SDMS Document ^
107514
02-S508-22B-SI-RI
FINAL DRAFT SITE INSPECTION REPORT AND HAZARD RANKING SYSTEM i\^OD£L BROOK INDUSTRIAL PARK BOUND BROOK, NEW aERSEY
PREPARED UNDER
TECHNICAL DIRECTIVE DOCUMENT NO. 02-8508-22B CONTRACT NO. 68-01-6699
FOR THE
ENVIROPIMSJ^TAL SERVICES DIYISIOfS U^.EmmXMMENTM. !?ROTECTIOi^^ AGENCY
APRIL 15, 1986
NUS CORPORATION SUPERFUND DIVISION
SUBMITTED BY REVIEWED/APPROVED BY
4^ c^<>^^ •>^.. J^ QTUKhl^^ a^ DONALD HES5EMER RONALD M. NAMAr PR03ECT MANAGER REGIONAL PROJECT MANAGER Contents
—.... • •-• i- « S«ction 1 Site Inspection Report Executive Summary 2 Environmental Protection Agency Form 2070-13 3 Maps and Photographs * Documentation Records for Hazard Ranking System 3 Hazardous Ranking System Scoring Forms 6 Bibliography of Information Sources 7 Press Release Summary - MITRE Hazardous Ranking System 3 Attachments - Cited Documents
L
10M2S SECTION 1
SITE INSPECTION REPORT EXECUTIVE SUMMARY
100026 m CJUHHCRAnOSJ Q A Halliburton Company
POTENTIAL HAZARDOUS WASTE SITE SITE INSPECTION REPORT EXECUTIVE SUMMARY
Brook Industrial Park NEW . Site Name EPA Site ID Number
100 West Main Street Bound Brook, New Jersey 02-8508-22B Address TDD Number
SITE DESCRIPTION
The Brook Industrial Park is a ^.5 acre complex of light industries and warehouses situated on the north banks of the Raritan River in the Borough of Bound Brook, New Jersey. The industrial park is bordered to the north by the Central Railroad of New Jersey and to the south by the Lehigh Valley and Port Reading Railroads which are situated next to the Raritan River. Residential areas are located on the north side of the Central Railroad tracks and to the west of the site.
The facility has been in existence since the late 1800's. Industrial, chemical, and pesticide production, usage, and storage operations began here in 1971 when Blue Spruce Chemical occupied some of the buildings. The storage of Agent Orange on the site has also been documented. Mr. Richard Schleck is currently the owner of the property. Other occupants of the buildings at the Brook Industrial Park include; Consolidated Steel Fabricators (manufacturer of steel products), K. Jabat, Inc. (extruded plastic products), Jame Fine Chemicals, Inc. (specialty chemicals), National Metal Finishings Corporation (metal plating), and Sterling Center Corporation (pet supplies). . These companies have operated at Brook Industrial Park for ten to twelve years.
Several of these operations have been cited for inadequate housekeeping and waste disposal practices. Investigations by the Middlebrook Regional Health Commission and the New Jersey Department of Environmental' Protection (NJDEP) were initiated when workers within the buildings became ill.
Testing by NJDEP and USEPA has shown contamination of the buildings, soils, and groundwater. Fines and indictments have been served to several of the operators for damages and lack of compliance with mandates for •» remedial action. EPA has authorized a Remedial Investigation/Feasibility ^ study (RI/FS) for the Blue Spruce International Site.
HAZARD RANKING SCORE: 5^= 58.68 (Saw= 100, Ssw= 17M, Sa=0) SFE=0, SDC=62.50
Prepared by: Scott Engle Date: 2/6/86 of NUS Corporation 100027 SECTION 2
ENVIRONMENTAL PROTECTION AGENCY FORM 2070-13
r
100028 POTENTIAL HAZARDOUS MASTE SITE 1. IDENTIFICAfiON SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER PART 1 - SITE LOCATION AND INSPECTION INFORMATION NJ NEW ri" !;iTg WAHk AND LUCAIIUH 01 ^ITE NAME (Legal, cooaon, or descriptive nam of site) 02 STREET, ROUTE NO., OR SPECIFIC LOCATION IDENTIFIER
' Brook Industrial Park 100 West Main Street 03 cm 04 STATE 05 ZIP CODE 06 COUNTY 07 COUNTY 08 CONG DIST. CODE Bound Brook NJ 08805 Somerset 35 NJ05 09 COORDINATES 10 TYPE OF OWNERSHIP (Check one) LATITUDE LON&ITUOE I A. PRIVATE B. FEDERAL C. STATE _ D. COUNTY ~ E. MUNICIPAL ~ F. OTHER 4 QO 3 3' 3 0". 0 7 40 3 2' 2 9V S. UNKNOWN
III. INSPECTION INFORMATION 01 DATE OF INSPECTION 02 SITE STATUS 03 YEARS OF OPERATION X ACTIVE 1971 / Current UNKNOWN 6/ 19/85 INACTIVE BEGINNING YEAR ENDING YEAR MONTH DAY YEAR AGENCY PERFORMING INSPECTION (Check all that apply) _ A. EPA XB. EPA CONTRACTOR NUS Corporation C. MUNICIPAL D. MUNICIPAL CONTRACTOR (Nane of fim) (Nane of fim) E. STATE F. STATE CONTRACTOR G. OTHEA (Name of fins) (Specify) 05 CHIEF INSPECTOR 06 TITLE 07 ORGANIZATION 08 TELEPHONE NO. Richard Califano Toxicologist NUS Corp. (201) 225-6160 09 OTHER INSPECTORS 10 TITLE II ORGANIZATION 12 TELEPHONE NO. Don Hessemer Environmental Scientist NUS Corp. (201) 225-6160 Paul McNally Biologist NUiS Corp. (201) 225-6160 Jim Brown Soil Chemist NUS Corp. (201) 225-6160 Steve Maness Site Safety Officer NUS Corp. (201) 225-6160 Barry Bestle Technician NUS Corp. (201) 225-6160
13 SITE REPRESENTATIVES INTERVIEWED 14 TITLE 15 ADDRESS 16 TELEPHONE NO. Richard Schleck Owner 100 West Main Street (201) 469-7760 Bound Brook, New Jersey
17 ACCESS GAINED BY 18 TIME OF INSPECTION 19 WEATHER CONDITIONS (Check one) X PERMISSION 0950 Clear, Sunny, Temp. 70OF. (mid) WARRANT
IV. INFORMATION AVAILABLE FROM 01 CONTACT 02 OF (Agency/Organization) 03 TELEPHONE NO. Diana Messina U.S. Environmental Protection Agency (201) 321-6685 100029 04 PERSON RESPONSIBLE FOR SITE INSPECTION FORM 05 AGENCY 06 ORGANIZATION 07 TELEPHONE NO. 08 DATE
Scott W. Engle, Pete Von Schondorf, Charlotte Ryden NUS Corp. Region II FIT (201) 225-6160 1/28/86 MONTH DAY YEAR EPA FORM 2070-13 (7-81) POTENTIAL HAZARDOUS WASTE SITE 1. IDENTiFlCAribN SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER" PART 2 - WASTE INFORMATION NJ NEW
II. WASTE STATES. QUANTITIES. AND CHARACTERISTICS _ 01 PHYSICAL StAfES (Check all that apply) 02 wA^t^ quANtlTY At SIT^ 03 WASTE CHARACTERISTICS (Check all that apply) A. SOLID E. SLURRY (Measures of waste X A. TOXIC E. SOLUBLE I. HIGHLY VOLATILE J B. POWDER. FINES X F. LIQUID quantities Mst be X B. CORROSIVE F. INFECTIOUS ~ J. EXPLOSIVE ~ C. SLUDGE ~ G. GAS Independent) ~ C. RADIOACTIVE G. FLAWUBLE X K. REACTIVE It D. PERSISTENT H. IGNITA8LE * L. INCOMPATIBLE X D. OTHER Incorporated with soil i wastes TONS * ~ M. NOT APPLICABLE (Specify) CUBIC YARDS NO. OF DRUMS * Soil and Water Contaminants III. WASTE TYPE CATEGORY SUBSTANCE NAME 01 GROSS AMOUNT 02 UNIT OF MEASURE 03 C0M4ENTS
SLU SLUDGE
OLW OILY WASTE
SOL SOLVENTS Unknown Soil and Water Contaminants
PSD PESTICIDES Unknown Soil and Water Contaminants
OCC OTHER ORGANIC CHEMICALS Unknown Soil and Water contaminants
IOC INORGANIC CHEMICALS Unknown Soil and Water Contaminants
ACO ACIDS Unknown Water Contaminants
BAS BASES
MES HEAVY METALS Unknown Soil and Water Contaminants IV. HAZARDOUS SUBSTANCES (See Appendix for aost frequently cited CAS Numbers) 06 MEASURE OF CATEGORY 02 SUBSTANCE NAME 03 CAS NUMBER 04 STORAGE/DISPOSAL METHOD 05 CONCENTRATION CONCENTRATION
PSD Aldrin 309-00-2 Soil Contamination 38.6 ppm PSD Dieldrin 60-57-1 Soil Contamination 10 ppm PSD Chlordane 57-74-9 Soil Contamination 958 ppm PSD DDT 50-29-3 Soil Contamination 292 ppm PSD Al pha-Endosulfan 115-29-7 Soil Contamination 6 ppm PSD Heptachlor epoxide 1024-57-3 Soil Contamination 0.62 ppm PSD Heptachlor 76-44-8 Soil Contamination 5 ppm
PSD Endrin 72-20-8 Soil Contamination 1.4 ppm PSD Methoxychlor 72-43-5 Soil Contamination 70 ppm PSD Malathion 121-75-5 Soil Contamination 37 ppm
PSD alpha-BHC 319-84-6 Soil Contamination 1.43 ppm
PSD beta-BHC 319-85-7 Soil Contamination 2.79 ppm PSD delta-BHC 319-86-8 Soil Contamination 1.4 ppm OCC i 2.3,7.8-TCDD (Dioxin) 1746-01-6 Soil Contamination 6.1 •. ppb See Attachment A
V. FEEDSTOCKS (See Appendix for CAS NumbersT CATEGORY 01 FEEDSTOCK NAME 02 CAS NUMBER CATEGORY 01 FEEDSTOCK NAME 02 CAS NUMBER
FDS Toluene 108-88-3 FDS Chromium 7440-47-3
FDS Xylene • 1330-20-7' FDS Nickel 7439-97-6
FDS Arsenic 7440-38-2 FDS Mercury 7440-02-0
FDS Cadmium 7440-43-9 FDS
VI. SOURCES OF INFORMATION (See specific references, e.g., state files, sample analysis, reports) Site Inspection Report, Blue Spruce International, Inc., NUS Corporation Region II FIT, 6/19/85. NJDEP Background Files, Blue Spruce, National Metals, Jame Fine. EPA/NUS Background Files, Brook Industrial Park. AIIAtllMLNI A
POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT Oi STATE 02 SITE NUMBER PART 2 - WASTE INFORMATION NJ NEW
IV. HAZARDOUS SUBSTANCES (See Appemlix for aost frequently cited CAS Nuabers) CATEGORY 02 SUBSTANCE NAME 03 CAS NUMBER 04 STORAGE/DISPOSAL METHOD 05 CONCENTRATIONCENTRATIOr1 N CONCENTRATION SOL Benzene 71-43-2 Groundwater Contamination 260 ppb
SOL Chlorobenzene 108-90-7 Soil Contamination 890 ppb
SOL Carbon tetrachloride 55-23-5 Groundwater Contamination 2 : ppb SOL Chloroform 67-66-3 Groundwater Contamination 22 ppb SOL Ethyl benzene • 100-41-4 Groundwater Contamination 340 ppb SOL Tetrachloroethene 127-18-4 Groundwater Contamination 160 ppb SOL Toluene 108-88-3 Groundwater Contamination 9000 ppb SOL Trichloroethene, 79-01-6 Groundwater Contamination 141 .. ppb i: SOL Total Xylenes 1330-20-7 Groundwater Contamination 3140 ppb '^ OCC 1,2-dichloroethane 107-06-2 Groundwater Contamination 24 ppb OCC. 2-ehloro toluene. 95-49-8 Groundwater Contamination 36 ppb , OCC 1,2,4-trimethylbenzene 25551-13-7 Groundwater Contamination 49 ppb ,, OCC 1,3,5-triroetbylbenzene 25551-13-7 Groundwater Contamination 16 ppb OCC l,2-dichloroben2ene 95-50-1 Groundwater Contamination 64 ppb OCC .1,4-dichlorobenzene 106-46-7 Groundwater Contamination 46 ppb
OCC Hexachlorobutadiene 76-58-3 Soil Contamination 6 - ppb • OCC n-butylbenzene 104-51-8 Groundwater Contamination 14 . ppb OCC Sec-butyl benzene 135-98-8 Groundwater Contamination 27 ppb
• OCC • Trans-1,2-dichloroethene 540-59-0 Groundwater Contamination 28 ppb OCC 1,2-dichloropropane 78-87-5 Groundwater Contamination 16 ppb '• ,. OCC Fluorene 86-73-7 Groundwater Contamination 1.5 ppb OCC 4-nitrophenol 100-02-7 Groundwater Contamination 44 ppb
OCC 1,1,1-trichloroethane 71-55-6 Groundwater Contamination 6.4 ppb OCC Trifluorotoluene 999 Groundwater Contamination 190 ppb MES Lead 7439-92-1 Groundwater Contamination 1041 ppb
loooat POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 ilTE NUMBER PART 3 - DESCRIPTION OF HAZARDOUS CONDITIONS AND INCIDENTS NJ NEW
TmngARDUUi; CPNUlllUHiS AMD 1NC1ULHI5 01 X A. GROUNDWATER CONTAMINATION 02 X OBSERVED (DATE: 12/80 )POTENTIAL ALLEGED 03 POPUUTIOM POTENTIALLY AFFECTED: 149.864 04 SARRATIVE DESCRIPTION Contamination of the industrial well at Jame Fine has been documented. Metal plating wastes from National Metals are stored in cinder block basins which open directly to the groundwater on the site. Samples from NJDEP monitoring wells at the industrial park have also shown contamination to be present.
Ql. X B. SURFACE WATER CONTAMINATION 02 X OBSERVED (DATE: 8/15/80 ) POTENTIAL ALLEGED 03 POPULATION POTENTIALLY AFFECTED: 76.390 04 NARRATIVE DESCRIPTION Site 1s located adjacent to Raritan River, a water supply f^r some communities in Middlesex County, Surface runoff from i site may reach the river, carrying contaminants In suspension or solution. The relationship of the groundwater aquifer and I the Raritan River Is not established, NJDEP detected Lindane and Aldrin In a water sample collected from the river downstream of the point of discharge of surface runoff from the industrial park on August 15, 1980. • ,,. 01 X C. CONTAMINATION OF AIR 02 X OBSERVED (DATE: 8/26/85 ) X POTENTIAL ALLEGED I 03 POPOUTION POTENTIALLY AFFECTED: Unknown 04 NARRATIVE DESCRIPTION I. ^ Soil contaminants may become airborne and affect nearby area. Gaseous emissions may be associated with uncovered liquid containers (located within the buildings of the industrial park). Incidents of worker exposure to gaseous emissions have I': been recorded.
01. _ D. FIRE/EXPLOSIVE CONDITIONS 02 OBSERVED (DATE: ) POTENTIAL ALLEGED , 03 POPULATION POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION i il No known potential.
01. X E. DIRECT CONTACT 02 X OBSERVED (DATE: 8/26/85 ) X POTENTIAL ALLEGED 03 POPUUTION POTENTIALLY AFFECTED: 54 04 NARRATIVE DESCRIPTION Soils and groundwater at the site are known to be contaminated. Workers within the park may be affected through airborne inhalation, contact with liquids, or traffic exposure by walking. The Blue Spruce building structure has been found to be contaminated. Workers may come in contact with contaminated walls and floors.
01 X F. CONTAMINATION OF SOIL 02 X OBSERVED (DATE: 6/19/85 ) POTENTIAL ALLEGED 03 AREA POTENTIALLY AFFECTED: 4.5 acres* 04 NARRATIVE DESCRIPTION (ACRES) Contamination of the soils was documented during on-site investigations on the above date. Wind-blown contaminants would greatly Increase the affected area. Spillage and runoff to adjacent areas was documented 10/17/80. * The area reflected here is on-site only.
01. X G. DRINKING WATER CONTAMINATION 02 OBSERVED (DATE: ) X POTENTIAL ALLEGED 03 POPULATION POTENTIALLY AFFECTED: 149.864 04 RARRATIVE DESCRIPTION A June 29, 1983 report filed by NJ Department of Health, reported no contamination to a local private drinking water well. Hpwever, reports from onsite wells indicate the -probability for contamination exists. Inquiries to the Elizabethtown Water Company indicate 149,864 subscribers to their system drawing from public supply wells.
01 X H. WORKER EXPOSURE/INJURY 02 X OBSERVED (DATE: 7/30/80 ) POTENTIAL ALLEGED 03 iJORKERS POTENTIALLY AFFECTED: _54 04 NARRATIVE DESCRIPTION Workers at Consolidated Steel Fabricators complained of nausea, headache, dizziness, and burning throat from Irritation from substances suspected to originate from the Blue Spruce facility. Middle Brook Regional Health Commission employees suffered burning eyes and skin on 7/30/80 due to chemicals suspected to originate from Blue Spruce. Worker exposure to metal plating solvents and chromic acid was documented at National Metal on 9/7/82 by Middlebrook Regional Health Commission.
01 J< I. POPULATION EXPOSURE/INJURY 02 OBSERVED (DATE: ) XPOTENTIAL ALLEGED 03 POPULATION POTENTIALLY AFFECTED: 44.587* 04 NARRATIVE DESCRIPTION The potential for migration of contaminants by air, soil and water to areas outside the facility is great. . » *Above figure reflects estimated population within a 3-mile radius.
« EPA FORM 2070-13 (7-81) ^ ; . {00032 POTENTIAL HAZARDOUS WASTE SITE I. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER PART 3 - DESCRIPTION OF HAZARDOUS CONDITIONS AND INCIDENTS NJ NEW
II. HAZARfa6uS CONDITIONS AND INCIDENTS (Continued) 01 X J. DANAGE T6 tlO^ •' 02 OBSERVED (DATE: ) X POTENTIAL ALLEGED 04 NRRRATIVE DESCRIPTION The potential exists for damage to terrestrial and aquatic flora from contaminated soil, groundwater, and surface water.
01 X K. DAMAGE TO FAUNA 02 OBSERVED (DATE: ) X POTENTIAL ALLEGED 04 NARRATIVE DESCRIPTION (Include naBe(s) of species) ~ » - -. Ri^noff may bring pollutants/contamination into the Raritan River, also groundwater may contaminate river if hydraul ically connected. Game fish in the river may be affected. » " 01 XL. CONTAMINATION OF FOOD CHAIN 02 OBSERVED (DATE: ) X POTENTIAL ALLEGED 04 NARRATIVE DESCRIPTION ~ , Game fish existing 1n the Raritan River may also be affected and consumed by water fowl and/or people.
01 X M. UNSTABLE CONTAINMENT OF WASTES 02 X OBSERVED (DATE: 12/80 )" _ POTENTIAL _ ALLEGED (Spills/runoff/standing liquids/leaking druas) 03 POPULATION POTENTIALLY AFFECTED: 149.864 04 NARRATIVE DESCRIPTION Basement flooding of Blue Spruce building has been alleged while the building was occupied. Flooring has been hosed off and runoff allowed to settle in basement. Metal plating wastes have been dumped into unlined basins at National Metal. The basins are connected directly to the shallow aquifer beneath the site.
01 X N. DAMAGE TO OFFSITE PROPERTY 02 OBSERVED (DATE: ) X POTENTIAL ALLEGED 04 NARRATIVE DESCRIPTION The potential exists for contamination dispersal to affect neighboring residential and business areas.
01 X 0. CONTAMINATION OF SEWERS, STORM DRAINS, WWTPs 02 X OBSERVED (DATE: 4/15/82 ) POTENTIAL ALLEGED I 04 NARRATIVE DESCRIPTION A broken sewer line in the basement of the Blue Spruce building may have allowed contaminated water 1n the basement to enter the sewer system. Jame Fine discharges its waste water directly to the sewer system. 4/15/82 sample analysis of r discharge: ortho-chlorotoluene-12720 ppb, para-chlorotoluene-4900 ppb, toluene-3000 ppb, tetrachloroethylene-170 ppb. I 01 X P, ILLEGAL/UNAUTHORIZED DUMPING 02 X OBSERVED (DATE: 1/9/84 ) POTENTIAL ALLEGED 04 NARRATIVE DESCRIPTION On the above cited date, dumping of liquid wastes at National Metal was still ongoing. Some remedial measures were to have been in place by 11/13/84, however, complete compliance with state ordered actions was still unconfirmed in August, 1985. i : : 05 DESCRIPTION OF ANY OTHER KNOWN, POTENTIAL. OR ALLEGED HAZARDS Sampling of the Blue Spruce building structure in June 1985 revealed the presence of dioxin and Agent Orange herbicides in the flooring and walls.
III. TOTAL POPUUTION POTENTIALLY AFFECTED: 149.864 — IV. COMMENTS The effects of contaminants on population , flora and fauna is unknown
V . SOURCES OF INFORMATION (Cit«! specific re ferences. e 9-1 state files. sample ana lysis. reports) NJDEP Background Files. EPA/NUS Background Files. EPA FORM 2070-13 (7-81) IQC993 POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER PART 4 - PERMIT AND DESCRIPTIVE INFORMATION NJ NEW II. PERMIT INFORMATION ,.01 TYPE OF PERMIT ISSUED 02 PERMIT NUMBER 03 DATE ISSUED 04 EXPIRATION DATE 05 COMMENTS (Check all that apply) A. NPDES There are no known permits held by site owner.
B. UIC
C. AIR
X D. RCRA Jame Fine NJD054120571 10/9/80 Unknown
_ E. RCRA INTERIM STATUS
_ F. SPCC PLAN
_ G. STATE (Specify)
_ H. LOCAL (Specify)
_ I. OTHER (Specify)
J. NONE III. SITE DESCRIPTION 01 Storage/Disposal 02 AMOUNT 03 UNIT OF MEASURE 04 TREATMENT 05 OTHER (Check all that apply) (Check all that apply) A. SURFACE IMPOUNDMENT A. INCINERATION X A. BUILDINGS ON SITE 8. PILtS B. UNDERGROUND INJECTION C. DRUMS, ABOVE GROUND Less than 40 C. CHEMICAL/PHYSICAL D. TANK. ABOVE GROUND 0. BIOLOGICAL 06 AREA OF SITE E. TANK, BELOW GROUND E. WASTE OIL PROCESSING F. LANDFILL F. SOLVENT RECOVERY G. LANOFARM G. OTHER RECYCLING/RECOVERY 4.5 H. OPEN DUMP H. OTHER Oumpinq on ground surface (Acres) I. OTHER Ground surfac^__e an_ d 3.270 Gallons/day (Specify) and in cinder (Specify) open basins block basins. within building. 07 COMMENTS The contamination of the environs of the industrial park, which has resulted from improper disposal activities at the individual facilities, is difficult to trace back to one particular individual or event. IV. CONTAINMENT ' ~~~~ '. 01 CONTAINMENT OF WASTES (Check one) _ A. ADEQUATE. SECURE _ 8. MODERATE _ C. INADEQUATE, POOR X D. INSECURE, UNSOUND, DANGEROUS 02 DESCRIPTION OF DRUMS, DIKING, LINERS, BARRIERS, ETC. Blue Spruce - pesticides were stored in unsealed 55 gallon drums and smaller containers and on plastic sheets in and around the building. The alleyway in front of the building was used to store Agent Orange. Drums have been reported to have been leaking at times. Spillage in the building was routinely swept into the basement. National Metals - metal plating wastes were dumped directly into unlined basins. Jame Fine - past practice of discharging waste water to ground, allowed to drain to Raritan River. V. ACCESSIBILITY 01 WASTE EASILY ACCESSIBLE: X YES NO 02 COMMENTS Blue Spruce - as the result of spills, surface soils and groundwater have been contaminated. Building is closed and fencing partially encloses one access way to the building's entrance. National Metal - the unlined basins are reportedly covered. Safety measures to prevent worker exposure ars reportedly Inadequate.
'VI SOURCES OF INFORMATION (Cite specific references, e.g.. state files, sample analysis, reports)
NJDEP Background Files. EPA/NUS Background Files.
EPA FORM 2070-13 (7-81) ^06»34^ POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER PART 5 - DEMOGRAPHIC. AND ENVIRONMENTAL DATA NJ NEW
11. DRlNKINfi WATER SUPPLT^ UriYPt OF URliiltlHe SUPPLV 02 STATUS 03 DISTAHCe TO SITE (Check as applicable) SURFACE WELL ENDANGERED AFFECTED MONITORED COMMUNITY A. X B. X A, X B. C. X A. • 25 (mi) NWt-CQMMUNITY C. 0. X D. E. X F. X B. On-site (•1) III. GROUNDWATER 01 GROUNDWATER USE IN VICINITY (Check one)
A. ONLY SOURCE FOR DRINKING X B. DRINKING C. COMMERCIAL. INDUSTRIAL. IRRIGATION 0. NOT USED, UNUSEABLE (Other sources (Linited other sources available) available) COMMERCIAL, INDUSTRIAL, IRRIGATION (No other water sources available) 02 POPULATlOti SEftvED BY GfeOUNO WATER: 149.86T 03 DISTANCE TO NEAREST DRINKING WATER WELL: •25 (ai) 04 DEPTH TO GROUNDWATER 05 DIRECTION OF GROUNDWATER FLOW 06 DEPTH TO AQUIFER 07 POTENTIAL YIELD 08 SOLE SOURCE AQUIFER OF CONCERN OF AQUIFER (ft) South (ft) Unknown (gpd) YES X NO 09 DESCRIPTION OF WELLS (Including useage, depth, and location relative to population and buildings) The nearest municipal well is within 1.25 miles of the site and is approximately 400 feet in depth. The nearest private well used for domestic needs is within .25 mile of the site and less than 35 feet in depth. The majority are over 100 feet in deptb. An industrial well is located within the Jame Fine facility and is known to be contaminated.
10 RECHARGE AREA 11. DISCHARGE AREA X YES COMMENTS' Aquifer is recharged through X YES COMMENTS Aquifer may be hydraulically connected _ NO permeable overburden. "NO to the Raritan River. IV. SURFACE WATER 01 SURFACE WATER USE (Check one) X A. RESERVOIR, RECREATION B. IRRIGATION, ECONOMICALLY C. COMMERCIAL, INDUSTRIAL D, NOT CURRENTLY USED DRINKING WATER SOURCE ~ IMPORTANT RESOURCES
02 AFFECTED/POTENTIALLY AFFECTED BODIES OF WATER NAME: AFFECTED DISTANCE TO SITE
Raritan River X .09 (mi)
(ni) (mi)
V DEMOGRAPHIC AND PROPERTY INFORMATION 01 TOTAL POPULATION WITHIN ' 02 DISTANCE TO NEAREST POPULATION ONE (1) MILE OF SITE TWO (2) MILES OF SITE THREE (3) MILES OF SITE
A. 11.341 B. 22.635 44,587 • 125 (mi) NO. OF PERSONS NO. OF PERSONS NO. OF PERSONS
03 NUMBER OF BUILDINGS WITHIN TWO (2) MILES OF SITE 04 DISTANCE TO NEAREST OFF-SITE BUILDING
7.749 ; .125 (Bi) 05 POPULATION WITHIN VICINITY OF SITE (Provide narrative description of nature of population within vicinity of site, e.g., rural, village, densely populated urban area) Moderately populated area, containing single or two family homes.
EPA FORM 2070-13 (7-81) 4Mfl^ POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER" PART 5 - WATER. DEMOGRAPHIC. AND ENVIRONMENTAL DATA NJ NEW
VI. ENVIRONMENTAL IHfOimAliOH ' 01 «RMEA6ILny OF UHi>AiURATED ZOME (Check one) A. 10-6 . 10-8 ca/sec _ B. 10-* - 10-6 ca/sec _ C. 10-4 . io-3 ca/sec X D. GREATER THAN 10-3 ca/sec
02 PERMEABILITY OF BEDROCK (Check one) A. IMPERMEABLE X B. RELATIVELY IMPERMEABLE C. RELATIVELY PERMEABLE D. VERY PERMEABLE (Leis than 10-6 ca/sec) (lO"* - 10-6 ca/sec) (10-2 . 10-4 ca/sec) (Greater than 10-2 ca/sec)
03 DEPTH TO BEDROCK 04 DEPTH OF CONTAMINATED SOIL ZONE 05 SOIL pH 20 (ft) 20 (ft) ' Unknown 06 NET PRECIPITATION 07 ONE YEAR 24 HOUR RAINFALL 08 SLOPf SITE SLOPE DIRECTION OF SITE SLOPE TERRAIN AVERAGE SLOPE 12 (in) 3 (in) S • South 3 I
09 FLOOD POTENTIAL 10 SITE IS IN 100 YEAR FLOODPLAIN _ SITE IS ON BARRIER ISLAND, COASTAL HIGH HAZARD AREA. RIVERINE FLOODWAY 11 DISTANCE TO WETLANDS (5 acre alnlmua) 12 DISTANCE TO CRITICAL HABITAT (of endangered species) ESTUARINE OTHER Not Appi icable (mi)
A.; 5 (Bi) B. .09 (•i) ENDANGERED SPECIES: 13 LAND USE IN VICINITY DISTANCE TO: COMMERCIAL/INDUSTRIAL RESIDENTIAL AREAS: NATIONAL/STATE PARKS. AGRICULTURAL LANDS FORESTS. OR WILDLIFE RESERVES PRIME AG LAND AG LAND A. (ai) B. • 125 (mi) C. 1.75 (ai) D. 1.75 (ai)
14 DESCRIPTION OF SITE IN RELATION TO SURROUNDING TOPOGRAPHY
L The site is located on the northern bank of the Raritan River, approximately 500 feet from the river. Several buildings are within the industrial park. The site slope is gentle and pitches to the south and southwest towards the river and two seasonally wet.drainge ditches. The topography of the site 1s artificial, the result of fill placed prior to the 1940's. Early maps of the area show the site being adjacent to a shallow lake or marsh. This condition may have existed prior to construction of the site (building) or the result of construction. Flooding has occurred at the site.
VII SOURCES OF INFORMATION (Cite specific references e.g.. state files, sample analysis, reports)
Kirkham, W.C. 1975. Soil Survey of Somerset County, New Jersey Department of Agriculture Soil Conservation Service. NJDEP Bakckground Files.
lOOd.36 POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER PART 7 - OWNER INFORMATION NJ NEW
PARENT COMPANY (If applicable) •mniiiiftmiiNAME o oi D + B NUMBER 08 NAME 09 D t B WIMBER Richard Schleck 03 STREET ADDRESS (P.O. Box, RFD<. etc.) 04 SIC CODE 10 STREET ADDRESS (P.O. Box. RFOI. etc.) 11 SIC CODE 100 West Main Street 05 CITY 06 STATE 07 ZIP CODE 12 CITY 13 STATE 14 ZIP CODE Bound Brook NJ 08805
01 NAME 02 D + B NUMBER 08 NAME 09 0 + B NUMBER
03 STREET ADDRESS (P.O. Box, RF0#, etc.) 04 SIC CODE 10 STREET ADDRESS (P.O. Box. RFD#. etc.). 11 SIC CODE
05 CITY 06 STATE 07 ZIP CODE ' 12 CITY 13 STATE 14 ZIP CODE
01 NAME 02 0 + B NUMBER 08 NAME 09 D + B NUMBER
03 STREET ADDRESS (P.O. Box. RFD#. etc.) 04 SIC CODE 10 STREET ADDRESS (P.O. Box. RFO#, etc.) 11 SIC CODE
I 05 CITY 06 STATE 07 ZIP CODE 12 CITY 13 STATE 14 ZIP CODE
01 NAME 02 D + B NUMBER 08 NAME 09 D + B NUMBER I; 03 STREET ADDRESS (P.O. Box, RFD«. etc.) 04 SIC CODE 10 STREET ADDRESS (P.O. Box. RFD#. etc.) 11 SIC CODE
05 CITY 06 STATE 07 ZIP CODE 12 CITY 13 STATE 14 ZIP CODE
[ III. PREVIOUS OWNER(S) (List most recent first) IV. REALTY OWNER(S) (If applicable; list most recent first)" 01 NAME 02 0 + B NUMBER 01 NAME 02 D + B NUMBER
!'• Brook Associates (Partnership) ii.. 03 STREET ADDRESS (P.O. Box. RFD#. etc.) 04 SIC CODE 03 STREET ADDRESS (P.O. Box. RFD#. etc.) 04 SIC CODE 100 West Main Street r 05 CITY 06 STATE 07 ZIP CODE 05 CITY 06 STATE 07 ZIP CODE 1, Bound Brook NJ 08805 01 NAME 02 D + B NUMBER 01 NAME 02 D + B NUMBER
03 STREET ADDRESS (P.O. Box. RFDI, etc.) 04 SIC CODE 03 STREET ADDRESS (P.O. Box, RFDI, etc.) 04 SIC CODE
* 05 CITY 06 STATE 07 ZIP CODE 05 CITY 06 STATE 07 ZIP CODE
01 NAME 02 D + B NUMBER 01 NAME 02 D + B NUMBER
03 STREET ADDRESS (P.O. Box, RF0#. etc.) 04 SIC CODE 03 STREET ADDRESS (P.O. Box. RFD#. etc.) 04 SIC CODE
05 CITY 06 STATE 07 ZIP CODE 05 CITY 06 STATE 07 ZIP CODE
V. SOURCES OF INFORMATION (Cite specific references, e.g., state files, sample analysis, reports)
NJDEP Background Files, Borough of Bound Brook Tax Assessor Office. EPA FORM 2070-13 (7-81) 100017 POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER" PART 8 - OPERATOR INFORMATION NJ NEW
II. CURRENT OPERATOR(sT OPERATOR'S PARENT COMPANY (If applicable)" 01 NAME Consolidated Steel Fabricators,02 D + B Number10 NAME 11 D + B NUMBER K. Jabat Inc., Jame-Fine Chemicals, Inc., National Metal Finishings Corp., Sterling Center Corporation 03 STREET ADDRESS (P.O. Box, RFD#. etc.) 04 SIC CODE 12 STREET ADDRESS (P.O. Box. RFDI, etc.) 13 SIC CODE 100 West Main Street 05 CITY 06 STATE 07 ZIP CODE 14 CITY 15 STATE 16 ZIP CODE Bound Brook NJ 08805 08 YEARS OF OPERATION 09 NAME OF OWNER '
10 - 12 years III. PREVIOUS OPERATOR(S) (List most recent first: PREVIOUS OPERATOR'S PARENT COMPANIES (If applicable) Provide only if different froa owner) 01 NAME 02 0 -)- B Nuaber 10 NAME IID + BNUMBER Blue Spruce International, Inc. 03 STREET ADDRESS (P.O. Box. RFDI. etc.) 04 SIC CODE 12 STREET ADDRESS (P.O. Box. RFDI, etc.) 13 SIC CODE o/c TIFA Limited 05 CITY 06 STATE 07 ZIP CODE 14 CITY 15 STATE 16 ZIP CODE Milllngton NJ 07980 08 YEARS OF OPERATION 09 NAME OF OWNER 11 years Arnold Livingston
01 NAME 02 0 -f B Nuaber 10 NAME 11 D + B NUMBER
03 STREET ADDRESS (P.O. Box. RFDI, etc.) 04 SIC CODE 12 STREET ADDRESS (P.O. Box, RFDI. etc.) 13 SIC CODE
05 CITY 06 STATE 07 ZIP CODE 14 CITY 15 STATE 16 ZIP CODE
08 YEARS OF OPERATION 09 NAME OF OWNER
01 NAME 02 Q t B Nuaber 10 NAME 11 D t B NUMBER
03 STREET ADDRESS (P.O. Box, RFDI, etc.) 04 SIC CODE 12 STREET ADDRESS (P.O. Box, RFOI, etc.) 13 SIC CODE
05 CITY 06 STATE 07 ZIP CODE 14 CITY 15 STATE 16 ZIP CODE
08 YEARS OF OPERATION 09 NAME OF OWNER
IV. SOURCES OF INFORMATION (Cite specific references, e.g.. state files, sample analysis, reports) NJDEP Background Files.
100030
EPA FORM 2070-13 (7-81) POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 SitE NUMBER PART 9 - GENERATOR/TRANSPORTER INFORMATION NJ NEW
II ON-SITE GENERATOR 01 NAME Blue Spruce International, Inc., 02 0 + 8 NUMBER Jame Fine Chealcals Inc., National Metal Finishings Corp., K. Jabat Inc. 03 STREET ADDRESS (P.O. Box. RFPI, etc.) 04 SIC CODE 100 West Main Street 05 CITY 06 STATE 07 ZIP CODE Bound Brook NJ 08805
III OFF-SITE GENERATORdT 01 NAME 02 D + B NUMBER 01 NAME 02 D + B NUMBER
03 STREET ADDRESS (P.O. Box. RFDI. etc.) 04 SIC CODE 03 STREET ADDRESS (P.O. Box. RFDI. etc.) 04 SIC CODE
05 CITY 06 STATE 07 ZIP CODE 05 CITY 06 STATE 07 ZIP CODE
01 NAME 02 D + B NUMBER 01 NAME 02 D -I- B NUMBER
03 STREET ADDRESS (P.O. Box, RFDI, etc.) 04 SIC CODE 03 STREET ADDRESS (P.O. Box. RFDI. etc.) 04 SIC CODE
05 CITY 06 STATE 07 ZIP CODE 05 CITY 06 STATE 07 ZIP CODE
IV. TRANSPORTER(S) 01 NAME 02 D -«• B NUMBER 01 NAME 02 D + B NUMBER
03 STREET ADDRESS (P.O. Box. RFDI. etc.) 04 SIC CODE 03 STREET ADDRESS (P.O. Box. RFDI. etc.) 04 SIC CODE
05 QITY 06 STATE 07 ZIP CODE 05 CITY 06 STATE 07 ZIP CODE
01 NAME 02 D -t^ B NUMBER 01 NAME 02 D + B NUMBER
03 STREET ADDRESS (P.O. Box, RFDI. etc.) 04 SIC CODE 03 STREET ADDRESS (P.O. Box, RFDI, etc.) 04 SIC CODE
05 CITY 06 STATE 07 ZIP CODE 05 CITY 06 STATE 07 ZIP CODE
V. SOURCES OF INFORMATION (Cite specific references, e.g., stat files, sample analysis, reports) NJDEP Background Files.
10003.9
EPA FORM 2070-13 (7-81) POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER PART 10 - PAST RESPONSE ACTIVITIES NJ NEW
II. PAST RESPONSE ACTIVITIES 01 A. WATER SUPPLY CLOSED 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history. 01 B. TEMPORARY WATER SUPPLY PROVIDED 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history. , •; 01 C. PERMANENT WATER SUPPLY PROVIDED 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history. 01 _X_ D. SPILLED MATERIAL REMOVED 02 DATE: 4/82 03 AGENCY: . NJDEP 04 DESCRIPTION One truck load of contaminated soil was removed from the site. 01 _X_ E. CONTAMINATED SOIL REMOVED 02 DATE: 4/82 03 AGENCY: NJDEP 04 DESCRIPTION One truck load of contaminated soil was removed from the site.
01 F. WASTE REPACKAGED 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history. 01 G. WASTE DISPOSED ELSEWHERE 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history.
01 H. ON SITE BURIAL 02 DATE: 03 AGENCY: 04 DHCRIPTION No past history,
01 I. IN SITU CHEMICAL TREATMENT 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history, 01 J. IN SITU BIOLOGICAL TREATMENT 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history.
01 K. IN SITU PHYSICAL TREATMENT 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history.
01 L. ENCAPSULATION 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history.
01 M. EMERGENCY WASTE TREATMENT 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history,
01 __ N. CUTOFF WALLS 02 DATE: 03 AGENCY: 04 DESCRIPTION No past history.
01 _X_ 0. EMERGENCY DIKING/SURFACE WATER DIVERSION 02 DATE: 2/19/80 03 AGENCY: NJDEP 04 DESCRIPTION NJDEP ordered Jame Fine Chemicals, Inc. to construct a dike to prevent waste water from leaving property and entering the Raritan River. 03 AGENCY: 01 P. CUTOFF TRENCHES/SUMP 02 DATE: 04 DESCRIPTION No past history. 01 Q. SUBSURFACE CUTOFF WALL 02,DATE: 03 AGENCY: 04 DESCRIPTION No past history. lOOA^i^ POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER' PART 10 - PAST RESPONSE ACTIVITIES NJ NEW
O; BATE; U AfiCNCt: 04 DESCRIPTION No past history. 01 JL S. CAPPING/COVERING 02 DATE: . 7/16/83 03 AGENCY: NJDEP 04 DESCRIPTION (2 .3,7.8 -TCDO) outside the 01 T. BULK TANKAGE REPAIRED 02 DATE: . 03 AGENCY: 04 DESCRIPTION No past history, 01 U. GROUT CURTAIN CONSTRUCTED 02 DATE: . 03 AGENCY: 04 DESCRIPTION No past history. . 01 V. BOnOM SEALED 02. DATE: . 03 AGENCY: 04 DESCRIPTION No past history. I 01 W. GAS CONTROL 02 03 AGENCY: 04 DESCRIPTION DATE: No past history.
01 X. FIRE CONTROL 02 03 AGENCY: 04 BESCRIPTION DATE: No past history. 01 Y. LEACHATE TREATMENT 02 03 AGENCY: 04 DESCRfPTION DATE: No past history. 01 Z. AREA EVACUATED 02 03 AGENCY: 04 DESCRIPTION DATE: No past history. 01 JL 1. ACCESS TO SITE RESTRICTED 02 8/13/83 03 AGENCY: 04 DESCRIPTION DATE: Owner of the Industrial Park (Schleck) installed a fence to restrict access to contaminated alley way. The Blue Spruce building is locked and not accessible to anyone without personal protective equipment. 01 2. POPULATION RELOCATED 02 DATE: 03 AGENCY: f-' 04 DESCRIPTION I No past history. 01 3. OTHER REMEDIAL ACTIVITIES 02 DATE: 03 AGENCY: 04 DESCRIPTION • No past history.
III. SOURCES OF INFORMATION (Cite specific references, e.g., state files, sample analysis, reports) NJDEP Background 'Files.
