DOCSLIB.ORG

(19) United States (12) Patent Application Publication (10) Pub

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
(19) United States (12) Patent Application Publication (10) Pub US 20050048403A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2005/0048403 A1 Kuroki (43) Pub. Date: Mar. 3, 2005 (54) PLANOGRAPHIC PRINTING PLATE (57) ABSTRACT MATERIAL AND PLANOGRAPHIC PRINTING PLATE PREPARING PROCESS Disclosed is a planographic printing plate material compris ing a hydrophilic support and provided thereon, a light (75) Inventor: Takaaki Kuroki, Tokyo (JP) sensitive layer and an overcoat layer in that order, Wherein the light sensitive layer contains (a) an alkali soluble poly Correspondence Address: mer, (b) a polymeriZable compound having an ethylenically FRISHAUF, HOLTZ, GOODMAN & CHICK, unsaturated bond, (c) a polymerization initiator, and (d) an PC anionic dye represented by the following formula (1), 767 THIRD AVENUE 25TH FLOOR NEW YORK, NY 10017-2023 (US) Formula (1) (73) Assignee: KONICA MINOLTA MEDICAL & GRAPHIC, INC., Tokyo (JP) (21) Appl. No.: 10/923,415 (22) Filed: Aug. 20, 2004 (30) Foreign Application Priority Data Aug. 29, 2003 (JP) ................................ .. JP2003-306272 Publication Classi?cation (51) Int. Cl? ..................................................... .. G03F 7/00 (52) US. Cl. ............................................................ ..430/300 US 2005/0048403 A1 Mar. 3, 2005 PLANOGRAPHIC PRINTING PLATE MATERIAL there is a method Which increases solubility of light sensitive AND PLANOGRAPHIC PRINTING PLATE layer. Typically, a resin having a high acid value or a PREPARING PROCESS photoinitiator system for accelerating reaction by heating has been studied. HoWever, satisfactory preheating latitude FIELD OF THE INVENTION has not yet obtained considering printing durability. Further, the above negative-Working photopolymeriZation type print [0001] The present invention relates to a planographic printing plate material With high sensitivity Which is capable ing plate material has problem in that sludge is likely to be produced in a developer, and does not have a satisfactory of being exposed With laser, and a process of preparing a planographic printing plate employing the same, and par running property. ticularly to a planographic printing plate material capable of being exposed With loW poWer laser, Which improves stor SUMMARY OF THE INVENTION age stability and preheating latitude, and minimizes sludge, [0006] An object of the invention is to provide a plano and a process of preparing a planographic printing plate graphic printing plate material providing high sensitivity, employing the same. high printing durability, and good preheating latitude, and a process of preparing a planographic printing plate employ BACKGROUND OF THE INVENTION ing the same. [0002] In recent years, as a printing plate for off-set printing, a large number of computer to plate (CTP) systems DETAILED DESCRIPTION OF THE have been developed and put into practical use, Which INVENTION imageWise exposes directly to a planographic printing plate material employing laser light based on digital image data to [0007] The present inventors have studied an extensive study. As a result, they have found that the preheating record an image on the material. As the CTP systems, there latitude is Widened by employing a speci?c anionic dye, are a silver salt system, a radical polymeriZation system and storage stability is greatly improved by employing eosin a thermal system, Which differ in characteristics. having a speci?c structure, and a combined use of a [0003] The radical polymeriZation system has character titanocene compound provides good preheating latitude as istics providing high sensitivity and high printing durability, Well as high sensitivity and printing durability, and com and is Widely applied in printing ?elds such neWspaper pleted the invention. Further, they have found that use of the printing. The general radical polymerization is disclosed in anionic dye in the invention provides a good running prop many literatures such as Japanese Patent O.P.I. Publication erty. No. 10-104835. A composition comprising an arene com [0008] The above object of the invention is attained by the pound as a polymeriZation initiator is disclosed in Japanese folloWing constitution. Patent O.P.I. Publication No. 1-152109. Japanese Patent Publication No. 2755723 discloses, as a composition