Xile Hu – Curriculum Vitae
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Small Molecule Activation at Uranium Coordination Complexes: Control of Reactivity Via Molecular Architecture
FEATURE ARTICLE www.rsc.org/chemcomm | ChemComm Small molecule activation at uranium coordination complexes: control of reactivity via molecular architecture Ingrid Castro-Rodrı´gueza and Karsten Meyer{*b Received (in Cambridge, UK) 27th September 2005, Accepted 15th November 2005 First published as an Advance Article on the web 24th January 2006 DOI: 10.1039/b513755c Electron-rich uranium coordination complexes display a pronounced reactivity toward small molecules. In this Feature article, the exciting chemistry of trivalent uranium ions coordinated to classic Werner-type ligand environments is reviewed. Three fundamentally important reactions of R the [(( ArO)3tacn)U]-system are presented that result in alkane coordination, CO/CO2 activation, and nitrogen atom-transfer chemistry. Introduction Historically, this is not surprising considering that until fairly recently, synthetic access to uranium(III) coordination From a synthetic chemist’s perspective, it is rather remarkable compounds was restricted due to lack of suitable starting that after fifty years of synthetic organometallic actinide i-Pr 3 materials. With the exception of homoleptic [( ArO)3U] and research, much is still unknown about the non-aqueous its derivatives,4 it was not until Clark and Sattelberger’s inorganic coordination chemistry of low-valent uranium.1,2 synthesis of the solvated trivalent [UI3L4] (L = THF and 5 aDepartment of Chemistry, University of California, Latimer Hall, DME) and the solvent-free [((Me3Si)2N)3U] complexes Berkeley, California, 94720, USA. E-mail: [email protected]; reported in a 1997 issue of Inorganic Synthesis that coordina- Tel: +1 510 642 2516 tion chemists finally had a synthetic protocol.6–9 This provided bDepartment of Chemistry and Biochemistry, University of California @ San Diego, 9500 Gilman Drive MC 0358, La Jolla, California, 92093- a convenient and highly reproducible entry into the exciting 0358, USA world of trivalent uranium chemistry. -
DANIEL J. MINDIOLA Professor (W/Tenure), Department Of
Updated 7/26/18 DANIEL J. MINDIOLA Professor (w/tenure), Department of Chemistry, University of Pennsylvania Email: [email protected] Phone: (215) 898-5247 FAX: (215) 573-9711 Webpage: http://mindiolagroup.chem.upenn.edu/ Born in 1974. Education Ph.D. August 2000 Massachusetts Institute of Technology, Cambridge, MA – Ph.D. in Chemistry, (Advisor Christopher C. Cummins) Thesis Title: Thesis Title: “Arene Extrusion Reactions and Synthesis and Reactivity Studies of Complexes Supported by Sterically Demanding Anilide Ligands.” (Dissertation Committee: C. C. Cummins, R. R. Schrock, and D. Seyferth) B.S. May 1996 Michigan State University, College of Natural Science, East Lansing, MI – B.S. in Chemistry with honors (Undergraduate Mentor: Prof. Kim R. Dunbar) Research Experience August 1- Brush Family Chair Professor, University of Pennsylvania, present Philadelphia, PA. 2017-2018 Visiting Professor, State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai, China (1 month) 2016-2017 Visiting Professor, KAIST, Daejeon, Republic of Korea. July. 1, 2013- Presidential Chair Professor of Chemistry, University of Pennsylvania, 2018 Philadelphia, PA. 2010-2013 Department of Chemistry, Indiana University. Full Professor. May 2012 Visiting Professor, Japan Society for the Promotion of Science (JSPS), Japan. 2009-2010 Visiting Professor, Friedrich-Alexander Universität, Erlangen-Nürnberg, Germany. 2007-2010 Department of Chemistry, Indiana University. Associate Professor with tenure. 2002-2007 Department of Chemistry, Indiana University. Assistant Professor. 2000-2002 Department of Chemistry, University of Chicago. Postdoctoral Research Fellow under the direction of Prof. Gregory L. Hillhouse. Metal mediated N2O reductions and synthesis and reactivity studies of group 10 metal-ligand multiple bonds. 1996-2000 Department of Chemistry, Massachusetts Institute of Technology. -
DANIEL J. MINDIOLA Professor (W/Tenure
Updated 7/5/18 DANIEL J. MINDIOLA Professor (w/tenure), Department of Chemistry, University of Pennsylvania Email: [email protected] Phone: (215) 898-5247 FAX: (215) 573-9711 Webpage: http://mindiolagroup.chem.upenn.edu/ Born in 1974. Education Ph.D. August 2000 Massachusetts Institute of Technology, Cambridge, MA – Ph.D. in Chemistry, (Advisor Christopher C. Cummins) Thesis Title: Thesis Title: “Arene Extrusion Reactions and Synthesis and Reactivity Studies of Complexes Supported by Sterically Demanding Anilide Ligands.” (Dissertation Committee: C. C. Cummins, R. R. Schrock, and D. Seyferth) B.S. May 1996 Michigan State University, College of Natural Science, East Lansing, MI – B.S. in Chemistry with honors (Undergraduate Mentor: Prof. Kim R. Dunbar) Research Experience July 1-present Brush Family Chair Professor, University of Pennsylvania, Philadelphia, PA. 2017-2018 Visiting Professor, State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai, China (1 month) 2016-2017 Visiting Professor, KAIST, Daejeon, Republic of Korea. July. 1, 2013- Presidential Chair Professor of Chemistry, University of Pennsylvania, 2018 Philadelphia, PA. 2010-2013 Department of Chemistry, Indiana University. Full Professor. May 2012 Visiting Professor, Japan Society for the Promotion of Science (JSPS), Japan. 2009-2010 Visiting Professor, Friedrich-Alexander Universität, Erlangen-Nürnberg, Germany. 2007-2010 Department of Chemistry, Indiana University. Associate Professor with tenure. 2002-2007 Department of Chemistry, Indiana University. Assistant Professor. 2000-2002 Department of Chemistry, University of Chicago. Postdoctoral Research Fellow under the direction of Prof. Gregory L. Hillhouse. Metal mediated N2O reductions and synthesis and reactivity studies of group 10 metal-ligand multiple bonds. 1996-2000 Department of Chemistry, Massachusetts Institute of Technology. -
Prof. Dr. Karsten Meyer, FRSC
Prof. Dr. Karsten Meyer, FRSC Karsten Meyer studied chemistry (October 1989 – 1994) at the Ruhr-University of Bochum (Germany) and received his Diploma in May 1995. Starting in summer 1995, he performed his PhD thesis work under the direction of Professor Karl Wieghardt at the Max-Planck-Institute in Mülheim / Ruhr (Germany) and received his Ph. D. (Dr. rer. nat, summa cum laude) in January 1998. With a DFG postdoctoral fellowship, Karsten proceeded to gain research experience in the laboratory of Professor Christopher Cummins at the Massachusetts Institute of Technology (1998 – 2000, MIT, Cambridge, MA, USA). In January 2001, he was appointed to the faculty of the University of California, San Diego (UCSD) as an Assistant Professor and was named an Alfred P. Sloan Fellow in 2004. In 2006 he accepted an offer (C4/W3) to be the Chair of the Institute of Inorganic & General Chemistry at the Friedrich-Alexander- University of Erlangen-Nürnberg (FAU), Germany. Professional Career Oct. 1989 Study of Chemistry at the Ruhr-University-Bochum in Germany May 1995 Diploma (Ruhr-University-Bochum) July 1995 PhD Studies at the Max-Planck-Institute in Mülheim/Ruhr, Germany under the supervision of Prof. Dr. Karl Wieghardt Jan. 1998 Dissertation (Dr. rer. nat., summa cum laude) “Molecular and Electronic Structure of High-Valent Transition-Metal Nitrido Complexes” Feb. 1998 Postdoctoral Studies at the Max-Planck-Institute Mülheim/Ruhr (Germany) Oct. 1998 Postdoctoral Studies at the Massachusetts Institute of Technology (MIT) under the direction of Prof. Christopher C. Cummins, USA Jan. 2001 Assistant Professor at the University of California, San Diego (UCSD), USA Jan. -
