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Book of Abstracts LYON - FRANCE MAY 30TH - JUNE 3RD 2010 0-Index Mise En Page 1 17/05/10 16:41 Page2 0-Index_Mise en page 1 17/05/10 16:41 Page1 Book of Abstracts LYON - FRANCE MAY 30TH - JUNE 3RD 2010 0-Index_Mise en page 1 17/05/10 16:41 Page2 WELCOME FROM THE CHAIR Formerly known as the Natural Gas Con version Symposium (NGCS), the triennial No vel Gas Con version Symposium has brought together the world's leaders in synthesis gas production and utilisation since 1987 to share information on the latest trends in research and technology development in these fields. The ninth edition of the Novel Gas Conversion Symposium (“NGCS 9”) tak es place in Lyon, France from May 30th to June 3 rd, 2010, in the prestigious "Cité des Cong rès" along the Rhone ri ver. With more than 450 scientists, researchers, and industry executives from over 40 countries participating, NGCS 9 continues the tradition of high quality academic, industry, and technical interaction for which the symposia series is well known. Lyon has a rich historical and cultural heritage, with its 2000 y ear-old historic centre recognised as a UNESCO World Heritage Site. Today, this brilliant city is also fully immersed in 21st century modernity. In this respect, the choice of Lyon to host the NGCS 9 was largely motivated by its dense and dynamic industrial surroundings with large refineries, petrochemical, chemical and gas industries, strongly networked with high level public and private research centres. This is perfectly illustrated by the three co-organizers of the event, IRCELYON-CNRS-UCBL for academia, IFP for public and private research centres and Total for large companies. This Symposium Book of Abstracts includes the short abstracts of 5 plenaries lectures, 19 keynotes lectures, 115 oral presentations and 364 posters, which have been peer reviewed before selection. The extended abstracts are presented in the USB memory stick. These documents reflect the extreme interest of our worldwide scientific community for the topics encompassed by the symposium: 1. Natural gas and biogas purification (filtration, CH4/CO2 separation, sulfur and nitrogen removal, etc.) 2. Production of synthesis gas from natural gas, coal, biomass or waste; clean coal; syngas chemistry: purification, water gas shift (WGS), reverse WGS and synthetic natural gas (SNG) 3. Synfuels: Fischer-Tropsch synthesis, gas to liquids, coal to liquids, biomass to liquids, methanol, higher alcohols and DME 4. Direct-indirect conversion of methane to oxygenates, olefins, aromatics; C1-C3 intermediates to chemicals 5. Energy (IGCC, catalytic combustion, hydrogen production from C1-C4 gases) and novel concepts for feedstock activation (plasma, dense membrane, etc.) 6. Technical-economical studies, technology demonstration, industrial processes and plant operation Following the excellence requirements of all the NGCS events, particular care has been taken to balance academia and industrial participation, as well as to of fer the opportunity to participate to high quality scientists from all over the world (28 countries are represented for oral presentations). We would like to gratefully acknowledge here the efficient help of the NGCB, the ISAB, the scientific and local committees and all the institutions and companies which have supported the symposium. We wish all the participants a brilliant meeting and do hope that science and friendship will merge again to continue the strong tradition of the NGCS series. Claude Mirodatos (IRCELYON-CNRS-UCBL) Francis Luck (Total) Slavik Kasztelan (IFP) NGCS 9 Chairmen 9th Novel Gas Conversion Symposium 0-Index_Mise en page 1 17/05/10 16:41 Page3 SYMPOSIUM COMMITTEES Local Organising Committee Claude Mirodatos (IRCELYON, CNRS-UCBL, FR) - Chairman Francis Luck (TOTAL, FR) - Chairman Slavik Kasztelan (IFP, FR) - Chairman Yves Schuurman (IRCELYON, CNRS-UCBL, FR) - Vice-Chairman Marta Bausach (IRCELYON, CNRS-UCBL, FR) - Vice-Chairman and Conference Secretariat Michel Lacroix (IRCELYON, CNRS-UCBL, FR) Natural Gas Conversion Board (NGCB) Ad Punt (Shell, NL) - Chairman Anders Holmen (Norwegian University of Science & Technology, NO) - Vice-Chairman Per Bakkerud (Haldor Topsøe, DK) - Secretary Theo Fleisch (Fuel Conversion Solutions, USA) - Treasurer Gordon Kelly (Johnson Matthey Catalysts, UK) - Chairman - IFC Enrique Iglesia (University of California at Berkeley, USA) - Chairman - ISAB Carlos Apesteguia (INCAPE, AR) Xinhe Bao (Dalian Institute of Chemical Physics, CN) Alex Bell (University of California at Berkeley, USA) Krijn de Jong (University of Utrecht, NL) Jay Labinger (California Institute of Technology, USA) Claude Mirodatos (IRCELYON, CNRS-UCBL, FR) Rob Motal (Chevron, USA) Sebastian Muschelknautz (Linde, DE) Jens Rostrup-Nielsen (Haldor Topsøe, DK) Domenico Sanfilippo (IT) Lanny Schmidt (University of Minnesota, USA) David Trimm (CSIRO, AU) Wataru Ueda (Hokkaido University, JP) Steve Venables (Sasol, SA) Programme Committee (topics coordinators) David Farrusseng (IRCELYON, CNRS-UCBL, FR) Marco Tagliabue (ENI S.p.A, IT) Anders Holmen (Norwegian Univ. of Science and Technology, NO) Yves Schuurman (IRCELYON, CNRS-UCBL, FR) Andrei Khodakov (UCCS, Univ. des Sciences et Technologies de Lille, FR) Jean-Luc Duplan (IFP Lyon, FR) Alain Kiennemann (Univ. Louis Pasteur, Ecole Chimie Polymeres et Materiaux, FR) Mikhail Yu Sinev (Semenov Institute of Chemical Physics, Russian Academy of Sciences, RU) Daniel Duprez (LACCO, CNRS, Poitiers, FR) Narcis Homs (Faculty of Chemistry, Univ. of Barcelona, ES) Cristina Maretto (Total, FR) Robert Motal (Chevron, USA) Arend Hoek (Shell, NL) Lyon - France - 30 May-3 June 2010 SYMPOSIUM COMMITTEES 0-Index_Mise en page 1 17/05/10 16:41 Page4 9th Novel Gas Conversion Symposium 0-Index_Mise en page 1 17/05/10 16:41 Page1 INDEX 1 INDEX ACCORDING TO NGCS 9 SESSIONS AWARD RECIPIENT AR - Supported Cobalt Catalysts for Fischer-Tropsch Synthesis 15 PLENARY LECTURES PL1 - Structure sensitivity of methane and CO activation 19 PL2 - Direct methane conversion routes to chemicals and fuels 21 PL3 - Research on thermochemical conversion of biomass at the National Renewable Energy Laboratory 23 PL4 - Supported cobalt catalysts for Fischer-Tropsch synthesis 25 PL5 - Enabling small scale GTL 27 KEYNOTE PRESENTATIONS KN1 - Catalytic activation and functionalization of methane and ethane 31 KN2 - Core-shell-like Capsule Catalyst for One-Step Synthesis from Syngas: Spatial-Confined Effect and Shape Selectivity 31 KN3 - C-H bond activation on isolated metal centre on oxide surfaces 32 KN4 - Production of Synthesis Gas. Novel Catalysts for Low Steam: Carbon Applications 32 KN5 - Recent developments in the Fischer-Tropsch synthesis over supported cobalt catalysts 33 KN6 - Cobalt particle size effects on catalytic performance for the production of synthesis gas from ethanol steam reforming Smaller is better 33 KN7 - Deactivation and regeneration of cobalt based Fischer-Tropsch synthesis catalysts 34 KN8 - Emerging technologies for olefins production from non-conventional feedstock’s: MTO/OCP technology demonstration 34 KN9 - CH4/CO2 separations for gas upgrading by adsorption and membranes processes 35 KN10 - Pearl GTL, Development of an Integrated World Scale Complex in Qatar 35 KN11 - Bridging the gap between lab and practice in ethane oxidative dehydrogenation 36 KN12 - Natural gas: removal of main impurities and mercaptans 36 KN13 - Bio-Syngas via CHOREN’s gasification technology - Operation of BTL Demo plant and future prospects 37 KN14 - