DOCSLIB.ORG

Tape Casting of Preceramic Polymers Toward Advanced Ceramics: a Review

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Tape Casting of Preceramic Polymers Toward Advanced Ceramics: a Review Tape casting of preceramic polymers toward advanced ceramics: A review Dachamir Hotza, Rafael Nishihora, Ricardo Machado, Pierre-marie Geffroy, Thierry Chartier, Samuel Bernard To cite this version: Dachamir Hotza, Rafael Nishihora, Ricardo Machado, Pierre-marie Geffroy, Thierry Chartier, et al.. Tape casting of preceramic polymers toward advanced ceramics: A review. International Journal of Ceramic Engineering & Science, 2019, 1 (1), pp.21-41. 10.1002/ces2.10009. hal-02386877 HAL Id: hal-02386877 https://hal-unilim.archives-ouvertes.fr/hal-02386877 Submitted on 11 Dec 2020 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Received: 4 March 2019 | Revised: 10 April 2019 | Accepted: 10 April 2019 DOI: 10.1002/ces2.10009 REVIEW ARTICLE Tape casting of preceramic polymers toward advanced ceramics: A review Dachamir Hotza1,2 | Rafael K. Nishihora1 | Ricardo A. F. Machado1 | Pierre‐Marie Geffroy2 | Thierry Chartier2 | Samuel Bernard2 1Department of Chemical Engineering (EQA), Federal University of Santa Abstract Catarina (UFSC), Florianópolis, Brazil In the last 20 years, tape casting, a standard wet‐shaping process to produce thin ce- 2Institute of Research for Ceramics ramics, has been applied to manufacture polymer‐derived ceramics (PDCs). Si‐based (IRCER), University of Limoges polymers, such as polysiloxanes and polysilazanes, also known as preceramic poly- (UNILIM), Limoges, France mers (PCPs), have been used as precursors/binders replacing conventional raw ma- Correspondence terials and additives for tape casting process. Thermal processing of PCPs is carried Dachamir Hotza, Department of Chemical out at lower temperatures in comparison with classical ceramic sintering, particularly Engineering (EQA), Federal University of Santa Catarina (UFSC), 88040‐900 of carbides and nitrides. Furthermore, polymeric precursors can be converted into Florianópolis, SC, Brazil. hybrid or composite ceramics, when parts of the polymers remain unreacted. Inert or Email:[email protected] reactive fillers might be used to reduce both shrinkage and porosity inherently caused Funding information by the weight loss occurring during polymer pyrolysis while forming new ceramic Centre National de la Recherche phases in the final materials. Alternatively, pore formers might also be added to Scientifique; Coordenação de Aperfeiçoamento de Pessoal de Nível tailor pore shape, connectivity, and volume (macroporosity). Nevertheless, current Superior, Grant/Award Number: equipment and process parameters for tape casting‐based products must be eventu- 88887.192309/2018‐00; Campus ally adjusted to fit the characteristics of ceramic precursors. Therefore, the aim of France, Grant/Award Number: 88887.192309/2018‐00; Conselho this review is focused on listing and discussing the efforts to produce PDCs using Nacional de Desenvolvimento Científico tape casting as a shaping technique. Interactions of system components and effects e Tecnológico, Grant/Award Number: of treatment, particularly thermal stages, on final microstructure and properties are 400775/2014‐0 Abbreviations: ADA, AzoDicarbonAmide, C2H4N4O2; AFCOP, Active Filler Controlled Polymer Pyrolysis; Al(acac)3, Aluminum acetylacetonate, Al(C5H7O2)3; Ceraset SN, polysilazane (Honeywell ( https ://www.lab-honey well.com/produ cts/brand s/honey well/), formerly AlliedSignal, USA), (C=O) (N‐R)(CH3)(H)(Si‐NH)(C2H3)(CH3)(Si‐NH) [(CH3)(R)Si‐NH)]n with n = 1‐20 and R = H, CH=CH2; CTE, Coefficient of Thermal