pro [0009] 1. A planographic printing plate material compris viding high sensitivity and high printing durability, a pho ing a hydrophilic support and provided thereon, a light topolymeriZable composition Which comprises a polymer sensitive layer and an overcoat layer in that order, Wherein binder, a free-radical polymeriZable compound, a photore the light sensitive layer contains (a) an alkali soluble poly duction dye (photo-initiator), and a trihalomethyl compound mer, (b) a polymeriZable compound having an ethylenically and a metallocene compound as another photo-initiator, and unsaturated bond, (c) a polymeriZation initiator, and (d) an discloses in the examples a composition comprising an anionic dye represented by the folloWing formula (1), alcohol soluble eosin, a trihalomethyltriaZine, and a titanocene compound. Acomposition disclosed in this patent document provides excellent sensitivity and printing dura Formula (1) bility, Which is preferred, hoWever, a planographic printing plate material comprising the composition is greatly loWered in storage stability after long term storage, resulting in insuf?cient practical properties. [0004] The radical polymeriZation system generally employs a process comprising exposure, heat treatment, Water Washing, alkali development, and Water Washing in that order. This system is a preferred one to obtain high printing durability by completing the radical polymeriZation. HoWever, When printing plate materials having a different thickness Were processed, the printing plate materials are heated at preheating to different temperature due to the different thickness, producing problem of causing develop ment failure. As the countermeasure, an attempt has been made in Which arrangement of rollers in an automatic processing machine (automatic processor) or pre-determi [0010] Wherein R1 represents a substituted or unsubsti nation (provision) of preheating conditions to each plate tuted alkyl group having a carbon atom number of from 4 to 18, a cycloalkyl group having a carbon atom number of from thickness is examined. 4 to 18, or a substituted or unsubstituted aryl group having [0005] As an effective method to Widen the latitude as a carbon atom number of from 6 to 18; R2 through R11 printing plate materials to various preheating conditions, independently represent a hydrogen atom, a halogen atom, a US 2005/0048403 A1 Mar. 3, 2005 substituted or unsubstituted alkyl group having a carbon [0020] 10. The planographic printing plate material of atom number of from 1 to 6, a cycloalkyl group having a item 9 above, Wherein the light sensitive layer further carbon atom number of from 4 to 6, a substituted or contains a polyhalogenated compound as the polymeriZation unsubstituted aryl group having a carbon atom number of initiator. from 6 to 18 or —N(R12) (R13) in Which R12 and R13 independently represent a substituted or unsubstituted alkyl [0021] 11. The planographic printing plate material of group having a carbon atom number of from 1 to 6, a item 10 above, Wherein the polyhalogenated compound is a cycloalkyl group having a carbon atom number of from 4 to polyhalomethylsulfone, a polyhalomethyl oXadiaZole, or a 6, or a substituted or unsubstituted aryl group having a compound having a polyhaloacetyl structure represented by carbon atom number of from 6 to 18; and Y+ represents a the folloWing formula (2), hydrogen ion, an alkali metal ion or an onium ion. R21—CX2— (c:o) _R22 Formula (2) [0011] 2. The planographic printing plate material of item [0022] Wherein R21 represents a hydrogen atom, a bromine 1 above, Wherein the light sensitive layer contains a metal atom, a chlorine atom, an alkyl group, an aryl group, an acyl locene compound as the polymeriZation initiator. group, an alkylsulfonyl group, an arylsulfonyl group or a [0012] 3. The planographic printing plate material of item cyano group; R22 represents a hydrogen atom or a monova 2 above, Wherein the light sensitive layer further contains a lent organic substituent, provided that R21 and R22 may polyhalogenated compound as the polymeriZation initiator. combine With each other to form a ring; and X represents a bromine atom or a chlorine atom. [0013] 4. The planographic printing plate material of item 3 above, Wherein the polyhalogenated compound is a poly [0023] 12. The planographic printing plate material of any halomethylsulfone, a polyhalomethyl oXadiaZole, or a com one of items 8 through 11 above, Wherein the alkali soluble pound having a polyhaloacetyl structure represented by the polymer has a Weight average molecular Weight of from folloWing formula (2), 15,000 to 500,000, and an acid value of from 30 to 200. R21—CX2— (c:o) _R22 Formula (2) [0024] 13. The planographic printing plate material of any one of items 8 through 12 above, Wherein the alkali soluble [0014] Wherein R21 represents a hydrogen atom, a bromine polymer has repeating a monomer unit having an ethyleni atom, a chlorine atom, an alkyl group, an aryl group, an acyl cally unsaturated bond in an amount of from 5 to 50 mol % group, an alkylsulfonyl group, an arylsulfonyl group or a in the molecule. cyano group; R22 represents a hydrogen atom or a monova lent organic substituent, provided that R21 and R22 may [0025] 14. The planographic printing
Load more

Recommended publications
  • Assessment of New Persistent Organic Pollutants-Pesticides in Air
    ASSESSMENT OF NEW PERSISTENT ORGANIC POLLUTANTS-PESTICIDES IN AIR AND SOIL SAMPLES FROM SITES IN NAIROBI AND MOUNT KENYA BY JULIE KIDAHA (I56/68771/2011) A thesis submitted for Examination in partial fulfilment of the requirements for Award of the Degree of Master of Science in Environmental Chemistry of the University of Nairobi 2015 i DECLARATION I declare that this thesis is my original work and has not been submitted elsewhere for examination, award of a degree or publication. Where other people‟s work, or my own work has been used, this has properly been acknowledged and referenced in accordance with the University of Nairobi‟s requirements.. …………………………………. Date................ JULIE KIDAHA (156/68771/2011) This thesis has been submitted with our approval as university supervisors ……………………………………… Date................ Prof. Shem. O. Wandiga Department of Chemistry, University of Nairobi ………………………………………… Date................ Dr. Deborah A. Abong‟o Department Of Chemistry, University Of Nairobi ii DEDICATION I dedicate this work to my beloved children; Jeanne, Jael, Jerry and Josh. iii ACKNOWLEDGEMENTS My sincere gratitude goes to my supervisors Prof. Shem. O. Wandiga and Dr. Deborah A. Abong‟o for their intellectual input in this work. Their guidance and mentorship is highly appreciated. I am indebted to Dr. Vincent Madadi for his valuable comments that helped me shape my ideas. His selfless commitment in training me during sampling, sample preparation and analysis is highly appreciated. I am grateful to him for the supply of solvents used in this work. I acknowledge my employer, The Teachers‟ Service Commission for granting me study leave with pay. This went along way in ensuring that I met my financial obligations while studying.
    [Show full text]
  • Maria Goreti Da Silva Monteiro Prof. Doutora Maria Luísa Fernandes
    UNIVERSIDADE DE LISBOA FACULDADE DE LETRAS ÁREA DE LITERATURAS, ARTES E CULTURAS COMUNICAÇÃO EMPRESARIAL, INGLÊS E TRADUÇÃO: UM ESTUDO DO CORREIO ELECTRÓNICO EM EMPRESAS PORTUGUESAS DE MOLDES PARA PLÁSTICOS NO QUADRO DA GRAMÁTICA SISTÉMICO-FUNCIONAL Maria Goreti da Silva Monteiro Dissertação orientada pela Prof. Doutora Maria Luísa Fernandes Azuaga DOUTORAMENTO EM LINGUÍSTICA (Linguística Inglesa) 2010 Em memória de meus pais e de L. J. ii AGRADECIMENTOS O percurso de anos que conduz à conclusão de uma dissertação de doutoramento permite conviver com pessoas que ajudam a reflectir e materializar projectos iniciais, muitas vezes vagos e dispersos. As valiosas colaborações de um número dessas pessoas, bem como o seu incentivo e dedicação não podiam deixar de ser aqui e agora registadas. Agradeço à Prof. Doutora Luísa Azuaga, minha orientadora, em primeiro lugar, não apenas por acompanhar o meu trabalho desde o primeiro momento, mas também pelas palavras de encorajamento, essenciais para a conclusão de cada etapa. Agradeço, ainda, o seu convite para integrar a equipa de pesquisa do CEAUL, um local de estudo e, tão importante, de discussão de saberes. Ao mesmo tempo, não teria sido possível chegar a este ponto sem o apoio do IPL / ESTG, que proporcionou condições indispensáveis a uma maior dedicação ao doutoramento. Para tal, muito colaboraram a Coordenadora do Departamento de Ciências da Linguagem e todos os meus colegas, a quem agradeço de forma muito especial. Não posso deixar de lembrar que este estudo só foi exequível com o particular apoio das empresas que, por motivo de sigilo a elas devido, não são nomeadas, mas que têm a minha permanente gratidão.