100041 POTENTIAL HAZARDOUS WASTE SITE 1. IDENTIFICATION SITE INSPECTION REPORT 01 STATE 02 SITE NUMBER PART 11 - ENFORCEMENT INFORMATION NJ NEW
II. ENFORCEMENT INFORMATION
01 PAST REGULATORY/ENFORCEMENT ACTION X YES _ NO
02 DESCRIPTION OF FEDERAL. STATE. LOCAL REGULATORY/ENFORCEMENT ACTION
Blue Spruce Since 1975 there have been, numerous complaints and fines filed against Blue Spruce International by Federal and State agencies. Few of these fines have been collected. In response to these fines the NJDEP started testing the environs around the Blue Spruce International building. The findings of these tests have shown contaminants have migrated from the site into the soil, groundwater and surface waters. The extent of contamination is not known. Remedial action at the site has consisted of: removal of cyie tr;uck load of soil, placement of an asphalt patch over soil contaminated with 2,3,7,8-TCDD outside the Blue Spruce building and a fence erected to limit access to a 2,3,7,8-TCDD contaminated alley way. Windows have been boarded and closed with cinder block. Stucco has also been applied to the exterior walls. , EPA has authorized an RI/FS for the Blue Spruce International site and the owner of Blue Spruce has been indicted for unlawful disposal of hazardous wastes generated from the pesticide plant. National Metal On August 7, 1985, an Administrative Order and Notice of Civil Administrative Penalty Assessment was served to Mr. Joseph Conrad (President of National Metal) and Mr. Richard Schleck and Mrs. Mary Frascella (joint owners of Brook Industrial Park). They were cited for unlawful discharge of wastes, failure to report such discharge and failure to comply with state recommendations for clean-up and monitoring actions.
Jame Fine Chemicals, Inc. Administrative Consent Order issued 4/29/80 to cease discharge of waste water into ground and surface waters of the state and to submit an engineering proposal for treatment and/or disposal of its wastes. Civil Administrative Penalty Assessment - $3750.
9/24/80 - Civil Administrative Penalty Assessment reduced from $3750 to $1250.
III. SOURCES OF INFORMATION (Cite specific references, e.g., sUte files, sample analysis, report) EPA/NUS, NJDEP Background Files.
I0OO43 EPA FORM 2070-13 (7-81) SECTION 3
MAPS
100043 WPS
Map ^'9-e 3 p,„,,,,^ .''*^ ^°"^ Map ^/9^^e 4 provides a" p'"''' '°'''^'°" ^^^ '•ocation Map ^'' ' ^°^^^^>e TCDO Sample
IOOO44 »:; (QUAD) BOUND BROOK. N.J.
SITE LOCATION MAP FIGURE 1 BROOK INDUSTRIAL PARK/BOUND BROOK, N.J. IMUS SCALE: V'2000' J ^ (20R=(DRAT)CDN A Halliburton Compan\ 100045 o 2 < 2 O 2 < 2 O 2 o < < 2 < o O O O o Ul 2^
£ CO > o CO < ec Ul LU .J Ul o zo a 5> Z cs < UJ UJ o o > s z z c s < c 3 3 < < o M UJ 3 O (0 a oc S & 09 s
! 1 r r
.1,1,11
o o c a
SL CD < S oc (A
o < e H (O 3 O z o o oc
100048 BROOK INDUSTRIAL PARK
LEGEND ® NJDEP WELL SAMPLE • SURFACE WATER SAMPLE • SOIL SAMPLE • •'AME FINE PRODUCTION WELL SAMPLE
FIGURE 3 SAMPLE LOCATION MAP BROOK INDUSTRIAL PARK, BOUND BROOK, NJ. IMUS caqpoRATONj APPHOX. SCALE: r-104' ^^ A Halliburton Company 10004? I eOMVAMv or *f w Jtm*fr SZ:Mrrl'~^^:^ .MAltQMM -5 «^^ I ttiti. ,..a vjsLas iii 121
LEGEND: H > 5.0 ppb TCDO • 21-0 ppb TCOD • <1.0 ppb TCDO
ENLARGEMENT OF GRIDS 2.3,4,8,9,10
: - • •%
'8 • » 10^
FIGURE 4 POSITIVE TCDD SOIL SAMPLE LOCATION MAP BLUE SPRUCE INTERNATIONAL, INC., BOUND BROOK, NJ. IMUS CXDRP^ORATTCDIN APPROX. SCALE: 1'-70' J A Halliburton Conn.pany 100048 •-' 'n----
SECTION 4 DOCUMENTATION RECORDS FOR HAZARD RANKING SYSTEM
m
100649 GROUNDWATER ROUTE
1 OBSERVED RELEASE Contaminants detected (5 maximum): Benzene, toluene, ortho-xylene, meta-xylene, para-xylene
Rationale for attributing the contaminants to the facility: NJDEP sample results 1/5/82 Background well sample contained aromatic hydrocarbons and chlorinated hydrocarbons in quantitites below the 1 ppb detection limit. Downgradient monitoring well #1 contained toluene at 9000 ppb, benzene at 260 ppb, meta-xylene at 2000 ppb, ortho-xylene at 860 ppb, and para-xylene at 280 ppb. Ref: M » » »
2 ROUTE CHARACTERISTICS Depth to Aquifer of C Depth(s) from the ground surface to the highest seasonal level of the saturated zone water table(s) of the aquifer of concern: Water table exists at 3' below ground surface. Ref: #6, 26 Depth from the ground surface to the lowest point of waste disposal/storage: 20 feet; waste has seeped through the building basement into the underlying soils. This is indicated by test results by NJDEP of basement soils and downgradient monitoring wells. Ref: #1, 3, 22, 23 lOOOSO Net Precipitation Mean annual or seasonal precipitation (list months for seasonal): Mean annual precipitation is 45 inches. Ref: //8 Mean annual lake or seasonal evaporation (list months for seasonal): Seasonal evaporation is 33.0 inches. Ref: #8 Net precipitation (subtract the above figures): 12 inches Permeability oi Unsaturated Zone Soil type in unsaturated zone: ii: Soil Conservation Service classifies this area as urban: NJDEP well records show construction fill over sands and gravels. Ref: #6, 26 Permeability associated with soil type: Variable permeability is associated with this soil type by the Soil Conservation Service: Reference is made to inches per hour. Scored on basis of greater than 10-3 cm/sec Ref: //6 Physical State Physical state of substances at time of disposal (or at present time for generated gases): Solids (powder) and liquids (solutions) have been observed. Ref: #9, 12, 28, 29 • • » fOOASi 3 CONTAINMENT Containment Method(s) of waste or leachate containment evaluated: Direct introduction of wastes to the groundwater is documented at National Metal Finishings Corp. At Blue Spruce, contaminants were kept in leaking drums or other similar containers that were open and frequently spilled. Ref: //lO, 11, 12, 13, 28 Method with highest score: Leaking drums and frequent spills. * WASTE CHARACTERISTICS Toxicity and Persistence Compouid(s) eveduated: Dioxin Chlordane Chromium Aldrin Lindane Ref: y/1, 2, 23, 22, 25, 8, 19, 31 Compound with highest score: ^ Chromium Note: Toxicity/Persistance Value = 18. Ref: #8, 31 Hazardous Waste Quantity Total quantity of hazardous isubstances at the facility, excluding those with a containment score of 0 (Give a reasonable estimate even if quantity is above maximum): 3,270 gallons of liquid waste per day are estimated to be generated by National Metals. This practice has continued for 10 years. Total amount is estimated at 7,848,000 gallons or 15,696 drums based on 240 working days per year, Ref: #8, 28, 29, 37 Basis of estimating cind/or computing waste quantity: Industrial User Report recorded daily output. Ref: #29 . 100052 5 TARGETS Gromdwater Use Use Distance to Nearest Well Location of nearest well drawing from aquifer of concern or occupied building not served by a public water supply: 162 West Main Street, Bound Brook, NJ No public supply hook-up is presently available. Ref: #27, 33, 34 Distance to above well or building: Less than )i mile. Ref: #34 Population Served by Groundwater Wells Within a 3-Mile Radius Identified water-supply well(s) drawing from aquifer(s) of concern within a 3-mile radius and populations served by each: 98 private wells identified in Bound Brook and South Bound Brook x 3.8 = 373 Elizabethtown Water Co. has 2 public supply wells within 3 miles of the site: Mountain Station well services an isolated section of Bridgewaterf Green Brook Road well services all of Warren Township, population of 9000 and system is interconnected with Common Wealth Water Company which services 100,000+ Ref: #14, 27, 33 Computation of land area irrigated by supply well(s) drawing from aquif eKs) of concern within a 3-mile radius, and conversion to population (1.5 pe<^le per acre). Information unavailable; will not alter score. Total population served by groundwater within a 3-mile radius: 100,000 plus Ref: #14, 27, 33 10005.1 SURFACE WATER ROUTE 1 OBSERVED RELEASE Contaminants detected in surface water at the facility or downhill from it (5 maximum): Trichloroethane 2400 ppb Tetrachloroethylene 6300 ppb Trichloroethylene 80 ppb Toluene 175 ppb .- Ethylbenzene 65 ppb Ref: #16 Rationale for attributing the contaminants to the facility: Analysis of a sample of discharge water from Jame Fine Chemical that was following over land drainage patterns to the Raritan River. Ref: #16 » * • 2 ROUTE CHARACTERISTICS Facility Slope and Intervening Terrain Average slope of facility in percent: 3% Ref: #17 [ Name/description of nearest downslope surface water: i Raritan River, a major river of Central New Jersey and the center of drainage in this part of the state. Ref: #16 Average slope of terrain between facility and above-cited surface water body in percent: 3% Ref: #17 Is the facility located either totally or partially in surface water? No, site is totally out of any surface water. • Ref: #17 100054 Is the facility completely surrounded by areas of higher elevation? No, general slope of the area is toward the Raritan River. Ref: #17 1-Year 24-Hour Rainfall in Inches 3 Ref: #8 Distance to Nearest Downslope Surface Water 500 feet Ref: #17 Physical State of Waste Solid (powder), liquid (solution) Ref: #9, 12 3 CONTAINMENT Containment Method(s) of waste or leachate containment evaluated: Drums were used to contain waste, resulting in leakage and spills. Ref: #10, 11, 12, 13 Method with highest score: Leaking and unsealed drums, frequent spills. Ref: #8 100055 ^• WASTE CHARACTERISTICS Toxicity and Persistence Compaund(s) evaluated Aldrin Dioxin Lindane Ref: #16, 25 Compound with highest score: Dioxin Ref: #19 Hazardous Waste Quantity Total quantity of hazardous substances at the facility, excluding those with a containment score of 0 (Give a reasonable estimate even if quantity is above maximum): An estimated 14000 gpd of contaminated process cooling water was discharged for 28 days. 14000 gpd X 28 days = 392,000 gallons 392,000 gal • 50 gal/drum = 7840 drums Ref: #16 Basis of estimating and/or computing waste quantity: Discharge was first noted on 2/14/80, sampled on 2/19/80 and again on 3/27/80. Flow was still constant on the second sampling. Ref: #7, 8, 16 • • » 5 TARGETS Surface Water Use Use(s) of surface water within 3 miles downstream of the hazardous substance: Recreational Ref: #14, 30 lOOOSfi Is there tidal influence? No there is not. Ref: #17 Distance to a Sensitive Environment Distance to 5-acre (minimum) coastal wetland, if 2 miles or less: Not Applicable Distance to 5-acre (minimum) fresh-water wetland, if 1 mile or less: 500 feet Ref: #17 Distance to critical habitat of an endangered species or national wildlife refuge, if 1 mile or less: Not Applicable Population Served by Surface Water Location(s) of water-supply intake(s) within 3 miles (free-flowing bodies) or 1 mile (static water bodies) downstream of the hazardous substance and population served by each intake: No surface water intakes exist downstream from the site in the prescribed 3 miles. Ref: #14 100057 Computation of land area irrigated by above-cited intake(s) and conversion to population (1.3 people per acre): Not Applicable Total population served: Not Applicable Name/description of nearest of above water bodies: Raritan River, however all intakes within'the 3 mile radius are upstream. Ref: #14 Distance to above-cited intakes, measured in stream miles. Not applicable Ref: #14 10 100058 AIR ROUTE 1 OBSERVED RELEASE Contaminants detected: Contaminants were not identified. Air sampling for specific contaminants was not conducted. Ref: #18 Date and location of detection of contaminants Inside Blue Spruce International building, 6 ppm OVA, June 19, 1985. Ref: #18 Methods used to detect the contaminants: OVA, operated in accordance with NUS Operating Guidelines Manual. Ref: #32 Rationale for attributing the contaminants to the site: Detection was inside Blue Spruce International building. Ref: #18 • » » 2 WASTE CHARACTERISTICS Reactivity and Incompatibility Most reactive compound: Not applicable, no identification of gases. Most incompatible pair of compounds: Not applicable, no identification of gases. 11 100050 Toxicity Most toxic compound: Not Applicable Hazardous Waste Quantity Total quantity of hazardous waste: Not Applicable Basis of estimating and/or computing waste quantity: Not Applicable » • » 3 TARGETS Population Within 4-Mile Radius Circle radius used, give population, and indicate how determined: 0 to 4 mi 0 to 1 mi 0 to 1/2 mi 0 to 1/* mi 76,390 11,341 1,478 Unknown Ref: #15 Distance to a Sensitive Environment Distance to 5-acre (minimum) coastal wetland, if 2 miles or less: Not Applicable Distance to 5-acre (minimum) fresh-water wetland, if 1 mile or less: 500 feet Ref: #17 12 10O06O Distance to critical habitat of an endangered species, if 1 mile or less: Not Applicable Land Use Distance to commercial/industrial area, if 1 mile or less: Site is an active industrial complex. Ref: #18, 17 Distance to national or state park, forest,' or wildlife reserve, if 2 miles or less: 1,000 feet Ref: #17 Distance to residential area, if 2 miles or less: 500 feet Ref: #17 Distance to agricultural land in production within past 5 years, if 1 mile or less: Not Applicable Distance to prime agricultural land in production within past 5 years, if 2 miles or less: 1.75 miles Ref: #17, 6 Is a historic or landmark site (National Register or Historic Places and National Natural Landmarks) within the view of the site? No there is not. Ref: #17 13 1900B1 FIRE AND EXPLOSION 1 CONTAINMENT Hazardous substances present: No potential fire hazard has been registered with the office of the clerk of building permits for the Borough of Bound Brook. Ref: #35 Type of containment, if applicable: Not Applicable. No potential hazards were identified in the on-site investigation Ref: #35 » • » 2 WASTE CHARACTERISTICS Direct Evidence Type of instrument and measurements: Not Applicable. Ignitabllity Compound used: Not Applicable Reactivity V Most reactive compound: Not Applicable Incompatibility Most incompatible pair of compounds: Not Applicable. « • • 14 100062 Hazardous Waste Quantity Total quantity of hazardous substances at the facility: Not Applicable. Basis of estimating and/or computing waste quantity: Not Applicable. * • » 3 TARGETS \ Distance to Nearest Population Not Applicable. I. Distance to Nearest Building Not Applicable. I 'f • Distance to Sensitive Environment Distance to wetlands: Not Applicable. il. « Distance to critical habitat: ,,, Not Applicable Land Use Distance to commercial/industrisd area, if 1 mile or less: Not Applicable. lOOOB.l Distance to national or state park, forest, or wildlife reserve, if 2 miles or less: Not Applicable Distance to residential area, if 2 miles or Jess: Not Applicable. Distance to agricultural land in production within past 5 years, if 1 mile or less: Not Applicable Distance to prime agricultural land in production within past 5 years, if 2 miles or ! less: ' Not Applicable. [ i. Is a historic or landmark site (National Register or Historic Places and National Natural Landmarks) within the view of the site? Not Applicable. ^ Population Within 2-Mile Radius Not Applicable. Buildings Within 2-Mile Radius t Not Applicable. 16 1000B4 I DIRECT CONTACT 1 OBSERVED INCIDENT Date, location, and pertinent details of incident: &/26/$5 Middlesex County Utilities Authority Pump Station workers experience burning eyes and skin due to chemical infiltration suspected to have originated from the Blue Spruce building. Ref: #21 8/1/80 Consolidated Metal Fabricators-Brook Industrial Park workers complain of nausea, headache, dizziness, burning throat. Irritant is again suspected to have originated from the Blue Spruce building. Ref: #20 • • * 2 ACCESSIBILITY Describe type of barrieKs): Blue Spruce Building is now sealed and locked, dioxin area has limited access, and has been capped with asphalt. However the remainder of site is accessible to other workers in the industrial park. Ref: #18 • • • 3 CONTAINMENT ^ Type of containment, if applicable: I i Material contained in drums or open containers has been removed from the building and the building locked. Known dioxin areas now have limited access. i|. Ref: #18 * » • 4 WASTE CHARACTERISTICS Toxicity Compounds evaluated: Dioxin Malathion Lindane DDT Aldrin Ref: #22, 23, 1, 3, 24, 25 Compound with highest score: Dioxin Ref: #19, 8 fOOOBS * * * 17 5 TARGETS Population Within One-Mile Radius 11,341 Ref: #15 Distance to Critical Habitat (of Endangered Species) No Critical Habitat located within 3 mile radius of the site. Ref: #36 i. 18 lOOOBB Facility name: Brook Industrial Park Location: Bound Brook, Somerset County, New Jersey EPA Region: II Persons(s) in charge of the facility: Richard Schleck 100 West Main Street Bound Brook, New Jersey 08805 Name of Reviewer: Scott Engle Date: Jainuary 31, 1986 General description of the facility: (For example: landfill, surface impoundment, pile, container; types of hazardous substances; location of the facility; contamination route of major concern; type of information needed for rating; agency action, etc.) Bound Brook Industrial Park is a 4.5 acre multiple services complex. Activities of the tenant industries has included chemical and insectide manufacture and storage, metal plating, plastics extrusion and steel fabrication. From 1971 to 1982 the Blue Spruce International firm formulated pesticides that were banned for use in the United States and could only be exported. Lax processing and housekeeping practices caused Blue Spruce to be investigated by the local Health Department and the New Jersey Department of Environmental Protection. Investigations showed frequent spills into the facility's basement and adjacent outdoor areas. National Metal Finishings Inc. has been cited for umpermitted discharge to metal plating wastes into the groundwater for the last 10 years. Operation of this facility is ongoing. From 2/14/80 to 3/27/80, Jame Fine Chemical, Inc. illegally discharged their cooling water used in the manufacture of L and D mandelic acid to the Raritan River. The major concerns at the industrial park are infiltration of waste into the groundwater and neighboring Raritan River. Waste storage and contamination of the buildings and surrounding area also pose a health hazard to the worker population. Investigations have already documented contamination of the industrial well located on- site and runoff into the Raritan River. The walls and floors of the Blue Spruce facility are also known to contain hazardous chemicals. Score: SM = 58.68 (Sgw = 100 Ssw = 17.48 Sa = o) SFE = O SDC = 62.50 100067 HRS COVER SHEET SECTIONS HAZARD RANKING SYSTEM 8CORINQ FORMS 100068 Ground 'ttMur Rout* Work Sr«««t Assignao vaiu* Multl- Rating Factor Scero (Circia 0n«i siiar Sce>« (Sacnon) CD 0bs*rv«0 R«<««a« ® 4^ «9 3.1 If O0a«rv«0 rwaaaa >a givan a scora ot 4S. orocaao to iin« [7]. If ooaanrad raiaaaa is 91 van • scora of 0. orecaad to iin« gl \2i Rout* Cnvaetansttcs ' 3.2 Oaetn to Aquifar o< 0 12 3 Concmn NM ^rveipttation 0 13 3 ParmMOriity o( tn« 0 1 2 j Unaaturvtod Zo«i« Physical Suta 0 12 3 Total Routa Otarsaanattcs Scora IS GO Containmant 0 12.^ 3.3 LiJ Wasta Cnaractanatica 3.4 Toxtcity / Par sistanea 0 3 « 9 12 1S(5» 1 ^^ 18 Hazaraoua waata 0l23<5«7(£)l' ^ 8 Quantity Total waata Cnaractanstics Scora Z6 Q Targota 3.5 Ground Watar Us* 0 1 2 Q) 3 1 9 0i3tanca to Naaraat 0 4 8 8 10 *0 Aaii / Poouianon 12 18 18 20 Sarrao 24 30 32 3S UO Total Targais Score H^ «9 0 If lino Q] la 48. muitloiy Q x Q * [3 If Hn* Q] la 0. muitioly [1] x [3] « Q * [s] [5733c S7 .330 LU OiviOa Ima (Tj Qy 57.330 inO multioly 8y 100 Sqw' 100 FIGURE 2 GROUND WATER ROUTE WORK SHEET 100069 Surfaco Wator Rout* Wont SA««t Asaign«d Valu* MuitK Rating Factor Sear* Max. R*f. (CIrei* On*) oli*r Seor* (Saetteni | Is" Obaarv^j n*iaaa« 0 (43) 1 45 © 4.1 If oeaorvvd ralaaaa la giv«n a vaiua of 48. precaao to Una [7]. If oeaarv«o raiaaa* la gtvan a valua of 0. groca«0 to iin« [Il Routa C?i«ract*natlea 4.2 r Facility Slop* and Intaryaning 0 12 3 1 3 Tarrain 1-yr. 24-hr. RalnfaM 0 12 3 1 3 •iatanc* to Naaraat Surfac* 0 12 3 2 8 Watar Pttyaieai Stat* 0 12 3 Total Rout* Charaetansties Seor« IS UJ Contaln«n*nt 0 12 3 4.3 Q] Waat* Cnaractariatica 4.4 Toxicity / Paraiatanc* 0 3 8 « 12 1S@ '5 Hazardoua Wast* 0 1 2 3 4 5T®8 1 Quantity Total Waat* CAar»ct*natiea Scora 26- 2« LD Targota 4.S Surfaca Watar Us* 9 Oistanca to a Sanalttv* (T) 3 8 Snvironmant ^ • Poouianon S*r Total Targats Scor* 10 5S If lln* QJ ia 0, muitleiy [z] « [H « H « Q IIZ50 84,390 n Olvida lina [?] By &4.3S0 «nd multioly Oy 100 I )^ /7. Vo-.rs- PiQURE 7 SURFACE WATER ROUTE WORK SHEET 100070 Air Rout* went Sfi*«t Assignod Vaiu* MultK RaUng Factor Scor* Max. flaf. (Clret* On*) Blior Scor* (Sacnoni Q Ob**rvad Raiaaa* ® 4S 5.1 Oat* and uocation: Sampilng Pfotocoi: O'^A u<.zd /^^ hecfU. d i^t-Af If lln* Q] ia 0. tna S, • 0. Entar on iin* [9] . If Iin* Q] ia 48. tft* Q] Waat* CAaractanatica 5.2 Raactivity and 0 12 3 incompatiDillty ToKteity 0 12 3 Hazardoua Waat* 012348878 Quantity Total Wasta Charactanates Scora 20 m Targats 5.3 Pooulation Within 0 9 12 19 18 30 4.MII* Radlua 21 24 27 30 Oistanca to Sansittv* 0 1 2 3 8 Envfronmant Und Us* 0 12 3 3 Total Targats Scora 39 Q Multlolv Q X [2] X Q] 35.100 uJ Olvida lina Q Qy 35.100 and muitioiy Oy 10Q s, - O FIGURES AIR ROUTE WORK SHEET 100071 S s^ Groundwatar Routa Scora iS^^) (00 / 0- OOd . 1 Surfaea Watar Rout* Scor* (S,w) [7.4^2-5- 32>ir.b3^4 Air Rout* Scor* t00072 Fir* and Csoioaion Worn SA*«t AssiQn*d vaiua Multi- Rating Factor Scor* Max. R*f. (Clrcia Ona> Oi)*r Scora (Sactioni m Containm*nt o 7.1 m waat* Charactanatics 7.2 Olr*a Evid*nca 0 tgnitaatiity 0 1 2 3 naactKity 0 1 2v 3 incomeaiiMiity 0 1 2 3 Hazaroewa waat* 0 1 2 3 4 5 8 7 8 Quantity Total waata Cnaractanaaea Scor* 20 Si Targats 7.3 Oistanca to Naaraat 0 1 3 4 5 Pooulation Oistanc* to Naaraat 0 1 3 Building OiatarKa to Sansitiv* 0 1 3 Environmont Und Us* 0 1 3 Poouianon WitMn 0 1 3 4 5 2-MII* Radlua Buildings Within 0 12 3 4 5 2-Mil* Radlua Total Targats Scora o 24 a 1,440 Muitlpiy Q X []] X Q o lH Oivida lina [T] Oy 1.440 and muitiDiy Oy 100 SPS - O FIGURE 11 FIRE AND EXPLOSION WORK SHEET 100073 Oir*et Contact Wert SltMt Asaign«d vaiua Multt> Rating Factor SCOfS Max. R*f. (Crct* On*) 8i»*r 3C0f9 1 (S«etieni G] 00a«r>«d ineMMM 0 (^ 1 A-sr 4« 8.1 If Una Q] ia 46. proc**d to im* Q . iflin* Q] la 0. proeaod to Hn* Q] 1 0 Aec***iWlKy 0 l' 2 3 i 3 8.3 ' 1 IS [ ffl Waa» CAaraetanattca " Toxie«y 0 1 I (s) S 13 IB L ••* 1 kSrarvra tA « 0l234(r) 4 2. A. Total Tsrgva Sdoni 32 \^ 21 If una 0 i* 4S. multl0iy Q] x (Tj x Q] llZ^oo If Un0 Q is 0. mwrttoly Q * 5] * 3 * 3 21.800 \\JJ Oiv*d* Iin* [7] Oy 21,800 and multtely Oy 100 SQC * '^"2- •'•TO FIGURE 12 OIRECT CONTACT WORK SHEET 100074 SECTION 6 BIBLiOQRAPHY OF INFORMATION SOURCES 10OO75 BIBLIOGRAPHY OF INFORMATION SOURCES HRS MODEL SOURCE LOCATION N3DEP survey, 1980 and 1981, on-site contamination - NUS Corp. Blue Spruce International, Table 2, Region II Office N3DEP survey 1980-1982, on-site groundwater contamination NUS Corp. versus Federal standards and criteria, Table D-2. Region II Office Indoor and outdoor soil contamination. Blue Spruce NUS Corp. International, 1980-1982, Table D-3. Region II Office N3DEP Sample Analyses, background well and Monitoring NUS Corp. Well #1, Brook Industrial Park, 1/5/82. Region II Office Van Houten, F.B., 1969, Late Triassic Newark Group, North NUS Corp. Central New Jersey and Adjacent Pennsylvania and New York; Region II Office from Geology of Selected Areas in New Jersey and Eastern Pennsylvania; Editor Seymour Subitzky, p. Sl'f. Kirkham, W.C. et al., 1976, Soil Survey of Somerset County, NUS Corp. New Jersey. United States Department of Agriculture Soil Region IlOffice Conservation Service, p. kd-kl, p. 102-105, Map 21. Memo to Kathy Van Hook from Gregory Cunningham, NJDEP, NUS Corp. June 12, 198^. Region II Office 8. Mitre Corporation; 198^^, Uncontrolled Hazardous Waste Site NUS Corp. Ranking System. A User's Manual. Region II Office 9, Kunze, Robert; Middle Brook Health Commission, Background NUS Corp. File, August k, 1980. Region II Office 10. Patterson, Donald; February 19, 1980, Complaint NUS Corp. Investigation, New Jersey Department of Environmental Region II Office Protection. 11. Moore, Doug; June 10, 1980, Spill File -Possible Pesticide NUS Corp. Spill at Tifa Company, New Jersey Department of Region II Office EnvironmentaJ Protection. 12. Faherty, Dennis; August 6, 1980, Spill File - Tifa (Blue Spruce) NUS Corp. Company, 100 West Main Street, Bound Brook, New Jersey Region II Office Department of Environmentcd Protection. NUS Corp. FIT Region II 100076 BIBLIOGRAPHY OF INFORMATION SOURCES (Cont'd) HRS MODEL SOURCE LOCATION 13. Faherty, Dennis; August 6, 1980, Spill File - Blue Spruce NUS Corp. Company, Bound Brook, New Jersey, New Jersey Department of Region II Office Environmental Protection. 1^. Al Maz, Elizabethtown Water Company, 1341 North Avenue, NUS Corp. Plainfield, NJ, (201) 756-4088. Region II Office 15. "Graphical Exposure Modeling System, United States NUS Corp. Environmental Protection Agency. Region II Office 16. Administrative Consent Order against Jame Fine Chemical NUS Corp. by New Jersey Department of Environmental Protection, Region II Office April 29, 1980. 17. United States Geological Survey, Bound Brook Quadrangle, 1977, NUS Corp. Topographic Map, 7.5 minute series. (Public supply wells Region II Office within a three mile radius are indicated.) 18. NUS Coporation, Field Log Book //1446 entry 20, June 1985. NUS Corp. Region II Office 19. Fire Protecton Guide on Hazardous Materials, 1978, editor NUS Corp. National Fire Protection Association, Quincy, Ma. Chapter 49, Region II Office p. 1-305 and Chapter 491M, p. 1-450. 20. August 1, 1980, Bound Brook Borough Municipal Court Affidavit. NUS Corp. Region II Office 21. February 13, 1981, Health Officer Correspondence, NUS Corp. Dr. Ronald Cohen. Region II Office NUS Corp. 22. Laboratory Results, General Testing Corporation, 2/17/82. Region II Office NUS Corp. 23. Laboratory Results, Rossnagel and Associates, 12/9/80. Region II Office NUS Corp. 24. U.S. Environmental Protection Agency, 7/18/80 Pollution Report. Region II Office NUS Corp. 25. U.S. Environmental Protection Agency, 8/12/83 Pollution Report. Region II Office 26. NJDEP - Analysis of Water Samples Taken from Monitoring Wells NUS Corp. and Well Logs at Brook Industrial Park. Region II Office 27. Middle-Brook Regional Health Commission, Well Survey, 1984. NUS Corp. ,,. Region irOffice , . NUS Corp. FIT Region II 11(0077 BIBLIOGRAPHY OF INFORMATION SOURCES (Cont'd) HRS MODEL SOURCE LOCATION 28. Administrative Order and Notice of Civil Administrative NUS Corp. Penalty Assessment in the matter of National Metal Region II Office Finishing Corporation and Brook Industrial Park, August 7, 1985, State of New Jersey Department of Environmentcd Protection. 29. Industrial User Pretreatment Base Line Report from NUS Corp. National Metal Finishings Corporation, Inc. to Region II Office U.S. EPA, October 6, 1980. 30. Letter from Ronald Cohen, Health Officer, Middle-Brook NUS Corp. Regional Health Commission, 8/2/84. Region II Office 31. Sax, Irving, Dangerous Properties of Industrial NUS Corp. Chemicals, 6th Edition, 1984. Region II Office 32. NUS Corporation Operating Guidelines Manual, NUS Corp. Section 5.5, Organic Vapor Analyzer Operations, Region II Office 1984. 33. Telecon beteen Bob Demoss of the Water Engineering Dept. NUS Corp. and the.office of Henry Patterson III, both of the Region II Office Elizabethtown Water Co., and Scott Engle of NUS Corp., 2/7/86. 34. Well Records, NJDEP, Division of Water Resources. NUS Corp. Region II Office 35. Telecon between Clerk in charge of building permits NUS Corp. Borough of Bound Brook and Scott Engle of NUS Corp., Region II Office 2/10/86. 36. Fish and Wildlife Service List of Endangered and NUS Corp. Threatened Wildlife and Plants, January 9, 1985, Region II Office Bureau of National Affairs, Inc. 37. Telecon: Doug Pozzie, EPA and Don Hessemer, NUS NUS Corp. 3/27/86, 1005. Region II Office NUS Corp. FIT Region II 100078 SECTION 7 PRESS RELEASE SUMMARY-MITRE HAZARD RANKING SYSTEM 100079 SUMMARY STATEMENT BROOK INDUSTRIAL PARK BOUND BROOK, NEW JERSEY The Brook Industrial Park is a 4.5 acre complex of light industries and warehouses situated on the north banks of the Raritan River in the Borough of Bound Brook, Somerset County, New Jersey. The industrial park is bordered to the north by the Central Railroad of New Jersey and to the south by the Lehigh Valley and Port Reading Railroads which are adjacent to-the Raritan River. Residential areas are located on the north side of the Central Railroad Tracks and west of the site. The facility has been in existance since the late 1800's. IndustriaL chemical and pesticide production, usage and storage operations began here in 1971 when Blue Spruce Chemical occupied some of the buildings on the site. The storage of Agent Orange on the site has also been documented. .Mr. Richard Schleck is currently the owner of -the property. Other occupants of the buildings at the Brook Industrial Park include; Consolidated Steel Fabricators (manufactuer of steel products), K. Jabat, Inc. (extruded plastic products), Jame Fine Chemicals, Inc. (specialty chemicals), National Metal Finishings Corporation (metal plating), and Sterling Center Corporation (pet supplies). These companies have operated at Brook Industrial Park for the past ten to twelve years. Several of these operations have been cited for inadequate housekeeping and waste disposal practice. Investigations by the Middlebrook Regional Health Commission and the New Jersey Department of Environmental Protection were initiated when workers within the buildings became ill. Testing by NJDEP and U.S. EPA has shown contamination of the buildings, soils and groundwater. Fines and indictments have been served to several of the operators for damages and lack of compliance with mandates for remedial action. The primary concern is for residents adjacent to the Brook Industrial Park, users of local water resources, and the workers of industries within Brook Industrial Park. Direct contact with waste could occur through groundwater use and through contact with site soils. : Other concerns exist including surface runoff of contaminated soils into the Raritan River and degradation of air quality due to airborne soils. Soil runoff and air quality degradation have not been fully evaluated to this date. 1000^0 SUMMARY STATEMENT (CONPD) BROOK INDUSTRIAL PARK BOUND BROOK, NEW JERSEY Some of the contaminated soil surfaces have been covered with an asphalt cap, and access to the industrial park is limited by a fence surrounding it. The Environmental Protection Agency has authorized a Remedial Investigation/Feasibility Study for the Blue Spruce International site. 100081 SECTIONS ATTACHMENTS- CITED DOCUMENTS 100082 REFERENCE #1 100083 Inl:| I •' llil !,lll I lilllnrilllCil Mill HI.IM MI:Ui:i IN 11 llMiM I IINr-.l , INI'. nr.v; l^lllll i.M'iiiiiin I.iirii:i:riri>rvi Iiiri:. <|.|Mh> (lllilli Nihil' '..'I I vi..y;, , IVIIO •Hill i'/i:i) I'/llO milniiHii mm 13 Ji/^ UJArtrjt Hoiirii III i>uH iMui, iunuiii III emu 1111-10 '..UUIII '.Mtil;lll III in iii;. :iii HI tiii i:iii III! i.i til,Ml ,1, -.i. • 0' ,i I il I III 0,6:':' ?.'»4;-i I I ..Su'^ I'l.ii/'.i ;|,iMiui-> |!|li: ('.It'll O..V,il ..17, (.n ' o.-r.n) O.tlillll 0 . 0(1 •l,lllllll,l lit IIII ll' : I.:' 1 !:i II , |> ' llllH ()..'i:;:. 0./','4 |.,|. ' luiii I .'.JO:' 1 .:.'ii o.ii:'0 1 .nil/. (,,,.' lull 0.1")7 O.l'V'.' :;.oii.s O.OIIJ .rJ. I-III ,.,! ' I'l'l 11.4.5:' 1 .iiJ >•. O.-Ji'i O.llo/. 7:..;..';;; iiii.-l.liii:;yi II 11, i 1 ti. V i:.' I iKi,.'/:.!;", K^ Mil II. nil I- rr I'll r I I'll (,i> iiii.i.i mir. ( ^^•K/M - -^^r 4/Krn^^t I Am I :• u i.ii I.'ll) UN Mil niKi|iiniN(M mil I'llll. Ml:lli:i IMII I'iHr'il IIINM , I Mn. Mr.).lllliii l;IIUI:illi l.lllil.L N I I:M I I liil'.i (|i|.iii) (I'liiiii Mill! I' :,iiivH)'i, I'^UO ,niil I'.'I; I ' IVill - ! mill lurii; mn iiiiiii iiiiiiiiiiii: r;iiii iiiiiiiiHiiuArt:i{ HAIil. •.'lllllll (II HIIIIIUMIi Ml ;'i III IIN lit II liiMii iiiiiiNr; Ill Nl in nil. i.imrnui Ul 11 i:> i:iii iiicrii iii'iiii .«' • I I ll t 11, 0.04 0 . O.' O.OOl'li Mdll HI ANK iii'l. ili'l.i'i I eil o o REFERENCE #2 1000% I i'llll I 0-2 lli( .'ilir (Jlidimi'Urtlfcll CIINIrtHJMrtriON WnSDS IIHI.IiAI. UlrtlJli/tliHS AMU llilliniA ii'.yiHiiH 1(11111:1111 ciiNCFNiKAininsdviio iyu:M HKlNKIHri UiMKII ii I ANHiSKH'i UATIH lllliM 1 lY l;HMri:l(N AND CKI ICIilA -11 : I :- •11 IhCINI Illli I Nil II IHFCIIHHI NH, I SIKiliKSII.H ! ui.i I;; HAKKriKIIIIHHI lAMi; I IMrtXUKIH ! HAXIHIIH 1 NO rtliVI IHJil: liHifl I 114 UFI I FINK I ICIINl/lMIN, ICIIinAHIN. ! Id si'iiii!;i ANH IIIIMAH I C.MIC.F I: t (i:- lo I 1) ( i;.0 I flTT)!'ll tVtl !i* t itvtis* ; 11: vi: I a*-' IIHIIK Tiixii;! IY" I ! I )ii'ii..*-tii.' -'(iOdi:!)'* 4:Mno) t ! Hi:,".';io/70 O . i.n II ***! I 1^ I IMMI .'I'ltl' i.'di:') ) 4 (113 ) I ! •".I'l |:.| !.»• I Ili-li-M III.' :',Mii:'> I * I li'i I > I I'l'ii.'i'iir- 4'/(II.') I t I .11 III .1, I I' 1.1 ,ii; ti I o I i ill' :'((i;f) I ,:!(iio) I I '00/•.'()/HI: 0,40 III I III iil'iMi. iMii' iiiyiii.') I ll 1111 I .I'll I III '.'I'dKM 100 0. 17 l.ll I II I nil,,.-1 ll .,111 • :MIK!) :' III 11,1 I.I 1.1,11 III' :i/.(ii:') I I« I III-1 III', I III 11.1-11 f- :".'(ii;') I ll I I.I III., II I r'l Kill') II.:'(110) 400 I, 'I ii 111,11.1 iiiii.ii.'i>i,i' 41', (111') /:iO 400 I,.' I' 11 ll I I'l I,.,111' /, di:') :'4. 4(110) 100 o 0,74 I I I , .' In I ll Im ml III- '.'imi.') I 4dlL'> '/'.'(i/:?/()/m: If'.' 11 11 11 11 > I I • I' I 111', 11,1' l/idlL') I I ll) I I'lii -I'lii ;i lodi:') 400 I I I'll I i-iii' I ilidIO) o,oo:iii iii'i ii> I i:ii 1.11 I ill- 1.1,000/1.100/1:101 I (IK') \ Hill ii|>lii-iii) I 4 4di:)) I I-1 I'll ll I III III' t lii'iif I (II.') li-'iOdlO) :'-ioo/i /•:,/:•{> 11 O , (10 I II I '11 III- I7(IK') :'i:iOo/;':!(»()/.54.< :! 7000 (IK') 14.100 1,1,1 I I 11 ll I III I'l'l.Ii,int.- /,. 4 (110 ) :'oo N(;/w(-/ioo« ;; J (1400 I I II ll 11)I 111- l.lii'iip I'll (II.') 141 dlO> 0 ;'ooo/:'0()//:i i! 11) r I 'Mil (ll 111 iii'iii' I VO(IK') 1 I I , :', 4 I (' I Mil.' I It y I liiMi.riMio 47(IK') I I I f .1, S I I J till-1 ll > I III-I I.'I'll I* 1/.