Xile Hu – Curriculum Vitae
Xile Hu – Curriculum Vitae Date of Birth: August 7, 1978 Address: École Polytechnique Fédérale de Lausanne Institute of Chemical Sciences and Engineering Laboratory of Inorganic Synthesis and Catalysis EPFL-SB-ISIC, BCH 3305 CH 1015 Lausanne, Switzerland Telephone: +41 (0)21 693 97 81 Fax: +41 (0)21 693 93 05 E-mail: [email protected] Website: http://lsci.epfl.ch RESEARCH TOPICS Our main research goal is to develop catalysts composed of earth-abundant elements for chemical transformations of relevance to synthesis, energy, and sustainability. Current research topics include: (i) Base metal catalysis for organic synthesis (ii) Bio-mimetic and bio-inspired chemistry of redox active enzymes (iii) Inexpensive and scalable inorganic catalysts for water splitting and CO2 reduction; solar fuels EDUCATION Postdoc., California Institute of Technology, USA, February 2005 – June 2007. Advisor: Prof. Jonas C. Peters Ph.D. in Chemistry, University of California, San Diego, USA, December 2004. Advisor: Prof. Karsten Meyer M.S. in Chemistry, University of California, San Diego, USA, June 2002. Advisor: Prof. Karsten Meyer B.S. in Chemistry, Peking University, Beijing, P. R. China, June 2000. Advisor: Prof. Jianhua Lin AWARDS AND HONORS (independent career) 2019 Fellow, European Academy of Sciences 2019 Royal Society of Chemistry Homogeneous Catalysis Award 2018 Resonate Award, Caltech 2017 National Latsis Prize, Swiss National Science Foundation and the Latsis Foundation 2017, 18 Highly Cited Researcher (Web of Science, Clarivate Analytics) 2017 Tajima -
Page 1 of 2 05. 2019 Xile Hu (胡喜示) – Short CV Date of Birth: August 7
Xile Hu (胡喜乐) – Short CV Date of Birth: August 7, 1978 E-mail: [email protected] Website: http://lsci.epfl.ch Academic position June 2016 – present, Full Professor of Chemistry, École Polytechnique Fédérale de Lausanne, Switzerland. January 2013 – May 2016, Associate Professor of Chemistry, EPFL. July 2007 – December 2012, Assistant Professor of Chemistry, EPFL. Education Postdoc., California Institute of Technology, USA, February 2005 – June 2007. Advisor: Prof. Jonas C. Peters Ph.D. in Chemistry, University of California, San Diego, USA, December 2004. Advisor: Prof. Karsten Meyer B.S. in Chemistry, Peking University, Beijing, P. R. China, June 2000. Advisor: Prof. Jianhua Lin Awards and honors (from independent career) 2019 Royal Society of Chemistry Homogeneous Catalysis Award 2018 Resonate Award, Caltech 2017 National Latsis Prize, Swiss National Science Foundation and the Latsis Foundation 2017, 18 Highly Cited Researcher (Web of Science, Clarivate Analytics) 2017 Tajima Prize, International Society of Electrochemistry 2017 Organic Letters Outstanding Publication of the Year Lectureship Award, ACS 2016,18 European Research Council (ERC) Proof-of-Concept Grant 2016 Bau Family Award in Inorganic Chemistry 2015 European Research Council (ERC) Consolidator Grant 2015 Outstanding Reviewer Award, Wiley-VCH, ChemPubSoc Europe, ACES 2015 Young Researcher Award, European Federation of Catalysis Societies 2014 Fellow, Royal Society of Chemistry (UK) 2014 European Medal for Bio-Inorganic Chemistry (Eurobic Medal) 2014 Organometallics Young Investigator