Expansion; DBE, Di‐n‐ButylEther, C8H18O; DCP, DiCumyl Peroxide, C18H22O2; DMF, DiMethylFormamide, HCO‐N(CH3)2; Durazane 1800, (organo)silazane (Merck ( https ://www.merck group.com/en/brand s/pm/az-produ cts.html), Germany), [(C2H3)(CH3)Si–NH)0.2n(H(CH3)Si–NH)0.8n; Eucryptite, Li2O·Al2O3·xSiO2 with x = 2 for stoichiometric composition; FA, FormAmide, CH3NO; FGC(s), Functionally Graded Ceramic(s); FGM(s), Functionally Graded Material(s); H44, solid phenylmethyl polysiloxane (Wacker ( https ://www.wacker.com/cms/en/produ cts/produ ctsea rch/produ ct-search.jsp), Germany),[(C6H5)0.62(CH3)0.31(OR)0.07SiO1.5]n, n < 20, where R can be either a hydroxyl (‐OH) or a alkoxy group (‐OC2H5); H62C, liquid methyl‐phenyl 4 vinyl hydrogen polysiloxane (Wacker , Germany), [(C6H5)0.44(CH3)0.24(C2H3)0.16(H)0.16SiO1.5]n; Imidazole, C3H4N2; LTCC, Low‐Temperature Cofired 4 Ceramics; MK, solid methyl polysilsesquioxane (Wacker , Germany), (CH3SiO1.5)n with n = 130‐150; MSE100, liquid methoxy functional methyl 4 polysiloxane (Wacker , Germany), [CH3SiO1.1(OCH3)0.8]n; MTES, MethylTriEthoxySilane, CH3Si(OC3H5)3; MTMS, MethylTriMethoxySilane, CH3Si(OCH3)3; NTE, Negative Thermal Expansion; Oleic acid, (9Z)‐octadec‐9‐enoic acid, CH3(CH2)7CH=CH(CH2)7COOH; PCP(s), PreCeramic Polymer(s); PDC(s), Polymer‐Derived Ceramic(s); PHPS, PerHydroPolySilazane, (H2Si–NH)n; SOFC(s), Solid Oxide Fuel Cell(s); Spodumene, Li2O·Al2O3·4SiO2; TBC(s), Thermal Barrier Coating(s); TMIA, TriMethylIminoAlane; Xylene, C8H10; YSZ, Yttria‐Stabilized Zirconia, xY2O3·yZrO2; Zr(acac)4, Zirconium acetylacetonate, Al(C5H7O2)4. This is an open access article under the terms of the Creat ive Commo ns Attri bution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. © 2019 The Authors. International Journal of Ceramic Engineering & Science published by Wiley Periodicals, Inc. on behalf of American Ceramic Society Int J Ceramic Eng Sci. 2019;1:21–41. wileyonlinelibrary.com/journal/ces2 | 21 22 | HOTZA ET AL. stressed out. Gaps in the literature concerning processing optimization are pointed out, and suggestions are given for further development of PDCs produced by tape casting. KEYWORDS polymer‐derived ceramics, polysilazanes, polysiloxanes, preceramic polymers, tape casting oxide ceramics like mullite,33 or mixed non oxide ceramics 1 INTRODUCTION 34 | like SiCO, SiCNO, or SiAlON. The elimination of organic moieties occurring during pyrolysis results in the formation Tape casting is a standard wet‐shaping process to produce of an inorganic material. The ceramic material forms through thin ceramics.1 Single dried tapes, with thickness ranging a complex microstructural evolution, which depends on the from 50 to 1000 μm,2 are usually further submitted to lamina- PCPs molecular architecture and pyrolysis conditions, leading tion, debinding, and sintering.3,4 Sintered tapes or laminates to nanosized crystalline phases embedded in an amorphous are applied mainly as electronic substrates,5 multilayered matrix.35 The absence of a sintering step enables thermal pro- capacitors,6 multilayered packages,7 piezoceramics,8 and cessing at lower temperatures without the need for pressure, components for solid oxide fuel cells (SOFCs).9 Novel tape as compared with classical ceramic powder processing.36 casting applications include 3D printed laminates,10 func- Furthermore, polymeric precursors can be converted into hy- tionally graded materials (FGMs),11 and porous membranes brid ceramics, when parts of the polymers remain unreacted.37 or supports.12 Shaping of PCPs by tape casting offers innovative com- Typically, tape casting is carried out from slurries com- position, microstructure and mainly in terms of design possi- prised basically by a ceramic powder, a liquid (organic sol- bilities, but poses new challenges in terms of process control. vent or water), and additives, such as dispersants, binders, and Conventional tape casting needs organic additives that are plasticizers.13,14 Due to environmental and safety issues, the burned out in a subsequent step. If appropriately selected, use of water‐based systems is increasing in importance.15‒18 PCPs have the advantage of a high ceramic yield (>70 wt.