Electricity on Demand
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Photovoltaics energy storage t takes neither a science fiction fan nor a clairvoy- ant to launch the theory that electricity will be the Ideterminant energy form of the future. It is simply the most logical development. Electricity can be used safely and efficiently in all manner of applications, and – when generated from a renewable source – is also clean energy. But electricity does have one decisive disadvan- tage: it must be consumed immediately – storage has to date remained both complex and subject to expen- sive losses. The limited capacity of storage batteries, for example, is the chief obstacle to the widespread breakthrough of electric cars, a path of development with the potential to solve a massive share of the glo- bal CO2 problem. When oil tanks or coal bunkers are taken as the yardsticks for the energy density, cost ef- fectiveness and useful lifetime of electricity storage technologies, it becomes painfully evident: the stor- age problem is yet to be solved for electricity. This fact naturally has direct repercussions for the photovoltaics sector with its dependence on sun- light as a primary energy source. When the European PV industry claims that it is prepared to cover half of the continent’s power demand with solar electricity by 2050, then this must necessarily be described as ambitious. It will require not only reliable supplies of materials, sufficient investment capital and adequate manufacturing capacities, but also a solution to the storage problem – and that well before 2050. Many circumstances can be covered by the power supply systems in the industrialised countries, but one op- tion is very definitely unacceptable, namely that half of the generating capacity simply goes off-grid when darkness falls. If electricity is to be generated from re- newable sources on a larger scale, then it must also be possible to store it. Of the renewable energies cur- rently under discussion, only biogas seems suitable as a baseload source. Wind and solar energy, by con- trast, are subject to marked fluctuation: you may get the full nominal output, or nothing at all – depending Decentralised and fluctuating power generation from the sun and wind is becoming on the momentary irradiation or wind intensity. more and more widespread. The expansion of power grids is thus important – but still not sufficient. Storage capacities are imperative. Photos (2): E.on Netz Diverse approaches Various, in some cases quite exotic projects are aimed at overcoming today’s expensive and cumber- some battery concepts. In 2007, there were press re- Electricity on ports that Sony is working on a bio-battery which functions on the principle of photosynthesis. A year ago, news spread concerning experiments aimed at developing a bio-battery at the University of Colora- do. The idea: cells pump ions through a membrane demand and produce a potential difference which can be ex- ploited. It is similarly two years since the scientific There are certain technology challenges which have waited journal “Technology Review” reported on a battery prototype devised at the Japanese elite university in vain over several decades for a satisfactory solution. The Waseda. It is less than a millimetre thick, can be fully economical storage of electricity is one of them. But charged in just one minute and is said to handle 1,000 charging cycles. The positive electrode of the intensive work in the meantime is driving advances along battery is made not from a metallic compound, but in- stead from polymers. The cathode film forms only af- various avenues . ter the precursor material is subjected to UV radia- 108 Sun & Wind Energy 4/2009 tion. According to “Technology Review”, the perfor- The first commercial availability is expected for 2009, mance data of the battery are satisfactory: 0.84 volts but there are only two manufacturers worldwide. and a specific capacity of 106 mAh. The journal has also described a flexible battery in connection with Vanadium redox flow battery: This battery type func- the European solar polymer battery project: this bat- tions with salts dissolved in a liquid electrolyte. The tery comprises further-developed lithium ion batte- electrolyte is held in separate tanks and is only ries which are charged via an integrated dye solar pumped to the electrodes and the membrane in the cell. The battery is extremely thin and light, and with- central reaction cell when necessary. The vanadium stands also high temperatures. But several more redox flow battery is just one of a number of material years can be expected to pass before these new con- variants, but “is still the only one which functions”, cepts are ready for practical applications. says Dirk Uwe Sauer, Professor and storage expert at the RWTH University in Aachen, Germany. This points Common battery concepts to interesting cost-reducing potential, because