Bridgewater Review

Volume 2 | Issue 3 Article 13

Jul-1984 Research Note: PCBs in the Acushnet River Estuary Jacek Sulanowski Bridgewater State College

Recommended Citation Sulanowski, Jacek (1984). Research Note: PCBs in the Acushnet River Estuary. Bridgewater Review, 2(3), 25-27. Available at: http://vc.bridgew.edu/br_rev/vol2/iss3/13

This item is available as part of Virtual Commons, the open-access institutional repository of Bridgewater State University, Bridgewater, . Cultural Commentary Continued McCarthy would cooperate with the New Adminis­ tration. But to Ike's dismay the Senator, now Chairman of the Government Operations Committee, stepped up his campaign to ferret out Communists. Eisenhower personally loathed McCarthy, but hesitated to grapple with him, explaining, "I will not get in the gutter with that PCBs In The guy." McCarthy began his campaign with an investigation Acushnet River Estuary by Jacek Sulanowski into subversion in the Voice of America, the government Assistant Professor of agency for overseas broadcasts. His chief counsel, Roy Earth Sciences and Geography Cohn, and committee staff assistant G. David Schine, made a highly publicized tour of American information offices in Europe, searching for subversive books and MUCh media attention has recently been devoted to potentially toxic terrorizing employees. substances disseminated throughout various components of the environment. By early 1954, McCarthy was at the height of his In almost every case these substances had been manufactured and distributed power. A Gallup Poll ofJanuary 1954, reported that fifty under the assumption that they did not pose a threat to man. Indeed when tested percent of those interviewed expressed a favorable by methods current at the time of their initial introduction the substances were opinion of him. But when, in his increasingly reckless considered benign. It was only later when technologically advanced and more course, he turned his guns on the Army, the sensitive methods of analyses were developed that the presence of these Eisenhower Administration broke with McCarthy. At substances was considered to be of real concern. Unfortunately, in the interval issue was whether the Army was protecting and even between introduction and detection, the accumulation of these substances had promoting Communists. The Army fought back, frequently reached staggering proportions. charging that Roy Cohn had sought preferential treatment for his sidekick G. David Schine, who had been Under these circumstances, the problem can no longer be solved by the simple drafted in 1953. expedient of cessation of production. Methods must be devised to deal with the already accumulated substances. Frequently, because of the urgency, these The clash became the subject ofa Senate investigation which was televised from April 22 to June 17. Like the methods constitute only stop-gap measures which do little more than transfer later Watergate hearings, it was compelling drama, the pollutants from one environmental component to another while awaiting attracting millions of viewers, who quickly realized that the development of technology which will permanently neutralize the McCarthy was a crude and cruel bully. As one columnist pollutants. observed, "No one who saw that flower of evil will ever Polychlorinated biphenyls (PCBs) are but one example of such substances. forget it." Originally made commercially available in 1929, they share with many other The dramatic highlight, which assured McCarthy's halogenated hydrocarbons the characteristic of excellent resistance to denouement, occurred when the Army counsel, Joseph degradation. From the time of introduction through 1975, approximately 600 Welch, outraged by McCarthy's attack on a young million kilograms (kg) ofPCBs were produced in the United States alone. These colleague, cried out, "Until this moment, Senator, I think compounds were found to be extremely useful in a wide variety of industrial I never really gauged yourcruelty or your recklessness ... applications. Their stability at high temperatures and voltages made them ideal And he added, "Have you no sense of decency, Sir, at long last?" The gallery applauded and McCarthy's lubricating and insulating oils respectively. Also related to their stability was bullying days were over. In December 1954, the Senate their use to extend the life of certain pesticides. Other applications included nerved itself against his insults and voted to "condemn" their incorporation in the manufacture of rubber and plastics as corrosion and McCarthy. Thereafter McCarthy was a voice in the flame retardants. Paradoxically this stability, which caused the PCBs to be so wilderness, snubbed by all, save the hard-core Red attractive in industrial and agricultural applications, is also the source oftheir baiters. His