SAFETY DATA SHEET

Issuing Date: 05-Oct-2015 Revision Date: 05-Oct-2015 Version 1

1. IDENTIFICATION

Product Name Dawn Ultra Dishwashing Liquid, Original Scent

Product ID: 97591965_RET_NG

Product Type: Finished Product - Consumer (Retail) Use Only

Recommended use Dish Care

Restrictions on Use Use only as directed on label.

Synonyms Dawn Ultra Dishwashing Liquid, Pomegranate Awakening (97591967_RET_NG) Dawn Ultra Dishwashing Liquid, Apple Orchard Harvest (97591968_RET_NG)

Manufacturer PROCTER & GAMBLE - Fabric and Home Care Division Ivorydale Technical Centre 5289 Spring Grove Avenue Cincinnati, Ohio 45217-1087 USA

Procter & Gamble Inc. P.O. Box 355, Station A Toronto, ON M5W 1C5 1-800-331-3774

E-mail Address [email protected]

Emergency Telephone Transportation (24 HR) CHEMTREC - 1-800-424-9300 (U.S./ Canada) or 1-703-527-3887 Mexico toll free in country: 800-681-9531

2. HAZARD IDENTIFICATION

"Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the product.

This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.

Hazard Category Eye Damage / Irritation Category 2B

Signal Word WARNING

Hazard Statements Causes eye irritation

Hazard pictograms None

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Precautionary Statements - Wash hands thoroughly after handling Prevention

Precautionary Statements - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if Response present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF SWALLOWED: Drink 1 or 2 glasses of water

Precautionary Statements - None Storage

Precautionary Statements - None Disposal

Hazards not otherwise classified None (HNOC)

3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation

Chemical Name Synonyms Trade Secret CAS-No Weight % Sulfuric acid, mono-C10-16-alkyl Sulfuric acid, No 68585-47-7 15 - 20 esters, sodium salts mono-C10-16-alkyl esters, sodium salts Poly(oxy-1,2-ethanediyl), Poly(oxy-1,2-ethanediyl), No 68585-34-2 5 - 10 alpha-sulfo-omega-hydroxy-, alpha-sulfo-omega-hydro C10-16-alkyl ethers, sodium salts xy-, C10-16-alkyl ethers, sodium salts Amine oxides, C10-16-alkyldimethyl Amine oxides, No 70592-80-2 5 - 10 C10-16-alkyldimethyl Ethanol Ethanol No 64-17-5 1 - 5

4. FIRST AID MEASURES

First aid measures for different exposure routes

Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists.

Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists.

Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if symptoms occur.

Inhalation Move to fresh air. If symptoms persist, call a physician.

Most important symptoms/effects, None under normal use conditions. acute and delayed

Indication of immediate medical attention and special treatment needed, if necessary

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

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Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray.

Unsuitable Extinguishing Media None.

Special hazard None known.

Special protective equipment for As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH fire-fighters (approved or equivalent) and full protective gear.

Specific hazards arising from the None. chemical

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing.

Advice for emergency responders Use personal protective equipment as required.

Methods and materials for containment and cleaning up

Methods for containment Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.

Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible products None known.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .

Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL Ethanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm Mexico: TWA 1000 ppm TWA: 1900 mg/m3 Mexico: TWA 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3

Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia Ethanol 64-17-5 TWA: 1000 ppm TWA: 1000 ppm STEL: 1000 ppm STEL: 1000 ppm TWA: 1880 mg/m3 TWA: 1880 mg/m3

No relevant exposure guidelines for other ingredients

Exposure controls

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Engineering Measures Distribution, Workplace and Household Settings: Ensure adequate ventilation

Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction

Personal Protective Equipment

Eye Protection Distribution, Workplace and Household Settings: No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Use appropriate eye protection

Hand Protection Distribution, Workplace and Household Settings: No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Protective gloves

Skin and Body Protection Distribution, Workplace and Household Settings: No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Wear suitable protective clothing

Respiratory Protection Distribution, Workplace and Household Settings: No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY): In case of insufficient ventilation wear suitable respiratory equipment

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State @20°C liquid Appearance Various color by product Odor Scented Odor threshold No information available

Property Values Note pH value 9.0 - 9.2 10% aqueous solution Melting/freezing point No information available Boiling point/boiling range 100 - 104 °C / 212 - 219 °F Flash point No Flash to Boiling (NFTB) Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air Upper flammability limit No information available Lower Flammability Limit No information available Vapor pressure No information available Vapor density No information available Relative density 1.04 Water solubility 100% Solubility in other solvents No information available Partition coefficient: n-octanol/waterNo information available Autoignition temperature No information available . Decomposition temperature No information available .

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Viscosity of Product No information available VOC Content (%) Products comply with US state and federal regulations for VOC content in consumer products.

10. STABILITY AND REACTIVITY

Reactivity None under normal use conditions.

Stability Stable under normal conditions.

Hazardous polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

Conditions to Avoid None under normal processing.

Materials to avoid None in particular.

Hazardous Decomposition Products None under normal use.

11. TOXICOLOGICAL INFORMATION

Product Information Information on likely routes of exposure

Inhalation No known effect. Skin contact No known effect. Ingestion No known effect. Eye contact Irritating to eyes.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Acute toxicity No known effect. Skin corrosion/irritation No known effect. Serious eye damage/eye irritation Irritating to eyes. Skin sensitization No known effect. Respiratory sensitization No known effect. Germ cell mutagenicity No known effect. Neurological Effects No known effect. Reproductive toxicity No known effect. Developmental toxicity No known effect. Teratogenicity No known effect. STOT - single exposure No known effect. STOT - repeated exposure No known effect. Target Organ Effects No known effect. Aspiration hazard No known effect. Carcinogenicity No known effect.

Component Information

Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation Poly(oxy-1,2-ethanediyl), 68585-34-2 >2001 mg/kg - - alpha-sulfo-omega-hydroxy-, C10-16-alkyl ethers, sodium salts

12. ECOLOGICAL INFORMATION

Ecotoxicity

The product is not expected to be hazardous to the environment.

Persistence and degradability No information available.

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Bioaccumulative potential No information available.

Mobility No information available.

Other adverse effects No information available.

13. DISPOSAL CONSIDERATIONS

Waste treatment

Waste from Residues / Unused Disposal should be in accordance with applicable regional, national and local laws and Products regulations.

Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations.

California Hazardous Waste Codes 331 (non-household setting)

14. TRANSPORT INFORMATION

DOT Not regulated

IMDG Not regulated

IATA Not regulated

15. REGULATORY INFORMATION U.S. Federal Regulations

SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):

Chemical Name CAS-No Hazardous Extremely Hazardous CERCLA/SARA 302 Substances RQs Substances RQs TPQ Sodium hydroxide 1310-73-2 1000 lb -

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following substance(s) which are either listed as hazardous air pollutants (HAPS) or VOC's per the Clean Air Act:

Chemical Name CAS-No CAA (Clean Air Act) - 1990 Hazardous Air Pollutants Phenoxyethanol 122-99-6 X

Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42):

Chemical Name CAS-No CWA - Reportable CWA - Toxic CWA - Priority CWA - Hazardous Quantities Pollutants Pollutants Substances Sodium hydroxide 1310-73-2 1000 lb - - X

California Proposition 65

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This product is not subject to warning labeling under California Proposition 65.

U.S. State Regulations (RTK)

Chemical Name CAS-No New Jersey Ethanol 64-17-5 X

Chemical Name CAS-No Massachusetts Ethanol 64-17-5 X

Chemical Name CAS-No Pennsylvania Ethanol 64-17-5 X Sodium hydroxide 1310-73-2 X Phenoxyethanol 122-99-6 X

International Inventories

United States All intentionally-added components of this product(s) are listed on the US TSCA Inventory.

Canada This product is in compliance with CEPA for import by P&G.

Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act

16. OTHER INFORMATION

Issuing Date: 05-Oct-2015 Revision Date: 05-Oct-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of SDS

Page 7 / 7 Material safety data sheet Gel Spice Company, Inc. 48 Hook Road Bayonne, NJ, 07002 Tel: 201-339-0700

Blue Food Color 3.2. Mixture Safety Data Sheet Blue Food Color according to Federal Register / Vol. 77, No. 58 / Monday, March 26, Safety Data Sheet 2012 / Rules and Regulations according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 02/17/2016 EN (English US) Page 1 2012 / Rules and Regulations SECTION 1: Identification 02/17/2016 EN (English US) 2/6 1.1. Identification Name Product identifier % Classification (GHS-US) Product form : Mixture trade name component* (CAS No) Trade Secret 11.626284704 Product name : Blue Food Color 4598 Skin Irrit. 2, H315 Product code : S9123 *Chemical name, CAS number and/or exact concentration have 1.2. Relevant identified uses of the substance or mixture been withheld as a trade secret and uses advised against Full text of H-phrases: see section 16 No additional information available SECTION 4: First aid measures 1.3. Details of the supplier of the safety data sheet 4.1. Description of first aid measures Shank's Extracts, Inc. First-aid measures general : Never give anything by mouth 350 Richardson Drive to an unconscious person. If you feel unwell, seek medical Lancaster, PA 17603 advice (show the label where possible). T 717-393-4441 - F 717-393-3148 First-aid measures after inhalation : Remove person to fresh www.shanks.com air and keep comfortable for breathing. Allow victim to 1.4. Emergency telephone number breathe fresh Emergency number : CHEMTREC: 1-800-424-9300 air. Allow the victim to rest. SECTION 2: Hazard(s) identification First-aid measures after skin contact : Remove affected 2.1. Classification of the substance or mixture clothing and wash all exposed skin area with mild soap and Classification (GHS-US) water, followed Skin corrosion/irritation by warm water rinse. Wash skin with plenty of water. Take Category 2 off contaminated clothing. If skin H315 irritation occurs: Get medical advice/attention. Full text of H statements : see section 16 First-aid measures after eye contact : Rinse immediately 2.2. Label elements with plenty of water. Obtain medical attention if pain, blinking GHS-US labeling or redness Hazard pictograms (GHS-US) : persist. Rinse eyes with water as a precaution. GHS07 First-aid measures after ingestion : Rinse mouth. Do NOT Signal word (GHS-US) : Warning induce vomiting. Obtain emergency medical attention. Call a Hazard statements (GHS-US) : H315 - Causes skin irritation poison Precautionary statements (GHS-US) : P264 - Wash hands center/doctor/physician if you feel unwell. and any affected areas thoroughly after handling 4.2. Most important symptoms and effects, both acute P280 - Wear protective gloves/protective clothing/eye and delayed protection/face protection Symptoms/injuries : Not expected to present a significant P302+P352 - If on skin: Wash with plenty of a doctor, a hazard under anticipated conditions of normal use. POISON CENTER Symptoms/injuries after skin contact : Irritation. P321 - Specific treatment see doctor if affected 4.3. Indication of any immediate medical attention and P332+P313 - If skin irritation occurs: Get medical special treatment needed advice/attention Treat symptomatically. P362+P364 - Take off contaminated clothing and wash it before reuse SECTION 5: Firefighting measures 2.3. Other hazards 5.1. Extinguishing media No additional information available Suitable extinguishing media : Foam. Dry powder. Carbon 2.4. Unknown acute toxicity (GHS US) dioxide. Water spray. Sand. Not applicable Unsuitable extinguishing media : Do not use a heavy water stream. SECTION 3: Composition/information on 5.2. Special hazards arising from the substance or ingredients mixture 3.1. Substance Not applicable Reactivity : The product is non-reactive under normal SECTION 8: Exposure controls/personal conditions of use, storage and transport. protection 5.3. Advice for firefighters 8.1. Control parameters Firefighting instructions : Use water spray or fog for cooling trade name component exposed containers. Exercise caution when fighting any OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (mist, total chemical fire. Prevent fire-fighting water from entering particulate) environment. 5 mg/m³ (mist, respirable fraction) Protection during firefighting : Do not enter fire area without 8.2. Exposure controls proper protective equipment, including respiratory protection. Appropriate engineering controls : Ensure good ventilation of Do the work station. not attempt to take action without suitable protective Personal protective equipment : Avoid all unnecessary equipment. Self-contained breathing exposure. apparatus. Complete protective clothing. Hand protection : Wear protective gloves/protective SECTION 6: Accidental release measures clothing/eye protection/face protection. protective gloves. 6.1. Personal precautions, protective equipment and Eye protection : Chemical goggles or safety glasses. Safety emergency procedures glasses. 6.1.1. For non-emergency personnel Skin and body protection : Wear suitable protective clothing. Emergency procedures : Ventilate spillage area. Evacuate Respiratory protection : Wear appropriate mask. unnecessary personnel. Avoid contact with skin and eyes. Environmental exposure controls : Avoid release to the 6.1.2. For emergency responders environment. Protective equipment : Do not attempt to take action without Other information : Do not eat, drink or smoke during use. suitable protective equipment. Equip cleanup crew with SECTION 9: Physical and chemical proper protection. For further information refer to section 8: "Exposure controls/personal properties protection". 