Sr. No. Name of Annexure Page No

LIST OF ANNEXURES

Sr. No. Name of Annexure Page No. I Detail of Total Area and List of Products with their Production Capacity, 15-20 CAS No. and LD 50 Values II Layout Map of the Plant 21 III Brief Process Description/Mass Balance/Chemical Reaction 22-174 IV Detail of Storage of Raw Material and their Copnsumption with CAS No. 175-198 V Details of Effluent Treat ment Scheme and Disposal with Flow Diagram 199 -201 VI Details of Hazardous Waste Generation & Disposal 202 VII Details of Water Consumption, Waste Water Generation and Treatment 203-204 with Flow Diagram VII I Details of Stack and Vents 205 IX Storage, Transportation and Handling of Hazardous Chemicals 206-207 X Risk of Accident from Other Hazardous and their Controls 208 XI Socio - Economic Impacts 209 XII Proposed Terms of Reference for EIA Studies 210 -211 XIII Lease of Plot 212

14 Annexure : I

I.1 Detail of Area

Sr.No. Description Capacity 1 Proposed Capacity 1200 MT/Month 2 Total Area 12000 Sq.M. 3 Lease Area 12000 Sq.M. 4 No. of well to be drilled 1

I. 2 List of Products with their Capacity, CAS No. & LD 50 Values :-

Cate Grou Sr.No gory p Quanti .of wise wise CAS no. / ty Total Sr.N Sr.N Name of the Products LD50 /LC50 CI no. MT/M Prod o. of o. of onth ucts Prod Prod ucts ucts 1.Total No. of Products : Category : A+B = 147; Total Production capacity of All Products : 1200 MT/Month Category-A: Pigments (Group 1+2+3+4+5 = 106 ) Group-1: Pigment Red = 49 1 1 1 Pigment Red 2 6041-94-7 LD50 Oral, Rat 8110 mg/kg 2 2 2 Pigment Red 3 2425-85-6 LD50 Oral, Rat 8180 mg/kg 3 3 3 Pigment Red 4 2814-77-9 LD50 Oral, Rat 8140 mg/kg 4 4 4 Pigment Red 5 6410-41-9 LD50 Oral, Rat 8190 mg/kg 5 5 5 Pigment Red 12 6410-32-8 LD50 Oral, Rat 8160 mg/kg 6 6 6 Pigment Red 14 6471-50-7 NA dermal route (LD50 > 2000 7 7 7 Pigment Red 38 6358-87-8 mg/kg bw) 8 8 8 Pigment Red 48:1 7585-41-3 200 LD50 Oral, Rat 8160 mg/kg 9 9 9 Pigment Red 48:2 7023-61-2 LD50 Oral, Rat 8190 mg/kg 10 10 10 Pigment Red 48:3 15782-05-5 LD50 Oral, Rat 8130 mg/kg 11 11 11 Pigment Red 48:4 5280-66-0 LD50 Oral, Rat 8160 mg/kg 12 12 12 Pigment Red 48:5 N.A. NA 13 13 13 Pigment Red 49 1248-18-6 NA 14 14 14 Pigment Red 49:1 1103-38-4 NA 15 15 15 Pigment Red 49:2 1103-39-5 NA 16 16 16 Pigment Red 49:3 6371-67-1 NA

15 17 17 17 Pigment Red 52:1 17852-99-2 NA 18 18 18 Pigment Red 52:2 12238-31-2 NA 19 19 19 Pigment Red 53 2092-56-0 NA 20 20 20 Pigment Red 53:1 5160-02-1. LD50 Oral, Rat 8190 mg/kg L.D.50 ACUTE ORAL(RATS) : 21 21 21 Pigment Red 53:3 73263-40-8 ABOUT 5,000mg/KG 22 22 22 Pigment Red 57:1 5281-04-9. LD50 Oral, Rat 8140 mg/kg 23 23 23 Pigment Red 63:1 6417-83-0 NA 24 24 24 Pigment Red 63:2 35355-77-2 LD50 rat (oral): > 2.000 mg/kg 25 25 25 Pigment Red 81 12224-98-5 LD50 rat : 8260 mg/kg 26 26 26 Pigment Red 81:1 80083-40-5 LD50 rat (oral): > 2.000 mg/kg 27 27 27 Pigment Red 81:x 63022-06-0 LD50 rat (oral): > 2.000 mg/kg 28 28 28 Pigment Red 81:y N.A. LD50 rat (oral): > 2.000 mg/kg 29 29 29 Pigment Red 81:2 75627-12-2 LD50 rat (oral): > 2.000 mg/kg 30 30 30 Pigment Red 81:3 68310-07-6 LD50 rat (oral): > 2.000 mg/kg 31 31 31 Pigment Red 81:4 85959-61-1 LD50 rat (oral): > 2.000 mg/kg 32 32 32 Pigment Red 112 6535-46-2 LD50 Oral, Rat 8290 mg/kg 33 33 33 Pigment Red 122 980-26-7 LD50 Oral, Rat 8290 mg/kg 34 34 34 Pigment Red 123 24108-89-2 LD50 rat (oral): > 2.000 mg/kg 35 35 35 Pigment Red 144 5280-78-4 LD50 Oral, Rat 8380 mg/kg 36 36 36 Pigment Red 146 5280-68-2 LD50 Oral, Rat 8360 mg/kg 37 37 37 Pigment Red 168 4378-61-4 NA 38 38 38 Pigment Red 169 12237-63-7 LD50 Oral, Rat 5000 mg/kg 39 39 39 Pigment Red 170 2786-76-7 LD50 Oral, Rat 8270 mg/kg 40 40 40 Pigment Red 175 6985-92-8 LD50 Oral, Rat 8350 mg/kg 41 41 41 Pigment Red 176 12225-06-8 LD50 Oral, Rat 8380 mg/kg 42 42 42 Pigment Red 177 4051-63-2 LD50 Oral, Rat 8340 mg/kg LD50 Species: rat Value: > 5,000 43 43 43 Pigment Red 178 3049-71-6 mg/kg 44 44 44 Pigment Red 179 5521-31-3 LD50 Oral, Rat 8290 mg/kg 45 45 45 Pigment Red 188 61847-48-1 LD50 rat (oral): > 2.000 mg/kg 46 46 46 Pigment Red 202 3089-17-6 LD50 Oral, Rat 8360 mg/kg 122390 -98 - 47 47 47 Pigment Red 254 LD50 Oral, Rat 8380 mg/kg 1 Oral LD50: >10 g/kg (rats) 48 48 48 Pigment Red 256 79102-65-1 practically non-toxic 122390 -98 - 49 49 49 Pigment Red 264 LD50 Oral, Rat 8320 mg/kg 1 Group-2: Pigment Yellow = 32

16 50 50 1 Pigment Yellow 1 2512-29-0 LD50 Oral, Rat. >10000mg/kg 51 51 2 Pigment Yellow 3 6486-23-3 LD50 Oral, Rat 8252mg/kg 52 52 3 Pigment Yellow 12 6358-85-6 LD50 Oral, Rat .>5000mg/kg 53 53 4 Pigment Yellow 13 5102-83-0 LD50 Oral, Rat .>5000mg/kg 54 54 5 Pigment Yellow 14 5468-75-7 LD50 Oral, Rat .>5000mg/kg 55 55 6 Pigment Yellow 16 5979-28-2 Not Listed 56 56 7 Pigment Yellow 17 4531-49-1 LD50 Oral, Rat 8230 mg/kg 57 57 8 Pigment Yellow 61 12286-65-6 LD50 Oral, Rat 8160 mg/kg 58 58 9 Pigment Yellow 62 12286-66-7 LD50 rat (oral): > 5,000 mg/kg 59 59 10 Pigment Yellow 63 14569-54-1 Not Listed 60 60 11 Pigment Yellow 65 6528-34-3 LD50 Oral, Rat 8230 mg/kg 61 61 12 Pigment Yellow 73 13515-40-7 LD50 Oral, Rat 8190 mg/kg 62 62 13 Pigment Yellow 74 6358-31-2 LD50 Oral, Rat 8260 mg/kg 63 63 14 Pigment Yellow 83 5567-15-7 LD50 Oral, Rat 8390 mg/kg 64 64 15 Pigment Yellow 93 5580-57-4 LD50 Oral, Rat 14000 mg/kg 65 65 16 Pigment Yellow 97 12225-18-2 LD50 Oral, Rat 8250 mg/kg 66 66 17 Pigment Yellow 101 2387-03-3. LD50 rat (oral): > 2.000 mg/kg oral route (LD50 > 15 000 67 67 18 Pigment Yellow 120 29920-31-8 200 mg/kg bw) 68 68 19 Pigment Yellow 121 61968-85-2 NA 69 69 20 Pigment Yellow 138 30125-47-4 LD50 rat (oral): > 5.000 mg/kg 70 70 21 Pigment Yellow 139 36888-99-0 LD50 Oral, Rat 2000 mg/kg 71 71 22 Pigment Yellow 151` 31837-42-0 LD50 Oral, Rat 8330 mg/kg 72 72 23 Pigment Yellow 153 68859-51-8 NA 73 73 24 Pigment Yellow 154 68134-22-5 LD50 Oral, Rat 8250 mg/kg 74 74 25 Pigment Yellow 155 68516-73-4 NA 75 75 26 Pigment Yellow 174 78952-72-4 LD50 Oral, Rat =980mg/kg 76 76 27 Pigment Yellow 180 77804-81-0 LD50 Oral, Rat 5000mg/kg oral route (LD50 > 5000 mg/kg 77 77 28 Pigment Yellow 181 74441-05-7 bw) 78 78 29 Pigment Yellow 182 67906-31-4 NA LD50 Species: rat (male/female) 79 79 30 Pigment Yellow 183 23792-68-9 Value: > 5,000 mg/kg Oral LD50 value of 5 mg/kg or 80 80 31 Pigment Yellow 191 129423-54-7 greater in rats. 81 81 32 Pigment Yellow 191:1 154946-66-4 LD50 Oral, Rat 2000mg/kg Group-3: Pigment Orange = 8 82 82 1 Pigment Orange 5 3468-63-1 LD50 Oral, Rat 8120 mg/kg 200 83 83 2 Pigment Orange 13 3520-72-7 LD50 Oral, Rat 8190 mg/kg

17 84 84 3 Pigment Orange 16 6505-28-8 LD50 Oral, Rat 8120 mg/kg 85 85 4 Pigment Orange 34 15793-73-4 LD50 Oral, Rat 8250 mg/kg 86 86 5 Pigment Orange 36 12236-62-3 LD50 Oral, Rat 8210 mg/kg 87 87 6 Pigment Orange 43 4424-06-0 LD50 Oral, Rat 2000 mg/kg 88 88 7 Pigment Orange 62 52846-56-7 LD50 Oral, Rat 8370 mg/kg 89 89 8 Pigment Orange 64 72102-84-2 LD50 Oral, Rat 8270 mg/kg Group-4: Pigment Blue = 10 90 90 1 Pigment Blue 1 1325-87-7 NA 91 91 2 Pigment Blue 15 147-14-8 LD50 Oral, Rat. >3200mg/kg 92 92 3 Pigment Blue 15:1 147-14-8 LD50 Oral, Rat. >3200mg/kg 93 93 4 Pigment Blue 15:2 147-14-8 LD50 Oral, Rat. >3200mg/kg 94 94 5 Pigment Blue 15:3 147-14-8 LD50 Oral, Rat 2000mg/kg 200 95 95 6 Pigment Blue 15:4 147-14-8 LD50 Oral, Rat 2000mg/kg 96 96 7 Pigment Blue 15:6 147-14-8 LD50 Oral, Rat 2000mg/kg 97 97 8 Pigment Blue 16 574-93-6 LD50 Oral, Rat 2000mg/kg 98 98 9 Pigment Blue 60 81-77-6 LD50 Oral, Rat > 980 mg/kg 99 99 10 Pigment Blue 62 57485-98-0 LD50 Oral, Rat 2000mg/kg Group-5: Pigment Violet = 7 100 100 1 Pigment Violet 1 1326-03-0 LD50 Oral, Rat 2000mg/kg 101 101 2 Pigment Violet 1x N.A. LD50 Oral, Rat 2000mg/kg 102 102 3 Pigment Violet 3 1325-82-2 LD50 Oral, Rat 2000mg/kg 103 103 4 Pigment Violet 19 1047-16-1 200 LD50 Oral, Rat 8420 mg/kg 104 104 5 Pigment Violet 23 6358-30-1 LD50 Oral, Rat 2000mg/kg 105 105 6 Pigment Violet 27 12237-62-6 LD50 Oral, Rat. >3200mg/kg 106 106 7 Pigment Violet 29 81-33-4 LD50 Oral, Rat 2000mg/kg Total of Category-A ( Group 1 + 2 + 3 + 4 + 5 ) 1000 Category-B: Solvent Dyes Group-1: Red Solvent Dyes = 13 107 1 1 Solvent Red 19E 6368-72-5 NA 108 2 2 Solvent Red 23 85-86-9 NA Acute oral toxicity: LD50(Rat): 109 3 3 Solvent Red 24 85-83-6 8110mg/kg Acute oral toxicity: LD50(Rat): 110 4 4 Solvent Red 52 81-39-0 200 8160mg/kg Acute Toxicity: Oral-dog LD 111 5 5 Solvent Red 111 82-38-2 50:>8 g/kg Acute oral toxicity: LD50(Rat): 112 6 6 Solvent Red 135 20749-68-2 8260mg/kg 113 7 7 Solvent Red 151 144013-41-1 NA

18 Acute oral toxicity: LD50(Rat): 114 8 8 Solvent Red 168 71832-19-4 8220mg/kg Acute oral toxicity: LD50(Rat): 115 9 9 Solvent Red 169 27354-18-3 8230mg/kg Acute oral toxicity: LD50(Rat): 116 10 10 Solvent Red 179 479-27-6 8260mg/kg Acute oral toxicity: LD50(Rat): 117 11 11 Solvent Red 197 52372-39-1 8190mg/kg 118 12 12 Solvent Red 207 15958--69-6 NA 119 13 13 Solvent Red 227 2944-28-7 NA Group-2: Yellow Solvent Dyes = 12 120 14 1 Solvent Yellow 2 6370-43-0 NA 121 15 2 Solvent Yellow 14 842-07-9 NA 122 16 3 Solvent Yellow 18 6407-78-9 NA 123 17 4 Solvent Yellow 33 8003-22-3 Skin, rabbit: LD50 = >2 gm/kg. 124 18 5 Solvent Yellow 43 19125-99-6 NA 125 19 6 Solvent Yellow 44 2478-20-8 NA 126 20 7 Solvent Yellow 72 61813-98-7 NA 127 21 8 Solvent Yellow 114 7576-65-0 NA 128 22 9 Solvent Yellow 131 71819-82-4 NA Acute oral toxicity: LD50(Rat): 129 23 10 Solvent Yellow 157 27908-75-4 8200mg/kg 106768-99- LD50 rat (oral): > 2,000 mg/kg 130 24 11 Solvent Yellow 163 4 (OECD Guideline 423) 131 25 12 Solvent Yellow 167 N.A. NA Group-3: Orange Solvent Dyes = 3 Acute oral toxicity: LD50(Rat): 132 26 1 Solvent Orange 60 61969-47-9 8090mg/kg Acute oral toxicity: LD50(Rat): 133 27 2 Solvent Orange 63 16294-75-0 8190mg/kg LD50 Intraperitoneal Rat=306 0 134 28 3 Solvent Orange 105 31482-56-1 MG/KG Group-4: Blue Solvent Dyes = 6 135 29 1 Solvent Blue 35 17354-14-2 NA Acute oral toxicity: LD50(Rat): 136 30 2 Solvent Blue 36 14233-37-5 8080mg/kg Acute oral toxicity: LD50(Rat): 137 31 3 Solvent Blue 97 61969-44-6 8200mg/kg 138 32 4 Solvent Blue 101 6737-68-8 NA 139 33 5 Solvent Blue 102 15403-56-2 NA

19 Not acutely toxic via the oral 140 34 6 Solvent Blue 104 116-75-6 route (LD50 > 5000 mg/kg bw) Group-5: Violet Solvent Dyes = 4 141 35 1 Solvent Violet 13 81-88-1 LD50 Oral, Rat. >500mg/kg Acute oral toxicity: LD50(Rat): 142 36 2 Solvent Violet 14 67577-84-8 8110mg/kg 143 37 3 Solvent Violet 38 63512-14-1 NA Acute oral toxicity: LD50(Rat): 144 38 4 Solvent Violet 59 6408-72-6 8220mg/kg Group-6: Green Solvent Dyes = 3 145 39 1 Solvent Green 3 128-80-3 LD50 = 3660 mg/kg ( Rat ) 146 40 2 Solvent Green 28 71839-01-5 LD50 = 3660 mg/kg ( Rat ) 147 41 3 Solvent Green 33 10671-57-8 NA Total of Category-B ( Group 1 + 2 + 3 + 4 + 5 + 6 ) 200

Total All Products Category - A(106) + Category-B (41) = 147 1200

Annexure : II

Construction Works

Layout Map of the Plant with Area Teble :-

Sr.No. Particular Area in Sq Mtrs 1 Process (Pigment and Solvent) 3675 2 Storage ( Raw Material and Finished Produst) 1102 3 Administration Office & Lab 200 4 Parking 500 5 Effluent treatment Plant 750 6 Green Belt 3960 7 Open Space for Roads, Loading & unloading 2058 Total Land Area 12,000

21 Annexure : III

Production and Manufacturing Process with Chemical Reaction and Mass Balance Detail

Total Number of Pigments Total Quantity per Month A Pigments (1 + 2 + 3 + 4 + 5 ) = 106 ( 1 + 2 + 3 + 4 + 5 ) = 1000 MT per Month

1 Pigment Red Quantity per Month = 200 MT per Month

1) Pigment Red 2 cas no.6041-94-7:- Manufacturing Process: - 2,5 DCA cas no.95-82-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol AS cas no. 92-77-3. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed. a. Diazotization of DCPNA DCPNA Diazotization DCPNA Diazo C6H5CI 2N + 2HCI + NaNO 2 C6H3CI3N 2 + NaCI + 2H 2O Mol.Wt. 162 + 73 + 69 185.5 + 58.5 + 36 b. Coupling with Naphthol AS DCPNA Diazo + Naphthol AS + C.S. Flacks Coupling Pigment Red 2 C6H3CI3N 2 + C 17 H13 NO 2+ NaOH C23 H15 CI 2N3O2+ H 2O + NaCI Mol.Wt. 185.5 + 263 +40 436 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: - Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2955 2 ICE 2000 Washing water for Re-Use 3000 3 DCPNA 390 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 170 6 Naphthol AS 610 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9955 TOTAL 9955

2) Pigment Red 3 cas no.2425-85-6:-

Manufacturing Process: -

Red G Base/ MNPT89-62-3 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol. Cas no. 135-19-3 Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of Red G Base

Red G Base Diazotization Red G Base Diazo C7H8N2O2 + 2HCI + NaNO 2 C7H6CIN 3O2 + NaCI + 2H 2O Mol.Wt. 152+ 73 + 69 199.5 + 58.5 + 36

b. Coupling with B-Naphthol Red G Base Diazo + B-Naphthol + C.S. Flacks Coupling Pigment Red 3 C7H6CIN 3O2 + C 10 H8O+ NaOH C17 H13 N3O3 + H 2O + NaCI Mol.Wt. 199.5 + 144 +40 307 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2795 2 ICE 2000 Washing water for Re -Use 3000 3 Red G Base 525 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 195 6 B-Naphthol 490 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9795 TOTAL 9795

3) Pigment Red 4 cas no.2814-77-9:-

Manufacturing Process: -

OCPNA cas no.121-87-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol cas no.135-19-3 . Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of OCPNA

OCPNA Diazotization OCPNA Diazo C6H5CIN 2O2 + 2HCI + NaNO 2 C6H3CI 2N3O2 + NaCI + 2H 2O Mol.Wt. 172.5+ 73 + 69 220 + 58.5 + 36

b. Coupling with B-Naphthol

OCPNA Diazo + B-Naphthol + C.S. Flacks Coupling Pigment Red 4 C6H3CI 2N3O2 + C 10 H8O + NaOH C16 H10 CIN 3O3+ H 2O + NaCI Mol.Wt. 220 + 144 + 40 327.5 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2780 2 ICE 2000 Washing water for Re-Use 3000 3 OCPNA 550 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 200 6 B-Naphthol 445 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9780 TOTAL 9780

4) Pigment Red 5 cas no.6410-41-9 :-

Manufacturing Process: -

Fast Red ITR cas no.6410-41-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol AS ITR cas no.92-72-8. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of Fast Red ITR

Fast Red ITR Diazotization Fast Red ITR Diazo C11 H18 N2O3S + 2HCI + NaNO 2 C11 H18 CIN 2O3S + NaCI + 2H 2O Mol.Wt. 258 + 73 + 69 305.5 + 58.5 + 36 b. Coupling with Naphthol ASITR

Fast Red ITR Diazo + Naphthol ASITR + C.S. Flacks Coupling Pigment Red 5 C11 H18 CIN 2O3S +C 19 H16 CINO 4 + NaOH C30 H31 CIN 4O7S+ H 2O + NaCI Mol.Wt. 305.5 + 357.5 + 40 626.5 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2720 2 ICE 2000 Washing water for Re -Use 3000 3 Fast Red ITR 450 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 130 6 Naphthol ASITR 555 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9720 TOTAL 9720

5) Pigment Red 12 cas no.6410-32-8: -

Manufacturing Process: -

2-Methyl,4-Nitro Toludine [PNPT 99-52-5] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol ASD cas no. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of PNPT

PNPT Diazotization PNPT Diazo C7H8N2O2 + 2HCI + NaNO 2 C7H6CIN 3O2 + NaCI + 2H 2O Mol.Wt. 152 + 73 + 69 199.5 + 58.5 + 36

b. Coupling with Naphthol ASD

PNPT Diazo + Naphthol AS D + C.S. Flacks Coupling Pigment Red 12 C7H6CIN 3O2 +C 18 H15 NO 2+ NaOH C25 H20 N4O4 + H 2O + NaCI Mol.Wt. 199.5 + 277 +40 440 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2785 2 ICE 2000 Washing water for Re -Use 3000 3 PNPT 360 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 160 6 Naphthol ASD 680 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9785 TOTAL 9785

6)Pigment Red 14[ CAS No.6471-50-7 ]: -

Manufacturing Process: -

p-Chloro-O-nitro aniline [PCONA CAS No.89-63-4] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol ASD [ CAS No. 135-61-5]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of PCONA

PCONA Diazotization PCONA Diazo C6H5CIN 2O2 + 2HCI + NaNO 2 C6H3CI 2N3O2 + NaCI + 2H 2O Mol.Wt. 172.5+ 73 + 69 220 + 58.5 + 36 b. Coupling with Naphthol ASD

PCONA Diazo + Naphthol ASDL + C.S. Flacks Coupling Pigment Red 14 C6H3CI 2N3O2 +C 18 H15 NO 2+ NaOH C24 H17 CIN 4O4 + H 2O + NaCI Mol.Wt. 220 + 277 +40 460.5 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Recycled Water 3000 Effluent to ETP 2750 2 ICE 2000 Washing wa ter for Re -Use 3000 3 PCONA 405 Water Evaporation in 3000 Drying 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 150 6 Naphthol ASD 610 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9750 TOTAL 9750

7) Pigment Red 38 cas no.6358-87-8:-

Manufacturing Process: -

3,3-Dichloro Benzidine [3,3-DCB cas no.91-94-4] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mole 1-p-tolyl-3-methyl-5-pyrazolone [PCEP / Carb Ethox.cas no.99-33-8 ]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of 3,3-DCB

3,3-DCB Diazotization 3,3-DCB Diazo C12 H10 N2CI 2+ 4HCI + 2NaNO 2 C12 H6 N4CI 4 + 2NaCI + 4 H 2O Mol.Wt. 253 + 146 + 138 348 + 117 + 72

b. Coupling with PCEP

3-3-DCB Diazo + PCEP + C.S. Flacks Coupling Pigment Red 38 C12 H6 N4CI 4 +2[C 12 H12 N2O3] +2NaOH C36 H28 Cl 2N8O6+ 2H 2O + 2NaCI Mol.Wt. 348 + 464 +80 739 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2995 2 ICE 2200 Washing water for Re-Use 3000 3 3,3-DCB 350 Water Evaporation in Drying 3000 4 HCI 415 Finish Product 1000 5 Sodium Nitrite 190 6 PCEP 640 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9995 TOTAL 9995

8) Pigment Red 48:1 cas no.7585-41-3:-

Manufacturing Process: -

2B Acid cas no.88-51-7 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid cas no.92-70-6. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Barium Chloride is added & is heated up to 75 to 80 0C to form Barium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 2B Acid

2B Acid Diazotization 2B Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5+ 73 + 69 269 + 58.5 + 36 b. Coupling with BON Acid

2B Acid Diazo+ BON Acid +C.S.Flacks Coupling Pigment Red 48:1 C7H6CI 2N2O3S I+ C 11 H8O3+3NaOH +BaCI 2 C18 H11 CIN 2O6S.Ba + 3H 2O + 3NaCI Mol.Wt. 269 + 188 + 120 + 208 555.5 + 54 + 175.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3063 2 ICE 2000 Washing water for Re -Use 3000 3 2B Acid 550 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 170 6 BON Acid 468 7 C.S.Flacks 200 8 Barium Chloride 200 9 Fresh Water for Washing 3000 TOTAL 10063 TOTAL 10063

9) Pigment Red 48:2 cas no.7023-61-2:-

Manufacturing Process: -

2B Acid cas no 88-51-7. is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid cas no.92-70-6 . Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of 2B Acid

2B Acid Diazotization 2B Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36

b. Coupling with BON Acid

2B Acid Diazo+ BON Acid + C.S. Flacks Coupling Pigment Red 48:2 C7H6CI 2N2O3S I+ C 11 H8O3+3NaOH +CaCI 2 C18 H11 CIN 2O6S.Ca + 3H 2O + 3NaCI Mol.Wt. 269 + 188 + 120 + 111 458.5 + 54 + 175.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3113 2 ICE 2000 Washing water for Re -Use 3000 3 2B Acid 550 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 170 6 BON Acid 468 7 C.S.Flacks 20 0 8 Calcium Chloride 250 9 Fresh Water for Washing 3000 TOTAL 10113 TOTAL 10113

10) Pigment Red 48:3 cas no.15782-05-5:-

Manufacturing Process: -

2B Acid cas no 88-51-7 . is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid cas no.92-70-6. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Strontium Chloride is added & is heated up to 75 to 80 0C to form Strontium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of 2B Acid

2B Acid Diazotization 2B Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36

b. Coupling with BON Acid

2B Acid Diazo+ BON Acid +C.S.Flacks Coupling Pigment Red 48:3 C7H6CI 2N2O3S I+ C 11 H8O3+3NaOH +SrCI 2 C18 H11 CIN 2O6S.Sr + 3H 2O + 3NaCI Mol.Wt. 269 + 188 + 120 + 158.5 505.5 + 54 + 175.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3103 2 ICE 2000 Washing water for Re -Use 3000 3 2B Acid 550 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 170 6 BON Acid 468 7 C.S.Flacks 200 8 Strontium Chloride 240 9 Fresh Water for Washing 3000 TOTAL 10103 TOTAL 10103

11) Pigment Red 48:4 cas no. 5280-66-0:-

Manufacturing Process: -

2B Acid cas no.88-51-7 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid cas no.92-70-6. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Manganese Chloride is added & is heated up to 75 to 80 0C to form Manganese Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of 2B Acid

2B Acid Diazotization 2B Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36

b. Coupling with BON Acid

2B Acid Diazo+ BON Acid +C.S.Flacks Coupling Pigment Red 48:4 C7H6CI 2N2O3S I+ C 11 H8O3+3NaOH +MnCI 2 C18 H11 CIN 2O6S.Mn + 3H 2O + 3NaCI Mol.Wt. 269 + 188 + 120 + 126 473.5 + 54 + 175.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycl ed Water 3000 Effluent to ETP 3108 2 ICE 2000 Washing water for Re-Use 3000 3 2B Acid 550 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 170 6 BON Acid 468 7 C.S.Flacks 200 8 Manganese Chloride 245 9 Fresh W ater for Washing 3000 TOTAL 10108 TOTAL 10108

