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Characterization of N-Alkanes, Pristane and Phytane in the Cretaceous/ Tertiary Boundary Sediments at Kawaruppu, Hokkaido, Japan
Geochemical Journal, Vol. 33, pp. 285 to 294, 1999 Characterization of n-alkanes, pristane and phytane in the Cretaceous/ Tertiary boundary sediments at Kawaruppu, Hokkaido, Japan HAJIME MITA and AKIRA SHIMOYAMA Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan (Received December 24, 1998; Accepted April 22 , 1999) Normal alkanes from C12 to C36, pristane and phytane were identified in the Cretaceous/Tertiary (K/T) boundary sediments at Kawaruppu, Hokkaido, Japan. These compounds were found at the levels of sub to a few nmol g-1. Total concentrations of the n-alkanes within the boundary claystone were generally one third to one half of those in the sediments above and below the claystone. The smaller concentrations within the claystone were mainly due to smaller concentrations of longer chain n-alkanes (C25 to C31) than in the sediments above and below it. The longer chain n-alkanes were likely from terrestrial plants and reflected their small population at the end of Cretaceous. The concentration of longer chain n-alkanes decreased rapidly at the base of the boundary claystone, indicating the sudden cease of terrestrial n-alkane input, continued low to the horizon at the upper two thirds of the claystone and then, started increasing toward the top of the claystone. The n-alkane concentration change indicates the period of the small input of terrestrial n-alkanes to be ca. 7,000 years at most and the recovery period to be ca. 2,000 years. The depth distribution pattern of pristane plus phytane concentrations in the K/T sediments roughly resembles that of the n-alkanes. -
Carbon Geochemistry of Serpentinites in the Lost City Hydrothermal System (30°N, MAR)
Available online at www.sciencedirect.com Geochimica et Cosmochimica Acta 72 (2008) 3681–3702 www.elsevier.com/locate/gca Carbon geochemistry of serpentinites in the Lost City Hydrothermal System (30°N, MAR) Ade´lie Delacour a,*, Gretchen L. Fru¨h-Green a, Stefano M. Bernasconi b, Philippe Schaeffer c, Deborah S. Kelley d a Institute for Mineralogy and Petrology, ETH Zurich, CH-8092 Zurich, Switzerland b Geological Institute, ETH Zurich, CH-8092 Zurich, Switzerland c Laboratoire de Ge´ochimie Bioorganique, UMR 7177 du CNRS, Universite´ Louis Pasteur, Strasbourg, France d School of Oceanography, University of Washington, Seattle, WA 98195, USA Received 18 June 2007; accepted in revised form 30 April 2008; available online 24 May 2008 Abstract The carbon geochemistry of serpentinized peridotites and gabbroic rocks recovered at the Lost City Hydrothermal Field (LCHF) and drilled at IODP Hole 1309D at the central dome of the Atlantis Massif (Mid-Atlantic Ridge, 30°N) was exam- ined to characterize carbon sources and speciation in oceanic basement rocks affected by long-lived hydrothermal alteration. Our study presents new data on the geochemistry of organic carbon in the oceanic lithosphere and provides constraints on the fate of dissolved organic carbon in seawater during serpentinization. The basement rocks of the Atlantis Massif are charac- 13 terized by total carbon (TC) contents of 59 ppm to 1.6 wt% and d CTC values ranging from À28.7& to +2.3&. In contrast, 13 total organic carbon (TOC) concentrations and isotopic compositions are relatively constant (d CTOC: À28.9& to À21.5&) 13 and variations in d CTC reflect mixing of organic carbon with carbonates of marine origin. -
Polskaakademianauk Instytutpaleobiologii
POLSKA AKADEMIA NAUK INSTYTUT PALEOBIOLOGII im. Romana Kozłowskiego SILURIAN AND DEVONIAN HETEROSTRACI FROM POLAND AND HYDRODYNAMIC PERFORMANCE OF PSAMMOSTEIDS Sylurskie i dewońskie Heterostraci z Polski oraz efektywność hydrodynamiczna psammosteidów Marek Dec Dissertation for degree of doctor of Earth and related environmental sciences, presented at the Institute of Paleobiology of Polish Academy of Sciences Rozprawa doktorska wykonana w Instytucie Paleobiologii Polskiej Akademii Nauk pod kierunkiem prof. dr hab. Magdaleny Borsuk-Białynickiej w celu uzyskania stopnia doktora w dyscyplinie Nauki o Ziemi oraz środowisku Warszawa 2020 CONTENTS ACKNOWLEDGMENTS…………………………………………………………….….... 3 STRESZCZENIE………………………………………………………………….....….. 4 SUMMARY……………………………………………………………………….…….. 