(IK') I (l|..| i X ,• I I'll!' • .1140(ii;') ll.dIO) iMili ill 1 .(>:'( 110) 0.0000/4 IM )' I ll I III :'.4((io) I I 0,0000/1 riilin il'iiii- I . ,'(110) I t (>.0004(. 4,4' Hlil .1.1'. (110) o.ooi)(i:'4 4,4' HIM .1.^(110) 4,4' HHIi :'4.;.(iK') 'J'laiai'i Hill. (I. (iiil.iiii: > 1 .4;'(IK') I t o,|i ' -HHI o,;'(ii:') I 1 0.0111/, ii,|i ' Hin: I'./.:. (110) I • ll'il 'il.liioii I .(Kill ) I I /i 1 lull i 11 lilt. I A I dl 1 ) I I l', I'SI-II t c :'40(IK') :r7;'.(ii:') I: '.>() II'IIIHI i nil. IMd.l) 1( IK!) 10 10 I!ll I'l.HI illli IMKIKM 4I:J(H;') '.:.:'0 (110) so M) Cni'inM 16 (III > 1000 1000 I I'CIt .17'.' 0(111 > 300 I I'.til A40(tl'.!) 1041 (IK') f.6 (O'J) SO TiO lilM I 'I I y 0, Til 11:') 1 , I dIO) Nil Kr I :'oi (III') ';IO(O:M ly (111 > 0 . 14 4 I III -10 (HI ) 11,4 / 11.1 r'.'/i (111 > ;;ooo r.ooo TABLE 0-2 ON-SITE GROUNDWATER CONTAMINATION VERSUS FEDERAL STANDARDS AND CRITERIA NOTESi a- Water Quality Criieria-U.S. EnvironmenUl Protection Agency (1910), Federal Register 0} (321) b - Year o( Maximum Reported Concentration c - MCL-Maximum Contaminant Level. National primary Interim drinking water regulation. Code ol Federal Hegulationi (1911) Title 40, Part Ul d - RMCL-Recommended Maximum Contaminant LeveL U.S. Environmental Protection Agency (19t e - SNARLS-Suggested No Adverse Respoilse Levels. U.S. Environmental Protection Agency, Office of Drinking Water i - Based on I day/10 day/Cltronic exposures g - Human Toxiciiy-Based on ingestion of contaminated water and contaminated aquatic organlsmv h - Levels which may relgst in incremental increase ol cancer risk over the lifetime estimated at 10'^ bated on ingestion ol contaminated water and contaminated aquatic organisms I - NC-Not calculated o oo REFERENCE #3 loooas lAHU 0-a INHIIlIK AND OIIIHIIIIK SOU (IINI Ah (NAI IDN MAX 1 HUM ritl omen I.ONCI NlliAlinUlK 171)0 17li:') (ALl IJNlTti IN IJG/B) UUUiDIi Mill 0111 m 11)11 Hi'ii.-i'iie ! I l.ll I II I Illli.-lt.'OliC II '2.0(1101 1 1 1170 (IK') 1.4 1 I , .' Hi I It I III III'I.Ii'tne .'4.4(11(1) 11 0, ;i I (uo) 1 1 l.ll ll. • l.ll II I HI :!2dr.') I' Kli I (' I 111 (11 III'III' ili'lli I I III. ill I III nil.' .r.'di.'i 1.4 ,' I f- I I >ll ll I II I III' l.lll'IIH Ic'.OdlO) I40(IK^) 1.4 1 liil'i.',..- IV (IK') I 111'! I :: / \ i-iit". ISdlO) o.:'io(o.'.') I , L', \ I I tii.1-1 ll y I l.i-nr^iiK 11 I I ,:' H 11 ll I iii'(iliirii:'!,.')ie El.:' ((10) ^ i i 1.:./. (uo) t 1 .;i I , .1 |i i I ll 1 i>i'iil>i*ii.:i'iie 11 lli.'::'ii ll J III (ittii l.'til t eiu' II 5.7U(U0)I 1 1 t i 1 n Idi Ill 1 :.'. :io (111) 1 /.oy(0i) J : l3U./i3dlO) I 0 11'. 00 (IK') 3 ! :'o o il i 1' 1l l 1 III 1 .711(111 > 1 I ,70(111 ) i II 0,1 y (110); I ?,40(1IO) 3 1 10 0 1. • ll ril'iit,' 7.11(110) 0 .), 10(UI ) s ii S,.I;M 110)1 3,;i .'.6 , 00 ( HO ) 3 1 .10 o -i:. ') , 4' I'HI :'7.'dio) 0 ! 'JllOdlD J I ! II ,43(110) 1 9.S 7,07(UO) '* 1 a.' 0 •1 HHI ii:i7dio) 0 ! .i0.4(BI> s It O.fi/idlO) I I fi3. tO(UO) • 3* 1 :.o 0 ,4 HHH i;i7dif)) ! 40.t(lll> It 1,:J6(U0)! 7,5 1.117(110) 4 1 4 o '1 ll.l '1 1 iiilot. ill'III ! 6.'.'.'AIM ) I 0,1 •:, (a I) .1 ! I 0.6tO 100091 •7«Mie, Ave. * 5f(//M€.. 'i SK1^"" '^fl Jf^^ • '. ... ^^ •"•\ L'*'.' '-"N AmiSa::-:-- I llflll I—^vi*«^«^4 V7« . Ote«r((ntnt al tniiiontntmtt froiKiiort BACT. 'wAB NO. rUAStnTt OR MINT OlWKIon ol Wittr Rttoufcit Wmi BALLPOINT flti WATER ANALYSIS OATC RCC'O. UUhlCI»ALl£V OUNTV ^^ ^ _^^ STRtAM )§p..o,n f?/?n<.>A- r BOTTUC NO. MCli'l I V CBOmCJT 5 fen^^CNi'^.^ti^ ^ '''<• mrE '-'-" icoui-NAME -J ^-IL SNT. RtMAUKl fJL trORCT Rack'rrR,oorjn fn.iu. Cj^i^,rJi.-^At<^>y y,\: READ JilL. SXJ KTlO N lOtN-nKICATION NUMHER YR. .MO. DAY IIOUIl' t s c » t FIELD ANALYSIS ANALYSIS UNITS pARA.M^rrER \ /ALUE RNfK3. ••f aw«i««T.mo 'c PIC. 1 1. . SV^ <;/'Ati OCU PI 1 • T . O o.o.-winkKf not. 1 , • ^' ^_ L • - 1. Oo.O.-^roM n«i. ^Ai?orhJ^c \^Aeb(M>bct^ P • 1 _ • o'^ (fl«iai MOO, Prtj oniA^^^K^ " P •" ji Q J«i«ii* 0«e(n'ft. 0), a p 1 '' %• O a««« Hiignt-fl. n(, 1 ^ . - n$»«e. Cono. p^ a -'• •' • P a p QS4llnliy°/00 MIO. 1 D P GTId«SU«* F702U u a p BACTERIOLOGICAL • OILLTIO.NS (REOL'ESTED) -D- P PtMl COIKOfin •1 •J •3 .4 •5|-6 Ton* Call'orm 10 1 10 to to to tOl 10 D P^ f«»l • 1 • 3|^4 1-5 -a D P ttrtoiococel 10 1 10 10 to 1 I0| to TO • • P CJ MPN Fill IS. F.CJI«Otl CMf BlI. 1 j -•"'-> /lOO *i '—'*' nun. , G • • P • P 1 T-.-^--'' , •••; PI Ftcji S:r»»t ,»,.,, 1 • • P , • P « J /lOO mi 1 j, n p a p ^ UIOCIIOUCAL O.XVCE^ Ot,H.VNU a , p 1 se eo res C NoC a' p CONC.^ a . , p 1 • BOO a p ^ • p ,i I a 800 Gs-OA' ' PIK >• P1I 1 1 . • •• . p —_ ^»n\ CHAl.N OFCUSTOOr OATI TIME FAOM (NAME) _fc!l a^V ^ ft^^ CAamiit aa«uw Pjrx 1 • W«nr Qjsi.iv ln«n(arv Caoy ?««« 3 • W^itf fl«SOU(eti CaSylFo'Trsntmiiiior ^»'t 2 •C>.«mri(ry Coiiy Pjfx 4 • Sjtitriology Couy — —. — rvrvn UI3TT -y—eyv/^M'M • •»••- Pan tlWhiiel • Aaier Ou4liiv Invtntory Cooy Port JlPinxl • Wjiof Ht\ou(C*« CoOylPa' TrimmiitiOnl *v\ IUJi**"! • Chani.iiiy Couv Part •HY»llOv»l • Bjcieriolo^y Cooy » 100093 STATi Of NtA jCtiScY Dtparunint ot Environmantal ProlKtion OACT. LAO NO. ' PltASiTYreORfRINT Oiviilon of Wttf r nisourcvs %rttt BAlLfOINTPEN WATER ANALYSIS 0AT|1.0eCD. COUNTY ST A e AM , •_• I I ^A^eii?i'S BOTTLE NO. U5j^ /WM/V >7-H(5g7- Mag ^ . Z (jgpphtlft^o. »fPB«SeNTATlVl ^^ rrrw cOuu NAMC — • ••' ENT. mCMAH.li »TOHKT ^OhJiTC{:!n^'& toe-LL. ^ / BIZaO •' »''we 0 MS u JTATION IDENTIFICATION NU.MBER YR. MO. DAY iioun sc . X • ^•^'^^'/ "^^ /^^ • M 1 FIELD ANALYSIS ANALYSIS UNITS PARA.METER VALUE H.\tKS. Q W»ttr T«mo 'c PlO, -ff- I Q O.O.-WlnMltr PldO. g D O.O.-ProM nj». 0()iX fh'chlO'^f-iH'h^tiJi' DP^ (fl»ia) p • S«npl* Oapilt'lt pj. Q d««* H«t«nt-tt. P«S, P»5. D S4iiftiiy '/oo P4I0, a6 CTTo\^it>* a TIPI SUM ^oan. a c\ BACTERIOLOGICAL • DILLTICNS (REQLESTED) Ffcti Caii'O"^ •2 .3' •5 -6 ii Totll COH'OfTij 'OJt 10 10 10 10 10 s' Ftcai TTTT •4 1-5 1-6 Bm: ^\> ''I'Vi. StrcaiecMci 10 1 10| 10 lOl 10 TO 'W- I MPN PIKIi, til FfCSI toll /IflO ml IMF PJUll, i7 Ftcil SlrfSt ——i^ W • MPI N p:i»n. • p.(^icV^/o.^.^b(V.it».vi?. /IQQ mi . I I ,• k ik D Tot eon a MPN PJHOli /10« mi n a BIOCHK.Mir-\L0.\YGE.N UE.NU.NU INITIAL a Q IHB I JAVPUE a_ SEED y£S• NOD n CONC.% D a<30 __ |. Oi-OAv pjia G BOO Ct-OAY Pll ll D .J- CHAIN OF CUSTODY OATC TIME FAOM (NAME) EEEOai Minim .i«-UJ9e2- —M-trv^n-e.-„;„iom»n.i>^ «! n I I - ChsrDistrv Laboraior"' , C^tmiii ^ivK. Pirt I • Wjnr Uii»liiv li^vtntory Coov Pifi J • *vt(»r ffaio«ri;«i l^Oyi^O'' i'»'^"^'"" P»n2 •Ciem.ttfv Cooy Port 4 • 8»et»fidiocy Cooy 100094 REFERENCE #5 100035 w (fini £^i:•^r-r>^ t A'n,-, ^ I-.;•(.., ^-i (^ 'S'-y r.^ j i.-,(-^^ .-Lz ic-. _ tai4or FIELD TRIP NO. 4 LATE TRIASSIC NEWARK GROUP, NORTH CENTRAL NEW JERSEY AND ADJACENT PENNSYLVANIA AND NEW YORK F. B. VAN HOUTEN Department of Geological and Geophyaical Science*, PriTueton Univertity, Princeton, New Jeney 08540 GENERAL GEOLCXJY deposits of the Coastal Plain Province to the south east. LNTBODUCTION In addition to their general northwest dip Newark General statement. The Late Triassic Newark strata are locally warped into open anticlines and Group is preserved in a southwest-trending basin synclines (fig. 11) and are broken by many small that reaches from Rockland County, New York, to normal faults which complicate attempts to estimate northeast Lancaster County, eastern Pennsylvania. thickness of the formations. In the central part of This is the largest of six major (and several minor) the basin a few large faults with several thousand Triassic rift valleys in a sinuous belt more than feet of vertical displacement may be part of a trans- 1,000 miles long, from Nova Scotia to North Caro current system involving those of the northwest lina (and in subsurface as far south as Florida). border as well (Sanders, 1962, p. 40). This faulting The Newark Basin is the largest of three lobes has nearly doubled the width of the basin. (Newark, Gettysburg, Culpeper) connected by narrow corridors in a 300-mile arcuate tract from SEDIMENTARY ROCK UNITS AND TYPE .\REAS southeastern .New York to northeastern Virginia. Newark Group (System in early reports) —Red- It is about 140 miles long and a maximum of 32 field, 1856, p. 357; Newark, east-central New Jersey. miles wide along the Delaware River. Stockton Formation —Kiimmel, 1897, p. 35—40; The Newark Group consists of 16,000-20,000 feet vicinity of Stockton, west-central .New Jersey. (4,880-6,100m) of nonmanne sedimentary rocks Lockatong Formation —Kiimmel, 1897, p. 40-47; and associated intrusive and extrusive basic rocks along Lockatong Creek between St(x:kton and (fig. 1). Their strike generally parallels the trend Frenchtown, west-central New Jersey. of the basin and they dip 10-20°NW. Along the Brunswick Formation —Kiimmel, 1897, p. 47-35; northwestern margin these rocks are bounded by along Raritan River, vicinity of .New Brunswick, Precambrian and Paleozoic rocks of the Reading central New Jersey. Prong of the New England Upland (the Highlands). Hammer Creek Formation —Glaeser, 1963, p- Most of this boundary is a system of high-angle 184; along Hammer Creek in Richland Quadrangle. faults, but intermittendy the Triassic deposits over Pennsylvania. lap on rocks of the upland terrane. Within the basin The common succession of rocks in the NewarK .Newark strata lie on Paleozoic and subordinate Pre Group (fig. 1), as in most of the Triassic basins, con cambrian rocks of the Blue Ridge and Piedmont sists of a lower, l(x:ally conglomeraric arkose, the provinces (fig. 2). .\long the southeastern margin Stockton Formation, a ma.ximuni of 6,000 '^eet .Newark deposits overlap on Precambrian and (1,830m) thick, grading upward into a redd''h- Paleozoic rocks of the Piedmont Province, includ brown mudstone deposit, the Doinswick F.rmu ing soda-rich schist and gneiss. .Newark strata, in tion, estimated to be as much as 18,000 feet (4.^.-'Omi turn, are overlapped by Cretaceous and younger thick. .\s in other basins, this sequence is thickest 314 10001^ REFERENCE #6 100097 Klk^lTOvvN , UJC, «.-f d. Soil Svt^M.^ of Scv/w-rsft-]- (2au>i4y r >^^ / SOIL SURVEY 46 Rivers and their tributaries in mixed sedin Riverhead sandy loam. 3 ^° ;5„PS'is'in''u*r^ washed frorri upland soils and in the underlying (RhC).-This gently slopmg to strongly sloping son siltstone, or fine-grained sandstone. In a representative profile in an area of blue: ^tMwHthissoUinmap^^ ture, the surface layer is dark-brown silt loam of K,mewh.t P~r^y dra,n_ai ^^'^J^^X e sbpes are less inches thick. It is mottled in the lower 7 inc 5S??Xni anJ'^^S'wheTslopes are more than 15 subsoil is friable, mottled dark reddish-brown about 30 inches thick. The substratum, between 40 and 65 inches, is reddish-brown stratified I'.. '*'Se"'"organic-matter content is moderately high in the IP gravel. ,Jface l7yer. This layer is generally m good "Ith anij it In unlimed areas these soils are strongly aci wWfs up early in spring. It can be plowed an(^ cultivated strongly acid in the upper part and very strong !^after heavy rain, and it does not generally crust or medium acid in the substratum. Natursil fertilii Sd. Runoff is slow or medium, and the hazard of erosion The rooting zone is deep. Permeability is modt is slizht or moderate. , j- the availab e water capacity is high. The water This soil is suited to a wide variety of crops, including a depth of 1 foot to 3 feet late in winter anc com alfalfa, small grains, soybeans, vegetables, fruit, hay, spring, and it does not drop much in summer nature and other specialized crops. Contour cultivation, summer is extremely dry. Stream overflow ger minimum tillage, and cover crops are effective in curs several times every spring and after most a; maintaining the organic-matter content and good tilth and heavy rain in any season. controlling runoff and erosion. Capability unit Ille-oS; Most areas of Rowland soils have been clearec woodland suitability group Sol. ing. The native vegetation consists of forests of =. wood trees as ash, white and pin oaks, walnut, w • sycamore, maple, and, river birch. Because j Rowland Series damage these soils are not well suited to crops i The Rowland series consists of deep, moderately well are well suited to pasture. Com and soybeans ari j drained and somewhat poorly drained soils. These nearly some of the higher positions, but flood damagi j level soils are on flood plains of the rivers and major Sod production is a special use, but flood dama j streams. They are about 3 to 8 feet above normal stream every year. Flood control is impractical he\ level and are subject to frequent stream overflow (fig. 10). watershed is so extensive. These soils are used (j They formed along the Raritan, Lamingion, and Millstone for parks and are good sites for ground-water poj i Figure /O.-Rowiand soili planted to bariey.Cropt grown on these soU. are often damaged by nooding. 10009R SOMERSET COUNTY, NEW JERSEY 47 Representative profile of Rowland silt loam in In unlimed areas these soils are strongly acid to very Rranchburg Township; in bluegrass pasture along the strongly acid. Natural fertility is medium. The rooting Raritan River, one-eighth mile north of Lehigh Valley Rail- zone is deep. Permeability is moderately slow, and the oad and one-eighth mile east of County Road 567: available water capacity is high. All—0 to 3 inches, dark-brown (7.5YR 4/2) sill loam: moderate, Most areas of Royce soils have been cleared for farming fine, granular structure: friable; many Tine roots; very (fig. 11). The native vegetation consists of forests of such strongly acid; abrupt, smooth boundary. hardwood trees as white, red, and black oaks; ash; beech; A12—3 to 10 inches, dark-brown (7.5YR 4/2) silt loam; few. fine, faint, dark reddish-brown (SYR 3/4) mottles; moderate, maple; and hickory. Idle areas seed in rapiiily with coarse, granular structure; friable: many roou; very redcedar. The soils are well suited to all general crops, strongly acid: gradual, wavy boundary. including com, soybeans, small grains, and vegetables, B—10 to 40 inches, dark reddish-brown (5YR 3/4) silt loam; few. fruits, nursery, and other specialized crops. fine, faint, dark reddish-gray (SYR 4/2) mottles; weak, coarse, subangular blocky structure: friable; few roots; few. Representative profiles of Royce silt loam, 2 to 6 thin, discontinuous clay films on ped faces; common black percent slopes, in Franklin Township; south of Amwell stains on ped faces; very strongly acid; abrupt, wavy Road, 75 yards east of Grouser Road and 1 mile south of boundary, Middlebush: lie—40 to 65 inches, reddish-brown (5YR 4/3) stratified sand and gravel; single grained; Itxise; strongly acid. Ap—0 to 8 inches, dark reddish-brown (SYR 3/3) silt loam; weak, medium, granular structure: friable; many fine roots: The solum ranges from 28 to 40 inches in thickness. Depth to bed •' many, medium, tubular pores; 5 percent white quartzose rock ranges from 4 to 8 feet. Coarse fragments make up 0 to 10 pebbles: slightly acid: abrupt, smooth boundary. percent of the .\ and B horizons and 20 to 50 percent of the C ho Bit—8 to 12 inches, dark reddish-brown (2.5YR 3/4) silt loam; rizon. weak. fine, granular structure: friable, slightly sticky an(i The Al 1 horizon has a hue of 7.5YR or SYR. a value of 3 to 5. and slightly plastic; few fine roots: common, medium, tiibuiar a chroma of 2 to 4. The A12 horizon has a hue of 7.5YR or SYR. a pores: few. thin, discontinuous clay films in pores and on value of 4 or 3, and a chroma of 3 or 4. faces of peds: 5 percent white quartzose pebbles; slightly The B horizon has a hue of 7.5YR. SYR. or 2.SYR. Value and acid; gradual, wavy boundary. chroma are 3 or 4. Texture is silt loam or loam. B2U—12 to 20 inches, dark reddish-'brown (2.5YR 3/4) clay loam, The C horizon has a hue of SYR, 7.SYR. or 2.SYR; a value of 3 or reddish brovim (2.5YR S/4) dry; moderate, medium, suban 4; and a chroma of 3 or 4. This horizon, above a depth of 40 inches, gular blocky structure: friable, slightly sticky and slightiv is sandy loam to silt loam. Below a depth of 40 inches are gravelly, plastic; thin patchy clay films on faces of peds and in pores; cobbiy. and sandy strata. 10 percent white quartzose pebbles; strongly acid: clear. Rowland soils are on slight rises and natural levees on flood plains wavy boundary. near the streams. They are next to the dark-gray, poorly drained B22t—20 to' 30 inches, reddish-brown (2.5YR 4/4) clay loam: Bowmansville soils in slight depressions and old stream meanders. moderate, coarse, subangular blocky structure: friable; thin Rowland soils do not have the gray B horizon that is commonly in discontinuoua clay films on faces of peds: S percent white Bowmansville soils. quartzose pebbles and some shale fragments: strongjy acid: clear, wavy boundary. Rowland silt loam (Ro).—This soil is generally nearly 1IR3—30 to 48 inches, reddish-brown (2.5YR 4/4) and dusky-red level, but there are minor hummocky areas and slopes of (lOR 3/4) shaly loam; weak, coarse, subangular biockv more than 2 percent. The soil is on flood plains along structure; firm; thin patchy clay films on shale fragments major streams. and on faces of peds: 26 percent shale fragments; verv strongly acid: clear, wavy boundary. Included with this soil in mapping are areas of sandy IIR—48 inches, dusky-red (lOR 3/4) partly weathered relatively un loam, loam, and gravelly loam soils. Also included are disturbed shale. some areas of well-drained soils nearer the streams and at The .lolum ranges from 40 to 60 inches in thickness. Depth to bed slightly higher elevations and areas of Bowman.sville soils rock ranges from 3V, to 6 feet. Coarse fragments of rounded quartz in depressions. ose gravel make up S to 20 percent of the A horizon- and the upper The organic-matter content is medium to high. The sur part of the B horizon. Coarse fragments of mostly shale and siltstone chips make up 15 to 60 percent of the lower part of the B horizon face layer is generally easy to till. Runoff is slow, and the and the C horizon. hazard of erosion is slight. During flooding, however, The A horizon has a hue of SYR, a value of 3. and a chroma of -i rapidly flowing water gouges the soil in some places and or-}. deposits material in other places. In places surface or The B horizon ha.> The Royce series consists of deep, well-drained soils. and in slight depressions. These gently sloping soils are on high positions in the land Royce soils are deeper than Penh and Klinesville .soils. They are scape on undulating and rolling uplands. They formed in a redder than Readington and Lansdowne soils and dn not have the thin mantle of mixed marine sediment and in the under mottles that are commonly in those soils. lying material weathered from red shale, siltstone, or fine Royce silt loam, 2 to 6 percent slopes (RyBi.—This sandstone. gently sloping soil is on slight rises on the undulating In a representative profile in a cultivated area, the sur uplands. v- face layer is dark reddish-brown silt loam 8 inches thick. Included with this soil in mapping are small areas of The subsoil is about 40 inches thick. The upper 4 inches is nearly level soils, a few areas of moderately eroded soils, dark reddish-brown silt loam, the middle 18 inches is dark and a few areas where the surface layer is loam. In some reddish-brown and reddish-brown clay loam, and the included areas quartzose gravel makes up more than 15 lower 18 inches is reddish-brown and dusky-red shaiy percent of the surface layer. Also included are some small loam. Shale bedrock is at a depth of 48 inches. areas of Birdsboro and Lansdowne soils. 100099 NEW JERSEY - SHEET NUMBER 21 I Jen, in Soil series and Foundations for dwellings— njap symbols Septic-Unk Sewage lagoons Sanilarj- landfillsi absorption fields Ulth basements Without basements Severe: hazard of Udifluvents and Ochrepts: Severe: hazard of .Severe: hazard of Severe: hazard of Severe: hazard of ! frequent stream frequent stream frequent stream ! UD. frequent stream frequent stream overflow. overflow. overflow. overflow. overflow. ' Urban land: Urn. Too variable to rate. Waichung: Wc. Severe: seasonal Severe: se.isonal .Severe: seasonal Severe: sea.sonal Severe: season.al high water table high water iftble Iiigh water table high water table high water table at a depth of U lo at a depth ui U to dt a depth uf U tu at a depth of 0 to at a depth of 0 to 1 foot. 1 loot. 1 foot. ' I foot. 1 foot. ^\^lippany: WhA ...; Severe: seasonal Severe: aeasoniil .Severe: ^asunal Slight Severe: seasonal high water table high wnter tnbie high water table high water table St a depth of i .It a depth of I at 3 depth of i at a depth of i foot to U feet. foot to Ii feet: foot to Ii feet; foot to Ii feeil high frost-action slow permeability. potential. ' Onsite deep studies of the underlying strata, water table, and hazards of aquifer pollution need to be made for landfills deeper than 5 or Relief Sourland Movmtain. is in the southern part of the county near Neshanic. A pair of V-shaped steep ridges (Watchun'g Somerset County has nearly all o[ its acreage in the Mountains) extends from the vicinity of Watchung Piedmont Plateau. Only about 6 percent, or 11.800 acres, through Martinsville and Chimney Rock to Pluckemin. is in the Highlands. Elevation ranges from 10 feet along Blufflike escarpments are adjacent to some streams, such the RariianRiver near Somerset to 85" feet on a hill nonh as at Dock Watch Hollow and Millington Gorge. of Bemardsville. ^ The Highland area is made up of moderate slopes on the The Piedmont area in the county is made up of gently uplands that drop abrupdy to the bordering lowlands of undulating and moderately sloping upland plains and nar the Piedmont Plateau. Some streams and drainagewavs row flood plains along the major streams. A steep ridge. have cut deeply into the hills, making deep indentations. Time The length of time the parent material has been iii place and exposed to the active forces of climate and vegetation is reflected in the degree of horizon differentiation, al though this is influenced by other factors as well. .^ ma ture soil is one that has well-defined, genetically related horizons; an immature soil is one that shows little or no horizonation. In this county deep soils that have cieariy expressed horizons indicate that the soil material has been in the same place for thousands of years. Soil horizons have formed as a result of the movement of clays, organic matter, and bases from the A horizon into the B horizon. This movement was caused by the action of water over long periods. Immature soils on flood plains do not have such characteristic horizons. Processes of Horizon Differentiation Several processes are involved -in the formation of soil horizons in the soils of Somerset County. These include the accumuladon of organic matter, the leaching of soluble salts, the reduction and translocation of iron, the forma-_ Figure 12.—Traprock quarry in the Watchung .Mountains. The tion of soil structure, and some translocation and loss of basalt is crushed and used as road mantle, roofing granules. clay minerals, aluminum, silica, and iron. The processes and aggregate. are continually taking place and generally at the same lOOlOl SOMERSET COUNTS, .NEW JERSEY 105 soils used for community developmeni—Continued Local roads Lawns, landscaping, Picnic and Campsites for and streets and golf fairways .\thletic fields play areas trailers and Paths and trails tents Severe: hazard of fre Severe: hazard of Severe: hazard of Severe: hazard of Severe: hazard of Severe: hazard of quent stream overflow. frequent stream frequent stream frequent stream frequent stream frequent stream overflow. overflow. overflow. overflow. overflow. Severe: seasonal high Severe: seasonal Severe: seasonal Severe: seasonal Severe: seasonal Severe: seasonal water table at a depth high water table high water table hizn water table high water table high water uble of 0 to 1 foot. at a depth of U to at a depth of 0 to ai'a depth oi 0 to at a depth of 0 to at a depth of 0 lo 1 foot. 1 foot. 1 foot.' I foot. 1 foot. Severe: seasonal high Severe: seasonal Severe: seasonal Moderate; water Severe: water Moderate: water water table at a depth high wjiter table high water i.tble table above a table above a table above a of J foot to U feet. :n. a depth of V .11 a depth of V depth of 20 inchei depth of 20 inches depth of 20 inches foot to Ii feet. foot to U feet. for short periods for short periods for short periods during season of during season of during season of use. use. use. 6 feet. time throughout the profile. They are measured in thou is high and pore space is low. Genesis of fragipans is not sands of years. fully understood, but studies show that swelling and The accumulation of organic matter takes place with the shrinking take place in alternating wet and dry periods. decomposition of plant residue. This process darkens the This may account for the tight packing of soil panicles surface layer and helps form the Al horizon^ Organic mat and. also, the gross polygonal pattern of cracks in fragi ter, once it has been lost, takes a long time Co be replaced. pans. Clay, silica, and oxides of aluminum are the cement The surface layers of the soils in the county average about ing agents' that most commonly cause brittleness and hard 3.5 percent organic matter. ness. Mature soib in Somerset County have distinct subsoil horizons. It is believed that some of the lime and other soluble salts are leached before translocation of iron and Major Soil Horizons clay takes place. Many factors affect this leaching, such as The results of the soil-forming factors and processes can the kinds of salt originally present, the depth to which the be distinguished by the different layers, or soil horizons, soil solution percolates, and the texture of the soil profile. seen in a soil profile. The soil profile extends from the sur Most well drained ana" moderately well drained soils in face down to material that is little altered by the soil-form Some.'set County have yellowish-brown or reddish-brown ing processes. horizons in the subsoil. These colors result mainly from The .A horizon is the surface layer. The uppermost part, thin coatings of iron oxides on sand and silt grains, al which contains the largest accumulation of organic mat^e.^ though in some soils, such as those of the Lehigh series. is called the .Al horizon. Beneath the .Al horizon many the colors are inherited from the underlying bedrock. soils have a layer of maximum leaching, called the .A2 ho Weak to moderate development of subangular blocky rizon. The .A2 horizon of some soils in Somerset County structure has taken place, and the subsoil generally shows brownish colors as a result of the oxidation of iron. contains considerably more clay than the overlying .sur The B horizon lies beneath the .A horizon and is com face horizons. monly called the subsoil. It is the horizon of maximum ac The reduction and transfer of iron are associated mainly cumulation, or illuviation, of clay. iron, aluminum, or with the wetter, more poorly drained soils. This process is other compounds leached from the A horizon. In some called gleying. Poorly drained to very poorly drained soils, soils the B horizon is formed through alteration in place such as Croton, Cokesbury, and Watchung. have a subsoil rather than through illuviation. The alteration may he and underlying material that are grayish in color, indicat caused by oxidation and reduction of iron or by the ing the reduction and transfer of iron. Moderately well weathering of clay minerals. Generally the B horizon is drained co somewhat poorly drained soiis have yellowish- firmer than the .A horizon and has blocky or prismatic brown, reddish-brown, and gray mottles, which indicate structure. It is generally lighter in color than the .Ai ho the segregation of iron. rizon but darker than the C horizon'. Some immature soils .A fragipan developed in the subsoil of many moderately do not have a B horizon. well drained and somewhat poorly drained soils. This ho The C horizon is below the .A or B horizon. U consists oi rizon is very firm and brittle when moist and hard when material that has been little altered by the soil-forming dry. Soli particles are tightly packed, so that bulk density processes but has been modified by weathering. 100102 ' PRIME FARMLAND 1 i • NEW JERSEY IMPORTANT FARMLANDS INVENTORY Prime Farmlands AOELPHIA Fine sandy loam, 0-2% slopes Fine sandy loam, 0-31 slopes Fine sandy loam, 2-51 slopes Fine sandy loam, clayey substratum, 0-2% slopes Fine sandy loam, clayey substratum, 2-5X slopes Loam, 0-2% slopes Loam, 2-5% slopes AOELPHIA GLAUCONITIC VARIANT Fine sandy loam, 0-2% slopes Fine sandy loam, 2-5% slopes ANNANOALE Gravelly loam, 3-8% slopes Gravelly loam, 3-8% slopes eroded Annandale - Edneyville gravelly loam, 3-8% slopes ARENDTSVILLE Gravelly loam, 2-6% slopes ATHOL Gravelly loam, 2-6% slopes AURA Loamy sand, 0-2% slopes Loamy sand, 0-5% slopes Loamy sand, 2-5% slopes Sandy loam, 0-2% slopes Sandy loam, 0-5% slopes Sandy loam, 2-5% slopes Sandy loam, moderately firm, 2-5% slopes Gravelly sandy loam, 0-2% slopes- Gravelly sandy loam, 0-5% slopes Gravelly sandy loam, 2-5% slopes Loam, 0-2% slopes Loam, 2-5% slopes Aura - Downer loamy sand, 0-5% slopes Aura - Oowner sandy loam, 0-5% slopes . Aura - Sassafras, loamy sand, 0-5% slopes Aura - Sassafras, sandy loam, 0-5% slopes 8ARCLEY Fine sandy loam, loamy finesand, 0-2% (drained) 8ARTLEY Loam, 0-3% slopes Loam, 3-8% slopes 100103 PRIME FARMLAND 6 MARLTON Sandy loam, 0-2% slopes Sandy loam, 0-5% slopes Sandy loam, 2-5% slopes Fine sandy loam, 0-2% slopes Fine sandy loam, 2-5% slopes Soils, 2-5% slopes Soils, 2-5% slopes, eroded Loam, 2-5X slopes MATAPEAKE Loam, 0-2% slopes Loam, 2-5% slopes Silt loam, 0-2% slopes Silt loam, 2-5% slopes MATAWAN Loamy sand, 0-5% slopes Sandy loam, 0-2% slopes Sandy loam, 0-5% slopes Sandy loam, 2-5% slopes MATTAPEX Silt loam, 0-2% slopes Silt loam, 2-5% slopes Silt loam, clayey substratum, 0-2% slopes Silt loam, clayey substratum, 2-5% slopes Silt loam, glauconitic substratum, 0-2%.slopes Silt loam, glauconitic substratum, 2-5% slopes Mattapex i Bertie loam MECKESVILLE Gravelly 1 oam, 2!-6 % slopes MIDDLEBURY Loam MOUNT LUCAS Silt loam. 0-•2% slopes Silt loam. 0-•6% slopes Silt loam, 2-•5% slopes Silt loam. 2-•6% slopes NESHAMINY Gravelly loam, 2-6% slopes Silt loam, 0-6% slopes Silt loam, 2-6% slopes Gravelly silt loam, 3-8% slopes 100J04 REFERENCE #7 100105 \ NEW JERSEY STATE PEPARTMENT OF ENVtROWMEWTAL ^WQTgrjign irpau of BnrLrcnnental Etfaluatitp^^ >^n1 ^i^te A«qesaiEnt, HaiA ^, OmnlnyhMi^ Wcathera Reglai. Btforcanent DATE JUN 12 1984 DNR Wftsteaater Dlacharge. Jame Fine Qiemlcal. Inc.. Brook Industrial Paaic. Bound Broqlc, Soqerset Cbunty ttla mmnrwrrtri Is ccDcemlng your recent Inquiry regarding tbe fanser discbarge ^t JaoB Fine CbemLcal, Inc. in Bound Brook. Please be advised tbat on Harch 27^ 1960, Mr. Janes Grtsavage, Jr. of tbe Office of Ckooer and TtaBdc Substances Besearcb and I collected vestewater saoples Iron Jaoe Fine's discbarge. Tbe Chain of Qistody sheet used to relinqui^ tbe saiqples to tbe laboratory for analyses Is attacbed. lbs letters JF-1 under tbe coliim "Sairple Nuaber" on tbe Cbain of Custody Identif^s tbe saoples oollerted of Jane Fine's wastenater discbarge.; • I If you have any qpestioos ccctact me at 2-M38. I A20:gk Attacbment cc: Joseph 11. Uikulka, Chief, Nortbem Begioo Wllliatn Kransr, N.J. Geological Survey Eleoent M 1 1 1 1 . I ' 1 1 • \ '• • \ •1 • 1 i lOC^lOfi •mtmi CHAIK<^F CUSTODY RECORD M^^-K^j. i ^' \\ iNwiiOMikiMTAi Monniew AOINCT . UOMN M u tuivnuAMCf t ANMrsi iivisieN .' ~) lOltON. MIW Jitur %*%» ~ '' Ml*, •kttam—4 A4*«aa '- !•••*• 6 (i) nt&MOl. CAT i'jOJPC^ CAT2^j ^// ptJH CATr^0i6e,AJCATSj(^IJ^e/kc^r,jli)cJ^i, J. /A/-2 / OJ CAT J^^ 4/* ; (I) Pes CATZ J (^) finA CAr^^Y/| 6^^^^'^S'p) /M fiArj «/• */o J* J» Je • UCr/ Jo 4o J. J. 6 Jo 4. Uc-/ e/Q Jo of* Jo ^mimm AtwKg ls«f««iiMifv <•» S«*#A#i O.t. h •f^^? ••ta««i«fc«d tri t*es ta«»t* , taMa^aitfca^ Ifi tM»4«.4 If: (••• Oal. l.ai.a !.• Ckaa*. .1 C.d.^T (•lia^.Mi.4 ty: t.iti«a4 tip: r.aa 9a). I.ataa la« Ckaa«. a4 C«M.4f Mka^ar tat* Ma. • I 100107 REFERENCE #» 100108 /•?. TIFA COMPANY 100 West Main Street Bound Brock, N.J. 0 8805 August 4, 1980 - 7:00 PM Drums at TIFA Company were noted to be labeled as follows Lethane 3 84 Chlordane 7 2% DDVP - approximately ten 55-gallon full drums Aldrin - 5-gallon cans Tergitol - a wetting agent Atlox 3404F Chem-Germ Synthrin - EPA Number 279NY Arsenic Trioxide - four 400-pound containers Mentor Acetone Barbasco Methanol Extraction Lindane Triethanol Amine NOTE : Many drums were i-nmarked - Some were leaKing Third floor contained cases of new unmarked 1-gallon containers Robert Kunze Health Inspector 10O1O9 I August 4, 1980 •' " David Munn called our office giving us the following result: from samples taken at TIFA: Liquid coming from TIFA front entrance contained: 32 ppb Lindane 103 ppb Aldrin 54 ppb ODD 4 7 ppb DDT Liquid coming from the rear of the building contained: 208 ppb Lindane River Samples Contained: 1.7 3 ppb Lindane .35 ppb Aldrin Robert Kunze Health Inspector 100110 REFERENCE #10 loom y ^ i. '-OJ TO Feb. 19, 153- u J' -Id '':t:=fS3n 0. Eiiji Spr-uce Interrtiticr^al Coinpany SU3j£CT I "vO Valley P.odd S:iriin-r, 'IJ C79GQ CcrDlaint [nvest.iGaliion r. :r ;^ ::v,i3:i-a^icn: D=;. 2:^. 1379 f r" - 1:30-12:01 Dec. 31, 1979 frz'-x 1Q:C0 to 12:00 Pc.-sor'/s; Co-itact^d: Larry fiiizyka - N. J. Office of Hazardous Substance Control On 12-27-7.9 at approximately 9:30 a.m. this investigator and Larry Huzyka of tre Office cf Hazardous Substance Control arrived at 100 '•/. Main Street, 3ound Srco'y to coj'duct c joint inspection of the above naiTied firm at this location. The GPC ha; received ir-cr-aticn. frc.- Air Ppllucion Ccnt'-ol of possible pesticide storage— v'clat'c.-s at this site (3ee attached dated o-13-79'and 12-7-79). Because this irfor.~=ti jr: also cortairird -allegations of possible dischr::rcje into the environrrant _o • (•:--zardo'-;3 agents, Mr. iiuzyka acco:7.panied this investigator. .The firms building v,;3 1 coked and repeated ringing of an entry buzzer on the door produced no ansv/e"-. Tr^ ex':3rior of the prS'-'ise? was. inspected and no evidence of any discharges fro ths buiicirg was found. An employee in the building adjacent and attached tc the Bli.i-2 Soruce building (v,ro did not want to be identified) supplied the information th?.; a'lr'" heavy rains a noxious, odorous liquid v/as purrped out of the Blue Spruce bu::cirg on the ground behind the building. .The Raritan River is Icc.