%) Nevertheless, the replacement of organic solvents by water at moderate temperatures (as low as 1000°C).38 However, the presents some challenges in controlling the rheological and organic/inorganic transformation is accompanied by a den- drying behavior of the slurry.19,20 In addition, some raw mate- sity increase that gives rise either to a high shrinkage or to a rials, particularly nonoxides, can react adversely with water.21 high porosity. In this regard, reactive fillers might be used to Thus, organic solvent‐based tape casting remains used in the form new ceramic phases and reduce both shrinkage and po- industrial shaping process for producing thin, flat ceramics. rosity.39 Nevertheless, current equipment and process param- Crystalline/amorphous, oxide/nonoxide, single/compos- eters for tape cast‐based products must be eventually adjusted ite ceramics have been processed by tape casting. Alumina22 to fit the characteristics of ceramic precursors, for instance, and zirconia23 are the most frequent tape cast oxides, not to with the use of a protective atmosphere. mention many composites from them.24 Silicon carbide and Therefore, the aim of this review is focused on listing and aluminum nitride are among the most common nonoxide ce- discussing the efforts to manufacture PDCs using tape cast- ramics shaped by this technique.25‒28 Nonetheless,
Load more

Recommended publications
  • Fabrication and Characterization of Heat Flux Sensor Using Polymer Derived Ceramics
    FABRICATION AND CHARACTERIZATION OF HEAT FLUX SENSOR USING POLYMER DERIVED CERAMICS A Dissertation Presented to The Faculty of the Graduate School University of Missouri In Partial Fulfillment Of the Requirements for the Degree Doctor of Philosophy In Mechanical and Aerospace Engineering By SUNGHOON JUNG Dr. Frank Z. Feng, Dr. Jinn-Keun Chen, Dissertation Supervisors December 2011 The undersigned, appointed by the Dean of the Graduate School, have examined the dissertation entitled FABRICATION AND CHARACTERIZATION OF HEAT FLUX SENSOR USING POLYMER DERIVED CERAMICS Presented by SUNGHOON JUNG A candidate for the degree of Doctor of Philosophy And hereby certify that in their opinion it is worthy of acceptance Professor Dr. Frank Feng, Dissertation Supervisor Professor Dr. Jinn-Kuen Chen, Dissertation Supervisor Professor Dr. Robert Tzou Professor Dr. Yuwen Zhang Professor Dr. Tushar Ghosh ACKNOWLEDGEMENTS With all my heart, I would like to express big appreciation to my advisors, Dr. Frank Feng and Dr. JK Chen. Throughout our project, they have been supporting me with generosity, patience and kind encouragement. In spite of difficulties encountered, their patience and encouragement were crucial for me to finish my PhD degree successfully. I am grateful to Dr. Hao Li and his students for their cooperation regarding laboratory sharing. Most of my experiment results are obtained from the equipments in his laboratory. Without his allowing me to use them, our work would have been tougher than it was. I also thank Dr. Lombardo for the journal paper work and technician Richard for his help on my experiment setup. Also I would like to say ―thank you‖ to my committee members, Dr.
