Professor Helmer Fjellvåg, Publication List

Total Page:16

File Type:pdf, Size:1020Kb

Professor Helmer Fjellvåg, Publication List Professor Helmer Fjellvåg, University of Oslo − Publication list Publication list (Full publications in international journals with referee) 1. On the structural and magnetic properties of Cr1-tVtP, Mn1-tVtP and Mn1-tCrtP Selte, K., Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A33 (1979) 391-395 2. Magnetic structures and properties of Cr1-tFetAs Selte, K., Fjellvåg, H., Kjekshus, A. and Andresen, A.F. Acta Chem. Scand. A33 (1979) 727-731 3. Magnetic properties of transition metal substituted MnP. Fjellvåg, H., Kjekshus, A., Zieba, A. and Foner, S. J. Phys. Chem. Solids 45 (1984) 709-718. 4. Magnetic and structural properties of transition metal substituted MnP. I. Mn1-tCotP (0.00 ≤ t ≤ 0.30). Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A38 (1984) 563-573. 5. On the structural and magnetic properties of Co1-tNitAs and CoAs1-xSbx. Fjellvåg, H., Selte, K. and Stave, F. E. Acta Chem. Scand. A38 (1984) 687-691. 6. Magnetic and structural properties of transition metal substituted MnP. II. Mn1-tVtP (0.00 ≤ t ≤ 0.25). Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A38 (1984) 703-710. 7. Magnetic and structural properties of transition metal substituted MnP. III. Mn1-tFetP (0.00 ≤ t ≤ 0.30). Fjellvåg, H., Kjekshus, A. and Andresen, A. F. Acta Chem. Scand. A38 (1984) 711-717. 8. Magnetic and structural properties of transition metal substituted MnP. IV. Mn1-tNitP. Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A38 (1984) 719-724. 9. Structural and magnetic properties of Mn1-tMotAs Fjellvåg, H., Selte, K. and Danihelka, P. Acta Chem. Scand. A38 (1984) 789-794. 10. Neutron diffraction investigation of MnAs under high pressure Andresen. A.F., Fjellvåg, H. and Lebech, B. J. Magn. Magn. Mat. 43 (1984) 158-160. 11. On the magnetic and structural properties of the MnAs1-xPx system (x ≤ 0.18) Fjellvåg, H. Andresen, A.F. and Bärner, K.J. Magn. Magn. Mat. 46 (1984) 29-39. 12. Formation and crystal structure of ThNi2Dx. Andresen. A. F., Fjellvåg, H. and Maeland, A. J. J. Less- Common Metals 103 (1984) 27-31 13. Magnetic behaviour of Mn1-tCrtAs (0.20 < t 0.40) Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A38 (1984) 1-13. 14. Structural and magnetic phase diagram for the MnAs-CrAs system. Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A39 (1985) 671-680. 15. Pressure induced phase transitions in MnTe2. Fjellvåg, H. Kjekshus, A. Chattopadhyay, T. K., Hochheimer, H. D., Hönle, W. and von Schnering, H. G. Phys. Lett. 112A (1985) 411-413. 16. Magnetic and structural properties of transition metal substituted MnP. V. Mn1-tCrtP (0.00 ≤ t ≤ 0.40). Fjellvåg, H., Kjekshus, A. and Andresen, A. F. Acta Chem. Scand. A39 (1985) 143-151. 17. Magnetic and structural properties of transition metal substituted MnP. VI. Mn1-tMotP and Mn1-tWtP. Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A39 (1985) 199-207. 18. Magnetic and structural properties of Cr1-tTitAs. Fjellvåg, H. and Kjekshus, A. J. Solid State Chem. 59 (1985) 9-22. 19. Structural and magnetic properties of Mn1-tTitAs. Zieba, A., Fjellvåg, H. and Kjekshus, A. J. Phys. Chem. Solids 46 (1985) 275-286. 20. Effect of magnetic field on MnAs0.88P0.12 below 80 K. Fjellvåg, H., Kjekshus, A. and Andresen, A.F. J. Magn. Magn. Mat. 50 (1985) 287-290. 21. On the crystal structure and magnetic properties of MnNiGe. Fjellvåg. H. and Andresen, A. F. J. Magn. Magn. Mat. 50 (1985) 291-297. 22. On the properties of Ni2SnP Furuseth, S. and Fjellvåg, H. Acta Chem. Scand. A39 (1985) 537-544. Acta Chem. Scand. A39 (1985) 143-151. 23. Crystal and magnetic structure of MnSb2O4. Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A39 (1985) 389-395. 