12) Pigment Red 48:5 [ cas no. N.A.]:-

Manufacturing Process: -

2B Acid cas no.88-51-7 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid cas no.92-70-6. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Magnesium Chloride is added & is heated up to 75 to 80 0C to form Magnesium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of 2B Acid

2B Acid Diazotization 2B Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36

b. Coupling with BON Acid

2B Acid Diazo+ BON Acid + C.S. Flacks Coupling Pigment Red 48:5 C7H6CI 2N2O3S I+ C 11 H8O3+3NaOH +MgCI 2 C18 H11 CIN 2O6S.Mg + 3H 2O + 3NaCI Mol.Wt. 269 + 188 + 120 + 95 442.5 + 54 + 175.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3108 2 ICE 2000 Washing water for Re -Use 3000 3 2B Acid 550 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 170 6 BON Acid 468 7 C.S.Flacks 200 8 Magnesium Chloride 245 9 Fresh Water for Washing 3000 TOTAL 10108 TOTAL 10108

13) Pigment Red 49 [ cas no.1248-18-6]: -

Manufacturing Process: -

Tobias Acid cas no.81-16-3 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol cas no.135-19-3 Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Sodium Hydroxide is added & is heated up to 75 to 80 0C to form Sodium Salt & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of Tobias Acid

Tobias Acid Diazotization Tobias Acid Diazo C10 H9NO 3S + 2HCI + NaNO 2 C10 H7CIN 2O3S + NaCI + 2 H 2O Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36

b. Coupling with B-Naphthol

2B Acid Diazo+ B-Naphthol+C.S. Flacks Coupling Pigment Red 49 C10 H7CIN 2O3S + C 10 H8O +2NaOH C20 H13 N2O4S.Na + 2H 2O + N aCI Mol.Wt. 270.5 + 144 + 80 400 + 36 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3100 2 ICE 2000 Washing water for Re -Use 3000 3 Tobias Acid 600 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 185 6 B-Naphthol 395 7 C.S.Flacks 200 8 Sodium Hydroxide 245 9 Fresh Water for Washing 3000 TOTAL 10100 TOTAL 10100

14) Pigment Red 49:1 [ cas no.1103-38-4]: -

Manufacturing Process: -

Tobias AcidCAS No.81-16-3 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol 135-19-3. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Barium Chloride is added & is heated up to 75 to 80 0C to form Barium Salt & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of Tobias Acid

Tobias Acid Diazotization Tobias Acid Diazo C10 H9NO 3S + 2HCI + NaNO 2 C10 H7CIN 2O3S + NaCI + 2 H 2O Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36

b. Coupling with B-Naphthol

2B Acid Diazo+ B-Naphthol+C.S. Flacks Coupling Pigment Red 49:1 C10 H7CIN 2O3S + C 10 H8O+2NaOH + 1/2 BaCl 2 C20 H13 N2O4S.Ba 1/2 + 2H 2O + 2NaCI Mol.Wt. 270.5 + 144 + 80 + 104.5 446 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3100 2 ICE 2000 Washing water for Re -Use 3000 3 Tobias Acid 600 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 185 6 B-Naphthol 395 7 C.S.Flacks 200 8 Barium chloride 245 9 Fresh Water for Washing 3000 TOTAL 10100 TOTAL 10100

15) Pigment Red 49:2 cas no. 1103-39-5: -

Manufacturing Process: -

Tobias Acid CAS No.81-16-3 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol 135-19-3. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of Tobias Acid

Tobias Acid Diazotization Tobias Acid Diazo C10 H9NO 3S + 2HCI + NaNO 2 C10 H7CIN 2O3S + NaCI + 2 H 2O Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36

b. Coupling with B-Naphthol

2B Acid Diazo+ B-Naphthol+C.S. Flacks Coupling Pigment Red 49:2 C10 H7CIN 2O3S + C 10 H8O+2NaOH + 1/2 CaCI 2 C20 H13 N2O4S.Ca 1/2 + 2H 2O + 2NaCI Mol.Wt. 270.5 + 144 + 80 + 55 396.5 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product : -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3063 2 ICE 2000 Washing water for R e-Use 3000 3 Tobias Acid 600 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 185 6 B-Naphthol 395 7 C.S.Flacks 200 8 Calcium Chloride 208 9 Fresh Water for Washing 3000 TOTAL 10063 TOTAL 10063

16)Pigment Red 49:3 [ CAS NO.6371-67-1]: -

Manufacturing Process: -

2-Amino-1-naphthalene Sulphonic acid. [ Tobias Acid CAS No.81-16-3] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol [ CAS NO.135-19-3]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Strontium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of Tobias Acid

Tobias Acid Diazotization Tobias Acid Diazo C10 H9NO 3S + 2HCI + NaNO 2 C10 H7CIN 2O3S + NaCI + 2 H 2O Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36

b. Coupling with B-Naphthol

Tobias Acid Diazo+ B-Naphthol+C.S. Flacks Coupling Pigment Red 49:3 C10 H7CIN 2O3S + C 10 H8O+3NaOH +SrCI 2 C17 H13 CIN 2O4S.Sr 1/2 + 3H 2O + 3NaCI Mol.Wt. 270.5 + 144 + 120 + 158.5 463.5 + 54 + 175.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2986 2 ICE 2000 Washing water for Re -Use 3000 3 Tobias Acid 598 Water Evaporation in Drying 3000 4 HCI 405 Finish Product 1000 5 Sodium Nitrite 185 6 B-Naphthol 390 7 C.S. Flacks 200 8 Strontium Chloride 208 9 Fresh Water for Washing 3000 TOTAL 9986 TOTAL 9986

17) Pigment Red 52:1 cas no.17852-99-2: -

Manufacturing Process: -

C Acid cas no.88-53-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid cas no.92-70-6 Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of C Acid

C Acid Diazotization C Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36

b. Coupling with BON Acid

C Acid Diazo+ BON Acid +C.S. Flacks Coupling Pigment Red 52:1 C7H6CI 2N2O3S + C 11 H8O3+2NaOH +1/2CaCI 2 C18 H12 CIN 2O6S.Ca 1/2 + 2H 2O + 2NaCI Mol.Wt. 269 + 188 + 80 + 55.5 439.5 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Ef fluent to ETP 3090 2 ICE 2000 Washing water for Re -Use 3000 3 C Acid 550 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 205 6 BON Acid 455 7 C.S. Flacks 200 8 Calcium Chloride 205 9 Fresh Water for Washing 3000 TOTAL 10090 TOTAL 10090

18) Pigment Red 52:2 [ cas no.12238-31-2]: -

Manufacturing Process: -

C Acid cas no.88-53-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid cas no.92-70-6. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Manganese Chloride is added & is heated up to 75 to 80 0C to form Manganese Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of C Acid

C Acid Diazotization C Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36

b. Coupling with BON Acid

C Acid Diazo+ BON Acid +C.S. Flacks Coupling Pigment Red 52:2 C7H6CI 2N2O3S + C 11 H8O3+2NaOH + 1/2 MnCI 2 C18 H12 CIN 2O6S.Mn /2 + 2H 2O + 2NaCI Mol.Wt. 269 + 188 + 80 + 62.5 446.5 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 300 0 Effluent to ETP 3100 2 ICE 2000 Washing water for Re -Use 3000 3 C Acid 550 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 205 6 BON Acid 455 7 C.S. Flacks 200 8 Manganese Chloride 215 9 Fresh Water for Washing 3000 TOTAL 10100 TOTAL 10100

19) Pigment Red 53 cas no. 2092-56-0 :-

Manufacturing Process: -

C-Acid cas no.88-53-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol cas no.135-19-3. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Sodium Hydroxide is added & is heated up to 75 to 80 0C to form sodium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of C Acid

C Acid Diazotization C Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36

b. Coupling with B-Naphthol

C Acid Diazo+ B-Naphthol+C.S. Flacks Coupling Pigment Red 53 C7H6CI 2N2O3S + C 10 H8O+2NaOH C17 H12 CIN 2O4S.Na + 2H 2O + NaCI Mol.Wt. 269 + 144 + 80 399 + 36 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3120 2 ICE 2000 Washing water for Re -Use 3000 3 560 Water Evaporation in Drying 3000 C- Acid 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 205 6 B-Naphthol 435 7 C.S. Flacks 200 8 Sodium Hydroxide 245 9 Fresh Water for Washing 3000 TOTAL 10120 TOTAL 10120

20) Pigment Red 53:1 cas no.5160-02-1 :-

Manufacturing Process: -

C-Acid cas no.88-53-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol cas no.135-19-3. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Barium Chloride is added & is heated up to 75 to 80 0C to form Barium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of C Acid

C Acid Diazotization C Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36

b. Coupling with B-Naphthol

C Acid Diazo+ B-Naphthol+C.S. Flacks Coupling Pigment Red 53:1 C7H6CI 2N2O3S + C 10 H8O+2NaOH +1/2BaCI 2 C17 H13 N2O4S.Ba 1/2 + 2H 2O + 2NaCI Mol.Wt. 269 + 144 + 80 + 104 444 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3120 2 ICE 2000 Washing water for Re -Use 3000 3 C- Acid 560 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 205 6 B-Naphthol 435 7 C.S. Flacks 200 8 Barium Chloride 245 9 Fresh Water for Washing 3000 TOTAL 10120 TOTAL 10120

21) Pigment Red 53:3 [ CAS NO.73263-40-8]: -

Manufacturing Process: -

2-amino-4-methyl-5-chloro benzene Sulphonic acid [C Acid CAS No.88-53-9] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol [ CAS NO.135-19-3]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Strontium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of C Acid

C Acid Diazotization C Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36 b. Coupling with B-Naphthol

C Acid Diazo+ B-Naphthol+C.S. Flacks Coupling Pigment Red 53:3 C7H6CI 2N2O3S + C 10 H8O+3NaOH +SrCI 2 C17 H13 CIN 2O4S.Sr 1/2 + 3H 2O + 3 NaCI Mol.Wt. 269 + 144 + 120 + 158.8 462.5 + 54 + 175.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2986 2 ICE 2000 Washing water for Re -Use 3000 3 C Acid 598 Water Evaporation in Drying 3000 4 HCI 405 Finish Product 1000 5 Sodium Nitrite 185 6 B-Naphthol 390 7 C.S. Flacks 200 8 Strontium Chloride 208 9 Fresh Water for Washing 3000 TOTAL 99 86 TOTAL 9986

22) Pigment Red 57:1 cas no. 5281-04-9: -

Manufacturing Process: -

4B Acid cas no88-44-8 . is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid cas no.92-70-6. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of 4B Acid

4B Acid Diazotization 4B Acid Diazo C7H9NO 3S + 2HCI + NaNO 2 C7H7CIN 2O3S + NaCI + 2 H 2O Mol.Wt. 187 + 73 + 69 234.5 + 58.5 + 36

b. Coupling with BON Acid

4B Acid Diazo+ BON Acid +C.S. Flacks Coupling Pigment Red 57:1 C7H7CIN 2O3S + C 11 H8O3+ 3NaOH + CaCI 2 C18 H12 N2O6S.Ca + 3H 2O + 3NaCI Mol.Wt. 234.5+ 188 + 120 + 111 424 + 54 + 175.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3090 2 ICE 2000 Washing w ater for Re -Use 3000 3 4B Acid 530 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 205 6 BON Acid 475 7 C.S. Flacks 200 8 Calcium Chloride 205 9 Fresh Water for Washing 3000 TOTAL 10090 TOTAL 10090

23) Pigment Red 63:1[ cas no.6417-83-0]: -

Manufacturing Process: -

Tobias Acid [ cas no.81-16-3]is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid [cas no.92-70-6]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of Tobias Acid

Tobias Acid Diazotization Tobias Acid Diazo C10 H9NO 3S + 2HCI + NaNO 2 C10 H7CIN 2O3S + NaCI + 2 H 2O Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36 b. Coupling with BON Acid

Tobias Acid Diazo+ BON Acid +C.S. Flacks Coupling Pigment Red 63:1 C10 H7CIN 2O3S + C 11 H8O3+ 3NaOH + CaCI 2 C21 H12 N2O6S.Ca + 3H 2O + 3NaCI Mol.Wt. 270.5 + 188 + 120 + 111 460 + 54 + 175.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3090 2 ICE 2000 Washing water for Re -Use 3000 3 Tobias Acid 530 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 205 6 BON Acid 475 7 C.S. Flacks 200 8 Calcium Chloride 205 9 Fresh Water for Washing 3000 TOTAL 10090 TOTA L 10090

24) Pigment Red 63:2 [ CAS No.35355-77-2]: -

Manufacturing Process: - 2-Amino-1-Naphthalenesulphonic Acid [Tobias Acid CAS No.81-18-3] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid [CAS No.92-70-6]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Manganese Chloride is added & is heated up to 75 to 80 0C to form Manganese Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of Tobias Acid Tobias Acid Diazotization Tobias Acid Diazo C10 H9NO 3S + 2HCI + NaNO 2 C10 H7CIN 2O3S + NaCI + 2 H 2O Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36

b. Coupling with BON Acid Tobias Acid Diazo+ BON Acid +C.S. Flacks Coupling Pigment Red 63:2 C10 H7CIN 2O3S + C 11 H8O3+ 2NaOH + 1/2 MnCI 2 C21 H14 N2O6S.Mn 1/2 + 2H 2O + 2NaCI Mol.Wt. 270.5 + 188 + 80 + 62.5 448 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in K gs 1 Recycled Water 3000 Effluent to ETP 3015 2 ICE 2000 Washing water for Re -Use 3000 3 Tobias Acid 530 Water Evaporation in Drying 3000 4 HCI 405 Finish Product 1000 5 Sodium Nitrite 200 6 BON Acid 475 7 C.S. Flacks 200 8 Manganese Chloride 205 9 Fresh Water for Washing 3000 TOTAL 10015 TOTAL 10015

45 25) Pigment Red 81 PMA salt [ cas no. 12224-98-5.]:-

Manufacturing Process: -

2 Moles of 3-[(ethyl amino)-4-methyl Phenol [ EAMP]Cas No.120-37-6 is condensed with phthalic Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into phosphomolybdic acid salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of EAMP with Phthalic Anhydride: -

EAMP Phthalic Anhydride + Condensation Pigment Red 81 Hydroxide Ethanol hydride 2[ C 9H13 NO ] + C 8H4O3 + C 2H5OH C28 H31N2O3PMA Salt + H 5O3 Mol.Wt. 2 x 151 + 148 + 46 443+PMA salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 EAMP 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re -use 950 3 Ethanol 1000 Washing water for Re -Use 2000 4 Phosphomolybdic acid [ PMA] 100 Evaporation loss 1265 5 Water for Washing 3000 TOTAL 5215 TOTAL 5215

26) Pigment Red 81:1 SMT salt [ cas no.80083-40-5]:-

Manufacturing Process: -

2 Moles of 3-[(ethyl amino)-4-methyl Phenol [ EAMP]Cas No.120-37-6 is condensed with phthalic Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into Silicotungstomolybdic [SMT ] acid salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of EAMP with Phthalic Anhydride: -

EAMP Phthalic Anhydride + Condensation Pigment Red 81:1 Hydroxide Ethanol hydride 2[ C 9H13 NO ] + C 8H4O3 + C 2H5OH C28 H31 N2O3SMT Salt + H 5O3 Mol.Wt. 2 x 151+ 148 + 46 443+SMT salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 EAMP 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re-use 950 3 Ethanol 1000 Washing water for Re -Use 2000 4 Silicotungstomolybdic [SMT ] acid 100 Evaporation loss 1265 5 Water for Washing 3000 TOTAL 5215 TOTAL 5215

27) Pigment Red 81:x PM salt[ cas no.63022-06-0 .]:-

Manufacturing Process: -

2 Moles of 3-[(ethyl amino)-4-methyl Phenol [ EAMP]Cas No.120-37-6 is condensed with phthalic Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into Phosphoric molybdic [PM]acid salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of EAMP with Phthalic Anhydride: -

EAMP Phthalic Anhydride + Condensation Pigment Red 81:x Hydroxide Ethanol hydride 2[ C 9H13 NO ] + C 8H4O3 + C 2H5OH C28 H31 N2O3PM Salt + H 5O3 Mol.Wt. 2 x 151+ 148 + 46 443+PM salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 EAMP 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re -use 950 3 Ethanol 1000 Washing water for Re-Use 2000 4 Phosphoric molybdic [PM]acid 100 Evaporation loss 1265 5 Water for Washing 3000 TOTAL 5215 TOTAL 5215

28) Pigment Red 81:y SM salt [ cas no.N.A.]:-

Manufacturing Process: -

2 Moles of 3-[(ethyl amino)-4-methyl Phenol [ EAMP]Cas No.120-37-6 is condensed with phthalic Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into Silicomolybdic [SM]acid salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of EAMP with Phthalic Anhydride: -

EAMP Phthalic Anhydride + Condensation Pigment Red 81:x Hydroxide Ethanol hydride 2[ C 9H13 NO ] + C 8H4O3 + C 2H5OH C28 H31 N2O3SM Salt + H 5O3 Mol.Wt. 2 x 151 + 148 + 46 443+SM salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 EAMP 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re -use 950 3 Ethanol 1000 Washing water for Re-Use 2000 4 Silicomolybdic [SM]acid 100 Evaporation loss 1265 5 Water for Washing 3000 TOTAL 5215 TOTAL 5215

49 29) Pigment Red 81:2 SM Salt[ cas no..75627-12-2]:-

Manufacturing Process: -

2 Moles of 3-[(ethyl amino)-4-methyl Phenol [ EAMP]Cas No.120-37-6 is condensed with phthalic Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into Silicomolybdic [SM]acid salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of EAMP with Phthalic Anhydride: -

EAMP Phthalic Anhydride + Condensation Pigment Red 81:x Hydroxide Ethanol hydride 2[ C 9H13 NO ] + C 8H4O3 + C 2H5OH C28 H31 N2O3SM Salt + H 5O3 Mol.Wt. 2 x 151 + 148 + 46 443+SM salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 EAMP 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re -use 950 3 Ethanol 1000 Washing water for Re -Use 2000 4 Silicomolybdic [SM]acid 100 Evaporation loss 1265 5 Water for Washing 3000 TOTAL 5215 TOTAL 5215

50 30) Pigment Red 81:3 PM Salt [ cas no.68310-07-6 .]:-

Manufacturing Process: -

2 Moles of 3-[(ethyl amino)-4-methyl Phenol [ EAMP]Cas No.120-37-6 is condensed with phthalic Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into Phosphoric molybdic [PM]acid salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of EAMP with Phthalic Anhydride: -

EAMP Phthalic Anhydride + Condensation Pigment Red 81:x Hydroxide Ethanol hydride 2[ C 9H13 NO ] + C 8H4O3 + C 2H5OH C28 H31 N2O3pM Salt + H 5O3 Mol.Wt. 2 x 151+ 148 + 46 443+PM salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 EAMP 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for R e-use 950 3 Ethanol 1000 Washing water for Re -Use 2000 4 Phosphoric molybdic [PM]acid 80 Evaporation loss 1245 5 Water for Washing 3000 TOTAL 5195 TOTAL 5195

31) Pigment Red 81:4 PTMA salt[ cas no.85959-61-1 .]:-

Manufacturing Process: -

2 Moles of 3-[(ethyl amino)-4-methyl Phenol [ EAMP]Cas No.120-37-6 is condensed with phthalic Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into Phosphotungstomolybdic [PTMA] acid salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of EAMP with Phthalic Anhydride: -

EAMP Phthalic Anhydride + Condensation Pigment Red 81:x Hydroxide Ethanol hydride 2[ C 9H13 NO ] + C 8H4O3 + C 2H5OH C28 H31 N2O3PTMA Salt + H 5O3 Mol.Wt. 2 x 151 + 148 46 443+PTMA salt 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 EAMP 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re -use 950 3 Ethanol 1000 Washing water for Re-Use 2000 4 Phosphotungstomolybdic [PTMA] acid 80 Evaporation loss 1245 5 Water for Washing 3000 TOTAL 5195 TOTAL 5195

52 32) Pigment Red 112 cas no.6535-46-2: -

Manufacturing Process: -

2,4,5-Trichloroaniline [TCA cas no.636-30-6] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol ASD cas no.135-61-5 . Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C to& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of TCA

TCA Diazotization TCA Diazo C6H4CI 3N + 2HCI + NaNO 2 C6H2CI 4N2 + NaCI + 2 H 2O Mol.Wt. 196.5+ 73 + 69 244 + 58.5 + 36 b. Coupling with Naphthol ASD

TCA Diazo+ Naphthol ASD +C.S. Flacks Coupling Pigment Red 112 C6H2CI 4N2 + C 18 H15 NO 2 + NaOH C24 H16 CI 3N3O2 + H 2O + NaCI Mol.Wt. 244 + 277 + 40 484.5 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Recycled Water 3000 Effluent to ETP 2730 2 ICE 2000 Washing water for Re -Use 3000 3 TCA 410 Water Evaporation in 3000 Drying 4 HCI 395 Finish Product 1000 5 Sodium Nitrite 150 6 Naphthol ASD 575 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9730 TOTAL 9730

33) Pigment Red 122 [ CAS NO. 980-26-7 /16043-40-6.]: -

Manufacturing Process: -

1. Dimethyl Succinosuccinate [DMSS CAS No.6289-46-9] is condensed with 2 moles of p- Toluidine in methanol under efflux condition to form 2,5-diaryl amino-3,6-dihydroxy terephthalate [ DADHT]. 2. Then resulting product is oxidised with resist salt to form 2,5-di -p-toluidino -terephthalic acid dimethyl ester [DTTA-DME dimethyl ester CAS No.114508-42-8]. 3. Then it is hydrolyzed in alkaline condition & aqueous medium to form 2,5-Bis-(p-toluidino) terephthalic acid [DTTP Acid CAS.No. 10291-28-8] 4. Then it is further cyclised in presence of Poly phosphoric acid then finally pigmentation is done in presence of IBA/DMF as per Quinacridone as Pigment Red 122

1.Condensation of DMSS with p-Toluidine: - DMSS + 2[p-Toluidine] Condensation DADHT C10 H12 O6 + 2[C 7H9N] C24 H26 N2O4 + 2H 2O Mol.Wt.228 + 2X[107] Methanol 406 + 36

2.Oxidation Of DADHT with Resist Salt: - DADHT Condensation DTTA dimethyl ester C24 H26N2O4 + O 2 C24 H24 N2O4 + H 2O2 Mol.Wt. 406 + 32 Resist Salt 404 + 34

3.Hydrolysis of DTTA dimethyl ester:- DTTA dimethyl ester Hydrolysis DTTP Acid C24 H24 N2O4 + 2NaOH +2HCL C22 H20 N2O4 + 2NaCI + 2CH 3OH Mol.Wt. 404 + 80 + 73 Methanol 376 + 117 + 64

4.Cyclisation of DTTP Acid with Poly Phosphoric Acid & Pigmentation to form Pigment Red 122:- DTTP Acid Poly Phosphoric Cyclisation Pigment Red 122 Triphosphoric Acid acid monohydrate C22 H20 N2O4 + C22 H16 N2O2 + H 5P3O10 .H 2O H3PO 4.P 2O5 Mol.Wt. 376 + 238 DMF /IBA 340 + 274

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Methanol 5500 Finish Product 1000 2 Dimethyl 800 Water Evaporation in Drying 2500 Succinosuccinate 3 p-Toluidine 880 Methanol Recov ery for Re -Use 5225 4 Resist Salt 300 Washing water for Re-Use 7000 5 NaOH 275 Effluent to ETP 7500 6 HCL 250 DMF /IBA Recovery for Re-Use 6650 7 Poly Phosphoric Acid 1800 Inorganic & solvent residue 680 8 DMF / IBA 7000 9 Water for Reaction 7000 10 Water for Isolation 7000 TOTAL 30555 TOTAL 30555

55 34) Pigment Red 123 [ CAS NO.24108-89-2]: -

Manufacturing Process: -

Perylene Tetracarboxydianhydride[ PTCDA cas no.128-69-8] is condensed with 2 mole of 3,5- Dimethylaniline [ 3,5-DMA cas no.108-69-0] in aqueous medium in reflux condition at 95--100 0C for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C by adding water for isolation. Then reaction mass is filtered. filtrate is sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed a. Condensation of Perylene Tetracarboxydianhydride with 3,5-Dimethylaniline: -

PTCDA 3,5-DMA Condensation Pigment Red 149 C24 H8O6+ 2[C 8H11 N] C40 H26 N2O4 + 2H 2O Mol.Wt. 392 + 2x 121 Water+ Pipyridine 598 + 36

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Water 3000 Finish Product 1000 2 PTCDA 650 Water Evaporation in Drying 2500 3 3,5 -DMA 395 Washing water for Re -Use 3000 4 Pipyridine 10 Effluent to ETP 2555 5 Water for I solation 2000 6 Water for Washing 3000 7 TOTAL 9055 TOTAL 9055

35) Pigment Red 144 cas no. 5280-78-4: - Manufacturing Process: - 2,5-DichloroAniline [DCA cas no ] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 3-Hydroxy,2-Naphthoyl Chloride. Coupled mass is stirred till coupling reaction gets complete. Then 2 moles of this monodye is condensed with 1 mole of 2-Chloro,1,4- Diaminobenzene 615-66-7 & heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of DCA MCA Diazotization MCADiazo C6H5CI 2N + 2HCI + NaNO 2 C6H3CI 3N2 + NaCI + 2 H 2O Mol.Wt. 162 + 73 + 69 209.5 + 58.5 + 36 b. Coupling with 3-H,2-Naphthoyl Chloride DCA Diazo + 3-H,2-Naphthoyl Chloride +C.S. Coupling Mono Dye Flacks C17 H9CI 3N2O2 + H 2O + NaCI C6H3CI 3N2 + C 11 H7CIO 2 + NaOH Mol.Wt. 209.5 + 206.5 + 40 379.5 + 18 + 58.5 c.Condensation with DABC 2 mole Mono Dye + DABC Coupling Pigment Red 144 2[C 17 H9CI 3N2O2] + C 6H7CIN 2 + 2NaOH C40 H23 CI 5N6O4 + 2H2O + 2NaCI Mol.Wt. 759 + 142.5 + 80 828.5 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Recycled Water 3000 Effluent to ETP 3005 2 ICE 2000 Washing water for Re -Use 3000 3 DCA 490 Water Evaporation in Drying 3000 4 HCI 395 Finish Product 1000 5 Sodium Nitrite 190 6 3-H,2-Naphthoyl Chloride 500 7 C.S. Flacks 250 8 DABC 180 9 Fresh Water for Washing 3000 TOTAL 10005 TOTAL 10005

36) Pigment Red 146 cas no.5280-68-2: -

Manufacturing Process: -

Fast Red KD Base cas no.120-35-4is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol AS LC cas no.137-92-1. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of Fast Red KD Base Fast Red KD Base Diazotization Fast Red KD Base Diazo C14 H14 N2O2 + 2HCI + NaNO 2 C14 H12 CIN 3O2 + NaCI + 2 H 2O Mol.Wt. 242 + 73 + 69 289.5 + 58.5 + 36 b. Coupling with Naphthol AS LC Fast Red KD Base Diazo+ Naphthol ASLC +C.S. Coupling Pigment Red 146 Flacks C33 H27 CIN 4O6 + H 2O + NaCI C14 H12 CIN 3O2 + C 19 H16 CINO 4 + NaOH Mol.Wt. 289.5 + 357.5 + 40 610.5 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Recycled Water 3000 Effluent to ETP 2740 2 ICE 2000 Washing water for Re -Use 3000 3 Fast Red KD Base 400 Water Evaporation in 3000 Drying 4 HCI 395 Finish Product 1000 5 Sodium Nitrite 150 6 Naphthol AS LC 595 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9740 TOTAL 9740

37) Pigment Red 168 [ cas no. 4378-61-4 ] :-

Anthanthrone Cas No.641-13-4 is Brominated with Liquid Bromine Cas No.7726-95-6 in water.Then filtered & Product is washed with Hot Water & washing water is reused in next batch for reaction in next batch & wet cake then it is dried in spin flash dryer, pulverized & packed

a. Bromination of Anthanthrone: -

Anthanthrone + Liquid Bromine Bromination Pigment Red 168 C22 H10 O2 ] + 2Br 2 C22 H8Br 2O2 + 2HBr Mol.Wt. 306 + 320 464 + 162

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Anthanthrone 800 Finish Product 1000 2 Liquid Bromine 205 3 Water for Reaction 200 0 Washing water for Re -Use 3000 4 Water for Washing 3000 Evaporation loss 2005 5 TOTAL 6005 TOTAL 6005