9.1. Information on basic physical and chemical Emergency procedures : Ventilate area. properties 6.2. Environmental precautions Physical state : Liquid Avoid release to the environment. Prevent entry to sewers Color : dark blue and public waters. Notify authorities if liquid enters sewers or Odor : characteristic public waters. Odor threshold : No data available 6.3. Methods and material for containment and cleaning pH : No data available up Melting point : Not applicable Methods for cleaning up : Take up liquid spill into absorbent Freezing point : No data available material. Soak up spills with inert solids, such as clay or Boiling point : No data available diatomaceous earth as soon as possible. Collect spillage. Flash point : > 100 °C Store away from other materials. Relative evaporation rate (butyl acetate=1) : No data Other information : Dispose of materials or solid residues at available an authorized site. Flammability (solid, gas) : No data available 6.4. Reference to other sections Explosion limits : No data available See Heading 8. Exposure controls and personal protection. Explosive properties : No data available For further information refer to section 13. Oxidizing properties : No data available Vapor pressure : No data available Blue Food Color Relative density : 1.035 - 1.25 Relative vapor density at 20 °C : No data available Safety Data Sheet Solubility : Water: Solubility in water of component(s) of the according to Federal Register / Vol. 77, No. 58 / Monday, March 26, mixture : 2012 / Rules and Regulations • : 576 g/l (at 20 °C) • : 630 g/l (at 20 °C) 02/17/2016 EN (English US) 3/6 SECTION 7: Handling and storage Log Pow : No data available 7.1. Precautions for safe handling Blue Food Color Precautions for safe handling : Ensure good ventilation of the work station. Wash hands and other exposed areas with Safety Data Sheet mild according to Federal Register / Vol. 77, No. 58 / Monday, March 26, soap and water before eating, drinking or smoking and when 2012 / Rules and Regulations leaving work. Provide good 02/17/2016 EN (English US) 4/6 Auto-ignition temperature : No data available ventilation in process area to prevent formation of vapor. Decomposition temperature : No data available Avoid contact with skin and eyes. Viscosity : No data available Wear personal protective equipment. Viscosity, kinematic : No data available Hygiene measures : Wash contaminated clothing before Viscosity, dynamic : No data available reuse. Do not eat, drink or smoke when using this product. 9.2. Other information Always wash hands after handling the product. No additional information available 7.2. Conditions for safe storage, including any incompatibilities SECTION 10: Stability and reactivity Storage conditions : Keep only in the original container in a 10.1. Reactivity cool, well ventilated place away from : acids and bases. The product is non-reactive under normal conditions of use, Keep container closed when not in use. Store in a well- storage and transport. ventilated place. Keep cool. 10.2. Chemical stability Incompatible products : Strong bases. Strong acids. Not established. Incompatible materials : Sources of ignition. Direct sunlight. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. In accordance with DOT 10.5. Incompatible materials Not regulated for transport Strong acids. Strong bases. TDG 10.6. Hazardous decomposition products No additional information available fume. Carbon monoxide. Carbon dioxide. Transport by sea SECTION 11: Toxicological information No additional information available 11.1. Information on toxicological effects Air transport Acute toxicity : Not classified No additional information available trade name component SECTION 15: Regulatory information LD50 oral rat 12600 mg/kg 15.1. US Federal regulations LD50 dermal rabbit > 10 g/kg trade name component LC50 inhalation rat (mg/l) > 570 mg/m³ (Exposure time: 1 h) Listed on the United States TSCA (Toxic Substances Control ATE US (oral) 12600.000 mg/kg body weight Act) inventory Skin corrosion/irritation : Causes skin irritation. EPA TSCA Regulatory Flag Y2 - Y2 - indicates an exempt Serious eye damage/irritation : Not classified polymer that is a polyester and is made only from reactants Respiratory or skin sensitization : Not classified included in a specified list of low concern reactants that Germ cell mutagenicity : Not classified comprises one of the eligibility criteria Carcinogenicity : Not classified for the exemption rule Reproductive toxicity : Not classified 15.2. International regulations Specific target organ toxicity (single exposure) : Not CANADA classified trade name component Specific target organ toxicity (repeated Listed on the Canadian DSL (Domestic Sustances List) exposure) WHMIS Classification Uncontrolled product according to : Not classified WHMIS classification criteria Aspiration hazard : Not classified EU-Regulations Potential Adverse human health effects and trade name component symptoms Listed on the EEC inventory EINECS (European Inventory of : Based on available data, the classification criteria are not Existing Commercial Chemical Substances) met. National regulations Symptoms/injuries after skin contact : Irritation. SECTION 12: Ecological information Blue Food Color 12.1. Toxicity Safety Data Sheet Ecology - general : The product is not considered harmful to according to Federal Register / Vol. 77, No. 58 / Monday, March 26, aquatic organisms or to cause long-term adverse 2012 / Rules and Regulations effects in the environment. 02 trade name component LC50 fish 1 51 - 57 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) Blue Food Color Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/17/2016 EN (English US) 5/6 12.2. Persistence and degradability Blue Food Color Persistence and degradability Not established. 12.3. Bioaccumulative potential Blue Food Color Bioaccumulative potential Not established. trade name component BCF fish 1 (no bioaccumulation) Log Pow -1.76 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions. Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) Material safety data sheet Gel Spice Company, Inc. 48 Hook Road Bayonne, NJ, 07002 Tel: 201-339-0700