-ated v/ithin a;::ro.-.';r-ately 200 feet of the building and the terrain is flat or gently sloping tc./f.rd the T\--;'^r. This person took i!r. I'uzyka's card and said he "would call hi- t r.exi ti-? he siw th-is discharge. This person also stated that apparently empty pesticide ccntai."ers throuv/n cut onto tire ground adjacent to the rear of the b'j-;'': v,5:-e le't ",'.^r^ '.zr s.^ve'".!: -'.onths befc-re being put in a dj-npster and hau"!ed av.e.y. ."'jzyka called tm co~panies rain office in Stirling, ilJ fr'c:? a nearby ;:• 000tn. -fter a short conversation, Mr. iXuzykd alL'iged to thi: investigator th:it he cou' "ot reach; '\r. Livingston, owner of the firn, v.\-l that ?. cc.-pany secr-r^tar 'r.iz ti. ' •••r. Kuzyka's office phone riu'ce?-, said W-r. Livingston v;'X;ld call v.'-: h: --•."', up. ':':•-. "lijy'ia then ->r,-j'it ilin "':-=;-V i so/, Wc. Jo;;:! V.-'-^On, f^V" -."ce until see e'.MCr^nc;? o' ci•!=;•:'^T.zry^ v;as noted, at v;hirh tiri he v/O!. :o act. :nves:igac.-:r anu '. iluzyK.a rec:;rn::d to the site and ascertimsc;!\ ^ h - - :s 3tn i ;c:-::: .-::J :pp:ren::y •mncc-.pied.. It was noccd that the gr;-e outside the Hue Strutc; tuild-fn were in an unlockec, . r» i^-.. on 2-i-j f t> i \'\ 100112 S,;ruce I-.ternational Co, On 12/31.'79 this investigator r^'z\^r:\=': to the Blue Soruce building at 100 v:. I'ai-; St., Bound 3rook, Upon driving around to the rear c* the building where the pasticide containers were noted on the previous visit, this investigator observed two arpiOyees of Slue Spruce standing in an open double doorv;ay. These persons, [szo" observing this investigators arrival, imnediately shut and locked the doers. This investigator went to the front door and repeatedly r-anc the entry buzzer-, 'lo c-e ^r.'i-.iiraz tna door. Move'^ents of the persons inside tne building could be heard. ~i;-s investigator returned to the side of the buildinc \,'mr^ the pesticide container: we'"e to e.' 1. "Synthrin Concentrate 40" (EPA P.eg. Mo. 4316-372) Cans were stacked haphazardly, tops were open and cans were half-full of rainwater and/or Synthrin-water ni.xture (see photographs) Label statorents included: "CAUTIO:i" "KEEP CUT CF REACH CF CHILCREn" "This^product is toxic to fish and birds. Keep out of any body of water. Do not contaminate water by cleaning of equipment, or'disposal of wa3tes'^ "Return to drum reconditioner or destroy by perforating or crushing and burying in a safe place av;_ay fro^ a water source." 2. "Kocide ICI" (EPA Reg. Ho. 3901-1) E~pty bags with substantial powder residue v/ere wrapped in a plastic sheet open on the top and side. Label state-ents included: 'XAUTIOM: KEEP OUT OF REACH OF CHILDREii" "Do not conta.^inate water by cleaning of equipment or by disposal of wastes" "Do not reuse container. Destroy when empty" 3. "Aqi.:a-xl==n" _ (EPA Reg. Mo. 25^-103) Empty plastic bags were stuffed into uncovered, upright 55 gallon drum. Label state.ments included: "Do not reuse empty bag. Destroy by burying in a safe place." "CA!JT:0:I: Kseo out of reach of children" "Tyfanon Malathion" (EPA Reg. rio. not legible) Open, joright, er.oty 55 gallon drur- with other ("Acua-Kleen") e-'pty pestis-id- S • ,j: - - - • f - •a - [ •; ' * •' "' " . ' 1 b e 1 ? t;; r ~. - 3,- '- - \'^n^ {< -'-i^'. • ".•'.G~:CE - Oru.-:3 3'"Cu':d never be r-euse'J. Empty G.-U':S i;houid bo decomtamin.-^.te- by •..•:G"ing witn rot-5- cr-ustic soda soliition. Ti^ey should then be perfni-.--i-.-- - -, .n-1 .-> re •itC.I or c.n Uoor •j-ninq "o t'-^ O.^C this investin?.tor revir-jv/^d the Glue Spruce file .'3.tti£.'i2t .'Notice cf Prosecutir.n dated P./. 100113 1^ - International Co. a^ Slue Jr p^5^" Conclusions Blue Spruce International Company at 100 W. '''ain Street, Bound Brook was discarding pesticide containers in a manner inconsistent v/ith the pesticide products Federal registered .labels. The disposal area was an unlocked, untended area accessible to anyone, approximately 200 feet from the Raritan River, in particular, the following products with applicable label sta.e.'nents were noted: a. "Synthrin Concentrate 40" (EPA, Reg. Tio.' 4315-372) "Ciuticn-" "Keep out of reach of chi". iren" "Ratu-n to drum /•acc.:-ditioner or aestroy ty perforating or crusnmg and burying in a safe place away from a water source." b. "Kocide 101" (ERA Reg. No. 8901-1) "Caution: Keep out of reach of children" c. ".Aqua-Klaen" (EPA Reg. No. 264-109) "Do not reuse empty bag. Destroy by burying in a safe place. "Caution: ' Keep out of reach of children". ' ^ d. "Tyfanon Malathion"- (ERA Reg. Mo. not legible) • "Caution: Keep out of reach of children." "Motice - Durms shoyld never be reused. Empty drums should be deccmtaminated by washing with hot 5'; caustic scda solution. They should then be perforated to prevent further use and discarded in a safe place." The containers of the above named pesticides appeared to be unrinsed and substantial residues were present. Cn :2/'3'./79 at approximately 10 a.m. er.-ployees of Blue Spruce '"" = --aticna"! Company denied this investigator access to the firms pesticide storage area Blue Spruce International Comoany has an unsatisfied Jlotice of Prosecution dated 3/25/77 for violation of fl.J.A.C. 7:30-1.10(b) and 'I.J.A.:. 7:30-1.lOf. Recc" 'dati ens 1. Sen-. .rzir tor v .0 laficn c I. u . .-V. C. /; j ^- - I . 10 '^ c / . 2. "z:-: ,:• thi Of'it; ;tv:-nry C-::^:':! 'or ;.^---.5:-:;.;tiC''; for fail:;r^ -.z I,''..- . - : z -.virrant tc searcn tne prem-ises at luO '.'.. ;!din Street, Etun'J 3?.c?'.', to which was denied this investigitor in violation of N.J.S.A. 13:r-i i> (ry-.J^l r-\J\hj'^-C-r- » Do.".":'z '^ z'^'^i'- :.vj 1001}4 II. .s.::?,-: o:: VISITS TO ?L/U:T: i/ Februery 17, IS67 - Preliminary visit and discussion. Uculd llV.e a letter frou D-.-. PluEoar, detailing project goals, etc., v.-hich he ulll hava to subalt to Iiain Office for approval of participation in pro^ran. ?ebruar>' 25, 196/ - Further discussions and so::ie aore infomacion, but again, no tour of planu. f/^y,^7. Jrv/,'c ....V ..„' ,y..^'V../ '.-.^..'..v -.<• .^S^.J^.^ /i' /J J TZ<'. , /-^r- , •»-^> /'^'''^'^ '*' ^' ^ ^'^ ^''"'' ' ^^'^^'•'^r'^- 100115 REFERENCE #TI 100116 -«^--j^ NEW JERSEY STATE DEPARTMENT OF fc.> /^ONNENTML PRtJTSCTiqix WUMv o J -^rb { - o ;^ TO SUBJECT Poaeible Peaticide Spill at TlFa Company OHSC ^80-3-28-2 Friday, March 28, 1980 1100 Received from Tom Allen an assignment to investigate a possible pesticide spill at TiFa Company, 100 West Main Street, Bound Brook. 1430 Arrived on site. Spoke to Mr. Richard Kiley and Mr. Bernard Kiley from K. Jabat Company adjacent to TiFa. They informed me that TiFa Company blends pesticides and ships them to the main plant in Millington. After inspecting the area around the plant, two samples were collected. Sample //C1A026 was taken from the water runoff and sample #014027 was a soil ^^ ^ sample taken from the run off area. Several empty pesticide containers m£ f*<^ »n"*'^^^ o< TlFa Company bearing various labels such as: Rotenone, Zineb, Pyrenone, and Sythrin. 1530 Secured from site. 1600 Arrived at Division of Fish & Game Fisheries Lab, Lebanon. Tom LaFisca, Chemist, agreed to store the samples until they are needed. Wednesday. April 9, 1980 1115 Picked up pesticide samples at Fisheries Lab. 1330 Arrived at TiFa Company. Inspection of site showed no change in situation. Runoff is still continuing to flow from inside the storage area. A one liter sample (C14028) Cwater sample)was collected. Thursday, April 10, 1980 Delivered pesticide samples to Health Department for analysis. Monday, June 9. 1980 As of this date results have not been returned. DM:lc 10 100118 OM.012 mmmAM0^ -^ -IERSEY JTTATE OEPARTMENT OP EN . ...JNMENTAL PROTgCTIO K TO Spill File F ROM Dennis Faherty DATE August 6. 1980 SUBJECT Tifa (Blue Spruce) Company, 100 West Main Street, Bound Brook ^c-~7~ hc-(n July 31, 1980 1240 Arrived at Bound Brook Health Department for a scheduled meeting.prior to a joint inspection of the Tifa facility. Met with the following people: Robert Kunze - Bound Brook Health Department Sue Sergay - Bound Brook Health Department Joseph Vittelaro - Pesticide, D.E.P. Dave Munn - Pesticide Control, D.E.P. Mr. Kunze showed us a sample of a fed-pink liquid taken the day before from a puddle alongside drums in the alley between the buildings. He also had photographs of these drums,''^;' I 1300 We arrived at the Tifa Company, 100 West Main Street, Bound Brook. A large red-pink stain (similar to the sample at the Health Department) was observed .. and photographed in the gravel parking lot. Mr. Kunze noted that the sta!in«tf ; covered a larger area than the day before, and that four (4) of the drums in the alley were missing. The red-pink stain appears to be a runn-off problem, and eventually can be traced off the fenced property toward a intermlttenC feeder stream. The feeder stream is a tributary to the Raritan River. The employees at the adjacent companies have been complaining of nauseous odors coming from the Tifa company building. Ms. Sergay took a survey of the employees that were complaining of the odors. Mr. Vittelaro, Mr. Munn and I, equipped with respirators, inspected the exterior property of the Tifa facility. There were large red-pink stains in the a4ley near the remaining drums and along the building. Photographs were taken. We looked inside the building and observed 55 gallon drums being stored, marked "DVPP". Puddles of a red unknown liquid were observed on the floor alongside the stored drums. In the back of the building, we observed a black sludge. Samples were taken. An employee of one of the adjacent buildings informed the Health Department officials that he had observed bags marked "arsenic" being stored in the basement. The industrial complex in which the Tifa Company is housed, has a flooding problem after every rain. Again, there is threat of pesticide tainted run-off water getting into the Raritan River everytime there is a heavy rain.- A sample of a puddle of rain water was taken alongside the back door. A water sample was also taken at the intermittent feeder stream. We secured. Recommendation: The analysis of the samples must indicate that the material being washed off the Tifa Company property by rain is listed by O.H.S.C. as a hazardous substance.4fter this has been established, an in-plant inspection should be made to evaluate the flooding problem and correct the storage proceedures. Finally, a Notice of Violation should be levied against the Tifa Company for 1) discharging a hazardous substance into the waters of the State and 2) failing to notify the D.E.P. of such a discharge. DF:efw 100119 REFERENCE #13 lOOlSA OrA-a 12 •^i- FROM Dennis Faherty DATE August' 6, 1980 SUBJECT Tifa (Blue Spruce) Company, 100 West Main Street, Bound Brook *;^^^-~7- 50-63 July 31, 1980 1240 Arrived at Bound Brook Health Department for a scheduled meeting prior to a joint inspection of the Tifa facility. Met with the following people: Robert Kunze - Bound Srook Health Department Sue Sergay - Bound Brook Health Department Joseph Vittelaro - Pesticide, D.E.P. Dave Munn - Pesticide Control, D.E.P. Mr. Kunze showed us a sample of a red-pink liquid taken the day before from a puddle alongside drums in the alley between the buildings. He also had photographs of these drums .'^^V 1300 We arrived at the Tifa Company, 100 West Main Street, Bound Brook. A large red-pink stain (similar to the sample at the Health Department) was observed and photographed in the gravel parking lot. Mr. Kunze noted that the stainrf covered a larger area than the day before, and that four (4) of the drums in v\ the alley were missing. The red-pink stain appears to be a runa-off problem, and eventually can be traced off the fenced property toward a intermittent feeder stream- The feeder stream is a tributary to the Raritan River. The employees at the adjacent companies have been complaining Of nauseous odors coming from' the Tifa company building. Ms. Sergay took a survey of the employees that were complaining of the odors. Mr. Vittelaro, Mr. Munn and I, equipped with respirators, inspected the exterior property of the Tifa facility. There were large red-pink stains in the a-^ley near the remaining drums and along the building. Photographs were taken. We looked inside the building and observed 55 gallon drums being stored, marked "DVPP". Puddles of a red unknown liquid were observed on the floor alongside the stored drums. In the back of the building, we observed a black sludge. Samples were taken. An employee of one of the adjacent buildings informed the Health Department officials that he had observed bags marked "arsenic" being stored in the basement. The industrial complex in which the Tifa'Company is housed, has a flooding problem after every rain. Again, there is threat of pesticide tainted run-off water getti-'^ i-co the Raritan River everytime there is a heav;/ rain.- -•^ sample of a puddle of rain vatar was taken alongside the back door. .A. water sample was also taken at the intertiittent feeder stream. We secured. Recommendation: Tne analysis of the sar.ples must indicate that the material being '-ashed off the Tifa Ccr.pany property fay rain is listed fay O.H.S.C. as a hazaracus substance-4f"er this has been established, an in-?Iant inspection should be .-hade to evaluate the flooding problem and correct the storage proceedures. Finally, a Notice -of Violation should be levied against the Tifa Company for 1) dischargir x# a nazarccus jufastance ir.to '.e waters 0 f the State and 2) failing to notify the D.Z.?. c: such a dischc 100121 '\J MJ J - ' I ° ' Oz-C/vr/? ^.i - J'j^ / - c 3 .- BLUE SPRUCE Sampling History C14026 Sample of water runoff from area behind the Bound Brook plant- Collected 3-28-80 by D. Moore, OHSC (memo 6-10-80). Analysis: "— p,p-DDT 8. 0 ppb S> 0 V \' t •\ p,p-DDD 3 1 ppb 0,p-DDT ' 3 0 ppb p,p-DDE 0 a ppb malathion 22 3 ppb C14027 Soil sample from area covered by water running off from wall in back of Blue Spruce building. Collected 3-28-80 by D. Moore, OHSC (memo 6-10-80)^ Analysis: p,p-DDT 415 pob o,o-DDT 165 pob p,p-DDD 125 ppb C14028 Samole of water runoff from back of Blue Spruce building. Collected 4-9-80 by D. Moore, OHSC (memo 6-10-80). Analysis: malathion 0.5 Dob C14626 Water sample taken from purplish puddle at site of spill - barrels with cutoff tops, possibly used in mining and then washed. Collected 7-30-BO by Susan Sergey of Middle Brook Regional Heait.h Commission. Analysis: lindane 32.58 opb aldrin 103.30 pDb DDD 53.71 ppb DDT 47.00 ppb CL4627 Water sample from same location as Cl-1626, :l-0 S. Sergey, same date. Analysis: lindane 53.36 ppb aldrin 85.11 ppb C14G29 t7ater same' from runoff flowinn out of ti.^j bi: of Blue Spruce buiKli-nq. Collected 7-31-30 by Vitellaro and Munn, BPC (memo 3-1 -FiO: Ari.il y; lindane 20a.5L ppb aldrin ND JP«t22 -2- C14629 Water samole from Raritan River downstream of entrance point of runoff from Blue Spruce. Collected 7-31-80 by Vitellaro and Munn, BPC. Analysis: lindane 1.73 opb aldrin 0.35 ppb C14630 Soil sample taken near rear cellar door of Blue Spruce. Collected 7-31-80 by Vitellaro and Munn, BPC. Analysis: lindane .04% = 400 ppm aldrin ND arsenic 6116.28 mg/kg = 6116.28 ppm C05576 Water sample taken from flooded cellar at Blue Spruce. Collected 8-8-80 by D. Munn, BPC (memo 8-14-80). Analysis: lindane , 384.29 ppb aldrin 0.32 ppb p,p DDT ' 1.23 ppb o,D DDT 0.33 ppb p,p DDE 0.21 ppb p,0 DDD 1.00 opb C05577 Soil sample taken near drums located in alley in front of Blue Spruce; drums labeled "Chem-Sect Aldrin Rice Seed Treater." Collected 8-8-80 by D, Munn. Analysis: ald'-i.n 3.7% C05578 Swab sample taken from back of a pickup truck carrying the rice seed treater drums. Collected 8-8-30 by D. Munn. Tested "positive" for lindarie CQ5582 Water samole from (r'jnoff stream) Raritan River, upstream from Blue Spruce. Analysis: aldrin ND lindane ND C05584 Water samole from feeder stream Lo Rarit.;ri Kl • downstream .f'rom observed entry point u f i u; Blue Spruce. Same location as (:l4i)J9. I'v.' 8-15-30 by D. Mun.n, BPC. Analv::ii;: aldrin 13 Dpb lindane 03 upb -3- C05583 Water sample from Raritan River feeder stream at observed point of entry of Blue Spruce runoff. Collected 8-15-80 by D. Munn. Analysis: aldrin .21 ppb lindane .20 ppb C4065a Soil sample taken from northwest corner of Blue Spruce basement. Collected by G. Allen, OHSC, 8-26-80. Analysis: chlordane 377,027 ppb (377 ppm) p,p'-CDT 2,000 ppb ( 2 ppn) p,p'-DDE ( 10. a" ppm) p,p'-DDD 10,837 pob (138.9 ppm) 138,894 ppb C40655 Soil sample from southeast corner of Blue Sprue; basement. G. Allen^8-26-80. Analysis: chlordane 3,607 ppb 3.6 pom) p,p'-DDT 8,264 ppb 8.3 ppm) p,p '.-DDE 194 ppb .2 ppm) p,p'-DDD 7,193 ppb [ 7.2 ppm) o,p -DDT 283 ppb [ .3 ppm) C4Q656 Soil sampie from middle of Blue Spruce basement. G. Allen, BzZ^-M.^ Analysis: chlordane 957,770 ppb (959 8 ppm) p,D'-DDT 292,067 ppb (292 .0 i'pm) D,p'-DDE 8,394 ppb ( 8. 4 pun) p,p'-DDD 44,077 ppb ( 44 .1 pp.../ 0,p -DDT 49,900 ppb ( 49 .9 ppm) C40657 Soil samole from southwest corner of Blue Spruct: basement. G. Allen, 8-26-80. Analysis: chlordane 4,041 ppb 4 .0 rioni) D.p'-DDT 3,5 79 ppb 3 . i) r.c,iii) p,p'-DDE 186.5 ppb .2 n;-jm) D,p'-DDD 4,669 ppb 4 . 7 Ojjia) o,p•- DDT 317.3 pub .3 cor.\) C4 0 659 Soil sample from northcant corner o[ blue Sfiract-.- basement. G. Allen, 3-2o-'dO. Analysis: chlordano 1,313 pph ( 1.3 opi.,^ p,p' -urn' , 426 ppD ( .4 pun) p,p'-DDD 1,254 ppb ( 1.2 !j;)m) min REFERENCE #14 180195 y^SA I Ajor-H^ /^ut. ^ r / <:^,^'/^^l 1 . /UJ (z^ I) -7 ST, - c/^ef? I Dr^J-L^r, ^ f- uJfiJJs ujf4-fi>^. c^ 3 r^J-e. r -f ^/0>^A AcLi>-r-7V/iL-/ PcLr~k'C - HOUr.-h:L^y^ SJ-2rJz^:r>yj LJ^JpJs ^ i^/'^/V Lr.^^ -^ ^ut^ r %\- %• ^f J.2" •? 4^ " cie,&p c^5^V -A t^.A.' ^ f^Z /^'' ^03 ' de.&to (Lcscd V& 4^/ C^^eic^ t^n>ol< /Co^g/ ^ 7 /D '' 2^S' cle^i^ . (fa^d -^ 2.2 ' o (^ " ^iO ' (L^j^^ C^^^J -A £7 ^ 0 d x^ <;g5rt (A^^^n-^'tv^'Ex^. ;ji•r|/^^c.<^ rjgju^^ lorrrjce. \'N \A W(?X.\ ^urwi^Kch^^QCx^'K^ear^ '-.' REFERENCE #15 106197 Z II D D ti D D •.- D Dli D D B Li I' D D D £i D i: D i) f i V: Ii j.i n Ii D I' 0 )J U i.i 'J)? • D D1' D).! D I> ij i.i Ii i.i !• Ii i; ,.i li !• u D I' Li Ii J10 Is I: j: ii r:: i M r: I:;;; r,": i; •, n r^ -!•• 3Enter the location identifier.; lat/lonS ^ 3Enter the latitude in de<5reeSf minuteiir and second-;; N 40 33 30 . 3 ) -^ 3 3Enter the longitude in decrees? ;iiinutes. and seconds i W 74 32 2? - 3£nter the rin^ distance in (Km): .40 3 . -.J .•"•Entf?r the next* rin^ distance in \'KiTi)i^ .31 - -' . • 3 3Eiiter the next rin^ distance in (Km), 1.6 3 ^ ' . -. 3Enter the next rin^iJ distance in (Km)! 3*2 - ..3 3 3Enter the ne.xt rin<3 distance in IKITI>J 4,B 3 .J ' .. _ 3 3£nter the next ring distance in (Km); 6.4 3 • ^ 3Enter the next ring distance in (Kiii)» 3 • M ri ii M M H M H M ii M M M H fi fi M ii M iM M H H M n M M n ft fi M M M ri ii M ii ii fi M ii H ii H ?i M ii M ri ii ii ii M M li^i i*i M M ii ii ii M M M M M ii ii ii ii iM M ii ii ft IN ;: ':.4-0ct-S5 03;: 43 nH ' DnL.ine Cap COMM 3 D D D D D B D Tj D D D H D D D D D .0.0 D D D .0 D D D D D D D D D D D D n D D D D D D Ei D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D D ? oEnter GO to be<3in processin-:^: GO 3 3 Da t a set n a me i B3PR Length: 6 ..j Ho* of variables I 4 3 3 * 1 POP lOLISE ? .D-ISTANCE ; SECTOR 11 0 0 0.40000001 1 n j 3S?9 1473 0.81000000 1 O r 7442 2322 1,6000000 1 4 1 11294 3665 3.2000000 1 '" > 2i?52 774? 4.3000002 1 / 1 31003 10673 6.4000001 1 .3 (End of data for these variables.) ..' 3Pres5 !-:l.~TURM to continue» type Pnnn to position record 3or type Ei'JD to exit data window^ [• ii M M M H !i M ii ii M M ii ii H ii i*i ii M M M ii ii M fi ii ii ii ii H ii M H ii ii H M ii ii ii (i ii ii ii M M ii M ii ii ii M H ii M ii ii ii ii M M M ii ii H ii ii ii ii M ii ii ii ii ii ii n I i .:. 4-Oct-Hi^ est 45 AM GnLine Cap (^lu^vliccJ e>pD^uire MoJJi^ 'Syc-Lr^^ lAn'i-ko ^-^-^'-^ Wo\^^m 4- ' leetss REFERENCE #16 lOOtSfl g>tcitr flf HPUI 3prHPg DEPARTMENT OF ENVIRONMENTAL PROTECTION DIVISION OF WATER RESOURCES TRENTON. NEW JERSEY 08625 APR 2 9 1980 CERTIFIED MAIL I:. RETURN RECEIPT REQUESTED Mr. James R. Schleck Registered Agent Jame Fine Chemicals, Incorporated 100 W. Main Street Bound Brook, New Jersey 088 05 Re: Unpermitted Wastewater Discharge, Jame Fine Chemicals, Inc. Bound Brook Borough Dear Sir: There is enclosed for service upon you an ADMINISTRATIVE ORDER and NOTICE OF CIVIL ADMINISTRATIVE PENALTY ASSESSfffiNT issued by this Department pursuant to the provisions of N.J.S.A. 58:10A-l(b) and N.J.S.A. 58:lOA-10(d). If you have any questions concerning this ORDER and NOTICE, please feel free to contact Mr. Joseph Mikulka, Manager, Region IV, Western Bureau of Compliance, Enforcement Element, at the address above or by telephoning (609) 292- 0576. Very truly yours, ORIGINAL SfGNED BY A'^'::;.."" ~ • -•••• '^lorr-Top Arhord'--Scrhiffman--- '^ Director Enclosure I00I9 IN THE MATTER OF : ADMINISTRATIVE ORDER AND !^ JAflE FINE CHEMICALS, INC. : NOTICE OF CIVIL ADMINISTRATIVE ,r. PENALTY ASSESSMENT *^ The following FINDINGS are made, and ORDER and NOTICE issued pursuant to the authority vested in the Commissioner of the ;• New Jersey Department of Environmental Protection (NJDEP) i and duly delegated to the Director of the Division of Water Resources by N.J.S.A 13:1D-1 et. seq.; N.J.S.A. .13:lB-5; and the New Jersey Water Pollution Control Act, ^ N.J.S.A. 58:10A-1 et. seq. (hereinafter ."The Act"). i FINDINGS OF FACT 1. On February 19, 1980 a representative of the NJDEP inspected the Jame Fine Chemical, Incorporated (hereinafter [' "Jame Fine") facilities located on W. Main Street in the !, Borough of Bound Brook, County of Somerset, State of New Jersey, and observed an unpermitted discharge of contaminated 1^ wastev/ater into the Raritan River. Analyses of a discharge sample collected during said inspection revealed significant " concentrations of trichloroethane (2,400 ppb), tetrachlor- oethlyene (6,300 ppb), trichloroethlylene (80 ppb), toluene (175 ppb), ethyl benzene (65 ppb), m,p-xylene (200 ppb), O-xylene (65 ppb) and chemical oxygen demand (480 ppm). Jame Fine was informed by the NJDEP representative during the ) inspection that said unpermitted discharge of pollutants must be eliminated. 2. During that same February 19, 1980 investigation, the NJDEP representative observed spillage and poor housekeeping practices at Jame Fine, which have potential to cause contam ination of the Raritan River and area groundwaters. Analyses of a sample of ponded surface water, which was contaminated by the above spillages and poor housekeeping practices, and which was collected during said inspection, revealed significant concentrations of methylene chloride (14,640 ppb), chloroform. 1001 fit (10,000 ppb), trichloroethylene (40,000 ppb), cumene, (450 ppb), toluene (82 ppb), ethylbezene (546 ppb), m,p-xylene (786 ppb) and o-xylene (460 ppb) and chemical oxygen demand (9,517 ppm). Jame Fine was informed by the NJDEP representa tive during said inspection that said spillages must be . . cleaned up and that adequate and responsible housekeeping procedures would have to be implemented. 3. These discharges are not sanctioned under permits issued by NJDEP or by the United States Environmental Pro tection Agency (USEPA). 4. Discharging pollutants without a permit into waters of the State, or on to land from which they might flow or drain into surface waters or groundwaters of the State, is a violation of N.J.S.A. 58:10A-1 et seq. ORDER NOW-TKEREFOPvE IT IS ORDERED THAT: 5. Jame Fine shall immediately cease all its discharges of wastev;aters and pollutional materials into ground and surface v;aters of this State, including discharges due to spillages and poor housekeeping, upon receipt of this Order. All such discharges shall be disposed of in a manner acceptable to NJDEP. 6. Jame Fine shall submit a specific engineering proposal, including an implementation schedule with specific target dates, for a permanent system of treatment and/or disposal of its wastewaters and pollutional materials to NJDEP for review within sixty(60) consecutive days of receipt of this Order. 7. Upon rece.ipt of written approval by NJDEP, Jame Fine shall implement all proposals, as approved, in accordance with the approved time schedule. NOTICE OF CIVIL ADMINISTRATIVE PENALTY ASSESSMENT 8. Based upon the above FINDINGS, the Department has determined that an assessment of Civil Administrative Penalty. should be made pursuant to N.J.S.A. 58:10A-10(d) and N.J.A.C. 7:14-8.1 e_t seq - 9. Based upon a review of the criteria contained in N.J.A.C. 7:14-8.10, The Department has determined that the amount of the penalty should be set at $3,750.00. 100192 10. Any submission of information required by the Notice and Order shall be made to: Mr. Joseph M. Mikulka, Manager Region IV Western Bureau of Compliance Enforcement Element Division of Water Resources P.O. Box CN-029 Trenton, New Jersey 08625 11. NOTICE IS HEREBY GIVEN that'pursuant to N.J.S.A. 52:14B-1 et seq. and N.J.S.A. 58:lOA-10(b), Jame Fine is entitled to a hearing before the Department of Environmental Protection. Any hearing request must be delivered to the address below within twenty(20) business days from receipt of this Order and Notice. Said hearing request does not stay the terms or effects of this Order and Notice. The request should be mailed to: Richard E. Bellis Assistant Director Enforcement Element Division of Water Resources P.O. Box CN-029 Trenton, New Jersey 08625 12. NOTICE IS FURTHER GIVEN that pursuant to N.J.S.A. 52:14B-9(b)(4) and N.J.A.C. 15:15-10.2(b)(4), the applicant shall furnish the Department with a definite and detailed statement of the matters it will assert in the requested hearing. Any request for a hearing must include a writte.n statement specifying with particularity: (i) Any of the findings of fact set forth above, or specified portions thereof, which the applicant disputes; (ii) The applicant's counter statement of any facts so disputed; and (iii) The Order provisions to which the applicant objects, the reasons for such objections, and any alternative provisions proposed by the applicant. If there are no Findings of Fact in dispute, the Department may deny the request for a hearing. Any matters not contested shall be considered in full force and effect. 13. NOTICE IS FURTHER GIVE^ that if no request for a hearing is received within twenty(20) business days, this Order and Notice shall become final and the Penalty shall become due loon3 immediately thereafter. Payment shall be made to the Department of Environmental Protection at the address referenced in paragraph 10- 14. NOTICE IS FURTHER GIVEN that pursuant to N.J.S.A. 58:10A-10(e), any person who violates this Administrative Order or who fails to pay an Administrative Penalty in full shall be subject to civil penalties of up to $10,000.00 per day for each day of violation. 15. NOTICE IS FURTHER GIVEN that pursuant to N.J.S.A. 58:10A-10(f), willful or negligent violation of N.J.S.A. 58:10A-1 et^. seq. is a misdemeanor punishable, upon conviction, by criminal penalties of up to $25,000.00 per day of violation. This Order and Notice shall be effective upon receipt. 'ORIGINAL SIGNED BY ^R 2 9 m^ r^'^^^ ^^^"'^^?^!^ Date Arnold Schiffman Director Itf0l.l4 RATIONALE FOR FUBB AMOUNT Jame Fine Chemicals, Inc. Sgrlousneas; The dlacharge is approxlaately 14,000 f^pd of proceaa and cooling vater into an FV-Z atreaii. The dlscharf.e contains high amounca of COD and organic chealcals and Is likely to cause B»derate dana Seriouaneas factor; 0.75 Type; Jaaie Fine discharges most of Its industrial vaste to the POTW and allowedly was unaware of the presence of the above cited dlacharge: therefore, the violation vlll be considered to be unintentional but foreseeable. In addition, the discharge contains hazardous pollutants and has highly toxic characteristics, therefore, an additional value of 0.25 vrlll be added to the type factor, reflecting the hazardous nature of the discharge. Type factor: 0.75 + 0.25 " 1.0 Foraulat 0.75 x 1.0 x $5,000 - $3,750 AA4:0003081:J 10O135 • i}(-^ r -V-f--f f f- ..^-^—f ^ ^ f ^ ^ -r- ^i—1_„..(.__-^„„^_-. ;V ^H^-t-f-H—J—\—^—/ i I J i I ) i—I I I I- I I i i T-^ <-^ )6-.n.-'^y-A-A-t'-'^-^-AH ^JJJ;,^p,;5^;:,e,pCt^.AHt-,^-^^A-^^^ :^ii±x=xpt ^. . 1 •3'» 1J .^-T^bv^frr:: v,**'"' /»?r^'i \,^^^ CD : -7^a^;^^^>^-^M# .-.('•'•''• ir .ftSEY STATE DEPARTMENTOl' HH 1.0m .2 Tone & Date Received STREAM OR WAST^AT^ ^^K^? Y By Lab* — S«pt. 75 Lab. No. FIELD INFORMATION , PLEASE TYPE OR PRINT WITH BAULPOINT PEN ^//f _ idJli Hour. A.M. P.M. >r Sample No. ^ c^T3/9 Composite Period^^^^^_^__ In^eivai' Collected by ^^/)/^A^/!^.^ ~7^: Residual Chlorine: Municipa, l ity ,^^.^^^>X^, ^ Immediate Plant. ( ,^J^^{r /-, ,( r Developed Stream '- d^o-tr^J-^-J::- Flow Rate Location yS''S~ /^y /<%^^^-«r '^'~r~y ^ \ Temperature Description and Remarks: ITEMS CIRCLED BELOW ARE UNSATISFACTORY Dilutions Requested 10 1 1 10-1 10-2 10-3 10-4 1 10-5 10.6 . (Bacteriological) 1 1 1 Ii LABORATORY RESULTS BACTERIOLOGICAL Coliform MPN/100 ml. _ (Confirmed Test); Fecal Coliform MPN/100 ml. Fecal Streptococci:MPN/100 ml.. Other LiHiZ ::••-••:!. c. 3n:*/ ): 0 .. ,1 -.--> •-> •-« ',• ••^{] CHEMICAL AND PHYSICAL ANALYSES (mgj./Iiter, unleM otherwise notedl^i-r'--' ^-'••^TT'J '•;IV Gr L.'.i:.:.'.;:.L:S S E"J]. Color (units) Chloride Sulfate Other Determinations 1 i Odor (cold) Suspended Solids Grease & Oil Turbidity (units) Ash Cyanide /< //)j r- ,.^ V ^ rvN r ^ pH Total Solids Chromium Total fi^rii/Uf^e. r» 11 «*J ."rfc" 1 V|C Acidity to pH 4 Ash Chromium Hex. -i^iiD^.X^cH 1*=;^ Alkalinity to pH 4 Total PO4 Ortho - PO4 J^\Mo(><>-^-^j^P^ '^-- Nitrite N MBAS Copper 1 Nitrate N ^Phenols Lead • Ammonia N Z . COD 95/7 Arsenic jt\i\^\l}i-^lj!-»^ <• Total Kjel. N ^ Iron Zinc i- O BIOCHEMICAL OXYGEN DEMAND (mgj./iiter) Field D.O. Lab. D.O. Seed Required: Yes No 1 • PLE.^SE jSample Cone. ?o CIRCLE 0.1 0.2 0.3 1.0 2.0 5.0 10 25 50 75 100 ! BOD5 'ff^i^t 5f 100197 >\ eJ^ iEY STATE DEPARTMENT OF HEAI Time k 0«te Received CnMv29 STREAM OR W|((gfEV7AT^^fl^^ By Libs s«et. 75 Lab. No. . FIELDjIi^fPRMATION PLEASE TYPE OR PRINT WITH BALLPOINT PEN •'^•'A'^^^^t^ifCcflfection ^-^— i^ij^ Hour. O J ^<^ P.M. Sample No. ^ ITEMS CIRCLED BELOW ARE UNSATISFACTORY Dilutions Requested J^ 1. JJ2i 10-2 I 10-3 ISL JJJi JLQ:s i (Bacteriological) LABORATORY RESULTS BACTERIOLOGICAL = Coliform MPN/100 ml. _ (Confirmed Test); Fecal Coliform MPN/fGO ml. .Fecal StTeptococci:.MPN/100 ml. Other CHEMICAL AND PHYSICAL ANALYSES (mgs./liter, unless otherwise noted) Color (units) Chloride Sulfate Ot>er Determihatierts Odor (cold) Suspended Solids Grease & Oil tXai'^.^.^,: c^.c^^j^ Turbidity (units) Ash Cyanide '- ^[M^as^^d.a>.'C -'^ 4 pH Total Solids Chromium Total •\ Ammonia N ^ ^ COD 4J 7 Arsenic Total Kjel. N | Iron Zinc '!D = f;::!-::"""7.'.::r: 1.1 L3V/ BIOCHEMICAL OXYGEN DEMAND (mgj./liter) Field D.O. Lab. D.O. Seed Required: Yes Htri^„3,380 PLEASE (Sample Cone. % CIRCLE 0.1 0.2 0.5 1.0 2.0 5.0 10 25 (,c5 loot fig 3 K^^^ 'RacUi-^-^ -) S hA>^^r la 100141 Fire Protection Guide on Hazardous Materials 7th Edition Ii] HUS CORPORA'^^^ REGION II SENT TO. Nadonai Fire Procectioti Association Batterymarch Park Quincy, .VIA 02269 100142 49-1 Hazardous Chemicals Data NFrA 4«— 1«7S 1975 EdiHen of NFPA 49 The L97.5 edition of Hazardous Chetnicais Data incorporates cii&a^ea prepared by the Sectional Committee on Properties of Hazardous Chemicals and adopted by the National Fire Pro tection .-Association at the 197.5 .\imual Meeting on recommenda tion of the Correlating Committee of the Committee on Chemicals and Explosives. It supersedes the 1973 edition. .Amendments adopted in 1975 are summarized beginning on page 49-4. Origin and D«v«lapm«nt of No. 49 The compilation of information on hazardous chemicals waa originated by the NFP.A Committee on Hazardous Chemicals and Explosives in cooperation with the .American Chemical So ciety. .-A Table of Common Hazardous Chemicals (NFPA No. 49)' was adopted in 1928. Revisions were adopted in 1929, 1931, 1935, 1938, 1939, 1941, 1942^ 1944, 1946 and L950. A. complete revision, prepared by the Sectional Committee on Properties of Hazardous Chemicals, was adopted in 1961 under the new title, Hazardous Chemicals Data (NFP.^No. 49M). .•Amendments were adopted in 1962, 1963, 1964, 1965, 1966, 1967, 1968, 1969, 1971, 1972, 1973, and 1975. Starting with the 1964 edition, the identifying number of Hazardous Chemicals Data has been NFF.A 49. The data presented are subject to additions and revisions and are not all-inclusive, but are presented as the most authoritative information available to date. The purpose in listing a substance is not to discourage its proper use, but rather to make available information relative to its hazardous properties and hre Sghting phases in order to promote and improve methods oc ore protec tion and prevention. This is not a regulatory standard and does not include all possible detailed informaiioa with regard co hazards, storage safeguards, &re ngricmg, or unusual conditions which may be encountered. 100143 491M-1 Manual of Hazardous Cheinicai Reactions NFPA Na. 491 M — I97S IQ^ 'aaauai was prepared by the Sectional Comaiittee on Hazardous I'fwiriiiai Reactiooa of the NFP.A Comnuttee on Chemicala and Ex it has been approved tor publicaxioa by the Sectional Com- on Hazardoua Chemical Reactions ind by the Cotieiating Cota- ,.y^' ^^ ^'th edition represents the addition at approziinateiy fractions to che 2.350 reactions appearing in the fourth edition put>- "> '97L .\s further iu'ormation on hazardous reactions is aceu- the Committee plans to publish revised editions. Those who ^ references to reactions not included or who have peiaonai Imowi- ^CoI«^*"^°"* reactions are requested to send the informarinn to ^""''"tee Secretary, using the tear sheets at the end oi the manual, Committee on Chemicals and Explosives Carrmiaaat CocnntlR** Or. RobwT W. Vma Ooiab. CWim—. PitUbiOt a Mioinc tad Su'aty Bimrtit CMMT, Surwtu oi Miam. 1*3. Oaoanaaot « cte Intanor. -teoo roHMi Av*. Picuburca. ?