Characterization of Vanadium Flow Battery. Revised
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Electrochemical Cells
Electrochemical cells = electronic conductor If two different + surrounding electrolytes are used: electrolyte electrode compartment Galvanic cell: electrochemical cell in which electricity is produced as a result of a spontaneous reaction (e.g., batteries, fuel cells, electric fish!) Electrolytic cell: electrochemical cell in which a non-spontaneous reaction is driven by an external source of current Nils Walter: Chem 260 Reactions at electrodes: Half-reactions Redox reactions: Reactions in which electrons are transferred from one species to another +II -II 00+IV -II → E.g., CuS(s) + O2(g) Cu(s) + SO2(g) reduced oxidized Any redox reactions can be expressed as the difference between two reduction half-reactions in which e- are taken up Reduction of Cu2+: Cu2+(aq) + 2e- → Cu(s) Reduction of Zn2+: Zn2+(aq) + 2e- → Zn(s) Difference: Cu2+(aq) + Zn(s) → Cu(s) + Zn2+(aq) - + - → 2+ More complex: MnO4 (aq) + 8H + 5e Mn (aq) + 4H2O(l) Half-reactions are only a formal way of writing a redox reaction Nils Walter: Chem 260 Carrying the concept further Reduction of Cu2+: Cu2+(aq) + 2e- → Cu(s) In general: redox couple Ox/Red, half-reaction Ox + νe- → Red Any reaction can be expressed in redox half-reactions: + - → 2 H (aq) + 2e H2(g, pf) + - → 2 H (aq) + 2e H2(g, pi) → Expansion of gas: H2(g, pi) H2(g, pf) AgCl(s) + e- → Ag(s) + Cl-(aq) Ag+(aq) + e- → Ag(s) Dissolution of a sparingly soluble salt: AgCl(s) → Ag+(aq) + Cl-(aq) − 1 1 Reaction quotients: Q = a − ≈ [Cl ] Q = ≈ Cl + a + [Ag ] Ag Nils Walter: Chem 260 Reactions at electrodes Galvanic cell: -
Characterization of Battery for Energy Storage Applications – Lead Acid
Abstract #1672, 224th ECS Meeting, © 2013 The Electrochemical Society Characterization of battery for energy storage applications curves of a lead acid battery (YUASA, NP4-6). It has a – lead acid battery, lithium battery, vanadium redox normal voltage of 6 V and capacity of 4 Ah. The battery flow battery, and capacitor power was drained at 0.5 A till the cell voltage down to 3.0 V. The E-I curve was recorded by linear scanning Chih-Lung Hsieh1, Yen-Ting Liu2, Kan-Lin Hsueh2, amperometry at scanning rate of 0.01 A/s. The battery is Ju-Shei Hung3 then charge at 0.5 A for 2 hours. The SOC was assumed reached 25%. The E-I curve was then recorded. This 1. Institute of Nuclear Energy Research, Taoyuan, Taiwan procedure was carried out for SOC at 50%, 75%, and 2. Dept. Energy Eng., National United University, Miaoli, 100%. When cell voltage reached 7.0 V during charge Taiwan was considered as 100% SOC. Curves shown on Fig. 2 3. Dept. Chem. Eng., National United University, Miaoli, was measured result of laed acid battery. These curves Taiwan can be described by following equations. Where the IR accounts for internal resistance. Last term of equation [1] is the voltage cahge due to acitvation over-potential. The purpose of this study is to measure the charge/discharge characteristics of four different During Charge components for energy storage application. They are lead RT nF E E 1 iRI o ln o exp[ )]( [1] acid battery, lithium battery, vanadium redox flow battery, nF SO 2 H 4 RT [ 4 [] ] and capacitor. -
3 PRACTICAL APPLICATION BATTERIES and ELECTROLYSIS Dr
ELECTROCHEMISTRY – 3 PRACTICAL APPLICATION BATTERIES AND ELECTROLYSIS Dr. Sapna Gupta ELECTROCHEMICAL CELLS An electrochemical cell is a system consisting of electrodes that dip into an electrolyte and in which a chemical reaction either uses or generates an electric current. A voltaic or galvanic cell is an electrochemical cell in which a spontaneous reaction generates an electric current. An electrolytic cell is an electrochemical cell in which an electric current drives an otherwise nonspontaneous reaction. Dr. Sapna Gupta/Electrochemistry - Applications 2 GALVANIC CELLS • Galvanic cell - the experimental apparatus for generating electricity through the use of a spontaneous reaction • Electrodes • Anode (oxidation) • Cathode (reduction) • Half-cell - combination of