vana- dium, after all, is expensive. The batteries impress by For the time being, we must continue to make do with way of a long lifetime and their insensitivity to deep the familiar electrochemical storage media which discharging. There are presently three commercial function according to the principle: Electrode materi- suppliers, one of whom – VRB Power, headquartered al reacts with electrolyte. The lithium battery is the in Richmond, Canada – covers the wider spectrum only chemistry-free alternative: The ions are here from 5 to 10,000 kW. European Sales Manager Hugh pumped from one electrode to the other. Sharman estimates the 2008 turnover to have been Only a few of the battery concepts can be deemed one million dollars and sees an annual “doubling, if promising, as an overview reveals: not more”. According to Sharman, the concept has al- ready begun to steal business from the lead battery Lead battery: This is still the workhorse option. The in the field of telecommunications. lead battery is an inexpensive, technically mature system with a high level of efficiency, but also one Sodium-nickel chloride battery: This “high-tempera- significant drawback: the limited lifetime. The high ture” battery – also known as the “ZEBRA battery” – weight is generally not a problem for fixed-location requires an operating temperature of around 350°C applications. Lead batteries are thus the measure for to be maintained, though this can be guaranteed any new storage technology. It is difficult to imagine through its own heat generation while kept on charge. any kind of further “research breakthrough” for this The lifetime of the sodium-nickel chloride battery fur- battery type. The massive demand for standardised ther exceeds that of the vanadium redox flow battery, batteries for fixed installations, however, could force its efficiency ratio is better, and it is also a little the price down still further: whereas the cheapest cheaper in daily operation. Vital development re- The tasks for grid control lead batteries with slow discharge rates for non- search is still ongoing, as there are safety issues con- centres – like that of the E.on mobile use are priced at around 100 €/kWh, car start- cerning the molten sodium, which causes sealing Netz in Lehrte/Germany – er batteries cost barely 25 €/kWh. problems. The battery is currently undergoing testing would be made much simpler in electric vehicles. The only two fixed installations to in future if solar electricity Zinc-bromine battery: This type of battery is in the date are to be found in Canada and Great Britain. could be stored at the place of meantime no more expensive than a lead battery, but generation. achieves twice the lifetime. Even so, it has so far not Sodium-sulphur battery: This battery has a lot in advanced beyond demonstration projects with stor- common with the sodium-nickel chloride battery, in- age capacities of up to 500 kWh in the USA and Japan. cluding the high temperature, and is already in quite Sun & Wind Energy 4/2009 109 Photovoltaics energy storage widespread use in Japan – albeit for grid stabilisation water which is required for an open lead battery. This rather than for off-grid energy storage. Again as with is no doubt in part why nickel-cadmium batteries are the sodium-nickel chloride battery, there is only one still the only non-lead systems in use for 840 instal- manufacturer of such batteries. lations with off-grid photovoltaic generation in China, for example. One important disadvantage is the re- Lithium-ion battery: The market share of this battery duced capacity after a partial discharge. Moreover, type is increasing constantly. To date, however, the the batteries contain more than 0.002 % of the high- extremely high efficiency and low weight – a decisive ly toxic heavy metal cadmium, which means that they factor for laptops, mobile phones and vehicles – have been banned in the EU since 2008 – with the ex- must be traded off again high costs and inferior safe- ception of batteries for cordless electric tools. ty. Dirk Uwe Sauer nevertheless expects “a signifi- cant reduction in the costs to around 300 €/kWh for Nickel-metal hydride battery: These batteries incor- non-mobile batteries without peripherals in the com- porate a cathode with nickel hydroxide and an anode ing years”, and believes that the technology could of a metal hydride – a metal alloy capable of revers- play “a key role in many areas of electrical energy ible hydrogen storage. The electrolyte is an alkali of storage” in the medium term. This assessment is potassium. Nickel-metal hydride batteries have es- backed by the fact that there are many manufactur- sentially replaced their NiCd counterparts. The ener- ers and variants of the technology. On the other gy density is twice that of a nickel-cadmium battery, hand, the availability of lithium is as limited as that but they react sensitively to overcharging and over- of many other resources.