-^ tS313 Choscar t. Baboack.t Stcrtsari. •uwul rirn Prot*eiio« .Kma., 470 AtlMue .iv»_ Souoo. M.A. 0«10 l_ _ *»'>ur)r. CT H«iirr T. Rlctman. lutiwu oi Maiun al -|^« itiOMf REFERENCE #20 10014S "^^^d -r -i 1^ t: c DOUNn DROdK MUNICITM, COURT STATE or NEV/ JERSEY ) ) SS COIItlTY OF SOMERSET ) AFFIDAVIT Gii-.an riergey and Robert Kunze, being duly isworn upon oath ci'iponc: and says: 1. He are tlie Sanitarians for trie Middle Brook Regional .Kealtii Commisr: ion and for the Borough of Bound Brooic. 2. Wo havc'reAsonable evidence to suspect a health hazard ' sy.i^'"' based on the following facts: • (.1).. On July 30th a complaint was filed with the' Health ncp.Trtmont at 336-3090 by employees of Consolidated Steel pLThriccitori, 100 West Main Street, Bound Brooic. (b) Complainant and investigation by Robert Kunze and Eii.';an Serg'jy ravcaied purple substance left a trail from the c- of Tifa Company, 100 Wast Main Street, Bound Brook around the l;'iilciing and towards the Raritan River. (c) Sov-jn drums, fifty-five gallons potential capacity v nioc'.d adj.;\cant to the door labelled "Chem-Sect Rice Seed Trc;. Al(lri:i". Tlie color inside the barrels was purple and was the cn\nc as tlio effluent. -• •' (d) MorcK Index ninth edition page 32 litts Aldrin as re ^qiiirintj "C.iution: Poisoning may occur by ingestion, inhalation .Tkin .ibsorption. Severe symptoms may result...". (o) Five out of seven employees of Consolidated Steel- F.ibricators had varied symptoms of nausea, headaches, * (iir.7.incrjs and burning tliroat. (f) Susan Sergey and Robert Kunze, Sanitarians for the DocoiJ'jh of QOMnd Brook looked through-^an open window and v;cvc ':;:no::';'-J to iieavy fumes. Said employees during following tvcr.; fo'ir lioun TUL'fcrad from dizzines5, nausea and blurred visior.. {'j) 2a3cd on inspection cf July 30th and subsequent rci- '.-poction c.-i July 31st reasonable evidence of a public health lui;;ar'l exists. 3. Ol-.hnr in:pcctors have indicated to the abo''o t'.vQ ncntionc:: Sani'.:;'r L.ins that access lias been previously refused ip.dicati:'.(; a noc'i !or .i search warrant. .; . It is .-.ccassary to make an inspection of Tifa Ccnpany, IDO '.-.'.-ir^t Mai.T Straot, Bound Drock, .Mew Jersey in orcer to »i:.L,->ji'.. .1 j.u J. C = !.--ilLa hazard decs e:;i3t iascd or. ivi.i.zT.z^. acourrMiIatcil •..'nilo doing an i.-.snection of the surroundi.-.q ai"e?. . 3 . "or these roisons, it is ro.'ipei.tfully requested t.hat a so.-'.r •..-.•'.rr.T:it be issuod allowing the below signed Sanitarians ar.d :r.c L'-irc ncf.arC'Tion': -o rr.aka an inspection of the promises located a!: 100 V.'cst :;a a jtreet, Bound Drook, New Jersav. (• Susan Sci-ycy (J y^ lOwcrc Kunze /,. me this 1st day of August, 1?30 100146 BOUND BROOK MUNICIPAL COURT STATE or NEW JERSEY ) ) SS COUMTY OF SOMERSET 1 SEARCH WARWVNT 1. This matter being opened to the Court under oath by l.obert Kunze, Sanitarian for the Bound Brook Board of Health, on application for.the issuance for a search warrant for the' pcemincs described below, and the Court having reviewed the af f idavit ,j3f said Mr. Robert Kunze and Susan Sergey and being ^ ?3ntistied therefrom that located therein and thereon there is a health and fire hazard due to the following stipulated fact: (a) . On July 30th a complaint was filed with the Health Dcpart.'nent at 3SS-S090 by employees of Consolidated Steel Fabricators, 100 West Main Street, Bound Brook. (b) Complainant and investigation by Robert Xunze and Susan Sergey revealed purple substance left a trail from -he of Tifa Company, 100 West Main Street, Bound Brook around the building and towards the Raritan River. (c) Seven drums, fifty-five gallons potential capacity .stored adjacent to the door labelled "Chem-Sect Rice Seed' T-.s Aldrin". The color inside the barrels was purple and was the color as the effluent. (d) Merck index ninth edition page 32 lists Aldrin as r ,^ quiring "Caution: Poisoning may occur by ingestion, inhalatic ^kin .Tbr3orption. Severe symptoms may result...". (o) Five out of seven employees of Consolidated Steel Fabricators had varied symptoms of nausea, headaches, * ditr.iness and burning throat. •(f) Suson Sergey and Robert Kunze, Sanitarians Cor the ncrou'jh of Bound Brook looked througti iin open window and v.-c.-; c:i!ior.':6 to heavy fumes. Said employees during following tv.-c: !()-.:i: hours suCfored from dizziness, nausea and blurred visi.r (rj) riascd on inspection of July 30 thftnd/^•yi>b!>ecil£." - "' '-•'icctjon cn July 3,1st reasonable evidence or a 'public rv.',i2:; li.i::.-'.rd exists. ^ c:iar^!0 or control as such premisosi • • XJ. X-^i ^i,' ^^U. f>'J~^s—r -t^ ;i_^^u.-,_- ,. . 3. '.-•jii ar'i ncreuy orccrcu, i'n" -na event vou 30i:a anv o: •. • ai'oi''":iTion';io."i'':d ."riscol ancous, to give a receipt for ti'.c oi:,\: •^o 3cir-:'.l to the person from -.jhcm it was taken or whose _-o.= : It '..•."•.•; ;:oiind, or i.-. ch.o absc.ice of such person to lea'.'e a c: f.!; i.- •..•.-..rrnnt togeti-.er with such receipt ir. or upon the sai-J pr<-;;ni-;os froin '.viiich -he property i.T taken. •I. All infotmatian cvntair-.ed in the affidavit under oath : in junpcrt of the application for this search warrant is c> incor::ora:od iicroin by reference and the executing officer; directed to fr.iiiiiarize themselves with the contents there: 100147 r rou are further authori'^cd- to execute this warrant wit--,i: f^n (10) days from t.he is;;uancu hereof, and thereafter to Tc- ll^r^. prompt return to me with a written inventory of the pre, soizod hereunder. iliCi*— /-••''/^ <^ 7..,^U^. i , ,. The eollo.inc ^s^ ^esc^x^tion of_ 1 100 West Main Street '" ^"'"i ^ ^ / sound Brook, New Jersey 03305 ^^^^, ^/-/"^-^ N^^cholaZJsL L. aisseli, JrX Acting Judge for Bound Brook \ --V<- • \ • \ \ • > : '.. 100149 REFERENCE #21 100149 ^1- Or~... ^ ^ 3oroucTh of Watch unc February 13, 1981 Gecrge Psak, Esq. 2S1 ra.'^t ;'.ain rtra-st Sorh.erville,. ::. J. C8876 Dear lir. Fsa) F.nclo£ed fir.d surrj-.ary of inspection-s r.ade at 3-luc rpruco International, 100 West i'ain Street/ BooKd Brook for your records. hincerely. P.cnald Coiian !'.ealth Officer t.v- :rns r.nc *i lOoiso Bound Brook, N.J. INSPECTIONS MADE BY MR. ROBERT KUNZE 1/22/81 Noted 3 workers cleaning out basement 1/16/81 Noted 2 workers cleaning up running water 1/15/81 Checked Blue Spruce - No Activity 12/18/80 12/17/80 Checked Blue Spruce - See Bob for details 12/11/80 Checked Blue Spruce - No Activity 12/10/30 Checked Blue SPruce - Observed 3 monitoring wells 12/ 1/30 Checked Blue Spruce - No Activity 11/26/80 Checked Blue SPruce - Red Liquid Flowing 11/25/80 Checked Blue Spruce, - No Activity 11/17/30 . " 11/13/80 " ' •• 11/12/80 Checked Blue Spruce -2 men working inside 11/10/80 Checked Blue Spruce - 15 barrels of lindane being removed r 11/ 7/80 Checked Blue Spruce - Water Noted 11/ 6/80 Checked Blue Spruce - No Activity |[^ 11/ 3/80 " .. " 10/30/80 Checked Blue Soruce - Noted slow flow of water cut of rear l.^ 10/25/80 Checked Blue Spruce - Noted water flowing at 11:30 A..M. 10/28/80 Inspected Blue Spruce with Bruce Schwartz 10/27/30 .Meeting with Mr. Livingston, Mr. Seidel, Mr. Welaj, Mr. Barbai -Mr. Psak, Dr. Cohen & Miss Sergey 100I5Y Blue Spruce Corp. 100 West Main St, Bound Brook, N.J, INSPECTIONS MADE BY MISS SUSAN SERGEY .1/22/81 Noted 3 workers cleaning'out basement 1/ 9/81 Inspection - No Activity 1/ 8/81 1/ 5/81 12/ 4/80 " " • 12/ 1/80 • " " ' ' 11/25/80 . " " . 11/21/80 . " . 11/19/80 11/17/80 " " ^ 11/14/80 ,. .. 11/ 7/80 Visited Blue Spruce - DEP took soil & water samples 11/ 3/30 Inspection - No Activity 10/31/80 .... - • P 10/2 7/80 Meeting with Mr. Livingston, Mr. Seidel, Mx. Welaj, Mr. Barbai .Mr. Psak, .Mr. Schwartz & Dr. Cohen '^ -/JTT)) •Ididdle-Brook :CJ REGIONAL HEALTH COMMISSION 1200 MOUNTAIN AVENUE MIDDLESEX, NEW JERSEY 08846 (?01) }3St<090 PARTICIPATING MUNICIPALITIES '?3n 33S-7400. 80«0UCM o< eOUNO B«OCK TOWNSHIP ot GCEEN anoOK 80B0UCH ot MlOOLESEX •CROUCH ot SOUTH aouNo SPOOK BOBOUGH of SOUTH PUAINFIELO 80«0UCM o< WATCHUMG July 31, 1980 RS: Tifa Co., (Blue Spruce) 100 W. Main St., Bound Brook, N.J. EMPLOYEES C? CONSOLIDATED STEEL FABRICATORS: 9111 Pheysey Burning throat 538 Grove St. headache Upoer Montclair, N.J. 07043 746-7761 John Lentine Dizziness 268 So. Lincoln Ave. Headache Middlesex, N.J. 08846 356-4596 Rocco Cassio Headache 583 Orchard St. Rahway, N.J. Ernie Finizio Nausea PO Box 303 Stewartsville, N.J. 08386 James Wenz Nausea 1 Circle Drive • Headache Sonerville, N.J.08876 Lee Overran 24 6 Roycefield Rd Sor.crville, N.J. 08876 Robert Davis 234 "D" St Middlesex, N.J. 03346 PLASTIC COMPA^nr ON QTH-R SIDE OF TIFA: Richard Kileg 4 5-06 Fox Run Drive Fox Run Ant, Plai.-i'Sboro, N.J. 100153 r t i;::LK>,w.-r:s:x.'^'.1 4 v; *..v- •"V 1 •r 31 «r- ^a —. '•—>--» ,- — 1^ .• -^" * ^ 1 ^•",> • V.^ .-; • ••'•" C ^r- DDVP EMPTY BARRELS LABELED "ALDRIN" "X r. V ^x I r* E n JULY 31, 19 80 - 1:15 ?M Susan Sergey, Middle Erook Regional Health Com.mission AObert Kunze, .Middle Brock Regional Health Commission -ave Mu.".n, NJSDEP, Bureau of Pesticide Control Jce Vitellaro, NJSDEP, Bureau.'of Pesticide Control E.-aergency Response Coordinator Co."..->.is Faraday, .NJSDEP, Buroiiu of Hazardous Substa.-fces 1001S4 l^ DDVP E.MPTY BARRELS LABELED "ALDRIN* > ^i: J'JIY 31, 1980 - 1:15 .-M • .G.in Sergey, Middle Srook .Regional Health Com.T.ission ..ooert Kunze, Middle Brook Reg-ionai Health Comission Da-.-c .Munn, NJSDEP, Bureau of Pesticide Control -co Vitellaro, NJSDEP, Bureau.'o f • Pes ticide Cor. :rol E.nergency •'response Coordinator ' *• " .^•--..-.is Faraday, NJSDEP, Bureau of -{a-ardcus Substa.'foes 1001^5 REFERENCE #22 100156 - C i H_ s •- M^ I. p,;ll ^^^^^^ general wafer and wasfewafer testing specialists^ testing <^ " "^ - /Ji/C 6 .= ^^-•/^SXif - o ^ 126 John Oiraat 62S Oatamar* Ava. / 85 Trinny P»,ca corporation Rocf»««te«. NY 14623 Bunalo. NV 14202 / Hackanaack. NJ 07602 (7161424 1970 (716iaB3-«990 ' 12011 488-5242 Feb. 10, 1982 Mr. Dan Sheridan Peabody Clean Industry Inc. 2 Lincoln St. FEB l7b8Z Linden, N.J. 07036 g;r».V**«V"« C> Dear Mr. Sheridan: Attached are the results of analyses performed on soil samples taken on January 21 and January 25, 1982. The purpose of these samples were to determine the extent of contamination at specific levels. As the logs detail, three to five foot holes were manually dug by PCI personnel at each of seven sites. The site location's numbers are the same used during the first phase sampling. Manual excavations were done because we could not be confident of obtaining specific depth samples using the split spoon technique. The samples taken were: 1. Site 2-2 Rear yard of building A five foot hole was dug and samples removed at the two, three and five foot levels. Only the Sfoot 2 inch sample was analyzed. ' 2. Site 41-2 Alley Sample taken at the one foot level. This is a new site. Drums of material had been stored against the building at this site. 3. Site 36-2 Alley ill Sample taken at the 36 _inch depth. 4. Site 14-2 Basement Water filled to the 17 inch level in the hole. We attempted to pump the water out before sampling ^t it refilled too quickly. We manually dug the hole to t'fie three foot level and removed samples (through the water) usin^ a small sampling spoon. This procedure was agreed to by "Fred Gollob of GolLob Analytical Laboratories during a previous meeting on January 21, 1982. (See logs) 5. Site 19-2 Basement Sample taken at the tree foot level using the same procedure as at site 14-2. Water was found at the 12 incH level. 100157 Mr. Dan Sheridan -2- Feb. 10, 1982 6. Site 30-2 Room 3 Sample taken at the three foot level. Water was found at the 25" level and could not be oumpSd out. The 36" sample was taken through the water using the same procedure as in the base ment, (see site 14-2) ALl analyses were performed using the same methodolpgy as described in the Phase 1 report, dated November 3, 1981. All samples were taken by Richard Scheible of General Testing Corp., using sampling spoons. These spoons were washed and rinsed with methylene chloride before each sampling. 1 I hope this report is sufficient for your immediate needs. If you ] have any further questions, please do not hesitate to call. , f Sincerely, /l^yA^-^iyi'^^'^'^^^^ Richard Scheible Laboratory Director RS/cf End. r 100158 Water and Wastewater Testing Specialists general testing\A 328 John Suaai 62S Oalawara Ava. 85TnnnvPUc Rochaatar. NY 14623 «u Date samples ( ) racaivad ( J coUactad by General Testing 1/25/82 ANALYTICAL RESULTS P.O. #. (mg/l untan tutad otha Sample Description 2-2 Replicate Date(s] Time{s) Pentac h Lorobenzene <0.002 a Ipha - BHC <0.002 gamma - BHC (Lindane) <0.002 beta - BHC <0.002 D i ch lora n <0.002 Haptac hlor Analyiical procadura* in accordanca with Standard Matrtoda (w i*«« CM*t*«k»tfw«i'ut Wtfivr^wMi WM««wa««r, 'i^*'n canton and Mathoda (o< Chemical Analyvaol Waiat and VVaaiaa. EPA. ( 32S John S(ra«t general testing 825 Da4awara Ava. 96 Tfioitv PU<. Rochntar. NY 14623 BuHato. NY 14202 Maekantaek. Nj v corporation (7181424.1970 (7181 8B3-4990 (201|4aB-S24i LABORATORY REPORT Job No. i-snn o«« —F^h. in. ioflp Client Peabody Clean Industry Inc. Sampleis) Reference 2 Lincoln St. Linden, N.J. 07036 Blue Spruce Att: Dan Sheridan Bound Brook, N.J. Soil Samples - Phase 2 Date samples ( ir«ea>v«i ( xtcoiiactad by General Testing 1/25/82 ANALYTICAL RESULTS P.O. #. All results ug/g Sample Description 2-2 ^*r ar« Date Analviical procedures in xrcordar^e with Sundard Moihods tot ...« ^..MVIM'^MM** !*• m^mimt * C3B OalMwa Ava. 328 John SMM 88 Trimty Piscj general testing^^ •ufMo. NY 14203 Wocftaiar. NY 1 e>"naaek.Njo corporation (718)424.1170 (a01|4»«24: LABORATORY REPORT Job No. J-500 0»*» Feb. 10, 1982 Client Peabody Clean Industry Inc. SampieisI Reference 2 Lincoln St. Blue Spruce Linden, N.J. 07036 Bound Srook^ N.J. Att: Oan Sheridan Soil Samples - Phase 2 , Oat* samples i inacawMi ( ;(eo«Mnad by General Testing 1/25/82 ANALYTICAL RESULTS P.0.#. Al I-pesatts-Tjg/g-' Sample Description 14-2 Basewant; 5' \ DateUV;: 1/25/82 Time(s) 12:40 i Pent ach lorobenzene <0.02 I •/^i^alph a - BHC .<0.02 gamin a - BHC (Lindane) <0.02. ' ...: beta - BHC ..0.02 Dich loran <0.02 .v'.r^.Hapt achlor .:<3.02 delt a - BHC <0.02 ., _: ALdr in ...O.fli.;: Hept ach lor-epoxide <0.0?- ~.'T..- Ha I ath i on .-: Anatyrical precaduia* in accordanca wfftt Standard Meihoda for ••'• cmmninmiion oi malar ana vvaatawMiar, lam toman and Matftoda for Chamcai AnatyM a< Watar ar>d Wama*. EPA. (<1 indwatM towaat daMcuMa eorwanuainn wiin proeadwr* uaad Laborstorv Director Water and Wastewater Testing Specialist: general testing^ 328 JoAn Straai 625 Oalawara Ava. 85 Trinhv PU. Aocftanar. NY 14823 SuffUe. NY 14202 Hackanaack. NJ i corporation (7181 424-1970 (718)1 (2011406.52.! 0„« Feb. 10, 1982 LABORATORY REPORT JobNn J-500 Client Peabody Clean Industry Inc. Sample Date samples ( )r acaivad ( jtcooactad by General Testing 1/25/82 ANALYTICAL RESULTS P.O. #. All results -ug/g • Sample Description 19-2 6as •(...-fifi-.k...... •'?N Analr Matltods (or Chemical Anatyaai oi Waiar and Wastai. EPA. 100162 ( < I inrticaiaa loweat dataciaeia oorKantraion w«t> prooadura uaad Laboratory Director ""-If I iir. Water and Wastewater Testing Specialise general testing)^^ 328 Jorwi Slraa< 825 Oalawara Ave. 86TcwvtY P\ Rochaaiar. NY 14823 SuNato. NY 14202 Hackanaack. N. corporation (7181 424-1970 (718t 883-4380 (201l4a8-S, Oete Feb. 10, 1982 LABORATORY REPORT Job No. Jll9°. Client Peabody Clean Industry Inc. Sampleis) Reference 2 Lincoln St. Blue Spruce Linden, N.J. 07036 Sound Brook, N.J. Att: Oan Sheridan Soil Samples - Phase 2 Date samples ( i racaivad ( ;*eoAacTad by Ger>eral Testirig 1/25/82 ANALYTICAL RESULTS P.O. #. i'<)Qib(<*')t«;nf M )i« .«cm 3-3 Date(s) 1/25/82 Timels) 13:25 Pentach lorobenzene <0.2 alpha - BHC 0.63 gamma - BHC (Lindane) 0.38 beta - BHC Elute 0.54 0 i c h I o ra n Together Haptach lor <0.2 ' delta - BHC 0.20 Aldrin <0.2, . Hept ach lor-epoxide Elute ^j77- Malathi on Together al0ha-- - Ch lordans 1.42 VC'r 26 p^^ gaoHiva ELute Chlordane 1.12 o,p I _ DOE Together alpha - Endosulfan <0.20 P/P' - DOE 1.24 Oi e ldri n <0.20 o,p' - 000 (TDE) 4,54 Endrin <0,2 o,p' - DOT 1.66 P/P' > ODD (TDE) 8.18 beta - Endosul fan <0.2 P,P DOT 24.6 Endrin a Idehyde •VJ3J!*' Endosul fan sulfate. M i r e x f-^w. Methoxy ch lor Toxaphe ne ^Tj'Sii-.X.t.r:. .-.-J • . 7<--.v _y Analyiical orocadgrat in accordanca wirn.SiandardMatnadt (or tna tzammaiion o* Waiar and Waatawaiar. 14m 6Aion and looiea Melhodt (or CNamicM Analywi o( Watar ar>d WMiea. EPA. J --^ (<1 indidiaa kMraai dataciabla coocamrauon w«n procsdura uaad 'Labor^tcrw 0>r-scr3r Water and Wastewater Testing Specialists 328 John Slraai 825 Dataware Ava. 88TrMry PUci general testing^ Roefwatar, NY 14823 auffaio. NY 14202 Hackanaack. NJ Ci corporation (7181434.1970 (71811 (ai)4aM24i LABORATORY REPORT Job No J-500 Oete Feb. 10, 1982 Client Peabody Clean Industry Inc. Sampl«(s) Reference 2 Lincoln St. Blue Spruce Linden, N.J. 07036 Bound Brook, N.J. Att: Oan Sheridan Soil Samples - Phase 2 Date samples ( iroca ANALYTICAL RESULTS P.O. #. All results ug/g - Sample Description 36-2 AIU^ i' Dateis) 1/25/82 Time(s) 12:35 Pen tac h lorobenzene <0.002 alp ha - BHC <0,002 gam ma - BHC (Lindane) <0.002 .bet a - BHC . >.V— ~ -:•>- •J '. • - ., *»i'-«ii^* ' .•. Analytical orocadurea in accordance wtih Standard Mathoda (or Metnoda (or ChanM:al Artalyaia o( Waiar arMl Waataa. EPA. 100164 ( < I Indicataa knvaat datactaeta cortcanvauon wtth procadura uMd Laboratory Director- Water and Wastewater Testing Speciaiis; 328 Jdltn StraM 825 Dataware Ava. 85 Trinity pi general tesf/ng V^c^c: Rootanar. NY 14823 Buffaie. NY 14202 Hackanaack. N. (7181424-1970 (7181883-4890 corporation (2Q1|4a8-S LABORATORY REPORT Job No. i-srin Date F»h. in 10flp_ Client Peabody Clean Industry Inc. Sample(s) Reference 2 Lincoln St. Linden, N.j. 07036 Blue Spruce Att: Oan Sheridan Bound Brook, N. J. Soil Samples - Phase 2 Data samples ( i received ( xi coitected by General Testing 1/25/82 ANALYTICAL RESULTS P.O. #. (rKgrtUOttaBtaOMXMHWUII ALl results ug/g Sample Description 41-2 • Date(s) '• V2S/82 u^r-- -.'ii^ •...••:i-.'.': ..' . Time(s) 12:25 'vcis-.' ..• •• .-".i- , .••"'•.liaiisv;^..;;^^.^;..;; . Pentachloroben2ene :•'...-: Ma I at hi on , '.'.%:•..-. a Ipha - Chlordane <0.002 :• '•' '' '",• • o,p' - ooe 0.016 at^dt) ^^^ alpha - Endosulfan <0.002 P,p' - OOE 0^056. 0.019 ... Di eldr in ...:• ..•• o,p I _ ODD (TOE) ;£ndr in <0.002 o,p' - ODT o.msi ...P/P' - DDD (TOE) <0.002 ^ ""'•*•"'"' beta - Endosulfan .i.iiAjm »...T.:.-..... • .J. .. •...•.•., ••-t-ysxtii'.-^.. ^^:) Analytical procedure* in iccorOa.nca Wrt/v Standard IMeinoda (or 5 Meihoda (or QymrrucM AnalyM o( Water and Wtaiiaa. Ef A. .-:/t I <) Indicataa ksweat daieetaola cortcMttratam wtth procedure uaad Laboratory Director UCT^IiiX-;; Water and Wastewater Testing Specialist 328 Jdftn Street 825 Oalawara Ava. aSTrMcyPw general testing^s: ReettMtar. NY 14823 Buffalo. NY 14202 'Ckanaaek.Nj corporation (7181424-1970 (718)883-4990 (2011488-62. LABORATORY REPORT Job No. J-500 .Oete Feb. 10. 1982 Client Peabody Clean Industry Inc. Sampie ANALYTICAL RESULTS P.O. #. (n)OAiqi •'' Pentachlorobenzene 0.'l06 0.078 f " 742 ;-3^ alpha - BHC 0.056 0.041 U^rn gamma - BHC (Lindane) 0.089. 0.071 ' 80Z beta - BHC Elute fs. - 0.112 0.086 - 77X Oichloran Together • Haptachlor '0.123 0.096 • .' "752 delta - BHC 0.052 0.035 672 Aldrin , • 0.10Q - 0,068 / 682 Heptachlor-epoxide ELute .0,791 0.579 732. . Malathion Together r gamma - Chlordane 0.100 0.076 762 alpha - Chlordane 0.100 0.068 682 o,p' - OOE 0.122 0.104 852 alpha - EndosuLfan 0.119 . 0.086 722 p,p' - DOE 0.136 0.116 852 D.i e ldr in 0.104 0.075 722 o,p' - 000 (TOE) 0.132 0.092 702 Endrin 0.107. X 0.074 692 o,p' - DOT 0.118 V 0.093 79% rl p,p' - ODD (TDE) 0.079 •; 0.055 702 beta - EndosuLfan 0.200 i? 0.140 702 ' p,p' - DOT 0.124 Q.1Q4 912 Endrin aldehyde , ..- • *=-.';:-.••'Efidosu I fan sulfate ...f • ...... : - .' i—>-->r'^^'"*'' *.'•'•• h:L-7. Methoxych Lor ':' »••: -•• .*.'•'. , •«. V Toxaphene r s Analytical procadtiraa in accordance witn Surtdard Meihoda lor (ha Eiamlnaiion o( Waiar artd Waatawatar. 14th Edmoo and Methoda (or C^amac^ Analyala o« Watar and Waataa. EPA. ( < 1 indicataa kjwaat datactaola coocanttition wrth procedure uead L-hr «../ n: Water and Wastewater Testing Specialists general testing^-^ 328 John Straat 825 Oalawara Ava. 88 Trifwty Ptac Rocheatar. NY 14823 Buftate. NY 14202 Hackanaack. Nj c (71811 corporation^ ' (7181424-1970 (201)488-824 LABORATORY REPORT Job No. J-500 Oete Feb. 10, 1982 Client Peabody Clean Industry Inc. Sampleis) Reference 2 Lincoln St. Blue Spruce Linden, N. J. 07036 Bound Brooic, N.J. Att: Oan Sheridan Soil Samples - Phase 2 Quality Assurance - Blank Date samples ( tr. ( )*coUacted by General Testing 1/25/82 ANALYTICAL RESULTS P.O. # (n»ft('«'«««J«» «»in«Mi All results-iig/g Sample Description Blank i ; • / Date(s). Time(s) ,...,. Pentachlorobenzene <0.002 i V alpha - BHC • , ...r':.EndosuL f an sulfate •• i^*-* - .^...... '^jf^ex. ., _ . i-IwMethoxych lor 1. ' " ..-. . -*J.. Toxaphene . ^-^^ '-'••• ••;. • ...... 1 :.. .?--.- % Analytical procaduraa m accordanca with Standard Methoda lor ...• r..!*^ 6.y~..;~. -• «*<~r r-i "^srrr.-:•jr . \'rT. lisi=r . =rJ , Method* (or (^auMcal Analywa ol Water and Waataa. EPA. ( lOMRtf 1. REPORT \ of \ '^•.:. THE ELECTRON CAPTURE GAS CHRON^ATOGRAPHY ANALYSIS OF A) THE SOJCKLET EXTRACTED ACETONE/HEXANES-SOLUBLES EXAmlNED FOR PESTICIDES CONDUCTED ON THIRTEEN SOIL SAMPLES #ci+005i #Ci^0058 #Cif0052 #C^C059 #040053 #C40060 #CiK)054 #Ci4'006l #C40055 ' #040062 #C40056 #C40063 #C40057 B) THE ftlETHYLENE CHLORIDE EXHAUSTIVE LIQUID/LIQUID EXTRACTION CONDUCTED ON FOUR AQUEOUS WELL SAI.1PLES #C40064 #C40065 #C40066 I #C40067 TAKEN AT THE BLUE SPRUCE FACIHTY. BOUND iROOK, NJ I SUBMITTED BY THE NJDEP/OHSC• • , on • • ^'•~' i Dececber 9. 1980 TEST REPORT §9^91 i Copy No. _2. i Prepared by. ROSSNAGEL & ASSOCIATES Distribution; Office of. Hazardous l>rf CP Substances, NJDEP Enginecrinq & Tettiaf Conluitjnls Mr. Scott Santora Air • Wjler - E««rqr ' Chirloltc. H.C. . Medford. N.J. . AtUnti. G«. Chief Technical Services (609) 65^1^.^! (3 copies) F.epcrt Issued: December 15, I96O lOi^M Ill RESULTS Pesticides are identified by their RRT's vs. Aldrin u-nder standard conditions. Data from the ECD gas chromatographic run are presented in Table 1.1 through Table 1.17 inclusive. Tentative identification is made if the peak in the sample has an RRT of ^ 3/^ of the standard. - 'e- :• f.. 190170 COMPREHENSIVE rESTICIDE srAN (SOILS) /^jCJ^OQS'J' / Quantitative RRT (Aldrin:1.00) . Sasple Results ' Organochlorine ( 9^-03 g. —^10: Pesticide STD Concentration Nominal Concentration Reference Actual Factor During | Sample (50 ng/ral) Standard V/orkup) i Trifluralin>-' .44 o<-BHC .5^ Lindane .67 Pentachlorobenzene '^ .68 Dichlcran .74 ^-BHC .78 Heptachlor -/ .82 Aldrin (Reference) 1.00 Heptachlor Epoxide 1.52 iT-Chlor dane • /^ 1.70 o,p'-DDE - y 1.83 bC-Chlordane -^ Endosulfan (I)-^ 1.86 p,p'-DD£ / - ^- 1.93 -§-- Dieldrin-y 2.25 Captan 2.37 o,p'-TDE 2.54 Endrin ^ 2.65 o.p'-DDT 2.89 p.p'-TDE y 3.18 Endosxafan (II) ^ 3.48 p,p'-DDT 3.55 4.20 Mirex 6.29 Methoxychlor - 8.24 Toxaphene Multiplicity N-O- o^ Peaks i '^^'Analvst: r'- Genicola/M. Smith ROSSNAGEL^& ASSQCIATES. Date: 12/15/80 tnqinetfinq & T«tlinf ContuiUntt r^m^ Air • Wiler • Noi:e Lab Report: #8248 I 224 B( 7() • u-J<-.J u I A" (6C9)'"054-1441"' % rcrm rRA-363-lA 1001tt /- CCMPREHENSIVE' PESTICIDF SCAN (SOILS) z #C40052 Quantitative Sample Results Organochlorine RRT (Aldrin:!.00) ( ^ g' lOmi Pesticide STD Concentration Nominal Concentration Reference Actual Factor During (50 ng/ml) Standard Saisole V.'orkux)) Trifluralin .44 c<-BHC .5^ Lindane .67 Pentachlorobenzene .68 - ^JOQ rfg/h' Dichloran .74 . ,715: - >S-BHC .78 Z ^(a.QL Heptachlor .82 Aldrin (Reference) — .00 Heptachlor Epoxide - .52 IT-Chlordane- - .70 o.p'-DDE - .83 bC-Chlordane " .86 Endosulfan (I) 1.93 - ^5:*(1 4.. p.p'-DDS 2.25 Dieldrin 2.37 Captan 2.54 o,p'-TDE 2.65 Endrin 2.89 ..S3. _ o.p'-DDT 3.18 - S7S _ nf p.P •-TDE 3.^8 Endosulfan (II) 3.55 p.p'-DDT 4.20 Mirex 6.29 _ j^.i).. Methoxychlor 8.24 Toxaphene Multiplicity of Peaks H'd TABLE. 1.2' |:Coliiian: Glass, 6 ' x 4 mm, 1.5% SP-2250/1.95/5 SP-2401 U •. , , •;MS-^ ^ Supelcoport (100-120 Mesh) .kLtS- ^f •60 ml/min, N2 y.\ - s ^G.C: Varian 3700; ECD 10, 8x Recorder: Attn CDS 111 Data System '", '» . • ' • • Temoerature Controls: 195 C. Column (20'"0 C. true temperature when p,p'-DDT = 4.18 RRT) • 220 C, Injector - 250 C. Detector ^'Sample Siz,a: .5 p.1^ '•''^Analyst: v. Genicola/M. Smith ROSSNAGEL &'ASSOCIATES' ^^ Date: 12/15/8O ' Engineering & Testing Consultinti Air • Witer • Noiie if Lab Report :f 8248 II 224 _Rt. 70-' U.J(-.4 w 1 n«n55 (609)'"S5^-i4iii" f^ Form =RA-363-lA loot?? COMPREHENSIVE PESTICIDE SCAN (SCILS) ''-3 ^C40053 Quantitative Sajmple Results Organochlorine RRT (Aldrin:1.00) Pesticide STD ( -'/-O^' g. ~>iOno fH" Concentration N'ominal Concentration Reference Actual Factor During (50 ng/ral) Standard Sample V.'orkup) Trifluralin .44 o(-5HC .5^ Lindane .67 Pentachlorobenzene .68 Dichloran .74 . J7J0 _ /S-BHC .78 Heptachlor .82 Aldrin (Reference) .00 . LOJ)_ Heptachlor Epoxide .52 . U.J),- If-Chlordane • .70 . N.D— o,p'-DDE-- 83 . tJ.D.. c<-Chlordane 1.86 . £J.3— Endosulfan (I) 1.93 p,p'-DDE 2.25 . d.n,- Dieldrin 2.37 Caotan 2.54 o,p'-TDE 2.65 Endrin 2.89 o.p'-DDT 3.18 . U.D.- p.p'-TDE 3.48 Endosulfan (II) 3.55 p.p'-DDT 4.20 Mirex 6.29 Methoxychlor 8.24 Toxaphene Multiplicity of Peaks ^i^Column: Glass, 6' x 4 mm, TA3IZ 1.3^ J ^ 1.5^ SP-2250/1. 95f» SP-2401 Sj Supelcoport (100-120 Mesh)' -/J |g 60 ml/min, N2 v.? s SG.C: Varian 3700; ECD 10, 8x Recorder T^ttn CDS 111 Data System ^^Temperature Controls: 195 C. Column (200'C. true temperature when p,p'-DDT =4.18 RRT) 22b C. Injector 250 C. Detector Sample Sij 5.^: ^t^nalyst; ^. uenicola/M. Smith ROSS^:AGEL& ASSOCIATES m Date: 12/15/80 Enqineeting & Tetting CeniuIUnU Air • Witer - Nolje gLab Report: #8248 III 224 Rl. 70 • u./(f-.4 u I "5055 (609)^ S5^'-ii^i «ircrm =RA-363-lA 1101^9 COMPREH£NSI\^' PESTICIDE SCAN (SCILS) #040054 Quantitative RRT (Aldrin:1.00) Sample Results Organochlorine ( o?-^5 g' —J-'lOml Pesticide STD Concentration [ominal Concentration Reference Actual Factor During (50 ng/ml) Standard Sample V/orkup) fe'-t Trifluralin .44 c<-BHC • 5^ lindane 6I.J0.- .67 iJ^r-0'- Pentachlorobenzene .68 _ Qr^CQ alii Dichloran .74 /S-BHC .78 Heptachlor .82 Aldrin (J?eference) 1.00 UQO - -t.,LOO nM Heptachlor Epoxide 1.52 UD.- S*-Chlordane- 1.70 UD.- o,p'-DDE - 1.83 bLL.- b<-Chlordane ' 1.86 tL.D,- Endosulfan (I) 1.93 UfiS - p,p'-DDE 2.25 UD.- Dieldrin 2.37 &L'D.- 'Captan 2.54 UD.- c.p' '-TDE 2.65 U.D.- I:Endri n 2.89 U.D.- |'jo,p'-DDT 3.18 ^p.p'-TDE 3.48 b Endosulfan (II) .55 U.D.- p.p'-DDT i .20 h UD.^ S^irex 6.29 ^Methoxychlor 8.24 - M.D.- Toxaphene Multiplicity : t&z '4^ of Peaks N.D. S^ Column: Glass, 6' x 4 m.m, TABLE 1.4 ' / gr 1.5^ SP-2250A.95?5 SP-2401 ^i^. Supelcoport (100-120 Mesh) " g 60 mlAin, N2 vr W^' c. Varian 3700; ECD 10, 8x Recorder ^tn CDS 111 Data System 'r -•Temperature Controls: I95 C. Column (200'C. true temperature when p,p'-DDT = 4.18 RRT) 220 C. Injector j^. 250 C. Detector f Analyst" iv.^.^.-'&^a/M; . s.ith IPSSI^AGELS •ASSOCIATES Date: 12/15/80 Engineering & Testing Contultintt Air - Wiler - Noije i^^ab Report: #8248 IV 224 Bt. 7n • u.J<..a u ; ZZZ'A 1 0 (609) 654-144i r. ."orrr; =.RA-363-lA iaotf4 CCMPREHENSI\^ PESTICIDE SCAN (SOILS) Q-l #040055 Quantitative RRT (Aldrin:1.00) Sa.-nple Results I Organochlorine ^.03 g, ->-iOml Pesticide STD Concentration Nominal Concentration Reference Actual (50 ng/ml) Standard Sample Factor During V.'orkup) Trifluralin .44 tJ.D.- c<-BHC .5^ UD.- Lindane .67 UDt- Pentachlorobenzene .68 Jcl - - B\D- Dichloran .74 UD- ^-BHC .78 U.D.- Heptachlor .82 UD.- _ ^ UO- Aldrin (Reference) 1.00 Heptachlor Epoxide 1.52 - U^CL TT-Chlordane • 1.70 o,p'-DDE-- 1.83 ua- o<-Chlordane 1.86 Endosulfan (I) - 1.93 U.D.- - J-Q-^ p,p'-DD2 2.25 d.D- Dieldrin 2.37 UD.- Captan 2.54 UD,- - ^l(a- o.p'-TDE 2.65 bJ.D.- Endrin 2.89 UD.- _ ^a^j 1^ o.p'-DDT 3.18 ti.D,- p.p'-TDE 3.48 tL.a.- - Lij^a. _, Endosvilfaji (II) 3.55 2,^1- p.p'-DDT ^.20 d.D.- y^3- •4iirex 6.29 d.D.- Kethoxychlor 8.24 Toxaphene Multiplicity of Peaks Column: Glass , 6' x 4 mm, TABLE 1.5 ' / 1.5^ SP-2250/1.95?^ SP-2401 Supelcoport (100-120 Mesh) j:. 60* ml/min, N2 I'U.C: Varian 3700; ECD 10, 8x Record er ATtn |: CDS lit Data System .< f^jemperature Controls: I95 C. Column (200 C. true temperature when p.p'-DDT = 4 .18 RRT) * • 220 C. Injecto r V 250 C. Detecto K4.nalyst- • renicola/M. Smith ROSSN'AGELS ASSOCIATES \ 8: Date: 12/15/80 Engineering & Testing Coftiuitjnti Air - W«(er • Noise I Lab Report:#8248 V 2J4 Bt 7g • u.j(..J u I A»A i- <• (50 ng/ral) Standard Sample Factor During Workup) 'Trifluralin .44 o<-5.HC .5^ <53 _ , • Lindane .67 UD.- Pentachlorobenzene .68 x(^^ - • ^3. _ nM Dichloran .74 UD.- .78 JIA - :i Heptachlor .82 ±23 - . J*a - Aldrin (Reference) 1.00 IJJ)2-- i Heptachlor Epoxide' 1.52 UD.- • ^^ - ^l> i'-Chlordane- 1.70 LTLD- o.p'-DDE - 1.83 UO.- oC-Chlordane 1.86 UD.- Endosulfan (I) 1.93 p,p'-DDE 2.25 Dieldrin 2.37 U.D.- . 4:^0- rt(, Captan 2.54 UD.- Co, p'-TDE 2.65 u.n.- Endrin 2.89 U'D.- b,p'-DDT 3.18 UD.- p.p'-TDE 3.48 a,^^_ : t^'i ^ Endosulfan (II) 3.. 55 UD.- ;p,p'-DDT 4.20 UD.- ^irex 6.29 Kethoxychlor 8.24 ;Toxaphene Multiplicity of Peaks N.D. ^"^'0 ^%h TABLE 1.6- '' ^'"Column: Glass, 6* x 4 mm, 1.5f» SP-2250/1.95f» SP-2401 Supelcoport (100-120 Mesh) 7^-1 60 ml/min, N2 ^^'0 C: Varian 3700; ECD 10, 8x Recorder Attn CDS 111 Data System "<• I'iPemp era ture Controls: I95 C. Column (200 C. true temperature when p.p'-DDT = 4.18 RRT) " "•. 220 C. Injector y,, 250 C. Detector *;^Sa.mple Siz*: ^5 ^:u Laivst, '^'telia/M. s.ith • ROSSN'AGEL & •ASSOCIATES Date: 12/15/80 Engineering & Testing Consuit«ntt Air • Witef - Noise E^b Report: #32.48.VI .. r-r- l?-*. ?.•.. 70 • .'.'.iifi.-i. .'i.;. ZZZ'JI T -—~ 12 (609) 654-1441 I'-fcn:; f RA-363-lA fd0f78 COMPREHENSIVE' PESTICIDE SCAN (SOILS) 9-3 #040057 Quantitative RRT (Aldrin:!.00) Sample Results OrganochlorLne ( l'9& g. —).10ml Pesticide STD Concentration Nominal Concentration Reference Actual Factor During (50 ng/ml) Standard Sample '.vorkup) -Trifluralin .44 . U D. _ c<-BHC .5^ , U-D.- Lindane . UD,- Pentachlorobenzene .68 . j.L>£ - - .p^3- CLqfn Dichloran .74 . UD.- >8-BHC .78 , JLo - Heptachlor .82 , /^. i). _ _ j^i^a nm Aldrin (Reference) 1.00 Heptachlor Epoxide 1.52 . UD.- •jT-Chlordane- 1.70 . UI3 _ -$^300. o.p'-DDE-- 1.83 , UD,- bC-Chlordane 1.86 . d'D.- - J-S-a a2 Endosulfan (I) 1.93 . UD.- p.p'-DDS 2.25 -• . UD,- _ ^^.a Dieldrin 2.37 . UD- •Captan 2.54 UD.- - 4-La. o,p'-TDE 2.65 . UD— •£ndrin 2.89 _ J-1L>- o.p'-DDT , un.- - J^3.Q 3.18 UD.- _ <2. •^Mirex 6.29 - U.D,- :TMethoxychlor 8.24 i .Toxaphene Multiplicity - UD'- of Peaks N.D. iO ^^/^ p, TABLE 1.7 •'.Column: Glass, 6 ' x 4 m.m , J |- 1.5^» SP-2250/1.95f» SP-2401 p Supelcoport (100-120 Mesh) IP 60 ml/min, N2 '}V ['^JJ.C: Varian 3700; ECD 10, 8x Recorder Attn CDS 111 Data System ^ "••JTemp era ture Controls: I95 0. Column (200 C. true temperature when |/- ' p,p'-DDT =4.18 RRT) |;r 22b C. Injector E-^ 250 C. Detector 2':•C3T.^•n^ g Sixe i>« ^ nl «..•• Sample ^IJL&Y &Analyst:V7. ^- enicola/M. Smith ROSSNAGEL & "ASSOCIATES Date: 12/15/80 Engineering & Testing Conjultjnll -•> • I Air - Witef • Noiie liab Report: #8248 VII 224 7.1. 70 -Medford, H.l. 08055 ?.- (609) 654-1:^1^1 J-form FRA-363-IA 13 1O0IVV C0MPREHENSI\^' PESTICIDE SCAN (SOILS) Q-i #040058 Quantitative RRT (Aldrin:1.00) Sample Results Organochlorine ( 1.93 g. _).-i0ml a Pesticide STD Concentration ^7fominal Concentration Reference Actual Factor During (50 ng/ml) Standard Sample Workup) Jr : .44 Trifluralin . ti.D.- .5^ . U.D _ - ^ J.a ac o(-3HC .67 Lindane . UD.- .68 . UD- •Pentachlorobenzene .74 _ J-Ma ni Dichloran .78 . u.n.- - j^dr.Q nc ;8-BHC . U.D. _ .82 . UD.- Heptachlor 1.00 Aldrin (Reference) 1.52 - -^j'.n ^ Heptachlor Epoxide 1.70 S'-Chlordane- 1.83 .Q,p'-DDE . 1.86 KoC-Chlordane ' . M'lJ:- 1.93 .U.D.- _ i,75e- Endosulfan (I) 2.25 ;p,p'-DDE . UD.^ 2.37 . UD.- - ^Z-Q Hi l:Dieldrin 2.54 _ _ Kir ex 6.29 _ d.D.. Methoxychlor 8.24 Toxaphene Multiplicity - £J.D.. of Peaks N.Q. ^10 rij/j TABLE 1.8 f\''' Column: Glass, 6' x 4 m.m, / I, 1.555 SP-2250/1.95f« SP-2401 Supelcoport (100-120 Mesh) 60 ml/min, N« ' \ .1 .V :.C.: Varian 3700; ECD 10, 8x Recorder Attn ^ V CDS 111 Data System < temperature Controls: 195 C. Column (200 C. true temperature when p,p'-DDT =4.18 RRt) 22b C. Injector 250 C. Detector jarr.ple Size: 5 ;^1 ». p.alyst; F. Genicola/M. Smith ROSSNAGEL & ASSOCIATES Date 12/I.5/8O Engineering & Testing Consultants Ail - VViter - Noise ab Reporj-v. #8248 VITT 234 Rt. 70 • Medford. N.J. 08055 (609) 654-1441 ."err: fRA-363-lA looivt COMPREHENSIVE PESTICIDE SCAN (SOILS) 3-/ #040059 Quantitative RRT (Aldrin:1.00) Sample Results Organochlorine ( Q"0% g. -^.lOml Pesticide STD Concentration Nominal Conce.ntration Reference Actual Factor During (50 ng/ml) Standard Sa.mple V/orkup) Trifluralin .44 UD.- <5<-BHC .5^ U.D.- - -^J>J)dNi Lindane .67 UD- Pentachlorobenzene .68 UD.- Dichloran .74 JU - /5-BHC .78 - J9. _ 3^ Heptachlor .82 -J^-Jll Aldrin (Reference) 1 .00 UOI - - ji - A Heptachlor Epoxide 1.52 usy- '5*-Chlordane- 1.70 - QaS^D nf / o.p'-DDE . 1.83 UD.- _ j^-Q-tQ ^i\ bC-Chlordane 1.86 UtS- Endosulfan (I) 1.93 p.p'-DDE 2.25 UD. - Dieldrin 2.37 ua.- - j^LO- Captan 2.54 61. D.- o.p'-TDE 2.65 UD.- Endrin 2.89 UD.- U.D.- o.p'-DDT 3.18 _ :^s.<2 „ p,p'-TDE 3.^8 tL.D.- Endosulfan (II) 3.55 UD.- p.p'-DDT 5.20 UO- _ ^^^ S/ N.D.- ^irex 6.29 - un. :,'Kethoxychlor 8.24 - UD. Toxaphene Multiplicity 0 t of Peaks N.D. ^Q^' 0 ^f ^^ TABLE 1.9 :Dolumn: Glass, 6 ' x 4 m.m , 1.5f' SP-2250/1.9555 SP-2401 L Supelcoport (100-120 Mesh) ^** 60 ml/min, N2 fQ.C.: Varian 3700; ECD 10, 8x Recorder A^tn :• CDS 111 Data System .... .[i;emperature Controls: 195 C. Column (2 00 C. true temperature when p,?'-DDT =4.1 8 RRT) 22b C. Injector 250 C. Detector Analyst: ^. Genicola/M. S.