container, electrode and solution • Salt bridge - conducting medium through which the cations and anions can move from one half-cell to the other. • Ion migration • Cations – migrate toward the cathode • Anions – migrate toward the anode • Cell potential (Ecell) – difference in electrical potential between the anode and cathode • Concentration dependent • Temperature dependent • Determined by nature of reactants Dr. Sapna Gupta/Electrochemistry - Applications 3 BATTERIES • A battery is a galvanic cell, or a series of cells connected that can be used to deliver a self-contained source of direct electric current. • Dry Cells and Alkaline Batteries • no fluid components • Zn container in contact with MnO2 and an electrolyte Dr. Sapna Gupta/Electrochemistry - Applications 4 ALKALINE CELL • Common watch batteries − − Anode: Zn(s) + 2OH (aq) Zn(OH)2(s) + 2e − − Cathode: 2MnO2(s) + H2O(l) + 2e Mn2O3(s) + 2OH (aq) This cell performs better under current drain and in cold weather. It isn’t truly “dry” but rather uses an aqueous paste. -
Current State and Future Prospects for Electrochemical Energy Storage and Conversion Systems
energies Review Current State and Future Prospects for Electrochemical Energy Storage and Conversion Systems Qaisar Abbas 1 , Mojtaba Mirzaeian 2,3,*, Michael R.C. Hunt 1, Peter Hall 2 and Rizwan Raza 4 1 Centre for Materials Physics, Department of Physics, Durham University, Durham DH1 3LE, UK; [email protected] (Q.A.); [email protected] (M.R.H.) 2 School of Computing, Engineering and Physical Sciences, University of the West of Scotland, Paisley PA1 2BE, UK; [email protected] 3 Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, Al-Farabi Avenue, 71, Almaty 050040, Kazakhstan 4 Clean Energy Research Lab (CERL), Department of Physics, COMSATS University Islamabad, Lahore 54000, Pakistan; [email protected] * Correspondence: [email protected] Received: 30 September 2020; Accepted: 26 October 2020; Published: 9 November 2020 Abstract: Electrochemical energy storage and conversion systems such as electrochemical capacitors, batteries and fuel cells are considered as the most important technologies proposing environmentally friendly and sustainable solutions to address rapidly growing global energy demands and environmental concerns. Their commercial applications individually or in combination of two or more devices are based on their distinguishing properties e.g., energy/power densities, cyclability and efficiencies. In this review article, we have discussed some of the major electrochemical energy storage and conversion systems and encapsulated their technological advancement in recent years. Fundamental working principles and material compositions of various components such as electrodes and electrolytes have also been discussed. Furthermore, future challenges and perspectives for the applications of these technologies are discussed. -
Elements of Electrochemistry
Page 1 of 8 Chem 201 Winter 2006 ELEM ENTS OF ELEC TROCHEMIS TRY I. Introduction A. A number of analytical techniques are based upon oxidation-reduction reactions. B. Examples of these techniques would include: 1. Determinations of Keq and oxidation-reduction midpoint potentials. 2. Determination of analytes by oxidation-reductions titrations. 3. Ion-specific electrodes (e.g., pH electrodes, etc.) 4. Gas-sensing probes. 5. Electrogravimetric analysis: oxidizing or reducing analytes to a known product and weighing the amount produced 6. Coulometric analysis: measuring the quantity of electrons required to reduce/oxidize an analyte II. Terminology A. Reduction: the gaining of electrons B. Oxidation: the loss of electrons C. Reducing agent (reductant): species that donates electrons to reduce another reagent. (The reducing agent get oxidized.) D. Oxidizing agent (oxidant): species that accepts electrons to oxidize another species. (The oxidizing agent gets reduced.) E. Oxidation-reduction reaction (redox reaction): a reaction in which electrons are transferred from one reactant to another. 1. For example, the reduction of cerium(IV) by iron(II): Ce4+ + Fe2+ ! Ce3+ + Fe3+ a. The reduction half-reaction is given by: Ce4+ + e- ! Ce3+ b. The oxidation half-reaction is given by: Fe2+ ! e- + Fe3+ 2. The half-reactions are the overall reaction broken down into oxidation and reduction steps. 3. Half-reactions cannot occur independently, but are used conceptually to simplify understanding and balancing the equations. III. Rules for Balancing Oxidation-Reduction Reactions A. Write out half-reaction "skeletons." Page 2 of 8 Chem 201 Winter 2006 + - B. Balance the half-reactions by adding H , OH or H2O as needed, maintaining electrical neutrality. -
