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Noncovalent Bonds Through Sigma and Pi-Hole Located on the Same Molecule. Guiding Principles and Comparisons
molecules Review Noncovalent Bonds through Sigma and Pi-Hole Located on the Same Molecule. Guiding Principles and Comparisons Wiktor Zierkiewicz 1,* , Mariusz Michalczyk 1,* and Steve Scheiner 2 1 Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeze˙ Wyspia´nskiego27, 50-370 Wrocław, Poland 2 Department of Chemistry and Biochemistry, Utah State University Logan, Logan, UT 84322-0300, USA; [email protected] * Correspondence: [email protected] (W.Z.); [email protected] (M.M.) Abstract: Over the last years, scientific interest in noncovalent interactions based on the presence of electron-depleted regions called σ-holes or π-holes has markedly accelerated. Their high directionality and strength, comparable to hydrogen bonds, has been documented in many fields of modern chemistry. The current review gathers and digests recent results concerning these bonds, with a focus on those systems where both σ and π-holes are present on the same molecule. The underlying principles guiding the bonding in both sorts of interactions are discussed, and the trends that emerge from recent work offer a guide as to how one might design systems that allow multiple noncovalent bonds to occur simultaneously, or that prefer one bond type over another. Keywords: molecular electrostatic potential; halogen bond; pnicogen bond; tetrel bond; chalcogen bond; cooperativity Citation: Zierkiewicz, W.; Michalczyk, M.; Scheiner, S. Noncovalent Bonds through Sigma and Pi-Hole Located on the Same 1. Introduction Molecule. Guiding Principles and The concept of the σ-hole, introduced to a wide audience in 2005 at a conference in Comparisons. Molecules 2021, 26, Prague by Tim Clark [1], influenced a way of thinking about noncovalent interactions 1740. -
Socit Chimique De France 2014 Prize Winners
Angewandte. Angewandte News Chemie Socit Chimique de France 2014 Prize Nazario Martn (Universidad Complutense de Winners Madrid) is the winner of the Prix franco-espagnol Awarded … Miguel Cataln–Paul Sabatier. Martn was featured The Socit Chimique de France has announced its here when he was awarded the 2012 EuCheMS 2014 prize winners. We congratulate all the awar- Lectureship.[4a] Martn is on the International dees and feature our authors and referees here. Advisory Boards of Chemistry—An Asian Journal, Max Malacria (Institut de Chimie des Substan- ChemPlusChem, and ChemSusChem. His report on ces Naturelles; ICSN) is the winner of the Prix modified single-wall nanotubes was recently fea- Joseph Achille Le Bel, which is awarded to tured on the cover of Chemistry—A European recognize internationally recognized research. Mal- Journal.[4b] acria studied at the Universit Aix-Marseille III, Michael Holzinger (Universit Joseph Four- where he completed his PhD under the supervision nier, Grenoble 1; UJF) is the winner of the Prix M. Malacria of Marcel Bertrand in 1974. From 1974–1981, he jeune chercheur from the Analytical Chemistry was matre-assistant with Jacques Gore at the Division. Holzinger carried out his PhD at the Universit Claude Bernard Lyon 1 (UCBL), and Friedrich-Alexander-Universitt Erlangen-Nrn- from 1981–1983, he carried out postdoctoral berg. After postdoctoral research at the Universit research with K. Peter C. Vollhardt at the Univer- Montpellier 2 (UM2) and the Max Planck Institute sity of California, Berkeley. He returned to the for Solid-State Research, and working at Robert UCBL as matre de conferences in 1983, and was Bosch, he joined Serge Cosniers group at the UJF made professor at the Universit Pierre et Marie as a CNRS charg de recherche. -