24. Christensen, A. N., Fjellvåg, H. and Lehmann, M. S. "A time resolved powder neutron diffraction investigation of reactions of Portland cement compounds with water." Acta Chem. Scand. A39 (1985) 593-604.. 25. Paramagnetic scattering experiments on MnAs1-xPx with x=0.06, 0.12 and 0.18. Andresen, A. F., Fjellvåg, H., Steinsvoll, O., Kjekshus, A., Stølen, S. and Bärner, K. J. Magn. Magn. Mat. 62 (1986) 241-246. 26. Pressure induced transition in MnAs and MnAs0.80Sb0.20. Fjellvåg, H., Hochheimer, H. D. and Hönle, W. Phys. Lett. A118 (1986) 293-296. 27. Structural properties of Ni3+xSn4. Furuseth, S. and Fjellvåg, H. Acta Chem. Scand. A40 (1986) 695-700. 28. Structural properties of HfTe5 and ZrTe5 as seen by powder diffraction. Fjellvåg, H. and Kjekshus, A. Solid State Commun. 60 (1986) 91-93. 29. Pressure induced heli- to ferromagnetic transition in Mn0.615Cr0.385As. Andresen, A. F., Fjellvåg, H., Kjekshus, A. and Lebech, B. J. Magn. Magn. Mat. 62 (1986) 247-250. 30. Single crystal study of Mn0.8Co0.20P. Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A40 (1986) 634- 63630. 31. Structural properties of Mn1-tFetP (0.80 ≤ t ≤ 1.00). Fjellvåg, H., Kjekshus, A. and Andresen, A.F. Acta Chem. Scand. A40 (1986) 227-229. 32. Martensitic-like transformations in CrtMn1-tAs. Andresen, A.F., Bärner, K., Fjellvåg, H., Heinemann, K., Kjekshus, A. and Sondermann, U. J. Magn. Magn. Mat. 58 (1986) 287-296. 33. Structural and magnetic properties of MnAs0.90P0.10. Fjellvåg, H., Kjekshus, A. and Stølen, S. J. Solid State Chem. 64 (1986) 123-133. 34. Structural properties of VP1-xAsx. Fjellvåg, H. and Kjekshus, A. Mh. Chemie 117 (1986) 773-781. 35. Structural and magnetic properties of Mn1-tNitAs. Fjellvåg, H. Kjekshus, A. Andresen, A. F. and Zieba, A. J. Magn. Magn. Mat. 61 (1986) 61-8025. 36. Solid solution phases with MnP type structure: T1-tNitP (T = Ti - Co). Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A40 (1986) 8-16. 37. Structural and magnetic properties of V1-tTitAs. Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A40 (1986) 17-22. 38. Structural properties of Co3Sn2, Ni3Sn2 and some ternary derivatives. Fjellvåg, H. and Kjekshus, A. Acta Chem. Scand. A40 (1986) 23-30. 39. Adiabatic calorimetry and neutron diffraction studies of Ni(ND3)6](NO3)2. Andresen, A. F., Fjellvåg, H., Janik, J. A., Mayer, J., Sciesinski, J., Janik, J. M., Migdal-Mikuli, A., Mikuli, E., Rachwalska, M. and Stanek, T. Physica 138B (1986) 295-304. 40. The effect of additives on the reaction of Portland and alumina cement compounds with water. A time resolved powder neutron diffraction investigation. Christensen, A. N., Fjellvåg, H. and Lehmann, M. S. Acta Chem. Scand. A40 (1986) 126-141. 41. Time resolved powder neutron diffraction investigations of reactions of solids with water. Christensen, A. N., Fjellvåg, H. and Lehmann, M. S. Cem. Concr. Res. 16 (1986) 871-874. 42. On the low-high spin anomaly in the heat capacity of MnAs1-xPx. Fjellvåg, H., Grønvold, F., Kjekshus, A. and Stølen, S. J. Phys. C 20 (1987) 3005-3010. 43. Magnetic ordering in MnSe2. Chattopahyay, T., Rossat-Mignod, J. and Fjellvåg, H. Solid State Commun. 63 (1987) 65-67. 44. Low-temperature oxidative degradation of low-dimensional zirconium and hafnium tellurides. Fjellvåg, H., Furuseth, S., Kjekshus, A. and Rakke, T. Solid State Commun. 63 (1987) 293-297. 45. Magnetic phase transtion in MnTe2. Chattapadhyay, T. and Fjellvåg, H. Phys. Lett. A 120 (1987) 44-46. 46. Heat capacity of MnAs0.88P0.12 from 10 to 500 K. Thermodynamic properties and transitions. Labban, A. K., Westrum, E. F. Jr., Fjellvåg, H., Grønvold, F., Kjekshus, A. and Stølen, S. J. Solid State Chem. 70 (1987) 185-198. 47. Structural properties of Ni1-tRhtBi3. Fjellvåg, H. and Furuseth, S. J. Less-Common metals 128 (1987) 177-183. 48. Effect of external pressure and chemical substitution on the phase transitions in MnAs. Zieba, A., Zach, R., Fjellvåg, H. and Kjekshus, A. J. Phys. Chem. Solids 48 (1987) 79-89. 