    [Show full text]
  • Poly\Arylene Thioetherketone\Compositions Improved in Both Melt Stability and Crystallinity
    Europaisches Patentamt J European Patent Office CO Publication number: 0 296 877 Office europeen des brevets A2 EUROPEAN PATENT APPLICATION © Application number: 88305783.8 © int. Ci.4: C08K 5/00 , C08K 3/00 , C08L 81/02 @ Date of filing: 22.06.88 Priority: 22.06.87 JP 154801/87 © Applicant: KUREHA KAGAKU KOGYO 03.09.87 JP 221122/87 KABUSHIKI KAISHA 11.06.88 JP 142772/88 1-9-11, Nihonbashi, Horidome-cho Chuo-ku Tokyo 103(JP) Date of publication of application: 28.12.88 Bulletin 88/52 @ Inventor: Satake, Yoshikatsu 1-6, Ochiai Nishiki-machi Designated Contracting States: Iwaki-shi Fukushima-ken 974(JP) AT BE CH DE ES FR GB GR IT LI LU NL SE Inventor: Kashiwadate, Ken 108-3, Asahidai Kanayama-machi Iwaki-shi Fukushima-ken 974(JP) Inventor: lizuka, Yo 1-36-10, lino Chuodai Iwaki-shi Fukushima-ken 970(JP) Inventor: Katto, Takayuki 1-1-5, Nakaoka-machi Iwaki-shi Fukushima-ken 974(JP) Inventor: Shiiki, Zenya 28-1, Ochiai Nishiki-machi Iwaki-shi Fukushima-ken 974(JP) Inventor: Kouyama, Toshitaka 4-2-12, Nakaoka-machi Iwaki-shi Fukushima-ken 974(JP) ® Representative: Jones, Helen M.M. et al Gill Jennings & Every 53-64 Chancery Lane London WC2A1HN(GB) ® Poly(arylene thioetherketone)compositions improved in both melt stability and crystallinity. CN ^© Disclosed herein is a poly(arylene thioether-ketone) composition improved in melt stability and crystallinity, 1^ which comprises (A) 100 parts by weight of a melt-stable poly(arylene thioether-ketone) (PTK) and (B) 0.1-30 fS parts by weight of at least one basic compound selected from the group consisting of the hydroxides, oxides 00 and aromatic carboxylic acid salts of Group IIA metals of the periodic table other than magnesium and the {Qhydrocarbyl oxides, aromatic carboxylic acid salts, carbonates, hydroxides, phosphates and borates of Group IA G) metals of the periodic table.