3.1. Substance Green Food Color Not applicable (SENSITIZER-Y5) 3.2. Mixture Safety Data Sheet Green Food Color according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations (SENSITIZER-Y5) 03/03/2016 EN (English US) Page 1 Safety Data Sheet SECTION 1: Identification according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 1.1. Identification 2012 / Rules and Regulations Product form : Mixture 03/03/2016 EN (English US) 2/5 Product name : Green Food Color (SENSITIZER-Y5) Name Product identifier % Classification (GHS-US) Product code : S90109 trade name component* (CAS No) Trade Secret 15.699457819 1.2. Relevant identified uses of the substance or mixture 7336 Skin Irrit. 2, H315 and uses advised against *Chemical name, CAS number and/or exact concentration have No additional information available been withheld as a trade secret 1.3. Details of the supplier of the safety data sheet Full text of H-phrases: see section 16 Shank's Extracts, Inc. SECTION 4: First aid measures 350 Richardson Drive 4.1. Description of first aid measures Lancaster, PA 17603 First-aid measures after inhalation : Remove person to fresh T 717-393-4441 - F 717-393-3148 air and keep comfortable for breathing. www.shanks.com First-aid measures after skin contact : Wash skin with plenty 1.4. Emergency telephone number of water. Take off contaminated clothing. If skin irritation Emergency number : CHEMTREC: 1-800-424-9300 occurs: Get SECTION 2: Hazard(s) identification medical advice/attention. 2.1. Classification of the substance or mixture First-aid measures after eye contact : Rinse eyes with water Classification (GHS-US) as a precaution. Skin corrosion/irritation First-aid measures after ingestion : Call a poison Category 2 center/doctor/physician if you feel unwell. H315 4.2. Most important symptoms and effects, both acute Full text of H statements : see section 16 and delayed 2.2. Label elements Symptoms/injuries after skin contact : Irritation. GHS-US labeling 4.3. Indication of any immediate medical attention and Hazard pictograms (GHS-US) : special treatment needed GHS07 Treat symptomatically. Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H315 - Causes skin irritation SECTION 5: Firefighting measures Precautionary statements (GHS-US) : P264 - Wash hands 5.1. Extinguishing media and any affected areas thoroughly after handling Suitable extinguishing media : Water spray. Dry powder. P280 - Wear protective gloves/protective clothing/eye Foam. Carbon dioxide. protection/face protection 5.2. Special hazards arising from the substance or P302+P352 - If on skin: Wash with plenty of a doctor, a mixture POISON CENTER Reactivity : The product is non-reactive under normal P321 - Specific treatment see doctor if affected conditions of use, storage and transport. P332+P313 - If skin irritation occurs: Get medical 5.3. Advice for firefighters advice/attention Protection during firefighting : Do not attempt to take action P362+P364 - Take off contaminated clothing and wash it without suitable protective equipment. Self-contained before reuse breathing 2.3. Other hazards apparatus. Complete protective clothing. No additional information available SECTION 6: Accidental release measures 2.4. Unknown acute toxicity (GHS US) 6.1. Personal precautions, protective equipment and Not applicable emergency procedures SECTION 3: Composition/information on 6.1.1. For non-emergency personnel ingredients Emergency procedures : Ventilate spillage area. Avoid Flammability (solid, gas) : No data available contact with skin and eyes. Explosion limits : No data available 6.1.2. For emergency responders Explosive properties : No data available Protective equipment : Do not attempt to take action without Oxidizing properties : No data available suitable protective equipment. For further information Vapor pressure : No data available refer to section 8: "Exposure controls/personal protection". Relative density : 1.0593 6.2. Environmental precautions Relative vapor density at 20 °C : No data available Avoid release to the environment. Solubility : Water: Solubility in water of component(s) of the 6.3. Methods and material for containment and cleaning mixture : up • : 576 g/l (at 20 °C) • : 630 g/l (at 20 °C) Methods for cleaning up : Take up liquid spill into absorbent Log Pow : No data available material. Auto-ignition temperature : No data available Other information : Dispose of materials or solid residues at Decomposition temperature : No data available an authorized site. Viscosity : No data available 6.4. Reference to other sections Viscosity, kinematic : No data available For further information refer to section 13. Viscosity, dynamic : No data available SECTION 7: Handling and storage 9.2. Other information 7.1. Precautions for safe handling No additional information available Precautions for safe handling : Ensure good ventilation of SECTION 10: Stability and reactivity the work station. Avoid contact with skin and eyes. Wear 10.1. Reactivity personal The product is non-reactive under normal conditions of use, protective equipment. storage and transport. Hygiene measures : Wash contaminated clothing before 10.2. Chemical stability reuse. Do not eat, drink or smoke when using this product. Stable under normal conditions. Always wash hands after handling the product. 10.3. Possibility of hazardous reactions 7.2. Conditions for safe storage, including any No dangerous reactions known under normal conditions of incompatibilities use. Storage conditions : Store in a well-ventilated place. Keep 10.4. Conditions to avoid cool. None under recommended storage and handling conditions SECTION 8: Exposure controls/personal (see section 7). protection Green Food Color 8.1. Control parameters Green Food Color (SENSITIZER-Y5) Safety Data Sheet (SENSITIZER-Y5) according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Safety Data Sheet 03/03/2016 EN (English US) 4/5 according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 10.5. Incompatible materials 2012 / Rules and Regulations No additional information available 03/03/2016 EN (English US) 3/5 10.6. Hazardous decomposition products trade name component Under normal conditions of storage and use, hazardous OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (mist, total decomposition products should not be produced. particulate) 5 mg/m³ (mist, respirable fraction) SECTION 11: Toxicological information 8.2. Exposure controls 11.1. Information on toxicological effects Appropriate engineering controls : Ensure good ventilation of Acute toxicity : Not classified the work station. trade name component Hand protection : Protective gloves. LD50 oral rat 12600 mg/kg Eye protection : Safety glasses. LD50 dermal rabbit > 10 g/kg Skin and body protection : Wear suitable protective clothing. LC50 inhalation rat (mg/l) > 570 mg/m³ (Exposure time: 1 h) Respiratory protection : In case of insufficient ventilation, ATE US (oral) 12600.000 mg/kg body weight wear suitable respiratory equipment. Skin corrosion/irritation : Causes skin irritation. Environmental exposure controls : Avoid release to the Serious eye damage/irritation : Not classified environment. Respiratory or skin sensitization : Not classified SECTION 9: Physical and chemical Germ cell mutagenicity : Not classified Carcinogenicity : Not classified properties Reproductive toxicity : Not classified 9.1. Information on basic physical and chemical Specific target organ toxicity (single exposure) : Not properties classified Physical state : Liquid Specific target organ toxicity (repeated Color : Green exposure) Odor : Bland : Not classified Odor threshold : No data available Aspiration hazard : Not classified pH : No data available Symptoms/injuries after skin contact : Irritation. Melting point : Not applicable SECTION 12: Ecological information Freezing point : No data available 12.1. Toxicity Boiling point : No data available Ecology - general : The product is not considered harmful to Flash point : > 100 °C aquatic organisms or to cause long-term adverse Relative evaporation rate (butyl acetate=1) : No data effects in the environment. available trade name component Listed on INSQ (Mexican national Inventory of Chemical LC50 fish 1 51 - 57 ml/l (Exposure time: 96 h - Species: Substances) Oncorhynchus mykiss [static]) Listed on Turkish inventory of chemical 12.2. Persistence and degradability 15.3. US State regulations No additional information available trade name component 12.3. Bioaccumulative potential U.S. - Massachusetts - Right To Know List trade name component U.S. - New Jersey - Right to Know Hazardous Substance BCF fish 1 (no bioaccumulation) List Log Pow -1.76 U.S. - Pennsylvania - RTK (Right to Know) List 12.4. Mobility in soil SECTION 16: Other information No additional information available Full text of H-phrases: 12.5. Other adverse effects ------H315 Causes skin irritation Effect on the global warming : No known ecological damage SDS US (GHS HazCom 2012) caused by this product. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements SECTION 13: Disposal considerations only. It should not therefore be construed as 13.1. Waste treatment methods guaranteeing any specific property of the product Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions. Green Food Color (SENSITIZER-Y5) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/03/2016 EN (English US) 5/5 SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport TDG No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations trade name component Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag Y2 - Y2 - indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule 15.2. International regulations CANADA trade name component Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria EU-Regulations trade name component Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) National regulations trade name component Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Material safety data sheet Gel Spice Company, Inc. 48 Hook Road Bayonne, NJ, 07002 Tel: 201-339-0700

