Formation of Plastic Creases in Thin Polyimide Films
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Biocompatibility of Polyimides: a Mini-Review
materials Review Biocompatibility of Polyimides: A Mini-Review Catalin P. Constantin 1 , Magdalena Aflori 1 , Radu F. Damian 2 and Radu D. Rusu 1,* 1 “Petru Poni” Institute of Macromolecular Chemistry, Romanian Academy, Aleea Grigore Ghica Voda 41A, Iasi-700487, Romania; [email protected] (C.P.C.); mafl[email protected] (M.A.) 2 SC Intelectro Iasi SRL, Str. Iancu Bacalu, nr.3, Iasi-700029, Romania; [email protected] * Correspondence: [email protected]; Tel.: +40-232-217454 Received: 14 August 2019; Accepted: 25 September 2019; Published: 27 September 2019 Abstract: Polyimides (PIs) represent a benchmark for high-performance polymers on the basis of a remarkable collection of valuable traits and accessible production pathways and therefore have incited serious attention from the ever-demanding medical field. Their characteristics make them suitable for service in hostile environments and purification or sterilization by robust methods, as requested by most biomedical applications. Even if PIs are generally regarded as “biocompatible”, proper analysis and understanding of their biocompatibility and safe use in biological systems deeply needed. This mini-review is designed to encompass some of the most robust available research on the biocompatibility of various commercial or noncommercial PIs and to comprehend their potential in the biomedical area. Therefore, it considers (i) the newest concepts in the field, (ii) the chemical, (iii) physical, or (iv) manufacturing elements of PIs that could affect the subsequent biocompatibility, and, last but not least, (v) in vitro and in vivo biocompatibility assessment and (vi) reachable clinical trials involving defined polyimide structures. The main conclusion is that various PIs have the capacity to accommodate in vivo conditions in which they are able to function for a long time and can be judiciously certified as biocompatible. -
Design of the Alpha Cubesat: Technology Demonstration of a Chipsat-Equipped Retroreflective Light Sail
AIAA SciTech Forum 10.2514/6.2021-1254 11–15 & 19–21 January 2021, VIRTUAL EVENT AIAA Scitech 2021 Forum Design of the Alpha CubeSat: Technology Demonstration of a ChipSat-Equipped Retroreflective Light Sail Joshua S. Umansky-Castro,∗ João Maria B. Mesquita, † Avisha Kumar, ‡ Maxwell Anderson, § Tan Yaw Tung, ¶ Jenny J. Wen, ‖ V. Hunter Adams ∗∗ and Mason A. Peck †† Cornell University, Ithaca, NY, 14850 Andrew Filo ‡‡ 4Special Projects, Cupertino, CA, 95014 Davide Carabellese§§ Politecnico di Torino, Turin, Italy 10129 C Bangs ¶¶ Brooklyn, NY, 11216 Martina Mrongovius ∗∗∗ HoloCenter, Queens, NY 10004 Gregory L. Matloff ††† City Tech, Brooklyn, NY 11201 This paper provides an overview of Alpha, a rapidly developed, low-cost CubeSat mission to verify the performance of a highly retroreflective material for light-sail propulsion. Designed, integrated, and tested by students of the Space Systems Design Studio at Cornell University, this mission demonstrates a number of key technologies that enable next-generation capabilities for space exploration. In particular, this paper focuses on the novel application of ChipSats (gram scale spacecraft-on-a-chip technology) as a means of verifying Alpha’s sail orbit and attitude dynamics. Other innovations include an entirely 3D-printed structure to enable quick and inexpensive prototyping, an onboard Iridium modem that bypasses the need for ground- station radio equipment, retroreflective sail material that provides more deterministic thrust from laser illumination, and an attitude-control subsystem that provides full attitude and angular-rate control using magnetorquers only. In addition to these near-term technology demonstrations, Alpha is among the first exhibitions of holography in space, a medium that shows longer-term promise in several roles for interstellar travel. -
Sg423finalreport.Pdf
