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USOO8753759B2 (12) United States Patent (10) Patent No.: US 8,753,759 B2 Liao (45) Date of Patent: *Jun. 17, 2014 (54) BATTERY WITH CHLOROPHYLL 5,270,137 A * 12/1993 Kubota ......................... 429,249 ELECTRODE 5,928,714 A * 7/1999 Nunome et al. ........... 427,126.3 6,511,774 B1 1/2003 Tsukuda et al. 6,905,798 B2 6/2005 Tsukuda et al. (75) Inventor: Chungpin Liao, Taichung (TW) 7,405,172 B2 7/2008 Shigematsu et al. 2009/0325067 A1 12/2009 Liao et al. (73) Assignee: iNNOT BioEnergy Holding Co., George Town (KY) FOREIGN PATENT DOCUMENTS *) Notice: Subject to anyy disclaimer, the term of this TW I288495 B 10/2007 patent is extended or adjusted under 35 U.S.C. 154(b) by 460 days. OTHER PUBLICATIONS This patent is Subject to a terminal dis Dryhurst, Glenn, “Electrochemistry of Biological Molecules' claimer. Elsevier, Inc. (1977), pp. 408-415.* (21) Appl. No.: 13/075,909 * cited by examiner (22) Filed: Mar. 30, 2011 (65) Prior Publication Data Primary Examiner — Zachary Best (74) Attorney, Agent, or Firm — Novak Druce Connolly US 2012/O 148898A1 Jun. 14, 2012 Bove + Quigg LLP (30) Foreign Application Priority Data (57) ABSTRACT Dec. 13, 2010 (CN) .......................... 2010 1 0.585281 An exemplary battery is provided in the present invention. (51) Int. Cl. The battery includes a current collector, a positive-electrode HOLM 8/6 (2006.01) structure, a separation structure, a negative-electrode struc (52) U.S. Cl. ture and a housing. The positive-electrode structure, the sepa USPC ............................. 429/2; 429/218.1; 429/212 ration structure, the negative-electrode structure are encircled (58) Field of Classification Search in sequence inside of the housing. At least one of the negative USPC ........................................... 429/2, 218.1, 212 electrode structure and the positive-electrode structure com See application file for complete search history. prises chlorophyll. The battery of the present invention could store hydrogen by the chlorophyll of the positive-electrode (56) References Cited structure and/or the negative-electrode structure to generate U.S. PATENT DOCUMENTS electricity. 4,251,607 A * 2/1981 Yamaki et al. ................ 429/338 4.550,067 A * 10/1985 Horiba et al. ................. 429,213 19 Claims, 7 Drawing Sheets 100 - U.S. Patent Jun. 17, 2014 Sheet 1 of 7 US 8,753,759 B2 s 142 — 14 FG. 2 U.S. Patent Jun. 17, 2014 Sheet 2 of 7 US 8,753,759 B2 S1 PROVIDING A HGH POLYMER SOLUTION S2 PROVONG ANEGATIVE-ELECTRODESTRUCTURE S3 PROVIDING ASEPARATONSTRUCTURE S4 ASSEMBLNG THE NEGATIVE ELECTRODE AND THE SEPARATIONSTRUCTURE INTO A HOUSING S5 NSERTENG A CURRENT COLLECTOR NTO THE HOUSNG AND FING POSTVE-EECTRODE MATERA. THEREN TO FORMA POSTVE EECTRODESTRUCTURE FIG. 3 U.S. Patent Jun. 17, 2014 Sheet 3 of 7 US 8,753,759 B2 S11 SOWLY ADDING HGH POYMER POWOER NTO SOLVENTATA TEMPERATURE OF 4O DEGREE CE SUS TO FORMA FRST MXTURE S12 BLENONG THE FRST MIXTURE WHA MAGNE BENDER AT ARATE OF 500 - 700 RPM S13 WHETHER THE EECTRIC CONDUCTWTY OF THE FRST MXTURE S WHEN A RANGE OF 50ms/cm. TO 250 mSfcm S14 COMPETNG FIG. 4 U.S. Patent Jun. 17, 2014 Sheet 4 of 7 US 8,753,759 B2 S21 FERING THE CHOROPHY NPOWDER FORM BY AFTER MESH S22 POURNG THE HGH POLYMER SOLUTION TO FORMA SECONOMIXTURE S23 BLENDING THE SECONOMXTURE WTH A MAGNET BLENDER AT ARAE OF 500 - 700 RPM S24 WHETHER ACHEVNG UNFORM FUD OR NOT S25 COATNG THE UNFORM FLUD ON A CONDUCTEVE AYER S26 PLACNG THE ABOVE STRUCTURE INTO ANOVEN AND BAKNG ATA TEMPERATURE OF OO DEGREE CELSIUS, UNTL WATER EVAPORATES FIG. 5 U.S. Patent Jun. 17, 2014 Sheet 5 Of 7 US 8,753,759 B2 S31 TRMMING SEPARATORS S32 MMERSING THE TRIMMED SEPARATORS INTO THE HIGH POLYMER SOLUTION S33 TWO SEPARATORS ARE MADE BY TAKING OU THE SEPARATORS AND PACING THEM INTO AN OVEN AND BAKING THEM ATA TEMPERATURE OF 