Recent Progress in Vanadium Redox-Flow Battery Katsuji Emura1 Sumitomo Electric Industries, Ltd., Osaka, Japan
Recent Progress in Vanadium Redox-Flow Battery Katsuji Emura1 Sumitomo Electric Industries, Ltd., Osaka, Japan 1. Introduction Vanadium Redox Flow Battery (VRB) is an energy storage system that employs a rechargeable vanadium fuel cell technology. Since 1985, Sumitomo Electric Industries Ltd (SEI) has developed VRB technologies for large-scale energy storage in collaboration with Kansai Electric power Co. In 2001, SEI has developed 3MW VRB system and delivered it to a large liquid crystal display manufacturing plant. The VRB system provides 3MW of power for 1.5 seconds as UPS (Uninterruptible Power Supply) for voltage sag compensation and 1.5MW of power for 1hr as a peak shaver to reduce peak load. The VRB system has successfully compensated for 50 voltage sag events that have occurred since installation up until September 2003. 2. Principle of VRB The unique chemistry of vanadium allows it to be used in both the positive and negative electrolytes. Figure 1 shows a schematic configuration of VRB system. The liquid electrolytes are circulated through the fuel cells in a similar manner to that of hydrogen and oxygen in a hydrogen fuel cell. Similarly, the electrochemical reactions occurring within the cells can produce a current flow in an external circuit, alternatively reversing the current flow results in recharging of the electrolytes. These cell reactions are balanced by a flow of protons or hydrogen ions across the cell through a selective membrane. The selective membrane also serves as a physical barrier keeping the positive and negative vanadium electrolytes separate. Figure 2 shows a cell stack which was manufactured by SEI. -
Advances in Materials Design for All-Solid-State Batteries: from Bulk to Thin Films
applied sciences Review Advances in Materials Design for All-Solid-state Batteries: From Bulk to Thin Films Gene Yang 1, Corey Abraham 2, Yuxi Ma 1, Myoungseok Lee 1, Evan Helfrick 1, Dahyun Oh 2,* and Dongkyu Lee 1,* 1 Department of Mechanical Engineering, College of Engineering and Computing, University of South Carolina, Columbia, SC 29208, USA; [email protected] (G.Y.); [email protected] (Y.M.); [email protected] (M.L.); [email protected] (E.H.) 2 Chemical and Materials Engineering Department, Charles W. Davidson College of Engineering, San José State University, San José, CA 95192-0080, USA; [email protected] * Correspondence: [email protected] (D.O.); [email protected] (D.L.) Received: 15 June 2020; Accepted: 7 July 2020; Published: 9 July 2020 Featured Application: All solid-state lithium batteries, all solid-state thin-film lithium batteries. Abstract: All-solid-state batteries (SSBs) are one of the most fascinating next-generation energy storage systems that can provide improved energy density and safety for a wide range of applications from portable electronics to electric vehicles. The development of SSBs was accelerated by the discovery of new materials and the design of nanostructures. In particular, advances in the growth of thin-film battery materials facilitated the development of all solid-state thin-film batteries (SSTFBs)—expanding their applications to microelectronics such as flexible devices and implantable medical devices. However, critical challenges still remain, such as low ionic conductivity of solid electrolytes, interfacial instability and difficulty in controlling thin-film growth. In this review, we discuss the evolution of electrode and electrolyte materials for lithium-based batteries and their adoption in SSBs and SSTFBs. -
