US 2014O105947A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2014/0105947 A1 Schlossman et al. (43) Pub. Date: Apr. 17, 2014

(54) NATURAL ESTER, WAXOR OIL TREATED (60) Provisional application No. 61/044,458, filed on Apr. PIGMENT, PROCESS FOR PRODUCTION 11, 2008. THEREOF, AND COSMETIC MADE THEREWITH (30) Foreign Application Priority Data (71) Applicants: David Schlossman, Short Hills, NJ Apr. 10, 2009 (US) ...... PCT/USO9/40158 (US); Yun Shao, Belle Mead, NJ (US) Publication Classification (72) Inventors: David Schlossman, Short Hills, NJ (US); Yun Shao, Belle Mead, NJ (US) (51) Int. Cl. A68/92 (2006.01) (73) Assignee: Kobo Products, Inc., South Plainfield, A61O 1/02 (2006.01) NJ (US) (52) U.S. Cl. CPC. A61K 8/922 (2013.01); A61O 1/02 (2013.01) (21) Appl. No.: 14/110,000 USPC ...... 424/401; 427/212:427/220 (57) ABSTRACT (22) Filed: Dec. 18, 2013 The present invention provides compositions for natural cos metic products and, more particularly, to natural ester, wax or Related U.S. Application Data oil treated pigments, the products of Such treated pigments (62) Division of application No. 12/420,498, filed on Apr. and cosmetic products incorporating pigments treated with 8, 2009, now Pat. No. 8,623,386. natural ingredients. US 2014/O 105947 A1 Apr. 17, 2014

NATURAL ESTER, WAXOR OIL TREATED Sion. It is contemplated that a variety of products may incor PIGMENT, PROCESS FOR PRODUCTION porate the formulation and processes provided herein. For THEREOF, AND COSMETIC MADE example, emulsions such as makeup, foundation and mas THEREWITH cara; anhydrous hot pours such as lipsticks and blush; and powders such as pressed and loose powders may be made. CROSS REFERENCE TO PROVISIONAL 0010. In an embodiment of the present invention, there is APPLICATION provided a cosmetic composition comprising a pigment 0001. The present application claims priority to U.S. Pro treated with a natural Surface modifying agent. Suitable natu visional Application No. 61/044,458, filed Apr. 11, 2008, ral Surface modifying agents according to the present inven which is incorporated by reference herein in its entirety. tion include, without limitation, jojoba ester, hydrogenated jojoba oil and mixtures thereof. TECHNICAL FIELD 0011 Suitable pigments according to the present inven tion include, without limitation, minerals such as talc, mica 0002 The present invention relates to compositions for and sericite; metal oxides such as titanium dioxide, Zinc oxide natural cosmetic products and more particularly to natural and iron oxides; thermal plastic powders; and organic pig ester, wax or oil treated pigments, the products of such treated ments such as starch and cellulose. pigments and cosmetic products incorporating pigments 0012. In another embodiment of the present invention, treated with natural ingredients. there is provided a cosmetic composition comprising at least one hydrophobic natural Surface modified pigment selected BACKGROUND OF THE INVENTION from the group comprising titanium dioxide, yellow iron 0003 Minerals such as talc, mica and sericite, metal oxide, red iron oxide, black iron oxide, mica and silica, the oxides such as titanium dioxide, Zinc oxide and iron oxides, pigment being incorporated into a cosmetic product selected thermoplastic powders, organic pigments such as starch and from lipstick, loose or pressed powder, foundation, blush and cellulose, and other inorganic pigments are widely used in SUSCC. cosmetic products. Although they can be used without treat 0013. In an exemplary embodiment, the cosmetic compo ment, their performance can be significantly improved sition is an oil in water liquid make-up having between about through surface treatment. Special properties such as water 0.5 wt.% to about 15 wt.%, preferably about 1 wt.% to about proofness, low oil absorption, higher Solids loading, softness, 7 wt.% and more preferably about 4.5 wt.