Red Food Color 3.2. Mixture Safety Data Sheet Red Food Color according to Federal Register / Vol. 77, No. 58 / Monday, March 26, Safety Data Sheet 2012 / Rules and Regulations according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 02/17/2016 EN (English US) Page 1 2012 / Rules and Regulations SECTION 1: Identification 02/17/2016 EN (English US) 2/6 1.1. Identification Name Product identifier % Classification (GHS-US) Product form : Mixture trade name component* (CAS No) Trade Secret 15.141151453 Product name : Red Food Color 3923 Skin Irrit. 2, H315 Product code : S9119 *Chemical name, CAS number and/or exact concentration have 1.2. Relevant identified uses of the substance or mixture been withheld as a trade secret and uses advised against Full text of H-phrases: see section 16 No additional information available SECTION 4: First aid measures 1.3. Details of the supplier of the safety data sheet 4.1. Description of first aid measures Shank's Extracts, Inc. First-aid measures general : Never give anything by mouth 350 Richardson Drive to an unconscious person. If you feel unwell, seek medical Lancaster, PA 17603 advice (show the label where possible). T 717-393-4441 - F 717-393-3148 First-aid measures after inhalation : Remove person to fresh www.shanks.com air and keep comfortable for breathing. Allow victim to 1.4. Emergency telephone number breathe fresh Emergency number : CHEMTREC: 1-800-424-9300 air. Allow the victim to rest. SECTION 2: Hazard(s) identification First-aid measures after skin contact : Remove affected 2.1. Classification of the substance or mixture clothing and wash all exposed skin area with mild soap and Classification (GHS-US) water, followed Skin corrosion/irritation by warm water rinse. Wash skin with plenty of water. Take Category 2 off contaminated clothing. If skin H315 irritation occurs: Get medical advice/attention. Full text of H statements : see section 16 First-aid measures after eye contact : Rinse immediately 2.2. Label elements with plenty of water. Obtain medical attention if pain, blinking GHS-US labeling or redness Hazard pictograms (GHS-US) : persist. Rinse eyes with water as a precaution. GHS07 First-aid measures after ingestion : Rinse mouth. Do NOT Signal word (GHS-US) : Warning induce vomiting. Obtain emergency medical attention. Call a Hazard statements (GHS-US) : H315 - Causes skin irritation poison Precautionary statements (GHS-US) : P264 - Wash hands center/doctor/physician if you feel unwell. and any affected areas thoroughly after handling 4.2. Most important symptoms and effects, both acute P280 - Wear protective gloves/protective clothing/eye and delayed protection/face protection Symptoms/injuries : Not expected to present a significant P302+P352 - If on skin: Wash with plenty of a doctor, a hazard under anticipated conditions of normal use. POISON CENTER Symptoms/injuries after skin contact : Irritation. P321 - Specific treatment see doctor if affected 4.3. Indication of any immediate medical attention and P332+P313 - If skin irritation occurs: Get medical special treatment needed advice/attention Treat symptomatically. P362+P364 - Take off contaminated clothing and wash it before reuse SECTION 5: Firefighting measures 2.3. Other hazards 5.1. Extinguishing media No additional information available Suitable extinguishing media : Foam. Dry powder. Carbon 2.4. Unknown acute toxicity (GHS US) dioxide. Water spray. Sand. Not applicable Unsuitable extinguishing media : Do not use a heavy water stream. SECTION 3: Composition/information on 5.2. Special hazards arising from the substance or ingredients mixture 3.1. Substance Not applicable Reactivity : The product is non-reactive under normal SECTION 8: Exposure controls/personal conditions of use, storage and transport. protection 5.3. Advice for firefighters 8.1. Control parameters Firefighting instructions : Use water spray or fog for cooling trade name component exposed containers. Exercise caution when fighting any OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (mist, total chemical fire. Prevent fire-fighting water from entering particulate) environment. 5 mg/m³ (mist, respirable fraction) Protection during firefighting : Do not enter fire area without 8.2. Exposure controls proper protective equipment, including respiratory protection. Appropriate engineering controls : Ensure good ventilation of Do the work station. not attempt to take action without suitable protective Personal protective equipment : Avoid all unnecessary equipment. Self-contained breathing exposure. apparatus. Complete protective clothing. Hand protection : Wear protective gloves/protective SECTION 6: Accidental release measures clothing/eye protection/face protection. protective gloves. 6.1. Personal precautions, protective equipment and Eye protection : Chemical goggles or safety glasses. Safety emergency procedures glasses. 6.1.1. For non-emergency personnel Skin and body protection : Wear suitable protective clothing. Emergency procedures : Ventilate spillage area. Evacuate Respiratory protection : Wear appropriate mask. unnecessary personnel. Avoid contact with skin and eyes. Environmental exposure controls : Avoid release to the 6.1.2. For emergency responders environment. Protective equipment : Do not attempt to take action without Other information : Do not eat, drink or smoke during use. suitable protective equipment. Equip cleanup crew with SECTION 9: Physical and chemical proper protection. For further information refer to section 8: "Exposure controls/personal properties protection". 9.1. Information on basic physical and chemical Emergency procedures : Ventilate area. properties 6.2. Environmental precautions Physical state : Liquid Avoid release to the environment. Prevent entry to sewers Color : red and public waters. Notify authorities if liquid enters sewers or Odor : characteristic public waters. Odor threshold : No data available 6.3. Methods and material for containment and cleaning pH : No data available up Melting point : Not applicable Methods for cleaning up : Take up liquid spill into absorbent Freezing point : No data available material. Soak up spills with inert solids, such as clay or Boiling point : No data available diatomaceous earth as soon as possible. Collect spillage. Flash point : > 100 °C Store away from other materials. Relative evaporation rate (butyl acetate=1) : No data Other information : Dispose of materials or solid residues at available an authorized site. Flammability (solid, gas) : No data available 6.4. Reference to other sections Explosion limits : No data available See Heading 8. Exposure controls and personal protection. Explosive properties : No data available For further information refer to section 13. Oxidizing properties : No data available Vapor pressure : No data available Red Food Color Relative density : 1.06 - 1.07 Relative vapor density at 20 °C : No data available Safety Data Sheet Solubility : Water: Solubility in water of component(s) of the according to Federal Register / Vol. 77, No. 58 / Monday, March 26, mixture : 2012 / Rules and Regulations • : 576 g/l (at 20 °C) • : 630 g/l (at 20 °C) 02/17/2016 EN (English US) 3/6 SECTION 7: Handling and storage Log Pow : No data available 7.1. Precautions for safe handling Red Food Color Precautions for safe handling : Ensure good ventilation of the work station. Wash hands and other exposed areas with Safety Data Sheet mild according to Federal Register / Vol. 77, No. 58 / Monday, March 26, soap and water before eating, drinking or smoking and when 2012 / Rules and Regulations leaving work. Provide good 02/17/2016 EN (English US) 4/6 Auto-ignition temperature : No data available ventilation in process area to prevent formation of vapor. Decomposition temperature : No data available Avoid contact with skin and eyes. Viscosity : No data available Wear personal protective equipment. Viscosity, kinematic : No data available Hygiene measures : Wash contaminated clothing before Viscosity, dynamic : No data available reuse. Do not eat, drink or smoke when using this product. 9.2. Other information Always wash hands after handling the product. No additional information available 7.2. Conditions for safe storage, including any incompatibilities SECTION 10: Stability and reactivity Storage conditions : Keep only in the original container in a 10.1. Reactivity cool, well ventilated place away from : acids and bases. The product is non-reactive under normal conditions of use, Keep container closed when not in use. Store in a well- storage and transport. ventilated place. Keep cool. 10.2. Chemical stability Incompatible products : Strong bases. Strong acids. Not established. Incompatible materials : Sources of ignition. Direct sunlight. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. In accordance with DOT 10.5. Incompatible materials Not regulated for transport Strong acids. Strong bases. TDG 10.6. Hazardous decomposition products No additional information available fume. Carbon monoxide. Carbon dioxide. Transport by sea SECTION 11: Toxicological information No additional information available 11.1. Information on toxicological effects Air transport Acute toxicity : Not classified No additional information available trade name component SECTION 15: Regulatory information LD50 oral rat 12600 mg/kg 15.1. US Federal regulations LD50 dermal rabbit > 10 g/kg trade name component LC50 inhalation rat (mg/l) > 570 mg/m³ (Exposure time: 1 h) Listed on the United States TSCA (Toxic Substances Control ATE US (oral) 12600.000 mg/kg body weight Act) inventory Skin corrosion/irritation : Causes skin irritation. EPA TSCA Regulatory Flag Y2 - Y2 - indicates an exempt Serious eye damage/irritation : Not classified polymer that is a polyester and is made only from reactants Respiratory or skin sensitization : Not classified included in a specified list of low concern reactants that Germ cell mutagenicity : Not classified comprises one of the eligibility criteria Carcinogenicity : Not classified for the exemption rule Reproductive toxicity : Not classified 15.2. International regulations Specific target organ toxicity (single exposure) : Not CANADA classified trade name component Specific target organ toxicity (repeated Listed on the Canadian DSL (Domestic Sustances List) exposure) WHMIS Classification Uncontrolled product according to : Not classified WHMIS classification criteria Aspiration hazard : Not classified EU-Regulations Potential Adverse human health effects and trade name component symptoms Listed on the EEC inventory EINECS (European Inventory of : Based on available data, the classification criteria are not Existing Commercial Chemical Substances) met. National regulations Symptoms/injuries after skin contact : Irritation. SECTION 12: Ecological information Red Food Color 12.1. Toxicity Safety Data Sheet Ecology - general : The product is not considered harmful to according to Federal Register / Vol. 77, No. 58 / Monday, March 26, aquatic organisms or to cause long-term adverse 2012 / Rules and Regulations effects in the environment. 02/17/2016 EN (English US) 6/6 trade name component LC50 fish 1 51 - 57 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) Red Food Color Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/17/2016 EN (English US) 5/6 12.2. Persistence and degradability Red Food Color Persistence and degradability Not established. 12.3. Bioaccumulative potential Red Food Color Bioaccumulative potential Not established. trade name component BCF fish 1 (no bioaccumulation) Log Pow -1.76 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions. Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) Material safety data sheet Gel Spice Company, Inc. 48 Hook Road Bayonne, NJ, 07002 Tel: 201-339-0700