Notice: The cosmic study or position paper that is the subject of this report was approved by the Board of Trustees of the International Academy of Astronautics (IAA). Any opinions, findings, conclusions, or recommendations expressed in this report are those of the authors and do not necessarily reflect the views of the sponsoring or funding organizations. For more information about the International Academy of Astronautics, visit the IAA home page at www.iaaweb.org. Copyright 2019 by the International Academy of Astronautics. All rights reserved. The International Academy of Astronautics (IAA), an independent nongovernmental organization recognized by the United Nations, was founded in 1960. The purposes of the IAA are to foster the development of astronautics for peaceful purposes, to recognize individuals who have distinguished themselves in areas related to astronautics, and to provide a program through which the membership can contribute to international endeavours and cooperation in the advancement of aerospace activities. © International Academy of Astronautics (IAA) May 2019. This publication is protected by copyright. The information it contains cannot be reproduced without written authorization. Title: A Handbook for Post-Mission Disposal of Satellites Less Than 100 kg Editors: Darren McKnight and Rei Kawashima International Academy of Astronautics 6 rue Galilée, Po Box 1268-16, 75766 Paris Cedex 16, France www.iaaweb.org ISBN/EAN IAA : 978-2-917761-68-7 Cover Illustration: credit A Handbook for Post-Mission Disposal of Satellites -
Chapter 1 POLYIMIDES
Chapter 1 POLYIMIDES: chemistry & structure-property relationships – literature review 1.1 Introduction Polyimides are a class of thermally stable polymers that are often based on stiff aromatic backbones. The chemistry of polyimides is in itself a vast area with a large variety of monomers available and several methodologies available for synthesis. However, there has been considerable debate on the various reaction mechanisms involved in different synthesis methods. This review however, covers only the important fundamentals regarding the polyimide synthesis. The focus in this review will rest only on ‘aromatic’ polyimides as they constitute the major category of such materials. Secondly, the properties of polyimides can be dramatically altered by minor variations in the structure. The subtle variations in the structures of the dianhydride and diamine components have a tremendous effect on the properties of the final polyimide. This chapter reviews several such features that are important towards understanding these structure-property relationships. Specifically, the effects of changing the diamines, dianhydrides or the overall flexibility of the chain on the basic parameters like Tg and Tm are also examined. 1.2 Two step method for polyimide synthesis The most widely practiced procedure in polyimide synthesis is the two-step poly(amic acid) process. It involves reacting a dianhydride and a diamine at ambient conditions in a dipolar aprotic solvent such as N,N-dimethylacetamide (DMAc) or N- methylpyrrolidinone (NMP) to yield the corresponding poly(amic acid), which is then CHAPTER 1 3 cyclized into the final polyimide. This process involving a soluble polymer precursor was pioneered by workers at Dupont1 in 1950’s, and to this day, continues to be the primary route by which most polyimides are made. -
Preparation and Characterization of Polystyrene Hybrid Composites Reinforced with 2D and 3D Inorganic Fillers
micro Article Preparation and Characterization of Polystyrene Hybrid Composites Reinforced with 2D and 3D Inorganic Fillers Athanasios Ladavos 1,* , Aris E. Giannakas 2 , Panagiotis Xidas 3, Dimitrios J. Giliopoulos 3 , Maria Baikousi 4 , Dimitrios Gournis 4 , Michael A. Karakassides 4 and Konstantinos S. Triantafyllidis 3 1 Laboratory of Food Technology, Department of Business Administration of Food and Agricultural Enterprises, University of Patras, 30100 Agrinio, Greece 2 Department of Food Science and Technology, University of Patras, 30100 Agrinio, Greece; [email protected] 3 Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece; [email protected] (P.X.); [email protected] (D.J.G.); [email protected] (K.S.T.) 4 Department of Materials Science & Engineering, University of Ioannina, 45110 Ioannina, Greece; [email protected] (M.B.); [email protected] (D.G.); [email protected] (M.A.K.) * Correspondence: [email protected] Abstract: Polystyrene (PS)/silicate composites were prepared with the addition of two organoclays (orgMMT and orgZenith) and two mesoporous silicas (SBA-15 and MCF) via (i) solution casting and (ii) melt compounding methods. X-ray diffraction (XRD) analysis evidenced an intercalated structure for PS/organoclay nanocomposites. Thermogravimetric analysis indicated improvement in the thermal stability of PS-nanocomposites compared to the pristine polymer. This enhancement was more prevalent for the nanocomposites prepared with a lab-made organoclay (orgZenith). Citation: Ladavos, A.; Giannakas, Tensile measurement results indicated that elastic modulus increment was more prevalent (up to A.E.; Xidas, P.; Giliopoulos, D.J.; 50%) for microcomposites prepared using mesoporous silicas as filler. Organoclay addition led to Baikousi, M.; Gournis, D.; a decrease in oxygen transmission rate (OTR) values. -