% of a hydrophobic enhanced dispersibility, and resistance to low pH can be natural Surface modified pigment selected from the group enhanced through surface treatment. comprising titanium dioxide, yellow iron oxide and red iron 0004 Most common Surface modifying agents, such as oxide. methicone, silane, dimethicone, titanate, magnesium 0014. In another exemplary embodiment, the cosmetic myristate and perfluoroalcohol phosphate are all synthetic composition is a hotpour creating a liquid compact founda compounds and may involve undesirable complications. tion having between about 15% to about 75%, preferably about 25% to about 50% and more preferably about 40% of a SUMMARY OF THE INVENTION natural Surface modified pigment selected from the group 0005. In accordance with the present invention, plant comprising titanium dioxide, red iron oxide, yellow iron derived esters and wax Such as jojoba ester andjojoba wax in oxide, black yellow oxide, mica and silica. particular, are used to surface treat pigments and fillers. The 0015. In another exemplary embodiment, the cosmetic treated pigments may be hydrophobic and have a nice skin composition is a lipstick having between about 0.5% and feel and good adhesion. It is envisioned that the treated pig about 20%, preferably about 2% to about 10% and more ments in accordance with the present invention may be used preferably about 6% of a natural surface modified pigment in a wide range of cosmetic compositions. selected from the group comprising D&C Red No. 6 Barium 0006. In an aspect of the present invention, there is pro Lake, D&C Red No. 7 Calcium Lake and iron oxides. vided a cosmetic composition comprising a pigment treated 0016. In another exemplary embodiment, the cosmetic with a natural Surface modifying agent. composition is a pressed powder having between about 30% 0007. In another aspect of the present invention, there is to about 85%, preferably between about 50% to about 80% provided a cosmetic composition comprising at least one and more preferably about 72% of a natural surface modified hydrophobic natural Surface modified pigment selected from pigment selected from the group comprising sericite, yellow titanium dioxide, yellow iron oxide, red iron oxide, black iron iron oxide, red iron oxide and black iron oxide. oxide, mica and silica, the pigment being incorporated into a 0017. In another exemplary embodiment, the cosmetic cosmetic product such as lipstick, loose or pressed powder, composition is an emollient loose powder having between foundation, blush and Sunscreen. about 0.1% to about 10%, preferably between about 0.5% to 0008. In a further aspect of the present invention, there is about 2% and more preferably about 0.78% of a natural provided a process for making a natural Surface treated pig Surface modified pigment selected from the group comprising ment, comprising providing a pigment, blending the pigment yellow iron oxide, red iron oxide and black iron oxide. with a natural Surface modifying agent to produce a blend; 0018. In a further embodiment of the present invention, heating the blend to approximately 100 degrees C. to 110 there is provided a process for making a natural Surface degrees C.; and allowing the blend to cool to approximately treated pigment comprising providing a pigment; blending 18 degrees C. The material may then be milled. the pigment with a natural Surface modifying agent to pro 0009 Natural products are believed to be more compatible duce a blend; heating the blend to between about 80 degrees with the human body and more environmentally friendly. The C. to about 150 degrees C., preferably between about 100 cosmetic products contemplated by the present invention degrees C. to about 110 degrees C.; and allowing the blend to include natural products with a smooth feel and good adhe cool to approximately 18 degrees C. US 2014/O 105947 A1 Apr. 17, 2014

0019. A variety of pigments may be used to make casted pigments which are treated with them. More particularly, pigments in accordance with the present invention. For titanium dioxide treated with jojoba ester gives the product a example, minerals such as talc, mica and sericite; metal feel which is as dry as untreated pigment, but which is very oxides such as titanium dioxide, Zinc oxide and iron oxides; Smooth and on a par with the Smoothness of the pigment thermoplastic powders; organic pigments such as starch and treated with hydrogenated lecithin and Stearic acid. cellulose; and other inorganic pigments may be used. Mate 0026 Jojoba ester treated sericite also scores very high on rials having a large range of sizes, for example from about 5 the Smoothness scale, comparable to hydrogenated lecithin nm to 300nm or larger, as well as various shapes, for example, treated pigment and Substantially more Smooth than the pig without limitation, spherical and acicular, may be treated. For ment treated with lauroyl lysine or lecithin. example, materials that may be advantageously treated in 0027 Pigments treated with jojoba ester are almost com accordance with the present invention include microparticles pletely odorless, as compared to other treatments such as of the metal oxide titanium dioxide (TiO) (micro TiO) carnauba wax which have relatively strong odors. Likewise, having a primary particle size of less than about 200 nm and when subjected to high temperatures, such as 90° C., for a a pigmentary grade size (i.e., larger particle size) of greater relatively long time, Such as six hours, pigments, such as than about 200 nm, with an alumina coating such as that sold titanium dioxide and seracite exhibit virtually no odor by ISK under the trade name TTO-S-3. TTO-S-3 has a pri change, whereas pigments treated with Such materials as car mary particle size of about 15 nm and has an acicular shape. nauba and lauroyllysine exhibit odor increases in the range of Tipaque PF-671 is an example of a pigmentary grade TiO, about 30 to 90%. Thus, pigments treated with these other having an alumina and silica coating and a particle size of materials have odor levels dozens of times greater than pig about 210 nm that may be treated in accordance with the ments treated in accordance with the invention, both before present invention. and after exposure to high levels of heat. 0020. Another example of a material that may be treated in 0028 Moreover, despite the relative dryness of jojoba accordance with the present invention include microparticles treated pigments, the treatment is very effective in giving of Zinc oxide (ZnO) having a primary particle size less than mechanical stability to compacted powders, as compared to about 200 nm (micro ZnO) and a pigmentary grade size of untreated pigment compacts which tend to break apart with greater than about 200 nm, such as MZ-500, provided by mechanical shock and/or agitation. Tayca, is a micro ZnO with a primary particle size of about 20 0029. The present invention is additionally described by nm. Other examples of materials that may be used in accor way of the following illustrative, non-limiting examples that dance with the present invention include, without limitation, provide a better understanding of the present invention and of iron oxides such as those provided by Sun Chemical under the its many advantages. trade names C33-5 198 Cosmetic Black, C33-128 Cosmetic Russet and C33-8073 Cosmetic Yellow. EXAMPLES 0021. Yet another material that may be treated in accor dance with the invention is a macroparticle composite of Production of Coated Powders Smaller particles (e.g. Sunscreen particles) in a binder matrix and/or a macroparticle defining Voids holding Smaller par Example 1 ticles (for example, Smaller Sunscreen particles). Hydrophobically Coating Micro TiO, 0022. In accordance with the present invention, a natural coating is used in connection with a pigment to provide natu 0030 93 g of alumina treated 15 nm titanium dioxide sold ral products with superior feel and other desirable properties. under catalog number TTO-S-3 by ISK, as described above, The coating may be jojoba esters, which is a complex mixture was blended with 7 g of Jojoba ester (Floraester 70). The of esters produced by the transesterification/interesterifica blend was heated to approximately 100° C.-110° C. The tion of Simmondsia Chinensis (Jojoba) oil (q.v.), hydroge blend was held at a temperature of 100° C. for approximately nated Jojoba oil (q.v.), or a mixture of the two. In a preferred 1 hour. The blend was then allowed to cool to room tempera embodiment, Floraester 70 provided by Floratec is used. ture, which was approximately 18°C. The powder was milled However, any grade of Jojoba ester may be used in accor using a blender. dance with the present invention. 0023. Further, Jojoba wax, i.e., hydrogenated Jojoba oil, Example 2 may be used. Jojoba wax is the end product of the controlled hydrogenation of Simmondsia Chinensis (Jojoba) Oil (q.v.). Hydrophobically Coating Red Iron Oxide Pigment 0024. In accordance with the present invention, it is con 0031 97 g of red iron oxide sold under the trade name templated that other natural materials may be substituted for C33-128 Cosmetic Russet, as provided by Sun Chemical, was jojoba ester. Suitable materials for use in accordance with the blended with 3 g of jojoba ester under the trade name Flo methods of the invention, in addition to jojoba ester, jojoba raester 70 as provided by Floratec. The blend was heated to wax (that is hydrogenated jojoba oil) and jojoba oil include, about 100° C.