    [Show full text]
  • Powder Injection Moulding International September 2020 Vol
    0 FOR THE MIM, CIM AND SINTER-BASED AM INDUSTRIES 2 0 2 R E B M E C E D 4 . o N 4 1 . l o V in this issue Ceramic Injection Moulding ElementPlus: Ti-MIM for 3C MIM-Master Neo Published by Inovar Communications Ltd www.pim-international.com Publisher & Editorial Offices ® Inovar Communications Ltd CataMIM 11 Park Plaza Battlefield Enterprise Park • A direct replacement for all current Shrewsbury SY1 3AF United Kingdom commercially available catalytic debind Tel: +44 (0)1743 211991 feedstocks Fax: +44 (0)1743 469909 www.pim-international.com • Improved flow Managing Director & Editor • Stronger green and brown parts Nick Williams [email protected] For the MIM, CIM and sinter-based AM industries • More materials available and better Publishing Director Paul Whittaker surface finish [email protected] • Custom scale-up factors available Deputy Editor Emily-Jo Hopson-VandenBos Simulating sintering www.ryerinc.com • Faster cycle times [email protected] • 65°C / 150°F mold temperature Assistant Editor Kim Hayes distortion: Can MIM get a [email protected] Consulting Editors boost from Binder Jetting? ® Prof Randall M German AquaMIM Former Professor of Mechanical Engineering, San Diego State University, USA • Water Debind As I wrote in the introduction to Desktop Metal’s article on its Dr Yoshiyuki Kato Live Sinter simulation package, published in the September 2020 Kato Professional Engineer Office, Yokohama, Japan • Custom scale-up factors available issue of PIM International, sintering distortion is a fact of life Professor Dr Frank Petzoldt • Large selection of available materials Deputy Director, Fraunhofer IFAM, Bremen, to which we are accustomed in the Metal Injection Moulding Germany industry.
    [Show full text]
  • Development of New Matrix and Interfacial Materials for Ceramic Matrix Composites Gavin C
    University of Connecticut OpenCommons@UConn Doctoral Dissertations University of Connecticut Graduate School 8-26-2014 Development of New Matrix and Interfacial Materials for Ceramic Matrix Composites Gavin C. Richards University of Connecticut - Storrs, [email protected] Follow this and additional works at: https://opencommons.uconn.edu/dissertations Recommended Citation Richards, Gavin C., "Development of New Matrix and Interfacial Materials for Ceramic Matrix Composites" (2014). Doctoral Dissertations. 522. https://opencommons.uconn.edu/dissertations/522 Development of New Matrix and Interfacial Materials for Ceramic Matrix Composites Gavin C. Richards, PhD University of Connecticut, 2014 Pre-ceramic polymers are attractive, low cost materials for the manufacture of ceramic fibers and matrix materials in Ceramic Matrix Composites (CMCs). A new pre-ceramic polymer, an ethanol-modified polyvinylsilazane (PVSZ), was synthesized and characterized. The PVSZ polymer has been previously shown to be a viable precursor for silicon nitride and silicon carbide based ceramics, but lacked stability when exposed to air. The PVSZ polymer was synthesized via the ammonolysis of trichlorovinylsilazane in tetrahydrofuran (THF), and then reacted with ethanol to form the ethanol-modified PVSZ. The PVSZ polymer and ethanol- modified PVSZ resin were each characterized with Attenuated Total Reflectance spectroscopy (ATR), 1H Nuclear Magnetic Resonance ( 1H-NMR), and Gel Permeation Chromatography (GPC), Thermogravimetric Analysis (TGA), Residual Gas Analysis (RGA), and X-Ray Powder Diffraction (XRD) of the ceramic char after pyrolysis in various atmospheres. A second new modified PVSZ was also synthesized. Rather than use ethanol, a second silane monomer was added during synthesis, with the intent of stabilizing the polymer without incorporating oxygen. The new end cap modified PVSZ (EC-PVSZ) was characterized using the same methods outlined for the ethanol-modified PVSZ.
    [Show full text]
  • Formation of Micro and Mesoporous Amorphous Silica-Based Materials from Single Source Precursors
    inorganics Article Formation of Micro and Mesoporous Amorphous Silica-Based Materials from Single Source Precursors Mohd Nazri Mohd Sokri 1,2, Yusuke Daiko 1,3, Zineb Mouline 1, Sawao Honda 1,3 and Yuji Iwamoto 1,3,* 1 Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan; [email protected] (M.N.M.S.); [email protected] (Y.D.); [email protected] (Z.M.); [email protected] (S.H.) 2 Department of Energy Engineering and Advanced Membrane Technology Research Centre, Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia (UTM), Johor Bahru 81310, Malaysia 3 Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Agency, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan * Correspondence: [email protected]; Tel./Fax: +81-52-735-5276 Academic Editors: Samuel Bernard, André Ayral and Philippe Miele Received: 8 January 2016; Accepted: 1 March 2016; Published: 9 March 2016 Abstract: Polysilazanes functionalized with alkoxy groups were designed and synthesized as single source precursors for fabrication of micro and mesoporous amorphous silica-based materials. The pyrolytic behaviors during the polymer to ceramic conversion were studied by the simultaneous thermogravimetry-mass spectrometry (TG-MS) analysis. The porosity of the resulting ceramics was characterized by the N2 adsorption/desorption isotherm measurements. The Fourier transform infrared spectroscopy (FT-IR) and Raman spectroscopic analyses as well as elemental composition analysis were performed on the polymer-derived amorphous silica-based materials, and the role of the alkoxy group as a sacrificial template for the micro and mesopore formations was discussed from a viewpoint to establish novel micro and mesoporous structure controlling technologies through the polymer-derived ceramics (PDCs) route.
    [Show full text]
  • Preparation of Polysilazane Polymers and the Polymers Therefrom
    Europaisches Patentamt 19) European Patent Office © Publication number: 0 075 826 Office europeen des brevets A2 © EUROPEAN PATENT APPLICATION © Application number: 82108675.8 © int. ci.3: C 08 G 77/62 C 04 B 35/56 @ Date of filing: 20.09.82 © Priority: 21.09.81 US 304446 © Applicant: DOW CORNING CORPORATION 3901 S. Saginaw Road Midland Michigan 48640IUS) © Date of publication of application: 06.04.83 Bulletin 83/14 ©Inventor: Gaul, John Henry, Jr. 3212 Lawndale Drive © Designated Contracting States: Midland Michigan(US) BE DE GB NL © Representative: Hann, Michael, Dr. Patentanwalte Dr. Michael Hann Dr. H.-G. Sternagel Marburger Strasse 38 D-6300 Giessen(DE) © Preparation of polysilazane polymers and the polymers therefrom. What is disclosed is a process for preparing polysilazane polymers by contacting and reacting chlorine-containing disilanes with ammonia. The polysilazane polymers are useful as chemical intermediates to produce silicon- containing chemical compounds. They are also useful in the formation of silicon carbide-containing ceramic materials. This invention relates to the preparation of polysilazane polymers. These polymers are useful as chemical intermediates to synthesize organosilicon compounds. They are also useful, when fired at high temperatures, to form silicon carbide and silicon carbide containing ceramic materials. What is disclosed herein is a novel process to obtain novel polysilazane polymers which consists of contacting and reacting chlorine-containing disilanes with ammonia in an inert, essentially anhydrous atmosphere. As is well known in the art, halosilane monomers will react with ammonia and most organic compounds containing a primary or secondary amino group to give a variety of silazanes.
