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2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
IN the SUPREME COURT of the UNITED STATES No
IN THE SUPREME COURT OF THE UNITED STATES _______________ No. 18A1066 ROBERT WILKIE, SECRETARY OF VETERANS AFFAIRS, APPLICANT v. ALFRED PROCOPIO, JR. _______________ APPLICATION FOR A FURTHER EXTENSION OF TIME WITHIN WHICH TO FILE A PETITION FOR A WRIT OF CERTIORARI TO THE UNITED STATES COURT OF APPEALS FOR THE FEDERAL CIRCUIT _____________ Pursuant to Rules 13.5 and 30.2 of the Rules of this Court, the Solicitor General, on behalf of Robert Wilkie, Secretary of Veterans Affairs, respectfully requests a further 30-day extension of time, to and including June 28, 2019, within which to file a petition for a writ of certiorari to review the judgment of the United States Court of Appeals for the Federal Circuit in this case. The opinion of the en banc court of appeals (App., infra, 1a-50a) is reported at 913 F.3d 1371. The court of appeals entered its judgment on January 29, 2019. On April 22, 2019, the Chief Justice extended the time within which to file a petition for a writ of certiorari to and including May 29, 2019. The jurisdiction of this Court would be invoked under 28 U.S.C. 1254(1). 2 1. Under the Agent Orange Act of 1991 (Agent Orange Act), Pub. L. No. 102-4, 105 Stat. 11, veterans who “served in the Republic of Vietnam” during the period when the United States used the herbicide Agent Orange (January 9, 1962 to May 7, 1975), were presumptively exposed to that herbicide, 38 U.S.C. 1116(f), and are presumptively entitled to disability benefits if they develop specified diseases, 38 U.S.C. -
History of Seed in the U.S. the Untold American Revolution 660 Pennsylvania Ave SE Suite 302 Washington, D.C
History of Seed in the U.S. The Untold American Revolution 660 Pennsylvania Ave SE Suite 302 Washington, D.C. 20003 P (202) 547-9359 F (202) 547-9429 www.centerforfoodsafety.org Save Our Seeds An exhibition at the National Archives in Washington, D.C., What’s Cooking Uncle Sam?, traces the history of U.S. agriculture from “the horse and plow (SOS) to today’s mechanized farm.” While the exhibition contains humorous elements, including a corporate campaign to win the War Food A program of the Administration’s endorsement of its Vitamin Donuts—“For pep and vigor… Center for Food Safety Vitamin Donuts!”—it also chronicles a sobering story of American farming and how the effects of U.S. food and agricultural policies reach far beyond the borders of Uncle Sam. Throughout, it is clear that the path of agriculture begins with the seed. Over the past 40 years, the U.S. has led a radical shift toward commercialization, consolidation, and control of seed. Prior to the advent of industrial agriculture, there were thousands of seed companies and public breeding institutions. At present, the top 10 seed and chemical companies, with the majority stake owned by U.S. corporations, control 73 1 Debbie Barker percent of the global market. International Program Today, fewer than 2 percent of Americans are farmers,2 whereas 90 percent 3 Director of our citizens lived on farms in 1810. This represents perhaps a more transformative revolution than even the Revolutionary War recorded in our history books. August 2012 This report will provide a summary of U.S. -
Thejewish Thejewish
THE JEWISH VETERAN Volume 71 • Number 4 • 2017 JWV and Lack of Accountability at the Department of the VA Veterans Affairs Leaves Veterans Flabbergasted Page 14 By Lance Wang, Editor I had the opportunity to interact with limitation of their system, and share my NAZIS ARE NOT the Veterans’ Administration while in frustration. I don’t blame them. WELCOME IN AMERICA! uniform, much more so since retiring Why is it so difficult to bring the from the Army. As with any large or- problems in the VA to solution stages? Commentary By ganization I’ve encountered good and For years the VA has been neither fish PNC Dr. Robert Pickard bad. Certainly the good is the dedicated nor fowl – it did not have the account- functionaries who I encounter, many of ability nor true profit motive that civil- Page 4 whom are themselves veterans. I also ian medical agencies have, nor did it have been particularly pleased with the have the discipline to which a military service of a nearby VA Community- agency was subjected. It was designed Register Now! Based Outreach Clinic which provides to replace a 19th century system which responsiveness that I’ve never encoun- largely put the onus on charitable or- tered from a big city VA facility. They ganizations and local communities to have provided more continuity of care care for veterans. It was never fully re- than I encountered in the military or the sourced to perform its mission, result- The workload for the VA has only civilian world. However the “bad” side ing in fraud and scandals like we saw increased since the editorial was writ- has certainly made itself known. -