1 OO DEGREE CELSIUS, UNTIL WATER EVAPORATED S34 TAKING OUT THE FIRST OF THE TWO SEPARATORS, AND UNIFORMLY SPRAYING ELECTROLYTE MATERIA THEREON S35 DISPOSING THE SECOND OF THE TWO SEPARATORS ON TO THE FIRST OF THE TWO SEPARATORS FIG. 6 U.S. Patent Jun. 17, 2014 Sheet 6 of 7 US 8,753,759 B2 S4 ATACHING A NEGATIVE-ELECTRODE STRUCTURE ENTO THE HOUSING CLOSELY ROLLING UP T-E SEPARATION STRUCTURE BY A FRST HOLLOW ROD WITH AN INNER OIAMETER OF 4.5MM, AN OUTER DIAMETER OF 6.36 MM, AND A LENGTH OF S42 47.2MW TURNING THE FRS HOLLOW ROD WITH A ROLLE S43 SEPARAON SRUCTURE INTO THE HOUSING WITH THE NEGATIVE-ELECTROCDE STRUCTURE IN CLOCKWISE DRECTION AKING OUT THE FRST - OLLOW ROO N S44. COUNTERCLOCKWISE DIRECTION TO LEAVE THE SEPARAON STRUCTURE N THE HOUSING WITH THE NEGAVE-ELECTRODE STRUCTURE S47 WETER - SEPARATION STRUCTURES YES ATACHED ON THE NEGATIVE-ELECTRODE STRUCTURE IN THE OUSING YES S46 PULING OUTHE EPARATIONSTRUCTURE AND UDGN WHETHER THE SEPARATION STRUCTURE IS BAMAGE S46A REPLACNG THE SEPARATIONSTRUCTURE FIG. 7 U.S. Patent Jun. 17, 2014 Sheet 7 Of 7 US 8,753,759 B2 SLOWY FING THE POST VE-EECTRODE MATERA N POWDER FORM NTO THE HOUSING S5 WTH THE NEGATIVE-ELECTRODE STRUCTURE AND THE SEPARATION STRUCTURE THEREN S52 INSERTNG THE CURRENT COLLECTOR NTO THE CENTER OF THE HOUSING TAMPNG BY THE FRST HOLLOW ROD AND A S53 WSE AND CONTNUOUSLY FING THE POST VE EECRODE MATERA HEREN WHETHER THE AMOUNT OF THE POST VE-EECTRODE MATERA REACHES A NEEDED WEIGHT YES EMBELSHING THE POST VE-EECTRODE S55 STRUCTURE BY A SECONO HOOW ROD WITH AN INNER DAMETER 4.5 MM, AN OUTER DAMETER 9.94 MM, AND A LENGTH 47.2MM FIG. 8 US 8,753,759 B2 1. 2 BATTERY WITH CHLOROPHYLL FIG. 1 is a perspective view of a battery according to an ELECTRODE exemplary embodiment of the present invention; FIG. 2 is a sectional view of a negative-electrode structure CROSS-REFERENCE TO RELATED according to an exemplary embodiment of the present inven APPLICATION tion; FIG. 3 is a flow chart of a manufacturing method of a This application claims priority of Chinese Patent Appli battery according to an exemplary embodiment of the present cation No. 2010 10585281.3, filed on Dec. 13, 2010, entitled invention; “Battery” by Chungpin Liao, the disclosure of which is incor FIG. 4 is a detailed flow chart of the step S1 as shown in porated herein by reference in its entirety. 10 FIG.3: FIG. 5 is a detailed flow chart of the step S2 as shown in FIELD OF THE INVENTION FIG.3: FIG. 6 is a detailed flow chart of the step S3 as shown in The present invention relates to a battery, and more par FIG.3: ticularly to a battery using chlorophyll to generate electricity 15 FIG. 7 is a detailed flow chart of the step S4 as shown in FIG. 3; and and a manufacturing method thereof. FIG. 8 is a detailed flow chart of the step S5 as shown in BACKGROUND OF THE INVENTION FIG. 3. DETAILED DESCRIPTION OF THE INVENTION In recent years, portable electronic devices, such as mobile phones, portable cameras, notebook computers, digital cam Reference will now be made to the drawings to describe an eras, personal digital assistants (PDAs), CD players, are exemplary embodiment in detail. becoming popular owing to their lightweight and Small size. FIG. 1 is a perspective view of a battery 100 according to an Batteries used as a portable power source have also become 25 exemplary embodiment of the present invention. As shown in the focus of the public concern, and have been an essential FIG. 1, the battery 100 of the exemplary embodiment element of various portable electronic devices. includes a current collector 110, a positive-electrodestructure Although common batteries, such as carbon-Zinc batteries, 120, a separation structure 130, a negative-electrode structure alkaline batteries and secondary batteries, are allegedly envi 140 and a housing 150. The positive-electrode structure 120, ronment-benign, they in fact largely contain Substantial 30 the separation structure 130, the negative-electrode structure amounts of mercury and other heavy metals, such as cobalt. 