Advancing Focused Ion Beam Characterization for Next Generation Lithium-Ion Batteries
UC San Diego UC San Diego Electronic Theses and Dissertations Title Advancing Focused Ion Beam Characterization for Next Generation Lithium-Ion Batteries Permalink https://escholarship.org/uc/item/3sh5k04b Author Lee, Jungwoo Publication Date 2018 Peer reviewed|Thesis/dissertation eScholarship.org Powered by the California Digital Library University of California UNIVERSITY OF CALIFORNIA SAN DIEGO Advancing Focused Ion Beam Characterization for Next Generation Lithium-Ion Batteries A dissertation submitted in partial satisfaction of the requirements for the degree Doctor of Philosophy in NanoEngineering by Jungwoo Zema Lee Committee in charge: Professor Ying Shirley Meng, Chair Professor David P. Fenning Professor Eric E. Fullerton Professor Olivia A. Graeve Professor Ping Liu 2018 Copyright Jungwoo Zema Lee, 2018 All rights reserved. The Dissertation of Jungwoo Zema Lee is approved, and it is acceptable in quality and form for publication on microfilm and electronically: Chair University of California San Diego 2018 iii DEDICATION To my given and chosen family iv TABLE OF CONTENTS Signature Page ..................................................................................................................... iii Dedication ............................................................................................................................ iv Table of Contents ................................................................................................................ v List of Abbreviations ......................................................................................................... -
Chapter 13: Electrochemical Cells
March 19, 2015 Chapter 13: Electrochemical Cells electrochemical cell: any device that converts chemical energy into electrical energy, or vice versa March 19, 2015 March 19, 2015 Voltaic Cell -any device that uses a redox reaction to transform chemical potential energy into electrical energy (moving electrons) -the oxidizing agent and reducing agent are separated -each is contained in a half cell There are two half cells in a voltaic cell Cathode Anode -contains the SOA -contains the SRA -reduction reaction -oxidation takes place takes place - (-) electrode -+ electrode -anions migrate -cations migrate towards the anode towards cathode March 19, 2015 Electrons move through an external circuit from the anode to cathode Electricity is produced by the cell until one of the reactants is used up Example: A simple voltaic cell March 19, 2015 When designing half cells it is important to note the following: -each half cell needs an electrolyte and a solid conductor -the electrode and electrolyte cannot react spontaneously with each other (sometimes carbon and platinum are used as inert electrodes) March 19, 2015 There are two kinds of porous boundaries 1. Salt Bridge 2. Porous Cup · an unglazed ceramic cup · tube filled with an inert · separates solutions but electrolyte such as NaNO allows ions to pass 3 through or Na2SO4 · the ends are plugged so the solutions are separated, but ions can pass through Porous boundaries allow for ions to move between two half cells so that charge can be equalized between two half cells 2+ 2– electrolyte: Cu (aq), SO4 (aq) 2+ 2– electrolyte: Zn (aq), SO4 (aq) electrode: zinc electrode: copper March 19, 2015 Example: Metal/Ion Voltaic Cell V Co(s) Zn(s) Co2+ SO 2- 4 2+ SO 2- Zn 4 Example: A voltaic cell with an inert electrode March 19, 2015 Example Label the cathode, anode, electron movement, ion movement, and write the half reactions taking place at each half cell. -
Bipolar Nickel-Metal Hydride Battery Being Developed
Bipolar Nickel-Metal Hydride Battery Being Developed Electro Energy's bipolar nickel-metal hydride battery design layout-two parallel, 24-cell stacks. (Copyright Electro Energy; used with permission.) The NASA Lewis Research Center has contracted with Electro Energy, Inc., to develop a bipolar nickel-metal hydride battery design for energy storage on low-Earth-orbit satellites (NASA contract NAS3-27787). The objective of the bipolar nickel-metal hydride battery development program is to approach advanced battery development from a systems level while incorporating technology advances from the lightweight nickel electrode field, hydride development, and design developments from nickel-hydrogen systems. This will result in a low-volume, simplified, less-expensive battery system that is ideal for small spacecraft applications. The goals of the program are to develop a 1-kilowatt, 28-volt (V), bipolar nickel-metal hydride battery with a specific energy of 100 watt-hours per kilogram (W-hr/kg), an energy density of 250 W-hr/liter and a 5-year life in low Earth orbit at 40- percent depth-of-discharge. Electro Energy has teamed with Rhône-Poulenc, Eagle-Picher Industries, Inc., Rutgers University, and Design Automation Associates to provide a well-integrated battery design. Electro Energy is the prime contractor responsible for the overall management of the program, battery design and development, component development and testing, and cell and battery testing. Rhône-Poulenc is responsible for the metal hydride component development and improvement. Eagle-Picher is supporting component and hardware development, battery design, fabrication procedures, trade studies, and documentation. Rutgers is providing treated material for the nickel electrodes in the batteries as well as analytical support for new and cycled cell components. -
Battery Technologies for Small Scale Embeded Generation
Battery Technologies for Small Scale Embedded Generation. by Norman Jackson, South African Energy Storage Association (SAESA) Content Provider – Wikipedia et al Small Scale Embedded Generation - SSEG • SSEG is very much a local South African term for Distributed Generation under 10 Mega Watt. Internationally they refer to: Distributed generation, also distributed energy, on-site generation (OSG) or district/decentralized energy It is electrical generation and storage performed by a variety of small, grid- connected devices referred to as distributed energy resources (DER) Types of Energy storage: • Fossil fuel storage • Thermal • Electrochemical • Mechanical • Brick storage heater • Compressed air energy storage • Cryogenic energy storage (Battery Energy • Fireless locomotive • Liquid nitrogen engine Storage System, • Flywheel energy storage • Eutectic system BESS) • Gravitational potential energy • Ice storage air conditioning • Hydraulic accumulator • Molten salt storage • Flow battery • Pumped-storage • Phase-change material • Rechargeable hydroelectricity • Seasonal thermal energy battery • Electrical, electromagnetic storage • Capacitor • Solar pond • UltraBattery • Supercapacitor • Steam accumulator • Superconducting magnetic • Thermal energy energy storage (SMES, also storage (general) superconducting storage coil) • Chemical • Biological • Biofuels • Glycogen • Hydrated salts • Starch • Hydrogen storage • Hydrogen peroxide • Power to gas • Vanadium pentoxide History of the battery This was a stack of copper and zinc Italian plates, -
2020 Grid Energy Storage Technology Cost and Performance Assessment
Energy Storage Grand Challenge Cost and Performance Assessment 2020 December 2020 2020 Grid Energy Storage Technology Cost and Performance Assessment Kendall Mongird, Vilayanur Viswanathan, Jan Alam, Charlie Vartanian, Vincent Sprenkle*, Pacific Northwest National LaBoratory. Richard Baxter, Mustang Prairie Energy * [email protected] Technical Report Publication No. DOE/PA-0204 December 2020 Energy Storage Grand Challenge Cost and Performance Assessment 2020 December 2020 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States government. ii Energy Storage Grand Challenge Cost and Performance Assessment 2020 December 2020 Acronyms AC alternating current Ah ampere-hour BESS battery energy storage system BLS U.S. Bureau of Labor Statistics BMS battery management system BOP balance of plant BOS balance of system C&C controls & communication C&I civil and infrastructure CAES compressed-air energy