A Chemical War Without End: Agent Orange in Vietnam
A Chemical War without End: Agent Orange in Vietnam Marie-Hélène Lavallard* The Vietnam War (1961-1975) is known for the massive bombings of North Vietnam. More insidious, however, yet less well-known to the general public, was the chemical war waged from 1961 to 1971against South Vietnam. An immense environmental disaster and a human catastrophe taking numerous forms: health, economic, socio-cultural …, it had dramatic consequences which are still felt today. The American government and the chemical companies involved have eluded their responsibilities. For years, a conspiracy of silence has obscured the toxicity of the defoliants used. Those responsible have the effrontery to continue denying it today. Humanitarian aid is incommensurate with the needs. It is at the government level that support for Vietnam must be organized and the demand for just reparations must be made. During the Vietnam War, from 1961 to 1971, American aviation sprayed defoliants over Southern Vietnam to chase from the jungle the combatants taking shelter there, to cut the Ho Chi Minh trail by which weapons, supplies and medication came down from the North, to facilitate surveillance of roads, coastlines and waterways and to destroy the rice paddies, forcing villagers into "strategic hamlets" and thus depriving the guerillas of food and aid1. More than 77 million2 liters of defoliants were released by plane (95%), by helicopter, by boat, by tanker truck, and by men with backpack sprayers. More than 2,500,000 hectares were contaminated by these defoliants, the best known of which is Agent Orange. It contains dioxin, one of the most violent and most indestructible poisons known. -
Congener Patterns of Polychlorinated Dibenzo-P-Dioxins
Science of the Total Environment 746 (2020) 141098 Contents lists available at ScienceDirect Science of the Total Environment journal homepage: www.elsevier.com/locate/scitotenv Review Congener patterns of polychlorinated dibenzo-p-dioxins, dibenzofurans and biphenyls as a useful aid to source identification during a contamination incident in the food chain Ron L.A.P. Hoogenboom a,⁎, Rainer Malisch b, Stefan P.J. van Leeuwen a, Huig Vanderperren c, Helge Hove d, Alwyn Fernandes f, Alexander Schächtele b, Martin Rose e,g a Wageningen Food Safety Research, Wageningen UR, Akkermaalsbos 2, 6708 WB Wageningen, the Netherlands b EURL for POPs, CVUA, Bissierstraße 5, 79114 Freiburg, Germany c FLVV, Leuvensesteenweg 17, 3080 Tervuren, Belgium d NIFES, Strandgaten 229, 5004 Bergen, Norway e FERA Science Ltd, Sand Hutton, York YO41 1LZ, UK f School of Environmental Sciences, University of East Anglia, Norwich NR4 7TJ, UK g Manchester Institute of Biotechnology, University of Manchester, Manchester, UK HIGHLIGHTS GRAPHICAL ABSTRACT • Congener patterns are important tools for source identification. • TEQ contribution may be preferred over contribution to total sum. • Only PCDDs point to clay or chlorophenols, only PCDFs to PCB sources. • Mixed patterns point to minerals or burning processes. • Simple patterns indicate certain pesti- cides or herbicides. article info abstract Article history: Polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs) and biphenyls (PCBs) are still consid- Received 7 May 2020 ered among the most important groups of contaminants in the food chain. Self-control by food producers Received in revised form 13 July 2020 and official control by authorities are important activities that allow contaminant sources to be traced Accepted 18 July 2020 and promote further reduction in food and feed levels. -
Environmental Health Criteria 39 PARAQUAT and DIQUAT
Environmental Health Criteria 39 PARAQUAT AND DIQUAT Please note that the layout and pagination of this web version are not identical with the printed version. Paraquat and diquat (EHC 39, 1984) INTERNATIONAL PROGRAMME ON CHEMICAL SAFETY ENVIRONMENTAL HEALTH CRITERIA 39 PARAQUAT AND DIQUAT This report contains the collective views of an international group of experts and does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organisation, or the World Health Organization. Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization World Health Orgnization Geneva, 1984 The International Programme on Chemical Safety (IPCS) is a joint venture of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization. The main objective of the IPCS is to carry out and disseminate evaluations of the effects of chemicals on human health and the quality of the environment. Supporting activities include the development of epidemiological, experimental laboratory, and risk-assessment methods that could produce internationally comparable results, and the development of manpower in the field of toxicology. Other activities carried out by the IPCS include the development of know-how for coping with chemical accidents, coordination of laboratory testing and epidemiological studies, and promotion of research on the mechanisms of the biological action of chemicals. ISBN 92 4 154099 4 The World Health Organization welcomes requests for permission to reproduce or translate its publications, in part or in full. Applications and enquiries should be addressed to the Office of Publications, World Health Organization, Geneva, Switzerland, which will be glad to provide the latest information on any changes made to the text, plans for new editions, and reprints and translations already available. -
The United States' Chemical Defoliant Use During the Vietnam War and Its
ABSTRACT OATSVALL, NEIL SHAFER. War on Nature, War on Bodies: The United States’ Chemical Defoliant Use During the Vietnam War and Its Consequences. (Under the direction of Matthew Morse Booker.) During most of the Vietnam War, from 1961-1971, the United States military sprayed chemical defoliants on a significant part of the Vietnamese environment in order to gain a military advantage. US forces used these chemicals in an attempt to substitute technology and financial resources for manpower to triumph over a relatively technologically deficient enemy. This effort, dubbed “Operation Ranch Hand,” wrought incredible destruction not only on Vietnam’s natural setting, but also on everyone involved; Vietnamese and American, civilian and soldier. This work examines the consequences of defoliation, and aims to show that those outcomes proved more severe in both scale and efficacy than any anticipated results. It differs from previous studies by combining environmental, military, medical, and cultural factors and considering them as interrelated. Whenever possible this study also tries to bring in a Vietnamese perspective, though that is often impossible due to a lack of available evidence in English. In this war, the United States treated not only the Vietnamese Communists as enemies but also assaulted the natural environment as foe. The interconnections forged during this complicated interpretation of nature and enemy are essential to the study of Operation Ranch Hand and chemical defoliation operations. Nature mattered to both sides, and an -
Fact Sheet 8: the Use of Defoliants – Agent Orange
Fact Sheet 8: The use of defoliants – Agent Orange A highly controversial aspect of the Vietnam War was the widespread use of herbicides by the United States military. These chemicals caused the leaves of trees in the jungle to die. This made it easier to detect enemy positions and activities, especially from the air. Crops were also sprayed to deprive the enemy of food. These chemicals included the ‘Rainbow Herbicides’ – Agent Pink, Agent Green, Agent Purple, Agent Blue, Agent White and, most famously, Agent Orange. The US Air Force sprayed approximately 75 million litres (of which Agent Orange accounted for about 45 million litres) of concentrated herbicides, affecting an estimated 13% of South Vietnam's land. Humans exposed to Agent Orange were at risk of poisoning. Some estimates suggest that there were as many as 4 million victims of dioxin poisoning in Vietnam. Veterans of the war observed an increased risk of various types of cancer, while birth defects among their children were cited as evidence of the long-term harm caused by Agent Orange. The US government denied any conclusive scientific links between Agent Orange and health problems experienced by those exposed. In 1984 US veterans obtained a $180 million settlement from companies which produced Agent Orange. A small trust fund for New Zealanders who had been exposed was established as part of this settlement, but the fund was exhausted before the health problems of many veterans became apparent. The New Zealand government initially stated that no New Zealanders were deployed in areas where defoliants were used. A 2001 report found no evidence that exposure to defoliants had affected the health of veterans' children, although it did bring new evidence of exposure. -
Diquat Ecological Risk Assessment, Final Report