The Publications Files/27 Photopharmacology
Minireviews ChemPhotoChem doi.org/10.1002/cptc.202100001 1 Very Important Paper 2 3 The Issue of Tissue: Approaches and Challenges to the 4 5 Light Control of Drug Activity 6 [a] [a] 7 Mayank Sharma and Simon H. Friedman* 8 9 10 Many of the major challenges associated with drug delivery can modulate drug release. Because of these and other advantages, 11 potentially be addressed by linking drug action to light a range of mechanisms for using light to manipulate drug 12 irradiation. These challenges include the spacing, timing and activity has been developed, including photocleavage control, 13 amount of a drug’s activity. Once a drug’s activity is linked to photoconformational control, photothermal control and photo- 14 light, this activity can be more easily manipulated, because light degradation control. These major themes of light control will be 15 itself is easy to manipulate. One of the main issues that light described in this minireview, and illustrated with examples. In 16 control can address is off-target toxicity. This has the potential addition, the issue of tissue light permittivity, arguably the 17 to be limited if drugs are activated only in target tissues using major challenge for the discipline, will be described and 18 light. For drugs that are needed at varying concentrations analyzed. 19 through the day, varying light has the potential to temporally 20 21 22 1. Introduction larger community of researchers using light to manipulate 23 biological phenomena. 24 Light is a powerful chemical reagent: Where light goes, when it 25 is applied, and the amount of light delivered are all factors that 26 are relatively easy to regulate. -
Spotlights on Our Sister Journals: Chemistryopen 5
On these pages, we feature aselection computer,click on any of the items to of the excellent work that has recently read the full article. Otherwise please been published in our sister journals. see the DOIs for easy online access If you are reading these pages on a through Wiley Online Library. Iodine Adducts A. Reinholdt, T. Vosch, J. Bendix* Modification of s-Donor Properties of TerminalCarbideLigands Investigated Through Carbide–Iodine AdductFormation To give and take:terminal ruthenium carbidecomplexes [(Cy P) X Ru C] (1;X= halide or pseudohalide), form charge-transfer 3 2 2 adducts with I2 exhibitinglarge variation in bond lengths and stretching frequencies. This showsthat the auxiliary ligand sphere on rutheniumenables control over the s-donor properties of car- bide ligands, elucidating their isolobal relationship with carbon monoxide. Angew.Chem. Int. Ed. DOI: 10.1002/anie.201606551 Density Functional Theory J. I. Schweizer, L. Meyer,A.Nadj, M. Diefenbach, M. C. Holthausen* Unraveling the Amine-Induced Disproportionation Reaction of Perchlorinated Silanes—A DFT Study Aneo twist:ADFT study on the amine-induceddisproportionation reactionofSi2Cl6 to neo-Si5Cl12 discloses astepwise rather than a concerted silylene insertion mechanism, which was generally ac- cepted for over half acentury. The resulting pictureappears gener- alizabletothe relatedchloride-induced chemistry recently explored (see graphic). Chem. Eur.J. DOI: 10.1002/chem.201602724 Aza-Diels–Alder Reactions Y. Kumatabara, S. Kaneko, S. Nakata,S.Shirakawa,* K. Maruoka Hydrogen-BondingCatalysis of TetraalkylammoniumSalts in an Aza-Diels–Alder Reaction Under observation:Apiperidine-derived tetraalkylammoniumsalt with anon-coordinating counteranion worked as an effective hydro- gen-bonding catalyst in an aza-Diels–Alder reactionofimines anda Danishefskydiene. -