The Dynamics and Control of the Cubesail Mission — a Solar Sailing
© 2010 Andrzej Pukniel. THE DYNAMICS AND CONTROL OF THE CUBESAIL MISSION—A SOLAR SAILING DEMONSTRATION BY ANDRZEJ PUKNIEL DISSERTATION Submitted in partial fulfillment of the requirements for the degree of Doctor in Philosophy in Aerospace Engineering in the Graduate College of the University of Illinois at Urbana-Champaign, 2010 Urbana, Illinois Doctoral Committee: Professor Victoria Coverstone, Chair Professor John Prussing Professor Rodney Burton Professor Gary Swenson ABSTRACT The proposed study addresses two issues related to the slow emergence of solar sailing as a viable space propulsion method. The low technology readiness level and complications related to stowage, deployment, and support of the sail structure are both addressed by combining the CU Aerospace and University of Illinois-developed UltraSail and CubeSat expertise to design a small-scale solar sail deployment and propulsion experiment in low Earth orbit. The study analyzes multiple aspects of the problem from initial sizing and packaging of the solar sail film into two CubeSat-class spacecraft, through on-orbit deployment dynamics, attitude control of large and flexible space structure, and predictions of performance and orbital maneuvering capability. ii ACKNOWLEDGEMENTS The following work would have not been possible without the continuous support and encouragement of my advisor, Professor Coverstone. Her patience, scientific insight, and enthusiasm are a rare combination that fosters a unique research environment. It allows the students to develop both as highly competent engineers as well as young individuals. Few advisors sincerely care for their students’ personal development as much as Professor Coverstone and I consider myself privileged to be part of her research group. I would also like to thank Professors Rod Burton and Gary Swenson as well as Dr. -
Hybrid Solar Sails for Active Debris Removal Final Report
HybridSail Hybrid Solar Sails for Active Debris Removal Final Report Authors: Lourens Visagie(1), Theodoros Theodorou(1) Affiliation: 1. Surrey Space Centre - University of Surrey ACT Researchers: Leopold Summerer Date: 27 June 2011 Contacts: Vaios Lappas Tel: +44 (0) 1483 873412 Fax: +44 (0) 1483 689503 e-mail: [email protected] Leopold Summerer (Technical Officer) Tel: +31 (0)71 565 4192 Fax: +31 (0)71 565 8018 e-mail: [email protected] Ariadna ID: 10-6411b Ariadna study type: Standard Contract Number: 4000101448/10/NL/CBi Available on the ACT website http://www.esa.int/act Abstract The historical practice of abandoning spacecraft and upper stages at the end of mission life has resulted in a polluted environment in some earth orbits. The amount of objects orbiting the Earth poses a threat to safe operations in space. Studies have shown that in order to have a sustainable environment in low Earth orbit, commonly adopted mitigation guidelines should be followed (the Inter-Agency Space Debris Coordination Committee has proposed a set of debris mitigation guidelines and these have since been endorsed by the United Nations) as well as Active Debris Removal (ADR). HybridSail is a proposed concept for a scalable de-orbiting spacecraft that makes use of a deployable drag sail membrane and deployable electrostatic tethers to accelerate orbital decay. The HybridSail concept consists of deployable sail and tethers, stowed into a nano-satellite package. The nano- satellite, deployed from a mothership or from a launch vehicle will home in towards the selected piece of space debris using a small thruster-propulsion firing and magnetic attitude control system to dock on the debris. -
The Heliogyro Reloaded