49. Thermal, magnetic and structural aspects of transitions in Mn0.63Cr0.37As. Thermodynamic properties from 10 to 350 K. Komada, N., Westrum, E. F. Jr., Fjellvåg, H. and Kjekshus, A. J. Magn. Magn. Mat. 65 (1987) 37-52. 50. Transitions between helimagnetic states in Mn1-tCrtAs: Phase diagram and effect of strong magnetic field. Zieba, A., Fjellvåg, H. and Kjekshus, A. J. Magn. Magn. Mat. 68 (1987) 115-132. 51. Change in character of the paramagnetic to helimagnetic phase transtion in CrAs upon MnAs substitution. Fjellvåg, H., Kjekshus, A. and Zieba, A. J. Magn. Magn. mat. 67 (1987) 354-364. 52. Magnetic structure of MnP as probed by 57Fe. Häggström, L. , Sundqvist, T. and Fjellvåg, H. Phys. Rev. B 35 (1987) 6838-6840 53. Structure determination by use of the pattern decomposition and the Rietveld method on synchrotron X-ray and neutron powder data ; the structure of Al2Y4O9 and I2O4. Lehmann, M. S., Christensen, A. N., Fjellvåg, H., Feidenhans´l, R. and Nielsen, M. J. Appl. Cryst. 20 (1987) 123-129 54. Structural properties and phase transitions of Y2BaCuO5 and YBa2Cu3O9-d Fjellvåg, H., Karen, P. and Kjekshus, A. Acta Chem. Scand. A41 (1987) 283-293 55. X-ray photoelectron spectroscopy study of Y2BaCuO5 and YBa2Cu3O9-d \ Fjellvåg, H., Karen, P., Kjekshus, A. and Grepstad, J. K. Solid State Commun. 64 (1987) 917-921. 56. Crystal structure of Y2Cu2O5 refined from powder neutron diffraction data. Fjellvåg, H., Karen, P. and Kjekshus, A .Acta Chem. Scand. A42 (1988) 144-147. 57. On the properties of the YBa8Cu4O12+d phase Fjellvåg, H., Karen, P., Kjekshus, A. and Grepstad, J. K. Acta Chem. Scand. A42 (1988) 171-177. 58. Carbonatization of YBa2Cu3O6+x. Fjellvåg, H., Karen, P., Kjekshus, A., Kofstad, P. and Norby, T. Acta Chem. Scand. A42 (1988) 178-184. 59. Structural and magnetic properties of Mn1-tCrtAs1-xPX. Fjellvåg, H., Kjekshus, A.
Recommended publications
  • Doped Lanthanum Manganite Thin Films for SOFC Application
    INTERNATIONAL JOURNAL OF SCIENTIFIC & TECHNOLOGY RESEARCH VOLUME 5, ISSUE 04, APRIL 2016 ISSN 2277-8616 Spectroscopic And Electrical Properties Of Strontium - Doped Lanthanum Manganite Thin Films For SOFC B. S. Kamble, V. J. Fulari, R. K. Nimat Abstract: Strontium-doped lanthanum manganite (La1-xSrxMnO3-δ-LSM) has received much attention in recent years. Most studies have concentrated on thin film samples at low temperatures. La1-xSrxMnO3-δ (LSM) has proved to be efficient cathode material for solid oxide fuel cell (SOFC). In the present work the strontium-doped lanthanum manganite (La0.9Sr0.1MnO3-δ) were synthesized by spray pyrolysis technique in the thin film form on alumina substrate which was characterized by X-ray diffraction, scanning electron microscopy. The spectroscopic properties such as IR, FT-Raman have been studied. The temperature dependence resistivity and Dielectric constant was carried out at different frequencies. Film thickness measurement was carried out by using surface profilometer. X-ray diffraction results clearly indicated that sintered LSM at 900oC for 2 hours show the formation of single phase solid solution with pervoskite like structure. Crystalline size has been calculated by SEM microscopy. Resistivity of LSM thin film decreases as absolute temperature increases and Dielectric constant suddenly decreases at low frequency and became constant as frequency increases. The film thickness is about 200 nm and roughness of the sample is 4000Ao. Keywords: Spray Pyrolysis, Cathode, LSM, SOFC. ———————————————————— 1. Introduction: The strontium doped lanthanum manganite La1-xMxMnO3, The power generation by clean, efficient and eco-friendly is where, M=Alkaline earth metal, plays the attention as the biggest challenge for scientists and engineers.