Annual Report: CY2018 Chempubsoc Europe
1 Annual Report: CY2018 ChemPubSoc Europe Growth, change, awards, and sponsorship More scientists, more publications, more competition. As in the past, growth continued unabated worldwide in 2018 and is also reflected in the performance metrics of the ChemPubSoc Europe / Wiley-VCH publishing program, which now consists of 16 titles. The most recent product, ChemSystemsChem, was announced in Fall 2018. In 2018, the journals that are co-owned by ChemPubSoc Europe societies published nearly 9,000 articles (excluding contributions to the online publication ChemViews Magazine). Compared to the previous year, manuscript submissions grew by 12%, and the number of published articles rose by approximately 5%. A record number of full-text downloads, >8.9 million, was witnessed for the ChemPubSoc Europe journals, with increases in usage compared to the same time last year; notable among them ca. +20–30% for ChemCatChem, ChemElectroChem, ChemMedChem, and ChemPlusChem; and ca. +70% for ChemistrySelect and ChemPhotoChem. Approximately 3% of articles published in ChemPubSoc Europe's hybrid journals in 2018 were open access: ca. 10% at ChemBioChem and ca. 5% at ChemCatChem, Chemistry—A European Journal, ChemMedChem, and ChemPhysChem, respectively. ChemPubSoc Europe's gold open access journal, ChemistryOpen, experienced a ca. 47% growth in submissions compared to 2017. Generational change After the retirement of Peter Gölitz in November 2017, additional responsibility was taken on by Guido Herrmann (VP, Co-Managing Director Wiley-VCH, since April 1, 2017), Eva Wille (VP, Executive Director Wiley-VCH), Neville Compton (Editor-in-Chief of Angewandte Chemie and publisher for the GDCh journals), Haymo Ross (Editor-in-Chief of Chemistry—A European Journal and publisher of the ChemPubSoc Europe journals), Theresa Kueckmann (Editor-in-Chief of Chemistry—An Asian Journal and publisher for the Asian Chemical Editorial Society (ACES) journals), and Greta Heydenrych (development of new journals). -
Wiley Article Publication Charges for Hybrid Open Updated: 17 March 2021
Wiley Article Publication Charges for Hybrid Open Updated: 17 March 2021 Online Full Arti ISSN Journal Title USD $ 1467-6281 Abacus 2.500 1553-2712 Academic Emergency Medicine 3.000 1467-629X Accounting & Finance 3.000 1911-3838 Accounting Perspectives 2.500 1399-6576 Acta Anaesthesiologica Scandinavica 3.800 2053-2733 Acta Crystallographica Section A: Foundations and Advances 3.750 2052-5206 Acta Crystallographica Section B: Structural Science, Crystal Engineering and Mater 3.750 2053-2296 Acta Crystallographica Section C: Structural Chemistry 3.600 2059-7983 Acta Crystallographica Section D: Structural Biology 3.850 1755-6724 Acta Geologica Sinica (English Edition) 3.000 1600-0404 Acta Neurologica Scandinavica 4.000 1600-0412 Acta Obstetricia et Gynecologica Scandinavica 4.000 1755-3768 Acta Ophthalmologica 3.950 1651-2227 Acta Paediatrica: Nurturing the Child 3.300 1748-1716 Acta Physiologica 3.700 1600-0447 Acta Psychiatrica Scandinavica 3.600 1463-6395 Acta Zoologica 3.000 1360-0443 Addiction 3.700 1369-1600 Addiction Biology 3.700 2161-0029 Adultspan Journal 2.500 2701-0198 Advanced Biology 3.800 2578-0727 Advanced Control for Applications 2.500 2199-160X Advanced Electronic Materials 4.200 1614-6840 Advanced Energy Materials 5.000 1527-2648 Advanced Engineering Materials 4.100 1616-3028 Advanced Functional Materials 5.000 2192-2659 Advanced Healthcare Materials 4.200 1521-4095 Advanced Materials 5.000 2196-7350 Advanced Materials Interfaces 4.200 2365-709X Advanced Materials Technologies 4.200 2195-1071 Advanced Optical Materials -
