Consensus on Intermediate Scale Salt Field Test Design

Total Page:16

File Type:pdf, Size:1020Kb

Consensus on Intermediate Scale Salt Field Test Design SAND2017-3179R Consensus on Intermediate Scale Salt Field Test Design Spent Fuel and Waste Disposition Prepared for US Department of Energy Spent Fuel and Waste Science and Technology Kristopher L. Kuhlman, Melissa M. Mills & Edward N. Matteo Sandia National Laboratories March 28, 2017 SFWD-SFWST-2017-000099 DISCLAIMER This information was prepared as an account of work sponsored by an agency of the U.S. Government. Neither the U.S. Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness, of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. References herein to any specific commercial product, process, or service by trade name, trade mark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the U.S. Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the U.S. Government or any agency thereof. Sandia National Laboratories is a multi-mission laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-AC04-94AL85000. Consensus on Intermediate Scale Salt Field Test Design March 2017 iii SUMMARY This report summarizes the first stage in a collaborative effort by Sandia, Los Alamos, and Lawrence Berkeley National Laboratories to design a small-diameter borehole heater test in salt at the Waste Isolation Pilot Plant (WIPP) for the US Department of Energy Office of Nuclear Energy (DOE-NE). The intention is to complete test design during the remainder of fiscal year 2017 (FY17), and the implementation of the test will begin in FY18. This document is the result of regular meetings between the three national labs and the DOE-NE, and is intended to represent a consensus of these meetings and discussions. The suite of tests is essentially modular, each test consisting of a central test borehole with water vapor collection and liquid brine sampling equipment, surrounded by satellite observation and instrumentation boreholes. Observation boreholes will be associated with temperature, electrical resistivity, and acoustic emission (AE) measurements. The first test of this modular design will be isothermal (no heating), and the second stage will be heated to a maximum borehole temperature of approximately 120°C. Later tests will be designed using information gathered from the first two boreholes, will be conducted at other temperatures, and may include other measurement types and test designs. The suite of field tests is focused on the objectives of quantifying brine availability, brine migration, and brine chemistry under heat-generating-waste relevant conditions in bedded salt. To accomplish the first two objectives, we will quantify the mass flowrate of water and conservative tracer into the borehole while circulating out humidity inside the central test borehole. Brine chemistry will be monitored through brine and gas sampling during the experiment. To interpret water inflow data, we will use thermal- hydrologic (TH), thermal-hydrologic-chemical (THC), and thermal-hydrologic-mechanical (THM) modeling to estimate formation properties, given the applied boundary conditions and observed inflow data. To interpret observed chemistry data, we will use thermal-chemical (TC) and THC models to interpret observed changes in the chemistry of inflowing brine, from observations of precipitating minerals and samples of brine composition while constantly removing water vapor from the borehole. Appendix A presents key components from historic heater tests in both bedded and domal salt. One motivation for this test is to “get back underground” and rebuild capabilities that have been lost with retiring staff since the bulk of in situ testing in salt was conducted in the 1980s. That being the case, this report presents key references and figures from previous tests as a first step in the design and implementation of the current suite of tests. ACKNOWLEDGEMENTS The SNL authors want to thank LANL and LBNL staff who actively participated in the development of the test design from the early stages, including Phil Stauffer, Hakim Boukhalfa, Doug Weaver, Brian Dozier, Shawn Otto, Jonny Rutqvist, and Yuxin Wu. We would like to thank those who reviewed and commented on aspects of the proposed experiment design and this report, including Pat Brady, Bob MacKinnon, Bill Spezialetti, Prasad Nair, Carlos Jové Colón, and Paul Domski. Special thanks to Michael Schuhen and Wes Deyonge for insightful comments and helpful advice on test design, to Paul Domski for providing WIPP brine chemistry data, and to Charles Bryan and Carlos Jové Colón for review and material related to brine chemistry and acid gas generation. Thanks to Ernie Hardin for technical and editorial review of the entire report; his suggestions improved the report and aspects of test design. Consensus on Intermediate Scale Salt Field Test Design iv March 2017 CONTENTS SUMMARY ................................................................................................................................................. iii ACKNOWLEDGEMENTS ......................................................................................................................... iii CONTENTS ................................................................................................................................................. iv ACRONYMS ............................................................................................................................................... ix 1. INTRODUCTION .............................................................................................................................. 1 1.1 Field Test Goals ....................................................................................................................... 1 1.2 Relevant History ...................................................................................................................... 3 1.3 Proposed Field Test in Context of Performance Assessment................................................... 4 2. FIELD EXPERIMENTAL PROCESS DESCRIPTION .................................................................... 5 2.1 Location and Design Strategy .................................................................................................. 5 2.1.1 Test Interval Location to Avoid Interbeds and DRZ .................................................. 6 2.1.1 Expected MU-0 Lithology .......................................................................................... 7 2.2 Heated Borehole Backfill Considerations .............................................................................. 10 2.3 Test Interval and Observation Boreholes ............................................................................... 11 2.4 Test Conditions and Features ................................................................................................. 12 2.4.1 Test Matrix ................................................................................................................ 12 2.4.2 Access Drift Monitoring ........................................................................................... 15 2.4.3 Salt Temperature Monitoring .................................................................................... 15 2.4.4 Vapor Collection and Gas Sampling ......................................................................... 15 2.4.5 Brine Composition Sampling .................................................................................... 18 2.4.6 Gas Flowrate Damage Testing .................................................................................. 18 2.4.7 Geomechanical Monitoring ....................................................................................... 19 2.4.8 Cement Exposure Test .............................................................................................. 20 2.4.9 Electrical Resistivity Surveys ................................................................................... 20 2.4.10 Deuterated Water Tracer ........................................................................................... 20 2.4.11 Acoustic Emission Monitoring ................................................................................. 21 2.5 Expected Test Conditions and Processes ............................................................................... 22 2.6 First Borehole Test Objectives ............................................................................................... 25 2.7 Second Borehole Test Objectives .......................................................................................... 27 2.8 Follow-on Borehole Test Objectives ..................................................................................... 28 2.8.1 Stepwise Heating....................................................................................................... 28 2.8.2 Sealed Borehole Test ................................................................................................ 28 2.8.3 Long-term Brine Availability .................................................................................... 29 2.8.4 Other Follow-on Measurement
Recommended publications
  • Brine Evolution in Qaidam Basin, Northern Tibetan Plateau, and the Formation of Playas As Mars Analogue Site
    45th Lunar and Planetary Science Conference (2014) 1228.pdf BRINE EVOLUTION IN QAIDAM BASIN, NORTHERN TIBETAN PLATEAU, AND THE FORMATION OF PLAYAS AS MARS ANALOGUE SITE. W. G. Kong1 M. P. Zheng1 and F. J. Kong1, 1 MLR Key Laboratory of Saline Lake Resources and Environments, Institute of Mineral Resources, CAGS, Beijing 100037, China. ([email protected]) Introduction: Terrestrial analogue studies have part of the basin (Kunteyi depression). The Pliocene is served much critical information for understanding the first major salt forming period for Qaidam Basin, Mars [1]. Playa sediments in Qaidam Basin have a and the salt bearing sediments formed at the southwest complete set of salt minerals, i.e. carbonates, sulfates, part are dominated by sulfates, and those formed at the and chlorides,which have been identified on Mars northwest part of basin are partially sulfates dominate [e.g. 2-4]. The geographical conditions and high eleva- and partially chlorides dominate. After Pliocene, the tion of these playas induces Mars-like environmental deposition center started to move towards southeast conditions, such as low precipitation, low relative hu- until reaching the east part of the basin at Pleistocene, midity, low temperature, large seasonal and diurnal T reaching the second major salt forming stage, and the variation, high UV radiation, etc. [5,6]. Thus the salt bearing sediments formed at this stage are mainly playas in the Qaidam Basin servers a good terrestrial chlorides dominate. The distinct change in salt mineral reference for studying the depositional and secondary assemblages among deposition centers indicates the processes of martian salts. migration and geochemical differentiation of brines From 2008, a set of analogue studies have been inside the basin.
    [Show full text]
  • Potash Case Study
    Mining, Minerals and Sustainable Development February 2002 No. 65 Potash Case Study Information supplied by the International Fertilizer Industry Association This report was commissioned by the MMSD project of IIED. It remains the sole Copyright © 2002 IIED and WBCSD. All rights reserved responsibility of the author(s) and does not necessarily reflect the views of the Mining, Minerals and MMSD project, Assurance Group or Sponsors Group, or those of IIED or WBCSD. Sustainable Development is a project of the International Institute for Environment and Development (IIED). The project was made possible by the support of the World Business Council for Sustainable Development (WBCSD). IIED is a company limited by guarantee and incorporated in England. Reg No. 2188452. VAT Reg. No. GB 440 4948 50. Registered Charity No. 800066 1 Introduction 2 2 Global Resources and Potash Production 3 3 The use of potassium in fertilizer 4 3.1 Potassium Fertilizer Consumption 4 3.2 Potassium fertilization issues 6 Appendix A 8 1 Introduction Potash and Potassium Potassium (K) is essential for plant and animal life wherein it has many vital nutritional roles. In plants, potassium and nitrogen are the two elements required in greatest amounts, while in animals and humans potassium is the third most abundant element, after calcium and phosphorus. Without sufficient plant and animal intake of potassium, life as we know it would cease. Human and other animals atop the food chain depend upon plants for much of their nutritional needs. Many soils lack sufficient quantities of available potassium for satisfactory yield and quality of crops. For this reason available soil potassium levels are commonly supplemented by potash fertilization to improve the potassium nutrition of plants, particularly for sustaining production of high yielding crop species and varieties in modern agricultural systems.
    [Show full text]
  • Mining Methods for Potash
    Potash—A Vital Agricultural Nutrient Sourced from Geologic Deposits Open File Report 2016–1167 U.S. Department of the Interior U.S. Geological Survey Cover. Photos of underground mining operations, Carlsbad, New Mexico, Intrepid Potash Company, Carlsbad West Mine. Potash—A Vital Agricultural Nutrient Sourced from Geologic Deposits By Douglas B. Yager Open File Report 2016–1167 U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior SALLY JEWELL, Secretary U.S. Geological Survey Suzette M. Kimball, Director U.S. Geological Survey, Reston, Virginia: 2016 For more information on the USGS—the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment—visit http://www.usgs.gov or call 1–888–ASK–USGS. For an overview of USGS information products, including maps, imagery, and publications, visit http://store.usgs.gov/. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. Although this information product, for the most part, is in the public domain, it also may contain copyrighted materials as noted in the text. Permission to reproduce copyrighted items must be secured from the copyright owner. Suggested citation: Yager, D.B., 2016, Potash—A vital agricultural nutrient sourced from geologic deposits: U.S. Geological Survey Open- File Report 2016–1167, 28 p., https://doi.org/10.3133/ofr20161167. ISSN 0196-1497 (print) ISSN 2331-1258 (online) ISBN 978-1-4113-4101-2 iii Acknowledgments The author wishes to thank Joseph Havasi of Compass Minerals for a surface tour of their Great Salt Lake operations.