3.1. Substance Yellow Food Color Not applicable (SENSITIZER Y-5) 3.2. Mixture Safety Data Sheet Yellow Food Color according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations (SENSITIZER Y-5) 02/17/2016 EN (English US) Page 1 Safety Data Sheet SECTION 1: Identification according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 1.1. Identification 2012 / Rules and Regulations Product form : Mixture 02/17/2016 EN (English US) 2/6 Product name : Yellow Food Color (SENSITIZER Y-5) Name Product identifier % Classification (GHS-US) Product code : S9118 trade name component* (CAS No) Trade Secret 15.256641733 1.2. Relevant identified uses of the substance or mixture 2989 Skin Irrit. 2, H315 and uses advised against *Chemical name, CAS number and/or exact concentration have No additional information available been withheld as a trade secret 1.3. Details of the supplier of the safety data sheet Full text of H-phrases: see section 16 Shank's Extracts, Inc. SECTION 4: First aid measures 350 Richardson Drive 4.1. Description of first aid measures Lancaster, PA 17603 First-aid measures general : Never give anything by mouth T 717-393-4441 - F 717-393-3148 to an unconscious person. If you feel unwell, seek medical www.shanks.com advice (show the label where possible). 1.4. Emergency telephone number First-aid measures after inhalation : Remove person to fresh Emergency number : CHEMTREC: 1-800-424-9300 air and keep comfortable for breathing. Allow victim to SECTION 2: Hazard(s) identification breathe fresh 2.1. Classification of the substance or mixture air. Allow the victim to rest. Classification (GHS-US) First-aid measures after skin contact : Remove affected Skin corrosion/irritation clothing and wash all exposed skin area with mild soap and Category 2 water, followed H315 by warm water rinse. Wash skin with plenty of water. Take Full text of H statements : see section 16 off contaminated clothing. If skin 2.2. Label elements irritation occurs: Get medical advice/attention. GHS-US labeling First-aid measures after eye contact : Rinse immediately Hazard pictograms (GHS-US) : with plenty of water. Obtain medical attention if pain, blinking GHS07 or redness Signal word (GHS-US) : Warning persist. Rinse eyes with water as a precaution. Hazard statements (GHS-US) : H315 - Causes skin irritation First-aid measures after ingestion : Rinse mouth. Do NOT Precautionary statements (GHS-US) : P264 - Wash hands induce vomiting. Obtain emergency medical attention. Call a and any affected areas thoroughly after handling poison P280 - Wear protective gloves/protective clothing/eye center/doctor/physician if you feel unwell. protection/face protection 4.2. Most important symptoms and effects, both acute P302+P352 - If on skin: Wash with plenty of a doctor, a and delayed POISON CENTER Symptoms/injuries : Not expected to present a significant P321 - Specific treatment see doctor if affected hazard under anticipated conditions of normal use. P332+P313 - If skin irritation occurs: Get medical Symptoms/injuries after skin contact : Irritation. advice/attention 4.3. Indication of any immediate medical attention and P362+P364 - Take off contaminated clothing and wash it special treatment needed before reuse Treat symptomatically. 2.3. Other hazards No additional information available SECTION 5: Firefighting measures 2.4. Unknown acute toxicity (GHS US) 5.1. Extinguishing media Not applicable Suitable extinguishing media : Foam. Dry powder. Carbon SECTION 3: Composition/information on dioxide. Water spray. Sand. ingredients Unsuitable extinguishing media : Do not use a heavy water Storage conditions : Keep only in the original container in a stream. cool, well ventilated place away from : acids and bases. 5.2. Special hazards arising from the substance or Keep container closed when not in use. Store in a well- mixture ventilated place. Keep cool. Reactivity : The product is non-reactive under normal Incompatible products : Strong bases. Strong acids. conditions of use, storage and transport. Incompatible materials : Sources of ignition. Direct sunlight. 5.3. Advice for firefighters SECTION 8: Exposure controls/personal Firefighting instructions : Use water spray or fog for cooling protection exposed containers. Exercise caution when fighting any 8.1. Control parameters chemical fire. Prevent fire-fighting water from entering trade name component environment. OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (mist, total Protection during firefighting : Do not enter fire area without particulate) proper protective equipment, including respiratory protection. 5 mg/m³ (mist, respirable fraction) Do 8.2. Exposure controls not attempt to take action without suitable protective Appropriate engineering controls : Ensure good ventilation of equipment. Self-contained breathing the work station. apparatus. Complete protective clothing. Personal protective equipment : Avoid all unnecessary SECTION 6: Accidental release measures exposure. 6.1. Personal precautions, protective equipment and Hand protection : Wear protective gloves/protective emergency procedures clothing/eye protection/face protection. protective gloves. 6.1.1. For non-emergency personnel Eye protection : Chemical goggles or safety glasses. Safety Emergency procedures : Ventilate spillage area. Evacuate glasses. unnecessary personnel. Avoid contact with skin and eyes. Skin and body protection : Wear suitable protective clothing. 6.1.2. For emergency responders Respiratory protection : Wear appropriate mask. Protective equipment : Do not attempt to take action without Environmental exposure controls : Avoid release to the suitable protective equipment. Equip cleanup crew with environment. proper protection. For further information refer to section 8: Other information : Do not eat, drink or smoke during use. "Exposure controls/personal SECTION 9: Physical and chemical protection". Emergency procedures : Ventilate area. properties 6.2. Environmental precautions 9.1. Information on basic physical and chemical Avoid release to the environment. Prevent entry to sewers properties and public waters. Notify authorities if liquid enters sewers or Physical state : Liquid public waters. Color : clear Yellow orange 6.3. Methods and material for containment and cleaning Odor : characteristic up Odor threshold : No data available Methods for cleaning up : Take up liquid spill into absorbent pH : No data available material. Soak up spills with inert solids, such as clay or Melting point : Not applicable diatomaceous earth as soon as possible. Collect spillage. Freezing point : No data available Store away from other materials. Boiling point : No data available Other information : Dispose of materials or solid residues at Flash point : > 100 °C an authorized site. Relative evaporation rate (butyl acetate=1) : No data 6.4. Reference to other sections available See Heading 8. Exposure controls and personal protection. Flammability (solid, gas) : No data available For further information refer to section 13. Explosion limits : No data available Explosive properties : No data available Yellow Food Color Oxidizing properties : No data available Vapor pressure : No data available (SENSITIZER Y-5) Relative density : 1.05 - 1.07 Relative vapor density at 20 °C : No data available Safety Data Sheet Solubility : Water: Solubility in water of component(s) of the according to Federal Register / Vol. 77, No. 58 / Monday, March 26, mixture : 2012 / Rules and Regulations • : 576 g/l (at 20 °C) • : 630 g/l (at 20 °C) 02/17/2016 EN (English US) 3/6 SECTION 7: Handling and storage Log Pow : No data available 7.1. Precautions for safe handling Yellow Food Color Precautions for safe handling : Ensure good ventilation of the work station. Wash hands and other exposed areas with (SENSITIZER Y-5) mild soap and water before eating, drinking or smoking and when Safety Data Sheet leaving work. Provide good according to Federal Register / Vol. 77, No. 58 / Monday, March 26, ventilation in process area to prevent formation of vapor. 2012 / Rules and Regulations Avoid contact with skin and eyes. 02/17/2016 EN (English US) 4/6 Auto-ignition temperature : No data available Wear personal protective equipment. Decomposition temperature : No data available Hygiene measures : Wash contaminated clothing before Viscosity : No data available reuse. Do not eat, drink or smoke when using this product. Viscosity, kinematic : No data available Always wash hands after handling the product. Viscosity, dynamic : No data available 7.2. Conditions for safe storage, including any 9.2. Other information incompatibilities No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity SECTION 13: Disposal considerations The product is non-reactive under normal conditions of use, 13.1. Waste treatment methods storage and transport. Waste treatment methods : Dispose of contents/container in 10.2. Chemical stability accordance with licensed collector’s sorting instructions. Not established. Waste disposal recommendations : Dispose in a safe 10.3. Possibility of hazardous reactions manner in accordance with local/national regulations. Not established. Ecology - waste materials : Avoid release to the 10.4. Conditions to avoid environment. Direct sunlight. Extremely high or low temperatures. SECTION 14: Transport information 10.5. Incompatible materials Department of Transportation (DOT) Strong acids. Strong bases. In accordance with DOT 10.6. Hazardous decomposition products Not regulated for transport fume. Carbon monoxide. Carbon dioxide. TDG SECTION 11: Toxicological information No additional information available 11.1. Information on toxicological effects Transport by sea Acute toxicity : Not classified No additional information available trade name component Air transport LD50 oral rat 12600 mg/kg No additional information available LD50 dermal rabbit > 10 g/kg SECTION 15: Regulatory information LC50 inhalation rat (mg/l) > 570 mg/m³ (Exposure time: 1 h) 15.1. US Federal regulations ATE US (oral) 12600.000 mg/kg body weight trade name component Skin corrosion/irritation : Causes skin irritation. Listed on the United States TSCA (Toxic Substances Control Serious eye damage/irritation : Not classified Act) inventory Respiratory or skin sensitization : Not classified EPA TSCA Regulatory Flag Y2 - Y2 - indicates an exempt Germ cell mutagenicity : Not classified polymer that is a polyester and is made only from reactants Carcinogenicity : Not classified included in a specified list of low concern reactants that Reproductive toxicity : Not classified comprises one of the eligibility criteria Specific target organ toxicity (single exposure) : Not for the exemption rule classified 15.2. International regulations Specific target organ toxicity (repeated CANADA exposure) trade name component : Not classified Listed on the Canadian DSL (Domestic Sustances List) Aspiration hazard : Not classified WHMIS Classification Uncontrolled product according to Potential Adverse human health effects and WHMIS classification criteria symptoms EU-Regulations : Based on available data, the classification criteria are not trade name component met. Listed on the EEC inventory EINECS (European Inventory of Symptoms/injuries after skin contact : Irritation. Existing Commercial Chemical Substances) SECTION 12: Ecological information National regulations 12.1. Toxicity Ecology - general : The product is not considered harmful to Yellow Food Color aquatic organisms or to cause long-term adverse effects in the environment. (SENSITIZER Y-5) trade name component LC50 fish 1 51 - 57 ml/l (Exposure time: 96 h - Species: Safety Data Sheet Oncorhynchus mykiss [static]) according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Yellow Food Color 02/17/2016 EN (English US) 6 (SENSITIZER Y-5) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/17/2016 EN (English US) 5/6 12.2. Persistence and degradability Yellow Food Color (SENSITIZER Y-5) Persistence and degradability Not established. 12.3. Bioaccumulative potential Yellow Food Color (SENSITIZER Y-5) Bioaccumulative potential Not established. trade name component BCF fish 1 (no bioaccumulation) Log Pow -1.76 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SDS No.: HH0189 SAFETY DATA SHEET GENERAL STORAGE CODE GREEN