8 CHAPTER I…………………………………………………………………………….. 13 TRAQUAIRASPIDIDAE AND CYATHASPIDIDAE (HETEROSTRACI) FROM LOWER DEVONIAN OF POLAND CHAPTER II……………………………………………………………………….…… 24 A NEW TOLYPELEPIDID (AGNATHA, HETEROSTRACI) FROM THE LATE SILURIAN OF POLAND CHAPTER III…………………………………………………………………………... 41 REVISION OF THE EARLY DEVONIAN PSAMMOSTEIDS FROM THE “PLACODERM SANDSTONE” - IMPLICATIONS FOR THEIR BODY SHAPE RECONSTRUCTION CHAPTER IV……………………………………………………………………….….. 82 NEW MIDDLE DEVONIAN (GIVETIAN) PSAMMOSTEID FROM HOLY CROSS MOUNTAINS (POLAND) CHAPTER V……………………………………………………………………………109 HYDRODYNAMIC PERFORMANCE OF PSAMMOSTEIDS: NEW INSIGHTS FROM COMPUTATIONAL FLUID DYNAMICS SIMULATIONS 2 ACKNOWLEDGMENTS First and foremost I would like to say thank you to my supervisor Magdalena -
Lipid Analysis of CO2-Rich Subsurface Aquifers Suggests an Autotrophy-Based Deep Biosphere with Lysolipids Enriched in CPR Bacteria
The ISME Journal (2020) 14:1547–1560 https://doi.org/10.1038/s41396-020-0624-4 ARTICLE Lipid analysis of CO2-rich subsurface aquifers suggests an autotrophy-based deep biosphere with lysolipids enriched in CPR bacteria 1,2 3,4 1,3 3 3 Alexander J. Probst ● Felix J. Elling ● Cindy J. Castelle ● Qingzeng Zhu ● Marcus Elvert ● 5,6 6 1 7,9 7 Giovanni Birarda ● Hoi-Ying N. Holman ● Katherine R. Lane ● Bethany Ladd ● M. Cathryn Ryan ● 8 3 1 Tanja Woyke ● Kai-Uwe Hinrichs ● Jillian F. Banfield Received: 20 November 2018 / Revised: 5 February 2020 / Accepted: 25 February 2020 / Published online: 13 March 2020 © The Author(s) 2020. This article is published with open access Abstract Sediment-hosted CO2-rich aquifers deep below the Colorado Plateau (USA) contain a remarkable diversity of uncultivated microorganisms, including Candidate Phyla Radiation (CPR) bacteria that are putative symbionts unable to synthesize membrane lipids. The origin of organic carbon in these ecosystems is unknown and the source of CPR membrane lipids remains elusive. We collected cells from deep groundwater brought to the surface by eruptions of Crystal Geyser, sequenced 1234567890();,: 1234567890();,: the community, and analyzed the whole community lipidome over time. Characteristic stable carbon isotopic compositions of microbial lipids suggest that bacterial and archaeal CO2 fixation ongoing in the deep subsurface provides organic carbon for the complex communities that reside there. Coupled lipidomic-metagenomic analysis indicates that CPR bacteria lack complete lipid biosynthesis pathways but still possess regular lipid membranes. These lipids may therefore originate from other community members, which also adapt to high in situ pressure by increasing fatty acid unsaturation. -
Stable Carbon and Hydrogen Isotopic Fractionation of Individual N-Alkanes Accompanying Biodegradation: Evidence from a Group of Progressively Biodegraded Oils
中国科技论文在线 http://www.paper.edu.cn Organic Geochemistry 36 (2005) 225–238 Stable carbon and hydrogen isotopic fractionation of individual n-alkanes accompanying biodegradation: evidence from a group of progressively biodegraded oils Yongge Sun a,*, Zhenyan Chen b, Shiping Xu a, Pingxia Cai a a SKLOG, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Wushan, Guangzhou 510640, PR China b Exploration and Development Research Institute of Liaohe Oil Field Branch Company, PetroChina, Panjing, Liaoning 124010, PR China Received 10 March 2004; accepted 16 August 2004 (returned to author for revision 16 April 2004) Available online 11 November 2004 Abstract Seven crude oils of known source and maturity, representing a natural sequence of increasing degree of biodegrada- tion, were collected from reservoirs in the Liaohe Basin, NE China, in an effort to determine the magnitude and direction of isotopic shift of carbon and hydrogen in individual n-alkanes during microbial degradation. The results show that bio- degradation has little effect on the carbon isotopic composition of the whole oil. However, a sequential loss of n-alkanes leads to 13C depletion of the bulk residual saturate fraction. The stable carbon isotopic compositions of aromatics and macromolecular organic matter (resins and asphaltenes) follow a pattern, with an overall trend towards 13C enrichment of 0.8–1.7& in the residues. The stable carbon and hydrogen isotope values of individual n-alkanes demonstrate that they follow different trends during biodegradation. No significant carbon isotopic fractionation occurs for n-alkanes during slight to moderate biodegradation. However, there is a general increase of up to 4& in the d13C values of low molecular weight n-alkanes (C15–C18) during heavy biodegradation. -