-110°C. The blend was held at a temperature of without limitation, whale oil, Soya wax and candelilla. Jojoba 100° C. for approximately 1 hour. The blend was then allowed and jojoba esters, in particular, are preferred because they to cool to room temperature, which was approximately 18°C. both are very resistant to oxidation, more so than castor oil, The powder was milled using a blender. coconut oil, macadamia nut oil and even many fractions of mineral oil. The similarity of jojoba esters to human sebum Example 3 makes jojoba-based hydrophobizing coatings particularly preferred. Hydrophobically Coating a Pearlescent Pigment 0025. It is also noted that in accordance with the invention, 0032 98 g of a pearlescent pigment, such as that sold jojoba esters produce an unexpected array of properties in under trade name KTZTM Interval Red as provided by Kobo US 2014/O 105947 A1 Apr. 17, 2014

Products, Inc., was blended with 2 g of Jojoba ester under the Example 5 trade name Floraester 70. The blend was heated to 100° C-1 10°C. The blend was held at a temperature of 100° C. for Oil in Water Liquid Makeup approximately 1 hour. The blend was then allowed to cool to room temperature, which was approximately 18°C. The pow 0039 der was milled using a blending process with a blender. TABLE 1 Example 4 Oil in Water Liquid Makeup Ingredients %

Hydrophobically Coating of a Microsphere PartA (Oil Phase) 0033 95g of silica beads under trade name MSS-500W as Lanolin Alcohol and Mineral Oil 11...SO provided by Kobo was blended with 5g of Jojoba ester under Cetyl Esters 3.2O trade name Floraester 70. The blend was heated to 100-110° Stearic Acid 3.SO Glyceryl Monostearate 18O C. The blend was held at a temperature of 100° C. for approxi Talc 2.OO mately 1 hour. The blend was then cooled to room tempera Titanium dioxide (produced in Example 1) 4.OO ture, which was approximately 18°C. The powder was then Yellow iron oxide (alumina coated and 1.OO pulverized using a large Cuisinart food processor equipped processed as in Example 2) Red iron oxide (w.falumina coated and O4O with its S-shaped chopping blade. processed as in Example 2) Black iron oxide (w.falumina coated and O.15 processed as in Example 2) Test Results Part B (Water Phase) Hydrophobicity Propylene glycol 12.00 Triethanolamine 1.OO 0034) To test hydrophobicity, approximately 0.5 g-1 g of PE20 Sorbitan Monolaurate O.65 Magnesium Aluminum Silicate 1.OO both the uncoated powder pigments and the coated powder Carboxymethyl Cellulose O.30 pigments made from the above processes according to each of Deionized Water 57.20 the Examples 1-4 were tested. The powderpigment tested, in Preservatives and Fragrance O.30 each case, was gently spooned onto the Surface of water contained in a 4 oZ. jar. The jar contained 50 mL of water. 0040. A formulation for liquid make-up is shown in Table 0035. The uncoated powders immediately sank upon addi 1. The ingredients in Part A were combined in the following tion to the jar of water. The coated powers made according to order, lanolin alcohol and mineral oil, cetyl esters, Stearic acid, glyceryl monostearate, talc, titanium dioxide in accor Examples 1-4 floated on the water for more than an hour. dance with Example 1, yellow iron oxide in accordance with Thus, the coated powders showed hydrophobic qualities. Example 2, red iron oxide in accordance with Example 2, and black iron oxide in accordance with Example 2. Each ingre Skin Feel dient in Part A was added one at a time, mixing each compo nent in until homogenous and then the next ingredient was 0036. To test skin feel, a small portion of each of the added. The formulation in Part A was heated to 60° C. uncoated pigment powders and coated powders made in 0041. In a separate vessel, the ingredients of Part B were accordance with Examples 1-4 were tested. The pigment slowly combined by being added in the following order: powders were placed onto and rubbed against the Surface of propylene glycol, triethanolamine, PE 20 Sorbitan monolau the forearm using an index finger. rate, magnesium aluminum silicate, carboxymethyl cellulose and deionized water and preservatives and fragrance. 