Section 1 Chemical Product and Company Identifi cation Page E1 of E2

HOME SCIENCE TOOLS CHEMTREC 24 Hour Emergency USA Phone Number (800) 424-9300 665 Carbon Street Billings, MT 59102 1 703-741-5500 (from anywhere in the world). 800-860-6272 For laboratory and industrial use only. www.homesciencetools.com Not for drug, food or household use.

Product HYDROGEN PEROXIDE, 6% Synonyms Hydrogen Dioxide Section 2 Hazards Identifi cation Signal word: WARNING Precautionary statement: Pictograms: GHS07 P264: Wash hands thoroughly after handling. Target organs: Respiratory and gastrointestinal systems, skin, eyes P270: Do not eat, drink or smoke when using this product. P280: Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P312: IF SWALLOWED: Rinse mouth. Call a POISON CENTER or doctor if you feel unwell. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. GHS Classifi cation: P337+P313: If eye irritation persists: Get medical attention. Acute toxicity (Category 4) P501: Dispose of contents/container to a licensed chemical disposal agency in Eye irritation (Category 2A) accordance with local/regional/national regulations.

GHS Label information: Hazard statement: Supplementary information: H302: Harmful if swallowed. Do not tamper with venting mechanism. H319: Causes serious eye irritation.

Hazards not otherwise classifi ed: Health hazards not otherwise classifi ed (HHNOC) - Not Known Physical hazards not otherwise classifi ed (PHNOC) - Not Known Section 3 Composition / Information on Ingredients Chemical Name CAS # % EINECS Water 7732-18-5 <94% 231-791-2 Hydrogen peroxide 7722-84-1 6% 231-765-0 Acetanilide 103-84-4 0.05% 203-150-7

Section 4 First Aid Measures INGESTION: MAY BE HARMFUL IF SWALLOWED. Call physician or Poison Control Center immediately. Induce vomiting only if advised by appropriate medical personnel. Never give anything by mouth to an unconscious person.

INHALATION: MAY BE HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT IRRITATION. Remove to fresh air. If not breathing, give artifi cial respiration. If breathing is diffi cult, give oxygen. Get medical attention.

EYE CONTACT: CAUSES IRRITATION AND / OR BURNS TO EYES. Check for and remove contact lenses. Flush thoroughly with water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get immediate medical attention.

SKIN ABSORPTION: MAY BE HARMFUL IF ABSORBED THROUGH SKIN. CAUSES IRRITATION AND / OR BURNS TO THE SKIN. Remove contaminated clothing. Flush thoroughly with mild soap and water. If irritation occurs, get medical attention.