Development of Compound-Specific Hydrogen Isotope Ratio Analysis Of
Development of Compound-Specific Hydrogen Isotope Ratio Analysis of Biomarkers and their Application as New Proxy for Reconstruction of Palaeoenvironment and Palaeoclimate Entwicklung komponentenspezifischer Wasserstoffisotopen- Analyse von Biomarkern und deren Anwendung als neuartiger Proxy zur Rekonstruktion von Paläoumwelt und Paläoklima Dissertation zur Erlangung des akademischen Grades doctor rerum naturalium (Dr. rer. nat.) vorgelegt dem Rat der Chemisch-Geowissenschaftlichen Fakultät der Friedrich-Schiller-Universität Jena von Diplom Geologe Jens Radke geboren am 20.2.1967 in Bremerhaven Gutachter: 1. Prof.Dr.R.Gaupp 2. PD.Dr.G.Gleixner Tag der öffentlichen Verteidigung: 18.1.2006 Printed on 100% recycled paper (after ISO9706, 133 CIE, DIN 6738 LDK 24-85) Content Content ABSTRACT KURZFASSUNG ABBREVIATIONS 1 INTRODUCTION ......................................................................................................... 1 2 FRACTIONATION OF WATER ISOTOPES IN THE ENVIRONMENT ........................................ 2 2.1 Fractionation of water isotopes in the climate system......................................... 2 2.2 Fractionation of hydrogen in the biosynthesis of plant biomass.......................... 3 3 SEDIMENTS AND METHODS........................................................................................ 6 3.1 Sediment samples and stratigraphic framework ................................................. 6 3.2 Sample preparation for bulk and compound specific analysis ............................ 8 3.2.1 Sample -
Determination of Petroleum Hydrocarbons in Sediments
UNITED NATIONS ENVIRONMENT PROGRAMME NOVEMBER 1992 Determination of petroleum hydrocarbons in sediments Reference Methods For Marine Pollution Studies No. 20 Prepared in co-operation with IOC IAEA UNEP 1992 ~ i - PREFACE The Regional Seas Programme was initiated by UNEP in 1974. Since then the Governing Conncil ofUNEP has repeatedly endorsed a regional approach to the control of marine pollution and the management of marine and coastal resources and has requested the development of regional action plans. The Regional Seas Progranune at present includes ten regions and has over 120 coastal States participating in it (1),(2). One of the basic components of the action plans sponsored by UNEP in the framework of the Regional Seas Programme is the assessment of the state of the marine em~ronment and of its resources, and of the sources and trends of the pollution, and the impact of pollution on human health, marine ecosystems and amenities. In order to assist those participating in this activity and to ensure that the data obtained through this assessment can be compared. on a world-wide basis and thns contribute to the Global Environment Monitoring System (GEMS) of UNEP, a set of Reference Methods and Guidelines for marine pollution studies is being developed as part of a programme of c9mprehensive technical support which includes the provision of expert advice, reference methods and materials, training and data quality assurance (3). The Methods are recommended to be adopted by Governments participating in tbe Regional Seas Programme. The methods and guidelines are prepared in co-operation with the relevant specialized bodies of the United Nations system as well as other organizations and are tested by a number of experts competent in the field relevant to the methods described. -
Geological Survey of Ohio