SCIENCE CITATION INDEX EXPANDED - JOURNAL LIST Total Journals: 8631
SCIENCE CITATION INDEX EXPANDED - JOURNAL LIST Total journals: 8631 1. 4OR-A QUARTERLY JOURNAL OF OPERATIONS RESEARCH 2. AAPG BULLETIN 3. AAPS JOURNAL 4. AAPS PHARMSCITECH 5. AATCC REVIEW 6. ABDOMINAL IMAGING 7. ABHANDLUNGEN AUS DEM MATHEMATISCHEN SEMINAR DER UNIVERSITAT HAMBURG 8. ABSTRACT AND APPLIED ANALYSIS 9. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 10. ACADEMIC EMERGENCY MEDICINE 11. ACADEMIC MEDICINE 12. ACADEMIC PEDIATRICS 13. ACADEMIC RADIOLOGY 14. ACCOUNTABILITY IN RESEARCH-POLICIES AND QUALITY ASSURANCE 15. ACCOUNTS OF CHEMICAL RESEARCH 16. ACCREDITATION AND QUALITY ASSURANCE 17. ACI MATERIALS JOURNAL 18. ACI STRUCTURAL JOURNAL 19. ACM COMPUTING SURVEYS 20. ACM JOURNAL ON EMERGING TECHNOLOGIES IN COMPUTING SYSTEMS 21. ACM SIGCOMM COMPUTER COMMUNICATION REVIEW 22. ACM SIGPLAN NOTICES 23. ACM TRANSACTIONS ON ALGORITHMS 24. ACM TRANSACTIONS ON APPLIED PERCEPTION 25. ACM TRANSACTIONS ON ARCHITECTURE AND CODE OPTIMIZATION 26. ACM TRANSACTIONS ON AUTONOMOUS AND ADAPTIVE SYSTEMS 27. ACM TRANSACTIONS ON COMPUTATIONAL LOGIC 28. ACM TRANSACTIONS ON COMPUTER SYSTEMS 29. ACM TRANSACTIONS ON COMPUTER-HUMAN INTERACTION 30. ACM TRANSACTIONS ON DATABASE SYSTEMS 31. ACM TRANSACTIONS ON DESIGN AUTOMATION OF ELECTRONIC SYSTEMS 32. ACM TRANSACTIONS ON EMBEDDED COMPUTING SYSTEMS 33. ACM TRANSACTIONS ON GRAPHICS 34. ACM TRANSACTIONS ON INFORMATION AND SYSTEM SECURITY 35. ACM TRANSACTIONS ON INFORMATION SYSTEMS 36. ACM TRANSACTIONS ON INTELLIGENT SYSTEMS AND TECHNOLOGY 37. ACM TRANSACTIONS ON INTERNET TECHNOLOGY 38. ACM TRANSACTIONS ON KNOWLEDGE DISCOVERY FROM DATA 39. ACM TRANSACTIONS ON MATHEMATICAL SOFTWARE 40. ACM TRANSACTIONS ON MODELING AND COMPUTER SIMULATION 41. ACM TRANSACTIONS ON MULTIMEDIA COMPUTING COMMUNICATIONS AND APPLICATIONS 42. ACM TRANSACTIONS ON PROGRAMMING LANGUAGES AND SYSTEMS 43. ACM TRANSACTIONS ON RECONFIGURABLE TECHNOLOGY AND SYSTEMS 44. -
0 WILEY and MAYNOOTH UNIVERSITY WILEY READ AND
WILEY and MAYNOOTH UNIVERSITY ________________________________________ WILEY READ AND PUBLISH AGREEMENT ________________________________________ 0 THIS AGREEMENT is made on the 15th day of March, 2021 BETWEEN: John Wiley & Sons, Inc., a New York corporation, 111 River Street, Hoboken, New Jersey 07030, and its affiliates Wiley Periodicals LLC, John Wiley & Sons, Ltd, John Wiley & Sons Australia, Ltd, Wiley-VCH GmbH, John Wiley & Sons A/S, collectively “Wiley” or “Publisher” AND National University of Ireland Maynooth, Maynooth University, whose principal address is at Maynooth, Co Kildare, Ireland (“Maynooth University”), acting on its own behalf and as non-exclusive agent on behalf of the other Members of the Consortium. RECITALS WHEREAS Maynooth University has been appointed by Members of the Consortium, as their non-exclusive agent, to enter into agreements on the Members’ behalf for accessing electronic educational and research resources; AND WHEREAS the Publisher provides Wiley Online Library which is an electronic collection of online journals, books, and research resources, covering life, health, social, and physical sciences, and the Publishing Privilege that gives authors the option to publish articles on an open access basis in select Wiley journals.; AND WHEREAS Maynooth University wishes to enter into this Agreement in order for Members of the Consortium to be authorised to access and use the Licensed Material; AND WHEREAS the Consortium and the Publisher share the goal to transition to an open access model and the transition to full open access will include continued access to the Publisher’s journal content, AND WHEREAS the parties are desirous to contract on the basis of the terms and conditions of this Agreement. -