    [Show full text]
  • Solid Oxide Fuel Cells: Strontium-Doped Lanthanum Manganite Obtained by the Citrate Technique
    Solid Oxide Fuel Cells: Strontium-Doped Lanthanum Manganite Obtained by the Citrate Technique R. Chiba, R. A. Vargas, M. Andreoli, E. S. M. Seo Instituto de Pesquisas Energéticas e Nucleares - IPEN/CNEN - SP Centro de Ciência e Tecnologia de Materiais - CCTM Laboratório de Células a Combustível: Componentes Av. Prof. Lineu Prestes, 2242 - Cidade Universitária CEP 05508-000 - São Paulo - Brazil [email protected] Keywords: solid oxide fuel cell, strontium-doped lanthanum manganite, cathode, citrate technique. Abstract: Nowadays, the La1-XSrXMnO3 (LSM) is one of the most common cathodic materials used in the solid oxide fuel cells (SOFCs). The dopant strontium increases the electronic conductivity of the material, besides presenting an excellent electrochemical performance, relatively good chemical and thermal stability and compatibility with solid electrolyte of ZrO2/Y2O3 (YSZ). In this work, a contribution to the study of synthesis of LSM is presented with strontium concentration of 50 mol % by the citrate technique. The powders have been characterized for various techniques, as gas absorption and adsorption, X-ray fluorescence spectroscopy, laser scattering granulometry, gas helium picnometry, scanning electron microscopy (SEM), X-ray diffractometry (XRD) and calculations of theoretical density and particle average diameter. The ceramics have been characterized by SEM and XRD. The adequate characteristics of LSM have been evaluated aiming at the use in the preparation of suspensions for thin films cathodic of SOFCs. Introduction The strontium-doped lanthanum manganite (La1-XSrXMnO3 - LSM) is a ceramic material of great importance, which had mainly to its use as cathode in solid oxide fuel cells (SOFCs), that operate in high temperatures (800 to 1000 °C).
    [Show full text]
  • Role of Point Defects on the Properties of Manganites
    RECENT RESEARCH DEVELOPMENTS IN PHYSICS ROLE OF POINT DEFECTS ON THE PROPERTIES OF MANGANITES Lorenzo Malavasi*a, Maria Cristina Mozzatib, Paolo Ghignaa, Gaetano Chiodelli a, Carlo B. Azzonib and Giorgio Flora a Dipartimento di Chimica Fisica “M. Rolla”, INSTM, IENI/CNR Unità di Pavia of Università di Pavia, V.le Taramelli 16, I-27100, Pavia, Italy. *E-mail: [email protected] bINFM, Unità di Pavia and Dipartimento di Fisica “A. Volta”, Università di Pavia, Via Bassi 6, I-27100, Pavia, Italy. Abstract La1-xCaxMnO3+δ and La1-xNaxMnO3+δ samples with well defined cation molecularity and oxygen contents are analyzed with XRPD, electrical conductivity, electron paramagnetic resonance and static magnetization measurements. Point defects are introduced in the structure by: i) aliovalent cation doping (substitutional defects), ii) oxygen over-stoichiometry (cation vacancies) and iii) oxygen under-stoichiometry (oxygen vacancies). The cation doping mainly influences the material by affecting the tolerance factor and the oxidation of the Mn ions; the cation vacancies affect the magnetic properties by interrupting the interaction paths between Mn4+-Mn3+ ions whereas the oxygen vacancies have a stronger influence on the structural and electrical properties and act on the magnetic properties by the overall decrease on the Mn4+ amount and by the creation of sample regions with different magnetic features. We can state that the basic magnetic and electrical behaviors of the Ca- and Na-doped lanthanum manganite compounds are driven from the Mn4+-Mn3+ ratio and all the peculiar behaviors are indeed caused by defects, concentration gradient and, more generally, by lattice disorder. 1 Introduction Rare Earth manganite perovskites of general formula Ln1-xAxMnO3 (Ln = La, Pr; A = Ca, Sr) are, at present, among the most studied materials due to their relevant properties such as the colossal magneto-resistance (CMR) effect and charge and spin order.