THE HELIOGYRO RELOADED W. K. Wilkie, J. E. Warren Structural Dynamics Branch NASA Langley Research Center Hampton, VA M. W. Thomson, P. D. Lisman, P. E. Walkemeyer Jet Propulsion Laboratory California Institute of Technology Pasadena, CA D. V. Guerrant, D. A. Lawrence Department of Aerospace Engineering Sciences University of Colorado Boulder, CO ABSTRACT The heliogyro is a high-performance, spinning solar sail architecture that uses long - order of kilometers - reflective membrane strips to produce thrust from solar radiation pressure. The heliogyro’s membrane “blades” spin about a central hub and are stiffened by centrifugal forces only, making the design exceedingly light weight. Blades are also stowed and deployed from rolls; eliminating deployment and packaging problems associated with handling extremely large, and delicate, membrane sheets used with most traditional square-rigged or spinning disk solar sail designs. The heliogyro solar sail concept was first advanced in the 1960s by MacNeal. A 15 km diameter version was later extensively studied in the 1970s by JPL for an ambitious Comet Halley rendezvous mission, but ultimately not selected due to the need for a risk-reduction flight demonstration. Demonstrating system-level feasibility of a large, spinning heliogyro solar sail on the ground is impossible; however, recent advances in microsatellite bus technologies, coupled with the successful flight demonstration of reflectance control technologies on the JAXA IKAROS solar sail, now make an affordable, small-scale heliogyro technology flight demonstration potentially feasible. In this paper, we will present an overview of the history of the heliogyro solar sail concept, with particular attention paid to the MIT 200-meter-diameter heliogyro study of 1989, followed by a description of our updated, low-cost, heliogyro flight demonstration concept. -
Design of Power, Propulsion, and Thermal Sub-Systems for a 3U Cubesat Measuring Earth’S Radiation Imbalance
Article Design of Power, Propulsion, and Thermal Sub-Systems for a 3U CubeSat Measuring Earth’s Radiation Imbalance Jack Claricoats 1,† and Sam M. Dakka 2,*,† 1 Department of Engineering and Math, Sheffield Hallam University, Howard Street, Sheffield S1 1WB, UK; [email protected] 2 Department of Mechanical, Materials and Manufacturing Engineering, The University of Nottingham, University Park, Nottingham NG7 2RD, UK * Correspondence: [email protected]; Tel.: +44-115-748-6853 † These authors contributed equally to this work. Received: 22 April 2018; Accepted: 6 June 2018; Published: 11 June 2018 Abstract: The paper presents the development of the power, propulsion, and thermal systems for a 3U CubeSat orbiting Earth at a radius of 600 km measuring the radiation imbalance using the RAVAN (Radiometer Assessment using Vertically Aligned NanoTubes) payload developed by NASA (National Aeronautics and Space Administration). The propulsion system was selected as a Mars-Space PPTCUP -Pulsed Plasma Thruster for CubeSat Propulsion, micro-pulsed plasma thruster with satisfactory capability to provide enough impulse to overcome the generated force due to drag to maintain an altitude of 600 km and bring the CubeSat down to a graveyard orbit of 513 km. Thermal analysis for hot case found that the integration of a black high-emissivity paint and MLI was required to prevent excessive heating within the structure. Furthermore, the power system analysis successfully defined electrical consumption scenarios for the CubeSat’s 600 km orbit. The analysis concluded that a singular 7 W solar panel mounted on a sun-facing side of the CubeSat using a sun sensor could satisfactorily power the electrical system throughout the hot phase and charge the craft’s battery enough to ensure constant electrical operation during the cold phase, even with the additional integration of an active thermal heater. -
Deployable Propulsion, Power and Communication Systems for Solar System Exploration Les Johnson John A
Deployable Propulsion, Power and Communication Systems for Solar System Exploration Les Johnson John A. Carr NASA George C. Marshall Space NASA George C. Marshall Space Flight Center Flight Center Huntsville, AL 35812 Huntsville, AL 35812 256-544-7824 256.544.7114 [email protected] [email protected] Darren Boyd NASA George C. Marshall Space Flight Center Huntsville, AL 35812 256.544.6466 [email protected] Abstract— NASA is developing thin-film based, deployable ACKNOWLEDGEMENTS .............................................. 5 propulsion, power, and communication systems for small REFERENCES ............................................................... 5 spacecraft that could provide a revolutionary new capability allowing small spacecraft exploration of the solar system. By BIOGRAPHY ................................................................. 