Eurjoceuropean Journal of Organic Chemistry Inorganic Chemistry
A Journal of A Journal of EurJIC European Journal of EurJOCEuropean Journal of Organic Chemistry Inorganic Chemistry 42/2019 44/2019 www.eurjic.org www.eurjoc.org A Journal of Front Cover Front Cover Felicitas Lips et al. Chutima Kuhakarn et al. Amido Silicon Chalcogenide Compounds with Unprecedented Cluster Cores Azide-Triggered Bicyclization of o-Alkynylisocyanobenzenes: Synthesis of Supported by www.chemeurj.org and Low Oxidation State Silicon Atoms Tetrazolo[1,5-a]quinolines 22/2019 2019-25/66 21/2019 Front Cover: A Journal of Front Cover: A Journal of Y. Guo et al. S. M. Eyrilmez, C. Köprülüoğlu et al. Capsule-Structured Copper–Zinc Catalyst for Highly Efficient Impressive Enrichment of Semiempirical Quantum Mechanics-Based Hydrogenation of Carbon Dioxide to Methanol Scoring Function: HSP90 Protein with 4541 Inhibitors and Decoys www.chemsuschem.org www.chemphyschem.org 21/2019 A Journal of Special Issue: A Journal of 11/2019 Front Cover: New Concepts in F. H. Lutter et al. Front Cover: Homogeneous Cobalt-Catalyzed Cross-Couplings and Electrophilic Aminations M. Konya et al. using Organozinc Pivalates Cationic Polymerization via Activation Catalysis of Alkoxyamines Using Photoredox Catalysts www.chemcatchem.org www.chemphotochem.org SpecialPhotopoly- Issue: merisation Supported by Front Cover: F. D. Toste, E. Gross et al. Flexible NO2-Functionalized N-Heterocyclic Carbene Monolayers on Au(111) Surface 22/2019 Front Cover: Gurcan Gunaydin, Safacan Kolemen, Gorkem Gunbas et al. Mitochondria-Targeting Selenophene-Modified BODIPY-Based Photosensitizers for the Treatment of Hypoxic Cancer Cells www.chemmedchem.org Wiley VCH Dienstag, 29.10.2019 1911 / 150392 [S. 894/894] 1 21/2019 22/2019 Front Cover: Front Cover: A Journal of S. -
Last Updated 2017-10-3 Wiley Online Library Journals List 2018 Title
Last Updated 2017-10-3 Wiley Online Library Journals List 2018 2015 Title Journal DOI Wiley Online Library URL Impact Factor 1 ABACUS 10.1111/(ISSN)1467-6281 http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1467-6281 0.821 2 ACADEMIC EMERGENCY MEDICINE (ELECTRONIC) 10.1111/(ISSN)1553-2712 http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1553-2712 2.537 3 ACCOUNTING & FINANCE 10.1111/(ISSN)1467-629X http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1467-629X 0.927 4 ACCOUNTING PERSPECTIVES 10.1111/(ISSN)1911-3838 http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1911-3838 5 ACTA ANAESTHESIOLOGICA SCANDINAVICA 10.1111/(ISSN)1399-6576 http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1399-6576 2.049 6 ACTA ARCHAEOLOGICA 10.1111/(ISSN)1600-0390 http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1600-0390 7 ACTA GEOLOGICA SINICA (ENGLISH EDITION) (ELECTRONIC) 10.1111/(ISSN)1755-6724 http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1755-6724 1.996 8 ACTA NEUROLOGICA SCANDINAVICA (ELECTRONIC) 10.1111/(ISSN)1600-0404 http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1600-0404 2.559 9 ACTA OBSTETRICIA ET GYNECOLOGICA SCANDINAVICA 10.1111/(ISSN)1600-0412 http://obgyn.onlinelibrary.wiley.com/hub/journal/10.1111/(ISSN)1600-04 2.426 10 ACTA OPHTHALMOLOGICA 10.1111/(ISSN)1755-3768 http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1755-3768 3.032 11 ACTA PAEDIATRICA (ELECTRONIC) 10.1111/(ISSN)1651-2227 http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1651-2227 1.674 12 ACTA PHYSIOLOGICA (ELECTRONIC) 10.1111/(ISSN)1748-1716 -