    [Show full text]
  • Doping Strontium Into Neodymium Manganites Nanocomposites for Enhanced Visible Light Driven Photocatalysis
    www.nature.com/scientificreports OPEN Doping Strontium into Neodymium Manganites Nanocomposites for Enhanced Visible light Driven Received: 9 March 2019 Accepted: 13 August 2019 Photocatalysis Published: xx xx xxxx I. A. Abdel-Latif1,3,4, L. A. Al-Hajji2, M. Faisal3 & Adel A. Ismail2,5 Nd1−xSrxMnO3 nanocomposites perovskites were synthesized using sol gel method at diferent Sr content x = 0.3, 0.5, 0.7, and 0.9. The photocatalytic performance of the Nd1−xSrxMnO3 nanocomposites for photodegradation of Acridine orange dye (AO) was evaluated over visible light illumination. The single phase of orthorhombic pbnm was formed for x = 0.3 and 0.5; however monoclinic and orthorhombic were observed at x = 0.7 and 0.9. The Energy gap of the Nd1−xSrxMnO3 nanocomposites were estimated for all concentrations to be in the range of 3 ± 0.05 eV. The photocatalytic efciency of Nd0.3Sr0.7MnO3 nanocomposite was 95% of the initial AO dye concentration within 3 h illumination time. The linear increase of the photodegradation rate was found in our samples as a result of the increase of Sr contents from 0.3 to 0.7wt %. Interestingly, the Nd0.3Sr0.7MnO3 content has the highest degradation rate of AO which is two times faster than undoped NdMnO3. This superior behavior in photocatalytic activity of Nd0.3Sr0.7MnO3 nanocomposite emerges from large surface area, structural anisotropy, and small particle size. These fndings shows convincingly that the Nd1−xSrxMnO3 photocatalysts possess great promise for visible light driven photodegradation of AO dye. Serious environmental problems and daily energy demand are crucial subject to which increase the scientifc attention in order to develop new nontoxic, inexpensive, stable, and efcient materials to solve these issues.
    [Show full text]
  • AC Conductivity and Dielectric Study of Strontium Doped
    International Journal of Scientific Research in _______________________________ Research Paper . Physics and Applied Sciences Vol.6, Issue.5, pp.115-117, October (2018) E-ISSN: 2348-3423 A. C. Conductivity and Dielectric Study of Strontium Doped Lanthanum Manganite (LSM) thin films as Cathode for SOFC B. S. Kamble1*, V. J. Fulari2, R. K. Nimat3 1Department of Physics, D. B. J. College, Chiplun-415605, India 2Department of Physics, Shivaji University, Kolhapur-416004, India 3Department of Physics, Balasaheb Desai College, Patan-415206, India *Corresponding Author: [email protected] Available online at: www.isroset.org Received: 27/Sept/2018, Accepted: 19/Oct/2018, Online: 31/Oct/2018 Abstract- A.C. conductivity of LSM thin film prepared by spray pyrolysis technique and sintered at 900OC was measured at room temperature having various strontium concentrations. The results reveal that as strontium content increases a. c. conductivity increases. The experimental results of doped LSM thin films reveal that correlated barrier hopping (CBH) model is the most suitable model to explain the a. c. conduction mechanism. The dielectric constant was measured keeping frequency constant with varying temperature and it is found that as temperature increases dielectric increases and after peak it decreases. Keywords- Spray Pyrolysis, a. c. conductivity, Dielectric constant, Cathode, LSC, SOFC. I. INTRODUCTION chemical vapour deposition, Sol-gel and spray pyrolysis [4- 8]. Among these methods, the spray pyrolysis is simple, Recently, many researchers have been working on cost effective technique. In the present study LSM thin designing solid oxide fuel cell (SOFC) cathode materials film were synthesized by spray pyrolysis technique. A.C. which will reduce the operating temperature.
