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WTP-RPT-116 Rev 0 PNWD-3499 WTP-RPT-116 Rev 0 Vitrification and Product Testing of AZ-101 Pretreated High-Level Waste Envelope D Glass P. Hrma D. J. Bates P. R. Bredt J. V. Crum L. R. Greenwood H. D. Smith September 2004 Prepared for Bechtel National Inc. By Battelle—Pacific Northwest Division under Contract 24590-101-TSA-W000-00004 LEGAL NOTICE This report was prepared by Battelle Memorial Institute (Battelle) as an account of sponsored research activities. Neither Client nor Battelle nor any person acting on behalf of either: MAKES ANY WARRANTY OR REPRESENTATION, EXPRESS OR IMPLIED, with respect to the accuracy, completeness, or usefulness of the information contained in this report, or that the use of any information, apparatus, process, or composition disclosed in this report may not infringe privately owned rights; or Assumes any liabilities with respect to the use of, or for damages resulting from the use of, any information, apparatus, process, or composition disclosed in this report. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by Battelle. The views and opinions of authors expressed herein do not necessarily state or reflect those of Battelle. This document was printed on recycled paper. (9/97) Contents Abbreviations and Acronyms ...................................................................................................................... xi References................................................................................................................................................... xv Pacific Northwest National Laboratory Operating Procedures.................................................................xvii Testing Summary....................................................................................................................................... xix 1.0 Introduction....................................................................................................................................... 1.1 2.0 Quality Assurance Requirements...................................................................................................... 2.1 2.1 Application of RPP-WTP Quality Assurance Requirements................................................... 2.1 2.2 Conduct of Experimental and Analytical Work ...................................................................... 2.5 2.3 Internal Data Verification and Validation ............................................................................... 2.5 3.0 Objectives ......................................................................................................................................... 3.1 4.0 Success Criteria................................................................................................................................. 4.1 5.0 Experimental Method ....................................................................................................................... 5.1 5.1 Glass Formulation.................................................................................................................... 5.1 5.1.1 Blended AZ-101 HLW.................................................................................................. 5.1 5.1.2 HLW Glass Composition .............................................................................................. 5.6 5.1.3 HLW Feed Composition ............................................................................................... 5.7 5.2 Glass Fabrication ..................................................................................................................... 5.8 5.3 Chemical Analysis................................................................................................................. 5.14 5.4 Radiochemical Composition.................................................................................................. 5.15 5.5 Crystalline Phases.................................................................................................................. 5.18 5.6 Product Consistency Test ...................................................................................................... 5.19 5.7 Toxicity Characteristic Leaching Procedure.......................................................................... 5.21 6.0 Results............................................................................................................................................... 6.1 6.1 Chemical Composition ............................................................................................................6.1 iii 6.2 Radiochemical Composition.................................................................................................... 6.9 6.3 Crystalline Phases.................................................................................................................. 6.15 6.4 Product Consistency Test ...................................................................................................... 6.24 6.5 Toxicity Characteristic Leaching Procedure.......................................................................... 6.29 6.6 Comparison of the Durability and Crystallinity of Actual and Simulated AZ-101 IHLW.... 6.33 7.0 Conclusions....................................................................................................................................... 7.1 8.0 Acknowledgements........................................................................................................................... 8.1 Appendix A: Glass-Formulation Details................................................................................................... A.1 Appendix B: AZ-101 HLW Glass Chemical Analysis Data.....................................................................B.1 Appendix C: AZ-101 HLW Glass Radiochemical Analysis Data ............................................................C.1 Appendix D: TCLP QA Report (From RPL)............................................................................................ D.1 iv Tables Table S.1. Summary of Test Objectives and Results................................................................................. xx Table S.2. Test Exceptions......................................................................................................................... xx Table S.3. Summary of Success Criteria for AZ-101 HLW Glass ........................................................... xxi Table S.4. R&T Test Conditions.............................................................................................................xxiii Table S.5. AZ-101 HLW Glass Composition in Mass% ......................................................................... xxv Table S.6. Activities of Radionuclides Found in AZ-101 HLW Glass................................................... xxvi Table S.8. 7-day 90°C PCT Normalized Releases from AZ-101 HLW Glass........................................ xxvi Table S.9. TCLP Solution Concentrations and UTS limits ...................................................................xxvii Table 2.1. Applicable WTPSP Quality Assurance Procedures................................................................. 2.1 Table 5.1. Blending Mass Fractions for the Cs and Tc Eluates ................................................................ 5.2 Table 5.2. Composition of (Actual) Blended HLW, Additives, Corrective Chemicals, and AZ-101 HLW Glass (in mass fraction).............................................................................................5.2 Table 5.3. Compositions of Pretreated Tank AZ-101 HLW Sample and the Cs and Tc Eluates in Terms of Element Concentrations ................................................................................................ 5.3 Table 5.4. Radiochemical Composition of AZ-101 HLW (in µCi/g dry solids) and AP-101 and AZ-101 137Cs and 99Tc Eluates (in µCi/mL) ..................................................................................... 5.4 Table 5.5. Density (in g/mL) and Solid Content (in mass%) in AZ-101 and AP-101 Eluates ................. 5.6 Table 5.6. Compositions of Pretreated Tank AZ-101 HLW Sample, the Cs and Tc Eluates, and the Actual Blended HLW ................................................................................................................. 5.6 Table 5.7. Chemical Additives for 173 g Glass ........................................................................................ 5.8 Table 5.8. Mass Fractions of Glass Component Oxides in the Batch Chemicals Listed in Table 5.9...... 5.8 Table 5.9. AZ-101 Mineral and Chemical Glass-Former Additives......................................................... 5.9 Table 5.10. Compositions (in mg element/g glass) and Standard Deviations of Standard Reference Glasses ............................................................................................................................................ 5.15 Table 5.11. Radioisotopes with Half-Lives Longer than 10 Years, the N/N0 Values at t = 11 (2015) and 1111 (3115) Years, and the Principle Daughter Products ............................................ 5.17 v Table 5.12. CCC Approximated as a Series of Linear Segments ........................................................... 5.18 Table 5.13. Spinel Minerals ...................................................................................................................
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