    [Show full text]
  • Fertilizer Production Expertise HPD® Evaporation and Crystallization
    Fertilizer Production Expertise HPD® Evaporation and Crystallization WATER TECHNOLOGIES Fertilizer Expertise Case Study: Veolia NPK Fertilizers HPD® Evaporation and Crystallization systems from Veolia Research & Development NPK Process Capabilities Water Technologies provide innovative process solutions for large-scale fertilizer production facilities worldwide. IC Potash Corp. (ICP) - Sulfate of Potash (SOP) These systems allow production of a wide range of high-quality fertilizer products from natural sources (mined or solution mined deposits) or by-product streams from other processes that include: Chlorine / • Ammonium sulfate • Mono potassium phosphate Raw Materials Natural Gas Sulfur Phosphate Rock Hydrogen Gas Potash Source • Ammonium nitrate (MKP) • Potassium chloride (MOP) • Sodium nitrate • Potassium sulfate (SOP) • Phosphoric acid merchant/ technical/food/electrical • Monoammonium phosphate (MAP) grade ICP's Ochoa Mine project (New Mexico, USA) is • Diammonium phosphate • Potassium carbonate (DAP) • Potassium nitrate projected to produce approximately 714,000 TPY Ammonia Plant Sulfuric Acid Rock Grinding Hydrochloric Acid of Sulfate of Potash (SOP-K SO ) from Polyhalite • Epsom salt: Magnesium • Calcium phosphate 2 4 Plant Plant Plant ore (K SO .MgSO .2CaSO .2H O) for more than 50 sulfate heptahydrate • Calcium sulfate 2 4 4 4 2 years. • Magnesium sulfate • Calcium chloride monohydrate Veolia was selected to refine, confirm, and validate the overall ICP process utilizing HPD® Evaporation and Crystallization technologies through a series of bench and pilot-scale testing programs performed in Veolia’s in-house testing facility. The scope of the testing extended lants from the ore P leaching to the SOP crystallization process including Nitric Acid Plant Phosphoric Acid PlantPotassium Chloride Plant crystallization/redissolution of leonite (K2SO4.
    [Show full text]
  • S40645-019-0306-X.Pdf
    Isaji et al. Progress in Earth and Planetary Science (2019) 6:60 Progress in Earth and https://doi.org/10.1186/s40645-019-0306-x Planetary Science RESEARCH ARTICLE Open Access Biomarker records and mineral compositions of the Messinian halite and K–Mg salts from Sicily Yuta Isaji1* , Toshihiro Yoshimura1, Junichiro Kuroda2, Yusuke Tamenori3, Francisco J. Jiménez-Espejo1,4, Stefano Lugli5, Vinicio Manzi6, Marco Roveri6, Hodaka Kawahata2 and Naohiko Ohkouchi1 Abstract The evaporites of the Realmonte salt mine (Sicily, Italy) are important archives recording the most extreme conditions of the Messinian Salinity Crisis (MSC). However, geochemical approach on these evaporitic sequences is scarce and little is known on the response of the biological community to drastically elevating salinity. In the present work, we investigated the depositional environments and the biological community of the shale–anhydrite–halite triplets and the K–Mg salt layer deposited during the peak of the MSC. Both hopanes and steranes are detected in the shale–anhydrite–halite triplets, suggesting the presence of eukaryotes and bacteria throughout their deposition. The K–Mg salt layer is composed of primary halites, diagenetic leonite, and primary and/or secondary kainite, which are interpreted to have precipitated from density-stratified water column with the halite-precipitating brine at the surface and the brine- precipitating K–Mg salts at the bottom. The presence of hopanes and a trace amount of steranes implicates that eukaryotes and bacteria were able to survive in the surface halite-precipitating brine even during the most extreme condition of the MSC. Keywords: Messinian Salinity Crisis, Evaporites, Kainite, μ-XRF, Biomarker Introduction hypersaline condition between 5.60 and 5.55 Ma (Manzi The Messinian Salinity Crisis (MSC) is one of the most et al.
