Subject Index

Adsorbate-induced reconstructions 58 Carboxylates 9 Alkanedithiol/Au junctions 233 Charge transport 181 Alkoxide infiltration 151, 154 Chemical vapor deposition 144, 152 5-Alkoxy-isophthalic acid derivatives 106 Clean surfaces, reconstructions 55 Alumina films, epitaxial 74 Cobalt–dicarbonitrile superlattices, Amphiphilic ionic liquids (AILs) 163 Ag(111) 20 Anthraquinone 125 Cobalt phthalocyanine, Au(788) 69 Assembling units 49 Colloid templating, multiple-size 162 Atomic layer deposition (ALD) 171 Colloidal crystals 136, 141 ATR-SEIRAS 187 Colloidal films/crystals, fabrication 139 Au surfaces, vicinal 71 Computational modeling 26 Au(100), H2SO4 191 Conformational pseudopolymorphism Au(111), H2SO4 188 103 Au(111)-(1×1), aromatic carboxylic acids, Coordination systems, linear 16 self-assembly 212 Coordinatively unsaturated sites 3 Au/alkanedithiol/Au junctions, charge Copper–carboxylate 13 transport 233 Coronene 111 Au/molecule/Au junctions, charge Crystal engineering 89 transport 231 Crystals, colloidal 136, 141 Azobenzene, interconversion, UV 173 –two-dimensional 88 4,4-Azobenzene dicarboxylaic acid 19 Cu-phthalocyanine 120 Cu-TMA (1,3,5-benzoic tricarboxylic acid) Benzene carboxylic acid 94 13 Benzene tribenzoic acid 114 Current-induced tunneling spectroscopy Benzoic tricarboxylic acid (trimellitic acid) (CITS) 34 (TMLA) 15, 182, 194 Cyclothiopene 112 Bimodal porous silica, tailored 164 Biosensing polymer inverse opals 157 Dehydrobenzo[12]annulenes 116 Biphenyl dicarboxylic acid (BDA) 18 Density functional theory (DFT), 1,4-Bis(4-pyridyl)benzene, Cu(100) 16 metal–TMA 26 2,5-Bis(dodecyloxy)terephthalic acid 95 Desorption, oxidative 225 Block copolymer templating 161 – reductive 222 Boron nitride nanomesh 66 Deposition temperature 60 Bovine serum albumin (BSA) 169 Diamino triazine derivative 107 BPn adlayers, Au(111)-(1×1) 218 Diamond inverse opals 153 Dicarbonitrile nanomesh, Ag(111) 28 Cage compounds 34 Dicarbonitrile–polyphenyl 21 Carbamate 104 2,5-Dihydroxybenzohydroquinone Carbon-based networks 149 (DHBQ), Cu(II) 35 258 Subject Index

9,10-Dimethoxyanthracene 125 Layers, epitaxial inorganic 61 1,3-Dinonadecanoylbenzene 103 –epitaxialorganic 66 DNA/diazo resin 159 Local deposition, confined 167

Electrochemical deposition 153 Macropores 137 Electrochemistry 181 Manganese–carboxylate 19 Electrolyte gating 232, 238 Manganese porphyrins 127 Electropolymerization 157 Melt infiltration 152 Ethene monolayer, Cu3Pt(111) 52 Merocyanine dye dweivatives 106 Ethene-1,2-diyl-bisbenzoic acid 19 Mesopores 237 Meso-tetradodecylporphyrins 123 Fe–biphenolate networks, Ag(111)/Cu(100) Metal deposition, electrochemical 148 20, 24 – electroless 147 Fe–carboxylates 15 Metal films, epitaxial 59, 71 Fe–TMA 14 Metal ion arrays (MIAs) 33 Fe–TPA 14, 78 Metal ion–ligand assemblies, solid–liquid Films, epitaxial inorganic 61 interface 30 Fluorene 114 Metal oxide-based networks 154 Foldamers 93 Metal precursor infiltration/transformation Forces, directional, control 93 147 Functionality complementarity 92 Metal surfaces 1 – reconstructed 67 Ge opal 153 – templates 66 Graphene layers, Ir(111) 61 Metal-based networks 145 Grid-of-grids network 33 Metal-directed assembly 1 Metal–carboxylates, Cu surfaces 13 Herringbone/chevron pattern 56, 67, 202 Metal–ligand coordination 96 Hexabenzocoronene 118 Metal–organic coordination networks Hexabenzocoronene 61 (MOCNs) 17, 79 Hexabenzocoronene–anthraquinone 125 Metal–phthalocyanine 7 1-Hexadecyl-3-methylimidazolium Metal–porphyrin 7 chloride 163 4-Methyl-4-(n-mercaptoalkyl)biphenyls Hierarchical structure 136 on Au(111) 182, 187, 217 Highly oriented pyrolytic graphite (HOPG) Metalloporphyrin nanoarchitectures 12 33, 100 Metallosupramolecular engineering, in Honeycomb networks 20, 114, 194 vacuo, solid surfaces 8 HOPG 33, 100 Migration (rotation) energy barrier 8 Hydrogels 159 Molecular electronics 125 Hydrogen bonding 93 Molecular self-assembly, directional hydrogen bonding 193 Interface science 1 Monodendron 110 Inverse opal 136 Monolayers 39, 50, 52, 88, 124, 216 Ionic liquid templating 163 Multilayers 124 Iron oxide films, epitaxial 77 Island arrays, self-organized growth, Fe/Co N/Cu(100) 72 23 Nanomeshes, metal–organic honeycomb Isophthalic acid (ISA) 21 (1,3-benzenedicarboxylic acid) 94 Nanoparticle codeposition/infiltration 146 Kagomé lattices 19 Nonanedithiol 235 Subject Index 259