38) Pigment Red 169 CF [cas no. 12237-63-7 ] :-

Manufacturing Process: -

2 Moles of 3-[(ethyl amino)-4-methyl Phenol [ EAMP]Cas No.120-37-6 is condensed with phthalic Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into ferrous iron copper cyanide complex.[CF]acid salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of EAMP with Phthalic Anhydride: -

EAMP Phthalic Anhydride + Condensation Pigment Red 81:x Hydroxide Ethanol hydride 2[ C 9H13 NO ] + C8H4O3 + C 2H5OH C28 H31 N2O3 CF Salt + H 5O3 Mol.Wt. 2 x 151 + 148 + 46 443+CF salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 EAMP 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re -use 950 3 Ethanol 1000 Washing water for Re-Use 2000 4 ferrous iron copper cyanide complex 80 Evaporation loss 1245 5 Water for Was hing 3000 TOTAL 5195 TOTAL 5195

39) Pigment Red 170 [cas no 2786-76-7 ]: -

Manufacturing Process: -

p-Aminobenzamide2835-68-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol AS PH92-74-0. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of p-Aminobenzamide p-Aminobenzamide Diazotization PAB Diazo C7H8N2 + 2HCI + NaNO 2 C7H6CIN 3 + NaCI + 2 H 2O Mol.Wt. 136 + 73 + 69 183.5 + 58.5 + 36 b. Coupling with Naphthol AS PH

PAB Diazo + Naphthol AS PH +C.S. Flacks Coupling Pigment Red 170 C7H6CIN 3 + C 19 H17 NO 3 + NaOH C26 H22 N4O4 + H 2O + NaCI Mol.Wt. 183.5 + 307 + 40 454 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Recycled Water 3000 Effluent to ETP 2758 2 ICE 2000 Washing water for Re -Use 3000 3 p-Aminobenzamide 305 Water Evaporation in 3000 Drying 4 HCI 405 Finish Product 1000 5 Sodium Nitrite 160 6 Naphthol AS PH 688 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9758 TOTAL 9758

40)Pigment Red 175 cas no6985-92-8 : -

Manufacturing Process: -

Methyl-2-aminobenzoate [MAB cas no 134-20-3. ]is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2,3-dihydro-2-naphthylformamido Benzoimidazolone [DHNFBZ casa no. 26848-40-8 ]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of Methyl-2-aminobenzoate

MAB Diazotization MAB Diazo C8H9NO 2 + 2HCI + NaNO 2 C8H7CIN 2O2 + NaCI + 2 H 2O Mol.Wt. 151+ 73 + 69 198.5 + 58.5 + 36 b. Coupling with DHNFBZ

MAB Diazo + DHNFBZ +C.S. Flacks Coupling Pigment Red 175 C8H7CIN 2O2 + C 18 H13 N3O3 + NaOH C26 H19 N5O5 + H 2O + NaCI Mol.Wt. 215.5 + 319 + 40 481 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Recycled Water 3000 Effluent to ETP 2749 2 ICE 2000 Washing water for Re-Use 3000 3 Methyl-2-aminobenzoate 325 Water Evaporation in 3000 Drying 4 HCI 405 Finish Product 1000 5 Sodium Nitrite 154 6 DHNFBZ 665 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9749 TOTAL 9749

41) Pigment Red 176 cas no 12225-06-8: -

Manufacturing Process: -

Fast Red KD Base cas no. 120-35-4 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2,3-dihydro-2-naphthylformamido Benzoimidazolone [DHNFBZ cas no 26848-40-8]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of Fast Red KD Base

Fast Red KD Diazotization Fast Red KD Diazo C14 H14 N2O2 + 2HCI + NaNO 2 C14 H12 CIN 3O2 + NaCI + 2 H 2O Mol.Wt. 242 + 73 + 69 289.5 + 58.5 + 36 b. Coupling with DHNFBZ

Fast Red KD Diazo + DHNFBZ +C.S. Flacks Coupling Pigment Red 176 C14 H12 CIN 3O2 + C 18 H13 N3O3 + NaOH C32 H24 N6O5 + H 2O + NaCI Mol.Wt. 289.5 + 319 + 40 572 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Recycled Water 3000 Effluent to ETP 2777 2 ICE 2000 Washing water for Re-Use 3000 3 Fast Red KD Base 445 Water Evaporation in 3000 Drying 4 HCI 405 Finish Product 1000 5 Sodium Nitrite 162 6 DHNFBZ 565 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9777 TOTAL 9777

42) Pigment Red 177 [ CAS NO. 4051-63-2]: -

Manufacturing Process: -

Bromamine Acid [cas no.116-81-4] is self-condensed in Poly Propylene Glycol as a solvent in reflux condition with KOH & sodium chlorate at 125--130 0C for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C & isolated by Water. Then reaction mass is filtered. filtrate is distilled for recovery of Poly Propylene Glycol for recycle & remaining mass sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed a. Bromination: -

Anthraquinone 2KOH Sodium Condensation Pigment Red 177 Chlorate C28 H16 N2O4 + 2KBr +NaCI +H 2O +O 4 C22 H10 O2 + 2KOH + NaCIO 3 Mol.Wt. 306 + 2x 56 + 106 PPG 444.44 + 238 + 58.5 + 18 + 64

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Poly Propylene Glycol 2500 PPG recovery 2250 2 Bromamine Acid 1100 Finish Product 1000 3 KOH 250 Water Evaporation in Drying 2500 4 Sodium Chlorate 50 Washing water for Re -Use 3150 5 Water for Isolation 2000 6 Water for Washing 3000 7 TOTAL 8900 TOTAL 8900

43) Pigment Red 178 [ CAS NO. 3049-71-6]: -

Manufacturing Process: -

Perylene Tetracarboxydianhydride [PTCDA cas no.128-69-8] is condensed with 2 mole of Para amino Azobenzene [ PAAB cas no.60-09-3] in aqueous medium in reflux condition at 95--100 0C for 4- 5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C by adding water for isolation. Then reaction mass is filtered. filtrate is sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed a. Condensation of Perylene Tetracarboxydianhydride with Para Aminoazobenzene : -

PTCDA + PAAB Condensation Pigment Red 178 C24 H8O6 + 2[C 12 H11 N3] C48 H26 N6O4 + 2H 2O Mol.Wt. 392 + 2x 197 Water+ Pipyridine 750 + 36

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Water 3000 Finish Product 1000 2 PTCDA 650 Water Evaporation in Drying 2500 3 PAAB 515 Washing water for Re-Use 3000 4 Pipyridine 10 Effluent to ETP 2675 5 Water for Isolation 2000 6 Water for Washing 3000 7 TOTAL 9175 TOTAL 9175

44) Pigment Red 179 [ CAS NO. 5521-31-3]: -

Manufacturing Process: -

Perylene Tetracarboxydianhydride[ PTCDA cas no.128-69-8] is condensed with 2 mole of Mono methyl amine [ MMA cas no.74-89-5] in aqueous medium in reflux condition at 95--100 0C for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C by adding water for isolation. Then reaction mass is filtered. filtrate is sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed a. Condensation of Perylene Tetracarboxydianhydride with Mono methyl amine: -

PTCDA + MMA Condensation Pigment Red 179 C24 H8O6 + 2[CH 5N] C26 H14 N2O4 + 2H 2O Mol.Wt. 392 + 2x 31 Water+ Pipyridine 418 + 36

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Water 3000 Finish Product 1000 2 PTCDA 950 Water Evaporation i n Drying 2500 3 MMA 150 Washing water for Re-Use 3000 4 Pipyridine 50 Effluent to ETP 2705 5 Acetic Acid 55 6 Water for Isolation 2000 7 Water for Washing 3000 TOTAL 9205 TOTAL 9205

45) Pigment Red 188 cas no. 61847-48-1: -

Manufacturing Process: -

4-Carbomethoxy-3-Amino, 2, 5 Dichloro Benzanilide [OPLA cas no.59673-82-4] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol ASOL cas no.135-62-6. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of OPLA

OPLA Diazotization OPLA Diazo C15 H12 CIN 2O3+ 2HCI + NaNO 2 C15 H10 CI 2N3O3 + NaCI + 2 H 2O Mol.Wt. 339 + 73 + 69 386.5 + 58.5 + 36 b. Coupling with Naphthol ASOL

OPLA Diazo + Naphthol ASOL +C.S. Flacks Coupling Pigment Red 188 C15 H10 CI 2N3O3 + C 18 H15 NO 3 + NaOH C33 H24 CI 2N4O6+ H 2O + NaCI Mol.Wt. 386.5 + 293 + 40 643 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Recycled Water 3000 Effluent to ETP 2770 2 ICE 2000 Washing water for Re -Use 3000 3 OPLA 555 Water Evaporation in 3000 Drying 4 HCI 435 Finish Product 1000 5 Sodium Nitrite 135 6 Naphthol ASOS 445 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9770 TOTAL 9770

46) Pigment Red 202 [ CAS NO. 3089-17-6]: -

Manufacturing Process: -

1. Dimethyl Succinosuccinate [DMSS CAS No.6289-46-9] is condensed with 2 moles of 4-Chloro aniline [CAS No.106-47-8] in methanol under efflux condition to form 2,5-di(p-chloroanilino- 3,6-dihydroxy terephthalate [ DPCADHT]. 2. Then resulting product is oxidised with resist salt to form 2,5-di -p-chloroanilino -terephthalic acid dimethyl ester [DPCADHT dimethyl ester]. 3. Then it is hydrolyzed in alkaline condition & aqueous medium to form 2,5-Bis-(p-Chloro anilino ) terephthalic acid [DPCADHT Acid CAS.No. 41680-76-6] 4. Then it is further cyclised in presence of Poly phosphoric acid then finally pigmentation is done in presence of IBA/DMF as per Quinacridone as Pigment Red 202

1.Condensation of DMSS with p-Chloroaniline: - DMSS + 2[p-Chloroaniline] Condensation DPCADHT C10 H12 O6 + 2[C 6H6CIN] C22 H20 N2CI 2O4 + 2H 2O Mol.Wt.228 + 2X[127.5] Methanol 447 + 36

2.Oxidation Of DPCADHT with Resist Salt: - DPCADHT Condensation DPCADHT dimethyl ester C22 H20 N2CI 2O4 + O 2 C22 H18 N2CI 2O4 + H 2O2 Mol .Wt. 447 + 32 Resist Salt 445 + 34

3.Hydrolysis of DPCADHT dimethyl ester:- DPCADHT dimethyl ester Hydrolysis DPCADHT Acid C22 H18 N2CI 2O4 + 2NaOH +2HCL C20 H14 CI 2N2O4 + 2NaCI + 2CH 3OH Mol.Wt. 445 + 80 + 73 Methanol 417 + 117 + 64

4.Cyclisation of DPCADHT Acid with Poly Phosphoric Acid & Pigmentation to form Pigment Red 202:- DPCADHT Acid Poly Phosphoric Cyclisation Pigment Red 202 Triphosphoric Acid acid monohydrate C20 H14 CI 2N2O4 + H 3PO 4.P 2O5 C20 H10 CI 2N2O2 + H 5P3O10 .H 2O Mol.Wt. 417 + 238 DMF /IBA 381 + 274

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Methanol 5500 Finish Product 1000 2 Dimethyl 780 Water Evaporation in Drying 2500 Succinosuccinate 3 4-Chloroaniline 860 Methanol Recovery for Re -Use 5225 4 Resist Salt 300 Washing water for Re-Use 7000 5 NaOH 275 Effluent to ETP 7710 6 HCL 250 DMF /IBA Recovery for Re-Use 6650 7 Poly Phosphoric Acid 1800 Inorganic & solvent residue 680 8 DMF / IBA 7000 9 Water for Reaction 7000 10 Water for Isolation 7000 TOT AL 30765 TOTAL 30765

47) Pigment Red 254 [ CAS NO. 122390-98-1]: -

Manufacturing Process: -

2 moles of p-Chloro Benzo nitrile [ PCBN cas no.623-03-0] is condensed with 1 mole of Di- Isopropyl Succinate [ DIPS cas no.924-88-9] in Tetra Amyl Alcohol in reflux condition at 85-90 0C for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C by adding water for isolation. Then reaction mass is filtered.From filtrate, Tetra Amyl Alcohol & Methyl tetra butyl ether[MTBE Methanol] which generated in reaction is recovered for Re-use &remaining is sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed a. Condensation of p-Chloro Benzo nitrile with Di-Isopropyl Succinate: -

2 [PCBN] + DIPS Condensation Pigment Red 254 + MTBE 2[C 7H4NCI + C 10 H18 O4 Methanol C18 H10 CI 2N2O2 + C 6H16 O2 Mol.Wt.2 [ 137.5 ] + 202 Tetraamyl Alcohol 357 + 120 +KOH

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Tetra Amyl alcohol 3800 Finish Product 1000 2 PCBN 810 Water Evaporation in Drying 1995 3 KOH 180 Tetra Amyl Alcohol Recovery for re- 3610 Use 4 DIPS 411 MTBE Methanol Recovery for re -Use 600 5 Water for Isolation 3000 Washing water for Re-Use 3000 6 Water for Washing 3000 Effluent to ETP 1000 7 TOTAL 11205 TOTAL 11205

48) Pigment Red 256 [ CAS no.79102-65-1.]: -

Manufacturing Process: -

2-Amino-2,5-dichloro-N-N-dimethylbenenesulphonazamide [ ADCDMBSA CAS NO. 26175-68-8] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol ASOL [ CAS NO. 135-62-6 ] Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of ADCDMBSA

ADCDMBSA Diazotization ADCDMBSA Diazo C8H10 CI 2N2O2S + 2HCI + NaNO 2 C8H8CI 3N3O2S + NaCI + 2 H 2O Mol.Wt. 269 + 73 + 69 316.5 + 58.5 + 36 b. Coupling with Naphthol ASOL

ADCDMBSA Diazo + Naphthol ASOL +C.S. Flacks Coupling Pigment Red 256 C8H8CI 3N3O2S + C 18 H15 NO 3 + NaOH C26 H22 CI 2N4O5S+ H 2O + NaCI Mol.Wt. 316.5 + 277 + 40 573 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Recycled Water 3000 Effluent to ETP 2745 2 ICE 2000 Washing water for Re -Use 3000 3 AMSBA 518 Water Evaporation in 3000 Drying 4 HCI 405 Finish Product 1000 5 Sodium Nitrite 130 6 Naphthol ASRL 492 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9745 TOTAL 9745

49) Pigment Red 264 [ CAS NO. 122390-98-1]: -

Manufacturing Process: -

2 moles of 4-Phenylbenzonitrile [ PPBN cas no.2920-38-9] is condensed with 1 mole of Di- Isopropyl Succinate [ DIPS cas no.924-88-9] in Tetra Amyl Alcohol in reflux condition at 85-90 0C for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C by adding water for isolation. Then reaction mass is filtered.From filtrate, Tetra Amyl Alcohol & Methyl tetra butyl ether [MTBE Methanol] which generated in reaction is recovered for Re-use &remaining is sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed a. Condensation of 4-Phenylbenzonitrile with Di-Isopropyl Succinate: -

2 [PPBN] + DIPS Condensation Pigment Red 264 + MTBE 2[C 13 H9NC I + C 10 H18 O4 Methanol C30 H20 N2O2 + C 6H16 O2 Mol.Wt.2 [ 179 ] + 202 Tetraamyl Alcohol 440 + 120 +KOH

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Tetra Amyl alcohol 3800 Finish Product 1000 2 PPBN 835 Water Ev aporation in Drying 2030 3 KOH 180 Tetra Amyl Alcohol Recovery for re- 3610 Use 4 DIPS 425 MTBE Methanol Recovery for re-Use 600 5 Water for Isolation 3000 Washing water for Re-Use 3000 6 Water for Washing 3000 Effluent to ETP 1000 7 TOTAL 11240 TOTAL 11240

72 2 Pigment Yellow Quantity per Month = 200 MT per Month

50) Pigment Yellow 1 [CAS NO.2512-29-0]: -

Manufacturing Process: -

xis Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Acetoacetanilide [AAA cas no.102-01-2]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. Washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of MNPT MNPT Diazotization MNPT Diazo C7 H8 N2O2 + 2HCI + NaNO 2 C7 H6 N3CIO 2 + NaCI + 2 H 2O Mol.Wt. 152 + 73 + 69 199.5 + 58.5 + 36 b. Coupling with Acetoacetanilide MNPT Diazo + Acetoacetanilide Coupling Pigment Yellow 1 +C.S.Flacks C17 H16 N4 O4 + H 2O + NaCI C7 H6 N3CIO 2 + C 10 H11 NO 2 +NaOH Mol.Wt. 199.5 + 177 + 40 340 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2825 2 ICE 2000 Washing water for Re -Use 3000 3 MNPT 450 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 190 6 Acetoacetanilide 510 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9825 TOTAL 9825

51) Pigment Yellow 3 [ CAS NO. 6486-23-3 ] :-

Manufacturing Process: -

P-Chloro, O-nitro Aniline [PCONA cas no.89-63-4] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with AAOCA [cas no.93-70-9]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of PCONA

PCONA Diazotization PCONA Diazo C6 H5 N2O2.CI + 2HCI + NaNO 2 C6 H3 N3CI 2O2 + NaCI + 2 H 2O Mol.Wt. 172.5 + 73 + 69 220 + 58.5 + 36 b. Coupling with AAOCA

PCONA Diazo + AAOCA + C.S.Flacks Coupling Pigment Yellow 3 C6 H3 N3CI 2O2 + C 10 H10 CINO 2 + NaOH C16 H12 N4 O4. CI 2 + H 2O + NaCI Mol.Wt. 220 + 211.5 + 40 395 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2942 2 ICE 2200 Washing water for Re-Use 3000 3 PCONA 410 Water Evaporation in Drying 3000 4 HCI 435 Finish Product 1000 5 Sodium Nitrite 187 6 AAOCA 510 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9942 TOTAL 9942

52) Pigment Yellow 12 [ cas no.6358-85-6]:-

Manufacturing Process: -

3,3-Dichlorobenzidine [3,3-DCB cas no.91-94-1] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mole Acetoacetanilide[ cas no.102-01-2]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 3,3-DCB

3,3-DCB Diazotization 3,3-DCB Diazo C12 H10 N2CI 2 + 4HCI + 2NaNO 2 C12 H6 N4CI 4 + 2NaCI + 4 H 2O Mol.Wt. 253 + 146 + 138 348 + 117 +72 b. Coupling with AAA

3,3-DCB Diazo + 2 [AAA] + C.S. Flacks Coupling Pigment Yellow 12 C12 H6 N4CI 4+ 2[C 10 H11 NO 2 +2NaOH C32 H26 CI 2N6 O4+ 2H 2O + 2NaCI Mol.Wt. 348 + 354 +80 629 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2884 2 ICE 2000 Washing water for Re-Use 3000 3 3,3-DCB 264 Water Evaporation in Drying 3000 4 HCI 500 Finish Product 1000 5 Sodium Nitrite 200 6 AAA 730 7 C.S. Flacks 190 8 Fresh Water for Washing 3000 TOTAL 9884 TOTAL 9884

75 53) Pigment Yellow 13 [cas no.5102-83-0]:-

Manufacturing Process: -

3,3-Dichlorobenzidine [3,3-DCB cas no.91-94-1] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mole Acetoacet Meta Xylidin [ AAMX cas no.97-36-9]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 3,3-DCB

3,3-DCB Diazotization 3,3-DCB Diazo C12 H10 N2CI 2+ 4HCI + 2NaNO 2 C12 H6 N4CI 4 + 2NaCI + 4 H 2O Mol.Wt. 253+ 146 + 138 348 + 117 + 72 b. Coupling with AAMX

3,3-DCB Diazo + 2 [AAMX] + C.S. Flacks Coupling Pigment Yellow 13 C12 H6 N4CI 4+ 2[C 12 H15 NO 2+2NaOH C36 H34 CI 2N6 O4+ 2H 2O + 2NaCI Mol.Wt. 348 + 410 +80 685 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 2900 Effluent to ETP 3180 2 ICE 2400 Washing water for Re-Use 2900 3 3,3-DCB 340 Water Evaporation in Drying 3000 4 HCI 435 Finish Product 1000 5 Sodium Nitrite 190 6 AAMX 715 7 C.S.Flacks 200 8 Fresh Water for Washing 2900 TOTAL 10080 TOTAL 10080

76 54) Pigment Yellow 14 [cas no.5468-75-7]:-

Manufacturing Process: -

3,3-Dichlorobenzidine [3,3-DCB 91-94-1] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mole O-Acetoacetotoluidine [ AAOT cas no.93-68-5]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 3,3-DCB

3,3-DCB Diazotization 3,3-DCB Diazo C12 H10 N2CI 2+ 4HCI + 2NaNO 2 C12 H6 N4CI 4 + 2NaCI + 4 H 2O Mol.Wt. 253 + 146 + 138 348 + 117 + 72 b. Coupling with AAOT

3,3-DCB Diazo + 2 [AAOT] + C.S. Flacks Coupling Pigment Yellow 14 C12 H6 N4CI 4+ 2[C 11 H13 NO 2 + 2NaOH C36 H34 CI 2N6 O4+ 2H 2O + 2NaCI Mol.Wt. 348 + 410 +80 685 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 2900 Effluent to ETP 3180 2 ICE 2400 Washing water for Re-Use 2900 3 3,3-DCB 340 Water Evaporation in Drying 3000 4 HCI 435 Finish Product 1000 5 Sodium Nitrite 190 6 AAOT 715 7 C.S.Flacks 200 8 Fresh Water for Washing 2900 TOTAL 10080 TOTAL 10080

77 55) Pigment Yellow 16 [cas no.5979-28-2]:-

Manufacturing Process: -

2 Mole 2,4-Dichloroaniline [ cas no.554-00-7]is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol ASIRG[ cas no.4433-79-8]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of 2,4-DCA

2,4-DCA Diazotization 2,4-DCA Diazo 2[C 6 H5 NCI 2] + 4HCI + 2NaNO 2 C12 H6 N4CI 6 + 2NaCI + 4 H 2O Mol.Wt. 324 + 146 + 138 419 + 117 + 72

b. Coupling with Naphthol ASIRG

2,4-DCA Diazo+ Naphthol ASIRG+C.S. Coupling Pigment Yellow 16 Flacks C34 H28 CI 4N6 O4+ 2H 2O + 2NaCI C12 H6 N4CI 6 + C 22 H24 N2O4 +2NaOH Mol.Wt. 419 + 380 +80 726 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3720 2 ICE 2500 Washing water for Re-Use 3000 3 2,4-DCA 650 Water Evaporation in Drying 3000 4 HCI 675 Finish Product 1000 5 Sodium Nitrite 270 6 Naphthol ASIRG 425 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 10720 TOTAL 10720

78 56) Pigment Yellow 17 [cas no.4531-49-1:-

Manufacturing Process: -

3,3-Dichloro Benzidine [3,3-DCB cas no.91-94-1] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mol of O-Acetoacetanilide[ cas no.92-15-9]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 3,3-DCB

3,3-DCB Diazotization 3,3-DCB Diazo C12 H10 N2CI 2+ 4HCI + 2NaNO 2 C12 H6 N4CI 4 + 2NaCI + 4 H 2O Mol.Wt. 253+ 146 + 138 348 + 117 + 72 b. Coupling with O-Acetoacetanilide

3-3-DCB Diazo+ O-AA +C.S. Flacks Coupling Pigment Yellow 17 C12 H6 N4CI 4 + [C 11 H13 NO 3 +2NaOH C34 H30 CI 2N6 O6 + 2H 2O + 2NaCI Mol.Wt. 348 + 207 +80 689 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3080 2 ICE 2200 Washing water for Re -Use 3000 3 3,3-DCB 380 Water Evaporation in Drying 3000 4 HCI 485 Finish Product 1000 5 Sodium Nitrite 190 6 OAA 625 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 10080 TOTAL 10080

79 57)Pigment Yellow 61[ cas no.12286-65-6]:-

Manufacturing Process: -

O-Nitro Aniline PSA [ ONAPSA cas no.616-84-2] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with AAA[cas no.102-01-2]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of ONAPSA

ONAPSA Diazotization ONAPSA Diazo C6 H6 N2O5S + 2HCI + NaNO 2 C6 H4 N3O5SCI + NaCI + 2 H 2O Mol.Wt. 218 + 73 + 69 265.5 + 58.5 + 36 b. Coupling with AAA

ONAPSA Diazo+ AAA +C.S.Flacks Coupling Pigment Yellow 61 C6H4N3O5SCI +C 10 H11 NO 2+2XNaOH + 1/2 CaCI 2 C16 H13 N4O7S.Ca + 2H 2O + 2NaCI Mol.Wt. 265.5 + 177 + 80 + 55 424.5 + 36 + 1 17

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2960 2 ICE 2000 Washing water for Re-Use 3000 3 ONAPSA 450 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 190 6 AAA 510 7 C.S.Flacks 200 8 Calcium Chloride 135 9 Fresh Water for Washing 3000 TOTAL 9960 TOTAL 9960

58) Pigment Yellow 62 [cas no.12286-66-7]:-

Manufacturing Process: -

O-Nitro Aniline PSA [ ONAPSA cas no.616-84-2] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with AAOT[ cas no.93-68-5]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of ONAPSA

ONAPSA Diazotization ONAPSA Diazo C6 H6 N2O5S + 2HCI + NaNO 2 C6 H4 N3O5SCI + NaCI + 2 H 2O Mol.Wt. 218 + 73 + 69 265.5 + 58.5 + 36 b. Coupling with AAOT

ONAPSA Diazo+ AAOT +C.S.Flacks Coupling Pigment Yellow 62 C6H4N3O5SCI +C 11 H13 NO 2 +2XNaOH + 1/2 CaCI 2 C16 H13 N4O7S.Ca + 2H 2O + 2NaCI Mol.Wt. 265.5+ 191 + 80 + 55 439.5 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2950 2 ICE 2000 Washing water for Re -Use 3000 3 ONAPSA 450 Water Evaporation in Drying 3000 4 HCI 475 Finish Prod uct 1000 5 Sodium Nitrite 190 6 AAOT 500 7 C.S.Flacks 200 8 Calcium Chloride 135 9 Fresh Water for Washing 3000 TOTAL 9950 TOTAL 9950

81 59) Pigment Yellow 63 [cas no.14569-54-1]:-

Manufacturing Process: -

3,3-Dichloro Benzidine [3,3-DCB cas no.91-94-1] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mol of AAOCA[ 93-70-9]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 3,3-DCB

3,3-DCB Diazotization 3,3-DCB Diazo C12 H10 N2CI 2+ 4HCI + 2NaNO 2 C12 H6 N4CI 4 + 2NaCI + 4 H 2O Mol.Wt. 253+ 146 + 138 348 + 117 + 72 b. Coupling with AAOCA

3-3-DCB Diazo+ AAOCA + C.S. Flacks Coupling Pigment Yellow 63 C12 H6 N4CI 4+ 2[C 10H10 NO 2CI ]+ 2NaOH C32 H24 CI 4N6 O4 + 2H 2O + 2NaCI Mol.Wt. 348 + 2 X 211.5 + 80 698 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3150 2 ICE 2200 Washing water for Re-Use 3000 3 3,3-DCB 390 Water Evaporation in Drying 3000 4 HCI 485 Finish Product 1000 5 Sodium Nitrite 190 6 AAOCA 685 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 10150 TOTAL 10150

82 60) Pigment Yellow 65 [cas no.6528-34-3]:-

Manufacturing Process: -

M-Nitro P-Methoxy Aniline [MNPA cas no.96-96-8] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Acetoacet-2-anisidide[AAOA cas no.92-15-9]. Coupled mass is stirred till coupling reaction gets complete. Then reaction massis heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of MNPA

MNPA Diazotization MNPA Diazo C7H8N2O3 + 2HCI + NaNO 2 C7H6N3O3CI + NaCI + 2 H 2O Mol.Wt. 168 + 73 + 69 215.5 + 58.5 + 36 b. Coupling with AAOA

ONAPSA Diazo+ AAOA + C.S.Flacks Coupling Pigment Yellow 65 C7H6N3O3CI + C 11 H13 NO 3 +NaOH C18 H18 N4O6 + H 2O + NaCI Mol.Wt. 215.5 + 207 + 40 386 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2950 2 ICE 2000 Washing water for Re -Use 3000 3 MNPA 440 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 190 6 AAOA 510 7 C.S.Flacks 200 8 Calcium Chloride 135 9 Fresh Water for Washing 3000 TOTAL 9950 TOTAL 9950