death from alcoholism, in 1957, "merely environmental liability. Nearly the entire amount produced since their ratified his political demise," as one writer put it. introduction can be accounted for. More than half of the total is still in service Before McCarthy's self-destruction, he disrupted two and only approximately four percent has been degraded or incinerated. Of the Administrations, besmirched American political life, remainder it is estimated that 130 million kg are located in landfills or lowered morale throughout the federal government, and equipment dumps and 68 million kg have been released into the environment. contributed to a rigid foreign policy that stifled debate and inhibited the American government for years to come. McCarthy encouraged censorship, blacklists, and loyalty oaths and, while he never utlcovered a single Figure 1 Communist, many hundreds suffered because of his General Structure of obsession with subversion. polychlorinated biphenyls McCarthy operated in troubled times, but his brief success serves to remind us that the fabric ofcivil liberties is fragile and that "Great Simplifiers" are dangerous. 5' 6' 2._---~ People like McCarthy get their chance when fear and ,...----.... ignorance become tangled, when people do not understand life or history's complexities. While some liberals ofthe '50s thought they saw anemerging dictator 4' 4 and recalled the last days of Germany's Weimar Republic, McCarthy was no Hitler -- he had no program, his ambitions were limited. But this is no reason for complacency. Even the most optimistic student of American history must consider the possibility that in 5 another national crisis, a real Fuehrer could emerge to tantalize us with simple solutions to complex problems. 25 Polychlorinated biphenyls) (PCBs) Fairhaven, Massachusetts. The estuary of PCBs were discovered in the Acushnet comprise a large number of organic this river forms a natural harbor River in 1974 during analyses ofsamples for compounds where several chlorine atoms approximately four kilometers (km) long another group of hydrocarbons. occupy different positions on the ten carbon which was responsible for the importance of Investigators at the Woods Hole atoms of the biphenyl rings, giving rise to New Bedford as a commercial port during Oceanographic Institution (WHO!) found related chemicals known as isomers. About the nineteenth century. Former textile mills that certain substances, later identified as one hundred such PCB isomers, each with line the banks on the New Bedford side of PCBs, interfered with analytical procedures. its unique physical and chemical properties, the estuary. Two of these vacated mills have Subsequent sampling programs carried out have been manufactured by Monsanto been occupied by electronic component by investigators from WHOI, the Chemicals, U.S.A. Although the solubility manufacturers since World War II. PCB Environmental Protection Agency (EPA) of isomers generally decreases with mixtures were used by both companies in the and state agencies suggested that the extent increasing numbers of chlorine atoms on the manufacture of capacitors and leakage of of 'PCB pollution in the estuary was of biphenyl ring, each member of PCBs often these substances into the Acushnet River critical proportions. This information had exhibits unexpected properties leading to occurred during the manufacturing process. several consequences. In 1977 tht;.:..:.::.:..:.:...... detrimental effects on the environment. As a result, the Achusnet has received direct Sufficient data now exists which indicates discharge of PCB mixtures for nearly four that PCB mixtures have an adverse effect on decades. ';';%1111 biological systems. These effects range from disruption ofcommunity structure in certain Figure 2 marine systems to reproductive dysfunction Acushnet River Estuary and western in subhuman primates and include carcinogenicity in laboratory organisms. The observed effects of PCB mixtures on humans have to date been limited to relatively mmor impairments such as abnormal skin eruptions (chloracne). Carcinogenic effects of PCBs on human populations cannot at the present time be unequivocally determined due in part to the lack of a sufficiently long latency period. However, the lack of clear-cut causal relationships should not be construed as indicating that PCBs do not pose a serious potential health risk. New Bedford Following the detection of PCB mixtures Nasketucket in environmental samples during the 1960s, B<1-Y Monsanto voluntarily limited its range of PCB products and restricted sales to manufacturers of closed electrical components. Finally, in 1977, Monsanto ceased United States production of PCBs entirely. The cessation of production did not significantly ameliorate the problem since PCBs had already accumulated in the ..,... .