    [Show full text]
  • In Four Polar Bears (Ursus Maritimus) That Swam Malnourished from East Greenland to Iceland
    Science of the Total Environment 533 (2015) 290–296 Contents lists available at ScienceDirect Science of the Total Environment journal homepage: www.elsevier.com/locate/scitotenv Polyhalogenated compounds (PCBs, chlordanes, HCB and BFRs) in four polar bears (Ursus maritimus) that swam malnourished from East Greenland to Iceland Walter Vetter a,⁎, Vanessa Gall a, Karl Skírnisson b a University of Hohenheim, Institute of Food Chemistry, Garbenstr. 28, D-70593 Stuttgart, Germany b University of Iceland, Keldur, Institute for Experimental Pathology, IS-112 Reykjavík, Iceland HIGHLIGHTS GRAPHICAL ABSTRACT • Four polar bears swam in malnourished condition from East-Greenland to Iceland. • Organohalogen compounds (PCBs, chlor- dane, PBBs, PBDEs, HCB) were quantified. • Dec-602 was tentatively identified in all tissues and an unknown compound in liver. article info abstract Article history: Levels of organohalogen compounds (PCBs, chlordane, PBB 153, PBDEs, HCB) were determined in adipose tissue, Received 24 March 2015 liver, kidney and muscle of four polar bears which swam and/or drifted to Iceland in extremely malnourished Received in revised form 2 July 2015 condition. Since the colonization in the 9th century polar bears have been repeatedly observed in Iceland. Accepted 3 July 2015 However, in recent years three of the animals have clearly left their natural habitat in poor condition in May or Available online xxxx June, i.e. at the end of the major feeding season. The fourth bear is believed to have drifted with melting ice to Editor: D. Barcelo North-Eastern Iceland in mid-winter. The concentrations of the POPs were within the range or higher than the typical concentrations measured in polar bears from the East Greenland population.
    [Show full text]
  • Emerging Cont Emerging Contaminants in Ganga River Basin
    Report Code: 013_GBP_IIT_EQP_SOA_02_Ver 1_Dec 2011 Emerging Contaminants in Ganga River Basin with Special Emphasis on Pesticides GRB EMP : Ganga River Basin Environment Management Plan by Indian Institutes of Technology IIT IIT IIT IIT IIT IIT IIT Bombay Delhi Guwahati Kanpur Kharagpur Madras Roorkee Report Code: 013_GBP_IIT_EQP_SOA_02_Ver 1_Dec 2011 2 | P a g e Report Code: 013_GBP_IIT_EQP_SOA_02_Ver 1_Dec 2011 Preface In exercise of the powers conferred by sub-sections (1) and (3) of Section 3 of the Environment (Protection) Act, 1986 (29 of 1986), the Central Government has constituted National Ganga River Basin Authority (NGRBA) as a planning, financing, monitoring and coordinating authority for strengthening the collective efforts of the Central and State Government for effective abatement of pollution and conservation of the river Ganga. One of the important functions of the NGRBA is to prepare and implement a Ganga River Basin: Environment Management Plan (GRB EMP). A Consortium of 7 Indian Institute of Technology (IIT) has been given the responsibility of preparing Ganga River Basin Environment Management Plan (GRBEMP) by the Ministry of Environment and Forests (MoEF), GOI, New Delhi. Memorandum of Agreement (MoA) has been signed between 7 IITs (Bombay, Delhi, Guwahati, Kanpur, Kharagpur, Madras and Roorkee) and MoEF for this purpose on July 6, 2010. This report is one of the many reports prepared by IITs to describe the strategy, information, methodology, analysis and suggestions and recommendations in developing Ganga River Basin: Environment Management Plan (GRB EMP). The overall Frame Work for documentation of GRBMP and Indexing of Reports is presented on the inside cover page. There are two aspects to the development of GRB EMP.
    [Show full text]
  • (12) United States Patent (10) Patent No.: US 6,548,240 B2 Yamaguchi (45) Date of Patent: Apr
    USOO654824OB2 (12) United States Patent (10) Patent No.: US 6,548,240 B2 Yamaguchi (45) Date of Patent: Apr. 15, 2003 (54) PHOTOTHERMOGRAPHIC MATERIAL 6,060,228 A 5/2000 Suzuki ....................... 430/522 6,190,854 B1 * 2/2001 Sampei....................... 430/617 (75) Inventor: Tetsuo Yamaguchi, Kanagawa (JP) * cited by examiner (73) Assignee: Fuji Photo Film Co., Ltd., Kanagawa Primary Examiner Thorl Chea (JP) (74) Attorney, Agent, or Firm-Birch, Stewart, Kolasch & (*) Notice: Subject to any disclaimer, the term of this Birch, LLP patent is extended or adjusted under 35 (57) ABSTRACT U.S.C. 154(b) by O. davs. (b) by y Disclosed is a photothermographic material containing a non-photoSensitive Silver Salt, a photosensitive Silver halide (21) Appl. No.: 09/962,449 and a binder on a Support, which comprises a nucleating (22) Filed: Sep. 26, 2001 agent and a Surfactant represented by the following formula (65) Prior Publication Data US 2003/0008251A1 Jan. 9, 2003 Rf-(Rc)nm-Z Formula (F): (30) Foreign Application Priority Data wherein Rf represents a perfluoroalkyl group, Rc represents an alkylene group, and Z represents a group having an Sep. 27, 2OOO (JP) - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 2OOO-293867 anionic grOup, cationic grOup, betaine group or nonionic (51) Int. Cl." ................................................ G03C 11498 group required for imparting Surface activity, n is 0 or 1 and (52) U.S. Cl. ........................ 430/619, 430/598; 430/631 m is 1, 2 or 3. According to the present invention, there is (58) Field of Search ................................. 430/619, 264, provided a photothermographic material, in particular, for photomechanical processes, more specifically, for Scanners 430/631,598 and image Setters, which shows low fog and high Dmax References Cited (maximum density), and exhibits little increase of fog even (56) after the photoSensitive material after development is Stored U.S.