    [Show full text]
  • Perovskites in the Energy Grid and CO2 Conversion: Current Context and Future Directions
    catalysts Review Perovskites in the Energy Grid and CO2 Conversion: Current Context and Future Directions Ahmad Tabish 1,2 , Anish Mathai Varghese 1, Md A. Wahab 3 and Georgios N. Karanikolos 1,4,5,* 1 Department of Chemical Engineering, Khalifa University, P.O. Box 127788, Abu Dhabi, UAE; [email protected] (A.T.); [email protected] (A.M.V.) 2 Global Innovative Center for Advanced Nanomaterials, School of Engineering, Faculty of Engineering and Built Environment, The University of Newcastle, Ring Rd, Callaghan 2308, Australia 3 Institute of Advanced Study, Chengdu University, Chengdu 610106, China; [email protected] 4 Center for Catalysis and Separations (CeCaS), Khalifa University, P.O. Box 127788, Abu Dhabi, UAE 5 Research and Innovation Center on CO2 and H2 (RICH), Khalifa University, P.O. Box 127788, Abu Dhabi, UAE * Correspondence: [email protected] Received: 28 November 2019; Accepted: 25 December 2019; Published: 9 January 2020 Abstract: CO2 emissions from the consumption of fossil fuels are continuously increasing, thus impacting Earth’s climate. In this context, intensive research efforts are being dedicated to develop materials that can effectively reduce CO2 levels in the atmosphere and convert CO2 into value-added chemicals and fuels, thus contributing to sustainable energy and meeting the increase in energy demand. The development of clean energy by conversion technologies is of high priority to circumvent these challenges. Among the various methods that include photoelectrochemical, high-temperature conversion, electrocatalytic, biocatalytic, and organocatalytic reactions, photocatalytic CO2 reduction has received great attention because of its potential to efficiently reduce the level of CO2 in the atmosphere by converting it into fuels and value-added chemicals.
    [Show full text]
  • Evaluating Transition-Metal Oxides Within DFT-SCAN and SCAN+U Frameworks for Solar Thermochemical Applications 1Gopalakrishnan Sai Gautam and 2Emily A
    Evaluating transition-metal oxides within DFT-SCAN and SCAN+U frameworks for solar thermochemical applications 1Gopalakrishnan Sai Gautam and 2Emily A. Carter 1Department of Mechanical and Aerospace Engineering and 2School of Engineering and Applied Science, Princeton University, Princeton, NJ 08544-5263, United States Abstract Using the strongly constrained and appropriately normed (SCAN) and SCAN+U approximations for describing electron exchange-correlation (XC) within density functional theory, we investigate the oxidation energetics, lattice constants, and electronic structure of binary Ce-, Mn-, and Fe-oxides, which are crucial ingredients for generating renewable fuels using two-step, oxide-based, solar thermochemical reactors. Unlike other common XC functionals, we find that SCAN does not over-bind the O2 molecule, based on direct calculations of its bond energy and robust agreement between calculated formation enthalpies of main group oxides versus experiments. However, in the case of transition-metal oxides (TMOs), SCAN systematically overestimates (i.e., yields too negative) oxidation enthalpies due to remaining self-interaction errors in the description of their ground-state electronic structure. Adding a Hubbard U term to the transition-metal centers, where the magnitude of U is determined from experimental oxidation enthalpies, significantly improves the qualitative agreement and marginally improves the quantitative agreement of SCAN+U-calculated electronic structure and lattice parameters, respectively, with experiments. Importantly, SCAN predicts the wrong ground-state structure for a few oxides, namely, Ce2O3, Mn2O3, and Fe3O4, while SCAN+U predicts the right polymorph for all systems considered in this work. Hence, the SCAN+U framework, with an appropriately determined U, will be required to accurately describe ground-state properties and yield qualitatively consistent electronic properties for most transition- metal and rare earth oxides.