    [Show full text]
  • Experimental Drill Hole Logging in Potash Deposits Op the Cablsbad District, Hew Mexico
    EXPERIMENTAL DRILL HOLE LOGGING IN POTASH DEPOSITS OP THE CABLSBAD DISTRICT, HEW MEXICO By C. L. Jones, C. G. Bovles, and K. G. Bell U. S. GEOLOGICAL SURVEY This report is preliminary and has not been edited or Released to open, files reviewed for conformity to Geological Survey standards or nomenclature. COHTEUTS Page Abstract i Introduction y 2 Geology . .. .. .....-*. k Equipment 7 Drill hole data . - ...... .... ..-. - 8 Supplementary tests 10 Gamma-ray logs -T 11 Grade and thidmess estimates from gamma-ray logs Ik Neutron logs 15 Electrical resistivity logs 18 Literature cited . ........... ........ 21 ILLUSTRATIONS Figure 1. Generalized columnar section and radioactivity log of potassium-bearing rocks 2. Abridged gamma-ray logs recorded by commercial All companies and the U. S. Geological Survey figures 3« Lithologic, gamma-ray, neutron, and electrical resistivity logs ................. are in k. Abridged gamma-ray and graphic logs of a potash envelope deposit at end of 5« Lithologic interpretations derived from gamma-ray and electrical resistivity logs - ...... report. TABLE Table 1. Summary of drill hole data 9 EXPERIMENTAL DRILL HOLE LOGGING Iff POTASH DEPOSITS OP THE CARISBAD DISTRICT, HEW MEXICO By C. L. Jones, C. G. Bowles, and K. G>. Bell ABSTRACT Experimental logging of holes drilled through potash deposits in the Carlsbad district, southeastern Hew Mexico, demonstrate the consider­ able utility of gamma-ray, neutron, and electrical resistivity logging in the search for and identification of mineable deposits of sylvite and langbeinite. Such deposits are strongly radioactive with both gamma-ray and neutron well logging. Their radioactivity serves to distinguish them from clay stone, sandstone, and polyhalite beds and from potash deposits containing carnallite, leonite, and kainite.
    [Show full text]
  • Physical Properties Data for Rock Salt QC100 .U556 V167;1981 C.2 NBS-PUB-C 1981
    NATL INST OF STANDARDS & TECH R.I.C. NBS ,11100 161b7a PUBLICATIONS All 100989678 /Physical properties data for rock salt QC100 .U556 V167;1981 C.2 NBS-PUB-C 1981 NBS MONOGRAPH 167 U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards NSRDS *f»fr nun^^ Physical Properties Data for Rock Salt NATIONAL BUREAU OF STANDARDS The National Bureau of Standards' was established by an act of Congress on March 3, 1901. The Bureau's overall goal is to strengthen and advance the Nation's science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research and provides: (1) a basis for the Nation's physical measurement system, (2) scientific and technological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to promote public safety. The Bureau's technical work is per- formed by the National Measurement Laboratory, the National Engineering Laboratory, and the Institute for Computer Sciences and Technology. THE NATIONAL MEASUREMENT LABORATORY provides the national system of physical and chemical and materials measurement; coordinates the system with measurement systems of other nations and furnishes essential services leading to accurate and uniform physical and chemical measurement throughout the Nation's scientific community, industry, and commerce; conducts materials research leading to improved methods of measurement, standards, and data on the properties of materials needed by industry, commerce, educational institutions, and Government; provides advisory and research services to other Government agencies; develops, produces, and distributes Standard Reference Materials; and provides calibration services. The Laboratory consists of the following centers: Absolute Physical Quantities^ — Radiation Research — Thermodynamics and Molecular Science — Analytical Chemistry — Materials Science.
    [Show full text]
  • ~ United States Patent Office
    Patented Oct. 9, 1934 1,75,798 ~ UNITED STATES PATENT OFFICE 1,975,798 PROCESS FOR RECOVERING POTASSIUM SALTS FROM MINERALS Everett P. Partridge,‘ Park View Estates, and Foster Fraas, New Brunswick, N. J ., assignors to the United States of America, as represented by the Secretary of Commerce No Drawing. ApplicationJuly 21, 1932, Serial No. 623,810 11 Claims. (CI. 23-27) (Granted under the act of March 3, 1883, as amended April 30,1928; 37,0 0. G. 757) This invention described herein may be manu For example, when polyhalite, ground to pass a factured and used by or for the Government for screen with 10 meshes to the linear inch, is heated governmental purposes, Without the payment' to in contact with a stream of hydrogen, the poly us of any royalty thereon. _ ‘ halite is decomposed, with hydrogen sulphide, wa This invention relates to a method of treating ter vapor and free sulphur present in the waste 6 complex potassium minerals or salts for the gas. While‘reduction may take place slowly at’ purpose of manufacturinga product of relatively lower temperatures, it ?rst becomes evident at a high potassium content. _ temperature or approximately 650° C. The rate of reduction increases with increase in tempera The primary'object of the invention is the re 65 covery of potassium salts in ‘a valuable concen ture. This increase is particularly noticeable in trated form from the mineral polyhalite the range from 800 to 900° C. The volatilization of potassium compounds is small in this tempera (K2804.MgSO42CaSO42H2O) ture range, but increases rapidly with increase in temperature above approximately 1000° C.