    [Show full text]
  • Kinetic Analysis for Low Temperature Catalytic Hydro De-Chlorination Of
    Kinetic analysis for low temperature catalytic hydro de-chlorination of PCBs (poly-chlorinated biphenyls) A thesis submitted to the Graduate School of the University of Cincinnati in partial fulfillment of the requirements for the degree of Master of Science in Material Science and Engineering at the Department of Mechanical and Materials Engineering of the College of Engineering and Applied Sciences by Akshay Anil Khopade B.E Polymer Engineering University of Pune, 2014 at March 2019 Committee Members: Mingming Lu, PhD (Chair) Gregory Beaucage, PhD Mark Wang, PhD Fumin Ren, PhD ABSTRACT The environmental report published by the United Nations in 2018 paints a very grim picture of our environmental health around the world. Persistent organic pollutants (POPs) like polychlorinated biphenyls (PCBs) are one of the major causes of this environmental degradation. The Stockholm Convention is a global treaty that seeks to contain additional contamination of environment with POPs and, wherever feasible, remediate the contamination that has already occurred. Although the production of PCBs has been banned around the world, affordable and effective PCB cleanup technologies are still in high demand, as existing treatment technologies are very costly. The project studies a low temperature removal technology using catalytic hydrogenation. Two types of PCBs were studied in a flask system, 3 PCB and 2, 3 PCB. The catalyst studied for the hydro de-chlorination reaction is palladium on activated carbon and triethylamine (Pd/C and Et3N). Parameters such as reaction time, gas flow rate and catalyst dose were investigated. In addition, the kinetics of the hydro de-chlorination reactions were studied, which is essential in large scale commercial applications.
    [Show full text]
  • Curable Composition Härtbare Zusammensetzung Composition Durcissable
    (19) TZZ_Z¥Z_T (11) EP 1 036 807 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) Int Cl.: of the grant of the patent: C08G 65/32 (2006.01) C08L 83/04 (2006.01) 12.12.2007 Bulletin 2007/50 C08G 65/336 (2006.01) C08L 71/02 (2006.01) (21) Application number: 00400747.2 (22) Date of filing: 17.03.2000 (54) Curable composition Härtbare Zusammensetzung Composition durcissable (84) Designated Contracting States: • Kawakubo, Fumio BE CH DE FR GB LI NL Hyogo 654-0151 (JP) (30) Priority: 18.03.1999 JP 7322499 (74) Representative: Hubert, Philippe et al Cabinet Beau de Loménie (43) Date of publication of application: 158, rue de l’Université 20.09.2000 Bulletin 2000/38 75340 Paris Cédex 07 (FR) (73) Proprietor: KANEKA CORPORATION (56) References cited: Osaka-shi, Osaka 530-8288 (JP) EP-A- 0 397 036 EP-A- 0 532 049 EP-A- 0 584 978 EP-A- 0 829 504 (72) Inventors: EP-A- 0 844 266 WO-A-00/40654 • Odaka, Hidetoshi Hyogo 676-0026 (JP) • PATENT ABSTRACTS OF JAPAN vol. 1998, no. • Kanamori, Yuka 03, 27 February 1998 (1998-02-27) & JP 09 296046 Hyogo 673-0018 (JP) A (SANYO CHEM IND LTD), 18 November 1997 • Ito, Hiroshi (1997-11-18) Hyogo 676-0026 (JP) • Jyono, Hideharu Remarks: Hyogo 655-0872 (JP) Thefilecontainstechnicalinformationsubmittedafter • Iwakiri, Hiroshi the application was filed and not included in this Hyogo 651-2277 (JP) specification Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted.