61) Pigment Yellow 73 [cas no.13515-40-7]:-

Manufacturing Process: -

P-Chloro O-Nitro Aniline [ PCONA cas no.89-63-4] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Acetoacet-2-Anisidine [ AAOA cas no. 92-15-9]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of PCONA

PCONA Diazotization PCONA Diazo C6 H5N2O5CI + 2HCI + NaNO 2 C6 H3 N3O5CI 2 + NaCI + 2 H 2O Mol.Wt. 172.5 + 73 + 69 220 + 58.5 + 36 b. Coupling with AAOA

PCONA Diazo+ AAOA +C.S.Flacks Coupling Pigment Yellow 73 C6H3N3O5CI 2 + C 11 H13 NO 3 +NaOH C17 H15 N4O5CI + H 2O + NaCI Mol.Wt. 220 + 207 + 40 390.5 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2960 2 ICE 2000 Washing water for Re -Use 3000 3 PCONA 450 Water Evaporation in Drying 3000 4 HCI 475 Finis h Product 1000 5 Sodium Nitrite 190 6 AAOA 510 7 C.S.Flacks 200 8 Calcium Chloride 135 9 Fresh Water for Washing 3000 TOTAL 9960 TOTAL 9960

84 62) Pigment Yellow 74 [cas no.6358-31-2]:-

Manufacturing Process: -

2-Methoxy, -4-Nitroaniline [ MNOA cas no.97-52-9] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Acetoacet-2-Anisidine [ AAOA cas no. 92-15-9]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of MNOA

MNOA Diazotization MNOA Diazo C7H8N2O3 + 2HCI + NaNO 2 C7H6N3O3CI + NaCI + 2 H 2O Mol.Wt. 168 + 73 + 69 215.5 + 58.5 + 36 b. Coupling with AAOA

MNOA Diazo + AAOA +C.S.Flacks Coupling Pigment Yellow 74 C7H3N3O3CI + C 11 H13 NO 3 +NaOH C18 H18 N4O6 + H 2O + NaCI Mol.Wt. 215.5 + 207 + 40 386 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2980 2 ICE 2000 Washing water for Re-Use 3000 3 MNOA 465 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 190 6 AAOA 515 7 C.S.Flacks 200 8 Calcium Chloride 135 9 Fresh Water for Washing 3000 TOTAL 9980 TOTAL 9980

85 63) Pigment Yellow 83 cas no.5567-15-7:-

Manufacturing Process: -

3,3-Dichloro Benzidine [3,3-DCB c91-94-1 ]as no.] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mol of AADMCA cas no.4433-79-8. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 3,3-DCB

3,3-DCB Diazotization 3,3-DCB Diazo C12 H10 N2CI 2+ 4HCI + 2NaNO 2 C12 H6 N4CI 4 + 2NaCI + 4 H 2O Mol.Wt 253 + 146 + 138 348 + 117 + 72 b. Coupling with AADMCA

3-3-DCB Diazo+ AADMCA + C.S. Flacks Coupling Pigment Yellow 83 C12 H6 N4CI 4+ 2[C 12 H14 NO 4CI ]+ 2NaOH C36 H32 CI 4N6 O+ 2H 2O + 2NaCI Mol.Wt. 348 + 2 X 271.5 +80 818 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3150 2 ICE 2200 Washing water for Re-Use 3000 3 3,3-DCB 390 Water Evaporation in Drying 3000 4 HCI 485 Finish Product 1000 5 Sodium Nitrite 190 6 AADMCA 685 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 10150 TOTAL 10150

86 64) Pigment Yellow 93 cas no5580-57-4:-

Manufacturing Process: -

3-Amino-4-chloro-N-(3-chloro-2-methylphenyl) Benzamide is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with N, N -(2-chloro-5-methylbenzene-1,4-diyl) bis(3- oxobutanamide). Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of OAPC

OAPC Diazotization OAPCDiazo C14 H12 N2OCI 2+ 2HCI + NaNO 2 C14 H10 N3OCI 3 + NaCI + 2 H 2O Mol.Wt. 295 + 73 + 69 342.5 + 58.5 + 36 b. Coupling with N,N-CMBT

OACP Diazo+ N,N-CMBT +C.S.Flacks Coupling Pigment Yellow 93 2[C 14 H10 N3OCI 3] + C 15 H17 N2CIO 4 +NaOH C43 H35 N8O6CI 5 + 2H 2O + 2NaCI Mol.Wt. 685 + 324 + 80 937.5 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3070 2 ICE 2000 Washing water for Re-Use 3000 3 OAPC 620 Water Evaporation in Drying 3000 4 HCI 575 Finish Product 1000 5 Sodium Nitrite 200 6 NN-CMBT 340 7 C.S. Flacks 335 8 Fresh Water for Washing 3000 TOTAL 10070 TOTAL 10070

87 65) Pigment Yellow 97 cas no.12225-18-2: -

Manufacturing Process: -

2,5-Dimethoxyaniline-4-Sulphoanilide [DMASA cas no. is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with NAPTHOL AS-IRG cas no.4433-79-8].Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of DMASA

DMASA Diazotization DMASA Diazo C14 H16 N2O4S + 2HCI + NaNO 2 C14 H14 N3O4CIS + NaCI + 2 H 2O Mol.Wt. 308 + 73 + 69 355.5 + 58.5 + 36 b. Coupling with NAPTHOL AS-IRG

DMASA Diazo+ NAPTHOL AS-IRG +C.S.Flacks Coupling Pigment Yellow 97 C14 H14 N3O4CIS + C12H14ClNO4 +NaOH C26 H27 N4O8SCI + H 2O + NaCI Mol.Wt. 355.5 + 271.5 + 40 591 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2985 2 ICE 2000 Washing water for Re-Use 3000 3 DMASA 470 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 190 6 NAPTHOL AS-IRG 515 7 C.S.Flacks 200 8 Calcium Chloride 135 9 Fresh Water for Washing 3000 TOTAL 9985 TOTAL 9985

66) Pigment Yellow 101 [ CAS No.: 2387-03-3]

Manufacturing Process: -

2-hydroxynaphthalene-1-carbaldehyde and dihydrazine sulfate are suspended in water and methanol at room temperature. Stir it for 1 hour and then heat it to reflux temperature. Maintain reflux for 5 hours. Cool for filtration.Filter the pigment slurry and wash with water up to salt free.Filtrate sent to solvent recovery and wash water are sent to ETP.Wet cake is then dried and pulverized and then sent to packaging.

Chemical Reaction:

2-hydroxynaphthalene-1-carbaldehyde Condensate Pigment Yellow 101 and dihydrazine sulfate + dihydrazine C22H16N2O2 + H 2O + H2SO4 + 2NH2 sulfate + C11H8O2 + H10N4O4S

Mol.Wt.( 2 x 172) + 162 340 + 18 + 116 + 32

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 2-hydroxynaphthalene-1- 1052 Finished Product 1000 carbaldehyde 2 Dihydrazine 90 Methanol Recovery 3600 3 Methanol 4000 Aqueous Effluent to ETP 2522 4 Water 3500 Drying Loss 1520

TOTAL 8642 TOTAL 8642

89 67) Pigment Yellow 120 [ cas no.29920-31-8]: -

Manufacturing Process: -

5-Aminoisophthalic acid dimethyl ester [5-AIPA-DME cas no.99-27-4]is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 5-Acetylacetamino Benzoimidazolone[AABI cas no.26576-46-5]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C & treated with Aluminum Hydroxide to form Aluminum Salt & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of 5-AIPA-DME

5-AIPA-DME Diazotization 5-AIPA-DME Diazo C10 H10 NO 4 + 2HCI + NaNO 2 C10 H8N2O4CI + NaCI + 2 H 2O Mol.Wt. 209 + 73 + 69 256.5 + 58.5+ 36

b. Coupling with AABI

5-AIPA-DME Diazo + AABI +C.S. Flacks Coupling Pigment Yellow 120 C10 H8N2O4CI + C 11 H11 N3O3 +NaOH C21 H19 N5O7 + H 2O + NaCI Mol.Wt. 256.5 + 233 + 40 453 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3020 2 ICE 2000 Washing water for Re -Use 3000 3 5-AIPA-DME 490 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 190 6 AABI 510 7 C.S. Flacks 220 8 Aluminum Hydroxide 135 9 Fresh Water for Washing 3000 TOTAL 10020 TOTAL 10020

90 68) Pigment Yellow 121 [ cas no. 61968-85-2]:-

Manufacturing Process: -

3,3-Dichloro Benzidine [3,3-DCB cas no.] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2,4-Dimethylacetanilide [ AAMX cas no.97-36-9] . Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 3,3-DCB

3,3-DCB Diazotization 3,3-DCB Diazo C12 H10 N2CI 2+ 4HCI + 2NaNO 2 C12 H6 N4CI 4 + 2NaCI + 4 H 2O Mol.Wt. 253 +146 + 138 348 + 117 + 72 b. Coupling with AAMX

3-3-DCB Diazo + AAMX + C.S. Flacks Coupling Pigment Yellow 121 C12 H6N4CI 4 +2[C 12 H15 NO 2] + 2NaOH C34 H29 CI 3N6O4 + 2H 2O + 2NaCI Mol.Wt. 348 +2 X 205 +80 691 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 2500 Effluent to ETP 2390 2 ICE 2000 Washing water for Re-Use 2500 3 3,3 -DCB 390 Water Evaporation in Drying 3000 4 HCI 485 Finish Product 1000 5 Sodium Nitrite 190 6 AAMX 625 7 C.S. Flacks 200 8 Fresh Water for Washing 2500 TOTAL 8890 TOTAL 8890

91 69) Pigment Yellow 138 [ CAS NO.30125-47-4]: -

Manufacturing Process: -

2 moles of Tetrachloro Phthalic Anhydride [TCPA CAS No.117-08-8] & 8-amino Quinaldine [CAS No.18978-78-4] is condensed in the presence of ODCB or Xylene & Benzoic Acid in reflux condition at 140-142 0C& removing water from separator during reaction for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C by adding water & methanol for isolation. Then ODCB / Xylene is distilled out for recycle in next batch & remaining mass is filtered. From Filtrate, methanol is again distilled out for recycle in next batch & remaining filtrate is sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed

a. Condensation of Tetrachloro Phthalic Anhydride with 8-amino Quinaldine

TCPA 8-amino Quinaldine Condensation Pigment Yellow 138 2 x [C 8CI 4O3] + C 10 H10 N2 C22 H6CI 8N2O2 + 2H 2O + C 4 H 4 O 3 Mol.Wt. 2X 286 + 158 ODCB/Xy lene Benzoic Acid 641 + 36 + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 ODCB / Xylene 3000 Finish Product 1000 2 Tetrachloro Phthalic 750 Water Evaporation in Drying 1000 Anhydride 3 8-amino Quinaldine 275 ODCB / Xylene Recovery for Re-Use 2850 4 Benzoic Acid 30 Methanol Recovery for Re -use 950 5 Methanol 1000 Washing water for Re -Use 3000 6 Water for Isolation 2000 Effluent to ETP 1755 7 Water for Washing 350 0 TOTAL 10555 TOTAL 10555

92 70) Pigment Yellow 139 [ CAS NO.36888-99-0]: -

Manufacturing Process: -

1,2-Dicyanobenzene /Phthalonitrile [ CAS No.91-15-6] is condensed with 2 Mole of Barbituric acid [CAS No.67-52-7] in aqueous media with HCI in reflux condition for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C by adding water for isolation. Then mass is filtered. Filtrate is send in ETP for further treatment & recovery of Ammonium Chloride in MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed

a. Condensation of Phthalonitrile with Barbituric Acid

Phthalonitrile 2[Barbituric acid] Condensation Pigment Yellow 139 C8H4O2+ 2[ C 4H4N2O3] + HCI C16 H9N5O6 + NH 4CI Mol.Wt. 128 2 x 128 + 36.5 HCL/Water 367 + 53.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Water 3000 Finish Product 1000 2 Phthalonitrile 350 Water Evaporation in Drying 2000 3 Barbituric acid 700 Effluent to ETP for Ammonium 1225 Chloride recovery 4 HCL 175 Washing water for Re-Use 3000 5 Water fo r Washing 3000

TOTAL 7225 TOTAL 7225

71) Pigment Yellow 151[cas no.31837-42-0]: -

Manufacturing Process: -

Anthranillic acid[cas no.118-92-3] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 5-Acetylacetamino Benzoimidazolone[AABI cas no. 26576-46-5]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of Anthranillic Acid

Anthranillic acid Diazotization Anthranillic acid Diazo C7H7NO 2 + 2HCI + NaNO 2 C7H5N2O2CI + NaCI + 2 H 2O Mol.Wt. 137 + 73 + 69 184.5 + 58.5 + 36 b. Coupling with AABI

Anthranillic acid Diazo + AABI +C.S. Flacks Coupling Pigment Yellow 151 C7H5N2O2CI + C 11 H11 N3O3 +NaOH C18 H15 N5O5 + H 2O + NaCI Mol.Wt. 184.5 + 233 + 40 381 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2910 2 ICE 2000 Washing water for Re -Use 3000 3 Anthranillic Acid 490 Water Evaporation in Drying 3000 4 HCI 375 Finish Product 1000 5 Sodium Nitrite 180 6 AABI 510 7 C.S. Flacks 220 8 Aluminum Hydroxide 135 9 Fresh Water for Washing 3000 TOTAL 9910 TOTAL 9910

72) Pigment Yellow 153 [ cas no. 29204-84-0 ]: -

2,3-Dinitroso-n-phenylbutanamide [cas No.N.A,] is metalized with Nickel Chloride in aqueous media & is heated up to 95 to 100 0C to form Nickel Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch. & wet cake is dried in spin flash dryer, pulverized & packed

a. Metallization of 2,3-Dinitroso-n-phenylbutanamide

DNPBN Metallization Pigment Yellow 153 2[C 10 H11 N3O3] +NiCI 2 + 2NaOH C20 H20 N6NiO 6 + 2NaCI + 2H 2O Mol.Wt. 2 x221 + 129.5 + 80 499.5 + 117 + 36

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Pigment Yellow 153 1000 2 2,3-Dinitroso-n- 775 Drying Loss 3175 phenylbutanamide 3 C.S. Flacks 200 Washing water for Re-Use 3000 4 Nickel Chloride 200 5 Fresh Water for Washing 3000 TOTAL 7175 TO TAL 7175

73) Pigment Yellow 154 [cas no.68134-22-5]: -

Manufacturing Process: -

2-Aminotriflurotoluene [ ATFT cas no.88-17-5] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 5-Acetylacetamino Benzoimidazolone [AABI cas no.26576-46-5]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of ATFT

ATFT Diazotization ATFT Diazo C7H6NF 3 + 2HCI + NaNO 2 C7H4N2F3CI + NaCI + 2 H 2O Mol.Wt. 161 + 73 + 69 208.5 + 58.5 + 36 b. Coupling with AABI

ATFT Diazo + AABI +C.S. Flacks Coupling Pigment Yellow 154 C7H4N2F3CI + C 11 H11 N3O3 +NaOH C18 H14 N5F3O3 + H 2O + NaCI Mol.Wt. 208.5 + 233 + 40 405 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2910 2 ICE 2000 Washing water for Re -Use 3000 3 ATFT 490 Water Evaporation in Drying 3000 4 HCI 375 Finish Product 1000 5 Sodium Nitrite 180 6 AABI 510 7 C.S. Flacks 220 8 Aluminum Hydroxide 135 9 Fresh Water for Washing 3000 TOTAL 9910 TOTAL 9910

74) Pigment Yellow 155[ cas no.68516-73-4]: -

Manufacturing Process: -

2 Mol of 2-Amino, Dimethyl Terephthalate [ ADMT cas no.5372-81-6] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with N,N-Diacetoacetyl-p-Diamino Benzene [ DAPDAB cas no.25731-73-5 ].Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of ADMT

ADMT Diazotization ADMT Diazo 2[C 10 H11 NO 4] +4HCI + 2NaNO 2 C20 H18 N4O8CI 2 + 2NaCI + 4H 2O Mol.Wt. 418 + 146 + 138 513 + 117 + 72 b. Coupling with DAPDAB

ADMT Diazo + DAPDAB +C.S. Flacks Coupling Pigment Yellow 155 C20 H18 N4O8CI 2 + C 14 H16 N2O4 +2NaOH C34 H32 N6O12 + 2H 2O + 2NaCI Mol.Wt. 513 + 276 + 8 0 716 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2990 2 ICE 2000 Washing water for Re -Use 3000 3 ADMT 615 Water Evaporation in Drying 3000 4 HCI 515 Finish Product 1000 5 Sodium Nitrite 220 6 DAPDAB 400 7 C.S. Flacks 240 8 Fresh Water for Washing 3000 TOTAL 9990 TOTAL 9990

75) Pigment Yellow 174 [cas no. 78952-72-4]:-

Manufacturing Process: -

Pigment yellow 13 & Pigment Yellow 14 is mixed 50% each in Blender & Packed

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Pigment yellow 13 500 Effluent to ETP Nil 2 ICE Pigment Yellow 14 500 Washing water for Re-Use Nil TOTAL 1000 TOTAL

76) Pigment Yellow 180[CAS NO. 77804-81-0]:

Manufacturing Process: -

2-[Ethylene Dioxy] Dianiline [2-EDDA cas no.52411-34-4] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mole 5-Aetoacetamino Benzoimidazolone [AABI cas no.26576-46-5]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 2-EDDA

2-EDDA Diazotization 2-EDDA Diazo C14 H16 N2O2+ 4HCI + 2NaNO 2 C14 H12 N4CI 2O2+ 2NaCI + 4 H 2O Mol.Wt. 244+ 146 + 138 339 + 117 + 72 b. Coupling with AABI

2-EDDADiazo + AABI + C.S. Flacks Coupling Pigment Yellow 180 C14 H12 N4CI 2O2 +2[C 11 H11 N3O3] + 2NaOH C36 H32 N10 O8+ 2H 2O + 2NaCI Mol.Wt. 339 + 466 +80 732 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3070 2 ICE 2200 Washing water for Re-Use 3000 3 2-EDDA 380 Water Evaporation in Drying 3000 4 HCI 485 Finish Product 1000 5 Sodium Nitrite 205 6 AABI 600 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 10070 TOTAL 10070

77) Pigment Yellow 181[cas no.: 74441-05-7] -

Manufacturing Process: -

Para Amino Benzoyl Benzamide [PABB cas no.74441-06-8]is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 5-Acetoacetylylamino Benzoimidazolone[AABI]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of PABB

PABB Diazotization PABB Diazo C14 H13 N3O2 + 2HCI + NaNO 2 C14 H11 N4O2CI + NaCI + 2 H 2O Mol.Wt. 255+ 73 + 69 302.5 + 58.5 + 36 b. Coupling with AABI

PABB Diazo + AABI +C.S. Flacks Coupling Pigment Yellow 181 C14 H11 N4O2CI + C 11 H11 N3O3 +NaOH C25 H21 N7O5 + H 2O + NaCI Mol.Wt. 302.5 + 233 + 40 499 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3020 2 ICE 2000 Washing water for Re -Use 3000 3 PABB 490 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 190 6 AABI 510 7 C.S. Flacks 220 8 Aluminum Hydroxide 135 9 Fresh Water for Washing 3000 TOTAL 10020 TOTAL 10020

100

78) Pigment Yellow 182 [ CAS NO. 67906-31-4]: -

Manufacturing Process: -

2-amino-diethyl terephthalate [ADMT cas no.27210-70-4]is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with N-[acetoacetyl-6-methoxy-7-amino-quinoxaline,2,3-dione [AAMAQ]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of ADMT

ADMT Diazotization ADMT Diazo C10 H11 NO 4 + 2HCI + NaNO 2 C10 H9N2O4CI + NaCI + 2 H 2O Mol.Wt. 209 + 73 + 69 256.5 + 58.5 + 36 b. Coupling with AAMAQ

ADMT Diazo + AAMAQ +C.S. Flacks Coupling Pigment Yellow 182 C10 H8N2O4CI + C 12 H11 N4O4 +NaOH C22 H20 N6O8 + H 2O + NaCI Mol.Wt. 256.5 + 275 + 40 496 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 3020 2 ICE 2000 Washing water for Re -Use 3000 3 ADMT 490 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 19 0 6 AAMAQ 510 7 C.S. Flacks 220 8 Aluminum Hydroxide 135 9 Fresh Water for Washing 3000 TOTAL 10020 TOTAL 10020

101

79) Pigment Yellow 183 [cas no.23792-68-9]:-

Manufacturing Process: -

3,4-Dichloroaniline,6-sulphonic Acid [ DCASA cas no.6331-96-0] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 1,3-Sulphophenyl-3-methyl Pyrazolone [1,3-SPMP cas no.119-17-5 ]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of DCASA

DCASA Diazotization DCASA Diazo C6 H5CI 2NO 3S + 2HCI + NaNO 2 C6H3CI 3N2O3S + NaCI + 2 H 2O Mol.Wt. 242 + 73 + 69 289.5 + 58.5 + 36 b. Coupling with 1,3-PMP

DCASA Diazo+ 1,3-SPMP +C.S.Flacks Coupling Pigment Yellow 183 C6H3CI 3N2O3S + C 10 H10 N2O4S+2XNaOH C16 H12 N4O7S2.Ca + 2H 2O + 2NaCI +1/2 CaCI 2 Mol.Wt. 289.5 + 254 + 80 + 55 545 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2955 2 ICE 2000 Washing water for Re -Use 3000 3 DCASA 460 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 190 6 1,3-SPMP 490 7 C.S.Flacks 200 8 Calcium Chloride 140 9 Fresh Water for Washing 3000 TOTAL 9955 TOTAL 9955

102

80) Pigment Yellow 191 cas no. 129423-54-7 : -

Manufacturing Process: -

2B Acid cas no.88-51-7, is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 1,3- SPMP cas no.119-17-5. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 2B Acid

2B Acid Diazotization 2B Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36 b. Coupling with 1,3-SPMP

2B Acid Diazo+ 1,3-SPMP +C.S. Flacks Coupling Pigment Yellow 191 C7H6CI 2N2O3S +C 10 H10 N2O4S +2XNaOH + 1/2 CaCI 2 C17 H14 CIN 4O7S2.Ca + 2H 2O + 2NaCI Mol.Wt. 269 + 254 + 80 + 55 505.5 +36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2755 2 ICE 2000 Washing water for Re-Use 3000 3 2B Acid 475 Water Evaporation in Drying 3000 4 HCI 275 Finish Product 1000 5 Sodium Nitrite 150 6 1,3 -SPMP 495 7 C.S. Flacks 200 8 Calcium Chloride 140 9 Fresh Water for Washing 3000 TOTAL 9735 TOTAL 9735

103

81) Pigment Yellow 191:1[CAS NO.: 154946-66-4] : -

Manufacturing Process: -

2B Acid is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 1,3- SPMP. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Ammonium Chloride is added & is heated up to 75 to 80 0C to form Ammonium Salt & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 2B Acid

2B Acid Diazotization 2B Acid Diazo C7H8CINO 3S + 2HCI + NaNO 2 C7H6CI 2N2O3S + NaCI + 2 H 2O Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36 b. Coupling with 1,3-SPMP

2B Acid Diazo+ 1,3-SPMP +C.S. Flacks Coupling Pigment Yellow 191:1 C7H6CI 2N2O3S +C 10 H10 N2O4S +3XNaOH +2NH 4CI C17 H21 CIN 6O7S2 + 3H 2O + 3NaCI Mol.Wt. 269 + 254 + 120 + 107 520.5 + 54 + 175.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2755 2 ICE 2000 Washing water for Re-Use 3000 3 2B Acid 475 Water Evaporation in Drying 3000 4 HCI 275 Finish Product 1000 5 Sodium Nitrite 150 6 1,3-SPMP 495 7 C.S. Flacks 200 8 Ammonium Chloride 160 9 Fresh Water for Washing 3000 TOTAL 9755 TOTAL 9755

104

3 Pigment Orange Quantity per Month = 200 MT per Month

82) Pigment Orange 5 cas no.3468-63-1: - Manufacturing Process: - 2,4-Dinitro Aniline [2,4-DNA cas no.97-02-9] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Beta Naphthol cas no.135-19-3. Coupled mass is stirred till coupling reaction gets complete. Then in reaction is heated up to 75 to 80 0C to & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 2,4-DNA 2,4-DNA Diazotization 2,4-DNA Diazo C6H5N3O4+ 2HCI + NaNO 2 C6H3CIN 4O4 + NaCI + 2 H 2O Mol.Wt. 183 + 73 + 69 230.5 + 58.5 + 36 b. Coupling with Naphthol AS-OL 2,4-DNA Diazo+ Beta Naphthol +C.S. Flacks Coupling Pigment Orange 5 C6H3CIN 4O4 + C 10 H8O + NaOH C16 H10 N4O5 + H 2O + NaCI Mol.Wt. 230.5 + 114 + 40 338 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Recycled Water 3000 Effluent to ETP 2565 2 ICE 2000 Washing water for Re -Use 3000 3 2,4-DNA 518 Water Evaporation in 3000 Drying 4 HCI 270 Finish Product 1000 5 Sodium Nitrite 142 6 Beta Naphthol 435 7 C.S. Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9565 TOTAL 9565

105

83) Pigment Orange 13 [ 3520-72-7]:-

Manufacturing Process: -

3,3-Dichloro Benzidine [3,3-DCB] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mole PMP.Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 3,3-DCB

3,3-DCB Diazotization 3,3-DCB Diazo C12 H10 N2CI 2+ 4HCI + 2NaNO 2 C12 H6 N4CI 4 + 2NaCI + 4 H 2O Mol.Wt. 253 + 146+ 138 348 + 117 + 72 b. Coupling with PMP

3-3-DCB Diazo + PMP + C.S. Flacks Coupling Pigment Orange 13 C12 H6 N4CI 4 +2[C 10 H10 N2O] +2NaOH C32 H24 Cl 2N8O2+ 2H 2O + 2NaCI Mol.Wt. 348 + 348 +80 623 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2890 2 ICE 2200 Washing water for Re -Use 3000 3 3,3-DCB 490 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 105 6 PMP 510 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9890 TOTAL 9890

106

84) Pigment Orange 16 [CAS NO.: 6505-28-8]:-

Manufacturing Process: -

Ortho Dianisidine [ODA] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mole Acetoacetanilide [AOA].Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of OAD

OAD Diazotization ODA Diazo C14 H16 N2O2 + 4HCI + 2NaNO 2 C14 H12 CI 2N4O2 + 2NaCI + 4 H 2O Mol.Wt. 244 + 146 + 138 339 + 117 + 72

b. Coupling with AOA

ODA Diazo + AOA + C.S. Flacks Coupling Pigment Orange 16 C14 H12 CI 2N4O2 +2[C 10 H11 NO 2] +2 NaOH C34 H32 N6O6+ 2H 2O + 2NaCI Mol.Wt. 339 + 354 +80 620 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2885 2 ICE 2200 Washing water for Re -Use 3000 3 ODA 495 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 105 6 AOA 500 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9885 TOTAL 9885

107

85) Pigment Orange 34 [CAS NO. 15793-73-4] :-

Manufacturing Process: -

3,3-Dichloro Benzidine [3,3-DCB] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mole 1-p-tolyl-3-methyl-5-pyrazolone [PTMP].Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of 3,3-DCB

3,3-DCB Diazotization 3,3-DCB Diazo C12 H10 N2CI 2+ 4HCI + 2NaNO 2 C12 H6 N4CI 4 + 2NaCI + 4 H 2O Mol.Wt. 253 +146 + 138 348 + 117 + 72 b. Coupling with PTMP

3-3-DCB Diazo + PTMP + C.S. Flacks Coupling Pigment Orange 34 C12 H6 N4CI 4 +2[C 11 H11 N2O] +2NaOH C34 H28 Cl 2N8O2+ 2H 2O + 2NaCI Mol.Wt. 348 + 376 +80 651 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2903 2 ICE 2200 Washing water for Re-Use 3000 3 3,3-DCB 495 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 105 6 PTMP 518 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9903 TOTAL 9903

108

86) Pigment Orange 36 cas no 12236-62-3:-

Manufacturing Process: -

PCONA cas no. 89-63-4is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with AABI cas no 26576-46-5.Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of PCONA

PCONA Diazotization PCONA Diazo C6H5CIN 2O2 + 2HCI + NaNO 2 C6H3CI 2N3O2 + NaCI + 2H 2O Mol.Wt. 172.5+ 73 + 69 220 + 58.5 + 36 b. Coupling with AABI

PCONA Diazo + AABI + C.S. Flacks Coupling Pigment Orange 36 C6H3CI 2N3O2 + C 11 H11 N3O3+ NaOH C17 H13CI N6O5+ H 2O + NaCI Mol.Wt. 220 + 233 +40 416.5 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2905 2 ICE 2200 Washing water for Re -Use 3000 3 PCONA 505 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 115 6 AABI 500 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9905 TOTAL 9905

109

87) Pigment Orange 43 [ CAS No.: 4424-06-0] :-

Manufacturing Process:

In SS reactor charge 1.4.5.8-naphthalenetetracarboxylicacid- 1,8-monoanhydride, 1,2- diaminobenzene and water. Heat the mass to 100 temp. in 4 hrs. then further heat it to 145-150 temp. in 4 hrs. Maintain this temperature for 6 hrs. to complete condensation reaction. After complete condensation reaction mass is cool to 100 temp. in 4 hrs and further it cool to room temperature and pigment is isolated. Filter the pigment slurry and wash with water. ML and wash water are sent to ETP. Wet cake is then dried and pulverized and then sent to packaging.