    [Show full text]
  • Synthesis and Processing of Silicon Nitride and Related Materials Using Preceramic Polymer and Non-Oxide Sol-Gel Approaches
    Synthesis and processing of silicon nitride and related materials using preceramic polymer and non-oxide sol-gel approaches Andrew L. Hector Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ [email protected] Abstract The use of preceramic polymer and sol-gel processing methods in the production of silicon nitride and a number of related materials is reviewed. Amorphous ceramics in this system, that may contain additional carbon, boron and other elements, have a number of promising and/or useful high temperature properties. These include good mechanical properties and oxidation resistance at temperatures that can exceed 1500 °C with some materials, but also useful charge storage capability, catalytic activity and semiconducting or optical properties after doping. 1. Introduction Silicon nitride adopts two main structures formed from corner sharing tetrahedra, with α-Si3N4 adopting a simple hexagonal close packing arrangement and β-Si3N4 a more complex stacking sequence of the close packed layers [1]. It is often used as a hard material, and the cubic spinel high pressure form, which has been called c-Si3N4, has a high bulk modulus value of 290(5) GPa [2,3]. Conventional thermal ceramic processing of silicon nitride and related materials is limited by the very high temperatures required to achieve any mobility. Spark plasma sintering at 1500-1700 °C, just below the decomposition to the elements at ~1850 °C, may be used to produce compacts and molten sintering aids can reduce the sintering temperatures somewhat [4]. Under these conditions β-Si3N4 is the thermodynamically stable phase and hence this is the most used in engine parts, bearings and high temperature ceramics [5].
    [Show full text]
  • Preparation of Polysilazane Polymers and the Polymers Therefrom
    Europâisches Patentamt European Patent Office (ÏÏ) Publication number: 0 075 826 Office européen des brevets B1 ® EUROPEAN PATENT SPECIFICATION (§) Date of publication of patent spécification : 30.04.86 © mtci.4: C 08 G 77/62, C 04 B 35/56 (D Application number: 82108675.8 (g) Date offiling: 20.09.82 @ Préparation of polysilazane polymers and the polymers therefrom. (§) Priority: 21.09.81 US 304446 (73) Proprietor: DOW CORNING CORPORATION 3901 S. Saginaw Road Midland Michigan 48640 (US) (§) Date of publication of application: 06.04.83 Bulletin 83/14 ' (72) Inventor: Gaul, John Henry, Jr. 3212 Lawndale Drive (§) Publication of the grant of the patent: Midland Michigan (US) 30.04.86 Bulletin 86/18 (74) Représentative: Hann, Michael, Dr. (H) Designated Contracting States: Patentanwâlte Dr. Michael Hann Dr. H.-G. BEDEGB IML Sternagel Marburger Strasse 38 D-6300 Giessen (DE) (58) Références cited: DE-A-2 243 527 US-A-2 564 674 US-A-3 311571 CM 00 If) o o Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the Notice of shail a. European patent granted. opposition be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been ui paid. (Art. 99(1 ) European patent convention). Courier Press, Leamington Spa, England. disilanes in the preparation of silazane polymers has been limited to the formation of relatively low This invention relates to the preparation of molecular weight materials.
    [Show full text]
  • Polymeric and Ceramic Silicon-Based Coatings – a Review
    Journal of Materials Chemistry A Polymeric and ceramic silicon-based coatings – A review Journal: Journal of Materials Chemistry A Manuscript ID TA-REV-09-2018-009054.R1 Article Type: Review Article Date Submitted by the 21-Nov-2018 Author: Complete List of Authors: Barroso, Gilvan; University of Bayreuth, Ceramic Materials Engineering Li, Quan; Clemson University, Department of Materials Science and Engineering Bordia, Rajendra; Clemson University, Department of Materials Science and Engineering Motz, Guenter; University of Bayreuth, Ceramic Materials Engineering Page 1 of 45 Journal of Materials Chemistry A Polymeric and ceramic silicon-based coatings – A review Gilvan Barrosoa, Quan Lib, Rajendra K. Bordiab, Günter Motza,* aUniversity of Bayreuth, Ceramic Materials Engineering (CME), Bayreuth, Germany bClemson University, Department of Materials Science and Engineering, Clemson, SC, USA *corresponding author: [email protected] Silicon-based polymers are outstanding materials for coating applications. These compounds have excellent properties, such as strong adhesion to most substrates, and high chemical, thermal and UV resistance. Additionally, they can be converted into ceramic materials (polymer-derived ceramics) by a heat treatment and, in some cases, by chemical reactions or radiation. Hence, ceramic coatings can be obtained after deposition of the polymers by simple lacquer techniques. The properties and composition of polymeric and ceramic coatings can be changed by tailoring the chemical structure of the precursors or by the addition of fillers. This enables the preparation of coatings with a great variety of properties for different applications. In this review paper, the main aspects of the use of silicon polymers for coatings are elucidated. The advantages and disadvantages of these materials, and the processing methods developed are discussed.