    [Show full text]
  • High Levels of Halogenated Natural Products in Large Pelagic Fish from the Western Indian Ocean
    Environmental Science and Pollution Research https://doi.org/10.1007/s11356-021-14738-0 RESEARCH ARTICLE High levels of halogenated natural products in large pelagic fish from the Western Indian Ocean Qiong Wu1 & Catherine Munschy2 & Yann Aminot2 & Nathalie Bodin3,4,5 & Walter Vetter1 Received: 31 July 2020 /Accepted: 1 June 2021 # The Author(s) 2021 Abstract Concentrations, profiles and muscle-liver distribution of halogenated natural products (HNPs) and anthropogenic persistent organic pollutants (POPs) were investigated in five large pelagic fish species and one smaller planktivore fish species from the Western Indian Ocean. Analysis of swordfish muscle from the Seychelles revealed the predominance of HNPs, with the highest concentrations found for 2′-methoxy-2,3′,4,5′- tetraBDE (2′-MeO-BDE 68 or BC-2), 6-methoxy-2,2′,4,4′-tetraBDE(6-MeO- BDE 47 or BC-3) and 2,3,3′,4,4′,5,5′-heptachloro-1′-methyl-1,2′-bipyrrole (Q1), along with varied contributions of further HNPs. The mean concentration of ∑HNPs (330 ng/g lw) was one or two orders of magnitude higher than ∑DDTs (60 ng/g lw) and ∑PCBs (6.8 ng/g lw). HNPs (BC-2, BC-3 and Q1) were also predominant in individual samples of three tropical tuna species from the Seychelles and from other regions of the Western Indian Ocean (Mozambique Channel, off Somalia and Chagos Archipelago). Non-targeted gas chromatography coupled with electron capture negative ion mass spectrometry operated in the selected ion monitoring mode (GC/ECNI-MS-SIM) analysis of one swordfish sample indicated low abundance of rarely reported HNPs (three hexachloro-1′-methyl-1,2′-bipyrrole (Cl6-MBP) isomers and pentabromo-1,1′-dimethyl-2,2′-bipyrroles (Br5-DBP)) but no further abundant unscreened polyhalogenated compounds.
    [Show full text]
  • Program Booklet
    Table of Contents Schedule of Events Symposium Schedule of Events ............................................................ 3 Undergraduate Research and Scholarship Symposium Undergraduate Speakers and Presentation Schedule ........................... 4 Awards ................................................................................................... 6 March 30th, 2011 – Power Center Ballroom Keynote Speaker Biography ................................................................... 7 Abstracts ................................................................................................ 8 Acknowledgements Student set up 8:00 am – 9:00 am Continental breakfast for participants The organizers would like to thank all of the Faculty Mentors and Advisors for their unselfish service to and support of our 9:00 am Doors open to the public undergraduate scholars. 9:00 - 10:00 am Formal Presentations Session 1 This symposium would not have been possible without the hard work and diligence of the Undergraduate Organizing Committee members. Informal Poster Session 10:00 am - 11:00 am Guests are invited to walk around, peruse Kristen Friedrich – Chair student projects, and engage with the Josh Koslosky students Kait Wolf 11:00am – 12:00 pm Formal Presentation Session 2 Devin Bowen Jonathon Scott Break for Lunch 12:00 pm – 1:00pm Justin Stadelmyer Boxed lunch provided for participants Matthew Taylor Eddie Strauser Keynote Speaker Ashley Biernesser 1:00 pm – 2:00 pm Dean Christopher Duncan McAnulty College & Graduate School The organizing
    [Show full text]
  • State of the Cetacean Environment Report (SOCER) Global Compendium 2014 - 2018 Produced by the IWC Secretariat