-nith ROSSN'AGEL & ASSOCIATES i:> Date: 12/15/80 Engineering & Testing Consuilinli Air - W»ter • Noise ifeb Report: #8248 IX 224 et. 70 • U,4UfA K ( nsn<;5 (609)'654-ii;4i "" ^onn #RA-363-lA 1^ lOOlVt CCMPREHENSI\rE PESTICIDE SCAN (SOILS) 3-2. f #C4oo6o Quantitative RRT (Aldrin:1.00) Sample Results Organochlorine ( l''^l g. -410ml Pesticide STD Concentration .Vominal Concentration Reference Actual Factor During (50 ng/ml) Standard Sample V.'orkup) Trifluralin .44 - UD.- o<-BHC .5^ - UD- Lindane .67 - UD'- _ Date: 12/15/80 Engineering & Testing Coniuldnti Air - Water - Noise Lab .ReporJLL^8^^'^Q..JL- ._-. I}-* .o.t. 70 • .'.'.i;ifi.-i. :,'.;. osc:3 (609) 654-1441 7orm ,f.RA-363-lA 16 l0OI8t C0MPREHEN5I\^ PESTICIDE SCAN (SCILS) 3-3 #040061 C10 - iTy Quantitative RRT (Aldrin:1.00) Sample Results Organochlorine ( Q'.03 g, ~).lOml Pesticide STD Concentration jminal Concentration Reference Actual Factor During • (50 ng/ral) Standard Sample V/orkup) rifluralin .44 UD._ -BHC • 54 U.D.- ;,ndane .67 UD.- jntachlorobenzene .68 tl.D.- .chloran .74 UD.- -3KC .78 UD.- iptachlor .82 AJ.D,- .drin (Reference) .00 U.D.- -4=L,CL a(fl •ptachlor Epoxide .52 UD.- -4LCL m -Chlordane- .70 UkS- - 3qD- £i p'-DDE - .83 ua- - 4=^CL A -Chlordsme " .86 U.D.- - 4Z£,a n ;dosulfan (I) .93 U.D.- - 4.a.Q A p'-DDE .25 UD.- 'eldrin 37 un.- _ 4 Ld n- ptan 2.54 U.D.- - 4UP- L p'-TDE 2.65 UD- - 4.3J1 •.drin 2.89 U.D- p'-DDT 3.18 un.- - ^5^ p'-TDE 3.48 UD.- dosulfan (II) 3.55 UD.- _ ^^,D A: p'-DDT 4.20 U.D.- - 4r^.Q DA, rex 6.29 thoxychlor 8.24 - U.D\ xaphene Multiplicity _ :4-^*Q D%l<- of Peaks TABLE l.ll lumn: Glass, 6' x 4 m.m, y 1.5J4 SP-2250/1.95/5 SP-2401 'b^O Supelcoport (100-120 Mesh) 60 ml/min, ^2 ^y '^^^ \ u- C: Varian 3700; ECD 10, 8x Recorder Attn\ CDS 111 Data System \ -nperature Controls 195 C. Colu.mn (200 C. true temperature when p,p'-DDT = 4.18 RRT) 22b C. Injector 250 C. Detector ilyst'^'^ :'f^ti y. ^ienicola/Mi . Smith ROSSNAGEL & ASSOCIATES Date ; 12/15/80 Engineering & Testing Censultintt Air - Witer - Noise 3 Report: #8248 XI .. 7?4 St 70 • u.jr..J u ;- ZZZ'jj (6C9) 654-i44i ^RA-363-lA 17 100181 COMPREKENSI\^ PESTICIDE SCAN (SOILS) ^'1 #040062 Quantitative RRT (Aldrin:1.00) Sample Results Organochlorine ( ^'Ol g, —).lOml Pesticide STD Concentration )minal Concentration Reference Actual Factor During (50 ng/ml) Standard Sample V/orkup) -ifluralin .44 N.D.. -BHC .5^ UD.. .ndane .67 UD.. •ntachlorobenzene .68 U.D.. .chloran .74 -BHC .78 ^a. iptachlor .82 UD.. .drin (Reference) 1.00 iptachlor Epoxide 1.52 UD.. -Chlordane- 1.70 un.. p'-DDE - 1.83 un.. ii rChlordane 1.86 un. dosulfan (I) 1.93 UD.. p'-DDE 2.25 UA. eldrin 2.37 un,. ptan 2.5^ U.A. p«-TDE 2.65 UD.. .drin 2.89 M'D.. p'-DDT 3.18 UD,. p'-TDE 3.48 UD,. dosulfan (II) 3.5^ p'-DDT 4.20 un,. UD,. rex 6.29 UD.. thoxychlor 8.24 6L,D.. xaphene Multiplicity of Peaks N.O, lumn: Glas s , 6 ' x 4 m.m , TABLE 1.12 1.5?5 SP-2250/1.9555 SP-2401 .. ( Supelcoport (100-120 Mesh) 60 ml/min, N2 ^1 C: Varian 3700; ECD 10, 8x Recor der A' Xl CDS 111 Data System iperature Controls: 195 C. Column (200 C. true temperature when p,p'-DDT = 4.18 RRT) ' ^ 22b C. Inject or 250 C. Detect or alyst: ?.' Genicola/M. Srr.ith ROSSNAGEL & ASSOCIATES P?3 12/15/80 b'ate: Engineering & Testing Consultants Air - W«lef - Noise 0 Report: #8248 XII 224 Rt. 70 • Medford, K J, niia<;5 _ I (609) 654-1441 -RA-363-1A 1091 COMPREHENSIVE' PESTICIDE SCAN (SOILS) ^-2 #0400,63 Quantitative RRT (Aldrin:1.00) Sample Results Organochlorine ( 5-09 g. -^.'lOml Pesticide STD Concentration cminal Concentration Reference Actual Factor During (50 ng/ml) Standard Sample V.'orkup) '- Ifluralin 44 UD. - 4:^0. nq/q ^-EHC 54 d.D,. lindane 67 UD. -4t La M 'B.ntachlorobenzene 68 UD. 74 -^ua n.41 "H chloran 78 u.n.. 3-BHC 82 UD. _ :4'l'.Q j^ [eptachlor 00 M.D.. ildrin (Reference) 52 UD.. ^eptachlor Epoxide 70 UD.. - ^ La f-Chlordane- -4.5LCL 83 UD.. ;.,p'-DDE- - 86 UD.. - 4.^.a iC-Chlordane ' UD . '"ndosulfan (I) 93 i •., p'-DDE 2.25 MrD. . ;ieldrin 2.37 UD.. - 4r ua 2.54 UD,. lap tan 2.65 !.p'-TDE ti.h.. indrin 2.89 d.D.. - :^5:.(2 3.18 UD. - ^&C2 ,,p'-DDT 3.^.8 ;, p'-TDE UD. - 4.Q:,a •ndosulfan (II) 3.55 ua. ;,p'-DDT 4.20 UD.. _ 4r^'0 UD iirex 6.29 - un, -{zO-'Or^k lethoxychlor 8.24 - UD oxaphene Multiplicity of Peaks N.D. ^9.0a<^l:1 r.alyst: T. Xlenicola/?^. Smit^ ROSSNAGEL & ASSOCIATES , Date: 12/15/80 Engineering & Testing Consultinti k., . w .) .. . U:);. EO Report: #8248 XIII 224 Rt. 70 • Medford. N.J. 08055 (609) 654-1441 Itotsa COMPREHENSI\rE:" PESTICIDE SCAN C^t/y^TER) / #040064.^^ Quantitative ample Results RJO' Organochlorine r,/f£ ,i( Zoo ^^ —?-10m2 Pesticide STD Concentration Nominal Conce.ntration Reference Factor During S-AirfL£ (50 ng/ml) Standard V/orku-p) Trifluralin .44 ^.^ no N'T), «=<-5KC .5^ ^ .3 n>^'/A^y Lindane .67 JLH ^i,OU OWATPT JUJL Pentachlorobenzene .63 ^,C>f. A^^/r^H Dichloran .74 Ms£L ^Irny. JLD. /S-3HC .78 ^<.J 3_ ^//TT:; .82 H,D< Heptachlor <,os' MjM. N,n. Aldrin (i?eierence) 1.00 (o.Q' - nW/M 1.52 Heptachlor Epoxide ^.^T 0J^1 J±JL "S"-Chlordane. 1.70 4..-. 1.83 -CLD, p,p'-DDZ •-_. • 1.86 NtOr c<-Chlordane ' N, Dt. Endosulfan (I) i.93- JLDU- p,p'-DDE 2.25 Dieldrin • . 2.37 MJ^ Cat)tan 2.54 UlDt. o.p'-TDE ;.. 2.65 Endrin • '. . • 2.89 o,p'-DDT . 3.18 p, p'-TDE •''- 3.-48 Endosulfan (II) 3.55 4.20 p,p'-DDT '0^ >¥/^^ HW, Mirex :••-_ 6.29 ^J n.W/fif . t^D. Kethoxychlor; 8.24 ^.•? >w//^ Toxatshene •' Multiplicity JUL 01 Peaks- ^,S u N,D. TABLE 1.14 umn: Glass, 6 mm 1.55i SP-2250/1.9555 SP-2401 •J SuDelcoDort (100-120 Mesh) 60 ml/min, N^ Varian 3700; ECD lo", Sx Recorder .Attn ^ CDS 111-Data System '^e•^ature Controls: 195 C. Colum.^ (200 C. -true te.iiperature when p,p'-DDT =4.18 RRT) 22b C. Injector ^ 250 C. Detector "_ .' 9 lyst: Fy ^enicj3la/M. Smith - ROSSN_AG|L&^SmiATES. Date: /15/80 . c..:..;::,: L Tizlir.j Con.uliintj iir - Wiler • Noijt r;eoort: #8248 XIV 234 Rl. 70 • Me Mirex 6.29 Methoxychlor 8.24 Toxatjhene ' >• Multiplicity of Peaks- U~J:L Glass , 6' x 4. Era , TABLE 1.15 I.55J SP-2250/1.95f' SP-2401 Supelcoport (100-120 MeshO L 60 ml/min. N2 J Varian 370D; ECD 10, 8x Reccrder Attn^ CDS 111 Data System \ pe-^atu-^e Controls: 195 C. Coluri?. (200 C. true temperature when p,p'-DDT = 4.18 RRT) 9 22b C. Injector 250 C. Detector ^ .• i - -1 c «: -• h^ _ 12/15/S0 Engineering L Testing Consul.! jnli Air - Wjler- Hoist Report: #8248 XV 234 i^t. 70 - Meiiford. N.J. {IS055 21 (609) 654-1441 CCMPRE?{ENSIVE' PESTICIDE SC.^.N C^/?TgR) 3 #040066 Quantitative RRtPfff' .'WL-^V^- J results OrganochlorLne r//K£ Pesticide STD Nominal Concentration Refere.-ce (50 ng/ml) Standard Tri fluralin '=<-YHC .54 Lindane .67 Pentachlorobenzene .68 Dichloran .74 ^-BKC .78 Keptachlor .82 Aldrin (Referenc e) i.bo Heptachlor Epoxide 1.52 ^-Chlordane- 1.70 p,p'-DDE _ 1-.83 c<-Chlordane •. 1.86 Endosulfan (I) 1.93 p,p'-DDE 2.25 Dieldrin ; . 2.37 CaT3tan 2.54 o,p'-TDE ;;. 2.65 Endrin- • '. 2.89 o.D'-DDT 3.18 p,p'-TDE • Endosulfap. (II) '-'" 3.55 4.20 Mirex 6:29 Methoxychlor 8.24 Toxat)hens •'. :• Multiplicity • of Peaks- arji: Glass, 6' x 4 mrn, TABLE 1.16 / 1.5% SP-2250/1.95f' SP-2401 1,^ Supelcoport (100-120 Mesh) 60 ml/min, N2 _ \ .: Varian 3700; ECD 10, 8x Recorder Attn •; CDS 111- Data System .* )€-^ature Controls: 195 C. Coluz^n (200 C. true te.-perature when p,p'-DDT = 4.1s RRT)' 220 C. Injector 250 C. Detector %, : ;le Siza: J 5 ivs' -•enicola/M. Smith~ ROSSNAGEL S "ASSOCIATES, :ate : 12/15/80 En^ine'etiiNg 1 Ttiling ConsuH*"'; iir - W*ler- Haijt Repcrt: #8248 XVI 234 Rt. 70 • Wedforcf. N.J. Oi055 22 COMPREHENSIVE' PESTICIDE SC.^.N (!eierence "actor Duri'hg (50 ng/ml) Standard V.'orkut)) Trifluralin .44 < ./? r*t A/.n. c^-BHC .54 ^ Lindane .67 .^_il^_4IS£ Vr£>, ^. 'OC3 r\t\rr,^. A/./^. Pentachlorobenzene .68 <'0C r.Ai,^t Dichloran .74 NrO, Date: 12/15/80 Enginee.'ir.g i Testing Consullir.lj iir - Wiler - Hsise ) Report: af.qp.ufl YVTT 234 Rt. 70 • Medfarii. K.J. 02055 23 (509) 65i^-li^^l • 1» . REFERENCE #24 T.i lOftlW ^^^^rD/_ U.S. EMVTRavIMEOTAL PROTECTION PCmCi POLLUTION REPORT CATE: July 18, 1983 TD: J. Schafer, EPA Reqion II R. Dewling, EPA EJterqency Response and Hazardous 3. Metzger, EPA i^iaterials Inspection Branch EiTiergency Response Division Edison, N.J. 08837 J. Marshall, EPA w. Mugdan, EPA A. Praschak, EPA (201) 321-6670 - Coimercial F. Rubel, EPA (201) 548-8730 - 24 Hour Emergency R. Spear, EPA 340-6670 - FTS NRC USCG 3rd Dist. (mep) J. Stanton, ^UDEP K. Stoller, EPA B. Ogg, EPA TAT C. Simon, H>A .POLREP NO.: ene (1) and Final INCIDENT ^JA^E: Blue Spruce International, Inc. SITE/SPILL NO: 95 POLLtTTAWr: 2,3,7,3-Tetrachlorodibenzo-p-dioxin CIASSIFICATICN: iMajor SOURCE: Pesticide Manufacttjring, Brook Industrial Corrolex LDCATICN: 100 W. .*tein Street, Bound Brook, New Jersey AMOUNT: Uhkncwn WATER BODY: Un-named Tributary to the Raritan River 1. SITOATIGN: A. In June 1983, t±ie tUDEP collected sanples in and adjacent to Buildinq #8 of the Brook Industrial Conplex at 100 W. Main Street, Bound Brook, New Jersey. This Duilding was formerly occupied by Blue Spruce International, Inc. These samples showed concentrations of 2,3,7,8-Tte- trachlorodibenzo-c^ioxin (2,3,7,8-TCDD) greater than 1 ppb. B. On June 29 and 30, 1983, the FIT conducted confinnatory sampling. Of the fifteen (15) samples collected from inside and outside of Buildinq #8 and the surrounding neighbor.hood, two (2) sanples from inside the building shewed 2,3,7,8-TCDD levels of 6.1 and 5.7 and one (1) sample showed levels of 4.5 uqAq adjacent to the buildinq. 2. ACTION TAKEN: A. Or\ July 16, 1983, a clean-up contractor, Aaxon Industrial, Inc., was hired to place an asphalt patch CTver the area outside the 'ouilding where dioxin contamination had been documented. aeoiss -2- B. An a.sphalt patch measurinq approximately 40 ft. X 17 ft. was placed over the contaminated area. On the location where the contaminated soil outside the building was collected, the covering consisted of a layer of polyethylene sheeting and 3/4 inch plywood under the asphalt. A two inch PVC pipe with a cap was placed on tcp of the plyvood to allow for easy access to the soil for future samplinq. C. The cost of the project was $3,290.61. 3. FUTURE PLANS AND RECO^IMENDATIONS: No further action is to be taken at present. CASE PENDS CASE CLOSED SUBMITTED BY Bruce Spraque, Einerqency Response (TAT) Section 1001M REFERENCE #29 1onigt ^ U.S. ENVIRONMENTAL PRCrrECTICN AGENCY O2.-S501-O3 POLLUTION REPORT CATE: August 12, 1983 TD: J. S<±afer, EPA Region II R. Dewling, EPA Emergency Response Brancii B. Metzger, EPA Edison, NJ 08837 W. Librizzi, EPA Elnergency Response Division J. Marshall, EPA W. Mugdan, EPA (201) 321-6670 - Cocmercial A. Praschak, EPA (201) 548-8730 - 24 Hour Emergency F. Rubel, EPA 340-6670 - FTS R. Spear, EPA f NRC ' US03 Jrd Dist. (mep) J. Stanton, liJDEI* B. egg, EPA TAT ^^^^ 2^ 1983 I. POLREP NO.: Three (3) INCIDE^/^ NAME: Blue Spruce International, Inc. SITE/SPILL NO: 95 I POLLOTANT: 2,3,7,8-Tetrachlorodibenzo-p-dioxin ^ CLASSIFICATION: Major . SOURCE: Pesticide Manufacturing, Brooic Industrial Conplex LOCATION: 100 W. Main Street, Bound Brook, New Jersey AMOUNT: Unknown WATER aXY: Un-nan>ed Tributary to the Raritan River 1. SITUATION: A. Cn July 27", 1983, FIT conducted additional surface soil sanpling for dioxin outside of the building. The results indicated dioxin contamination of 1.2-4.7 ppb from the alleyway entrance to just above the area paved with asphalt on July 16, 1983. Another dioxin contaminated spot was identified on the front side of the building. B. ^UDEP requested on August 18/ 1983, that EPA fence off the alleyway. 2. ACnON TAKEN: A. Cn August 18, 1983, CERCLA notice letters were issued to the responsible parties by Region II, B. The owner of Brook Industrial Park, indicated on August 18, 1983, that they would install a fence. C. A four foot fence was installed on August 19, 1983, with hardware to be added. rv&cA^^ -2- 3. FUTURE PLANS AND RECOWMENDATiaiS: A. EPA will work with the owner of Brook Industrial Park and NJDEP in trying to get some additional action taken cn site. CASE PENDS X CASE CLOSED SUBMITTED \ fi Bruce Sprague, OSC 1 j Emergencjr y Respons- e (TAT) Section ^i-J'i^fc idoi^^ REFERENCE #2e MOltl r TABLE I • ANALYSIS OF WATER SAMPLES TAKEN FROM MONITORING ;;ELLS AT THE BLUE SPRUCE PREMISES V Well No. 1 Well No. 2 Well No. 3 Well N Sample No. Sample No. Sample No. Sample Chemical C-40064 C-40065 C-40066 C-4006 , Pentachlorobenzene .i 75 Aldrin 6.2 340 1.0 j: r-Chlorodane 28 Dieldrin 9.0 1^ o.p'-TDE 30 fr p.p'-TDE 130 h. EXHIBIT "A"r .y?« T? MOIIB DEPARTMENT OF ENVlRONMt-.NTAL PROTECTION piction. i DIVISION OF WATEFt RESOURCES Water leveJ at ' ! time after comp Z' \ / Boring No. x Project Plu<. Spraci IntefAj-tmnal Date start i^/^ 1 fxratlon ?>QU'< .Type of rig_ A«u3 Of) Insnrrtnr 5 A^o*t5 5 Sample Elev a Spoon Plow Classification Remarks d a ROD ation -J loo t G" Penc. loo t '•0"Elev.: blows / blov/ s / Q Casin g z Aver , % 4rjp rack . t " a Z" rVc "T^sst -•«.'. cU. odor '"^'-J 1 1 . •! 1 1 ffi , i 1 r \ pA^tieJef* odor • ' to - ;i6«i,t 4- d-3 L 2'9VC- qray^ If.S ..^- rrior« v./ji^ Iua4_-fi\*,« -2. 1 9- 4and.jr*Mi 1x33 3'''^ .. • 1 <( f- — . . lirtU 3;i+ . t^-bf.Jn 1^ • \S9- / / / / / -' 1 t A / '•J 1 "7 / :' • L^e-J ^^_ .^iC.'^bi^i SET frorr. .to. teoise SHEET OF. DEPARTMENT OF ENVIRONMLNTAL PROTECTION pletion. DIVISION OF WATEF< RESOURCES Water level at ' _ time after comp. Boring No. ;? Project Okia, S^aru^j. _Oate start 'X/M I oeation Saiuij On^k ( ^ C..>.^^ _Oate finish n-/a- .Type of rig ^»<»i /c.» u..»g(e.') _lnspcc tor _;$j_^££*^ Sample r Elev- Spoon Plow OT Classification [oRemarks a ROD VI ation >« o loo t 2 G" Pene. loo t ••0"Elev.: blov/s / Casin g blows / Q 1- Aver . ^1 >i ' 2«- f ^> 41 3' -2. ^ tr c^ e ^ ^^ • ~i ^'1 ' 5^ 5.0- i ^' > . i •> ' 7.5- k i -^ •it. !• ^v <7 n \ -. md 5/'/*^ 3W'« • ? ^ ! ^( 1 (25- ! 1 1 1 • •5.0- i7^ .-«./,<«• ./ rtf^,.^ 17.5- 1 1 t «* - ! 1 ' > t •-26- 1 :, i .SCREEN SE-^- trc.-n tc loom SHEET OF DEPARTMENT OK tNVIKUN Mt.N I AL rKvjicuiivjN pletion. DIVISION OF WATEH RESOURCES Water level at time after comp. Boring No. _3 Project. dUtL^ IOSJB. .Date start /a-/<^ 1 Qcatian 'SQIMA Bnaok f,,ii,.iooU»f?MKt*Makar'\ .Date finish /ijt/ .Type of rig Aug4., ^u« o^^eiJ Insaector 5> ^«*>eg5 Sample •^~ Elev- a. Spoon blow OT Classification =?emarks ation d a ROD w >> o "Q-Elev.: G" Pene. loo t Casin g blows / Too t blows / Q z Aver . \ ' ^ i.5- ^oad.^3 to ^_<. -a. _/ yr»i//i/c/^J / l-i^yp'/f ^ • J.O- i •R.5- •^ 1.0- . r^ red »''^y i^" 1 I 'L5_ a b.o i<- l«i*v \ r • '5.0- 5- 1 1 1 ** 1. SCREEN SET from. -to. SHEET OF. t901«l DEPARTMENT OF EMVlRONMt.NTAL PROTECTlCM pletion. DIVISION OF WATER RESOURCES Water level at . time after comp. Boring No. J-f Pro feet l^lnl ^prurn _Date start /2A 1 ngation 'SpOnA Brook f i>«>1 «<:(. «f fj.» .e Ij .Date finish ^V*^ .Type of rig_A-cc, . n >.< 0-<1.k^ Insnrrtnr $, A*Joa£:<; Sample Elev- "a Spoon blow m Classification (Bamacli. ation d RQO 0 loo t loo t ••0"Elev = Casin g blows / G" Pene. blov/ s / Q z 1- Aver , : V. ? .^^^^^ \ f '>!2- ^ 2-5- s , S ^^ S V -^ V' *> 1,5- ^ 1 w 0 « )0- ^ . =^ K[ '1.5- tS*..lJ,.'\ i Cfftg^U-S • K-O- • ^>- • i rcij-Mtli J • 5- 1 1 1 .SCREEN SET from ^to. SHEET OF. lOMtS ^ a/-l/ ? \. yerat \ /ocIfTJ tdxniK !: '^^^aim Q^y&x<5?o/7 •"•a,' r<*. i; ^^ O^ /r^onii-orina oJZl/s ^,^ t90209~ REFERENCE #27 100201 u / Middle-Brook REGIONAL HEALTH COMMISSION 1200 MOUNTAIN AVENUE MIDDLESEX NEW JERSEY QSSA6 (2011 3S«-ia«4 PARTICIPATING MUNICIPALITIES I (2011 is*.74ao aosouGH at aouNQ anooK i TOWNSHIP af SREEN SROOK j aOROUSH of MIQO|.£5£xi sonoucH at SOUTH sQONo aROQKl aoRoucH of SOUTH pt_>iNPiei.a | aOROUGM of WATCHUNG I February 17, 1984 -19 84 WELL SUR^/EY BOUND BROOK 1Q52 North. Mountain Ave, 112 West Second Street 3'21 Kings Court 312 Ware Court 290 West -Main Street 101 Talmage Avenue 400 "ivest Union Ave..^ 301 Evergreen i^ve. 510 Kalfin Street 3 20 Thompson Ave. 334 Wast High Street 419 West Union Ave. 13 3 Vosseller .^ve. 30 6 Evergreen Ave. 3 29 Evergreen Ave. 6 8 West Second Street 60 3 Church Street 418 Park Place 256 West High Street 34 2 West .^^econd Street 311 Highland Place 121 Linden T.venue 349 Lcngwood Ave. 4 34 West r.aple Ave. 3 36 Tal.^r.age Ave. 305 East High'Stree't •.•- 5 06 West Second Street 193 .West Jiigh Street :-.A-; 35 Fisher Ave. • 1784 ^Middlebrook ..Road ^.: 133 Vosseller Ave. .5 20 Church" Street;^:- _;• 36 Fisher .^-.ve. •'- 220 Mountain .i.ve . "'-' 350 West Second Street 545 West Second Street 10020} ^-0., ..«-_ ;^^ / 227 Vosseller -We. 6 34 Church Street Middlebrook Road 13 2 LaMonte Ave. 235 West Main Street 21 West High Street Evergreen Ave. 510 Dalay Place 44 West Second Street 280 West Main Street 3 39 Evergreen Ave, 30 Fisher Ave. 122 Talmage .^.ve. 16 2 West Main Street .5 21 West Second Street 518 Dalay Place 5 2 3 Longwood .\ve ^ 111 Linden Ave. 346 West High Street 348 Longwood Ave. 20 5 Talmage Ave. 291 West Main Street 319 Ware Court 313 Longwood Ave. 1790 Middlebrook Road 207 West Second A.ve. 34 9 Grove Ave, 116 Linden Ave. 117 Li.ide.n Ave. -». 114 Linden Ave. 796 Watchung Road 105 Tal.tiage Ave.. 5 37 Grove Ave, 64 3 Winsor Street 547 Winsor Street 5 28 Longwood Ave. 206 West Main Street 210-212 West f'ain Ctreet 219 West .Ham Street 220 West r.ain Street 25 0 West Main Street 294 West Main Street 318 West Main Street 54 7 Longwood Ave. 551 Longwood Ave. SOCJTH SOUND BROOK 10 5 Grant Ave. 7 Equator Ave. 126 Prospect Straet 115 Shields .^ve. 25 3 Elizabeth Scraet 47 Bell Street 110 Van Sickle Blvd. 115 Howard .-.ve . 244 Charlotte Ave. 2 24 Charlotte Ave ^/-^' too2ta ^CZ^ J . 46 Bell Street: '221 Nassau Street 22.5 Nassau Street 24 3 Canal Road i 77 Stewart Street 257 .Main Street 263 High Street Tonal Private Wells Bound Brook 81 South Bound Brook 17 ?T 98 looati REFERENCE #28 r' jooaiif JL. r- H r r ^tatr nf ^cw .i)rriu\i( DEPARTMENT OF ENVIRONMENTAL PROTECTION DIVISION OF WATER RESOURCES CN (»9 TflCNTON. New jCBSfY 0MJ5 JOHN w. GASTON JR.. ^.e. OIRK C. MOPV«*^ •E.j DIRECTOR Oe^UTV OiR6CTO« CERTIFIED MAIL RETURN RECEIPT REQUESTED >UG 71985 Mr. Joseph F. Conrad 100 West Main Street Box 265 Bound Brook, New Jersey 0830 5 Mr. Richard Schleck Brook Industrial .Park • iOO West Mam Street Bound Brook, New Jersey 08805 Mrs. Mary Frascella 16 Church Street Bound Brook, New Jersey 08 30 5 Re: Admi.iistracive Order and Notice of Civil Administrative Penalty Assessment National Metal Finishing Corporation Brook Industrial Park, Somerset County Gentlemen; There is e.'iclosed for service upon you an .Ad-mir.istracive Order and Notice of Civil Administrative Penalty Assessment, issued b\ this Department pursuant to the previsions of N.J.S.A. 5a:i0A-10(b) and N.J.S.A. 53:lGA-10(d). Please be advised that each cf you are :ointly and severably responsible for the submission and other require.ments of this .Administrative Order. However, e^cn. of you .may cocperate ir.c. suomit a combined response, at your discretion. fOOSM ^fx ]«r%e\- h An Equal Opportunity Employ er If you have any questions concerning this Order, contact Mr. Joseph M. Mikulka, Chief of the Bureau of Regional Enforcement, 1259 Route 46 - Building 2, Parsippany-Troy Hills, New Jersey 07054 or by telephoning (201) 299-7592. Very truly yours, ?ohn w. Gaston, Jr., P.E. Director i, zc: Dr. Ronald Cohen, Middlebrook Regional Health Commission l George Schiosser, Office of Regulatory Services 'i Ken Siet, Bureau of Ground Water Discharge Permits Joel Gol'umbek, USEPA, Region II ^ .V 100881 *talr uf ^'nu .iJrriirii DEPARTMENT OF ENVIRONMENTAL PROTECTION DIVISION OF WATER RESOURCES CN 039 rneNTON. Ncw jcRsev OMSS JOHN W. GASTON JR.. '.6. OIRK C. NORMAN. » 6 0IR6CT0R Oe^UTY OIRECTQR IN THE MATTER OF .«•.•..•••.»..••*••••*••«....«.. ADMINISTRATIVE ORDER * NATIONAL METAL ' AND NOTICE OF CIVIL ADMINISTRATIVE FINISHING CORPORATION • PENALTY ASSESSMENT • AND BROOK INDUSTRIAL PARK The following FINDINGS are made and ORDER and NOTICE is issued pursuant to the authority vested in the Commissioner of the New Jersey Department of Environmental Protection (NJDEP) by N.J.S.A. 13;1D-I et seq., the New Jersey Water Pollution Control Act, N.J.S.A. 58:10A-i et seq., and the Solid Waste Management Act, N.J.S.A. 13:iE-l et seq., and duly delegated to the Director of the Division of Water Resources pursuant to N.J.S.A. 13:13-4.. FINDINGS 1. Brook Industrial Park, a partnership between Mr. Richard C. Schleck and Mr. S. James Frascella, (who died intestate on' July 26, 1980), owns the Brook Industrial Park facility, located 100 West Main Street, Bou.nd Brook, (Block 1, Lot 34 cf the Borough of Bound Brook Tax Map), Somerset County, State of New Jersey (hereinafter "the facility"). Mrs. Mary Frascella, 'wife of the deceased, Mr. S. Ja.mes Frascella, is present..y the Administratix of Mr. Frascella's estate. 2. National Metal Finishings Corporation, a New Jersey corpora tion, is a tenant at the facility identified in paragraph 1. J. On Mayl4, 1981, a representative cf NJDEP inspected the premises of National Metal Finishings.Corporation. The results of the inspection are summarized below: a. Inside National Metal Finishings Corporation mam operations building a representative of NJDEP observed two pits which were approximately 10 feet Long, five feet Wide, and ten feet aeep. Although the pits appeared to be made of cinder blocks, Mr. Joseph Conrad, President of National Metal Finishings V<'H Jenev Is .An Equal Opportunity Ernplnver j . I .1.0.02:08 corporation, did not know the construction details cf the pita. b. A .hrorae plating unit described in paragraph . . above was situated within one of the pits (Pit tl). A metal screen covered the remaining area of tne pit, A chrome plating unit rested upon a metal screen which entirely covered the second pit (Pit f2). Pit i»l contained approximately 5 1/2 feet of a viscous brown sludge which floated upon a oily yellow brown liquid. c. Mr. Conrad indicated that the liquid in Pit iH consist ed of the wastes generated from metal grinding, polish ing and cleaning operations. He also indicated that these waste liquids are nor hauled off-site .wich..waste manifests, but are simply d.isrharged into the pit and rhae this mt^rnnei nf wagro disrosal had been used for- apprnvimaroly i-on LliU yeaxS , d.. Nation^l_ Metal J'inijfhings j:prporation did_.no'C possess. ^_ valid New' Jersey'Pollutant Discharge Elimination System (NJPDE5)" ipermit ""for" this discharge into the pit as required by the Regulations Concerning the New Jersey Pollution Discharge Elimination System, N.J.A.C, 7:14A-1.1 et seq. In addition National Metal Finishr- inqs Corporation did not nnr^fY rhm Unirart <;rarttg Fnvironmengal Protgction Agency nf 'hin disehargti, as required by Section 3010 of the Federal Resource Conservation and Recovery Act, (42 U.S.C. 3251 et seq.) 4. On September 4, 1981 and December 15, 1981, a representative of NJDEP determines that Pit $1 contained approximately 5.5 ;• feet of an oily brown liquid. A brown sludge floated upon I the Oily liquid. Reinspections on January 5, 1982 and April 15, 1982 revealed that the pit contained approxi.mately 7 J, feet of liquid and 4.7 feet of liquid respectively. Mr. I Conrad i.ndicated on January 5, 1982 that none of the liquid '^' in the pit had ever been disposed of at an off-site location and he could not explain the reason for the fluctuations of the liquid's depth in the pit. 5. On September 4, 1981, December 15, 1931, January 5, 1932, ; April 15, 1982 and May il, 1982, representatives of NJDEP collected samples from the liquid within Pit «1. The analytical r.gj.ults indicated the presence of toluene, J lOiHTtt the August 9, 1984 letter (such a removal of contamination from Che pit, implementation of a hydrogeologic study, and the suianittal of a NJPDES permit for the proper closure of the pit), and requested additior-I clarification from NJDEP. 15. On October Jl, ,1984, NJDEP sent National Metal Finishings Corporation a letter clarifying the required remedial actions, a.s requested. The letter directed National'Metal Finisnings Corporation, among other items, to (1) submit a NJPDES permit for the proper closure of the pit and to (2) submit a proposal for a hydrogeologic study with implementa tion dates, to NJDEP for approval. 16, 'Zn a letter dated November 13, 1984, Mr. Conrad, responded to NJDEP's letter of October 31, 1984. The response was unsatisfactory to NJDEP because National Metal Finishings Corporation submitted neither the required application to obtain an NJPDES permit nor the required proposal for a hydrogeologic study. 1; 17. The discharging of pollutants into the ground waters of the ''' State, or onto land from which t.hey might flow or drain into t.he ground waters of the State in a manner not in conformity I'' With a valid NJPDES permit, is a violation of the New Jersey ^'' Water Pollution Control Act, N.J.S.A. 58:10A-1 et seq., specifically, N.J.S.A. 5a:10A-6, and the Regulations concer ning the New Jersey Pollutant Discharge Elimination system, N.J.A.C. 7:14A-1.1 et seq., specifically, N.J.A.C. 7:14A-I.2(c). Furthermore, the operation of an existing hazardous waste facility without notifying, by August 18, •1980, the United States Environmental Protection Agency as f! required by Section 3010 of the Federal Resource Conserva tion and Recovery Act (42 U.S.C. 3251 et seq.) and without tiling a Part A application for t.he facility in accordance With 40 CFR 122.22(a) and (o is a violation of N.J.S.A. i3:lE-l et seq., specifically, N.J.S.A. 13:lE-5 and N.J.A.C. 7:26-12.3. ORDER .NOW THEREFORE IT IS HEREBY ORDERED THAT NATIONAL .METAL FINISHINGS CORPORATION AND BROOK INDUSTRIAL PARK SHALL: iS. Within ten (10) days of receipt of this Order, provide information to NJDEP concerning the current metnod or disposal of waste formerly discharged into tne pit, as well a's documentation that the disposal satisfies ail applicaole State and Federal regulations. 19. Within thirty {iO) days of receipt of this Order sucmit the following: t »»,• 1 I * (a) A completed New Jersey Pollutant Discharge Elimination System (NJPDES) permit application pursuant to N.J.A.C. 7:14A-1 et seq. This permit application shall include a closure plan for the waste dispc. ->i pits prepared m •accordance with the requirements of N.J.A.C. 7:l4A-i et seq., specifically, suochapter 4 and N.J.A.C. 7:26-1 et seq., specifically, subchapter 12.3 and 11.3 (b) A Part A application pursuant to N.J.A.C. 7:26-12. Submit t.he applications to: Office of Permits Admini.stration Water Quality Management Element Division of Water Resources CN-029 Trenton, New Jersey 08625 and John Trela, Chief Bureau of Ground Water Discharge Permits Division of Water Resources CN-029 Trenton,. New Jersey .08625 20. Within thirty (30) days of receipt of this Order, submit to . NJDEP for its review and approval, a detailed work plan, including an implementation schedule and cost estimate, to .conduct a hydrogeologic investigation at and in the vicinity of the facility, and to develop a remedial action plan. The .work plan shall be-based upon the Scope of Work set forth in Appendix B, which is attached hereto and incorporated herein by reference. The work plan shall be prepared for National Metal Fmishmgs Corporation and Brook Industrial Park and shall ce i.'npleraented by a qualified consultant acceptable to NJDEP. Within fifteen (13) days of receipt of NJDEP's comments on the work plan, modify the plan as necessary to conform with NJDEP's comments a.nd submit t.-.e modified work plan to NJDEP for its approval. 21. Within thirty (30) days from receipt of NJDEP's final approval of the work plan, implement the approved work plan - in accordance with the approved imple.mentaticn schedule. Within thirty (30) days of completion of the investigation, submit a report, pursuant to the approved work plan, detail ing the results of the hydrogeologic investigation and proposing a re.medial action plan to NJDEP for its review and approval. 22. Within fifteen -IS) days of receipt of NJDEP's comments and recommendaticn- jf the report, (which includes the proposed remedial plan), modify the report as necessary to conform with the'comments and recommendations, and submit the modified report to NJDEP for its removal. 23. Within thirty (30) days of receipt of NJDEP's ap(...ov«.. of the modified report required in paragraph 23, implement the approved remedial plan in accordance with the approved implementation schedule, within thirty (30) days from completion of all work required by the approved remedial plan, submit to the NJDEP a Final Report. This Final Report shall summarize all remedial work conducted at the sice and shall recommend any future remedial actions which may be necessary at che site. 24. Give NJDEP at least two weeks'prior notice of any work conducted pursuant to this Order so chat an NJDEP represent ative may be present during an on-site investigation or i: cleanup. 25. Provide NJDEP with monthly progress reports prepared by che qualified consultant, detailing the status of compliance with this Order, and shall include: (a) Identification of site and activity; (b) Status of work at the site and progress to date, including all data and field observations; (c) Percent of completion (e.g., percent of estimated, total work hours expended); (d) Difficulties encountered during-the reporting period; (e) Actions being taken to rectify problems; if) Activities planned for the next month; (g; List target and actual completion dates for eacn ele.ment of activity; (h) Provide an explanation of any deviation from the approved work plan scheaule. NOTICE OF CIVIL ADMINISTRATIVE PENALriT ASSESSMENT 26. Based upon the above FINDINGS, NJDEP has determined that a Civil Administrative-' Penalty should be assessed against National Metal Finishings Corporation and Brook Industrial Park, pursuant to N.J.S.A. 58:10A-10(d) and N.J.A.C. 7:14-8.1 et seq. 27. Based upon a review of the criteria contained in N.J.A.C. 7:14-8.1 et seq., NJDEP has determined that the amount of j'^'iiioiU the penalty should be set at $5,000.00. Payment must be made to NJDEP at the following address: ^ Joseph M. Mikulka, Chief Northern Bureau of Regional Enforcement Division ot Water Resources 1259 Route 46 - Building 2 Parsippany-Troy Hills, NJ 07054 28. Any submission of information required by this ORDER and •NOTICE (except for paragraphs 19 and 27) shall be made to Joseph M. Mikulka at the same address in paragraph 27 and: John Trela. Chief Bureau c: Ground Water Discharge Permits Division of water Resources i CN-029 ' Trenton, New Jersey 08625 ^' 29. NOTICE IS HEREBY GIVEN that pursuant to N.J.S.A. 52:143-1 et i. seq. and N.J.S.A. 5a:10A-10(b) and (d). National Metal Finishings Corporation ana Brook Industrial Park is entitled to a hearing before NJDEP. Any hearing request must be delivered to the person and address listed in the preceding paragraph within twenty (20) calendar days from receipt of this ORDER and NOTICE. A hearing request does not stay the terms or effect of this ORDER. 30. NOTICE IS FURTHER GIVEN that pursuant to N.J,S,A. 52:14B-9(b) and N.J.A.C. 1:1-5.Kb), the applicant in its application for a hearing shall furnish NJDEP with the following: (a) A statement of the legal autnority and jurisdiction u.nder wnich the hearing or action to be held is re quested pursuant to N.J.A.C. 1:1-5.1(b)(1) ; H • (b) A reference to the particular sections of the statutes and rules involved; (c) A short and plain statement of the matters of fact and law asserted; and (d) The Order provisions to which the applicant objects, the reasons for such obiections, and any alternative provisions proposed by the applicant. 31. The provisions of this Administrative Order and Penalty Assessment shall be binding on National Metal Finishings Corporation and Srook Industrial Park, its principals, agents, employees, successors, assigns, tenants and any trustee in bankruptcy or receiver appointed pursuant to a proceeding in law or equity. :'S: 32. No obligations imposed by chis ADMINISTRATIVE ORDER- AND PENALTY'ASSESSMENT (with the exception of paragraph 27), are intended to constitute a debt, damage claim, penalty or other civil action which should be limited or discharged m a bankruptcy proceeding. All obligations imposed by this ORDER shall constitute continuing regulatory obligations i.mposed pursuant co tne police powers of the State of New Jersey, intended to protect the public health, safety and welfare. 33. NOTICE IS FURTHER GIVEN that if no request for a hearing is received within twency (20) calendar days, this NOTICE shall become a final ORDER and the penalty would become due and payable. 34. NOTICE IS FURTHER GIVEN that pursuant to N.J.S.A. 58:lOA-lO(d), NJDEP is authorized to assess a Civil Adminis trative Penalty of S5,000 for each violation, and additional penalties of up to S500 for each day during which such violation continues after receipt of an Administrative Order • from NJDEP. / J5. NOTICE. IS FURTHER GIVEN that pursuant to N.J.S.A. 58:lOA-10(ej, any person who violates this Administrative Order, (or who fails to pay an Administrative Penalty in full) shall be subject to civil penalties of up to-$10,000 per day fpr eacn day of violation.. 36. NOTICE IS FURTHER GIVEN that pursuant to N.J.S.A. 58:lOA-10(f), any person who willfully or negligently •Violates N.J.S.A. 5a:10A-i et seq., shall, upon conviction, oe guilty of a misde.meanor and shall be punished by fine of not less than i2,500 nor more than $25,000 per day of • violation, or by imprisonment for not more than one (1) year or-by both. ^/i^-'-^WlM JOfiN W. GASTON, JR., ?.£. DIRECTOR DIVISION CF WATER RESOURCES 100^^ I.i APPENDIX A 100217 f..tm VST-OIO STATE OP NEW JERSEY a ^OC affi '. Oeo»rim«o» ot envianmtntu Protecnon 9ACT. i,Aa NO. PLlUSETYPtORPRIiNT Oivilion oi W4ltr RvMurctt WITH BAJLPOIMT PEN WATER ANALYSIS OATC BEC-O iSuSZiPAUTV COUNTY STRCAM •«vo.^^g^ <;g r- BOTTLE NO,' ' c522^Jp OATC SECO ItStNTATiVE riTce iCOciCOCUu NAMNAME ^ •^<-f-vn>;>V ACUAArfS SToneT ENT. ..CvJ^i^fAJC'-H'SH OEAO STATION (OE.STIFICATION iVWffl ER t M YR. .MO. OAT HOUR w ? £ sc.l 1 J m\d\?\ow\ i/^^Q.i . : , FIELD ANALYSIS ANALYSIS UNITS PARA.METE11 VALUE RMKS. • O *»*t»r T«mo "c "IS. j^pi- p . ^.Q O.O.-WlnhMr ^00 a p •~fJ^ 3 O.0.-Proo« • PJM p (Pi«iat MOO . cir'o\ y^\et^ Stttion laantif icjtrafi Numo«r YR. MO. OAY HOUR Swnoi* No S c p • , ' Bl 0^/Q^- il- 3 1 ' FIELD ANALYSIS SACTERIOLOCICAL - DILUTIONS (REOUESTEDI Q CyanMo POO7S0. Paeal Colilorm . 