    [Show full text]
  • Ceramic Nanocomposites from Tailor-Made Preceramic Polymers
    Nanomaterials 2015, 5, 468-540; doi:10.3390/nano5020468 OPEN ACCESS nanomaterials ISSN 2079-4991 www.mdpi.com/journal/nanomaterials Review Ceramic Nanocomposites from Tailor-Made Preceramic Polymers Gabriela Mera 1,†, Markus Gallei 2,†, Samuel Bernard 3 and Emanuel Ionescu 1,4,* 1 Institut für Materialwissenschaft, Technische Universität Darmstadt, Jovanka-Bontschits-Strasse 2, D-64287 Darmstadt, Germany; E-Mail: [email protected] 2 Ernst-Berl-Institut für Technische und Makromolekulare Chemie, Technische Universität Darmstadt, Alarich-Weiss-Strasse 4, D-64287 Darmstadt, Germany; E-Mail: [email protected] 3 Institut Européen des Membranes (UMR 5635-CNRS/ENSCM-UM2) CC 047-Place E. Bataillon, 34095 Montpellier Cedex 05, France; E-Mail: [email protected] 4 Department Chemie, Institut für Anorganische Chemie, Universität zu Köln, Greinstrasse 6, D-50939 Köln, Germany † These authors contribute equally to this paper. * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +49-6151-16-6344; Fax: +49-6151-16-6346. Academic Editor: Thomas Nann Received: 24 February 2015 / Accepted: 15 March 2015 / Published: 1 April 2015 Abstract: The present Review addresses current developments related to polymer-derived ceramic nanocomposites (PDC-NCs). Different classes of preceramic polymers are briefly introduced and their conversion into ceramic materials with adjustable phase compositions and microstructures is presented. Emphasis is set on discussing the intimate relationship between the chemistry and structural architecture of the precursor and the structural features and properties of the resulting ceramic nanocomposites. Various structural and functional properties of silicon-containing ceramic nanocomposites as well as different preparative strategies to achieve nano-scaled PDC-NC-based ordered structures are highlighted, based on selected ceramic nanocomposite systems.
    [Show full text]
  • STRUCTURE and PROPERTIES of POLYMER-DERIVED Sibcn CERAMICS by YAOHAN CHEN B.S. Sichuan University, China, 2005 M.S. Sichuan Univ
    STRUCTURE AND PROPERTIES OF POLYMER-DERIVED SiBCN CERAMICS by YAOHAN CHEN B.S. Sichuan University, China, 2005 M.S. Sichuan University, China, 2008 A dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Mechanical, Materials and Aerospace Engineering in the College of Engineering and Computer Science at the University of Central Florida, Orlando, Florida Spring Term 2012 Major Professor: Linan An © 2012 Yaohan Chen ii ABSTRACT Polymer-derived ceramics (PDCs) are a unique class of multifunctional materials synthesized by thermal decomposition of polymeric precursors. Due to their unique and excellent properties and flexible manufacturing capability, PDC is a promising technology to prepare ceramic fibers, coatings, composites and micro-sensors for high-temperature applications. However, the structure-property relationships of PDCs have not been well understood. The lack of such understandings drastically limited the further developments and applications of the materials. In this dissertation, the structure and properties of amorphous polymer-derived silicon carbonitride (SiCN) and silicoboron carbonitride (SiBCN) have been studied. The SiCN was obtained using commercially available polysilazane as pre-ceramic precursor, and the SiBCN ceramics with varied Si-to-B ratio were obtained from polyborosilazanes, which were synthesized by the hydroboration and dehydrocoupling reaction of borane and polysilazane. The structural evolution of polymer-derived SiCN and SiBCN ceramics from polymer to ceramics was investigated by NMR, FTIR, Raman, EPR, TG/DTA, and XRD. The results show a phase- separation of amorphous matrix and a graphitization of “free” carbon phase, and suggest that the boron doping has a great influence on the structural evolution.