Section 5 Fire Fighting Measures Suitable Extinguishing Media: Water only! Apply vast amounts for cooling and dilution. Protective Actions for Fire-fi ghters: In fi re conditions, wear a NIOSH/MSHA-approved self-contained breathing apparatus and full protective gear. Use water spray to keep fi re-exposed containers cool. Specifi c Hazards: During a fi re, irritating and highly toxic gases may be generated by thermal decomposition or combustion. This product is a strong oxidizer which may release oxygen and promote the combustion of fl ammable materials. Spontaneous combustion can occur if allowed to remain in contact with oxidizable materials. Drying of product on clothing or combustible material may cause fi re. Section 6 Accidental Release Measures Personal Precautions: Evacuate personnel to safe area. Use proper personal protective equipment as indicated in Section 8. Provide adequate ventilation. Environmental Precautions: Avoid runoff into storm sewers and ditches which lead to waterways. Containment and Cleanup: Remove all sources of ignition. Absorb with inert dry material, sweep or vacuum up and place in a suitable container for proper disposal. Wash spill area with soap and water. Section 7 Handling & Storage Page E2 of E2 Precautions for Safe Handling: Read label on container before using. Do not wear contact lenses when working with chemicals. Keep out of reach of children. Avoid contact with eyes, skin and clothing. Do not inhale vapors, spray or mist. Use with adequate ventilation. Avoid ingestion. Wash thoroughly after handling. Remove and wash clothing before reuse. Conditions for Safe Storage: Store in a cool, well-ventilated area away from incompatible substances. Keep away from ignition sources. Do not allow temperature of stor- age to rise above 100°F. Section 8 Exposure Controls / Personal Protection Chemical Name ACGIH (TLV) OSHA (PEL) NIOSH (REL) Exposure Limits: Hydrogen peroxide TWA: 1 ppm ; 1.4 mg/m3 (A3) TWA: 1 ppm ; 1.4 mg/m3 TWA: 1 ppm ; 1.4 mg/m3

Engineering controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower and fi re extinguishing material. Personnel should wear safety glasses, goggles, or faceshield, lab coat or apron, appropriate protective gloves. Use adequate ventilation to keep airborne concentrations low. Respiratory protection: None should be needed in normal laboratory handling at room temperatures. If misty conditions prevail, work in fume hood or wear a NIOSH/MSHA- approved respirator. Section 9 Physical & Chemical Properties Appearance: Clear, colorless liquid. Evaporation rate ( Water = 1): <1 Partition coeffi cient: Data not available Odor: Slightly pungent odor. Flammability (solid/gas): Data not available. Auto-ignition temperature: Data not available Odor threshold: Data not available. Explosion limits: Lower / Upper: Data not available Decomposition temperature: Data not available. pH: Data not available. Vapor pressure (mm Hg): 14 (water) Viscosity: Data not available. Melting / Freezing point: Approximately 0°C (32°F) (water) Vapor density (Air = 1): 0.7 (water) Molecular formula: Mixture Boiling point: Approximately 100°C (212°F) (water) Relative density (Specifi c gravity): Approximately 1.0 (water) Molecular weight: Mixture Flash point: Data not available Solubility(ies): Complete in water. Section 10 Stability & Reactivity Chemical stability: Stable Hazardous polymerization: Will not occur. Conditions to avoid: Excessive temperatures, heat, sparks, open fl ame and other sources of ignition. Contact with combustible materials may result in spontaneous combustion. Incompatible materials: Acids, bases, metals, metal salts, reducing agents, organic materials, alkalies,dust and dirt contaminants, fl ammable substances, oxidizable materials. Hazardous decomposition products: Oxygen, which will promote the combustion of fl ammable material.

Section 11 Toxicological Information

Acute toxicity: Oral-rat LD50: 800 mg/kg [50% hydrogen peroxide] Skin corrosion/irritation: Skin-rabbit - Slight irritant. Serious eye damage/irritation: Eyes-rabbit - Severe irritant. Respiratory or skin sensitization: Data not available Germ cell mutagenicity: Data not available Carcinogenity: Data not available NTP: No component of this product present at levels greater than or equal to 0.1% is identifi ed as a known or anticipated carcinogen by NTP. IARC classifi ed: Group 3: Not classifi able as to its carcinogenicity to humans. OSHA: No component of this product present at levels greater than or equal to 0.1% is identifi ed as a carcinogen or potential carcinogen by OSHA. Reproductive toxicity: Data not available STOT-single exposure: The substance or mixture is classifi ed as specifi c target organ toxicant, single exposure, category 3 with narcotic eff ects. STOT-repeated exposure: Data not available Aspiration hazard: Data not available Potential health eff ects: Inhalation: Expected to be irritating to respiratory tract. Ingestion: Expected to cause burns to the gastrointestinal tract. Skin: Expected to cause irritation and/or burns. As the concentration or time of exposure increases, the extent of damage increases. Eyes: Expected to cause irritation and/or burns. Could cause corneal damage which may occur several days later. Signs and symptoms of exposure: See Potential health eff ects above. Medical conditions which may be aggravated by exposure include conjunctivitis of the eye, dermatitis of the skin, asthma and respiratory diseases. Additional information: RTECS #: MX0900000 [Hydrogen peroxide] Section 12 Ecological Information Toxicity to fi sh: Gambusia affi nis (fi sh, fresh water), NOEC = 2.38 - 9.86 mg/l [Hydrogen peroxide] Toxicity to daphnia and other aquatic invertebrates: Daphnia magna (Crustacia), EC50 = 7.7 mg/l/24 hours [Hydrogen peroxide] Toxicity to algae: Chlorella vulgaris (Algae), EC50 = 2.5 mg/l/growth rate [Hydrogen peroxide] Persistence and degradability: No data available Bioaccumulative potential: No data available Mobility in soil: No data available PBT and vPvB assessment: No data available Other adverse eff ects: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Section 13 Disposal Considerations These disposal guidelines are intended for the disposal of catalog-size quantities only. Federal regulations may apply to empty container. State and/or local regulations may be diff erent. Dispose of in accordance with all local, state and federal regulations or contract with a licensed chemical disposal agency. Section 14 Transport Information (US DOT / CANADA TDG) UN/NA number: Not applicable Shipping name: Not Regulated Hazard class: Not applicable Packing group: Not applicable Reportable Quantity: No Marine pollutant: No Exceptions: Not applicable 2016 ERG Guide # Not applicable Section 15 Regulatory Information A chemical is considered to be listed if the CAS number for the anhydrous form is on the Inventory list. Component TSCA CERLCA (RQ) RCRA code DSL NDSL CA Prop 65 Hydrogen peroxide Listed Not listed Not listed Listed Not listed This product does not contain any chemicals known to the State of California to cause cancer or reproductive toxicity. Section 16 Other Information The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make indepen- dent determinations of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. NTP: National Toxicology Program, IARC: International Agency for Research on Cancer, OSHA: Occupational Safety and Health Administration, STOT: Specifi c Target Organ Toxicity, SE: Single Exposure, RE: Repeated Exposure, ERG: Emergency Response Guidebook. Form 06/2015 Revision Date: February 20, 2018 Supercedes: December 6, 2016