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AMENllMENT TO WILEY ONLINE AGREEMENT Amendment as of January 1, 2019 to the Agreement (the " Agreement " John Wi ley & Sons, Jnc. ("Wiley US"), a New York corporation, and its affiliates, including without limitation, John Wiley & Son of England and Wales, VCH Verla GmbH & o. a , a company mcorporate un er l 1e aws o ("Wiley Germany") and John Wiley & Sons Australia, Ltd., (.. Wiley Australia"), collectively ''Wiley" as successor m interest to I ey Subscription Services, Inc. and The Regents of the University of California, a non-profit academic institution, with its rinci al offices at !he California Di ital Library, University of California Office of the President, SA (the "Customer"). In signing this Amendment, the parties agree that the following terms shall amend and supersede the tenns of said Agreement as follows: I. Paragraph A.2. shall be amended to replace "Licensee" with "Customer''. 2. Paragraph G. I. "Term and Termination" is amended and the tenn of the License is extended to end on December 31, 2019. 3. All applicable Product Appendices are amended to reflect the Licensed Electronic Products for the 201 9 calendar year and the respective pricing for 2019. 5. Paragraph J.12 in the EAL Amendment 2013-15 is removed for 2019 and Lawrence Livermore National Laboratory (LLNL) no longer receives access to the American Geophysical Union (AGU) titles via the California Digital Library license. For the avoidance of doubt, LLNL has perpetual rights to v. I through 2018 of the AGU titles, as stated in the Perpetual Access rights of the Agreement and there are no fees for LLNL's continued access lo the content. -
2019 Selected Editions: SCIE,SSCI Selected Quartiles: 'Q1'
Journal Data Filtered By: Selected JCR Year: 2019 Selected Editions: SCIE,SSCI Selected Quartiles: 'Q1' Selected Category Scheme: WoS Rank Full Journal Title Journal Impact FactorJIF Quartile 1 CA-A CANCER JOURNAL FOR CLINICIANS 292.278 Q1 2 NEW ENGLAND JOURNAL OF MEDICINE 74.699 Q1 3 Nature Reviews Materials 71.189 Q1 4 NATURE REVIEWS DRUG DISCOVERY 64.797 Q1 5 LANCET 60.392 Q1 6 WHO Technical Report Series 59 Q1 7 NATURE REVIEWS MOLECULAR CELL BIOLOGY 55.47 Q1 8 Nature Reviews Clinical Oncology 53.276 Q1 9 NATURE REVIEWS CANCER 53.03 Q1 10 CHEMICAL REVIEWS 52.758 Q1 11 Nature Energy 46.495 Q1 12 JAMA-JOURNAL OF THE AMERICAN MEDICAL ASSOCIATION 45.54 Q1 13 REVIEWS OF MODERN PHYSICS 45.037 Q1 14 CHEMICAL SOCIETY REVIEWS 42.846 Q1 15 NATURE 42.778 Q1 16 SCIENCE 41.845 Q1 17 Nature Reviews Disease Primers 40.689 Q1 18 World Psychiatry 40.595 Q1 18 World Psychiatry 40.595 Q1 20 NATURE REVIEWS IMMUNOLOGY 40.358 Q1 21 NATURE MATERIALS 38.663 Q1 22 CELL 38.637 Q1 23 NATURE BIOTECHNOLOGY 36.558 Q1 24 NATURE MEDICINE 36.13 Q1 25 Living Reviews in Relativity 35.429 Q1 26 Nature Reviews Chemistry 34.953 Q1 27 NATURE REVIEWS MICROBIOLOGY 34.209 Q1 28 LANCET ONCOLOGY 33.752 Q1 29 NATURE REVIEWS NEUROSCIENCE 33.654 Q1 30 NATURE REVIEWS GENETICS 33.133 Q1 31 Annual Review of Astronomy and Astrophysics 32.963 Q1 32 JOURNAL OF CLINICAL ONCOLOGY 32.956 Q1 33 PROGRESS IN MATERIALS SCIENCE 31.56 Q1 34 Nature Nanotechnology 31.538 Q1 35 Nature Photonics 31.241 Q1 36 NATURE METHODS 30.822 Q1 37 Nature Catalysis 30.471 Q1 38 Energy & Environmental Science 30.289