1 -1 TT .* -« - a Total Conform • a t 10 (0 10 •« 10 •0 Q W«f«r T«mo "C POOOtO, D MBAS P3«3«a. . t .1 -• • a .% -a Paeal Scraotoeecei P33730. Q O.O. • Winklar P00300, 10 ' •a la i« ta 10 10 D PHanolt fotrolownt P4SSai. Q O.O. • ProD* • P00399. • Hydr P«=..co.i S"'** '•3'•"• #100 ml tJ*^' '31B13. MIn. Ac««(y P0043*. Qp*^ P00400, • at C4Ca 3 • AlKallniry P00410. O Samel* 0«a(n- 0 Salinity °/00 Pa0480, BIOCHEMICAL OXYGEN DEMAND TS^At • tot uVI P0IO02< INITIAL 0.0. (lao.l SAMPLE Q TMa Siaga P00067 Q Cr • has. u«/l P0t032. |—I vwaaihar SEED res (3 xP Q 0 P00041, /,/ ^ Conditioni "^ r CONC.% ^B Cr • lat uo/l P0I(M4." F CONDITION COOES ^ H« • tOI u«/l P719O0./(^> SOC1 y3kPB - tot UO/I ' P010S1, Q Flow Savarii P013S1, /^ D aooj P00310, ^F* - tot U9/I P0104S, .Savaritv P013 ^ r*^ ^ --<. •.\: O Mn . tot UO/I P0105S, . Savaritv P013 O Low LPval P33S, t/ '^°° D Hifln Ltval P340, 5i2n • tot uj/t P0t092, D .Savaritv P013 -r-r ^Cu • tot uo/l POI04J, OTOC poo«>a. ^ Cd - tot us/1 P01027, "*=a NOj .N P00B15, "^Ni . tot U9/1 P01087, 0 NOj * NO3 • N pooa30. Q Color Pt . Cou P00080, AOOITIONAL ANALYSIS Q NM3-N POOS 10. O Turoidity POOOTO, C Tot iCialdhal N P0062S, O Sutoandad Soi>.^, P0O530. a S-'^-'O'O Soi.d. ,,o5^o_ S O'lfo • PO4 at O PS71, ;a A^u/>ry//:.7/iqpp/- *"''04 QPSBO. O Tot. Solids POOSOO, C] Tot. Soiidt ''"ai^ P00510, a ' p DPSSS. P«otorioru« lot at ,Q Q^gjo^ n I"©!. 0'«iotvad '-' Soi.oi (TOSI P'0300, RESULTS mfi/L unlttt othtrvriia noted CHAtNOP CUSTOOV Oata TIma REPORT .^5^J8M^^TE: NOV fi mj—'- • '«'»l n«v.«v Form VST.QOt STATE OF Wew JERSEY 1^ 8/79- 0«» PLEASE TYPE OP PPINT , watrr Analysis 9ACT L*S NO WITH BALLPOINT PCM 0*re «6C 3 MUBStC I**!.!' • irae•• S/^fi-ggp-T- i|. 11- B^jin &iS,cxin. BOTTLE "O. CI 1 SI J3mIiJ. '• r^M£mLlliMii£S..•.OCariO M Loesr t4fi)f4 'hrfihtsT • C**CSt* Siati on OaMiif FIELD ANALYSIS BACTERIOLOGICAL - OlliUTIONS IREQUESTEOI ^JTB*^ (L>ai ROOtOO. Pacal Coliform - » -4 ^ ( / • • Alluilnlty Total Coliform I« , •« ' O Watar Tama 'c POOOIO, •« 0 at CaCO] POOtlO. * 1 * a -4 - s Pacal Straotoeorci -• __ MIn. AcMlty - O O.O. - Winklar ^0)00, tff t •0 10 CJ at CaCO] P«04)t. '• O 0.0. • Prooa P00111, • Cniorlda R00«4«. Pacaicoli g"'" '3.BIS. #100 ml tJMP P31B13. O P** (Plaidl P00400. Q MBAS P1IJ«0. Samoia Oaein-H. ;-; -PJOOOl, • Pacal Straot Q Ptianolt PJIJIO. P3t677. SIraam POOSd, "'"*/100ml _- Hardrwtt • lot • Pioo-CFS I—1 at CaCoj P00130, .' j'' O C<«a Ha>ani.lt ..A0«O4S , P0014S. Tof col • Sulfata P3IS0S. n Soac. ConO. MPN /too ml ?9Pau. O Oil * Qraata ^ots*. Q Sal-nxv °'00 PS0410, BIOCHEMICAL OXYGEN OEMANO f.. Patrofaum LJ Hydrocareont P4S50I. iNirjAL 0 0. IIJC I SAMPLE 1 U Tida S«9a P)02I 1, • Cyanida POOJJO. SEED vtj f • «o t' ' CONDITION COOES CONC.«. • At -tot u«/t P0I0O2 waacaf • Conoltloni P00S4I, O CO -tot uf/1 poiatr 000 _ Q Plow Savaritv POIISI. ncr-iotu«/i POiaj* 0 BOO as.oAv pjio. P013 D t-OAV PI I 2. • Cu - lot u«/1 P010<2, P013 • Pt - tot u«/i Poia«s, O Lov. Laval P33S, *" D M.gn Laval P3«0, • Mfl . tot U9/1 P7H00 NUTRIENTS LEVEL O MIGM O LOW O Mn • lot U4/I PO t 0 i S TOC •TTTrr X.' pooBia 5'S • NI .tot UO/1 P910« J. Q NOj • N P0061S. D NOj • NO3 • N P00«30, O Color Pt . Cou POOOSO. • PB • lot ««/1 ROUS I • I i 11 I a In .tot u«/1 POiat? G NMj N pao«io, n TuJOiOitv ^00070. . \ m AOOITIONAL ANALYSIS 0 Ta< <,aianai N POOSJS, Q Stito'xoad Sai'di POOS 30, Q Sw.oanoao Soi.oi POQS^Q P. fi««d a. Orm-.^O...' S'«"- 'O* a P860, Q Toi. Solid! POOSOO. » OP6«S, G Toi Sal>at l.aad POQSIO, '•"owno'ut 10c <• ,g^ CP6S0. rn Tot Oi««otw«d Soi.a» ITOSI P'O300. RESULTS m«;L unlaii otnar—va noiad CHAIN p^ CuSTQOv l>..—..: «»,..« Part 1. I i.Cltt8ft2i.M*WlKI&t January 22, 1932 NJDEP Sol id Waste Division 32 Hanover Street Trenton, NJ 08625 Attention: Mr. Wayne Howitz, Hazardous Waste Bureau Reference: Test Report No. SR6392 This report covers the analysis of two (2) liquid samples submitted to Stablex-Reutter, Inc. (S-R) on December 18, 1981. The samples were submitted for the following analyses: . Organics - Volatile Arornatic Hydrocarbons - Volatile Halogenated Hydrocarbons a Inorganics - - • - Metals (£? Procedure) This test report is organized in the following manner: "^ Sample Preparation - Analysis - Analytical Results I. Sample Preparation Organic Preparatory Uor'< A known weight (l.QO grams * 0.05 grams) of liomogenized sample is quantitatively transferred To a centrifuge tube and shaken vigorously . with 10 ml of pesticide grade methanol for five minutes. The mixture is allowed to separate, and is then centrifuged to facilitate sep aration of the two phases. An aliquot of the methanol layer is then analyzed by Gas Chromatography for volatile halogenated orgjnics and volatile aromdtic compounds. Any requii'sd dilutions are done with pesticide grade :/.c-tiiunol. The samples were also analyzed by static headspace techniques, in ;which:1.00 + 0.05 grams of sample is transferred to a 60 ml vial, and the vial" is crimped air tight with a rubber septum. The vials are heated to 60^0 for 30 minutes before injecting 5cc of the headspace '-Z.. Into *.!•'' '"•'" 'T'" en.ilvsis. too^ gv--:i.jie::-i^2Utt3r Ihc. .^S NJDEP Solid Waste Division Test Report No. SR5392 January 22, 1982 Page 2 of 4 Inorganic Analysis The EP extraction procedure was not performed for reasons described in the analytical results section. II. Analysis =-"' Following preparation, the samples were analyzed as described ll. in the foUowip" publication. . . Methods 501, 502 Federal Register,-Vol. 44, Ho. 233, December 3. 1979. (Columns and GC conditions for ••.._ . . aromatics and volatile halogenated organics). . EPA Test Methods for Evaluating Solid Waste - Physical/ Chemical Methods - Swa46-1920 (AAS conditions). The volatile Halogenated Organics were analyzed on the Hall Electrolytic Conductivity Detector. The aromatics were analyzed using a Photoionization Detector. III. Analytical Results The parameters analyzed and results are delineated in the following tables. The interlaboratory variability of the parameters analyzed in the type of sample matrix submitted has not been established by EPA, and could be at least _+ 202. S-R is currently evaluating the variability of all tests performed for NJDEP in different types of matrices. Volatile Aromatic Hydrocarbon Screen Samole and 0 esigna t ion SR6392-1 SR53 92-2 SR5392-1 Dup Constituent CE059 CEG7 0 CE069 Duo. Benzene < 1 <1 < 1 Toluene < I All results ire in microgr.ims of constitiient per gram of sample. 'DUO. - '•• too^ ^ ^bis::-?ceiitter Inc. •^ • • NJDEP Solid Waste Division Test Report No,, SR6392 Ja.iuary 22. 1982 Page 3 of 4 Volatile Halogenated Hydrocarbon Screen Sample and Designation X 1Recover y of spike SR6392-1 SR6392-2 SR6392-1 Dup. to sample run with Constituent CE069 CE070 CE069 Dup. these samples Vinyl Chloride* <1 <1 <1 .-- Methylene Chloride^ <1 <1 <1 91 Chloroform <1 <1 <1 111 Carbon Tetrachloride <1 <1. <1 ... Dibromochloromethane <1 <] <1 116 Sromodichloromethane <1 <1 <1 106 • 1.1.1 Trichloroethane <1 <1 <1 113 1.1.2 Trichloroethane <1 . <1 <1 --- Trichloroethylene <1 <1 <1 114 Tetrachloroethylene <1 <1 <1 127 1,2 Oichloroethane <1 <1 <1 . 95 1,1 Oichloroethylene <1 <1 <1 ._- 1,1 Oichloroethane <1 <1 ... <.|. 102 1,2-Oichloropropane <1 <1 <1 97 2-Chloroethylvinyl Ether <1 <1 <1 — Bromoform <1 <1 <1 • 120 1,1,2,2-Tetrachloroethane <1 •<1 <1 ... Chlorobenzene <1 <1 <1 65 All results are in micrograms of constituent per gram of sample. Dup. - Duplicate Analysis loom rijDEP • . . Sol id Waste Division Test Report No. SR6392 January ll, 198? Page 4 of 4 •EPA-EP Extraction Meta 1 Analysis Sample and Designation SR6392-1 SR6392-2 SR6392-1 Dup. EP Toxicity Const itueiI t CE059 CE070 - CE069 Duo. Limit Arsenic" <0.002 0.029 < 0.002 5.0 Barium ft - <0.1 < 0.1 < 0.1 100.0 Cadmium <0.1 <0.1 < 0.1 1.0 Chromium, total 20 32 19 5.0 Lead <.0.5 0.50 < 0.5 5.0 Mercury 0.029 <0.Q2 0.033 0.2 Selenium , <0.0« < 0.04 < 0.04 1.0 • Si Iver 0.50 <0.05 0.30 5.0 Nickel <0.5 <0.5 < 0.5 ... Chromium, hexavalent — ' 10 — — All results are in micrograms of constituent per gram of.sample. The EPA Extraction Procedure {19) as it appears in the.May 19, 19S0 edition of the "Federal Register" does not clearly define the extraction of liquid samples that iro, not filterable under the conditions of this test, such as oil or liquid hydrocarbon matrices. The Hazardous Waste Management Division of the EPA in Washington, O.C. was consulted to determine how the EPA Extraction Procedure should be applied to this type of waste. Upon recommendation of the EPA, the sample, as received, was treated as the EP extract. , If you have any questions concerning the above analysis, please don't hesitate to contact me. Respectfully submitted, STA5LEX-REUTTES. I,NC. Wi 1 1 i Jin J. Z ic-q ler Laboratory Manager l.'JZ/sl 100894 ^ Form VST-OOI STATE OF NEW JERSEY Ceo 7/81 • Oopanmvnt oi Environmvnial Prottction ' PLEASE TVP6 on P«IHT wat«f An« lysis 8ACT L*i NO • ITM BALLPOINT PCM OATE nfC'O -"-=p;v,;7, fitf.^r' "-'^^^/=y?^Fr itacait ? ' .aOTTLE NO. //5V if- 'Ki'a''fiei.:'\ L, adC TAL fti^rti//*// c-*='"'"' kiA,^ <>T(?e£-r klP'^CSCMtar •«( nr^t . 9|»I£ aec 3 =^^^^--,'«- ' =?fc4'l • .c-a-.» CuA'iTT'r f5/.SA><;A» p iT f .J^',:,yJ (.v4 Ahi ENT STO-«T «£A0 »-. OlV WA ; .• ,v JLS_J^ ^ Station Idantit leatlon Numear yn. MO. OAV HOUM Sameia No. s C J < MdilM Q 00 (U ' • , FIELO ANALYSIS BACTERIOLOGICAL - CMLUTtOMS IRCOUESTEOI Oe" (UABI (]l| P004*). Paeal Celi'arm * 1 -1 -1 -• • t - a Alkalinity Total Collfornv •a 1 • « -1 *a Pacal Straotococei MIn. AcMlty D O.O. • WlMtlara ) P«OJ««, *a • •0 •a to la •a IO • aaCaCoj (411 POOaK, Q O.O. • ProM (4>P002««. Pa«a.«.li a-'^UMPlUIS. ^fcniOTMo (4}) Pa««40. •lOOml ^"^ (ISIPIUIJ. O P** (Plaldl. •00400, n MBAS (41) PltKO. Sameia • Oaain. aSi'S't.tt. ujwoooi. S7Sulfata (4() P«0t4S. r~l Seae. Cond. OLVJ"" «7)PJ1J0J, 11 /IOO ml '-' "H'C (SlPOOOtS, Ooil »Or«aia(t7) PDOSK. —, PotrMaum . O Salinity °/00 (11 )Pa04 10. BIOCHEMICAL OXYGEN OEMANO U HyaracwDoni(41iP«SS01. INITIAL 0.0. (laO.l SAMPLE O T:da Staga (tl)PT0211, Qcytnido (41) PDe7I0. SEED "ts ['.1 NO LU CONDITION COOES CONC.K ^A. •tatu«/t (S0)PDI002. 1 waainar • 55 ca -tatu«/l (Sl)m027, Conoillont (t2|Pa004t, aoo_ L D Plow Savarity (1 ]) P« 11S1. 'lot u«/i (S2)P0t0)4 a BOO S-OAV(2|lPJlo. xl D Savaritv (J4) P013_ . «OAy(j»iPjij. Dcu •teiui/l(Sl)P01«t2 O Savarity (1S)P013_. • P. - lot u«/1 (S4)P0104S, (10 1 P] 40. a coo SJH, •lot u«/t(}I)P7M00, NUTRIENTS LEVEL O HIGH O LOW 1^ Mn -tot u«/l(S()POIOS$ a TOC (II) poodo ^Nl •tot utA (S7)PfllO«7 .a NOJ N (it)Paa(ii • tot uo/l (Si)Poiasi a NO] • NO3 • N (17)P00(J0, Q Color Pt . Cow (l'l|P«OOtO, s G Zn •tot uo/1(5«)P«10»7j DNMJ.N ai)'^o«io, O Turo.o.tv CJIPOOOT*. AOOITIONAL ANALYSIS Q Tot. Klaidani N (it)P«a(lS. D Suioanoao Soiidi(]4 )POOJ]0, n Sutoandad Soiid«(] S )PO0S4 0 , X 0] 3 . U Ortno • \ A»n p_ P O (20) P70507. « "po, D «n poo««o. D Tot. Soi.dt (3IIPO0JOO. O. 1 Pnofonorut* • Tot Soitdt • A.n (J71PO0JI0. . , p D (J:) pofl««s. a. """po« O (jii ptio«so. n ^ot Oiitol.ao (3I)P70]00. ^SoiidilTOSt a. ^— S*«.ipt« wj»U CyLCtiA^ k-tokii.'^O -H*»% Ptrt t (WhinI • Wtnr QuiUtv Inrtntory CoffY _ _H Environmentcl Pirt 2 (Csnanrl • Lttorttorf Caev TColOtnroat • fi*i r<«^11^Laboraiorv 100?2SI «orm VSTOIO 1 t CJOC STATE OP NEW JERSEY 8/79 Oaoartmant ol Envtronfnantal Protactton PLEASE TYPE OR PRINT Oivition of Wattr Ratourcet WITH DALLPOI.IT re^ WATER ANALYSIS MUN(CIPAI.lTY - .. _ , y STREAM scxTiwr WWc OATE aec-Q. zsztrrxTTTt—^"^ •' jnrcr COLL NAME neuARRS STORET U'/i STe. -enL C ^N rV / K/A-f^ A '^1 PEAO -7t* STATION IDENTIFICATION NUMBER YR. MO. DAY "ifeuR -scf J . g3.^o5 f 0\ob\. Ill 1 nELD ANALY3I3- ANALYSIS UNITS PAltAM£TEJl VALUE RMKi a Watar Ta«nB *C ' Ptfl. p ^^MmiiA .1 O O.O.-WlnhMr PJOO. a p Go.O..PreM Pitt, a p Oo" (Plaid) P400. a p a SamB4«^4otn..ti"'^f," " g p g p p O Salinity 7/00 ,, ..>>4(0. g p P TIda Slaoa P70211 a n p • BACTERIOLOGICAL- DILUTIONS (REQUESTED) Q p Pacal Conform -1 -2 .3 • 4 • s • 6 p Total Conform 10 1 10 10 10 10 10 10 • Pacal • 1 - 2 •3 • 4 • s • 6 g p Straotococei 10 1 10 10 10 10 10 10 a p g p g . P! 1 T • . 'M'". n'•*•'Siraot »..,,. '^-'-'MPN ... P1U77. p\ o».nii g 1 g p Tot eo«l 1 PllSOS, p /too mi 1 g. p ;'K ,.; 8I0CHE.MICALOXYGEN DEMAND p f J'; •. INITIAL O.O. (148.) SAMPLE g_ 1 r^'.' SEEO VES • NOQ g p . 1 1 CONC. p ,1 i • p aoo g. g_ p __, , 1 G aoo QSOAV PllO. Qt-OAY PJW. g p CHAIN OF CUSTODY OATE TIME PROM (NAME) REPORT SUaMlTltu (liZ^mi. ^^^^ CKamiit Rtviav Part I •'%B^PBBB»"°'Y Copy Part 3 -Watar Ratowreot Coov(For Trinimiit" Part 2 Part 4 ' Bacitf loioqv Coov form VS'i OOt STATE OP NCW JERSEY CHAIN OF CUSTCOV 7/81 O«oartm*nt ol environmental Protection PLCASe type OR PrtlNT W4(«r Analftis SACr. L*« NO _^ WITH BALLPOINT PEN lTPC*«t OATf mc-o T"'' <^cy\p.9.ss.Xl 80TTLE NO. I ' '.^ Y' 'Z t^frfl'^^V tA>n-AL PifJt5k-r^'L QC»Jl ion KA/^; ST/fSeT" >.C>-- Sucion l4«n<*'«ca<*OM Numo«f YR. MO. OAV HOUR Trrrr Samoia No. s c < • €^o^ I I 0 15 (1) ' • . FIELD ANALYSIS BACTERIOLOGICAL - 04LUTIONS (RfQUCSTEOI a»** (LAB) (It) RM4 0I. Paeal Coliform -1 -tj-t AiKiltfUCy Total Conform , •a 1 M ~ *• Ga«C«CO] (40) P00«10, -i •4 .J.. MIn. Adaity O O.O. - WlA«ter O O.O. • Prooa (4')P0t2tt. Paca.'.«. aMPN(„,P,„„, GCMortM («XI Pt*«4«. «ioami CJ"' (2i)PJUii a P" (Plaldt. (S»P«04»0, • MSAS (411 PIIK*. Oa«in. a Si«5»t.*t, («iwo««i. G Sulfata (4() P00t4S. (27|PltSO$. n Seae. Cond. •^"•/lOOml " •2»"C (1)P«00tS. GOll *araaM(4 7) POOtSC. Patroloum ^. . O Salinity ^/oa(l«|P904IO. BIOCHEMICAL OXYGEN OEMANO Q INITIAL 0.0. (IJO.I SAMPLE Hydra«jr»a«a<4«| P«SS«I. QTidaStaaa (ll)P'«211, Gcv*n«a« (4,, P0«72«. SEED vts [ _; "O L'.J CONOirtON COOES ONC.^i (5CA.. totut/i (somtti. Waatnar • Conoilloni (]2) P00041, totuMA (Sl)Ptlt27 000 _ 0 Plow Savarity (11) POllSl. ^Cr. tatu«/i (S2)P0I«I4 a aoo $ (15) POO GFa- totu«/1 (S4|P«1041 Gcoo (10) P140. GM^' iatu«/l(SS)P7it«0, NUTRIENTS — LEVEL Q MIGM O UOW G Mn ' tot u«/l(S()P9lots QTOC (IO POOIIO, ^Nl. Q NO2.N a<)p«9 "^arr t IWttittI • Wtnr Quality Intntory COPY Ptn 2 ICtntryi • Lteornonr Cot/r •^"^WrF^ lCal FIELD ANALYSIS ANALYSIS UNITS PARAMETER VALUE RMKS. G Watar Tamo 'c ' PlO. . \%\IO. 3C^VNi Of?!-) P 1 } * I G O.O.-winfctar PIOO. g H 1P 1 * Go.O..Prooa Pitt. 1 Q c^lo<^«M P Ge^ (Plaid) P«00. P A•HA G Sameia Oaotn-rt. P], P G Caoa Malfnt-ft. PIS, 1 11 g • Seae. Cono. g P P G Salinity'/OO P4t0. g P GTIdaSUfa .PT021 1- g g P BACTERIOLOGICAL • DILUTIONS (REgCESTED) g P Pacal Conform 1 - * -2 -3 .4 •5 1-6 1 Total Conform 10 1 10 10 10 10 10| 10 1 g P Paeii 1 - ' • 2 •3 .4 -S 1-6 1 g P SiraotececcI 10 1 10 10 10 to 10| 10 1 g P B...... DMPN PlUll. 1 g P 1 g P| i Q Paeal straot „„„. 1 P "^""/lOO mi L 1 1 a g PI r-i Tot eoti •.,.«. 1 ^ UMPN ... PllJOI. I P T •^ /IOO mi L g P BIOCHEMICAL OXYGEN DEMAiN D |g P « 1 SAMPI-E n SEED YEr s G NoCD g Pi 1 1 CONC* g Pj 1 1 aoo g P g P i 1 Gaoo Gs-OAVPiio.! 1 G»-OAv piw. [ i 1 1 1 1g P| 1 CHAIN OF CUSTODY 1— o<\ T E Tl ^<«e PROM (NAME) •la-, ;:;. 1 : if •.,11 EP V ?lj ^ •« 1 ; It D •JUN Z 8 193; 4M^|- JMJUUM ^.nvi-c.--,n'.^-pf~ JtiyiMfcJ-.' '.?-'^V ''r.-v t - • / Cnamlit Ri.ia.. Ptrt I .Watar Quality Invantory Caov Part 3 . Watar Ratoutcat CaPvlFor Tr»n«m.t«, Ptfi J . Camnirv Coov ^tn 4 - Bact*r I u ^\ C ^j^i If NATIONAL METAL FINISHINGS CORP., INC. ELECTROPLATING WEST MAIN STRBET • BOX 2aB • 80ON0 BROOK. NEW JERSEY 08808 • BOD 489*313 100 PRECISION PINISHINQ r rl. \vV ^\^ !v Av' (c--^\i v ^i.^ November 25, 1980 state of New Jersey Department of Environmental Protection Division of Water Resources P.O. Box CN-029 Trenton, New Jersey 08625 Gentlemen; Confirming our telephone conversation of today we have enclosed a copy of pretreatment base line report that was filed with the E.P.A. on 10-6-80. If any additional information is required please advise- Very truly yours. Jos\ph F. Conrad, President 0EC3 1980 JFC:mrh, End . XMOaSTRZAX. USER PUTUIATMEM7 BASS LIMB REPORT BLSVTROPLATBR NAMB AKO AD0RS8S National M«tal Flaiahlnga Corp., lnc< 100 Vaat'Naia Stxaat P.O. Box 265 Booad Brook, Haw Jaraay 0830S HAXB AMD LOCATXOa or PACZXiZTTi Saaa MATORB OP OPBXATZOBc Job Sbop Matal Piaiahing SIC No. 3471 Avaraga Prodactioa Rata Not cnowa WA8TB WATBR DZ8CHARGB TO POTWi Avaraga Plow 3370 gal/day All ragulatad, aon-ragulA'ta4« cooling and sanitary flows ara ooabinad into ona flow. thaaa flows ara aatinatad from watar aatar raadiags. POLOTAMTS ZN OZSCBAKGB Maaiaaa A'garaga (•g/1)t Cyanida Amaaabla K/A Cyanida Total Chroaiiua Cadaium Coppor Niokal La ad silT«r Zino Total Matals [j lfi&23| Tha foragoing inforaatioQ ia providad to tha bast of ay ability'at this tiaa. zt ia basad'on tha assuaption that tha aaandad ragulationa propoaad by BPA on July 3, 1980 (45 Pad. Rag. 45322) will ba adoptad in final fora, Tha schadula is basad on tha currant oonplianoa daadlina, whioh aay ba axtandad by EPA. Tha schadula oannot antieipata problaaa whtch aay ba ancountazad in actual financing, doaign and installation. Othar prasantly unknown factors includa tha availability of raaoval oradita and variancaa Raapactfnlly suboittad. Joseph P. Conrad, Praaidant !' Data Octobar 6, 1980 REFERENCE #30 .,%?^- i^m •..4 - Middle-BrooK a^CjONAL HEALTH COMMISSION 1200 MOUNTAIN AVENUE MIDOLESM. NEW Jfn&EY 0M4« PARTlCirATINa IIUNICIPALITIES BOROUGH •( SOUND MftOOK TOMN&HI^ Bf SRCfN UHOOK •OROUGH a( MIODueSEK aOROUQH al tOUTH tlOONO MROOK a080U0H al kOurn »UAINrit.L.O aoaottaii ai «vATCHUMc August 2, Ids') Mr. Bobert Kunze N.J. St^te D.E.P. Oiv. of Waste Management 1911 Princeton Avenue Trenton, N.J.' 08648 pe<)r Mr, Kunze: This is to inform you that the area of the Raritan River near the Brook Industrial Park in Bound Brook and South Bound Brook is used for recreat^.onal purposes such as fishing ^nd ^W^ottaing, Sincefely, Ronald Cohen Wealth Officer |^;pi€ i^^SmTl REFERENCE #31 I0fl?35 t=«. >cc*v->^ ^ J I Dangerous Properties of Industrial Materials Fifth Edition N. IRVING SAX Assisted by: Marilyn C. Bracken/Robert D. Bruce/William F. Durham/Benjamin Feiner/ Edward G. Fitzgerald/Joseph J. Fitzgerald/Barbara J. Goldsmith/John H. Harley/ Robert Herrick/Richard J. Lewis/James R. Mahoney/John F. Schmutz/ E. June Thompson/Elizabeth K. Welsburger/David Gordon Wilson VAN NOSTRAND REINHOLD COMPANY 2!S NEW YORK Cl^Cl^^Arl TORONU) LONDON MELBOURNE 100936 346 ALCOHOL, TERTIARY ALCOHOL, TERTIARY. See specific compound. 8a-hexahydro-l .4.5.8-dimethanonaphthalene. acta ALDEHYDE AMMONIA. Syn: acetaldehyde am lene, compound 118. Crystals, insol in water, sol in arc monia. White crystalline solid. CH3CH(NH:)0H, matics, esters, ketones, paraffins and halogenated sol mw: 61.08. bp: 110°, mp: 97°. vents. Ci:HgCl», mw: 365. mp: 104°-105°. THR = MOD irr to skin, eyes and mu mem via oral Acute tox data: Oral LD^o (rat) = 55 mg, kg. derma and inhal routes. LD50 (rat) = > 200 mg kg, [94] Fire Hazard: Mod, when exposed to heat or flame; THR = HIGH via oral, dermal and CNS routes. In readily decomp into acetaldehyde and ammonia gestion. inhal or absorption of this material into th: when heated. body can cause irritability, convulsions and depres E.xplosion Hazard: Mod, when exposed to heat or sion in from 1 to 5 hrs. Continued exposure cause flame. liver damage. An exper care. [3. 12. 102] See chlon Explosive Range: See ammonia. naied HC. Disaster Hazard: Mod dangerous when heated to Disaster Hazard: Dangerous; see chlorides. decomp, emits toxic fumes, can react with oxidiz ALFALFA MEAL. ing materials. THR = A mild sensitizer, which when inhaled ma\ ALDEHYDE C-8. See caprylaldehyde. cause asthma, running nose, sneezing, coughini and tearing eyes. Contact with skin may cause con ALDEHYDE C-16. See ethyl methyl phenyl glycidate. tact dermatitis. ALDEHYDES. See also specific compounds. All the Fire Hazard: Mod, when exposed to heat or flame; b; aldehydes possess anesthetic properties, but this is spont chemical reaction. obscured by their highly irr aaion on the eyes and mu Spontaneous Heating: Yes. Avoid moisture conten mem of the respiratory tract. The lower aldehydes, extremes. Fires may smolder for 72 hrs before be very sol in water, act chiefly on the eyes and tissues of coming noticeable. the upper respiratory tract. The higher aldehydes, less sol in water, tend to penetrate more deeply into the ALIPHATIC AMINES. See fatty amines. respiratory system and may affect the lungs. The above ALIPHATIC AND AROMATIC EPOXIDES. toxicity hazard rating is more accurate for the lower THR = Exper care of skin, lung, blood-forming tis molecular weight aldehydes. Some higher aldehydes sues. [14] and also the aromatic aldehydes may exhibit much ALIPHATIC AND AROMATIC EPOXIDE MONO lower toxicity. MERS AND POLYMERS. ALDEHYDINE. See 5-ethyl-2-methyl pyridine. THR = Exper care. See aliphaticand aromatic epox ides. [14] ALDERLIN. C,.Hi»ON, mw: 229.3. Acute tox data: Oral LD50 (rat) = 900 mg/kg; iv LD50 .4LIZARIN. Syn: 1.2-dihydro.xy amhraquinone. Or (rat) = 50 me kg; ip LD50 (mice) = 124 mg/kg. [i] ange-red crystals. C16H8O4. mw: 240.2, bp: 430° (sub THR = HIGH via ip and iv routes; MOD via oral limes), mp: 289°. route. An exper care to mice, [i] THR = MILD allergen. Fire Hazard: Slight, when exposed to heat or flame .ALDOL. Syns: aceialdol. 3-butanolal, oxybutyricalde- hyde. Clear, white to yellow syrupy liquid. CHgO:, can react with oxidizing materials. mw: 88.10, bp: 83° @ 20 mm, flash p: 150°F (OC), ALKALIES, (see also specific compounds.) d: 1.11. autoign. temp.: 482°F, vap. d: 3.04. A term loosely applied to the hydroxides and carbon THR = MOD via oral route. ates of the alkali metals and alkaline earth metals Fire Hazard: Mod, when exposed to heat or flame; as well as the bicarbcmate and hydroxide of am decomp into crotonaldehyde and water when monium. They can neutralize acids, change the colo heated. See crotonaldehyde. of indicators and impart a soapy taste and feel u Spontaneous Heating: No. aqueous solutions. Disaster Hazard: Dangerous; when heated to decomp, THR = Variable. The alkalies, as a group, constitut emits highly toxic fumes of crotonaldehyde; can re the commonest causes of occupational dermatitis act with oxidizing materials. They act on the skin as primary irr. Alkaline solu To Fight Fire: Water, alcohol foam, mist or water tions soften and dissolve the keratin layer, and th spray, CO2, dry chemical. skin becomes white, soggy, wrinkled and macerated Repeated exposure frequently results in the deve! ALDOMET. See methyl dopa. opment of chronic eczematous skir> conditions. Th-. ALDRIN) Syns: 1.2.3.4.10.10-he.xachloro-1.4,4a.5.8- stronger caustics may produce chemical burn For Countcrrneasurf Infornution and Abbreviations sac the Directory at the Beginnint of this Section. Ift0237 482 CHLORATES, N.O.S. WET added. Paraffin may be added as a desensitizer. sorbed through the skin as well as through other ; Recently, similar mixtures were used in Europe but portals. It is a CNS stimulant whose exact mode i with the addition of small amounts of nitroglycerin of action is unknown, but it may involve micro- or collodion cotton. Chlorate explosives are more somal enzyme stimulation. Animals poisoned by { sensitive than modem permissible explosives, and this and related compounds show an extremely i therefore, not as safe as for instance the perchlorate marked loss of appetite and neurological symp- 1 explosives, or the permissibics. Plastic mixtures of toms. The fatal dose to man-is unknown. It has been 1 chlorate explosives (containing nitroglycerin) are estimated to be between 6,to 60 g (1 5 to 2 oz.). One 1 somewhat less sensitive to shock and friction, in person receiving an accidental skin application of I spite of the nitroglycerin present, than the dryer 25% solution (amounting to something over 30 g explosives with no nitroglycerin. In this case the of technical chlordane) developed symptoms within i nitroglycerin or "explosive oil," as it is known, serves about 40 min and died before medical attention to wet the rest of the mixture. Barium chlorate is was obtained. In two patients, death followed ex- ; shipped and stored in wooden boxes, barrels, or posure to low oral doses of chlordane (2-4 g); on kegs. It should have isolated storage in a cool, microscopic examination both patients showed se ventilated place, away from acute fire hazards and vere chronic fatty degeneration of the liver, char should not be stored in the same building with acteristic of chronic alcoholism. Although these combustible materials, acids, sulfur, powdered mag two fatalities cannot be attributed exclusively to nesium or powdered aluminum. Examples of chlo chlordane, they are entirely consistent with previous rates used in the explosive industry, would be observations that the toxicity of other chlorinated potassium chlorate, sodium chlorate and barium hydrocarbons is much enhanced in the presence of chlorate. chronic liver damage. The dangerous chronic dose Disaster Hazard: Dangerous; shock will explode them; in man is unknown. when heated to decomposition, they can emit toxic One person poisoned by chlordane developed fumes and explode; can react with reducing mate convulsions within 40 min of gross skin contamina rials. tion and died, apparently of respiratory failure, CHLORATES, N.O.S. WET. See also chlorates, N.O.S. before medical aid could be obtained. CHLORAURIC ACID. See gold compounds. Acutely poisoned exper animals show similar signs. Exper animals exposed to repeated small CHLORAZENE. See chloramine. doses exhibit hyperexcitability, tremors, and con CHLORAZINE. See 2-chloro-4,6-bis(diethylamino)-s- vulsions, and those which survive long enough triazine. show marked anorexia and loss of weight. Symp CHLORBENSIDE. See p-chlorobenzyl-p-chlorophenyl toms in animals frequently occur within an hour of sulfide. the administration of a large dose, but death often CHLORCYCLINE. C,8H2iN2Cl, mw: 300.9. is delayed for several days depending on the dos THR = An exper teratogen. [3] age and route of administration. In any event, CHLORCYCLIZINE HYDROCHLORIDE. symptoms are of longer duration with chlordane C„H2iN:Cl-HCl, mw: 337.2. than with DDT under similar conditions. THR = An exper teratogen. [3] Laboratory findings are essentially normal, ex CHLORDAN. See chlordane. cept that the insecticide may be demonstrated in CHLORDANE! Syns: l,2.4,5,6,7,8,8-octachloro-4,7- tissues of poisoned animals by means of bioassay. methano-3a,4,7,7a-tetrahydroindane, chlordan, octa- A method for specific, quantitative chemical analy chloroietrahydro methano indane, "Octa Klor" sis for chlordane is now available using small ''1068" ''Velsicol 1068," ^Dowklor" "Ortho-Klor," amounts of subcutaneous fat. Chronically poi and other trade names. Colorless to amber, odorless, soned animals show degenerative changes in the viscous liquid. CioHeCU, mw: 409.75, bp: 175°, d: liver and kidney tubules. 1.57-1.63 (a 15.5°; 15.5°. Disaster Hazard: Dangerous; see chlorides. Treatment and Antidotes: Removal of the poison Acute tox data: Oral LD50 (rat) = 283 mg/kg; dermal from the skin or the alimentary tract should be LDsn (rat) = 700 mg/kg; ip LD50 (rat) = 343 mg/kg; attempted. Oil laxatives should be avoided. The oral LD50 (chicken) = 220 mg/kg. [3] nervous symptoms may best be combatted with THR = HIGH via oral and ip; MOD via dermal pentobarbital or phenobarbitai. routes. Has been implicated in develoment of aplas tic anemia. An exper care. [93] An insecticide. Must CHLORDIAZEPOXIDE. Syn: //fer/w/ij. C^HuON.Cl. be considered quite toxic. Chlordane is readily ab mw: 299.8. For Countcrnwisure Inforinilion ind Abbreviiiiom je« the Directorj «t the Befinnint of this Section. tomm 504 CHROMIC ACID SOLUTION common air contaminant. This material is usually tals. Cr, at wt: 52.01, mp: 1890°, bp: 2200°, d: 7.20, caustic in its action on skin, mu mem or organic vap. press: 1 mm (® 1616°. matter in general. THR = HIGH pulmonary toxicity. An exper (-t-) neo Fire Hazard: Dangerous; a very powerful oxidizing and care, [i, 6, 23, 95] See also chromium com agent. In contact with organic matter or reducing pounds. ' agents, causes violent reactions with acetic acid, Radiation Hazard: For permissible levels, see Section acetic anhydride, acetone, Al, NHj, anthracene. As, 5, Table 5A.5. Artificial isotope "Cr, Ti = 28d. CsHft, camphor, CIF3, CrS, ethyl ether, dimethyl decays to stable ^'V via ec. Emits 7"s of 0.32 MeV formamidc, alcohol, glycerol, hydrocarbons. HjS, and x-rays. CH3OH, naphthalene. P. K, organic matter, potas Fire Hazard: Mod, in form of dust. Reacts violently sium ferricyanide, pyridine, Se, Na, sodium amide, with NH4NO3, H:02, Li, NO, KCIO5, SO2. [19] S, turpentine. [19] CHROMIUM AMMINE NITRATES. Explosion Hazard: Upon intimate contact with power THR = May be heat- and impact-sensitive. [19] ful reducing agents, can cause violent explosions, CHROMIUM AMMINE PERCHLORATES. CHROMIC ACID SOLUTION. See also chromic acid. THR = May be impact-sensitive. [19] CHROMIC ACID-TREATED FATS AND OILS. CHROMIUM BORIDE. THR = A (S) care. [14] THR = See chromium compounds. CHROMIC ANHYDRIDE. See chromic acid. CHROMIUM CARBIDE. CHROMIC BROMIDE. Hexagonal olive-green crys THR = See chromium compounds. tals. CrBrs, mw: 291.76, mp: subl, d: 4.25 @ 0°. CHROMIUM CARBONYL. Colorless crystals. THR = See chromium compounds and bromides. Cr(CO)6, mw; 220.07, mp: subl @ room temp., sinters CHROMIC CHLORIDE. See chromium chloride III. @ 90°, decomp @ 130°, explodes @ 210°, bp: 151.0°, CHROMIC CHROMATE. CrjOn, mw: 452. d: 1.77, vap. press: 1 mm @ 36.0°, vap. d: 7.6. THR = An exper (-(-) neo and care, [i, 6] THR = VERY HIGH via iv route. CHROMIC FLUORIDE. Rhombic green crystals. CrFs, CHROMIUM CHLORIDE (H). Syn: chromium dichlo- mw: 109.01, mp: >1000°, subl 1100-1200°. d: 3.8. ride. CrCh, mw: 122.9. THR = See chromium compounds and fluorides. Vio Acute tox data: Oral LD50 (rat) = 1870 mg/kg. [3] lent reaction with (K + NH.Br). [19] THR = MOD via oral route. See also chromium com CHROMIC NITRATE. Monoclinic brown crystals. pounds. Cr(N03)3-7iH20, mw: 373.15, mp: 100°. CHROMIUM CHLORIDE (III). Syn: chromic chlo THR = See chromium compounds and nitrates. ride. CrCU. mw: 158.4, bp: 1300° (subl). CHROMIC-o-PHOSPHATE. Violet crystals. Acute tox data: Oral LDso(rat) = 1870 mg/kg; dermal Cr(P04)-2H:0, mw: 183.02, d: 2.42 @ 32.5°. LD50 (guinea pig) = 202 mg/kg. [i] THR = See chromium compounds and phosphates. THR = HIGH via dermal and MOD via oral routes CHROMIC SESQUESULFIDE III. Violet or red Violent reaction with Li. [19] powder. Cr2(S04)3, mw: 392.22, d: 3.012. . CHROMIUM CHLORIDE (IV). See chromium tetra THR = See chromium compounds and sulfates. chloridii. CHROMIC SULFITE. Greenish-white crystals. CHROMIUM COMPOUNDS. Chromic acid and it Cr2(S03)3, mw: 344.22, mp: decomp, d: 2.2. salts have a corrosive action on the skin and mu mem THR = See chromium compounds and sulfites. The lesions are confined to the exposed parts, affectini CHROMITE ORE. Syn: ferric chromate. chiefly the skin of the hands and forearms and the mi THR = An exper (-r) neo and care, [i, 6] See chro mem of the nasal septum. The characteristic lesion is: mium compounds. deep, penetrating ulcer, which, for the most part, doe not tend to suppurate, and which is slow in healing CHROMITE ORE ROAST. Small ulcers, about the size of a matchhead or end 0 THR =An exper (-i-) care. [3. 6] See chromium a lead pencil may be found, chiefly around the base 0 compounds. the nails, on the knuckles, dorsum of th€ hands an< CHROMITE ROAST LEACHED BROMIDE. forearms. These ulcers tend to be clean, and progres THR = An exper (T) care. [3. 6. 2] See chromium slowly. They are frequently painless, even though quit compounds. deep. They heal slowly, and leave scars. On the m: |CHRO.MIUMj Very hard metal, cubic steel, gray crys- mem of the nasal septum the ulcers are usually accom For Couniermeisure Information and Abbreviations see the Oirectort it the Betinninf of this Section. t0M% CHROMOUS CHLORIDE 505 panied by purulent discharge and crusting. If exposure mw: 154.92, mp: -96.5°, bp: 115.7°, d: 1.9145 @ continues, perforation of the nasal septum may result, 25°/4°, vap. press: 20 mm @ 20°. but produces no deformity of the nose. Chromate salts Acute tox data: sc LDLO (mice) = 545 mg/kg. [3] are recog care of the lungs, nasal cavity and paranasal THR = HIGH via sc and inhal routes. A strong irr. sinus, aiso exper care of the stomach and larynx. [14, Hydroiyzes to form chromic and hydrochloric acids. 23, 95, 62] Hexavalent compounds are said to be more See chromium compounds. Reacts violently with toxic than the trivalent. [61, 60,26,62,63,64] Eczema alcohol, ether, acetone, turpentine, NHj, (CI2 + C), tous dermatitis due to trivalent chromium compounds F2, P, PCI,, NaN,, S, SCI. [79] has been reported. Disaster Hazard: Dangerous; see chlorides. CHROMIUM DIFLUORIDE. See chromous fluoride. CHROMIUM-2,4-PENTANE DIONE DERIVATIVE. CHROMIUM FLUORIDE (III). CrF,, mw: 109. Syn: acetylacetonate of chromium. A solid. THR = HIGH via oral and sc routes. See also chro Cr(C5H762)3, mw: 349.33, mp: 216°, bp: 340°. mium compounds. Corrosive. THR = See chromium compounds. CHROMIUM FORMATE. Crystals. Ct{CY{Oih, mw: CHROMIUM PICRATE. Solid, Cr(C6H20H(N02)3]3, 187.1. mw: 739.4. THR = See chromium compounds. THR = See chromium compounds. Fire Hazard; See nitrates. CHROMIUM METAL AND ALLOYS OF IRON. Explosion Hazard: See explosives, high, and nitrates. NICKEL AND COBALT. Disaster Hazard: See nitrates. THR = A recog care. [3, 6] See chromium and nickel compounds. CHROMIUM POTASSIUM SULFATE. Sec chrome alum. CHROMIUM MONOARSENIDE. Gray, hexagonal crystals. CrAs, mw: 126.92, d: 6.35, @ 16°. CHROMIUM SULFATE. See chromic sulfate. THR = See arsenic and chromium compounds. CHROMIUM TETRACHLORIDE. CrCL, mw: 193.8. Fire Hazard: See arsine. THR = HIGH via inhal and oral routes. See chro Explosion Hazard: Dangerous; when heated to de mium compounds and chlorides. Violent reaction comp or on contact with water, steam, acid or acid with Na or K. [19] fumes, will react to produce toxic and flam vapors of CHROMIUM TETRAFLUORIDE. Brown, amor arsine. phous, hygroscopic mass, sol in water with hydrolysis. CHROMIUM MONOBORIDE. Orthorhombic, silvery CrF4, mw: 128.01, d: 2.89, mp: 200°, bp: approx400° crystals. CrB, mw: 62.83, mp: 2760°, d: 6.17. evolving intensely blue flame. THR = See chromium and boron compounds. THR = HIGH irr via oral and inhal routes. See also Fire Hazard: See boron hydrides. chromium compounds. Explosion Hazard: See boron hydrides. Disaster Hazard: Dangerous; see fluorides. Disaster Hazard: Dangerous; on contact with water, CHROMIUM TRIAMMINO TETROXIDE. steam, acid or acid fumes, will react to produce toxic Cr(NH3)304, mw: 167. and flam vapors of boron hydrides. THR = See chromium compounds. Incandesces when i i CHRO.MIUM MONOPHOSPHIDE. Gray-black crys heated. Detonates on impact. [19] tals. CrP, mw: 82.99, d: 5.7 (® 15°. CHROMIUM TRIOXIDE. See chromic acid. THR = See chromium compounds and phosphides. CHROMOMYCIN A3. Isolated from streptomyces Fire Hazard: Dangerous; upon contact with moisture, griseus. acid or acid fumes, phosphine is evolved. See THR = HIGH via oral and inhal routes. An exper phosphine. teratogen. [3] Explosion Hazard: See phosphides and phosphine. Disaster Hazard: Dangerous; see phosphides. CHROMOUS ACET.ATE. Red crystals. Cr(C;H,0:)2. mw: 170.10. CHROMIUM OXIDE III. Syn: green chromium oxide. Acute tox data: Oral LD.o (rat) = 11.260 mg kg. [J] Cr:03, mw: 152. THR = LOW via oral and inhal routes. See chromium THR = HIGH via inhal route. An exper (S) care. [3, compounds. 