I- No lobstering or fishing ~(t;~~~~:t:f~~~~~;~s;J~?~";'t;;;:::~\~~~'l II - No lobstering or fishing III for bottom-feeding fish III - No lobstering techniques for neutralizing these substances J/ ".:'.:'.' <':::':\~:':::"~:'i"""" Roundhill Pt. ar~:~t~~:o::::raPhic areas have been }\\%\\:.: :....:.....~\ '.: contaminated to a greater degree than , Health (MDPH) issued a warning against prominent in this regard due to the siting of . :,< Mishaum Pt. the consumption of fish and shellfish taken both heavy and light industries near Until recently scientists were unable to from the Acushnet Estuary. In the same year waterways. The in New York discern the environmental impact of the two capacitor manufacturers stopped state, whose sediments bear an estimated individual PCB isomers used in mixture using PCB mixtures. Finally, in 1979, the PCB load of 300,000 kg, is perhaps the best forms, since sensitive analytical techniques MDPH expanded its earlier warning by studied example. In the New England region were not available to detect parts per million issuing orders which closed the estuary and the Acushnet River Estuary bears the (ppm) concentration levels. The advent of adjoining portions of Buzzards Bay to dubious distinction of being similarly high resolution glass-capillary gas fishing (Figure 2). This action was taken burdened. chromatography now enables researchers to because PCB concentrations in fish which The Acuhsnet, a small river located on the determine the environmental persistance inhabited these waters exceeded the federal western shore ofBuzzards Bay, separates the and toxicity of minute amounts of PCB maximum of five parts per million (ppm) for communities of New Bedford and isomers a lied many years ago. edible tissue. 26 During this time a group of W.H.O.l. seems to be especially true when the Bridgewater State College using funds scientists had been involved in a nationwide generator is an independent academic provided for this purpose by the Pappas coastal pollution monitoring program laboratory desiring collaboration with Foundation of West Falmouth, named "Mussel Watch" which used the agencies which may have proprietary Massachusetts. common blue mussel as a sentinel organism. interests in the matter. This particular Particle size analyses of the twelve One of this group, Dr. John Farrington, problem was brought closer to resolution as stations sampled indicate that nearly one­ became very concerned about the elevated a result of the formation, in 1979, of the Ad third of the sediment is finer than medium levels contained in mussels from the Hoc Committee by State Representative silt. Assuming an average water depth offive Acushnet River Estuary and brought the Roger Goyette of New Bedford. Periodic meters and absolutely calm conditions, these resources of his laboratory to bear on the meetings of this committee increased the particles would stay in suspension for a problem. As a result, state ofthe art analyses general awareness of the PCB problem minimum of seven hours. An even more soon augmented the more routine analytical within the various agencies of the alarming consequence is that under the same procedures utilized by the other agencies Commonwealth and on the national level. conditions nearly one-sixth of the sediment involved in the problem. This was an which escapes capture would remain important development in that the more suspended in the water column for over four sophisticated analytical procedures brought Sufficient data now exists days. During this time it would be subject to, out complexities of the problem which were at minimum, transport by eight tidal cycles. not detected by standard methods. which indicates that PCB mixtures have an adverse Though the above are preliminary order The concentration of PCBs in the inner of magnitude calculations, they do suggest reaches ofthe Acushnet River Estuary (Area effect on biological systems. that even just the removal of affected I in Figure I) is due in part to the presence of sediments is not as simJ:>le a procedure as a hurricane barrier which was constructed in might be expected. When other factors such the mid-1960s. The restricted movement of It soon became obvious that attention to as disposal of the captured sediment are water and suspended sedimentary particles this problem was required since estimates of considered, it becomes obvious that quick through the harbor entrance has resulted in the costs ofdredging operations approached solutions to the problem are not the formation of a sink for pollutant 130 million dollars. Such a sum could not forthcoming and that alternatives should be compounds which are discharged into the easily be assimilated by either local or state based on well considered research. harbor. Consequently, PCB concentrations resources during these current fiscally Considering the foregoing, the no-action