140 and the housing 150 are encircled around the current Other than that, environmental pollutants are frequently used collector 110 in sequence. or released during battery manufacturing process. FIG. 2 is a sectional view of the negative-electrode struc Lithium batteries, though widely adopted as the largest ture 140 in accordance with an exemplary embodiment of the energy content among the portable batteries, are unstable in 35 present invention. As shown in FIG. 2, the negative-electrode electrochemical reactions. In worst scenarios, explosions can structure 140 of the exemplary embodiment includes a con occur due to its thermal runaway as the result of operating at ductive layer 141 and a negative-electrode layer 142, and the low load or under improper assemblage. Therefore, multiple negative-electrode layer 142 is formed on the conductive and complex protection mechanisms should be implemented layer 141. for their usage, such as the installation of a protection circuit, 40 The conductive layer 141 is made of conductive material. an exhaust vent, and isolation membranes, etc. The conductive material can be metal, metallic compound, or The price of the lithium batteries rises rapidly as a result of conductive polymeric material. The metal can be selected the depletion of lithium mineral, which is the main raw mate from a group consisting of aluminum and gold. The metallic rial of the positive electrode (such as Li CoO) and the compound can be selected from a group consisting of man negative electrode (such as LiC) of lithium batteries.
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  • Novel Contributions to the Solid-State Chemistry of Diazenides” 05/2009–11/2009 Master Thesis (Inorganic Chemistry) Ludwig-Maximilian University Munich (Prof

    Novel Contributions to the Solid-State Chemistry of Diazenides” 05/2009–11/2009 Master Thesis (Inorganic Chemistry) Ludwig-Maximilian University Munich (Prof

    Dissertation zur Erlangung des Doktorgrades der Fakultät für Chemie und Pharmazie der Ludwig-Maximilians-Universität München Novel Contributions to the Solid-State Chemistry of Diazenides Sebastian Bernhard Schneider aus München, Deutschland 2013 Erklärung Diese Dissertation wurde im Sinne von § 7 der Promotionsordnung vom 28. November 2011 von Herrn Prof. Dr. Wolfgang Schnick betreut. Eidesstattliche Versicherung Diese Dissertation wurde eigenständig und ohne unerlaubte Hilfe erarbeitet. München, 11.11.2013 …………………………………… (Sebastian Bernhard Schneider) Dissertation eingereicht am 11.11.2013 1. Gutachter: Prof. Dr. Wolfgang Schnick 2. Gutachter: Prof. Dr. Dirk Johrendt Mündliche Prüfung am 16.12.2013 To my family ACKNOWLEDGEMENTS First, I would like to express my gratitude to my supervisor Prof. Dr. Wolfgang Schnick for the opportunity to do my PhD under his guidance. Throughout the entire work, I appreciated his extraordinary expertise, the given freedom in research and writing and the support at any time. For being the co-referee of my thesis, I thank Prof. Dr. Dirk Johrendt. I am thankful to Prof. Dr. Konstantin Karaghiosoff, PD Dr. Markus Lackinger, Prof. Dr. Hans-Christian Böttcher, and Prof. Dr. Jörn Schmedt a. d. Günne for being available as examiners in my viva-voce. In addition, I have to thank various co-workers spread all over Germany and Europe. Hereby, special thanks go to • Volker L. Deringer, Dr. Ralf P. Stoffel as well as Prof. Dr. Richard Dronskowski (RWTH Aachen, Germany) for their long-lasting support with numerous theoretical calculations concerning novel diazenide compounds and for their ongoing enthusiasm until we found the final ground state. • Dr. Lkhamsuren Bayarjargal, Dr.