    [Show full text]
  • Protective Electronic Coatings Using Filled Polysilazanes
    Europaisches Patentamt 19 European Patent Office Office europeen des brevets © Publication number : 0 675 537 A2 12 EUROPEAN PATENT APPLICATION © Application number : 95302008.8 <&) int. ci.6: H01L 23/29 @ Date of filing : 27.03.95 (30) Priority: 01.04.94 US 221597 © Inventor : Haluska, Loren Andrew 4510 James Street Midland, Michigan (US) @ Date of publication of application Inventor : Michael, Keith Winton 04.10.95 Bulletin 95/40 2715 Siebert Midland, Michigan (US) @ Designated Contracting States : DE FR GB IT NL © Representative : Vandamme, Luc Johan Roger Dow Corning Limited, Cardiff Road © Applicant : DOW CORNING CORPORATION Barry, South Glamorgan CF63 2YL, Wales (GB) Midland, Michigan 48686-0994 (US) © Protective electronic coatings using filled polysilazanes. © The present invention relates to a method of forming protective coatings on electronic subs- trates and to the substrates coated thereby. The method comprises applying a coating compris- ing a polysilazane and a filler on a substrate and then heating the coated substrate at a tempera- ture sufficient to convert the polysilazane to a ceramic. CM < co If) If) h- LU Jouve, 18, rue Saint-Denis, 75001 PARIS 1 EP 0 675 537 A2 2 The present invention relates to a method of filler materials. The expression "filler" describes a forming protective coatings using compositions com- finely divided solid phase which is distributed within prising polysilazanes and fillers. These coatings are the polysilazane and the final ceramic coating. The useful on a variety of electronic substrates. expression "electronic substrate" includes electronic The use of polysilazanes to form ceramic coat- 5 devices or electronic circuits such as silicon based ings on electronic devices is known in the art.
    [Show full text]
  • Metal-Containing Ceramic Nanocomposites Synthesized from Metal Acetates and Polysilazane
    Open Ceramics 1 (2020) 100001 Contents lists available at ScienceDirect Open Ceramics journal homepage: www.editorialmanager.com/oceram Metal-containing ceramic nanocomposites synthesized from metal acetates and polysilazane Jun Wang a, Valerie Scholch€ a, Oliver Gorke€ a,Gotz€ Schuck b, Xifan Wang a, Gaofeng Shao a, Susan Schorr b,c, Maged F. Bekheet a,*, Aleksander Gurlo a a Fachgebiet Keramische Werkstoffe / Chair of Advanced Ceramic Materials, Institut für Werkstoffwissenschaften und-technologien, Technische Universitat€ Berlin, Hardenbergstraße 40, 10623, Berlin, Germany b Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, 14109, Berlin, Germany c Free University Berlin, Department of Geosciences, Malteserstraße 74-100, 12249, Berlin, Germany ARTICLE INFO ABSTRACT Keywords: Metal-containing (Mn, Fe, Co, Cu, Zn and Ag) polysilazane precursors are synthesized via one-step chemical Poly(vinyl)silazane reaction of metal acetates with poly(vinyl)silazane (Durazane 1800) at room temperature under argon atmo- Metal acetates sphere. The ATR-FTIR spectra of the synthesized metal-containing precursors reveal that the metal acetates used Metal-containing precursors – in the synthesis catalyze the hydrosilylation reaction between -Si-H and -Si-CH–CH groups in polysilazane. The Polymer-derived ceramics 2 XPS and XRD characterizations indicate that the metallic phase is directly generated in precursors after the re- Metal ⋅ Metal silicide action of Durazane 1800 polymer with Fe(CH3COO)2, Co(CH3COO)2 4H2O, CuCH3COO, Cu(CH3COO)2, AgCH3- Nanocomposites COO. Ceramic nanocomposites containing either metal or metal silicide are obtained after the pyrolysis of the synthesized metal-containing precursors at 700 C and 1100 C under argon atmosphere. 1.
    [Show full text]