    [Show full text]
  • Geology of the Tenth Potash Ore Zone, Permian Salado Formation
    ' OPEN FILE FEZOF2 146 GEOLOGY OF THE TENTH POTASH OREZONE: PERMIAN SALAD0 FORMATION, CARLSBAD DISTRICT, NEW MEXICO ROBERT C.M. GUNN AND JOHN M. HILLS I wish to thank the personnel of Noranda Mines Limited who allowed Gunn-to study and work on their potash exploration program, especially 0. Mr. Hinds, J. ,. Dr. J. J. M. Miller, Mr. J. Condon Mr.and J. F. Brewer., Information for this report could not have been obtained without their help and the friendly relation- ships with the following potash companies and individuals: Duval Corporation Mr. W. Blake Mr. M. P. Scroggin International Minerals and Chemical Corporation Mr. R. Koenig Kerr-McGee Chemical Corporation Mr. R. Lane National Potash Company Mr. P. Brewer United States Geological Survey Mr. C. L. Jones Independent Chemist who assayed Noranda potash core in Carlsbad Mr. T. J. Futch Independent Potash Consultant in Carlsbad Mr. E. H. Miller Dr. W. N. McAnulty, Dr. W. R. Roser and co-author Hills supervised Gun& original Masters thesis at Universityof Texas at El Paso upon which this paper is based. Dr. W. M. Schwerdtner of the University of Toronto has read the manuscript critically. Noranda Exploration Company has kindly permitted the publicationof insor- mation gathered from their properties. ABSTRACT The Tenth potash ore zone is a bedded evaporite deposit in the Permian (Ochoan) SaladoFormation in the Carlsbad district, Eddy and Lex counties, New Mexico.The rocksof the Tenth ore zone were precipitated in the super- saline part of the Permian basin and range from 6 to 10 feet (1.8 to 2.1 meters) .
    [Show full text]
  • K2SO4 Across the Neogene: Implications, Part 4 of 4
    www.saltworkconsultants.com Salty MattersJohn Warren - Tuesday, May 12, 2015 Danakil potash: K2SO4 across the Neogene: Implications, Part 4 of 4 marine brine feeds that most of the world’s larger Phaneorzo- How to deal with K2SO4 ic (SOP) potash ore deposits were precipitated (Warren, 2015). In this the fourth blog focusing on Danakhil potash, we look SOP is also produced from Quaternary Lake brines in China at the potash geology of formerly mined Neogene deposits in and Canada (see Cryogenic salt blog; 24 Feb. 2015). Sicily and the Ukraine, then compare them and relevant pro- cessing techniques used to exploit their K2SO4 ore feeds. This information is then used to hlep guide a discussion of process- ing implications for potash extraction in the Danakhil, where SOP in Messinian evaporites, Sicily kainite is the dominant widespread potash salt. As seen in the A number of potash mines on the island extracted kainitite from previous three blogs there are other potash mineral styles present the late Miocene Solofifera Series of Sicily (Figure 1). The last in the Danakhil, which constitute more re- stricted ore fairways than the widespread bedded kainaite, these other potash styles Sicilian-Maghrebian units (deep meteoiric -blog 2 of 4 and hydro- thermal - blog 3 of 4), could be processed Palermo X Kabylian-Calabrian units to extract MOP, but these other potash Calatami inner C styles are also tied to high levels of MgCl2, im Madonie M. in Petralia Nebrodi M. na b which must be dealt with in the brine pro- S. Ninfa asin Nicosia Be M.
    [Show full text]
  • Conversion of Langbeinite and Kieserite in Schoenite With
    ineering ng & E P l r a o c i c e m s e s Journal of h T C e f c h o Artus and Kostiv, J Chem Eng Process Technol 2015, 6:2 l ISSN: 2157-7048 n a o n l o r g u y o J Chemical Engineering & Process Technology DOI: 10.4172/2157-7048.1000225 Research Article Article OpenOpen Access Access Conversion of Langbeinite and Kieserite in Schoenite With Mirabilite and Sylvite in Water and Schoenite Solution Mariia Artus1* and Ivan Kostiv2 1Precarpathian National University named after V. Stephanyk 57, Shevchenko str., 76025 Ivano-Frankivsk, Ukraine 2State Enterprise Scientific-Research Gallurgi Institute 5a, Fabrychna str., 77300 Kalush, Ukraine Abstract The hydration of soluble Langbeinite and kieserite was investigated in the presence of potassium chloride and sodium sulfate. The addition of sodium sulfate affects water activity less than in the case of clean water. Therefore, we have conducted a research by adding water instead of schoenite solution. According to the results, hydration of Langbeinite by adding sodium sulfate in the first 240 hours occurs more intensively than without sodium sulfate with formation of a readily soluble schoenite and halite. Keywords: Langbeinite; Kieserite; Conversion ; Sodium sulfate; residue of hardly soluble langbeinite, kieserite and polyhalite, its drying Schoenite solution with obtaining potassium-magnesium concentrate, containing K2O - 20,4%, MgO – 16,0% and Cl - less than 1%. The solution after the Introduction stage of dissolution of ore is illuminated, evaporated, separated at first sodium chloride and then schoenite [5]. The polymineral potassium-magnesium ores contain both readily soluble minerals: kainite (KCl·MgSO4·3H2O), sylvite (KCl), halite During processing of kieserite hartzalts of Germany, containing (NaCl) as well as hardly soluble: langbeinite (K2SO4·2MgSO4), polyhalite 17-28% of kieserite, crushed ore is subjected to hot dissolution (K2SO4·MgSO4·2СаSO4·2H2O), kieserite (MgSO4·H2O).
    [Show full text]
  • Kieserite Mgso4 • H2O C 2001-2005 Mineral Data Publishing, Version 1
    Kieserite MgSO4 • H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Crystals are uncommon, dipyramidal {111}, with {110} and perhaps another dozen forms, to 10 cm; typically coarse- to fine-grained, massive. Twinning: On {001}, contact; polysynthetic about [110]. Physical Properties: Cleavage: On {110}, {111}, perfect; on {111}, {101}, {011}, imperfect. Tenacity: Friable to firm. Hardness = 3.5 D(meas.) = 2.571 D(calc.) = 2.571 Slowly soluble in H2O. Optical Properties: Translucent. Color: Colorless, pale gray, pale yellow; colorless in transmitted light. Luster: Vitreous. Optical Class: Biaxial (+). Orientation: Y = b; Z ∧ c = –76.5◦. Dispersion: r> v,moderate. α = 1.520 β = 1.533 γ = 1.584 2V(meas.) = 55◦ Cell Data: Space Group: C2/c. a = 6.912(2) b = 7.624(2) c = 7.642(2) β = 118.09(2)◦ Z=4 X-ray Powder Pattern: Klodawa, Poland. (ICDD 13-102). 3.41 (10), 4.84 (9), 3.33 (9), 2.527 (9), 2.055 (9), 3.05 (8), 2.567 (8) Chemistry: (1) (2) SO3 57.93 57.85 MgO 29.00 29.13 H2O 13.07 13.02 Total 100.00 100.00 • (1) Stassfurt, Germany. (2) MgSO4 H2O. Mineral Group: Kieserite group. Occurrence: Typically in marine salt deposits; rarely as a volcanic sublimate or efflorescence. Association: Halite, carnallite, polyhalite, anhydrite, boracite, sulfoborite, leonite, epsomite, celestine. Distribution: In Germany, from the Stassfurt-Westeregeln district, with large crystals from the Bartensleben mine, Saxony-Anhalt; in the Hildesia mine, near Hannover, and at Wathlingen, Lower Saxony, and many other places.
    [Show full text]