    [Show full text]
  • B-Site Substituted Lanthanum Strontium Ferrites As Electrode Materials for Electrochemical Applications*
    Pure Appl. Chem., Vol. 80, No. 11, pp. 2543–2552, 2008. doi:10.1351/pac200880112543 © 2008 IUPAC B-site substituted lanthanum strontium ferrites as electrode materials for electrochemical applications* Ulrich F.Vogt1,4,‡, Josef Sfeir3, Joerg Richter2, Christian Soltmann2, and Peter Holtappels2 1Laboratory of Hydrogen and Energy, EMPA, Swiss Federal Laboratories for Materials Testing and Research, Ueberlandstr. 129, 8600 Duebendorf, Switzerland; 2Laboratory of High Performance Ceramics, EMPA, Swiss Federal Laboratories for Materials Testing and Research, Ueberlandstr. 129, 8600 Duebendorf , Switzerland; 3Hexis Ltd., CH 8404, Winterthur, Switzerland; 4Department of Crystallography, University of Freiburg, D-79104 Freiburg, Germany Abstract: For electrochemical systems such as solid oxide fuel cells (SOFCs) or solid oxide electrolyzer cells (SOECs), perovskites are widely used as cathode material for the reduction of molecular oxygen. At present, strontium-substituted lanthanum manganite, La1–xSrxMnO3–δ (LSM), is used as standard SOFC cathode material for operation at high temperatures, whereas strontium-substituted lanthanum ferrite (LSF) is alternatively ex- plored for medium-temperature SOFCs. Moreover, LSF is considered to be a potential can- didate for oxygen separation membranes as the material reported interesting electrical prop- erties. The design of new perovskite-type La transition-metal oxides is of significant technological importance in order to reduce the operating temperature to 600–800 °C and thus to reduce the SOFC system cost. For investigations on a new material class, (La1–xSrx)yFe1–z(Ni,Cu)zO3–δ was synthe- sized by a spray-pyrolysis process and modified on the A-site in both stoichiometric and non- stoichiometric configurations and on the B-site by substituting Fe with Ni and Cu.
    [Show full text]
  • Synthesis and Magnetic Characterization of Lamno3 Nanoparticles
    RESEARCH Revista Mexicana de F´ısica 61 (2015) 166–169 MAY-JUNE 2015 Synthesis and magnetic characterization of LaMnO3 nanoparticles E. Hernandez´ a, V. Sagredoa and G.E. Delgadob aLaboratorio de Magnetismo, Departamento de F´ısica, Facultad de Ciencias, Universidad de Los Andes, Merida´ 5101, Venezuela. bLaboratorio de Cristalograf´ıa, Departamento de Qu´ımica, Facultad de Ciencias, Universidad de Los Andes, Merida´ 5101, Venezuela. Received 26 November 2014; accepted 30 January 2015 LaMnO3 Nanoparticles systems were prepared by the sol-gel auto-combustion method, in order to analyze the structure and magnetic behavior presented by the compound prepared following a new alternative route of synthesis. Structural characterization, morphology and crystallite size was performed by X-ray diffraction (XRD), infrared spectroscopy (IR) and electron microscopy (TEM). The XRD study together with a Rietveld analysis showed that the LaMnO3 compound crystallized in a perovskite hexagonal structure. The IR spectra showed that the compound has tensile energy bands in the Mn-O-Mn bonds related with the octahedron MnO6; which are attributed to a characteristic vibration of the ABO3 perovskite. An estimated size and morphological analysis was carried out by applying the Scherrer’s formula and using Transmission Electron Microscopy (TEM), revealing non-spherical shape and particle sizes between 13 nm and 18 nm. The magnetic measurements M(T ) were performed by using zero-field-cooled (ZFC) and field-cooled (FC) protocols which revealed a positive Weiss temperature indicating the presence of ferromagnetic interactions with a Curie temperature, TC = 150 K. Keywords: Auto-combustion; curie temperature; magnetization; manganites; nanoparticles; ferromagnetism; perovskite; Sol-Gel.
    [Show full text]
  • Doped Lanthanum Manganite
    th Proceedings of the 5 International Workshop on Hydrogen and Fuel Cells October 26 –29, 2010 Campinas, SP, Brazil ISSN 2179-5029 SINTERING AND ELECTRICAL PROPERTIES OF STRONTIUM - DOPED LANTHANUM MANGANITE (1) DIEGO PEREIRA TARRAGÓ (2) BERTA MORENO BURRIEL (2) EVA CHINARRO MARTIN (2) JOSÉ RAMÓN JURADO EGEA (3) CÉLIA DE FRAGA MALFATTI (1) VÂNIA CALDAS DE SOUSA (1)LABIOMAT – PPGEM – UFRGS, Porto Alegre, RS, Brazil (2) CSIC – ICV, Madrid, Spain (3) LAPEC – PPGEM – UFRGS, Porto Alegre, RS, Brazil ABSTRACT Lanthanum strontium manganites (LSM) are potential materials for cathode applications in solid oxide fuel cells (SOFC) due to their good catalytic activity, chemical stability and compatibility with electrolyte materials in high temperatures. The sinterability of single phase La 1-xSr xMnO 3 (x=0.18) perovskite powders and the electrical properties of the resulting samples are analyzed in this study. Using a heating microscope, the powders were pressed and sintered at different pressures and temperatures, resulting in an open porosity of 33.36% when compacted at 125 MPa and sintered at 1200°C. Top and cross-section s canning electron microscopy (SEM) micrographs revealed interconnected pores in the sintered body and, hence, a suitable microstructure for the application. The activation energy for conductance was 0.04 eV and the tested LSM bulk started to exhibit adequate electrical properties at about 500°C. KEYWORDS : Perovskite; Lanthanum manganite; Solid oxide fuel cell; Cathode; Conductivity. 1. INTRODUCTION The development of devices such as solid oxide fuel cells (SOFC) requires the production of materials focusing on cost effectiveness rather than on the ideal properties for the application, while simultaneously reaching a compromise among the properties.
