasonal cold water the D,O, shall not be less than 6 mg/1 for the season.

Class B Same as Above 6,5 - 8,0 Not to exceed an average None in concentrations or value of 1000 during any combinations which would be N monthly sampling period harmful or offensive to .,,_N nor 2400 in more than 20% humans, or harmful to animal of samples examined during or aquatic life, or any such period, water use specifically assigned to this class,

Class Bl Not less than 5 mg/1 during at 6.5 - 8.0 Same as Above Same as Above least 16 hours of any 24 hour period, nor less than 3 mg/1 at any time, For seasonal cold water fisheries at least 6 mg/1 must be maintained during the season. . Class C Same as Above 6,0 - 8.5 None in such concentrations Same as Above that would impair any usages specifically assigned to this class, **

Class Cl Not less than 2 mg/1 at any 6,0 - 8.5 Same as Above Same as Above time. TABLEV-A (CONTINUED)

DISSOLVEDOXYGEN pH COLIFORMBACTERIA CHEMICALCONSTITUENTS Class SA Not less than 6,5 mg/1, 6.8 - 8,5 Not to exceed a median None in concentrations or value of 70 and not more combinations which would than 10% of samples over be harmful to.human, 230. animal, or aquatic lifr or which would make the waters unsafe or unsuitable for fish or shellfish or their propagation, impair ::he palatability of same, or impair the waters for any . other uses,

N N u, Class SB Not less than 5,0 mg/1. 6.8 - 8.5 Not to exceed a median Same as Above value of 700 and not more than 10% of samples over 2300,

Class SC Not less than 5 mg/1 during 6.5 - 8.5 None in concentrations Same as Above at least 16 hours of any 24 that would impair any hour period and never less usages assigned to this than 3 mg/1. class, *"'

* These water quality standards are currently undergoing revision. The new revised standards will be published in 1978,

** No bacterial limit has been placed on this class because of urban runoff and combined sewer problems which have not yet been solved. In waters of this class not subject to this problem the criterion shall be less than an average of 5,000 coliform/100 ml. during any monthly sampling period. TABLEV-B

SELECTEDANALYSES OF UNPOLLUTEDWATERS

HOUSATONICRIVER MUMFORDRIVER EASTBRANCH AUCOOTCOVE PARAMETERS PEPPERILL DOUGLAS HINSDALE MARION* Dissolved Oxygen, mg/1 7.5-8.1 5.6 - 9.1 5 .6 - 12 .6 6.1 - 8.0

5-Dsy B,O.D., mg/1 1.8 3.6 2.5 0.3 Suspended Solids, mg/1 0.5 0.5 2.0 0.8

N N pH, standard units 6.8 6.6 8.0 8.2 °' Alkalinity, mg/1 15 4.0 65 114 Ammonia as N, mg/1 0.01 0.04 0.02 o.29 Nitrate as N, mg/1 0.1 0.2 0.1 o.o Total Phosphorus as P, mg/1 0.02 0.03 0.03 0.02 Total Coliform per 100 ml 650 160 400 10

Fecal Coliform per 100 ml 180 30 10

Color, standard units 35 15 10

Turbidity, standard units 0.6 1.0

Chlorides, mg/1 11 5.0 17,500

* Ocean