0037 Uncoated TiO, ZnO and iron oxides with particles 0042 Part A was then slowly added to Part B. The Parts sizes of at least 10 nm, had an abrasive and unpleasant feel. were mixed together using a blending process in a conven The coated TiO, ZnO and iron oxides coated with Floraester tional blender. The mixture was then poured into containers. 70 and/or Jojoba and prepared in accordance with Examples 1 and 2 provided a smooth and soft skin feel. Additionally, Example 6 uncoated mica talc had a smooth feel. Talc and mica coated with Floraester 70 and Jojoba and prepared according to Liquid Compact Foundation (Hot Pour) Example 3 also provided a smooth feel that was soft and 0043 Creamy. TABLE 2 0038. It is contemplated by the present invention that the treated pigments may be used in a wide variety of applications Liquid compact foundation (Hot pour including emulsions such as makeup, foundation, mascara % and Sunscreens; anhydrous hot pours such as lipsticks and blush; and powders such as pressed and loose powders. Some PartA possible applications are described below in the next set of Titanium dioxide (w/hydrophobic 26.76 Examples. The formulations shown are based on the total performed as in Example 1) weight percentage of the formulation. US 2014/O 105947 A1 Apr. 17, 2014

TABLE 2-continued TABLE 3-continued Liquid compact foundation (Hotpour Lipstick Ingredient % Red iron oxide (w/hydrophobic O.S4 Iron Oxides (wcoating in accordance with Example 1.OO performed as in Example 2) 2) Yellow iron oxide (w/hydrophobic O.S4 FD&C Blue No. 1 O.80 performed as in Example 2) Perfume 0.75 Black iron oxide (w/hydrophobic O16 Titanium Dioxide (and) Mica (wcoating) 1O.OO performed as in Example 2) Mica (w/hydrophobic performed as in 1O.OO Example 3) 0047. The castor oil was placed in a blender and heated to Silica (spherical) (w/hydrophobic 2.OO performed as in Example 4) 80° C. using a steam pan. The treated pigments and the dyes Part B including D&C red No. 6 barium lake with a coating prepared in accordance with Example 4, D&C red No. 7 calcium lake Squalane 1O.OO prepared in accordance with Example 4, iron oxides prepared Dimethicone (5cst) 17.00 Octyl hydroxystearate 7.OO in accordance with Example 2, and FD&C Blue No 1, were Polyglyceryl-3 diisostearate 3.00 added, to the castor oil using a Lightnin mixer under high Microcrystalline wax 7.OO speed for 30-60 minutes. Octyl palmitate 7.OO 0048. The candelilla wax, carnauba wax, beeswax, ozok Carnauba wax 1.OO erite paraffin wax, oleyl alcohol and lanolin alcohol were Part C preheated and melted together at 80-85°C. using a steam pan. Nylon-12 (12 micron spherical beads 8.OO These melted components were then added to the castor oil, sold by Kobo Products, Inc. under pigment and dye mixture. Mixing was continuous throughout catalog number SP-10.) the addition of each ingredient. 0049. The perfume was added and mixing was continued 0044 Part A: titanium dioxide in accordance with until the mixture was homogeneous. The titanium dioxide Example 1, red iron oxide in accordance with Example 2. and mica were then added and mixing continued until the yellow iron oxide in accordance with Example 2, black iron product was uniform. oxide in accordance with Example 2, and mica in accordance 0050. The lipstick was then formed in a manner consistent with Example 3 were micronized using a mixing process until with that known to those skilled in the art. the color was fully developed. Part B: squalane, dimethicone (5 cst), octyl hydroxy Stearate, polygly veryl-3 diisostearate, Example 8 microcrystalline wax, octyl palmitate and carnauba wax were heated to 195° F-200°F. while simultaneously stirring. Part B Pressed Powder was continuously stirred for 30 minutes. 