    [Show full text]
  • Study of the Durability of Doped Lanthanum Manganite Cathode Materials Under “Real World” Air Exposure Atmospheres
    Study of the Durability of Doped Lanthanum Manganite Cathode Materials under “Real World” Air Exposure Atmospheres P. Singh,1 M. K. Mahapatra,1 S. T. Misture,2 B. Hu,1 N. Q. Minh3, R. Ramprasad1 1Department of Materials Science and Engineering Center for Clean Energy Engineering, University of Connecticut, CT 2Materials Science and Engineering, Inamori School of Engineering, Alfred University 3Center for Energy Research, University of California San Diego WORK PERFORMED UNDER AGREEMENT DE-FE – 0009682 14th SECA Workshop, Pittsburgh July 24, 2013 Technical Contributors UConn: Manoj K. Mahapatra Asst. Research Professor Rampi Ram Prasad Professor Prabhakar Singh Professor Dr. Vineet Sharma Post-doctoral Fellow Dr. Boxun Hu Post-doctoral Fellow Michael Keane Graduate student Alfred U: Scott Misture Professor Mirela Dragan Post-doctoral Fellow Meredith Shi Graduate student Peter Metz Graduate student UCSD: Nguyen Minh Professor Imran Yashin Graduate student Outline Accomplishments Background Experimental Role of Humidity and CO2 Contribution of IC- AE interface Phase stability study using in-situ XRD Results and Discussion Future work Acknowledgements Accomplishments Electrochemical testing of LSM/YSZ/LSM symmetric cell in humidified air and CO2/air has been conducted for up to100 h and post-test analytical study (XRD, SEM-EDS, XPS, FTIR) has been performed. SrO/Sr(OH)2 has not been detected in the cells tested in dry air regardless of testing conditions. SrO/Sr(OH)2 has been detected in the cells in presence of humidity in air. Nucleation and growth of SrO increases with cathodic bias, increase in humidity content, temperature, and test duration. LSM degradation mechanism in humidified air has been developed and proposed.
    [Show full text]
  • Control of Magnetic Behavior in Lamno3 Thin Films Through Cationic Vacancies a Thesis Submitted to the Faculty of Drexel Univer
    Control of Magnetic Behavior in LaMnO3 Thin Films through Cationic Vacancies A Thesis Submitted to the Faculty of Drexel University by Cerina Gordon In partial fulfillment of the requirements for the degree of Master of Science in Materials Science and Engineering June 2017 © Copyright 2017 Cerina Gordon. This work is licensed under a Creative Commons Attribution 4.0 International License. ii Acknowledgements I would like to express thanks to all those who helped me and stood by me during the production of this work. In particular I’d like to thank Mark Scafetta and Dr. Steve May for providing the opportunity to study this problem, Mark for growing the films and Dr. May for prompting the study of this problem and providing the resources to study it. Growth of the films by Mark S. was funded by the National Science Foundatin (DMR- 1151649) I’d also like to thank my lab group for providing training on several of the tests performed, assisting in characterization and providing useful discussion and moral support. Similarly, I’d like to thank my committee members, Dr. Steve May, Dr. Goran Karapetrov and Dr. Garritt Tucker for the valuable discussion following my defense. Finally, I’d like to thank my friends and family for providing support and sticking it out with me, and providing an outside perspective to remind me of exactly what a general audience does and does not know. iii Table of Contents List of Tables ..................................................................................................................... v List of
    [Show full text]