Octadecyltrimethylammonium chloride Replica 136 163 Replica formation, porous 143 Oligo(phenylene ethynylene) 111 Opal infiltration, semiconductor Salophen 31 nanoparticles 150 Salt infiltration 151, 155 Optoelectronics 171 Scanning tunneling microscopy (STM) 1, Oxide reduction 152, 155 4, 11, 88, 90, 181 Oxide surfaces, templates 74 Scanning tunneling spectroscopy (STS) 181 PAHs, electron-poor 125 Self assembly 181 Particle film formation, strategies 140 – molecular, covalent bonds 216 Perylene bisimide derivatives 106 Self-assembled monolayers (SAMs) 39, Perylenetetracarboxylic-dianhydride 50 50, 52, 88, 216 Phenyloctane–graphite 96 Semiconductor networks 149 –2,2-bipyridine, Pd(OAc)2 30 Sensing platforms 168 Phtalocyanines 7 Shape complementarity 92 Phthalic acid (PA) Silica inverse opal, gold nanoparticles (1,2-benzenedicarboxylic acid) 94 170 Polybenzene carboxylate 24 Single molecules 181 Polycyclic aromatic hydrocarbons (PAHs) Solid–liquid interfaces, electrified 231 125 – metal ion–ligand assemblies 30 Polymer-based networks 155 Solvent-evaporation-mediated direct Polymerization, reactivity 126 physical casting (SEDPC) 163 Polymorphism 103 STM 1, 4, 11, 88, 181 Polyoxometalates (POMs) 34 Supramolecular chemistry/engineering 1, Poly(dimethyl siloxane) (PDMS) stamp 88 micromolding 161 Surface coordination chemistry 1 Poly(methyl methacrylate) (PMMA) 139 Surface engineering 216 Poly(thiophene-co-3-thiophenemethanol) Surfaces, vicinal 57 copolymer inverse opal, biotinylation Surfactant templating 163 169 Pores, 2D 112 Tecton 97 – alkyl chains 116 Template generation, strategies 55 – hydrogen bonds 113 Template removal 144 Porous networks 136 Template-assisted assembly 50 – hierarchical 160 Template-controlled assembly 51 Porous particles 165 Templates 136 Porphyrins 7 –2D 52 PS inverse opal 159 – metal surfaces 66 Pt(100)-hex reconstruction 57 –oxidesurfaces 74 PTCDA monolayers, self-assembled 50 – self-assembly 47 Pyrazine derivatives 106 Terephthalic acid (TTA) (1,4-benzenedi- Pyridine–Cu–pyridine 23 carboxylic acid) 94 4-[trans-2-(Pyrid-4-ylvinyl)]benzoic acid Terphenyl-1,4-dicarboxylic acid (TDA) (PVBA) 13 18 Tetracyanoethylene, Cu(100) 17 Quinacridone 98 Tetrakis-(4-carboxylphenyl)-21H,23H- porphyrin (TCPP) 201 Reactivity, 2D 125 Tetrapropylammonium hydroxide Relaxation 56 (TPAOH) 163 260 Subject Index

Tetra-pyridyl-porphyrin (TPyP) 11 1,3,5-Tris(10-carboxydecyloxy)benzene Tetrathiofulvalene 100 120 Titania 76 1,3,5-Tris(4-prydiyl)-2,4,6-triazine 115 TMA 94, 115, 182, 194 – Au(111) H2SO4 195 Ultra-high vacuum (UHV) 5, 90 TMA adlayers, Au(111)-(1×1) 197 Trimellitic acid (TMLA) 15, 182, 194 Vicinal surfaces 57, 68 Trimesic acid (TMA) 94, 115, 182, 194 Viologen derivatives, redox-active 238 1,3,5-Trimethylbenzene (TMB) 226, 235 Wall functionalization 165