6 leveraging recent advancements in thin films, photovoltaics, and miniaturized electronics, new mission-level capabilities will be enabled aboard lower-cost small spacecraft instead of their 1. INTRODUCTION more expensive, traditional counterparts, enabling a new generation of frequent, inexpensive deep space missions. The Near Earth Asteroid (NEA) Scout reconnaissance Specifically, thin-film technologies are allowing the mission will demonstrate solar sail propulsion on a 6U development and use of solar sails for propulsion, small, CubeSat interplanetary spacecraft and lay the groundwork for lightweight photovoltaics for power, and omnidirectional their future use in deep space science and exploration antennas for communication. missions. Solar sails use sunlight to propel vehicles through space by reflecting solar photons from a large, mirror-like sail Like their name implies, solar sails ‘sail’ by reflecting sunlight made of a lightweight, highly reflective material. This from a large, lightweight reflective material that resembles the continuous photon pressure provides propellantless thrust, sails of 17th and 18th century ships and modern sloops. -
Polyimide P84®NT Technical Brochure Polyimide P84®NT
Polyimide P84®NT Technical brochure Polyimide P84®NT Introducing an outstanding high performance polymer: Excellent performance at high temperatures Polyimide P84®NT is used in applications where ordinary plastics would sooner melt or decompose. High heat deflection temperature Polyimide P84®NT guarantees very good creep resistance even at elevated temperatures. High strength and excellent shape stability Parts and components made of Polyimide P84®NT provide a rigid struc- ture and can bear high mechanical stress and elongation. Very good impact resistance The high impact strength of Polyimide P84®NT ensures easy machinability with standard tools and good quality of edges and surfaces. Processing by state-of-the art sinter technologies Polyimide P84®NT is processable cost-efficiently by common sinter tech- nologies such as hot compression moulding or direct forming. Powder or granules are commercially available Commercially available polyimide raw material enables plastics processors to develop proprietary polyimide parts and compounds. Small particle size Homogenous blending with functional fillers or other polymers can be achieved by employing powder grades with particle size less than 10µm. Low wear and friction behaviour Tribological compounds with solid lubricants provide dry-lubricated solu- tions for demanding applications. 2 Why choosing Polyimide P84®NT? Demanding applications Restrictions of conventional polyimides High temperatures or frictional wear at high speeds and Processing semi-finished parts made of polyimide is of- loads often circumscribes the use of ordinary engineer- ten a difficult undertaking, and the raw material is some- ing plastics; hence, advanced high-performance poly- times not available commercially, prompting some poly- mers have taken their place in demanding applications. -
Near Earth Asteroid (NEA) Scout
Near Earth Asteroid Scout An Interplanetary 6U CubeSat Les Johnson NASA MSFC Near Earth Asteroid (NEA) Scout National Aeronautics and Space Administration Add Presentation Title to Master Slide 2 How does a solar sail work? Solar sails use photon “pressure” or force on thin, lightweight reflective sheet to produce thrust. National Aeronautics and Space Administration Add Presentation3 Title to Master Slide 3 Solar sails can spiral inward or outward from the Sun Image courtesy of Colorado Center for Astrodynamics Research National Aeronautics and Space Administration Add Presentation4 Title to Master Slide 4 Solar Sail Trajectory Control • Solar Radiation Pressure: Inward and outward Spiral Original orbit Sail Force Force Sail Shrinking orbit Expanding orbit Near Earth Asteroid Scout Overview The Near Earth Asteroid Scout Will – Image/characterize an asteroid – Demonstrate a low cost asteroid reconnaissance capability Key Spacecraft & Mission Parameters • 6U cubesat (20 cm X 10 cm X 30 cm) • ~85 m2 solar sail propulsion system • Manifested for launch on the Space Launch System (EM-1/2017) • Up to 2.5 year mission duration • 1 AU (93,000,000 mile) maximum distance from Earth Solar Sail Propulsion System Characteristics • ~ 7.3 m Trac booms • 2.5m aluminized CP-1 substrate • > 90% reflectivity 6 NEA Scout Overview Why NEA Scout? Target • Detect and track a Near Earth Asteroid (NEA) target • Characterize the physical properties of the unresolved NEA target • Flyby and characterize the physical properties of the resolved NEA target Measurements: NEA volume, spectral type, spin mode and orbital properties, address key physical and regolith mechanical SKG • ≥80% surface coverage imaging at ≤50 cm/px • Spectral range: 400-900 nm (incl.