GEOLOGICAL SURVEY OF OHIO. VOL. I.—PART II. PALÆONTOLOGY. SECTION II. DESCRIPTIONS OF FOSSIL FISHES. BY J. S. NEWBERRY. Digital version copyrighted ©2012 by Don Chesnut. THE CLASSIFICATION AND GEOLOGICAL DISTRIBUTION OF OUR FOSSIL FISHES. So little is generally known in regard to American fossil fishes, that I have thought the notes which I now give upon some of them would be more interesting and intelligible if those into whose hands they will fall could have a more comprehensive view of this branch of palæontology than they afford. I shall therefore preface the descriptions which follow with a few words on the geological distribution of our Palæozoic fishes, and on the relations which they sustain to fossil forms found in other countries, and to living fishes. This seems the more necessary, as no summary of what is known of our fossil fishes has ever been given, and the literature of the subject is so scattered through scientific journals and the proceedings of learned societies, as to be practically inaccessible to most of those who will be readers of this report. I. THE ZOOLOGICAL RELATIONS OF OUR FOSSIL FISHES. To the common observer, the class of Fishes seems to be well defined and quite distin ct from all the other groups o f vertebrate animals; but the comparative anatomist finds in certain unusual and aberrant forms peculiarities of structure which link the Fishes to the Invertebrates below and Amphibians above, in such a way as to render it difficult, if not impossible, to draw the lines sharply between these great groups. -
THE CLASSIFICATION and EVOLUTION of the HETEROSTRACI Since 1858, When Huxley Demonstrated That in the Histological Struc
ACTA PALAEONT OLOGICA POLONICA Vol. VII 1 9 6 2 N os. 1-2 L. BEVERLY TARLO THE CLASSIFICATION AND EVOLUTION OF THE HETEROSTRACI Abstract. - An outline classification is given of the Hetero straci, with diagnoses . of th e following orders and suborders: Astraspidiformes, Eriptychiiformes, Cya thaspidiformes (Cyathaspidida, Poraspidida, Ctenaspidida), Psammosteiformes (Tes seraspidida, Psarnmosteida) , Traquairaspidiformes, Pteraspidiformes (Pte ras pidida, Doryaspidida), Cardipeltiformes and Amphiaspidiformes (Amphiaspidida, Hiber naspidida, Eglonaspidida). It is show n that the various orders fall into four m ain evolutionary lineages ~ cyathaspid, psammosteid, pteraspid and amphiaspid, and these are traced from primitive te ssellated forms. A tentative phylogeny is pro posed and alternatives are discussed. INTRODUCTION Since 1858, when Huxley demonstrated that in the histological struc ture of their dermal bone Cephalaspis and Pteraspis were quite different from one another, it has been recognized that there were two distinct groups of ostracoderms for which Lankester (1868-70) proposed the names Osteostraci and Heterostraci respectively. Although these groups are generally considered to be related to on e another, Lankester belie ved that "the Heterostraci are at present associated with the Osteostraci because they are found in the same beds, because they have, like Cepha laspis, a large head shield, and because there is nothing else with which to associate them". In 1889, Cop e united these two groups in the Ostracodermi which, together with the modern cyclostomes, he placed in the Class Agnatha, and although this proposal was at first opposed by Traquair (1899) and Woodward (1891b), subsequent work has shown that it was correct as both the Osteostraci and the Heterostraci were agnathous. -
Using Information in Taxonomists' Heads to Resolve Hagfish And
This article was downloaded by: [Max Planck Inst fuer Evolutionsbiologie] On: 03 September 2013, At: 07:01 Publisher: Taylor & Francis Informa Ltd Registered in England and Wales Registered Number: 1072954 Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK Historical Biology: An International Journal of Paleobiology Publication details, including instructions for authors and subscription information: http://www.tandfonline.com/loi/ghbi20 Using information in taxonomists’ heads to resolve hagfish and lamprey relationships and recapitulate craniate–vertebrate phylogenetic history Maria Abou Chakra a , Brian Keith Hall b & Johnny Ricky Stone a b c d a Department of Biology , McMaster University , Hamilton , Canada b Department of Biology , Dalhousie University , Halifax , Canada c Origins Institute, McMaster University , Hamilton , Canada d SHARCNet, McMaster University , Hamilton , Canada Published online: 02 Sep 2013. To cite this article: Historical Biology (2013): Using information in taxonomists’ heads to resolve hagfish and lamprey relationships and recapitulate craniate–vertebrate phylogenetic history, Historical Biology: An International Journal of Paleobiology To link to this article: http://dx.doi.org/10.1080/08912963.2013.825792 PLEASE SCROLL DOWN FOR ARTICLE Taylor & Francis makes every effort to ensure the accuracy of all the information (the “Content”) contained in the publications on our platform. However, Taylor & Francis, our agents, and our licensors make no representations or warranties whatsoever as to the accuracy, completeness, or suitability for any purpose of the Content. Any opinions and views expressed in this publication are the opinions and views of the authors, and are not the views of or endorsed by Taylor & Francis. The accuracy of the Content should not be relied upon and should be independently verified with primary sources of information. -