0051 0.045 Part A was added to Part B and mixed until homo geneous. The mixture was allowed to cool to 180° F. Part C: nylon-12 was added to the mixture of Part A and Part B and TABLE 4 mixed until homogeneous. The mixture of Part A. Part Band Pressed Powder Part C was poured into pans at 165° F-170° F. % Example 7 PartA Sericite (with hydrophobic coating 70 Lipstick as in Example 4) Yellow iron oxide (with O.88 0046) hydrophobic coating as in Example 2) Red iron oxide (with hydrophobic O.76 TABLE 3 coating as in Example 2) Black iron oxide (with hydrophobic O.36 Lipstick coating as in Example 2) Ingredient % Part B Candelilla Wax 6.OO Squalane 1.8 Carnauba Wax 3.00 Pentaerythritol tetraoctanoate 1.2 Ozokerite 4.OO Dimethicone and 5 Paraffin Wax 2.OO rimethylsiloxysikiacate Yellow Beeswax 6.OO Part C Lanolin Alcohol 6.OO Oleyl Alcohol 1O.OO Nylon-12 (12 micron spherical 2O BHA O.20 beads sold by Kobo Products, Inc. Castor Oil 43.25 under catalog number SP-10.) D&C Red No. 6 Barium Lake (w.fcoating in 2.50 accordance with Example 4) D&C Red No. 7 Calcium Lake (w.fcoating in 2.50 0.052 Part A: sericite with a coating of jojoba ester pre accordance with Example 4) pared in accordance with Example 4, yellow iron oxide pre pared in accordance with Example 2, red iron oxide prepared US 2014/O 105947 A1 Apr. 17, 2014

in accordance with Example 2, and black iron oxide prepared 2. The process of claim 1, wherein the blend is heated to in accordance with Example 2 were mixed together in the between about 100° C. to about 110° C. order listed and passed through a pulverizer until the color 3. The process of claim 1, further comprising milling the was fully developed. pigment. 0053 Part B, made of squalane, pentaerythritol tetraoc 4. The process of claim 1 wherein the mean particle size of tanoate, dimethicone and trimethylsiloxysilicate, was pre the pigment lies substantially within the range of 10 nm to 200 warmed to 65°-70° C. Part B was then sprayed onto Part A. microns. Parts A and B were then mixed well with a blending process 5. The process of claim 1, wherein the pigment consists of using a conventional blender. Part B was then passed through one or more pigments selected from the group consisting of a pulverizer until the oil was completely dispersed. Part C. minerals such as talc, mica and sericite; metal oxides such as nylon-12, was added to Part B and blended well. If necessary, titanium dioxide, Zinc oxide and iron oxides; thermal plastic the mixture was passed through a pulverizer to fully develop powders; organic pigments such as starch and cellulose, the color. It was important not to overheat Part B. The mixture organic lakes, combinations of any of the foregoing, and was then passed through a #20 mesh screen at 1000 psi. composites of one or more of the foregoing. 0054 The product was then pressed in a conventional 6. The process of claim 5, wherein the pigment comprises a. metal oxides, and said metal oxides are selected from the group consisting of Sunscreen grades of titanium dioxide and Example 9 Zinc oxide, said metal oxide having a mean particle size between 10 nm and 200 nm. Emollient Loose Powder 7. The process of claim 5 wherein the pigment comprises metal oxides and said metal oxides are pigmentary grades of 0055 metal oxide. 8. The process of claim 5, wherein the pigment comprises TABLE 5 a pearlescent pigment having a mean particle size of 5-200 Emollient Loose Powder microns. 9. The process of claim 6, wherein the pigment comprises % Zinc oxide with a mean primary particle size of roughly about PartA 15 nm to 300 nm. 10. The process of claim 6, wherein the pigment comprises Mica 59.22 Yellow iron oxide (with hydrophobically applied coating as in O.24 titanium dioxide and has a mean primary particle size of Example 2) roughly about 15 nm. Red iron oxide (with hydrophobically applied coating as in O.24 11. The process of claim 5, wherein the pigment comprises Example 2) silica beads with a mean particle size of 2-40 microns. Black iron oxide (with hydrophobically applied coating as in O.30 Example 2) 12. The process of claim 1, further comprising formulating Part B the composition into a cosmetic composition or Sunscreen product, said cosmetic composition or Sunscreen product Squalane 6.90 selected from the group consisting of lipstick, loose or Pentaerythritol tetraoctanoate 4SO Dimethicone and trimethylsiloxysilicate 10.86 pressed powder, foundation, cream, lotion or blush. Silica (Spherical) 10.00 13. The process of claim 5, further comprising formulating the composition into a cosmetic composition or Sunscreen product, said cosmetic composition or Sunscreen product 0056 Mica, yellow iron oxide and black iron oxide which selected from the group consisting of lipstick, loose or make up Part A were added to a Waring Blender under a fume pressed powder, foundation, cream, lotion or blush. hood. Part