Chemical Reaction :-

1.4.5.8-naphthalenetetracarboxylicacid- Condensate Pigment Orange 43 1,8-monoanhydride + , 1,2- diaminobenzene C26H16N4O2 + 5H2O C14H10O7 + 2 (C6H8N2)

Mol.Wt. 286 + (2x 108) 412 + 90

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 1.4.5.8- 730 Finished Product 1000 naphthalenetetracarboxylicacid- 1,8-monoanhydride 2 1,2-diaminobenzene 552 Aqueous Effluent to ETP 3232 3 Water 3025 Drying Loss 1575 4 Water For washing 1500 TOTAL 5807 TOTAL 5807

110

88) Pigment Orange 62 [ cas no.52846-56-7]:-

Manufacturing Process: -

P-Nitro Aniline [PNA cas no.100-01-6] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with AABI [ cas no.26576-46-5]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of PNA

PNA Diazotization PNA Diazo C6H6N2O2 + 2HCI + NaNO 2 C6H4CIN 3O2 + NaCI + 2H 2O Mol.Wt. 138 + 73 + 69 185.5 + 58.5 + 36 b. Coupling with AABI PNA Diazo + AABI + C.S. Flacks Coupling Pigment Orange 62 C6H4CIN 3O2 + C 11 H11 N3O3+ NaOH C17 H14 N6O5+ H 2O + NaCI Mol.Wt. 208.5 + 233 +40 382 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2770 2 ICE 2000 Washing water for Re -Use 3000 3 PNA 375 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 185 6 AABI 625 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9770 TOTAL 97 70

111

89) Pigment Orange 64 cas no.72102-84-2:-

Manufacturing Process: -

Methyl aminolone cas no.67014-36-2 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Barbituric Acid cas no.67-52-7. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of Methyl aminolone

Methyl aminolone Diazotization Methyl aminolone Diazo C8H7N3O + 2HCI + NaNO 2 C8H5CIN 4O + NaCI + 2H 2O Mol.Wt. 161 + 73 + 69 208.5 + 58.5 + 36

b. Coupling with Barbituric Acid

MAO Diazo + Barbituric Acid + C.S. Flacks Coupling Pigment Orange 64 C8H5CIN 4O + C 4H4N2O3+ NaOH C12 H8N6O4+ H 2O + NaCI Mol.Wt. 208.5 + 128 +40 300 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2910 2 ICE 2200 Washing water for Re -Use 3000 3 Methyl aminolone 500 Water Evaporation in Drying 3000 4 HCI 385 Finish Product 1000 5 Sodium Nitrite 115 6 Barbituric Acid 510 7 C.S.Flacks 200 8 Fresh Water for Washing 3000 TOTAL 9910 TOTAL 9910

112 4 Pigment Blue Quantity per Month = 200 MT per Month

90) Pigment Blue 1[ CAS NO. 1325-87-7]: -

Manufacturing Process: -

3,4,9,10-Perylene Tetracorboxylic Acid Diamide [ PTCBAD cas no.81-33-4] is condensed with 2 moles of 4-Methoxybenzyl Chloride [PMBCI cas no.824-94-2] in aqueous media in reflux condition at 85-90 0C for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C by adding water for isolation. Then reaction mass is filtered. filtrate is sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed a. Condensation of PTCBAD with PMBCI: -

PTCBAD PMBCI 2 KOH Condensation Pigment Blue 1 C24 H10 N2O4 +2[C8H9CIO] + 2KOH C40 H26 N2O6 + 2H 2O + 2KCI Mol.Wt.390 + 2[156.5] + 112 630 + 36 + 149

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Water 3000 Finish Product 1000 2 KOH 270 Water Evaporation in Drying 2500 3 PTCBAD 780 KCI Recovery for re-Use 800 4 PMBCI 250 Washing water for Re -Use 3000 5 Water for Washing 3000 6 TOTAL 7300 TOTAL 7300

113

91) Pigment Copper Phthalocyanine Blue 15 [cas no.147-14-8]:-

Manufacturing Process: -

Crude copper Phthalocyanine is produced by condensing phthalic anhydride [cas no.85-44- 9], cuprous chloride and Urea [cas no.57-13-6] in presence of ammonium molybdate as catalyst in the presence cuprous chloride & ammonium molybdate as a catalyst in solvent like Nitrobenzene, Dichloro Benzene at reflux condition at 170-180 0C for 8-9 hrs till condensation reaction gets complete. During the reaction ammonia and carbon dioxide gas are evolved due to decomposition of urea, which are scrubbed in a two-stage water scrubbing system. After the condensation reaction, over, the product is transferred to Venulath dryer for recovery of solvent, where Trichloro benzene is distilled out using vacuum and crude copper Phthalocyanine blue is obtained as cake. This crude product is then stirred with 15 % Sulphuric acid and water. The mass is heated using live steam to 90 0C. During the process, inorganic impurities get dissolved in water while the product, which is insoluble, remains in the solid form. The slurry from the purification is taken to the filter press where the dissolved impurities are removed as filtrate, which is taken to the effluent treatment plant. The cake is then washed with water and the washings are also taken for treatment. The wet cake is then taken to the spin flash dryer. The product is obtained as a fine powder, which is then sent for packing.

Condensation of Phthalic Anhydride with Urea: -

Phthalic Anhydride+ Urea + Condensation Pigment Blue15 crude CuCI C32 H16 CuN 8 + 4[(NH 4)2CO 3 +4CO 2 + HCI 4[C 8H4O3]+ 8[CH 4N2O] + CuCl Mol.Wt.4X148 + 8[60] + 99 NB/DCB/ONT 575.5 + 4x96 + 4x44 + 36.5 AmmoniumMolybdate

Synthesis & Recovery of Ammonium Sulphate from reaction as by Product :-

Ammo. Carbonate + Spent Neutralization Ammonium Sulphate H2SO 4 4[(NH 4)2SO 4+ 2CO 2 + 4H 2O 4[(NH 4)2CO 3 + 4[H 2SO 4] Mol.Wt.4X96 + 4[98] 528 + 4x96 + 72

114

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 NB / DCB 3500 Finish Product 1000 2 Phthalic Anhydride 1110 Water Evaporation in Drying 3000 3 Urea 890 NB / DCB Recovery for re -Use 3325 4 Cuprous Chloride 205 45% Spent H 2SO 4 5800 5 Ammonium Molybdate 2.5 Ammonium Sulphate Recovery 1750 6 Steam 1800 Water Evaporation in Drying 0 7 45% Spent H 2SO 4 5800 Washing water for Re-Use 4000 8 Process water 10000 Effluent to ETP in MEE 8432 9 Water for Washing 4000 TOTAL 27307 TOTAL 27307

115

92) Pigment Alpha Blue 15:1[ cas no. 147-14-8]:- Manufacturing Process: -

Note:-There is No any Chemical Reaction Only removing of inorganic Impurities From CPC [ cas no. 147-14-8] is carried out. Take Sulphuric acid (98%) in a reaction vessel. Then slowly charge Copper Phthalocyanine crude. Maintain temperature just below 85 0C. So that as to dissolve it too completely. The mass is stirred further for 2-3 hrs. at 60 0Cand then cooled to room temperature by external circulation of water in jacket. Recycled water is then introduced as a thin spray into the vessel slowly; take care to maintain the temperature below 60 0C. The CPC separate out in the required form and is filtered off. After filtration process whatever mother liquor generated that contains approximate 38-40% of Sulphuric acid which is re-used in to the manufacture of CPC blue. Cake washed by hot Water which is re-used in next batch. The CPC cake is dried, Pulversed & packed.

Condensation of Phthalic Anhydride with Urea: - Pigment Blue15 crude Acid Pasting Pigment Alpha Blue 15:1 C32 H16 CuN 8 + H2SO 4 C32 H16 CuN 8 + Spent H 2SO 4

Mol.Wt.575.5 + 98 Water 575.5 + 98

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 CPC Blue Crude 1100 Finish Product 1000 2 Sulphuric Acid 98% 5000 Water Evaporation in Drying 3000 3 ICE 4000 45% Spent H 2SO 4 9500 4 Process Water for Dumping 8000 Ammonium Sulphate Recovery 1450 5 Ammonium Hydroxide 1500 Water Evaporation in Drying 6650 6 Process water 2000 Washing water for Re -Use 5000 7 Water for Washing 5000 TOTAL 26600 TOTAL 26600

116 93) Pigment Beta Blue 15:2 [ cas no. 147-14-8]: -

Manufacturing Process: -

Note: -There is No any Chemical Reaction Only removing of inorganic Impurities From CPC is carried out. Take Solvent like Xylene/IBA/MCB in a reaction vessel. Then slowly charge Copper Phthalocyanine crude. Maintain temperature just below 85 0C. So that as to dissolve it too completely. The mass is stirred further for 2-3 hrs. at 80 0C and then cooled to room temperature by external circulation of water in jacket &mass is filtered off. After filtration solvent is distilled out foe re-use. Cake washed by hot Water which is re-used in next batch. The CPC cake is dried, Pulversed & packed.

Condensation of Phthalic Anhydride with Urea: - Pigment Blue15 crude Acid Pasting Pigment Alpha Blue 15:2 C32 H16 CuN 8 + H2SO 4 C32 H16 CuN 8 + Spent H 2SO 4 Mol.Wt.575.5 + 98 Water 575.5 + 98

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 CPC Blue Crude 1100 Finish Product 1000 2 Solvent 5000 Water Evaporation in Drying 3000 3 Surfactant 10 Solvent Recovery 4750 4 Water for Washing 15000 Washing water for Re-Use 8000 Effluent to ETP 4360 TOTAL 21110 TOTAL 21110

117

94) Pigment Beta Blue 15:3 Beta Blue [ cas no. 147-14-8]: -

Manufacturing Process: -

Condensation of Phthalic Anhydride with Urea: - Pigment Blue15 crude Acid Pasting Pigment Alpha Blue 15 ;3 C32 H16 CuN 8 + H2SO 4 C32 H16 CuN 8 + Spent H 2SO 4 Mol.Wt.575.5 + 98 Water 575.5 + 98

Raw Material Consumption & Mass Balance for One TON Product: -

118 95) Pigment Beta Blue 15:4[ cas no. 147-14-8]: -

Manufacturing Process: -

Condensation of Phthalic Anhydride with Urea: - Pigment Blue15 crude Acid Pasting Pigment Alpha Blue 15:4 C32 H16 CuN 8 + H2SO 4 C32 H16 CuN 8 + Spent H 2SO 4 Mol.Wt.575.5 + 98 Water 575.5 + 98

Raw Material Consumption & Mass Balance for One TON Product: -

119 96) Pigment Beta Blue 15:6 [ cas no. 147-14-8]: -

Manufacturing Process: - Note: -There is No any Chemical Reaction Only removing of inorganic Impurities From CPC is carried out. Take Solvent like Xylene/IBA/MCB in a reaction vessel. Then slowly charge Copper Phthalocyanine crude. Maintain temperature just below 85 0C. So that as to dissolve it too completely. The mass is stirred further for 2-3 hrs. at 80 0C and then cooled to room temperature by external circulation of water in jacket &mass is filtered off. After filtration solvent is distilled out foe re-use. Cake washed by hot Water which is re-used in next batch. The CPC cake is dried, Pulversed & packed.

Condensation of Phthalic Anhydride with Urea: - Pigment Blue15 crude Acid Pasting Pigment Alpha Blue 15:6 C32 H16 CuN 8 + H2SO4 C32 H16 CuN 8 + Spent H 2SO 4 Mol.Wt.575.5 + 98 Water 575.5 + 98

Raw Material Consumption & Mass Balance for One TON Product: -

120 97) Pigment Blue 16 [ cas no. 574-93-6]: -

Manufacturing Process: -

Copper Phthalocyanine [cas n. 147-14-8]is chlorinated by Chlorine gas in the presence of molten Aluminum Chloride & Sodium Chloride under reflux condition at 180-190 0C till desired mole of chlorine [ 15 to 16] takes place. Chlorine & HCL gas evolves is scrubbed in Double effect Scribing system to recover spent HCL to re-use for self-consumption. After completion of chlorination, mass is drowning of all GLV mass in drowning vessel & than filter, wash & keep for finishing the green. For finishing the final green, MS reactor required with steam heating system. In this vessel charge solvent, emulsifier & do reflux than distilled solvent than filter, wash & dry in SFD. Make blend in blender for finish Packing.

Chlorination of CPC by AlCI3 & Chlorine Gas: - Pigment Blue15 crude Chlorination Pigment Blue 16 C32 H16 CuN 8 + 5AICI 3 + NaCI C32 CI 16 CuN 8 + 16 HCI Mol.Wt.575.5 + 5x133.5+ 58.5 Chlorine Gas 8CI 2 1091.5 to 1127 + 584

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 CPC Blue Crude 650 Finish Product 1000 2 AICI 3 700 Water Evaporation in Drying 3000 3 NaCI 300 Spent HCL Recovery 18-20% 8000 4 Chlori ne Gas 350 Aluminum salt recover 600 5 Water for Drowning 14000 MCB Recovery 450 6 MCB 500 Washing water for Re-Use 7000 7 Water for Washing 7000 Effluent to ETP 2450 TOTAL 23500 TOTAL 22500

121 98) Pigment Blue 60 [ CAS NO. 81-77-6]: -

Manufacturing Process: -

2 moles of 2-Amino Anthraquinone [ 2-AQ cas no.117-79-3] is self-condensed in Polyethylene Glycol [PEG] using Sodium Chlorate & KOH in reflux condition at 85-90 0C for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C by adding water for isolation. Then reaction mass is filtered.From filtrate, PEG is recovered for Re-use &remaining is sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed a. Condensation of 2-Amino Anthraquinone: -

2-Aminoanthraquinone Condensation Pigment Blue 60 2[C 14 H9NO 2 + 2NaCIO 3 C28 H14 N2O4 + 2H 2O + 2NaCI 2O 2 Mol.Wt.2 [ 223 ] + 2[106.5] PEG +KOH 442 + 36 + 117 + 64

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Poly Ethylene Glycol 1350 Finish Product 1000 2 KOH 270 Water Evaporation in Drying 2052 3 Sodium Chlorate 112 PEG Recovery for re -Use 1280 4 2-Amino Anthraquinone 1020 Washing water for Re-Use 3000 5 Water for Isolation 3000 Effluent to ETP 1420 6 Water for Washing 3000 TOTAL 8752 TOTAL 8752

122 99) Pigment Blue 62 [ CAS NO. 57485-98-0 / 82338-76-9]: -

Manufacturing Process: -

3,4,9,10-Perylene Tetracorboxylic Acid Diamide [ PTCBAD cas no.81-33-4] is condensed with 2 moles of Benzyl Chloride [BCI cas no.100-44-7] in aqueous media in reflux condition at 85-90 0C for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 35 0C by adding water for isolation. Then reaction mass is filtered. filtrate is sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed a. Condensation of PTCBAD with PMBCI: -

PTCBAD BCI 2 KOH Condensation Pigment Black 31 C24 H10 N2O4 + 2[C7H7CI] +2 KOH C38 H22 N2O4 + 2H 2O + 2KCI Mol.Wt.390+ 2[126.5] + 112 570 + 36 + 149

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Water 3000 Finish Product 1000 2 KOH 270 Water Evaporation in Drying 2510 3 PTCBAD 790 KCI Recovery for re -Use 800 4 BCI 250 Washing water for Re-Use 3000 5 Water for Washing 3000 6 TOTAL 7310 TOTAL 7310

123

5 Pigment Violet Quantity per Month = 200 MT per Month

100) Pigment Violet 1 [ CAS NO..1326-03-0]: -

Manufacturing Process: -

2 Moles of Diethyl meta amino Phenol [ DEMAP]Cas No.1326-03-0 is condensed with phthalic Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into phosphomolybdic acid [ PMA] salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of DEMAP with Phthalic Anhydride: -

DEMAP Phthalic Anhydride + Condensation Pigment Violet 1 Hydroxide Ethanol hydride 2[ C 10 H15 NO ] + C 8H4O3 + C 2H5OH C28 H31 N2O3PMA Salt + H 5O3 Mol.Wt. 2 x 165 + 148 + 46 443+PMA salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 DEMAP 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re-use 950 3 Ethanol 1000 Washing water for Re -Use 2000 4 Phosphomolybdic acid [ PMA] 100 Evaporation loss 1265 5 Water for Washing 3000 TOTAL 5215 TOTAL 5215

124

101) Pigment Violet 1x [ CAS NO..]: -

Manufacturing Process: -

a. Condensation of EAMP with Phthalic Anhydride: -

EAMP Phthalic Anhydride + Condensation Pigment Red 81 Hydroxide Ethanol hydride 2[ C 9H13 NO ] + C 8H4O3 + C 2H5OH C28 H31 N2O3SM Salt + H 5O3 Mol.Wt. 2 x 151 + 148 + 46 443+SAM salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 EAMP 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re -use 950 3 Ethanol 1000 Washing water for Re-Use 2000 4 Silicomolybdic acid [ SM] 100 Evaporation loss 1265 5 Water for Washing 3000 TOTAL 5215 TOTAL 5215

125 102) Pigment Violet 3 [ CAS NO.1325-82-2.]: -

Manufacturing Process: -

3 Moles of N,N’Dimethyl aniline [ DMA]Cas No.121-69-7 is self-condensed in ethanol Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into phosphomolybdic acid salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of DMA with Self: -

DMA + Ethanol Condensation Pigment Violet 1 Hydroxide 3[ C 9H13 NO ] + C 2H5OH hydride C234 H28 N3PM Salt + H 5O3 Mol.Wt. 3x 111 + 46 443+PM salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 DMA 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re-use 950 3 Ethanol 1000 Washing water for Re -Use 2000 4 Phosphomolybdic acid [ PM] 100 Evaporation loss 1265 5 Water for Washing 3000 TOTAL 5215 TOTAL 5215

126

103) Pigment Violet 19 [ CAS NO. 1047-16-1.]: -

Manufacturing Process: -

1.Dimethyl Succinosuccinate [DMSS CAS No.6289-46-9] is condensed with 2 moles of Aniline in methanol under efflux condition to form dimethyl 2,5-dianilino-3,6-dihydro-terephthalate [ DADHT].

2.Then resulting product is oxidised with resist salt to form 2,5-dianilino-3,6-dihydro-terephthalate dimethyl ester [DADHT dimethyl ester].

3.Then it is hydrolyzed in alkaline condition & aqueous medium to form 2,5-Bis-(p-anilino) terephthalic acid [DADHT Acid]

4.Then it is further cyclised in presence of Poly phosphoric acid then finally pigmentation is done in presence of IBA/DMF as per Quinacridone as Pigment Violet 19

1.Condensation of DMSS with Aniline: - DMSS + 2[Aniline] Condensation DADHT C10 H12 O6 + 2[C 6H7N] C22 H22 N2O4 + 2H 2O Mol.Wt.228 + 2X[93] Methanol 378 + 36

2.Oxidation Of DADHT with Resist Salt: - DADHT Condensation DADTA dimethyl ester C22 H22 N2O4 + O 2 C22 H20 N2O4 + H 2O2 Mol.Wt. 378 + 32 Resist Salt 376 + 34

3.Hydrolysis of DADTA dimethyl ester:- DADTA dimethyl ester Hydrolysis DADTA Acid C22 H20 N2O4 + 2NaOH +2HCL C20 H18 N2O4 + 2NaCI + 2CH 3OH Mol.Wt. 376 + 80 + 73 Methanol 376 + 117 + 64

4.Cyclisation of DADTA Acid with Poly Phosphoric Acid & Pigmentation to form Pigment Red 122:- DADTA Acid Poly Phosphoric Cyclisation Pigment Violet 19 Triphosphoric Acid acid monohydrate C20 H18 N2O4 + H 3PO 4.P 2O5 C20 H12 N2O2 + H 5P3O10 .H 2O Mol.Wt. 376 + 238 DMF /IBA 340 + 274

127 Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Methanol 5500 Finish Product 1000 2 Dimethyl 800 Water Evaporation in Drying 2500 Succinosuccina te 3 Aniline 830 Methanol Recovery for Re -Use 5225 4 Resist Salt 300 Washing water for Re-Use 7000 5 NaOH 275 Effluent to ETP treatment in MEE 7500 6 HCL 250 DMF /IBA Recovery for Re -Use 6600 7 Poly Phosphoric Acid 1800 Inorganic & solvent residue 680 8 DMF / IBA 7000 9 Water for Reaction 7000 1 Water for Isolation 7000 TOTAL 30505 TOTAL 30505

128

104) Pigment Violet 23 [ CAS NO. 6358-30-1.]: -

Manufacturing Process: -

1. Carbazole [ cas no.86-74-8] undergoes with Diethylsulphate [DES cas no.64-67-5] in the presence of Mono Chloro Benzene [MCB] & NaOH under efflux condition to form N-Ethyl Carbazole

2.Then N-Ethyl Carbazole undergoes Nitration with Nitric Acid in the presence of Mono Chloro Benzene [MCB] to form 3-Nitro-N-Ethyl Carbazole

3.Then 3-Nitro-N-Ethyl Carbazole undergoes Hydrogenation in presence of Ortho Dichloro Benzene using Raney Nickel as catalyst to form3-Amino-N-Ethyl Carbazole

4.Then 3-Amino-N-Ethyl Carbazole is further condensed &cyclised with Chloranil in presence of methanol to form Pigment Violet 23

1.Ethylationof Carbazole with Diethyl Sulphate[DES]: - Carbazole + DES Ethylation N-Ethyl Carbazole C12 H9N + C 4H10 O4S + 2NaOH C14 H13 N+ H 2O +Na 2SO 4 +C 2H5OH Mol.Wt.167 + 154 + 80 MCB 195 + 18 + 142 + 46

2.Oxidation Of DADHT with Resist Salt: - N-Ethyl Carbazole Nitration 3-Nitro-N-Ethyl Carbazole C14 H13 N + HNO 3 C14 H12 N2O2 + HO 2 Mol.Wt. 195 + 63 MCB 240 + 18

3.Hydrolysis of DADTA dimethyl ester: - 3-Nitro-N-Ethyl Carbazole Hydrogenation 3-Amino-N-Ethyl Carbazole C14 H12 N2O2 + H 2 C14 H14 N2 + O 2 Mol.Wt. 240 + 2 ODCB /Al/Ni 210 + 32

4.Cyclisation of DADTA Acid with Poly Phosphoric Acid & Pigmentation to form Pigment Violet 23:- 3-Amino-N-Ethyl Chloranil Condensation& Pigment Violet 23 Carbazole Cyclisation C34 H26 CI 2N4O2 + 2NaCI + 2H 2O 2[C 14 H14 N2] + C 6CI 4O2 2 NaOH Mol.Wt. 420 + 246 + 80 Methanol 593 + 117 + 36

129 Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Mono Chloro Benzene 1000 Finish Product 1000 2 Carbazole 800 Water Evaporation in Drying 2500 3 Di Ethyl Sulphate 470 Methanol Recovery for Re -Use 4750 4 NaOH Flacks 500 MCB Recovery for Re-Use 950 5 Nitric Acid 45% 600 ODCB Recovery for Re -Use 9500 6 Hydrogen Gas 8 DEG Recovery for Re -Use 950 7 Ortho Dichloro Benzene 10000 Washing water for Re-Use 8000 8 Sodium acetate 50 Effluent to ETP treatment in MEE 15778 9 Methanol 5000 Raney Nickel Recovery 8 10 Raney Nickel 8 Inorganic & solvent residue 680 11 DEG 1000 12 ICE 1000 13 Process Water for 15000 Reaction 14 Water for Washing 8000 TOTAL 43436 TOTAL 43436

130 105) Pigment Violet 27 [ CAS NO.12237-62-6]: -

Manufacturing Process: -

2 Moles of Methyl Violet react with 2Moles of Copper Sulfate in Presence of Sodium Ferocynide the result of Product will be Pigment Violet 27 (2Moles) , 2Moles of Sodium Sulfate and 1Mol of Ferocynide. Product is washed with Hot Water & washing water, then it is dried in spin flash dryer, pulverized & packed

a. Chemical Reaction : -

Methyl Violet + Copper Sulfate + Sodium Condensatio Pig.Violet 27 + Sodium Sulfate + Fero Fero n Cynide Cynide 2(C24H27N3)+ 2Na2So4 + 2(C24H27N3) + 2(CuSo4) + Fe(CN)6 Na4Fe(CN)6 2(357) + 2(159) + 303` 2 (357) + 2(142) + 211

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Methyl Violet 714 Finish Product 714 2 Copper Sulfate 159 Washing water for Re -Use 2000 3 Sodium FeroCynide 303 Evaporation loss 962 5 Water for Washing 2500 TOTAL 3676 TOTAL 3676

131

106) Pigment Violet 29 [ CAS NO.81-33-4.]: -

Manufacturing Process: -

3 Moles of N,N’Dimethyl aniline [ DMA]Cas No.121-69-7 is self-condensed in ethanol Then ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in next batch & wet cake converted into ferrous iron copper cyanide complex salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of DMA with Self: -

DMA + Ethanol Condensation Pigment Violet 1 Hydroxide 3[ C 9H13 NO ] + C 2H5OH hydride C234 H28 N3CF Salt + H 5O3 Mol.Wt. 2 x 111 + 46 443+CF salt + 53

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 DMA 600 Finish Product 1000 2 Phthalic Anhydride 515 Ethanol Recovery for Re-use 950 3 Ethanol 1000 Was hing water for Re -Use 2000 4 Ferrous Iron copper cyanide [ PM] 100 Evaporation loss 1265 5 Water for Washing 3000 TOTAL 5215 TOTAL 5215

132

Total Quantity per Month Total Number of Dyes B Solvents Dyes ( 1 + 2 + 3 + 4 + 5 + 6 ) = 200 MT per (1 + 2 + 3 + 4 + 5 + 6 ) = 41 Month

1 Red Solvent Dyes Quantity per Month =

Category B : SOLVENTS :-

1. Red Solvent Dyes –

107) Solvent Red 19E [ cas no. 6368-72-5] : -

Manufacturing Process: -

Garnet GB Base [ cas no.97-56-3] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with n-Ethyl-Naphthalene- amine [ n-ENA cas no.2437-03-8]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of Garnet GB Base

Garnet GB Base Diazotization Garnet GB Base Diazo C14 H15 N3 + 2HCI + NaNO 2 C14 H13 CIN 4 + NaCI + 2 H 2O Mol.Wt.225 + 73 + 69 272.5 + 58.5 +36 b. Coupling with n-ENA

Garnet GB Base Diazo + n-ENA +C.S. Flacks Coupling Solvent Red 19E C14 H13 CIN 4 + C 12 H13 N +NaOH C26 H25 N5 + H 2O + NaCI Mol.Wt. 272.5 + 171 + 40 407 + 18 + 58.5

133

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 1945 2 ICE 2000 Washing water for Re -Use 3000 3 Garnet GB Base 500 Water Evaporation in Drying 3000 4 HCI 400 Finish Product 1000 5 Sodium Nitrite 205 6 n-ENA 435 7 C.S. Flacks 200 8 Calcium Chloride 205 9 Fresh Water for Washing 2000 TOTAL 8945 TOTAL 8945