Utah State University DigitalCommons@USU All U.S. Government Documents (Utah Regional U.S. Government Documents (Utah Regional Depository) Depository) 11-2005 Diquat Ecological Risk Assessment, Final Report Bureau of Land Management Follow this and additional works at: https://digitalcommons.usu.edu/govdocs Part of the Life Sciences Commons, and the Physical Sciences and Mathematics Commons Recommended Citation Bureau of Land Management, "Diquat Ecological Risk Assessment, Final Report" (2005). All U.S. Government Documents (Utah Regional Depository). Paper 107. https://digitalcommons.usu.edu/govdocs/107 This Report is brought to you for free and open access by the U.S. Government Documents (Utah Regional Depository) at DigitalCommons@USU. It has been accepted for inclusion in All U.S. Government Documents (Utah Regional Depository) by an authorized administrator of DigitalCommons@USU. For more information, please contact [email protected]. Bureau of Land Management Reno, Nevada Diquat Ecological Risk Assessment Final Report November 2005 Bureau of Land Management Contract No. NAD010156 ENSR Document Number 09090-020-650 Executive Summary The United States Department of the Interior (USDI) Bureau of Land Management (BLM) is proposing a program to treat vegetation on up to six million acres of public lands annually in 17 western states in the continental United States (US) and Alaska. As part of this program, the BLM is proposing the use of ten herbicide active ingredients (a.i.) to control invasive plants and noxious weeds on approximately one million of the 6 million acres proposed for treatment. The BLM and its contractor, ENSR, are preparing a Vegetation Treatments Programmatic Environmental Impact Statement (EIS) to evaluate this and other proposed vegetation treatment methods and alternatives on lands managed by the BLM in the western continental US and Alaska. -
Agent Orange Review
Agent Orange Review Vol. 9, N0. 3 Information for Veterans Who Served in Vietnam September 1992 National Academy of Sciences Project Secretary Edward J. Derwinski Advances on the Agent Orange Issue: VA was cast as the enemy of the veteran. VA had absolutely no credibility on this issue. The National Academy of Sciences (NAS) is making Finally, in recent months, substantial progress on the Agent Orange project undertaken on we began to defuse much of the behalf of VA early this year. NAS officials have been gathering criticism and suspicion by herbicide literature from VA (including VA's 18-volume granting service connection for literature review) and other sources, making contact with conditions science tells us may scientists and other interested parties throughout the country, have been caused by exposure to and assembling a committee of experts to complete the project Agent Orange--such as non-Hodgkin's lymphoma and soft envisaged by Congress in Public Law 102-4, the "Agent tissue sarcomas. Orange Act of 1991." We're still being criticized by some who think we haven't gone far enough, and by some who feel there's not sufficient scientific proof for the decisions we have made. The public reaction~and the general lessening of Initial Committee Meeting tensions~seems to indicate we're right. This may be an important lesson for VA... The NAS Institute of Medicine's Committee to Review Committee Membership the Health Effects in Vietnam Veterans of Exposure to Herbicides held its first meeting on June 26, in Washington, DC. The Committee is chaired by Harold Fallon, M.D., Chair The morning session, which was opened to invited guests and of the Department of Medicine of the Medical College of speakers, was devoted to providing Committee members with Virginia in Richmond, Virginia. -
In the UNITED STATES COURT of APPEALS for VETERANS CLAIMS
In the UNITED STATES COURT OF APPEALS FOR VETERANS CLAIMS 13 - 3339 _______________ ROBERT H. GRAY, Appellant, v. ROBERT MCDONALD, Secretary of Veterans Affairs, Appellee. Brief of Amicus Curiae, Blue Water Navy Vietnam Veterans Association, and Military-Veterans Advocacy John B. Wells LA Bar #23970 P. O. Box 5235 Slidell, LA 70469-5235 (mail) 769 Robert Blvd., Ste 201D Slidell, LA 70458 (physical) 985-641-1855 985-649-1536 (fax) [email protected] Table of Contents Table of Authorities........................................................... ii Interest of the Amicus Curiae....................................................v Statement of the Issues. ....................................................... vi Statement of the Case. ........................................................ 1 Summary of the Argument...................................................... 2 History of the Blue Water Navy Controversy. ..................................... 2 Argument.................................................................... 6 I. The Finding That Da Nang Harbor Was Not Part of Inland or Internal Waters Was Arbitrary and Capricious, Unsupported by Substantial Evidence and in Violation of International Treaties and Supreme Court Jurisprudence.................................................... 6 II. The BVA Erred in Not Finding that the Veteran Suffered Direct Exposure to Herbicides. .................................................. 10 III. The BVA Finding that the Veteran’s Departure from the Ship Was Not Documented in the Deck Log