in the harbor area have reached levels as straitened times. In 1982 the Acushnet River alternative might seem attractive. However, high as 190,000 ppm near one of the Estuary was added to the list of U.S. EPA in the long term this alternative has serious manufacturing plants. Estimates of total hazardous waste sites making it thereby consequences. The hurricane barrier which PCB load in the harbor, based on several eligible for "Superfund" assistance. At the has provided a measure of protection to the cores and approximately twenty grab present time additional data on various Buzzards Bay ecosystem has never been samples, indicate that more than 100,000 kg aspects of the problem are being generated tested by a major storm. It is possible to of these pollutants are found within the in order to better define the problem and to envision a scenario in which a hurricane upper one-half meter of sediment. From the design an appropriate solution. overtops the barrier and transports the perspective ofthe health ofthe Buzzards Bay One of the solutions being considered is a polluted sediments into Buzzards Bay. ecosystem, the formation of this sink might dredging of the harbor sediments to a depth Under these circumstances a problem which be considered a boon in that the larger of one-half meter. Of the various was once localized and potentially soluble fishery has been protected from a potentially management alternatives, dredging appears becomes unmanageable as a result of major PCB impact for nearly twenty years. to be the most technically and economically inaction. However, the inner harbor sediments feasible method to alleviate the problem in cannot be considered a permanent sink for the near future. However, even under ideal pollutants. A recent study ofthe distribution conditions, dredging operations can only SELECTED REFERENCES of trace metals, another group of pollutants account for a capture of approximately Farrington, J. w., J. Sulanowski, A. C. Davis, N. which have accumulated in the harbor over Staresinic, B. W. Tripp, H. Levin, L. Stathoplos. 1983. ninety percent of the sediments. The PCB bio-geochemistry in the Acushnet River Estuary, the past eighty years, suggests that the remainder escapes as a result of the Massachusetts, pp. 165-167. Fourth International Ocean harbor is a "leaky sink" and that some trace resuspension of particles disturbed during Disposal Symposium, Plymouth, U.K. metals have been transported on suspended dredging. These particles will settle at Kalmaz, E. V. and G. D. Kalmaz. 1979. Transport, particles of sediment into the western velocities dependent on their diameter distribution and toxic effects of polychlorinated portion of Buzzards Bay. Since PCBs also biphenyls in ecosystems: Review. Ecol. Modeling, 6:223­ resulting in a prolonged suspension of fine­ 251 tend to be associated with solid surfaces, grained particles. In a suspended state these they may be transported in a similar fashion N. A. S. 1979. Polychlorinated biphenyls. A report particles are subject to transport out of the prepared by the Committee on the Assessment of resulting in a chronic but relatively low-level harbor and into Buzzards Bay. Polychlorinated Biphenyls in the Environment. discharge into Buzzards Bay. Analyses of Environmental Studies Board, Commission on Natural easily resuspended particles in the inner Resources, National Research Council. National The specific cause for concern relates to Academy of Sciences, Washington, D. C. harbor verify this suggestion. the high surface area-to-volume ratio offine Summerhayes, C, J. P. Ellis, P. Stoller, S. Briggs, M. G. Regardless of the precision involved, particules relative to coarser ones. Higher Fitzgerald. 1977. Fine-grained sediment and industrial scientific research alone may only delineate concentrations of PCBs should therefore be waste distribution and dispersal in New Bedford Harbor and western Buzzards Bay, Massachusetts. Technical a problem. The results of the research must associated with the fine particulate fraction Report W.H.O.1. 76-115, Woods Hold Oceanographic be transmitted and explained to those public of the sediment. A hypothesized Institution, Woods Hole, Mass. consequence of this relationship should be a officials who are responsible for the legal Zell, M. and K. Ballschmiter, 1980. Baseline studies of and policy aspects of environmental considerable net transport of PCBs into the Global Pollution III. Trace analysis of management. Frequently, this transfer of Buzzards Bay during dredging operations. polychlorinated biphenyls (PCB) by ECD glass capillary gas chromatography in environmental samples of information from generator to eventual user We are currently attempting to define the different trophic levels. Fresenius Z. Anal. Chem., is not as direct as might be supposed. This PCB-to-particle size relationship at 304:337-349. 27