134

108) Solvent Red 23 [CAS No. 85-86-9] : Manufacturing Process: Dissolve 4-(phenyldiazenyl) aniline in water and hydrochloric acid. Stir it for 1 hr. Cool it to 0 temp. and rapidly sodium nitrite solution. Maintain temp. below 10 and stir for 1 hr. For Coupler Dissolve naphthalen-2-ol in sodium hydroxide and water solution. Cool to 10 temp. Now, Add above prepared Diazo solution in coupler solution in about 1-2 hrs. After complete addition pH is 9-10. During addition maintain temp. 10-15. stir for 1 hr at this temp. Heat the mass to 40 and maintain for 3 hrs. Further heat it to 90temp. and maintain for 30 minute. Cool to 70 temp. for filtration. Filter the pigment slurry and wash with water up to salt free. Filtrate and wash water are sent to ETP. Wet cake is then dried and pulverized and then sent to packaging. Chemical a. Diazotization of 4-(phenyldiazenyl) (PAAB) :- PAAB Diazotization PAAB Diazo C12H11N3+ 2HCI + NaNO 2 C12H9N4Cl + NaCI + 2H 2O Mol.Wt. 197 + 72 + 69 243.5 + 58.5 + 36 b. Coupling with 5-methyl-2-phenylpyrazolidin-3-one :- PAAB Diazo + 5-methyl-2-phenylpyrazolidin-3- Coupling Solvent Yellow 72 one C17H16N4O2+ H 2O + NaCI

C12H9N4Cl + C10H8O + NaOH Mol.Wt. 243.5 + 144 + 40 350 + 18 + 58.5 Raw Material Consumption & Mass Balance for One TON Product: - Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Re-use Water 2145 Finished Product 1000 2 HCL 1145 Water for Reuse 2145 3 4-(phenyldiazenyl) aniline (PAAB) 575 Drying Loss 1500 4 Sodium Nitrite 507 Aqueous Effluent to ETP 5412 5 Water from Washing 2145 6 Sodium Hydroxide 260 7 Naphthalen-2-ol (Beta Naphthol) 420 8 Water For W ashing 2860 TOTAL 10057 TOTAL 10057

135

109) Solvent Red 24 [ cas no. 85-83-6] : -

Manufacturing Process: -

Garnet GB Base [ cas no.97-56-3] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Beta Naphthol [cas no.135-19-3]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of Garnet GB Base

Garnet GB Base Diazotization Garnet GB Base Diazo C14 H15 N3 + 2HCI + NaNO 2 C14 H13 CIN 4 + NaCI + 2 H 2O Mol.Wt.225 + 73 + 69 272.5 + 58.5 + 36 b. Coupling with Beta Naphthol

Garnet GB Base Diazo + B-N +C.S. Flacks Coupling Solvent Red 24 C14 H13 CIN 4 + C 10 H8O +NaOH C24 H20 N2O2 + H 2O + NaCI Mol.Wt. 272 .5 + 144 + 40 380 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2045 2 ICE 2000 Washing water for Re-Use 3000 3 Garnet GB Base 600 Water Evaporation in Drying 3000 4 HCI 400 Finish Product 1000 5 Sodium Nitrite 205 6 Beta Naphthol 435 7 C.S. Flacks 200 8 Calcium Chloride 205 9 Fresh Water for Washing 2000 TOTAL 9045 TOTAL 9045

136

110) Solvent Red 52 [ cas no. 81-39-0]: -

Manufacturing Process: - 6-Bromo anthrapyridone [6-BAPcas no .81-85-6.] is condensed with p-Toluidine [cas no.106- 49-0] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 6-BAP p-Toluidine Condensation Sol.Red 52 C17 H10 BrNO 2 + C 7H9N + KOH C24 H18 N2O2 + KBr + H 2O Mol.Wt.340 + 107 + 56 Xylene / 366 + 119 + 18 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 6-BAP 700 Water Evaporation in Drying 1000 3 p-Toluidine 310 Xylene / ODCB Recovery for recycled 950 4 Met hanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4160 TOTAL 9010 TOTAL 9010

137

111) Solvent Red 111 [ cas no. 82-38-2]: -

Manufacturing Process: -

1-Chloro Anthraquinone [1-Chloro AQ cas no .82-44-0.] is condensed with Methane amine [cas no.74-89-5] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1-Chloro AQ Methane amine Condensation Sol.Red 111 C14 H7CIO 2 + CH 5N + NaOH C15 H11 NO 2 + NaCI + H 2O Mol.Wt.242.5 + 31 + 40 Xylene / 237 + 58.5 + 18 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 1-Chloro AQ 713 Water Evaporation in Drying 1000 3 Methane amine 250 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4113 TOTAL 8963 TOTAL 8963

138 112) Solvent Red 135 [ cas no. 20749-68-2]: -

Manufacturing Process: -

Tetra Chloro Phthalic Anhydride [TCAP cas no .117-08-8.] is condensed with 1,8-Diamino Naphthalene [cas no.479-27-6] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: TCAP 1, 8-DAN Condensation Sol.Red 135 C8CI 4O3 + C 10 H10 N2 C18 H6CI 4NO 2 + 2 H 2O Mol.Wt.285 + 158 Xylene / 408 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Produc t 1000 2 TCAP 685 Water Evaporation in Drying 1000 3 1,8 -DAN 350 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4185 TOTAL 9035 TOTAL 9035

139 113) Solvent Red 151 [ cas no. 144013-41-1]: -

Manufacturing Process: - 6-Bromo anthrapyridone [6-BAPcas no .81-85-6.] is condensed with 3-Chloroaniline [cas no.108-42-9] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 6-BAP 3-Chloroaniline Condensation Sol.Red 151 C17 H10 BrNO 2 + C 6H6CIN + KOH C23 H15 CIN 2O2 + KBr + H 2O Mol.Wt.340 + 127.5 + 56 Xylene / 386.5 + 119 + 18 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 6-BAP 690 Water Evaporation in Drying 1000 3 3-Chloroaniline 315 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4155 TOTAL 9005 TOTAL 9005

140 114) Solvent Red 168 [ cas no. 71832-19-4]: -

Manufacturing Process: - 1-Chloro Anthraquinone [1-Chloro AQ cas no .82-44-0.] is condensed with Cyclo Hexylamine [cas no.108-91-8] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1-Chloro AQ Cyclo Hexylamine Condensation Sol.Red 168 C14 H7CIO 2 + C 6H13 N + NaOH C20 H13 NO 2 + NaCI + H 2O Mol.Wt.242.5 + 99 + 40 Xylene / 305 + 58.5 + 18 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 1-Chloro AQ 713 Water Evaporation in Drying 1000 3 Cyclo hexyl amine 291 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4154 TOTAL 9004 TOTAL 9004

141 115) Solvent Red 169 [ cas no. 27354-18-3]: -

Manufacturing Process: -

1-Chloro Anthraquinone [1-Chloro AQ cas no .82-44-0.] is condensed with 2-propanol amine [cas no.175-31-0] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1-Chloro AQ 2-Propanolamine Condensation Sol.Red 169 C14 H7CIO 2 + C 3H9N + NaOH C17 H15 NO 2 + NaCI + H 2O Mol.Wt.242.5 + 59 + 40 Xylene / 265 + 58.5 + 18 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 1-Chloro AQ 805 Water Evaporation in Drying 1000 3 2-Propanolamine 205 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for rec ycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4160 TOTAL 9010 TOTAL 9010

142 116) Solvent Red 179 [ cas no. 6829-22-7/ 89106-94-5]: -

Manufacturing Process: -

1,8-Diamino Naphthalene [1,8-DAN cas no .479-27-6.] is condensed with 1,8-Naphthalic Anhydride [cas no.81-84-5] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1,8-DAN 1,8-Naphthalic Anhydride Condensation Sol.Red 179 C10 H10 N2 + C 12 H16O3 C22 H12 N2O + 2H 2O Mol.Wt.158 + 198 Xylene / 320 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 1,8-DAN 445 Water Evaporation in Drying 1000 3 1,8 -Naphthalic Anhydride 560 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4155 TOTAL 9005 TOTAL 9005

143

117) Solvent Red 197 [ cas no. 52372-39-1]: -

Manufacturing Process: -

DEAMAP Aldehyde [cas no .17754-90-4.] is condensed with 2-Amino 2,3-Dihydro1-H- Benzamidazole-2-Methylpropionitrile [2-A,2,3-DHHBMMP cas No. 17754-90-4.] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: DEAMAP Aldehyde 2-A,2,3-DHHBMMP Condensation Sol.Red 197 C11 H15 NO 2 + C 13 H16 N4 C23 H19 N5O + CH 3OH + 4H 2 Mol.Wt.193 + 228 Xylene / 381 + 32 + 8 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 DEAMAP Aldehyde 525 Water Evaporation in Drying 1000 3 2-A,2,3 -DHHBMMP 590 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re -cycle for Re -Use 4265 TOTAL 9115 TOTAL 9115

144 118) Solvent Red 207 [ cas no. 15958--69-6]: -

Manufacturing Process: -

1, 8-Dichloro Anthraquinone [1,8-DCAQ cas no .82-43-9.] is condensed with 2 moles of Cyclo Hexylamine [cas No.108-91-8 in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1,8-DCAQ Cyclo Hexylamine Condensation Sol.Red 207 C14 H6CI 2O2 + 2[ C 6H13 N] + 2NaOH C26 H30 N2O2 + 2NaCI + 2H 2O Mol.Wt.277 + 2 x 99 + 80 Xylene / 402 + 117 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xyl ene / ODCB 1000 Finish Product 1000 2 1,8-DCAQ 725 Water Evaporation in Drying 1000 3 Cyclo Hexylamine 295 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4170 TOTAL 9020 TOTAL 9020

145 119) Solvent Red 227 [ cas no. 2944-28-7]: -

Manufacturing Process :

1-Chloro Anthraquinone [1-Chloro AQ cas no .82-44-0.] is condensed with Aniline [cas No.62- 53-3] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1-Chloro AQ Aniline Condensation Sol.Red 227 C14 H7CIO 2 + C 6H7N + NaOH C20 H13 NO 2 + NaCI + H 2O Mol.Wt.242.5 + 93 + 40 Xylene / 299 + 58.5 + 18 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 1-Chloro AQ 795 Water Evaporation in Drying 1000 3 Aniline 215 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4160 TOTAL 9010 TOTAL 9010

146

Yellow Solvent 2 Quantity per Month = Dyes

120) Solvent Yellow 2[CAS No.: 6370-43-0] Manufacturing Process :-

It is mono azo dyes for which first make Aniline is diazotized with sodium nitrite in presence hydrochloric acid at bellow 0 deg temp. and stir for 2 hr. Then dizo component is coupled with Di MethylAniline (D.M.A.) in Acidic medium at 5 deg temperature. Stir for 5 hr. a. Diazotization of Aniline

Aniline Diazotization 2,4-DNA Diazo C6H7N1 + HCI + NaNO 2 C6H7N=NCL + NaCI Mol.Wt. 93 + 36 + 69 140 + 58 b. Coupling with D.M.A.

2,4-DNA Diazo DMA Coupling Solvent Yellow 2 C6H7N=NCL + C8H11N1 + NaOH C14H15N3 + 2HCL Mol.Wt. 140 + 121 + 36 22 5 + 72

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Aniline 415 Finish Product 1000 2 HCL 1000 Washing Regenerate 1005 3 Sodium Nitrite 315 Water Evaporated 10570 4 D.M.A. 545 5 Water 5200 6 Ice 5100 TOTAL 12575 TOTAL 12575

147 121) SOLVENT YELLOW 14 [CAS NO.: 842-07-9]

Manufacturing Process :-

It is mono azo dyes for which first make Aniline is diazotized with sodium nitrite in presence hydrochloric acid at bellow 0 deg temp. and stir for 2 hr. Then dizo component is coupled with β Napthol in Alkaline medium at 5 deg temperature. Stir for 5 hr. a. Diazotization of Aniline

Aniline Diazotization 2,4-DNA Diazo C6H7N1 + HCI + NaNO 2 C6H7N=NCL + NaCI Mol.Wt. 93 + 36 + 69 140 + 58 b. Coupling with BetaNaphthol

2,4-DNA Diazo+ Beta Naphthol Coupling Solvent Yellow 14 C6H3CIN 4O4 + C10H8O1 + NaOH C16H14N2O + NaCl + H2O Mol.Wt. 140 + 144 + 40 248 + 58 + 18

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Aniline 415 Finish Product 1000 2 HCL 1000 Washing Regenerate 2125 3 Beta Naphthol 315 Water Evaporated 5747 4 Soda Ash/ NaOH 200 5 Water 3200 6 Ice 3100 TOTAL 8872 TOTAL 8872

148

122) Solvent Yellow 18 [CASNo.6407-78-9] :-

Manufacturing Process :-

Dissolve 2,4-dimethylaniline in water and hydrochloric acid. Stir it for 1 hr. Cool it to 0 temp. and rapidly sodium nitrite solution. Maintain temp. below 10 and stir for 1 hr. For Coupler Dissolve 5- methyl-2-phenylpyrazolidin-3-one in sodium hydroxide and water solution. Cool to 10 temp. Now add Add above prepared Diazo solution in coupler solution in about 1-2 hrs. After complete addition pH is 9-10. During addition maintain temp. 10-15. stir for 1 hr. at this temp. Heat the mass to 40 and maintain for 3 hrs. Further heat it to 90 temp. and maintain for 30 minute. Cool to 70 temp. for filtration.Filter the pigment slurry and wash with water up to salt free. Filtrate and wash water are sent to ETP. Wet cake is then dried and pulverized and then sent to packaging.

a. Diazotization of 2,4-dimethylaniline (2,4 Xylidine) 2,4 Xylidine Diazotization 2,4 Xylidine Diazo C8H11N+ 2HCI + NaNO2 C8H9N2Cl + NaCI + 2H 2O Mol.Wt. 121 + 73 + 69 168.5 + 58.5 + 36

b. Coupling with P.M.P. 2,4 Xylidine Diazo + P.M.P. + C.S. Flacks Coupling Solvent Yellow 18 C8H9N2Cl + C10H12N2O + NaOH C18H18N4O + H 2O + NaCI Mol.Wt. 168.5 + 176 + 39 306 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Water 3225 Finised Product 1000 2 HC L 1290 Water Reuse for Coupler 1620 3 2,4-dimethylaniline (2,4 Xylidine) 425 Aqueous Effluent to ETP 6950 4 Sodium Nitrite 575 Drying Loss 1500 5 Water For washing (ReUse) 1620 6 sodium hydroxide 130 7 5-methyl-2-phenylpyrazolidin-3-one 580 (P.M.P.) 8 Water for Washing 3225 TOTAL 11070 TOTAL 11070

149 123) Solvent Yellow 33 [ cas no. 8003-22-3]: -

Manufacturing Process: -

Phthalic Anhydride [ [cas no.85-44-9] is condensed with Quinaldine [ cas no.91-63-4] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: Phthalic Anhydride Quinaldine Condensation Sol.Yellow 33 C8H4O3 + C 10 H9N C18 H11 NO 2 + H 2O Mol.Wt.148 + 143 Xylene / ODCB 273 + 18

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Phthalic Anhydride 575 Water Evaporation in Drying 1000 3 Quinaldine 500 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4225 TOTAL 9075 TOTAL 9075

150

124) Solvent Yellow 43 [ cas no. 19125-99-6]: -

Manufacturing Process: -

1-Chloro-1,8-Naphthalic Anhydride [ [cas no.4053-08-1] is condensed with n-Butyl amine [ cas no.12226-96-9] in the presence of Methanol under reflux condition till completion of reaction. Then Methanol is distilled out for re-use & product is isolated by water. Then mass is filtered. Filtrate is collected for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1-CI-1,8-N.A. + n-Butyl Amine + Condensation Sol.Yellow 43 NaOH C20 H24 N2O2 NaCI+ 2H 2O C12 H5CIO 3 + 2[ C 4H11 N] Mol.Wt.232.5 + 2 X 73 + 40 Methanol 324 + 58.5 + 36

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Methanol 2000 Finish Product 1000 2 1-ChIoro-1,8-Naphthaline. A 735 Water Evaporation in Drying 1000 3 n-Butyl Amine 300 Methanol Recovery for recycled 1900 4 C.S.Lye 200 NaCI Recovery 350 5 Water for washing 5000 Washing water Re-cycle for Re-Use 3985 TOTAL 8235 TOTAL 8235

151 125) Solvent Yellow 44 [ cas no. 2478-20-8]: -

Manufacturing Process: -

1-Amino-1,8-Naphthalic Anhydride [ [cas no.6492-86-0] is condensed with 2,4- Dimethylaniline [ cas no.95-78-3] in the presence of Methanol under reflux condition till completion of reaction. Then Methanol is distilled out for re-use & product is isolated by water. Then mass is filtered. Filtrate is collected for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1-A-1,8-N.A. + 2,5-DMA Condensation Sol.Yellow 44 C12 H7NO 3 + C 8H11 N C20 H16 N2O2 + H 2O Mol.Wt.213 + 121 Methanol 316 + 18

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Methanol 2000 Finish Product 1000 2 1-Amino-1,8-Naphthaline. A 635 Water Evaporation in Drying 1000 3 2,5 D.M.A. 400 Methanol Recovery for recycled 1900 4 Water for washing 5000 Washing water Re -cycle for Re -Use 4135 TOTAL 8035 TOTAL 8035

152

126)Solvent Yellow 72 [CAS No.:61813-98-7]

Manufacturing Process:

Dissolve 2-methoxyaniline in water and hydrochloric acid. Stir it for 1hr. Cool it to 0 temp. and rapidly sodium nitrite solution. Maintain temp. below 10 and stir for 1 hr. Now For Coupler Dissolve 5-methyl-2-phenylpyrazolidin-3-one in sodium hydroxide and water solution. Cool to 10 temp. Now Add above prepared Diazo solution in coupler solution in about 1-2 hrs. After complete addition pH is 9-10. During addition maintain temp. 10-15. Stir for 1 hr at this temp. Heat the mass to 40 and maintain for 3 hrs. Further heat it to 90temp. andn maintain for 30 minute. Cool to 70 temp. for filtration. Filter the pigment slurry and wash with water up to salt free. Filtrate and wash water are sent to ETP. Wet cake is then dried and pulverized and then sent to packaging. a. Diazotization of 2-methoxyaniline 2-methoxyaniline Diazotization 2-methoxyaniline Diazo C7H9NO+ 2HCI + NaNO 2 C7H7N2OCl + NaCI + 2H 2O Mol.Wt. 123 + 72 + 69 169.5 58.5 + 36 b. Coupling with 5-methyl-2-phenylpyrazolidin-3-one 2-methoxyaniline + 5-methyl-2- Coupling Solvent Yellow 72 phenylpyrazolidin-3-one. + C.S. Flacks C17H16N4O2+ H 2O + NaCI C7H7N2OCl + C10H12N2O + NaOH Mol.Wt. 169.5 + 176 + 39 308 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Water 3250 Finished Product 1000 2 HCL 1300 ML+ Washing 7012 3 2-methoxyaniline 410 Water for Reuse 2440 4 Sodium Nitrite 575 Drying Loss 1500 5 Re -use Water 2440 6 Sodium hydroxide 130 7 5-methyl -2-phenylpyrazolidin -3-one 597 8 Water for Washing 3250 TOTAL 11952 TOTAL 11952

153

127) Solvent Yellow 114 [ cas no. 75216-45-4 / 7576-65-0]: -

Manufacturing Process: -

3-Hydroxy-2-methyl-4-quinolinecarboxylic acid [ [cas no.117-57-7] is condensed with Phthalic Anhydride [ cas no.85-44-9] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1-H-2,4-QCA. + Phthalic Anhydride Condensation Sol.Yellow 114 C11 H9NO 3 + C 8H4O3 C18 H11 NO 3 + CH 3OH + H 2O Mol.Wt.203 + 148 Methanol 289 + 32 + 18

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Xylene / ODCB 1500 Finish Product 1000 2 3-Hydroxy-2-methyl-4- 615 Water Evaporation in Drying 1000 quinolinecarboxylic acid 3 Phthalic Anhydride 410 Xylene / ODCB Recovery for recycled 1425 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 4000 Washing water Re-cycle for Re-Use 3200 TOTAL 8525 TOTAL 8525

154 128) Solvent Yellow 131 [ cas no71819-82-4]: -

Manufacturing Process:

In clean reaction charge Methanol, 6-chloro-1H,3H-benzo[de]isochromene-1,3-dione and 3-aminopropan-1-ol. Heat the reaction mass to reflux temp and maintain for 10 hrs. Cool the reaction mass to room temp for isolation. Filter the reaction mass and wash with water. Dry the wet cake and pulverize and sent for packing.

Chemical Reaction :-

6-chloro-1H,3H-benzo[de]isochromene- Condensate Solvent Yellow 131 1,3-dione + 3-aminopropan-1-ol C12H5ClO3 + (2 x C2H9NO) C18H20N2O4 + H2O + HC L Mol.Wt.232 + (2x75) 412 + 18 +36

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Methanol 2300 Finished Product 1000 2 6-chloro-1H,3H- 727 Methanol Receovery 2080 benzo[de]isochromene-1,3-dione 3 3-aminopropan -1-ol 300 Drying Loss 1500 4 Water for Washing 2300 Aqueous ML 1047 TOTAL 5627 TOTAL 5627

155 129) Solvent Yellow 157 [ cas no. 27908-75-4]: -

Manufacturing Process: -

tetra-Chloro-phthalic Anhydride [ TCPA cas no.117-08-8] is condensed with Quinaldine [cas no.91-63-4] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized

a. Condensation: Tetrachloro Phthalic Anhydride Condensation Sol.Yellow 157 Quinaldine C18 H7CI 4NO 2 + H 2O C8CI 4O3 + C 10 H9N Mol.Wt.285 + 143 Xylene / ODCB 410 + 18

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Tetra Chloro Phthalic 605 Water Evaporation in Drying 1000 Anhydride 3 Quinaldine 455 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4210 TOTAL 9060 TOTAL 9060

156 130) Solvent Yellow 163 [ cas no. 13676-91-0/106768-99-4]: -

Manufacturing Process: -

1, 8-Dichloro AQ [cas no.82-43-9] is condensed with Thiophene [cas no.108-98-5] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1, 8-DCAQ Thiophene Condensation Sol.Yellow 163 C14 H6CI 2O2 + 2[C 6H6S] + 2 NaOH C26 H16 O2S2 2NaCI + 2H 2O Mol.Wt.277 + 2 x 110 + 80 Xylene / 424 + 117 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 1, 8-Dichloro AQ 650 Water Evaporation in Drying 1000 3 Thiophene 405 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4205 TOTAL 9055 TOTAL 9055

157 131) Solvent Yellow 167 [ cas no. NA]: -

Manufacturing Process: -

1, Chloro A Q [cas no .82-44-0.] is condensed with Thiophene [cas no.108-98-5] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1-Cl-AQ Thiophene Condensation Sol.Yellow 167 C14 H7CIO 2 + C 6H6S + NaOH C20 H12 O2S NaCI + H 2O Mol.Wt.242.5 110 40 Xylene / 316 58.5 18 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 1-chloro AQ 685 Water Evaporation in Drying 1000 3 Thiophene 365 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4200 TOTAL 9050 TOTAL 9050

158

Orange Solvent 3 Quantity per Month = Dyes

132) Solvent Orange 60 [ cas no. 61969-47-9]: -

Manufacturing Process: -

1, 8-Diamino AQ [cas no.85-44-9] is condensed with Phthalic Anhydride [cas no.479-27-6] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is reused in next batch & cake is dried, pulverized a. Condensation: 1,8-DAAQ Phthalic Anhydride Condensation Sol.Orange 60 C10 H10 N2 + C 8H4O3 C18 H10 N2O + 2H 2O Mol.Wt.158 + 148 Xylene / 270 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs

1 Xylene / ODCB 1000 Finish Product 1000 2 1, 8 -DAAQ 500 Water Evaporation in Drying 1000 3 Phthalic Anhydride 530 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re -cycle for Re -Use 4180 TOTAL 9030 TOTAL 9030

159

133) Solvent Orange 63 [ cas no. 16294-75-0]: -

Bromo benzanthrone [cas no .81-96-9-.] is condensed with 2-AminoThiophene [cas no.137- 07-5] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: Bromobenzonthrone 2- Condensation Sol.Orange 63 AminoThiophene C23 H12 OS + NaBr + H 2O + NH 3 C17 H9BrO 0 + C 6H7NS + NaOH Mol.Wt.309 + 125 + 40 Xylene / 336 + 103 + 18 + 17 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Bromo benzanthrone 685 Water Evaporation in Drying 1000 3 2-AminoThiophene 365 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4200 TOTAL 9050 TOTAL 9050

160 134) Solvent Orange 105 cas no. 31482-56-1: -

Manufacturing Process: -

Para Nitro Aniline [ cas no.100-101-6] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Coupler M-8 [ cas no.148-87-8]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed a. Diazotization of PNA

PNA Diazotization PNA Diazo C6H6N2O2 + 2HCI + NaNO 2 C6H4CIN 3O2 + NaCI + 2 H 2O Mol.Wt.138 + 73 + 69 185.5 + 58.5 + 36 b. Coupling with M-8

PNA Diazo+ M-8 +C.S. Flacks Coupling Solvent Orange 105 C6H4CIN 3O2 + C 11 H14 N2 +NaOH C17 H17 N2O2 + H 2O + NaCI Mol.Wt. 185.5 + 174 + 40 323 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Recycled Water 3000 Effluent to ETP 2080 2 ICE 2000 Washing water for Re -Use 3000 3 PNA 560 Water Evaporation in Drying 3000 4 HCI 475 Finish Product 1000 5 Sodium Nitrite 205 6 M-8 435 7 C.S. Flacks 200 8 Calcium Chloride 205 9 Fresh Water for Washing 2000 TOTAL 9080 TOTAL 9080

161 Blue Solvent 4 Quantity per Month = Dyes

135) Solvent Blue 35 [ cas no. 17354-14-2]: -

Manufacturing Process: -

Quinizarine [cas no .91-63-4] is condensed with 2 moles of N-Butyl Amine [NBA cas No.109- 73-9] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is reused in next batch & cake is dried, pulverized a. Condensation: Quinizarine N-Butyl Amine Condensation Sol.Blue 35 C14 H8O4 +2 [C 4H11 N] C22 H26 N2O2 +2 H 2O Mol.Wt.240 + 2 x 73 Xylene / 350 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Quinizarine 685 Water Evaporation in Drying 1000 3 N-Butyl Amine 438 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re -cycle for Re -Use 4273 TOTAL 9123 TOTAL 9123

162

136) Solvent Blue 36[ cas no. 14233-37-5]: -

Manufacturing Process: -

Quinizarine [cas no .91-63-4.] is condensed with 2 moles of 2-Propan Amine [NBA cas No.75- 31-0] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is reused in next batch & cake is dried, pulverized a. Condensation: Quinizarine 2-propane amine Condensation Sol.Blue 36 C14 H8O4 +2 [C 3H9N] C20 H22 N2O2 +2 H 2O Mol.Wt.240 + 2 x 59 Xylene / 322 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Quinizarine 688 Water Evaporation in Drying 1000 3 2-propane Amine 448 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4286 TOTAL 9136 TOTAL 9136

163

137) Solvent Blue 97[ cas no. 61969-44-6 ]: -

Manufacturing Process: -

Quinizarine [cas no .91-63-4.] is condensed with 2 moles of Diethyl M-Toluidine [DEMT cas No.24544-08-9] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: Quinizarine DEMT Condensation Sol.Blue 97 C14 H8O4 +2 [C 11 H17N] C36 H38 N2O2 +2 H 2O Mol.Wt.240 + 2 x 163 Xylene / 530 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Quinizarine 590 Water Evaporation in Drying 1000 3 Ortho Toluidine 432 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4172 TOTAL 9022 TOTAL 9022

164

138) Solvent Blue 101[ cas no. 6737-68-8 ]: -

Manufacturing Process: -

Quinizarine [cas no .91-63-4.] is condensed with 2 moles of Ortho Toluidine [OT cas No.95-53- 4] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized

a. Condensation: Quinizarine Ortho Toluidine Condensation Sol.Blue 101 C14 H8O4 +2 [C 7H9N] C28 H22 N2O2 +2 H 2O Mol.Wt.240 + 2 x 107 Xylene / 418 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