    State of the Cetacean Environment Report (SOCER) Global Compendium 2014 - 2018 Produced by the IWC Secretariat The International Whaling Commission (IWC) The Red House, 135 Station Road, Impington, Cambridge, CB24 9NP United Kingdom www.iwc.int The cover image merges two photographs: Antarctica and Morocco. IWC SOCER GLOBAL COMPENDIUM 2014 - 2018 3 State of the Cetacean Environment Report (SOCER) Global Compendium 2014 - 2018 Editors: M. Stachowitsch*1, N.A. Rose¥2 and E.C.M. Parsons+3 Introduction The conservation status of cetaceans and the roles they play in their ecosystems can be understood only in the framework of the environments they inhabit. Those environments range from the open ocean to shallow coastal areas to freshwater rivers and lakes: all are undergoing rapid, primarily anthropogenically driven change. The multitude of threats, their severity and their ubiquity have shifted the topic of environmental concerns from a lower-level ranking in the International Whaling Commission’s Scientific Committee deliberations to a central hub interlinking every issue. Whether the topic be quota calculations, survey frequencies, whale watching or small cetaceans, all are influenced by the state of the respective species’ environment. The State of the Cetacean Environment Report (SOCER) is one part of the IWC’s effort to reflect this insight. The mission, based on a Commission Resolution in 1997 (IWC, 1998), has been to provide a non-technical summary of the most recently published research, legislation and other relevant developments. The focus is on the marine and certain freshwater environments, not necessarily directly on cetaceans per se. Nearly 1000 entries since 2003 (Stachowitsch et al., 2003) have provided updates on habitat degradation (including issues such as marine debris and ship strikes), chemical pollution, disease, noise impacts and mortality events (such as after oil spills).
    [Show full text]
  • Ep 1134611 A2
    Europäisches Patentamt *EP001134611A2* (19) European Patent Office Office européen des brevets (11) EP 1 134 611 A2 (12) EUROPEAN PATENT APPLICATION (43) Date of publication: (51) Int Cl.7: G03C 1/498 19.09.2001 Bulletin 2001/38 (21) Application number: 01106357.5 (22) Date of filing: 16.03.2001 (84) Designated Contracting States: (71) Applicant: FUJI PHOTO FILM CO., LTD. AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU Kanagawa-ken, 250-0193 (JP) MC NL PT SE TR Designated Extension States: (72) Inventors: AL LT LV MK RO SI • Oya, Toyohisa, Fuji Photo Film Co., Ltd. Kanagawa 250-0193 (JP) (30) Priority: 17.03.2000 JP 2000076016 • Katoh, Kazunobu, Fuji Photo Film Co., Ltd. 17.03.2000 JP 2000076053 Kanagawa 250-0193 (JP) 17.03.2000 JP 2000076141 • Hirano, Shigeo, Fuji Photo Film Co., Ltd. 17.03.2000 JP 2000076173 Kanagawa 250-0193 (JP) 27.03.2000 JP 2000085810 01.05.2000 JP 2000132181 (74) Representative: HOFFMANN - EITLE 01.05.2000 JP 2000132270 Patent- und Rechtsanwälte Arabellastrasse 4 81925 München (DE) (54) Photothermographic material and method for forming images (57) A photothermographic material comprising at resents a substituted or unsubstituted alkyl group, aryl least (a) a photosensitive silver halide, (b) a reducible group or heterocyclic group: silver salt, (c) a reducing compound represented by the following formula (1) or (2), (d) a binder and (e) a coupler 1 6 compound on the same side of a support: Q -NHNH-V (2) wherein, in the formula (2), Q1 represents a 5- to 7-mem- bered unsaturated ring bonding to NHNH-V6 at a carbon atom, and V6 represents a carbamoyl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfamoyl group.
    [Show full text]