Fish and Amphibians
Fish and Amphibians Geology 331 Paleontology Phylum Chordata: Subphyla Urochordata, Cephalochordata, and: Subphylum Vertebrata Class Agnatha: jawless fish, includes the hagfish, conodonts, lampreys, and ostracoderms (armored jawless fish) Gnathostomates: jawed fish Class Chondrichthyes: cartilaginous fish Class Placoderms: armored fish Class Osteichthyes: bony fish Subclass Actinopterygians: ray-finned fish Subclass Sarcopterygians: lobe-finned fish Order Dipnoans: lung fish Order Crossopterygians: coelocanths and rhipidistians Class Amphibia Urochordates: Sea Squirts. Adults have a pharynx with gill slits. Larval forms are free-swimming and have a notochord. Chordates are thought to have evolved from the larval form by precocious sexual maturation. Chordate evolution Cephalochordate: Branchiostoma, the lancelet Pikaia, a cephalochordate from the Burgess Shale Yunnanozoon, a cephalochordate from the Lower Cambrian of China Haikouichthys, agnathan, Lower Cambrian of China - Chengjiang fauna, scale is 5 mm A living jawless fish, the lamprey, Class Agnatha Jawless fish do have teeth! A fossil jawless fish, Class Agnatha, Ostracoderm, Hemicyclaspis, Silurian Agnathan, Ostracoderm, Athenaegis, Silurian of Canada Agnathan, Ostracoderm, Pteraspis, Devonian of the U.K. Agnathan, Ostracoderm, Liliaspis, Devonian of Russia Jaws evolved by modification of the gill arch bones. The placoderms were the armored fish of the Paleozoic Placoderm, Dunkleosteus, Devonian of Ohio Asterolepis, Placoderms, Devonian of Latvia Placoderm, Devonian of Australia Chondrichthyes: A freshwater shark of the Carboniferous Fossil tooth of a Great White shark Chondrichthyes, Great White Shark Chondrichthyes, Carcharhinus Sphyrna - hammerhead shark Himantura - a ray Manta Ray Fish Anatomy: Ray-finned fish Osteichthyes: ray-finned fish: clownfish Osteichthyes: ray-finned fish, deep water species Lophius, an Eocene fish showing the ray fins. This is an anglerfish. -
Upper Jurassic–Lower Cretaceous Source Rocks in the North Of
geosciences Article Upper Jurassic–Lower Cretaceous Source Rocks in the North of Western Siberia: Comprehensive Geochemical Characterization and Reconstruction of Paleo-Sedimentation Conditions Evgeniya Leushina 1,* , Timur Bulatov 1 , Elena Kozlova 1, Ivan Panchenko 2 , Andrey Voropaev 3, Tagir Karamov 1, Yakov Yermakov 1, Natalia Bogdanovich 1 and Mikhail Spasennykh 1 1 Skolkovo Institute of Science and Technology, Territory of Innovation Center “Skolkovo”, Bolshoy Boulevard 30, Bld. 1, 121205 Moscow, Russia; [email protected] (T.B.); [email protected] (E.K.); [email protected] (T.K.); [email protected] (Y.Y.); [email protected] (N.B.); [email protected] (M.S.) 2 MIMGO, Entuziastov Highway 21, 111123 Moscow, Russia; [email protected] 3 HYDROISOTOP GmbH, Woelkestr. 9, 85301 Schweitenkirchen, Germany; [email protected] * Correspondence: [email protected] Abstract: The present work is devoted to geochemical studies of the Bazhenov Formation in the north of the West Siberian Petroleum Basin. The object is the Upper Jurassic–Lower Cretaceous section, characterized by significant variations in total organic carbon content and petroleum gener- Citation: Leushina, E.; Bulatov, T.; ation potential of organic matter at the beginning of the oil window. The manuscript presents the Kozlova, E.; Panchenko, I.; Voropaev, integration of isotopic and geochemical analyses aimed at the evaluation of the genesis of the rocks in A.; Karamov, T.; Yermakov, Y.; the peripheral part of the Bazhenov Sea and reconstruction of paleoenvironments that controlled the Bogdanovich, N.; Spasennykh, M. accumulation of organic matter in sediments, its composition and diagenetic alterations. According Upper Jurassic–Lower Cretaceous to the obtained data, the sediments were accumulated under marine conditions with a generally Source Rocks in the North of Western moderate and periodically increasing terrigenous influx.