165

139) Solvent Blue 102[ cas no. 15403-56-2 ]: -

Manufacturing Process: -

Quinizarine [cas no .82-44-0.] is condensed with 1mole of propane 2-amine [OT cas No.95- 53-4]& Methane amine [cas no.74-89-5] each respectively in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: Quinizarine Propane amine Methane Condensation Sol.Blue 102 amine C18 H18 N2O2 +2 H 2O C14 H8O4 +C 7H9N + CH 5N Mol.Wt.240 + 107 + 31 Xylene / ODCB 294 + 36

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Quinizarine 790 Water Evaporation in Drying 1000 3 Propane Amine 212 Xylene / ODCB Recovery for recycled 950 4 Methane Amine 110 Methanol Recovery for recycled 1900 5 Methanol 2000 Washing water Re -cycle for Re -Use 4262 6 Water for washing 5000 TOTAL 9112 TOTAL 9112

166

140) Solvent Blue 104 [ cas no. 116-75-6 ]: -

Manufacturing Process: -

Quinizarine [cas no .91-63-4.] is condensed with 2 moles of Mesidine [cas No.88-05-1] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: Quinizarine Mesidine Condensation Sol.Blue 104 C14 H8O4 +2 [C 9H13 N] C32 H30 N2O2 +2 H 2O Mol.Wt.240 2 x 135 Xylene / ODCB 474 36

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Quinizarine 526 Water Evaporation in Drying 1000 3 Propane Amine 568 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Washing water Re -cycle for Re -Use 4244 5 Water for washing 5000 TOTAL 9094 TOTAL 9094

167

5 Violet Solvent Dyes Quantity per Month =

141) Solvent Violet 13 [ cas no. 81-88-1]: -

Manufacturing Process: -

Quinzarine [cas no .91-63-4.] is condensed with P-Toluidine [cas No.106-49-0] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: Quinzarine P-Toluidine Condensation Sol.Violet 13 C14 H8O4 + C 7H9N C21 H15 NO 3 + H 2O Mol.Wt.240 + 107 Xylene / 329 + 18 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Quinzarine 755 Water Evaporation in Drying 1000 3 P-Toluidine 355 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4260 TOTAL 9110 TOTAL 9110

168

142) Solvent Violet 14 [ cas no. 67577-84-8]: -

1,8-Dichloro Anthraquinone [1,8-DCAQ cas no .82-46-2.] is condensed with 2 moles of P- Toluidine [cas No.106-49-0] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: 1,8-DCAQ P-Toluidine Condensation Sol.Violet 14 C14 H6CI 2O2 +2 [C 7H9N ] + 2KOH C28 H22 N2O2 + 2KCI +2 H 2O Mol.Wt.277 + 2 x 107 + 2 x 56 Xylene / 418 + 149 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 1,8-DCAQ 725 Water Evaporation in Drying 1000 3 P-Toluidine 315 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4190 TOTAL 9040 TOTAL 9040

169

143) Solvent Violet 38 [ cas no. 63512-14-1]: -

Manufacturing Process: -

Quinizarine [cas no .91-63-4.] is condensed with 2 moles of 2,6-Dibromo P-Toluidine [2,6- DBPT cas No.6968-24-7] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: Quinizarine + 2,6-DBPT Condensation Sol.Violet 14 C14 H8O4 +2 [C 7H7Br 2N ] C28 H18 Br 4N2O2 +2 H 2O Mol.Wt.240 + 2 x 265 Xylene / 734 + 36 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Quinizarine 475 Water Evaporation in Drying 1000 3 2,6 -DBPT 538 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4163 TOTAL 9013 TOTAL 9013

170

144) Solvent Violet 59 [ cas no. 6408-72-6-]: -

Manufacturing Process: -

2,3-Dichloro-1,4-Diamino Anthraquinone [DCDA cas no .81-42-5.] is condensed with 2 moles of Phenol [cas No.] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized

a. Condensation: DCDA Phenol Condensation Sol.Violet 59 C14 H8CI 2N2O4 +2 [C 6H6O ] + 2 KOH C26 H18 N2O2 +2 H 2O + 2 KCI Mol.Wt.307 + 2 x 94 + 2 x Xylene / 422 + 36 + 2 x 74.5 56 ODCB

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 DCDA 765 Water Evaporation in Drying 1000 3 Phenol 247 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Methanol Recovery for recycled 1900 5 Water for washing 5000 Washing water Re-cycle for Re-Use 4162 TOTAL 9012 TOTAL 9012

171 6 Green Solvent Dyes Quantity per Month =

145) Solvent Green 3[ cas no. 128-80-3 ]: -

Manufacturing Process: -

Quinizarine [cas no .91-63-4.] is condensed with 2 moles of P-Toluidine [PT cas No.106-49-0] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: Quinizarine PT Condensation Sol.Green 3 C14 H8O4 +2 [C 18 H31 N] C28 H22 N2O2 +2 H 2O Mol.Wt.240 + 2 x 107 Xylene / ODCB 418 + 36

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Quinizarine 666 Water Evaporation i n Drying 1000 3 PT 346 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Washing water Re-cycle for Re-Use 4262 5 Water for washing 5000 TOTAL 9012 TOTAL 9012

172

146) Solvent Green 28:[ CAS NO.: 71839-01-5] -

Manufacturing Process: -

In clean reaction charge ODCB, 1,4-dichloro-5,8-dihydroxyanthracene-9,10-dione and 4- butylaniline. Heat the reaction mass to 160 temp. and maintain for 18 hrs. cool the reaction mass to room temp and add methanol for isolation. Filter the reaction mass and wash with water. Dry the wet cake and pulverize and sent for packing.

Chemical Reaction:

1,4-dichloro-5,8-dihydroxyanthracene- Condensate Solvent Green 28 9,10-dione + 4-butylaniline C14H6Cl2O4 + (2 x C10H15N) C34H34N2O4 + 2HCL Mol.Wt. 309 + (2x149 ) 534 + 73

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Output Qty.in Kgs Kgs 1 ODCB 1500 Finished Product 1000 2 1,4-dichloro-5,8- 680 ODCB Recovery 1350 dihydroxyanthracene-9,10-dione 3 4-bu tylaniline 327 Methanol Recovery 1350 4 Methanol 1500 Aqueous ML 1607 5 Water for Washing 2800 Drying Loss 1500 TOTAL 6807 TOTAL 6807

173 147) Solvent Green 33[ cas no. 10671-57-8 ]: -

Manufacturing Process: -

Quinizarine [cas no .91-63-4.] is condensed with 2 moles of Do Decyl Aniline [DDA cas No.104-42-7] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hsot water. Washing water is re-used in next batch & cake is dried, pulverized a. Condensation: Quinizarine DDA Condensation Sol.Green 33 C14 H8O4 +2 [C 18 H31 N] C50 H66 N2O2 +2 H 2O Mol.Wt.240 + 2 x 261 Xylene / ODCB 726 + 36

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs 1 Xylene / ODCB 1000 Finish Product 1000 2 Quinizarine 516 Water Evaporation in Drying 1000 3 DDA 568 Xylene / ODCB Recovery for recycled 950 4 Methanol 2000 Washing water Re -cycle for Re -Use 4234 5 Water for washing 5000 TOTAL 9084 TOTAL 9084

174 Annexure : IV :-

FACILITIES FOR STORAGE OF RAW MATERIAL

RAW MATERIAL STORAGE AND HANDLING

Raw Materials are received in drums, carboys, bags, tankers. All Storage tanks of Hazardous flammable substances are located within premises in separate storage area and stored with all precautionary process instrumentation and safety appliances. Large area is covered by well- designed ware house which contain Store office, raw material store, finished products store etc. The personnel protective equipments like Hand gloves, Safety Shoes, goggles,, clothing etc. are provided to those handling hazardous chemicals as per requirement.

LIST OF RAW MATERIALS :-

Consumption Sr.No. Raw Material CAS No. (MT/MT) Category - A : Pigments :- Group - 1 : Pigment Red 1 Pigment Red 2 :- 2.5 DCA 0.390 95-82-9 HCI 0.385 7647-01-0 Sodium Nitrite 0.170 7632-00-0 Naphthol AS 0.610 92-77-3 C.S. Flacks 0.200 1310-73-2

2 Pigment Red 3 Red G Base 0.525 89-62-3 HCI 0.385 7647-01-0 Sodium Nitrite 0.195 7632-00-0 B-Naphthol 0.490 135-19-3 C.S. Flacks 0.200 1310-73-2

3 Pigment Red 4 OCPNA 0.550 121-87-9 HCI 0.385 7647-01-0 Sodium Nitrite 0.200 7632-00-0 B-Naphthol 0.445 135-19-3 C.S. Flacks 0.200 1310-73-2

4 Pigment Red 5 Fast Red ITR 0.450 6410-41-9 HCI 0.385 7647-01-0 Sodium Nitrite 0.130 7632-00-0 Naphthol ASITR 0.555 92-72-8

175 C.S. Flacks 0.200 1310-73-2

5 Pigment Red 12 PNPT 0.360 99-52-5 HCI 0.385 7647-01-0 Sodium Nitrite 0.160 7632-00-0 Naphthol ASD 0.680 135-61-5 C.S. Flacks 0.200 1310-73-2

6 Pigment Red 14 PCONA 0.405 89-63-4 HCI 0.385 7647-01-0 Sodium Nitrite 0.150 7632-00-0 Naphthol ASD 0.610 135-61-5 C.S. Flacks 0.200 1310-73-2

7 Pigment Red 38 3,3-DCB 0.350 91-94-1 HCI 0.415 7647-01-0 Sodium Nitrite 0.190 7632-00-0 PCEP 0.640 99-33-8 C.S.Flacks 0.200 1310-73-2

8 Pigment Red 48:1 2B Acid 0.550 88-51-7 HCI 0.475 7647-01-0 Sodium Nitrite 0.170 7632-00-0 BON Acid 0.468 92-70-6 C.S.Flacks 0.200 1310-73-2 Barium Chloride 0.200 10361-37-2

9 Pigment Red 48:2 2B Acid 0.550 88-51-7 HCI 0.475 7647-01-0 Sodium Nitrite 0.170 7632-00-0 BON Acid 0.468 92-70-6 C.S.Flacks 0.200 1310-73-2 Calcium Chloride 0.250 10043-52-4

10 Pigment Red 48:3 2B Acid 0.550 88-51-7 HCI 0.475 7647-01-0 Sodium Nitrite 0.170 7632-00-0 BON Acid 0.468 92-70-6

176 C.S.Flacks 0.200 1310-73-2 Strontium Chloride 0.240 10042-76-9

11 Pigment Red 48:4 2B Acid 0.550 88-51-7 HCI 0.475 7647-01-0 Sodium Nitrite 0.170 7632-00-0 BON Acid 0.468 92-70-6 C.S.Flacks 0.200 1310-73-2 Manganese Chloride 0.245 7773-01-5

12 Pigment Red 48:5 2B Acid 0.550 88-51-7 HCI 0.475 7647-01-0 Sodium Nitrite 0.170 7632-00-0 BON Acid 0.468 92-70-6 C.S.Flacks 0.200 1310-73-2 Magnesium Chloride 0.245 7791-18-6

13 Pigment Red 49 Tobias A cid 0.600 81-16-3 HCI 0.475 7647-01-0 Sodium Nitrite 0.185 7632-00-0 B-Naphthol 0.395 135-19-3 C.S.Flacks 0.200 1310-73-2 Sodium Hydroxide 0.245 1310-73-2

14 Pigment Red 49:1 Tobias Acid 0.600 81-16-3 HCI 0.475 7647-01-0 Sodium Nitrite 0.185 7632-00-0 B-Naphthol 0.395 135-19-3 C.S.Flacks 0.200 1310-73-2 Barium chloride 0.245 10361-37-2

15 Pigment Red 49:2 Tobias Acid 0.600 81-16-3 HCI 0.475 7647-01-0 Sodium Nitrite 0.185 7632-00-0 B-Na phthol 0.395 135-19-3 C.S.Flacks 0.200 1310-73-2 Calcium Chloride 0.208 10043-52-4

16 Pigment Red 49:3

177 Tobias Acid 0.598 81-16-3 HCI 0.405 7647-01-0 Sodium Nitrite 0.185 7632-00-0 B-Naphthol 0.390 135-19-3 C.S. Flacks 0.2 00 1310-73-2 Strontium Chloride 0.208 10042-76-9

17 Pigment Red 52:1 C Acid 0.550 88-53-9 HCI 0.475 7647-01-0 Sodium Nitrite 0.205 7632-00-0 BON Acid 0.455 92-70-6 C.S. Flacks 0.200 1310-73-2 Calcium Chloride 0.205 10043-52-4

18 Pigment Red 52:2 C Acid 0.550 88-53-9 HCI 0.475 7647-01-0 Sodium Nitrite 0.205 7632-00-0 BON Acid 0.455 92-70-6 C.S. Flacks 0.200 1310-73-2 Manganese Chloride 0.215 7773-01-5

19 Pigment Red 53 C- Aci d 0.560 88-53-9 HCI 0.475 7647-01-0 Sodium Nitrite 0.205 7632-00-0 B-Naphthol 0.435 135-19-3 C.S. Flacks 0.200 1310-73-2 Sodium Hydroxide 0.245 1310-73-2

20 Pigment Red 53:1 C-Acid 0.560 88-53-9 HCI 0.475 7647-01-0 Sod ium Nitrite 0.205 7632-00-0 B-Naphthol 0.435 135-19-3 C.S. Flacks 0.200 1310-73-2 Barium Chloride 0.245 10361-37-2

21 Pigment Red 53:3 C Acid 0.598 88-53-9 HCI 0.405 7647-01-0 Sodium Nitrite 0.185 7632-00-0 B-Naphthol 0.3 90 135-19-3

178 C.S. Flacks 0.200 1310-73-2 Strontium Chloride 0.208 10042-76-9

22 Pigment Red 57:1 4B Acid 0.530 88-44-8 HCI 0.475 7647-01-0 Sodium Nitrite 0.205 7632-00-0 BON Acid 0.475 92-70-6 C.S. Flacks 0.200 1310-73-2 Calcium Chloride 0.205 10043-52-4

23 Pigment Red 63:1 Tobias Acid 0.530 81-16-3 HCI 0.475 7647-01-0 Sodium Nitrite 0.205 7632-00-0 BON Acid 0.475 92-70-6 C.S. Flacks 0.200 1310-73-2 Calcium Chloride 0.205 10043-52-4

24 Pigment Red 63:2 Tobias Acid 0.530 81-16-3 HCI 0.405 7647-01-0 Sodium Nitrite 0.200 7632-00-0 BON Acid 0.475 92-70-6 C.S. Flacks 0.200 1310-73-2 Manganese Chloride 0.205 7773-01-5

25 Pigment Red 81 EAMP 0.600 120-37-6 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 Phosphomolybdic acid [ PMA] 0.100 12026-57-2

26 Pigment Red 81:1 EAMP 0.600 120-37-6 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 Silicotungstomolyb dic [SMT ] acid 0.100 867-44-7

27 Pigment Red 81:x EAMP 0.600 120-37-6 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 Phosphoric molybdic [PM]acid 0.100 12026-57-2

179

28 Pigment Red 81:y EAMP 0.600 120-37-6 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 Silicomolybdic [SM]acid 0.100 11089-20-6

29 Pigment Red 81:2 EAMP 0.600 120-37-6 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 Silicomolybdic [SM]acid 0.100 11089-20-6

30 Pigment Red 81:3 EAMP 0.600 120-37-6 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 Phosphoric molybdic [PM]acid 0.080 12026-57-2

31 Pigment Red 81:4 EAMP 0.600 120-37-6 Phthalic Anhydrid e 0.515 85-44-9 Ethanol 1.000 64-17-5 Phosphotungstomolybdic [PTMA] acid 0.080 1325-80-0

32 Pigment Red 112 TCA 0.410 636-30-6 HCI 0.395 7647-01-0 Sodium Nitrite 0.150 7632-00-0 Naphthol ASD 0.575 135-61-5 C.S. Flacks 0. 200 1310-73-2

33 Pigment Red 122 Methanol 5.500 67-56-1 Dimethyl Succinosuccinate 0.800 6289-46-9 p-Toluidine 0.880 106-49-0 Resist Salt 0.300 127-68-4 NaOH 0.275 1310-73-2 HCL 0.250 7647-01-0 Poly Phosphoric Acid 1.800 8017-16-1 DMF / IBA 7.000 68-12-2

34 Pigment Red 123 PTCDA 0.650 128-69-8

180 3,5 -DMA 0.395 108-69-0 Pipyridine 0.010 110-86-1

35 Pigment Red 144 DCA 0.490 92-82-9 HCI 0.395 7647-01-0 Sodium Nitrite 0.190 7632-00-0 3-H,2 -Naphthoyl Chloride 0.500 2243-83-6 C.S. Flacks 0.250 1310-73-2 DABC 0.180 280-57-9

36 Pigment Red 146 Fast Red KD Base 0.400 120-35-4 HCI 0.395 7647-01-0 Sodium Nitrite 0.150 7632-00-0 Naphthol AS LC 0.595 137-92-1 C.S. Flacks 0.200 1310-73-2

37 Pigment Red 168 Anthanthrone 0.800 641-13-4 Liquid Bromine 0.205 7726-95-6

38 Pigment Red 169 EAMP 0.600 120-37-6 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 ferrous iron copper cyanide complex 0.080 544-92-3

39 Pigment Red 170 p-Aminobenzamide 0.305 2835-68-9 HCI 0.405 7647-01-0 Sodium Nitrite 0.160 7632-00-0 Naphthol AS PH 0.688 92-74-0 C.S. Flacks 0.200 1310-73-2

40 Pigment Red 175 Methyl-2-aminobenzoate 0.325 134-20-3 HCI 0.405 7647-01-0 Sodium Nitrite 0.154 7632-00-0 DHNFBZ 0.665 26848-40-8 C.S. Flacks 0.200 1310-73-2

41 Pigment Red 176 Fast Red KD Base 0.445 120-35-4

181 HCI 0.405 7647-01-0 Sodium Nitrite 0.162 7632-00-0 DHNFBZ 0.565 26848-40-8 C.S. Flacks 0.200 1310-73-2

42 Pigment Red 177 Poly Propylene Glycol 2.500 25322-69-4 Bromamine Acid 1.100 116-81-4 KOH 0.250 1310-58-3 Sodium Chlorate 0.050 7775-09-9

43 Pigment Red 178 PTCDA 0.650 128-69-8 PAAB 0.515 60-09-3 Pipyridine 0.010 110-86-1

44 Pigment Red 179 PTCDA 0.950 128-69-8 MMA 0.150 74-89-5 Pipyridine 0.050 110-86-1 Acetic Acid 0.055 64-19-7

45 Pigment Red 188 OPLA 0.555 59673-82-4 HCI 0.435 7647-01-0 Sodium Nitrite 0.135 7632-00-0 Naphthol ASOS 0.445 135-62-6 C.S. Flacks 0.200 1310-73-2

46 Pigment Red 202 Methanol 5.500 67-56-1 Dimethyl Succinos uccinate 0.780 787-07-5 4-Chloroaniline 0.860 106-47-8 Resist Salt 0.300 127-68-4 NaOH 0.275 1310-73-2 HCL 0.250 7647-01-0 Poly Phosphoric Acid 1.800 8017-16-1 DMF / IBA 7.000 68-12-2

47 Pigment Red 254 Tetra Amyl alcoho l 3.800 75-85-4 PCBN 0.810 623-03-0 KOH 0.180 1310-58-3 DIPS 0.411 924-88-9

182

48 Pigment Red 256 ADCDMBSA 0.518 26175-68-8 HCI 0.405 7647-01-0 Sodium Nitrite 0.130 7632-00-0 Naphthol ASOL 0.492 135-62-6

49 Pigment Red 264 Tetra Amyl alcohol 3.800 75-85-4 PPBN 0.835 2920-38-9 KOH 0.180 1310-58-3 DIPS 0.425 924-88-6

Group - 2 : Pigment Yellow 50 Pigment Yellow 1 MNPT 0.450 89-62-3 HCI 0.475 7647-01-0 Sodium Nitrite 0. 190 7632-00-0 Acetoacetanilide 0.510 102-01-2

51 Pigment Yellow 3 PCONA 0.410 89-63-4 HCI 0.435 7647-01-0 Sodium Nitrite 0.187 7632-00-0 AAOCA 0.510 93-70-9 C.S.Flacks 0.200 1310-73-2

52 Pigment Yellow 12 3, 3-DCB 0.264 91-94-4 HCI 0.500 7647-01-0 Sodium Nitrite 0.200 7632-00-0 AAA 0.730 102-01-2 C.S. Flacks 0.190 1310-73-2

53 Pigment Yellow 13 3,3 -DCB 0.340 91-94-4 HCI 0.435 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AAMX 0.715 97-36-9 C.S.Flacks 0.200 1310-73-2

54 Pigment Yellow 14 3,3 -DCB 0.340 91-94-4

183 HCI 0.435 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AAOT 0.715 93-68-5 C.S.Flacks 0.200 1310-73-2

55 Pigment Yellow 16 2,4-DCA 0.650 554-00-7 HCI 0.675 7647-01-0 Sodium Nitrite 0.270 7632-00-0 Naphthol ASIRG 0.425 4433-79-8 C.S.Flacks 0.200 1310-73-2 56 Pigment Yellow 17 3,3-DCB 0.380 91-94-4 HCI 0.485 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AAOA 0. 625 92-15-9 C.S.Flacks 0.200 1310-73-2

57 Pigment Yellow 61 ONAPSA 0.450 616-84-2 HCI 0.475 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AAA 0.510 102-01-2 C.S.Flacks 0.200 1310-73-2 Calcium Chloride 0.135 10043-52-4

58 Pigment Yellow 62 ONAPSA 0.450 616-84-2 HCI 0.475 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AAOT 0.500 93-68-5 C.S.Flacks 0.200 1310-73-2 Calcium Chloride 0.135 10043-52-4

59 Pigment Yellow 63 3,3-DCB 0.390 91-94-4 HCI 0.485 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AAOCA 0.685 93-70-9 C.S.Flacks 0.200 1310-73-2

60 Pigment Yellow 65 MNPA 0.440 96-96-8 HCI 0.475 7647-01-0

184 Sodium Nitrite 0.190 7632-00-0 AAOA 0.510 92-15-9 C.S.Flacks 0.200 1310-73-2 Calcium Chloride 0.135 10043-52-4

61 Pigment Yellow 73 PCONA 0.450 89-63-4 HCI 0.475 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AAOA 0.510 95-15-9 C.S.Flacks 0.200 1310-73-2 Calcium Chloride 0.135 10043-52-4

62 Pigment Yellow 74 MNOA 0.465 97-52-9 HCI 0.475 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AAOA 0.515 95-15-9 C.S.Flacks 0.200 1310-73-2 Calcium Chloride 0.135 10043-52-4

63 Pigment Yellow 83 3,3 -DCB 0.390 91-94-4 HCI 0.485 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AADMCA 0.685 4433-79-8 C.S.Flacks 0.200 1310-73-2

64 Pigment Yellow 93 OAPC 0.620 59158-04-2 HCI 0.575 7647-01-0 Sodium Nitrite 0.200 7632-00-0 NN -CMBT 0.340 39098-85-6 C.S. Flacks 0.335 1310-73-2

65 Pigment Yellow 97 DMASA 0.470 52298-44-9 HCI 0.475 7647-01-0 Sodium Nitrite 0.190 7632-00-0 NAPTHOL AS -IRG 0.515 4433-79-8 C.S.Flacks 0.200 1310-73-2 Calcium Chloride 0.135 10043-52-4

66 Pigment Yellow 101

185 2-hydroxynaphthalene -1-carbaldehyde 1.052 708-06-5 Dihydrazine 0.090 301-01-2 Methanol 4.000 67-56-1

67 Pigment Yellow 120 5-AIPA -DME 0.490 99-27-4 HCI 0.475 7647-01-0 Sodium Nit rite 0.190 7632-00-0 AABI 0.510 26576-46-5 C.S. Flacks 0.220 1310-73-2 Aluminum Hydroxide 0.135 21645-51-2

68 Pigment Yellow 121 3,3 -DCB 0.390 91-94-4 HCI 0.485 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AAMX 0.625 97-36-9 C.S. Flacks 0.200 1310-73-2

69 Pigment Yellow 138 ODCB / Xylene 3.000 95-50-1 Tetrachloro Phthalic Anhydride 0.750 117-08-8 8-amino Quinaldine 0.275 18978-78-4 Benzoic Acid 0.030 65-85-0 Methanol 1.000 67-56-1

70 Pigment Yellow 139 Phthalonitrile 0.350 91-15-6 Barbituric acid 0.700 67-52-7 HCL 0.175 7647-01-0

71 Pigment Yellow 151` Anthranillic Acid 0.490 118-92-3 HCI 0.375 7647-01-0 Sodium Nitrite 0.180 7632-00-0 AABI 0.510 26576-46-5 C.S. Flacks 0.220 1310-73-2 Aluminum Hydroxide 0.135 21645-51-2

72 Pigment Yellow 153 2,3 -Dinitroso -n-phenylbutanamide 0.775 N.A. C.S. Flacks 0.200 1310-73-2 Nickel Chloride 0.200 7718-54-9

186 73 Pigment Yellow 154 ATFT 0.490 88-17-5 HCI 0.375 7647-01-0 Sodium Nitrite 0.180 7632-00-0 AABI 0.510 26576-46-5 C.S. Flacks 0.220 1310-73-2 Aluminum Hydroxide 0.135 21645-51-2

74 Pigment Yellow 155 ADMT 0.615 5372-81-6 HCI 0.515 7647-01-0 Sodium Nitrite 0.220 7632-00-0 DAPDAB 0.400 25731-73-5 C.S. Flacks 0.240 1310-73-2

75 Pigment Yellow 174 Pigment yellow 13 0.500 5102-83-0 ICE Pigment Yellow 14 0.500 5468-75-5

76 Pigment Yellow 180 2-EDDA 0.380 52411-34-4 HCI 0.485 7647-01-0 Sodium Nitrite 0.205 7632-00-0 AABI 0.600 26576-46-5 C.S.Flacks 0.200 1310-73-2

77 Pigment Yellow 181 PABB 0.490 74441-06-8 HCI 0.475 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AABI 0.510 26576-46-5 C.S. Flacks 0.220 1310-73-2 Aluminum Hydroxide 0.135 21645-51-2

78 Pigment Yellow 182 ADMT 0.490 27210-70-4 HCI 0.475 7647-01-0 Sodium Nitrite 0.190 7632-00-0 AAMAQ 0.510 N.A. C.S. Flacks 0.220 1310-73-2 Aluminum Hydroxide 0.135 21645-51-2

79 Pigment Yellow 183 DCASA 0.460 6331-96-0

187 HCI 0.475 7647-01-0 Sodium Nitrite 0.190 7632-00-0 1,3 -SPMP 0.490 119-17-5 C.S.Flacks 0.200 1310-73-2 Calcium Chloride 0.140 10043-52-4

80 Pigment Yellow 191 2B Acid 0.475 88-51-7 HCI 0.275 7647-01-0 Sodium Nitrite 0.150 7632-00-0 1,3 -SPMP 0.495 119-17-5 C.S. Flacks 0.200 1310-73-2 Calcium Chloride 0.140 10043-52-4

81 Pigment Yellow 191:1 2B Acid 0.475 88-51-7 HCI 0.275 7647-01-0 Sodium Nitrite 0.150 7632-00-0 1,3 -SPMP 0.495 119-17-5 C.S. Flacks 0.200 1310-73-2 Ammonium Chloride 0.160 12125-02-9

Group - 3 : Pigment Orange 82 Pigment Orange 5 2,4 -DNA 0.518 97-02-9 HCI 0.270 7647-01-0 Sodium Nitrite 0.142 7632-00-0 Beta Naphthol 0.435 135-19-3 C.S. Flacks 0.200 1310-73-2

83 Pigment Orange 13 3,3 -DCB 0.490 91-94-4 HCI 0.385 7647-01-0 Sodium Nitrite 0.105 7632-00-0 PMP 0.510 89-25-8 C.S.Flacks 0.200 1310-73-2

84 Pigment Orange 16 ODA 0.495 119-90-4 HCI 0.385 7647-01-0 Sodium Nitrite 0.105 7632-00-0 AOA 0.500 102-01-2 C.S.Flacks 0.200 1310-73-2

188 85 Pigment Orange 34 3,3 -DCB 0.495 91-94-4 HCI 0.385 7647-01-0 Sodium Nitrite 0.105 7632-00-0 PTMP 0.518 86-92-0 C.S.Flacks 0.200 1310-73-2