A was mixed for 2-3 minutes at high speed. Part 2, 14. The process of claim 12 wherein at least one pigment is comprising the squalane, pentaerythritol tetraoctanoate, selected from the group consisting of titanium dioxide, yel dimethicone and trimethylsiloxysikiacate and silica (spheri low iron oxide, red iron oxide, black iron oxide, mica and cal), were pre-blended in a Waring Blender. Part B was added silica. to Part A and mixed. The mixture was then passed through a 15. The process of claim 14, wherein the cosmetic compo pulverizer until the oil was dispersed. sition is an oil in water liquid make-up having between about 0057 While the invention has been particularly shown and 0.5 wt.% to about 15 wt.% of the pigment, wherein the described with reference to preferred embodiments thereof, it uncoated is selected from the group consisting of titanium will be understood by those skilled in the art that various dioxide, yellow iron oxide red iron oxide, and black iron alterations in form and detail may be made therein without oxide. departing from the spirit and scope of the invention, as 16. The process of claim 15, wherein the oil in water liquid defined by the appended claims. make-up has between about 1 wt.% to about 7 wt.% of the 1. A process for making a coated pigment comprising: hydrophobic pigment. providing a pigment; 17. The process of claim 16, wherein the oil in water liquid blending the pigment with a natural Surface modifying make-up has about 4.5 wt.% of the hydrophobic pigment. agent to produce a blend; 18. The process of claim 14, wherein the cosmetic compo heating the blend to between about 80°C. to about 150° C.: sition is a hot pour creating a liquid compact foundation allowing the blend to cool to approximately 18° C. having between about 15% to about 75% of the hydrophobic whereby said pigment is directly coated with the agent pigment wherein the untreated pigment is selected from the producing a hydrophobic coated pigment, said agent group consisting of titanium dioxide, red iron oxide, yellow comprising a jojoba ester. iron oxide, black yellow oxide, mica and silica beads. US 2014/O 105947 A1 Apr. 17, 2014

19. The process of claim 18, wherein the liquid compact 26. The process of claim 25, wherein the pressed powder foundation comprises between about 25% to about 50% of has roughly about 72% of the hydrophobic pigment. the hydrophobic pigment. 27. The process of claim 14, wherein the cosmetic compo 20. The process of claim 19, wherein the liquid compact sition is an emollient loose powder having between about foundation comprises about 40% of the hydrophobic pig 0.1% to about 10% of the hydrophobic pigment wherein the ment. uncoated pigment is selected from the group consisting of 21. The process of claim 14, wherein the cosmetic compo yellow iron oxide, red iron oxide and black iron oxide. sition is a lipstick having between about 0.5% and about 20% 28. The process of claim 27, wherein the emollient loose of the hydrophobic pigment, wherein the uncoated pigment is powder has between about 0.5% to about 2% of the hydro an organic lake selected from the group consisting of D&C phobic pigment. Red No. 6 Barium Lake, D&C Red No. 7 Calcium Lake and 29. The process of claim 28, wherein the emollient loose iron oxides. powder has about 0.78% of the hydrophobic pigment. 22. The process of claim 21, wherein the lipstick comprises 30. The process according to claim 1, wherein the agent between about 2% to about 10% of the hydrophobic pigment. comprises a mixture of esters produced by the transesterifi 24. The process of claim 14, wherein the cosmetic compo cation or interesterification of Simmondsia Chinensis. sition is a pressed powder having between about 30% to about 31. The process according to claim 1 wherein the agent 85% of the hydrophobic pigment, wherein the untreated pig comprises Floraester 70 or substantially the equivalent. ment is selected from the group consisting of sericite, tita nium dioxide, yellow iron oxide, red iron oxide and black iron 32. The process according to claim 1 wherein the iodine oxide. value of the agent is less than 2 g/100g. 25. The process of claim 24, wherein the pressed powder 33. The process according to claim 1 wherein the melting has between about 50% to about 80% of the hydrophobic point of the agent is roughly about 66-70° C. pigment. k k k k k