6] Reacts violently with CIF3, glycerol, Li, 0¥i.:[19] CHROMOUS BROMIDE. White crystals. CrBr:, mw: CHROMIUM OXIDE IV. See chromic acid. 211.84, mp: 842°, d: 4.356. CHROMIUM OXYCHLORIDE. Syn: chromyl chlo THR = See chromium compounds. ride. Dark red liquid, musty burning odor. Cr02Ch, CHROMOUS CHLORIDE. See chromium chloride II. For Cbuntermnsure Informiiion and Abbreviations see the Directory at the Bejinnini of this Section. d 2,4-D. See 2,4-dichlorophenoxyacetic acid. emits highly toxic fumes of chlorides. Similar la DACRON. See polyethylene terphthalate (film). DDT. An exper (+) care, and neo. [i, 12] DACTIN. See l,3- For Countermeasure Information and Abbreviations sec the Dirrciory at tbe Be^inninc of this Section. 534 w^n DDT 535 stored in an exper animal than is sufficient as a volunteers have ingested up to 35 mg/day for 21 lethal dose for that same animal if given at one time. months with no ill effects. A study based on 75 human cases reported an aver Signs and Symptoms of Poisoning in Man: In pa age of 5.3 ppm of DDT stored in the fat. A higher tients who ate substantial doses of DDT in flour, content of DDT and its derivatives (up to 434 ppm the symptoms observed were vomiting, numbness of DDE and 648 ppm of DDT) was found in work and panial paralysis of the extremities, mild con ers who had very extensive exposure. Without ex vulsions, loss of proprioception and vibratory sen ception, the samples were taken from persons who sation of the extremities, and hyperaaive knee were either asymptomatic or suffering from some jerk reflexes. Symptoms appeared in 30 to 60 min disease completely unrelated to DDT. Careful hos after eating the DDT. The paralysis and numbness pital examination of workers, who had been very were most evident in the most distal portions of extensively exposed and who had volunteered for the extremities, and their intensity was directly examination revealed no abnormality which could proportional to the amount of DDT ingested. All be attributed to DDT. Much higher levels than the patients were apprehensive and excited; respira have been found in man have been observed in the tion was moderately rapid; pulse remained slow to fat of exper animals which were apparently asymp normal. The immediate protective mechanism in tomatic. DDT stored in the fat is eliminated only man, following substantial doses, is vomiting. With very gradually when further dosage is discontinued. smaller doses, nausea and vomiting are less promi After a single dose, the secretion of DDT in the nent, but diarrhea has been observed. Signs and milk and its excretion in the urine reach their height symptoms of chronic poisoning in man are un within a day or two and continue at a lower level known, although, judging from the observed micro thereafter. scopic changes in exper animals, liver and kidney Dangerous Acute Dose in Man: A dose of 20 g has dysfunaions should be looked for. The primary proved highly dangerous though not fatal to man. irr of DDT is practically nil, and it has little or no This dose was taken by 5 persons who vomited an tendency to produce allergy. Dermatitis induced unknown ponion of the material and even so re by DDT has occasionally been reported, but these covered only incompletely after 5 weeks. Smaller reports are unconfirmed; nevertheless the phe doses produced less important symptoms with rela nomenon should be expected to occur in rare tively rapid recovery. Exper ingestion of 1.5 g re instances. sulted in great discomfort and moderate neuro Laboratory Findings: Laboratory findings are essen logical changes including paracsthesia, tremor, tially negative except for the presence of DDT moderate ataxia, exaggeration of part of the re which may be quantitatively measured in stomach flexes, headache, and fatigue. Vomiting followed contents, urine, or tissues. only after 11 hours. Recovery was complete on the Treatment of Poisoning: Depending on the condi following day. The fatal dose of DDT for man is tion of the patient, attention should first be given not known. Judging fr>m the literature, no one has to the sedation or to the removal of poison which ever been killed by DDT in the absence of other in may have been taken internally. Stomach lavage secticides and/or a variety of toxic solvents. How and saline laxatives may be used. Oil laxatives ever, these common solvent formulations arc highly should be avoided; they promote absorption of fatal when taken in small doses, partly because of DDT and of many organic solvents. The five drugs the toxicity of the solvent, and perhaps because of of choice, arranged roughly in order of their effec the increased absorbability of the DDT; several tiveness, are phenobarbitai, pentobarbital, paralde fatal cases in man have been reported. Acute oral hyde, urethane, and calcium gluconate. Phenobar toxicity for man = 250 mg/kg. Acute oral LD50 bitai, which has been used in doses up to 0.7 g per (rat) =113 mg/kg (tech grade). Federal fruit and day in epilepsy, and pemobarbiul (0.25 to 0.5 g) vegetable tolerance = 7 ppm. are the barbiturates known to control convulsions Dangerous Chronic Dose in Man: Even less is known of central origin. Paraldehyde (average dosage 15 ce of the hazard of chronic DDT poisoning. It is orally, 1 cc undiluted intravenously, 35 ec rectally known that certain exper animals fed diets con in normal saline) controls the convulsions of D.DT- taining one part of DDT per million store the com poisoned animals. Urethane (human dosage 1 to 4 pound in their fat. The storage of DDT in man has g) has proved very effective in rats, but it should been mentioned above. The exact significance of be remembered that the hypnotic and narcotic ef these findings is not known and their funher in fects of urethane are not correspondingly high in vestigation is of the greatest importance. Human man.' Urethane has an added advantage, however. For Countermeasure Infonnalion and Abbreviations sec the Oirectorr at the B«tinnint of (hit Section. idMl2^ 536 DOVP of being tolerated in the young and the aged. The Spont Heating: No. objea of sedation is not to induce sleep but to To Fight Fire: Foam, CO2, dry chemical. restore a relative calm; however, the proper dos 1-DECANAL. Syns: caprylaldehyde, capric aldehvde, age in the presence of poisoning may be so large n-decylaldehyde, aldehyde-C-10. Colorless to light that it would induce anesthesia if poisoning were yellow liquid, floral fatty odor, sol in 80% alcohol, not present. fixed oils, volatile oils and mineral oils, insol in water Calcium gluconate has been used less than the and glyceroL GH3(CH2)gCHO, mw: 156, d: 0.831- other antidotes, but it is reported to control DDT- 0.838 (3 15°. induced convulsions in several animals. Since its Acute tox data: Oral LD50 (rat) = 3730 mg/kg. [3] mechanism of aaion is entirely different, it may be THR = MOD via oral route. Used as a synthetic used in addition to sedatives. Epinephrine is eon- flavoring substance and adjuvant. [109] traindicated. DECANE. Syn: decyl hydride. Liquid. CH3(CH2)8CH3, DDVP. See dimethyldichlorovinyl phosphate. mw: 142.3, mp: -29.7°, bp: 174.1°, lei = 0.8%, uel = DEAC. Sec diethyl aluminum chloride. 5.4%, flash p: 115°F (CC), d: 0.730@ 20°/4°, auto DEADLY NIGHTSHADE. ign. temp.: 410°F, vap. press: 1 mm(g) 16.5°, vap. d: 4.90.- Source of the alkaloids, atropine and belladonine. THR = A simple asphyxiant. Narcotic in high cone. DEAPASIL. See ^-aminosalicylic acid. See argon. DECARBORANE. Syns: i>oron hydride, decaboron tet- Fire Hazard: Mod, when exposed to heat or flame; radecahydride. Colorless needles. BioHu, mw: 122.3, can reaa with oxidizing materials. mp: 99.7°, d: 0.94. (solid), d; 0.78 (liquid @ 100°), Spont Heating: No. vap. press: 19 mm (5) 100°. Explosion Hazard: Mod, in its vapor form. Acute tox data: Oral LD50 (rat) = 64 mg/kg. Inhal To Fight Fire: Foam, CO2, dry chemical. LD50 (rat) = 46 ppm for 4 hrs. Dermal LD50 (rat) = DECA.NOIC ACID. Syns; decoic acid, decylic acid. 740 mg/kg. [3] White crystals, unpleasant odor, sol in most organic THR = HIGH via oral, inhal; MOD via dermal solvents and in dilute nitric acid, insol in water. routes. Self-ignites in O2. [19] CH3(CH2)8COOH, mw: 172.3, d: 0.8858, bp: 270°, DECABORON TETRADECAHYDRIDE. Sec deca- mp: 31.4°. borane. Acute tox data: iv LD50 (mouse) = 129 mg/kg. [i] DECACHLOROOCTAHYDO-l,3,4-METHENO-2H- THR = HIGH via iv route. CYCLOBUTA(cd) PENTALEN-2-0NE. See kepone. 1-DECANOL. See n-decyl alcohol. DECAHYDRONAPHTHALENE. See Decalin. 1-DECENE. Syn: n-decylene. Colorless liquid. DECAHYDRONAPHTHALENE, trans, flash p: H2CCH(CH2)7CH3, mw: 140.26, mp: -66.3°, bp: 129°F; autoign. temp.: 491°F, lei = 0.7%, uel = 5.4%, 172°, d: 0.7396 ^ 20°/4°, vap. press: 1 mm @ 95.7°, d: 0.87, vap. d: 4.77, bp: 195°. vap. d: 4.83, flash p: < 131°F, autoign. temp.: 455°F. THR = See Decalin. THR = U. Compounds in this group generally have irr Fire Hazard: Mod, via heat, flame and oxidizers. and narcotic action. See also hexene-1. To Fight Fire: Water spray, mist, alcohol foam, Fire Hazard: Mod, when exposed to heat or flame; dry chemical. can react with oxidizing materials. To Fight Fire: Foam, CO2, dry chemical. DECALIN. Syn: decahydronaphthalene. Water white DECYL ACRYLATE. Very slightly sol in water. liquid. C10H18, mw: 138.3, mp (cis): -43.3°, mp C,3H:402, mw: 212.4, flash p: 441°F (OC), d: 0.9. bp: {trans.): -30.1°, bp: (cis): 194.6°, flash p: 136°F, 157° @50mm. (CC), autoign. temp.: 482°F, vap. press: (cis) 1 mm@ . Acute tox data: Oral LDLO (rat) = 4930 mg/kg; der 22.5°, (trans) 10 mm @47.2°, d: 0.8963, vap. d: 4.76, mal LDLO (rabbit) = 4660 mg/kg. [3] See also lei = 0.7% @ 212°F, uel = 4.9% @ 212°F. esters. Acute tox data: Oral LD50 (rat) = 4170 mg/kg. Inhal THR = MOD via oral and dermal routes. LD50 (rat) = 500 ppm for 2 hrs. [i] Fire Hazard: Slight, when exposed to heat or flame. THR = MOD via oral and inhal routes. Irr to skin, To Fight Fire: Dry chemical, CO2, mist, spray. eyes and mu mem. Has caused kidney damage in exper animals. n-DECYL ALCOHOL. Syn: 1-decanol. nonyl carbinoL Fire Hazard: Mod. when exposed to heat or flame; Viscous, refractive liquid. CH..(CH:)8CH:OH. mw: can react with oxidizing materials. 158.3, mp: 7°, bp: 232.9°, flash p: 180°F (OC), d: m For Counurmcasure Infonnalion and Abbreviations see the Directory at the Beginninf of this Section. i3Bi^«3 4,5-OICHLORO-m-BENZENE OiSULFONAMIDE 557 Acute tox data: Oral LD» (rat) = 2460 mg/ kg; inhal DICHLORO-o-ANISIC ACID. Syn: banvel D. LCLO (rat) = 2000 ppm for 4 hrs; dermal LDw (rab C«H2COOH(Cl):OCH,. mw: 221. bit) = 650 mg/kg. [i] Acute tox data: Oral LD50 (rat) = 1040 mgkg. [3] THR = MOD via oral, inhal and dermal routes. THR = MOD via oral route. An herbicide. Fire Hazard: Mod, when exposed to heat, flame or 7,12-DICHL0R0BENZ(a)ANTHRACENE. powerful oxidizers. THR = An exper care. [23] Disaster Hazard: Dangerous; see chlorides. To Fight Fire: Alcohol foam, dry chemical. 1,3-DICHLORO BE.NZENE. See m-dichlorobenzcne. DICHLOROACETYLENE. Syn; dichloraceiylene. IL4-DICHL0R0 BE.NZENE] Seep-dichlorobcnzene. ClCiCCl, mw: 94.94. m-DlCHLOROBENZENE. Syn: l.J-dichlorobenzene. Acute tox data: Inhal TCLO (human) = 0.5 ppm; Colorless liquid. QHaClz, mw: 147.0, mp: -24.8°, inhal LCM (mouse) =19 ppm for 6 hrs; inhal LCjo bp: 173°,d:1.288(a)20°/4°,vap.press: 1mm (1)12.1°. (guinea pig) = 20 ppm for 4 hrs. [3] vap. d: 5.08. THR = HIGH via inhal route. HIGH via CNS route. THR = An insecticide and fumigant. Sec also o-di- Can be formed by thermal decomp (> 70°) from tri chlorobenzene and chlorobenzene. chloroethylene, as used in medicine. Symptoms in Fire Hazard: Mod; can react violently with Al. [19] clude a disabling nausea and intense jaw pain. Sec Disaster Hazard: Dangerous; see chlorides; can react also chlorinated hydrocarbons, aliphatic. vigorously with oxidizing materials. Explosion Hazard: Severe, when shocked or exposed To Fight Fire: Water, foam, CO:, dry chemical. to heat or air [79] Disaster Hazard: Highly dangerous; shock and heat o-DICHLOROBENZENE. Gear liquid. C:»H4Cl2. mw: will explode it; when heated to decomp or on con- 147.0, mp: -17.5°, bp: 180°-183°;fp: -22°, flash p: taa with acid or acid fumes, emits highly toxic I5rF, d: 1.307 @ 20°/20°, vap. d: 5.05, autoign. fumes of chlorides; can react vigorously with oxi temp.: 1198°F, lei = 2.2%, uel = 9.2%. Acute tox data: LCLO (rat) = 707 ppm for 7 hrs; dizing materials. oral LDLO (guinea pig) = 2000 mg/ kg. [3] ^2,>D!CHL0R0ALLYL DIISOPROPYL THIOCAR- THR = MOD via inhal and oral routes. Sec chloro BAMATE. Syns: diallaie, avadex. Brown liquid, benzene. The o-isomer is probably more toxic than slightiv sol in water, sol in organic solvents. the m- or p-forms. It is irr to skin and mu mem. [(CH3)2CH]2NC0SCH2G(C1):CHC1, mw: 270.2. bp: Exper produced liver and kidney injury. An exper 150° @ 9 mm, mp: 25°-30°. (±) care, [i, /] Acute tox data: Oral LDw (rat) = 395 mg/kg; dermal Fire Hazard: Mod. when exposed to heat or flame. LD» (rabbit) = 2000 mg/kg. Disaster Hazard: Dangerous; see chloride; can reaa THR = HIGH via oral; MOD via dermal routes. An vigorously with oxidizing materials. exper care. [i. 12] To Fight Fire: Water, foam, CO:, dry chemical. Disaster Hazard: Dangerous; when strongly heated, gives off highly toxic fumes. p-DICHLOROBENZENE. | Syn: 1,4-dichlorobenzene. 2,4-DICHLOROANILINE. Needle-like crystals. White crystals, penetrating odor. C«R For Countermeasure Infornution and Abbreviations see the Directorr ai the BninniOK of this Section. 1©0?I4 DIELDRIN 569 (aHi,):NH, mw: 181.32, mp: -1°, bp: 256°, flash p: fp: -72°, flash p: 425° F (COC), d: 0.916-0.922 (5) > 210°F (OQ, d: 0.910, vap. d: 6.27. 20°/20°. Acute tox data: Oral LD» (rat) = 373 mg/kg; sc LDso THR = U. Limited animal exper suggest LOW tox (mouse) = 135 mg/kg. [3] icity. See also esters and adipic acid. THR = HIGH via oral and sc route. An exper neo. [3] Fire Hazard; Slight, when exposed to heat or flame; Animal exper show intense local irr and nervous can react with oxidizing materials. exciution. Sec also cyclohcxylamine. To Fight Fire; Foam. CO:, dry chemical; Fire Hazard: Low, when exposed to heat or flame; DI-rt-DECYLAMINE. Liquid. (CioH:,):NH. mw: can react with oxidizing materials. 297.5. bp: 195° @ 12 mm. vap. d: 10.3. To Fight Fire; Alcohol foam, CO:, dry chemical. THR = U. See also amines. DICYCLOHEXYLA.MINE NITRITE. CrHrjN Fire Hazard: Mod, when exposed to heat or flame; NO:H, mw: 228.4. can react with oxidizing materials. Acute tox data; Oral LD50 (rat) ••= 284 mg/kg, oral To Fight Fire: Water spray, mist, foam, dry chemical. LD50 (mouse) = 205 mg/kg. [i] DIDECYL ETHER. C2oH420, mw: 298.4, autoign. THR = HIGH via oral route. An exper neo. [i] temp.: 419° F, vap. d: 10.3. Fire Hazard: Dangerous; see nitrates. THR = No data. Sec also ethers. Disaster Hazard: Dangerous; sec nitrates. Fire Hazard: Low. See ethers. DICYCLOHEXYL PHTHALATE. White soUd. To Fight Fire: Alcohol foam, water, mist or spray. CH4(COOC*Hn):, mw: 330.5. mp: 58°, bp: 200°- DIDECYL PHTHALATE. A clear liquid. 235° @ 4 mm, flash p: 405°F, d: 1.148 @ 20°, 20°, (CioH2iCO:)2C:«Ha. mw: 446, bp: 252° @ 4 mm, fp: vap. press: 0.1 mm @ 150°. -53°, flash p: 450° F (COC), d: 0.964-0.968 @ 20°/ THR = Probably MOD to LOW. 20°. Fire Hazard: Slight, when exposed to heat or flame; Acute tox data: Dermal LD50 (rabbit) = 17,000 mg/ kg. can reaa with oxidizing materials. [3] To Fight Fire: Water, foam, CO:, dry chemical. THR = Virtually non^toxic via dermal route. Sec also DICYCLOFENTADIENE. Colorless crystals. CoH,:. esters and phthalic acid. mw: 1313, mp: 32.9°, bp: 166.6°, d: 0.976 @ 35°, Fire Hazard: Slight, when exposed to heat or flame; vap. press: 10 mm (5) 47.6°, vap. d: 4.55, flash p: can react with oxidizing materials. 90°F(OC). To Fight Fire: Foam. CO:, dry chemical. Acute tox data: Oral LD?o (rat) = 353 mg. kg; inhal 3,8-DIDEHYDRO RETRONECINE. C8HnO:N, mw; LCLO (rat) = 500 ppm for 4 hrs; dermal LDso (rab 153.2. bit) = 5080 mg. kg. [3] THR = An exper neo to rats via sc route. [103] THR = HIGH via oral and inhal; MOD via dermal DIDIPHENYLAMINE FLUOSILICATE. White crys routes. tals. [(C6H<):NH]:- H:SiF6, mw: 482.5. mp: 169°. Fire Hazard; Dangerous, when exposed to heat or THR = HIGH. See fluosilicates. flame; can react with oxidizing materials. Disaster Hazard: Dangerous; sec fluosilicates. To Fight Fire: Alcohol foam. DIDODECYLAMINE. White solid, slight ammoniaeal DICYCLOPENTADIENYL IRON. See ferrocene. odor. (C,:H:5):NH, mw: 253.7, mp: 50°, bp: 210° (5) DICYCLOPENTENYL ALCOHOL. Liquid.CoH,?©, 1 mm. mw: 153.2. bp: 238°, flash p: 426° F, d; 1.07, vap. d: THR = U. See also amines. 5.3. DIDYMIUM .NITRATE. Violet-red, hygroscopic crys THR = U. Sec also alcohols. tals. Fire Hazard: Slight, when exposed to heat or flame; Comp: a mixture of praseodynium and neodymium can reaa with oxidizing materials. nitrates. To Fight Fire: Water, foam. CO;, dry chemical. THR = See nitrates. DHDECANOYDTRIETHYLENE GLYCOL ESTER. Radiation Hazard: Didymium salts are usually slightly C:6H5OOA, mw: 458.8. radioactive from the presence of thorium as an Acute tox data: Oral LD.o (rat) = 7460 mg/kg; der impurity. .1 -i** mal LD.o (rabbit) = 11,000 mg/kg. [3] Fire Hazard: See nitrates. I' THR = LOW via oral and dermal route. Disaster Hazard: See nitrates. # DIDECYL ADIPATE. A clear liquid. IDIELDRINJ Syns: 1.2.3.4.10,lO-hB.xachloro-6.7- (C,oH:iCO:):CH., mw: 426, bp: 240° (5) 4 mm. epoxy-1.4.4a.5,6.7,8.8a-octahydro-1.4.5.S-di- For Counicnneaaurc Inlbnnation and Abbrevialions ae* the Directory al tbe Bctinnini of this Section. 100^45 570 DIENESTRAL DIACETATE methanonaphthalene, compound 497, Octalox and the convulsions. Hyperexcitability and hyperir other trade names. White crystals, odorless, insol in tability are common findings. water, sol in common organic solvents. Ci:H8Cl60, Disaster Hazard: Dangerous; when heated to decon mw: 380.9, mp: 150°, vap. d: 13.1 emits highly toxic fumes of chlorides. THR = An exper (+) neo and care. [3, 102, 12] Used Treatment of Poisoning: Every effort should be ma as an inseaicide. Dieldrin is absorbed readily from to remove dieldrin from the skin by thorou the skin as well as through other portals. It aas as washing with soap and water or from the alimt a CNS stimulant, but the exact mechanism of this tary traa by the use of lavage and or saline la; action is entirely unknown. It also greatly reduces tives. Oil laxatives should be avoided. Exper w or eliminates appetite, apparently by an action on dogs and monkeys indicate that phenobarbitai the CNS. Either nervous symptoms or anorexia effective as an antidote. It has been necessary may appear first. However, appetite may occa give the drug in large doses over a period of 2 wee sionally return in animals which are extremely sick or more. The dosage which is required to keep p and which eventually die. See also chlorinated soned animals from showing hyperexcitability hydrocarbons. convulsions and which enables them to eat and b Dangerom Acute Dose in Man: The effeas of dieldrin have normally is often a dosage which would indu and aldrin are similar both quantitatively and quali sleep or even anesthesia in a normal animal of t tatively in animals as well as in man. Persons ex same species. In human beings the dosage should posed to oral dosages which exceed 10 mg/kg fre adjusted to the symptoms. quently become acutely ill. Symptoms may appear DIENESTRAL DIACETATE. Syn: 3,4-bis-{p-aceic within 20 min and in no instance has a latent period phenyl)-2,4-hexadiene. of more than 12 hrs been confirmed. No death or THR = U. A food additive permitted in the feed a; permanent sequelae have been reported following drinking water of animals, and' or for the treatme known poisoning by aldrin or dieldrin in man. In of food-producing animals. Also a food additi an attempted suicide by ingestion of dieldrin the permitted in food for human consumption. [109' 1 • dosage was estimated at 25.6 mg/ kg. The oral LDso of dieldrin for rats is 40-50 mg kg. DIEPOXY BUTANE. indicating a toxicity roughly five times that of THR = An exper care. {23] DDT. The dermal LDso of dieldrin in xylene for rats 1.2J,4-DIEPOXY BUTANE. Sec butadiene dioxide. is only slightly less than the oral toxicity (60 mg kg 1,16,7-DlEPOXY HEPTANE. CTH,:©:, mw: 128.1 for the female and 90 mg/kg for the male) indicat THR = An exper neo [3] and care. [23] ing an acute dermal toxicity roughly 40 times that of DDT. Tests with cenain other solvents indicate L15.6-DIEPOXY HEXANE. QHioO:. mw: 114.1 a factor of only six times. THR = An exper care and neo. [3, 23] Dangerous Chronic Dose: Nothing is known with cer DIEPOXY HYDRO MYRCENE. CoHi.O: , mw: tainty about the chronic toxicity of dieldrin for 170.3. man but poisoning has occurred from use of 0.5- THR = An exper neo. [3] 2.5% suspensions. Exper animals show a wide spe cies variation in their susceptibility to dieldrin. 1,18,9-DIEPOXY LIMONENE. See dipentene dio Repeated dermal applications of 10 mg or even 20 ide. mg;kg are tolerated by rats, whereas rabbits are 1.2,8,9-DIEPOXY NONANE. C.HuO:. mw: 156.3. killed by both of these dosages. Animals have THR = An exper neo. [i] shown convulsions as much as 120 days following 9,10.1113-DIEPOXY OCT.ADECANOIC ACID. the last dose of dieldrin indicating that dieldrin or C18H31O4. mw: 311.5. its derivatives and/or residual toxicant-induced in THR = An exper neo [3] to mice via dermal route. jury may persist in the body for a long time once severe poisoning has occurred. I.17.8.DIEPOXY OCTANE. Signs and Symptoms of Poisoning in Man: Early H:C0CH(CH:)4HC0CH:. mw: 141 symptoms include headache, nausea, vomiting, Acute tox data: Oral LDjo (rat) = 1070 mg, kg; derm: general malaise, and dizziness. With more severe LDso (rabbit) = 320 mg/kg. [i] poisoning, clonic and tonic convulsions ensue or THR = MOD via oral, HIGH via dermal routes. they may appear without the premonitory symp 1,14.5-DIEPOXY PENTANE. CjH^O:, mw: 100.1. toms just mentioned. Coma may or may not follow THR = .An exper care, [i, 2J] ^ For Couniermrasure Information and Abbrevialions see the Directorv at the Be(innin| of ihia Section. 100246 DIPENTYL MALEATE 621 ( tox data: Oral LDy> (rat) = 7.1 g/kg; oral LD Foe Counienncasurt Information and Abbrcviationa set the Directory at the Betinnint of this Section. 100P47 604 8,9-DIMETHYL-7,12-DIMETHYL BENZ(a)ANTHRACENE 8,9-DIMETHYL-7,12-DIMETHYLBENZ(i)AN- Acute tox data: Oral LDjo (rat) = 3000 mg/kg; inhal THRACENE. LCLO (rat) = 8000 ppm for 4 hrs. [3] THR = An exper care. [23] THR = MOD via oral and LOW via inhal routes. 9,10-DIMETHYL-7.12-DiMETHYLBENZ(*) Fire Hazard: Dangerous, when exposed to heat or ANTHRACENE. flame; can reaa vigorously with oxidizing materials. THR = An exper care. [23] To Fight Fire: Foam, CO:, dry chemical. N,N-DIMETHYL-4-[4'-<2',5'.DIMETHYLPYRIDYL- 3,6-DIMETHYL-2,5-p-DIOXANEDIONE. Syn: 1 '.OXIDE)AZO] ANILINE. lactide. Pale yellow, crystalUnc solid. C«Hi04, mw: THR = An exper neo. [3, 23] 144.1. mp:96°-I04». N,N-DIMETHYL-4-(4'-(3',5'-DIMETHYLPYRIDYL- THR = U. r-OXIDE)AZO)ANILINE. Disaster Hazard: Slight. THR = An exper neo. [3] {l6-DlMETHYL-m-DIOXAN-4-YL-ACETATE| Syns o,o-DIMETHYL-o^- For Counicrmcaiurc Information and Abbrevialiom tee the Directory tl the Betinnint of Ihii Section. 100?48 ** LITHIUM ALUMINUM DEUTERIDE 773 as a synthetic flavoring substance and adjuvant. ide, lead protoxide, lead monoxide. Tetragonal yel ( [109] low crystals. PbO, mw: 223.21, mp: 888°, d: 9.53. "NALYLOLEATE. Acute tox data: ip LDLO (rat) = 430 mg/kg. [3] THR = An exper care. [23] THR = HIGH via ip route. See lead compounds. Re acts with H:0:, Li:C2. [19] UNDANEI See 1,13,4,5,6-hexachlorocyclohexane. LITHIC ACID. See uric acid. UNOLEIC ACID. Syn: linolic acid. Colorless oil, eas ily oxidized by air, sol in ether and ethanol. LITHIUM. Silver-colored light metal, mixture of iso CH)(CH:)4CH= CHCH:CH= CH(CH2)7COOH, mw: topes Li' and Li'. Li, atwt: 6.94, mp: 179°, bp: 1317°, 280.4, d; 0.9038 @ 18°/4», mp: -12°, bp: 230° © 16 d: 0.534 @ 25°, vap. press: 1 mm @ 723°. THR = See lithium compounds for a discussion of nini. THR = LJ. Ingestion can cause nausea and vomiting. the toxicity of the lithium ion. Sec sodium for a A nutrient and/or dietary supplement food addi disoission which applies to the toxicity of metallic tive. [109] lithium. An exper teratogen. [3] LINOLIC ACID. See linolcic acid. Fire Hazard: Dangerous, when exposed to heat or LINSEED OIL. bp: 343°. mp: -19°, d: 0.93, flash p: flame. It also can reaa violently with air. As, Be, (raw oU): 432° F (CQ, flash p (boUcd): 403° F (CC), Br2, CHBr3, maleic anhydride, carbides, CO:, (CO + H:0), CBr4, CCU, Cl:, CHCI3, CrO,, CT, autoign. temp.: 650° F. CrCls, cobalt alloys, FeS, diborane, Mn alloys, THR = An allergen and a MILD irr. CH:Cl2, CH2I2. Mo:0,, Ni alloys, NbjOj, CFCI3, Fire Hazard: Slight, when exposed to heat or flame; HNO3, N:, organic matter, O:, P, Pt, rubber, sili can react with oxidizing materials. cates, NaCl, NaNO:, S, Ta205, TiO:, trichloro Spont Heating: Yes. ethylene, tetrachloroethylene, trichlorotrifluoroeth- Explosion Hazard: Violent reaaion with Cl:. [19] ane, WOj. V, V1P5, Hi'o, ZrCU, Fe alloys, CHI3, To Fight Fire: CO:, dry chemical LH2.[/9] UNTOX. S«e 1.13,4.5.6-hexachlorocyclohexane. Disaster Hazard: Dangerous; when burned, emits toxic LIQUEFIED CARBON DIOXIDE. Syn: liquid car fumes of lithium oxide and hydroxide, will react u bonic gas. Heavy gas or liquid under pressure. CO:, with water or steam to produce heat and hydrogen; mw: 44.0, mp: -56.6° (§> 3952 mm, bp: -78.5° (sub can reaa vigorously with oxidizing materials. Rc- limes), d: 1.977 g/liter (5)0°, d (liquid): I.IOK® -37°. aas with nitrogen at high temp. THR = This material is very cold and can damage To Fight Fire: Special mixtures of dry chemical, tissue exposed to it. Solid CO: goes direaly to soda ash. graphite. gaseous CO: (sublimes) which is mainly an asphyxi ant. See also carbon dioxide. LITHIUM ACETYLENE CARBIDE DIAMMINO. Disaster Hazard: Mod dangerous. UC=CH(NH3):, mw: 66.1. LIQUEFIED HYDROCARBON GAS. Syns: LP gas, THR = It will bum on contaa with CO:, Cl:. SO:, bottle gas, LPG. H:0. [19] THR = Olefinic impurities may lend a narcotic effea LITHIUM ACETYL SALICYLATE. Slightly hygro or it may act as a simple asphyxiant. scopic powder, decomp in moist air. LiC«H704. Fire Hazard: Dangerous, when exposed to heat or mw: 186.09. flame. THR = An irr material. See also lithium and aeetol. Explosion Hazard: U. Fire Hazard: Slight. Disaster Hazard: Mod dangerous; can reaa with LITHIUM ACID OXALATE. Colorless er\stals. oxidizing materials. LiHC:04 • H:0. mw: 113.98. mp: decomp. To Fight Fire: CO:, dry chemical, water spray. THR = See oxalates and lithium compounds. LIQUEFIED NONFLA.MMABLE GASES (CHARGED WITH NITROGEN, CARBON DIOX LITHIUM ALUMINATE. Syn: lithium-m-aluminate. IDE OR AIR). See specific component. White powder. LiAlO:, mw: 65.91, mp: > 1625=. d: 155 @ 25°. LIQUID CAMPHOR. See camphor oil (light.) THR = See lithium and aluminum compounds. LIQUID CARBONIC CAS. LITHIUM ALUMINUM DEUTERIDE. White jp Sec liquefied carbon dioxide. gray-white microcrystalline lumps or powder. LiAlD4, i!Qt'lD ROSIN. See tall oQ. mw: 42.0. mp: 150° with decomp (ignites in air), d: 9" HARGE. Syns: lead oxide, yellow plumbous ox- 1.02(5)25°. For Couaiermeasurt laformatioa and Abbreviation tec the Directorr al the Bcfinnini of this Section. 100249 ~^**^ ' ^ _ ._ '•" 4.t^1»«ftXACHLORO-1.4,4a.S.8,8*41EXAHYOR%1.4J>ENDO-EXO.OIME^ NAPHTHALENi Tizl _ ,.B|sastg.|fMM^ Danmx>t«; yfaeo-faeated t94«comp. A' '^1 iiiJi Wtffj VuiiiL^CiuL I of pfi^enS^*^^^" 'AutopsyTRowed^ pulmonary edema, dilation of the HEXACHLOROCYCLOHEXANE. Syns: BHC, 4r heart, fatty infiltration of the liver, and extensive DBH, benzenehexachloride. necrosis of blood vessels in the lungs, kidney and Acuic tox dau: Oral LDjo (rat) = 100 mg/kg; oral liver. LD» (wild birds) = 75 mg/kg. The use of thermal vaporizers with lindane has THR = HIGH via oral route. caused some clear-cut instances of acute poisoning. For example, two refreshment-stand operators suf 1A3,4,5,6-HEXACHL0R0CYCL0HEXANE(^). fered severe headache, nausea, and irritation of THR = An exper (±) care. [3, 5] See also y isomer. eyes, nose, and throat shortly after exposure to l^,4,5,6-HEXACHLOROCYCLOHEXANE(a). lindane vapors from a dispenser in which the in THR = An exper (+) care. [3, 5] See also y isomer. seaicide apparently became overheated. The symp i 1.24v4,5,6.fn:XACHLOROCYCLOHEXANE toms abated 2 hrs after tbe device was removed. (MIXED). Composed of 64% o, 10% fi, 13% 7, 9% Overheated lindane is more apt to cause respiratory A and 1% « isomers. Technical grade BHC. distress than lindane which is vaporized at lower THR = An exper (+) care, [i, J] temperatures. This is true because heat releases more of the compound and also causes some split 1^,4,5.6-HEXACHLORO CYCLOHEXANE (A). ting of the molecule into highly irr decomp products. Acute tox data: Oral LDjo (rat) = 1000 mg/kg. [i] On a chronic systemic basis the a, fi and y isomers THR = MOD via oral and ip routes. are exper care. Human care not definite. Has been HEXACHLOROCYCLOPENTADIENE. Yellow- to implicated in aplastic anemia. [3, 5] amber-colored liquid, pungent odor. CjCU, mw: Dermatitis, and perhaps other manifestations 27179, mp: 9.9°, bp: 239°. fp: -2°, flash p: none based on sensitivity represent a sort of chronic, (OC), d: 1.715 @ 15.5°/15.5°, vap. d: 9.41 though probably not systemic intoxication, which Acute tox data: Oral LDso (rat) = 113 mg/kg; dermal # has been observed in human beings. Dermatitis has LDso (rabbit) = 430 mg/ kg. [J] been reported in workers who came in contaa with THR = HIGH via oral and dermal routes. benzene hexachloride and its precursors during manufacture and without proper hygienic precau HEXACHLORODIBENZO-p-DIOXIN. Syn: HCDD. tions. Shortly after a lindane vaporizer was installed Coloricss solid. Ci2H:0;Cl*, mw: 390.9, mp: 239°. in her place of employment, a 35-year-old woman Acute tox data: Oral LDuo (rat) = 100 mg kg. [3] developed urticaria. The dermatitis improved dur 0.01 mg/kg in benzine was aaive in a rabbit ear ing weekends, but recurred when she returned to bioassay. Daily doses of 0.01 and 0.1 mg;kg —+ work. Patch tests were positive. Complete elimina assay in chick oedema bioassay. A teratogen. [81] tion of exposure resulted in permanent recovery. See also chlorinated dibeiuo-p-dioxins. The signs and symptoms of confirmed acute poi HEXACHLORODIPHENYL OXIDE. Lig.ht yellow, » • soning in man have paralleled those of experimental very viscous liquid. C12H4CUO, mw: 376.9, bp: i, animals. These signs and symptoms are: excitation, 230°-260° @ 8 mm. d: 1.60 (g 20° 60°, autoign. hyperirritability, loss of equilibrium, clonic-tonic temp.: 1148°F, vap. d: 13.0. convulsions, and later depression. There is some Acute tox data: Oral LDLO (guinea pig) = 50 mg kg. evidence that the pulmonary edenu and vascular collapse may be of neurogenic origin also. The [3] THR = HIGH via oral route. See closely related symptoms in animals systemically poisoned by the compound, aldrin. 7 isomer alone are essentially similar to those Fire Hazard: Low. caused by mixtures, although the onset may be earlier. Men acutely exposed to high air cone of To Fight Fire: Water sprav. fog, foam, drv chemical, lindane and its decomp products show headache, CO:. • ' • nausea, and irr of eyes, nose and throat. Disaster Hazard: Dangerous; see chlorides. Urticaria has followed exposure to lindane vapor l,2J.4.10.10-HEXACHLORO-l,4,4a.5.8,8a-HEXA- in rare instances. Unlike the signs and symptoms HYDRO-I,4.5,8-ENDO-EXO-DIMETHA.NO already mentioned, this allergic manifestation oc NAPHTHALENE. ••. • curs only in susceptible individuals, and usually only THR = .Animal exper show th^jQf tompoftnds of after a period of sensitization. this class are HIGH, causing liver injury and acne- For Counicrmaairc Information and Abbrvviatioia at« dw DirKior; at tbe B«(iiiiun| of Ibia Stction. lt02S« ^'^^^^^imM. 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Y2\Z.-5 '^B^V 1^^^>J5\a.l;^ ^ BETWEEN: -^,^ ^„.^, (^Oo^ OF: PHONE: "EvrcX^AAtx^^ Uj«^t«- C© Uc. )7^4-'ic^^ AND: J c.ti'Tt Ci>.->cle_ (NUS) DISCUSSION: X\-^gvj\rsA^ Oj Ao "TNa. ^•xva"Wv>c<- o^ QCL- COcx.VOLXX-\W< ~ Tcxac>x' ^ CX\o o\-V^r^f.\\^.>tL ' i; ^~ga<» L^^^^^A ^o^ ^t^\ Ao A-lv^L.'^'J r^'ArcQgk Cocrrb-i cJiLcji-a i-^,i,_ v O.VJ<- COq.AsiS- L ^!^Q->>^-•^ Q-^^•\Vxk; U "^ CXCCCV'dvw-^S \a ^ iA>^-v-\\^-r^ Ac -VTVS^ F-\xf qV-V^y,.^ fo^T ^ '5^J'^Z<^ cxoaxibj^-s \;ro^ A^... :^A\V<_ •:?->yy\v»—ualia—\ nog>«=' "<3^-,^.^V "^^-wAc v\ S^^-<-^^-\W>\v»t, Ny^BTO iVs-^^-r V^V"'y^r^ v ^ ^^ ^L4 tH? ^.(>H -^ «ftci^S- ^sArO^^"\Wi. ;?->r'-iA'^\s> ACTION ITEMS: TW2»r V'.l' NUS067SEVISE0 0S81 ^"^i/^t'tr r /^/^^ s^ »*«ili Ml HMt to #«ltli| W^'^tti^ 4 - r iw J • •• 55?' M • M ii«li iMi mmi} 9tm MT «t |«Hl«« irlaM OfMi fl* IBMPll* Utile mmr IM Ft* /^3' OastL^ c/tTi."^ i«««n«*. \^ iMI *IIIM Itov M - JMi IS. IHJ ^<»sli r"--" ^ID '•>^- I irti •4M«t ItMHtf f. 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