86 Pigment Orange 36 PCONA 0.505 89-63-4 HCI 0.385 7647-01-0 Sodium Nitrite 0.115 7632-00-0 AABI 0.500 26576-46-5 C.S.Flacks 0.200 1310-73-2

87 Pigment Orange 43 1.4.5.8 -naphthalenetetracarboxylicacid -1,8 - 0.730 monoanhydride 128-97-2 1,2 -diaminobenzene 0.552 95-54-5

88 Pigment Orange 62 PNA 0.375 100-101-6 HCI 0.385 7647-01-0 Sodium Nitrite 0.185 7632-00-0 AABI 0.625 26576-46-5 C.S.Flacks 0.200 1310-73-2

89 Pigment Orange 64 Methyl aminolone 0.500 67014-36-2 HCI 0.385 7647-01-0 Sodium Nitrite 0.115 7632-00-0 Barbituric Acid 0.510 67-52-7 C.S.Flacks 0.200 1310-73-2

Group - 4 : Pigment Blue 90 Pigment Blue 1 KOH 0.270 1310-58-3 PTCBAD 0.780 81-33-4 PMBCI 0.250 824-94-2

91 Pigment Blue 15 NB / DCB 3.500 7440-03-1 Phthalic Anhydride 1.110 85-44-9 Urea 0.890 57-13-6 Cuprous Chloride 0.205 7758-89-6 Ammonium Molybdate 0.003 12054-85-2

189 Steam 1.800 7732-18-5 45% Spent H 2SO 4 5.800 7664-93-9

92 Pigment Blue 15:1 CPC Blue Crude 1.100 147-14-8 Sulphuric Acid 98% 5.000 7664-93-9 Ammonium Hydroxide 1.500 1336-21-6

93 Pigment Blue 15:2 CPC Blue Crude 1.100 147-14-8 Solvent 5.000 108-90-7 Surfactant 0.010 112-80-1

94 Pigment Blue 15:3 CPC Blue Crude 1.100 147-14-8 Solvent 5.000 108-90-7 Surfactant 0.010 112-80-1

95 Pigment Blue 15:4 CPC Blue Crude 1.100 147-14-8 Solvent 5.000 108-90-7 Surfactant 0.010 112-80-1 96 Pigment Blue 15:6 CPC Blue Crude 1.100 147-14-8 Solvent 5.000 108-90-7 Surfactant 0.010 112-80-1

97 Pigment Blue 16 CPC Blue Crude 0.650 147-14-8

AICI 3 0.700 7446-70-0 NaCI 0.300 7647-14-5 Chlorine Gas 0.350 772-50-5

98 Pigment Blue 60 Poly Ethylene Glycol 1.350 35322-68-3 KOH 0.270 1310-58-3 Sodium Chlorate 0.112 09-09-75 2-Amino Anthraquinone 1.020 117-79-3

99 Pigment Blue 62 KOH 0.270 1310-58-3 PTCBAD 0.790 81-33-4 BCI 0.250 100-44-7

190 Group - 5 : Pigment Violet 100 Pigment Violet 1 DEMAP 0.600 1326-03-0 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 Phosphomolybdic acid [ PMA] 0.100 12026-57-2

101 Pigment Violet 1x EAMP 0.600 120-37-6 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 Sil icomolybdic acid [ SM] 0.100 11089-20-6

102 Pigment Violet 3 DMA 0.600 121-69-7 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 Phosphomolybdic acid [ PM] 0.100 12026-57-2

103 Pigment Violet 19 Methanol 5. 500 67-56-1 Dimethyl Succinosuccinate 0.800 6289-46-9 Aniline 0.830 106-47-8 Resist Salt 0.300 127-68-4 NaOH 0.275 1310-73-2 HCL 0.250 7647-01-0 Poly Phosphoric Acid 1.800 8017-16-1 DMF / IBA 7.000 68-12-2

104 Pigment Violet 23 Mono Chloro Benzene 1.000 108-90-7 Carbazole 0.800 86-74-8 Di Ethyl Sulphate 0.470 64-67-5 NaOH Flacks 0.500 1310-73-2 Nitric Acid 45% 0.600 7697-37-2 Hydrogen Gas 0.008 1333-74-0 Ortho Dichloro Benzene 10.000 95-50-1 Sodiu m acetate 0.050 127-09-3 Methanol 5.000 67-56-1 Raney Nickel 0.008 12635-27-7 DEG 1.000 111-46-6

105 Pigment Violet 27 Methyl Violet 0.714 8004-87-3

191 Copper Sulfate 0.159 7758-98-7 Sodium FeroCynide 0.303 13601-19-9

106 Pigment Violet 29 DMA 0.600 121-69-7 Phthalic Anhydride 0.515 85-44-9 Ethanol 1.000 64-17-5 Ferrous Iron copper cyanide [ PM] 0.100 14038-43-8

Category - B : Solvent Dyes Group - 1 : Red Solvent Dyes 107 Solvent Red 19E Garnet GB Base 0.500 97-56-3 HCI 0.400 7647-01-0 Sodium Nitrite 0.205 7632-00-0 n-ENA 0.435 2437-03-8 C.S. Flacks 0.200 1310-73-2 Calcium Chloride 0.205 10043-52-4

108 Solvent Red 23 4-(phenyldiazenyl) aniline (PAAB) 0.575 60-09-3 Sodium Nitrite 0.507 7632-00-0 Sodium Hydroxide 0.260 1310-73-2 Naphthalen-2-ol (Beta Naphthol) 0.420 135-19-3

109 Solvent Red 24 Garnet GB Base 0.600 97-56-3 HCI 0.400 7647-01-0 Sodium Nitrite 0.205 7632-00-0 Beta Naphthol 0.435 135-19-3 C.S. Flacks 0.200 1310-73-2 Calcium Chloride 0.205 10043-52-4

110 Solvent Red 52 Xylene / ODCB 1.000 95-50-1 6-BAP 0.700 81-85-6 p-Toluidine 0.310 106-49-0 Methanol 2.000 67-56-1

111 Solvent Red 111 Xylene / ODCB 1.000 95-50-1 1-Chloro AQ 0.713 82-44-0 Methane amine 0.250 74-89-5 Methanol 2.000 67-56-1

192

112 Solvent Red 135 Xylene / ODCB 1.000 95-50-1 TCAP 0.685 117-08-8 1,8-DAN 0. 350 479-27-6 Methanol 2.000 67-56-1 113 Solvent Red 151 Xylene / ODCB 1.000 95-50-1 6-BAP 0.690 81-85-6 3-Chloroaniline 0.315 108-42-9 Methanol 2.000 67-56-1

114 Solvent Red 168 Xylene / ODCB 1.000 95-50-1 1-Chloro AQ 0.713 82-44-0 Cyclo hexyl amine 0.291 108-91-8 Methanol 2.000 67-56-1

115 Solvent Red 169 Xylene / ODCB 1.000 95-50-1 1-Chloro AQ 0.805 82-44-0 2-propanolamine 0.205 175-31-0 Methanol 2.000 67-56-1

116 Solvent Red 179 Xylene / ODCB 1.000 95-50-1 1,8-DAN 0.445 479-27-6 1,8-Naphthalic Anhydride 0.560 81-84-5 Methanol 2.000 67-56-1

117 Solvent Red 197 Xylene / ODCB 1.000 95-50-1 DEAMAP Aldehyde 0.5 25 17754-90-4 2-A,2,3-DHHBMMP 0.590 6301-29-7 Methanol 2.000 67-56-1

118 Solvent Red 207 Xylene / ODCB 1.000 95-50-1 1,8-DCAQ 0.725 82-43-9 Cyclo Hexylamine 0.295 108-91-8 Methanol 2.000 67-56-1

119 Solvent Red 227 Xylene / ODCB 1.000 95-50-1

193 1-Chloro AQ 0.795 82-44-0 Aniline 0.215 62-53-3 Methanol 2.000 67-56-1 Group - 2 : Yellow Solvent Dyes 120 Solvent Yellow 2 Aniline 0.415 62-53-3 HCL 1.000 7647-01-0 Sodium Nitrite 0.315 7632-00-0 D.M.A. 0.545 127-19-5

121 Solvent Yellow 14 Aniline 0.415 62-53-3 HCL 1.000 7647-01-0 Beta Naphthol 0.315 135-19-3 Soda Ash/ NaOH 0.200 1310-73-2

122 Solvent Yellow 18 HCL 1.290 7647-01-0 2,4 -dimethyla niline (2,4 Xylidine) 0.425 95-68-1 Sodium Nitrite 0.575 7632-00-0 sodium hydroxide 0.130 1310-73-2 5-methyl -2-phenylpyrazolidin -3-one (P.M.P.) 0.580 89-25-8

123 Solvent Yellow 33 Xylene / ODCB 1.000 95-50-1 Phthalic Anhydride 0.575 85-44-9 Quinaldine 0.500 91-63-4 Methanol 2.000 67-56-1

124 Solvent Yellow 43 Methanol 2.000 67-56-1 1-ChIoro -1,8 -Naphthaline. 0.735 4053-08-1 n-Butyl Amine 0.300 12226-96-9 C.S.Lye 0.200 1310-73-2

125 Solvent Yellow 44 Methanol 2.000 67-56-1 1-Amino -1,8 -Naphthaline. A 0.635 6492-86-0 2,5 -DMA 0.400 95-78-3

126 Solvent Yellow 72 HCL 1.300 7647-01-0 2-methoxyaniline 0.410 90-04-0 Sodium Nitrite 0.575 7632-00-0

194 Sodium hydro xide 0.130 1310-73-2 5-methyl -2-phenylpyrazolidin -3-one 0.597 89-25-8

127 Solvent Yellow 114 Xylene / ODCB 1.500 95-50-1 3-Hydroxy -2-methyl -4-quinolinecarboxylic acid 0.615 117-57-7 Phthalic Anhydride 0.410 85-44-9 Methanol 2.0 00 67-56-1

128 Solvent Yellow 131 Methanol 2.300 67-56-1 6-chloro -1H,3H -benzo[de]isochromene -1,3 -dione 0.727 4053-08-1 3-aminopropan -1-ol 0.300 156-87-6

129 Solvent Yellow 157 Xylene / ODCB 1.000 95-50-1 Tetra Chl oro Phthalic Anhydride 0.605 117-08-8 Quinaldine 0.455 91-63-4 Methanol 2.000 67-56-1

130 Solvent Yellow 163 Xylene / ODCB 1.000 95-50-1 1, 8 -Dichloro AQ 0.650 82-43-9 Thiophene 0.405 108-98-5 Methanol 2.000 67-56-1

131 Solvent Yellow 167 Xylene / ODCB 1.000 95-50-1 1-chloro AQ 0.685 82-44-0 Thiophene 0.365 108-98-5 Methanol 2.000 67-56-1

Group - 3 : Orange Solvent Dyes 132 Solvent Orange 60 Xylene / ODCB 1.000 95-50-1 1, 8-DAAQ 0.500 82-43-9 Phthalic Anhydride 0.530 85-44-9 Methanol 2.000 67-56-1

133 Solvent Orange 63 Xylene / ODCB 1.000 95-50-1 Bromo benzanthrone 0.685 81-96-9 2-AminoThiophene 0.365 137-07-5

195 Methanol 2.000 67-56-1

134 Solvent Orange 105 PNA 0.560 100-101-6 HCI 0.475 7647-01-0 Sodium Nitrite 0.205 7632-00-0 M-8 0.435 148-87-8 C.S. Flacks 0.200 1310-73-2 Calcium Chloride 0.205 10043-52-4

Group - 4 : Blue Solvent Dyes 135 Solvent Blue 35 Xylene / ODCB 1.000 95-50-1 Quinizarine 0.685 91-63-4 N-Butyl Amine 0.438 109-73-9 Methanol 2.000 67-56-1

136 Solvent Blue 36 Xylene / ODCB 1.000 95-50-1 Quinizarine 0.688 91-63-4 2-propane Amine 0.448 75-31-0 Methanol 2.000 67-56-1

137 Solvent Blue 97 Xylene / ODCB 1.000 95-50-1 Quinizarine 0.590 91-63-4 Ortho Toluidine 0.432 95-53-4 Methanol 2.000 67-56-1

138 Solvent Blue 101 Xylene / ODCB 1.000 95-50-1 Quini zarine 0.590 91-63-4 Ortho Toluidine 0.432 95-53-4 Methanol 2.000 67-56-1

139 Solvent Blue 102 Xylene / ODCB 1.000 95-50-1 Quinizarine 0.790 91-63-4 Propane Amine 0.212 95-53-4 Methane Amine 0.110 74-89-5 Methanol 2.000 67-56-1

140 Solvent Blue 104 Xylene / ODCB 1.000 95-50-1

196 Quinizarine 0.526 91-63-4 Propane Amine 0.568 95-53-4 Methanol 2.000 67-56-1

Group - 5 : Violet Solvent Dyes 141 Solvent Violet 13 Xylene / ODCB 1.000 95-50-1 Quinzarine 0.755 91-63-4 P-Toluidine 0.355 106-49-0 Methanol 2.000 67-56-1

142 Solvent Violet 14 Xylene / ODCB 1.000 95-50-1 1,8 -DCAQ 0.725 82-46-2 P-Toluidine 0.315 106-49-0 Methanol 2.000 67-56-1

143 Solvent Violet 38 Xylene / ODCB 1.000 95-50-1 Quinizarine 0.475 91-63-4 2,6 -DBPT 0.538 6968-24-7 Methanol 2.000 67-56-1

144 Solvent Violet 59 Xylene / ODCB 1.000 95-50-1 DCDA 0.765 81-42-5 Phenol 0.247 108-95-2 Met hanol 2.000 67-56-1

Group - 6 : Green Solvent Dyes 145 Solvent Green 3 Xylene / ODCB 1.000 95-50-1 Quinizarine 0.666 91-63-4 PT 0.346 106-49-0 Methanol 2.000 67-56-1

146 Solvent Green 28 ODCB 1.500 95-50-1 1,4 -dichloro -5,8 -dihydroxyanthracene -9,10 -dione 0.680 2832-30-6 4-butylaniline 0.327 104-13-2 Methanol 1.500 67-56-1

147 Solvent Green 33

197 Xylene / ODCB 1.000 95-50-1 Quinizarine 0.516 91-63-4 DDA 0.568 104-42-7 Met hanol 2.000 67-56-1

198 Annexure : V

Details of treatment of Effluent (scheme and disposal) :-

1. Industrial Effluent :-

A) Concentrated Effluent B) Dilute Effluent

Treatment of Effluent :-

A) Concentrated Effluent

a) Effluent Characteristics (Before and After Treatment ).:-

Sr.No Parameter Inlet Outlet 1 PH 6.0 -9.5 7.0 -7.5 2 COD (mg/L) 2000 -5000 80 -100 3 BOD (mg/L) 700 -900 30 -60 4 TDS(mg/L) 15000 150 -200

b) Effluent Treatment Process :-

1. Pre-Treatment Section 2. PFET (Polymeric Film Evaporation Technology) 3. MEE (3 Stage Multi effect Evaporator)

1.PRE- TREATMENT SECTION:-

Initially Concentrate Effluent Comes to an equivalisation cum collection Tank( Feed Tank to ETP process plant). from feed tank, effluent is pumped to DAF through pipe Flocculation, where Oil & Grease Will be removed. DAF outlet goes to Flash Mixer to Flocculation and to Clarifier, Where hardness will be removed by Dosing Chemicals.

Clarifier treated water goes to PEET Feed Tank and Clarifier bottom outlet goes to Sludge sump and sludge will be disposed after dewatering by filter press.

2.PEET SECTION:-

From PEET tank, effluent is pumped to PEET Vessel, where water evaporation is done at lower temperature under vacuum by passing steam for sensible heating and vapour is re- compressed by means of centrifugal fan to utilize flash vapour heat. Condensate water (pure water) is collected separately to Condensate storage tank and concentrate is collected in MEE Feed tank.

199 3.MEE SECTION:-

From MEE Feed tank, Condensate effluent feed to MEE system where water is boiled under vacuum by passing steam in three stage multi effect evaporator. TVR (Thermo Vapour Recompressor) is used to enhance the steam economy. After Super Saturation Stage, salt is precipitated in Flash vessel, which will be removed in basket Centrifuge at 15% Moisture and mother Liquor again recirculated in 3 rd effect. Condensate water will be collected in Condensate storage tank (pure water).

B) Dilute Effluent :-

Dilute Effluent From Washing & Boiler Blow Down comes to another collection cum equivalisation tank (Feed Tank to RO) where effluent passess through RO and Consentrated Stream gose to MEE and permeate stream gose for recycle in the plant.

2. Domestic Effluent :-

Domestic Ffluent will be disposed through Septic Tank & Soakpit arrangement.

200

ETP Flow Diagram :-

201

Annexure : VI

Detail of Hazardous Waste Generation & Disposal :

Sr. Type/Name of Source of Category and Quantity Disposal Method no. Hazardous generation Schedule as per (MT/Month) waste HW Rules. 1. ETP Dry Sludge ETP Sch -I/ 15 MT/Month Collection, Storage, Transportation 35.3 & Disposal to TSDF Site 2. Used Oils Machineries Sch -I/ 50 Lts /Months Collection, Storage, Transportation & 5.1 & Sale out to Registered refineries Equipment 3. Discarded Raw Sch -I/ 12000Nos./Month Collection, Storage, Transportation Bags, Materila 33.1 & Used for in-house packing of Containers & storage some intermediates & ETP wastes, Drums & return back to Raw Material suppliers for same products 4. MEE Salt ETP Sch -I/ 75 MT/Month Collection, Storage, Transport and 33.1 send to common TSDF Site for Disposal or Sale to actual user having Rule 9 Permission 5 Spent Acid Process Sch -I/ 100 MT/ Month 26.3 3 HCL Process Sch -2/ 800 MT/Month Collection, Storage, Transportation [Hydrochloric Class C15 & Reuse in own premises in Acid] manufacturing process / Sale to 4 Ammonium Pro cess Sch -2/ 300 actual user having Rule 9 Carbonate -- Permission 5 Sodium Hypo Process Sch -2/ 320 chloride -- 6 Fly Ash from -- -- 120 MT /Month Collection, Storage, Transportation Boiler and sent to brick manufactuere. 7 Spent Solvents Process 26.4/sch -I 8 MT/Month Collection, Storage, Transpor tation & Reuse in own premises in manufacturing process / Sale to actual user having Rule 9 Permission

202 Annexure : VII

Water (Expected Source & Completing users) Unit : KLD

1. Water Source : Ground Water

2. Quantity of Water Required :-

Sr.No. Stream Fresh Water Recycled Water Total Water in KLD in KLD in KLD (A) Domestic 8 0 8 (B) Garderning 8 0 8 (C) Industrial 108 269 377 Total 124 269 393

Details of Water Consumtion, Waste Water generation and treatment :-

3. Water Balance :- Water Consumption & wastewater generation:-

SR. WATER CONSUMPTION WASTE WATER GENERATION PURPOSE NO. (KL/Day) (KL/Day) (A) Domestic 8 6 (B) Gardening 8 0

(C) Industrial Process 200 151 Scrubbing 1 1 Washing 120 117 Boiler 40 4 Cooling T ower 16 2 Total (C) 377 275 TOTAL (A+B+C) 393 281

*Out of Total 393 KLD Water Consumption: 1. Fresh water will be 124 KLD (Domestic 8KLD + Gardernining 8KLD + Industrial 108KLD) 2. Recycled Water will be 269 KLD (Total Industrial Only)

Domestic Sewage It is disposed off through septic/soak pit tank.

Industrial There shall be no wastewater discharge, treated waste water will be re-use Effluent back, & thereby will be achieved Zero Liquid discharge

203

Water consumption, Waste Water generation and Treatment Diagram :-

204

ANNEXURE-VIII DETAILS OF STACK AND VENTS

Stack Quantity Quantity Type of Air Pollution C ontrol Sr. Source of emission Type of Height in No. of Fuel emissions i.e. Measures No. With Capacity Fuel (meter) MT/Day Air Pollutants (APCM) 4 320 Hot Air Gen. 1 32 Mtrs (U2-8) PNG Cu.mt./ Adequate stack height (200000 kcal) Hrs 1 Adequate stack Multi Steam Boiler Briquette 2000kg / cyclone separator 2 5 Ton/hr. 32 Mtrs / Coal Hrs Dust Collector

PM & Bag filter

1 SO 2 Adequate stack Multi NOx cyclone separator Thermopack Boiler 2000 3 30 Mtrs Briquites Dust Collector (200000 kcal) Kgs/ Hr. & Bag filter

DG Set 2 100 4 250 KVA × 2 Nos. 11 Mtrs HSD Adequate stack height Lit/hr (Stand By) 6 480 Spin Flash Dryer Close 5 PNG Cu.mt./ No N.A. (Close Loop) Loop Hrs 2 160 Water Immerserd 6 Spray Dryer 15 Mtr. PNG Cu.mt./ No Cyclone separator for Hrs Dust Collector

205

ANNEXURE-IX STORAGE AND HANDLING OF HAZARDOUS CHEMICALS

Quantity Actually Name of Max. stored No. of Places of State & Sr. Control Messures Hazardous That (Including Storages its Type of No. Provided Chemical can be in Process Tank Storage Hazard stored & Handling) • Closed handling and Tank Liquid & traffereing Systems for 1 HCL (30%) 500MT 300MT 10 Tank Farm Corrosive Hazardous Chemicals. Area • Dyke wall and material Storage Liquid & collection systems are 2 H2SO4 20MT 10MT 1 Tank Area Corrosive provided to all material storage Tank Liquid & tank/s. 3 Acetic Acid 500MT 250MT 10 Tank Farm Corrosive • Fire Extiguishers and Area absorbents will be Tank available near Storage Liquid & 4 Nitic Acide 50 MT 10MT 1 Tank Farm tanks and storage area Corrosive Area

PRECAUTION DURING STORAGE , TRANSPORTATION AND HANDLING OF HAZARDOUS CHEMICALS :-

1. Liquids :-

• Always use the road tankers having authorization for transporting the said material. • Vendor asks to provide MSDS to tanker driver • Tankers clearly mark indentification of material being contained with mentioning Safety card. • Diver to have concerned safety office’s contact details to contact hi, in case of emergency. • Provide muffler on exhaust while etntering tanker within premises • Ensure earthing before starting any tranfferring. • SOP to cover routine checking of Tank farm area to be carried our for checking any spillage leakage. • Reading temperature & pressure are noted, recorded & reported immediately for intakeness. • Safety instruments like repture disc, Safety Valves checks at defined duration for intakeness. • Scheduled testing of tanks to be done for thickness testing. • Tanks to be painted or regular interval defined as per laws to protect them from atmospheric corrosion.

206 • Concerned persons are trained properly to use spill kit in case of observing any spillage inside warehouse. 2. Solids :-

• Vendor asks to provide MSDS to truck driver • Diver to have concerned safety office’s contact details to contact hi, in case of emergency. • Provide muffler on exhaust while etntering tanker within premises • SOP to cover routine checking of Tank farm area to be carried our for checking any spillage leakage.

3. Handling Corrosive Chemicals :-

When in contact with human tissues, most corrosive substances reduce chemical burns while certain other substances produce deep ulceration. Many corrosive substances have a defeating action on the skin and may cause dermatitis.

The Safegaurds against these hazards are :-

• Preventing or minimizing contact between corrosive substabnces and skin, mucos membranes and eyes. • Corrosive substances are not allowed to come in sontact with material that may react. • All the contains, Pipes, apparatus, installations and structures used for the manufacture, storage, transport or use of these substance are protected by suitable coating, impervious to and unaffected by corrosives. • All Containers or receptacies are clearly labled to indicate their contents and should bear the danger symbol for corrosive. • A high standard of maintance and good house keeping is essential. • Adequate ventilation and exhaust arrangement whether general or local, should be provided whenever corrosive toxic gased or dust are present. • Personal Protective devices are uased depending upon the nature of work viz; 1) Corrosion-resistant and impersious suits, or hand gloves, aprons etc. 2) Respirator, Gas mask or self contained breathing apparatus. 3) Barrier cream when exposure is not severe. • First Aid Treatment facilities are provided and all concern are instructed to folloe safe practiced such as ; 1) Proloned washinfg with Water 2) Removing Contaminated Clothing 3) Seeking immediate medical help • Safety showers and eye washers are provided.

207

ANNEXURE-X RISK OF ACCIDENT OF THE PROJECT WHICH COULD BE AFFECT HUMAN HELATH OR THE ENVIROMENT FROM ANY OTHER CAUSES.

Other Hazardos and Control :-

Sr. Name of the possible Its Sources & Its Effects on Place of its Control Measures No. Hazard or Emergency Reasons Persons, Effect Provided Property & Environment 1 Electricity Loose Burning, Shock, Surrounding Proper Earthing, (1)Burning Contacts, weak Death the accident Peridical Checking (2)Fire Earthing Short area of joints, Proper (3)Shock Circuit, Insulations of Improper Equipments etc. Insulation 3 Pipe Line Leakage Leaking of Pipe Physical/ Plant Area Proper (1)Corrosion line due to Chemical maintenance, (2)Toxic gas release corrosion, Thermal Burn Proper Selection of Loose contact, inhury (Major material for pipe etc. /Minor) lines. 4 Structural Failure Inside the Injury / Death to In the Factory Automatic Factory person, damage operestio periodic to property testing of safety valves, regular inspection and maintenance. 5 Tox ic realease from Outside the Injury/ Death Within & Alarm, Evacuation ourtside factory outside the recue the Welfare unit 6 Natural Calamity Nature Injury / Death to Within & Alarm, Evacuation persons, damage outside the recue the Welfare to property unit

208 ANNEXURE-XI

SOCIO - ECONOMIC IMPACTS

1) EMPLOYMENT OPPORTUNITIES :-

The manpower requirement for the proposed project is being expected to generate some permanent jobs and secondary jobs for the operation and maintenance of plant. This will increase direct / indirect employment opportunities and ancillary business development to some extent for the local population. This phase is expected to create a beneficial impact on the local socio-economic environment.

2) INDUSTRIES :-

Required raw materials and skilled and unskilled laborers will be utilized maximum from the local area. The increasing industrial activity will boost the commercial and economical status of the locality, to some extent.

3) PUBLIC HEALTH :-

The company regularly examines, inspects and tests its emission from sources to make sure that the emission is below the permissible limit. Hence, there will not be any significant change in the status of sanitation and the community health of the area, as sufficient measures have been taken and proposed under the EMP.

4) TRANSPORTATION AND COMMUNICATION :-

Since the existing factory is having proper linkage for the transport and communication, the development of this project will not cause any additional impact.

In brief, as a result of the proposed project there will be no adverse impact on sanitation, communication and community health, as sufficient measures have been proposed to be taken under the EMP. The proposed project is not expected to make any significant change in the existing status of the socio - economic environment of this region.

209 ANNEXURE-XII

PROPOSED TERMS OF REFERENCE FOR EIA STUDIES

1. Project Description :-

• Justification of project. • Promoters and their back ground • Project site location along with site map of 5 km area and site details providing various industries, surface water bodies, forests etc. • Project cost • Project location and Plant layout. • Existing infrastructure facilities • Water source and utilization including proposed water balance. • List of Products and their capacity • List of hazardous chemicals with their toxicity levels. • Mass balance of each product along with the batch size • Storage and Transportation of raw materials and products.

2. Description of the Environment and Baseline Data Collection :-

• Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 5 km area. • Study of Data from secondary sources. • Existing environmental status Vis a Vis air, water, noise, soil in 5 km area from the project

site. For SPM, RSPM, SO 2, NOx. • Ground water quality at 5 locations within 5 km. • Complete water balance

3. Socio Economic Data :-

• Existing socio-economic status, land use pattern and infrastructure facilities available in the study area were surveyed.

4. Impacts Identification and Mitigatory Measures. :-

• Impact on air and mitigation measures including green belt • Impact on water environment and mitigation measures • Soil pollution source and mitigation measures • Noise generation and control. • Solid waste quantification and disposal. • Control of fugitive emissions

210 5. Environmental Management Plan :-

• Details of pollution control measures • Environment management team • Proposed schedule for environmental monitoring including post project

6. Risk Assessment :-

• Details on storage facilities • Identification of hazards • Consequence analysis • Recommendations on the basis of risk assessment done • Disaster Management Plan.

7. Information for Control of Fugitive Emissions

8. Post Project Monitoring Plan for Air, Water, Soil and Noise.

9. Occupational Health and Safety Program for the Project.

211 ANNEXURE-XIII

LEASE OF PLOT :-

212

213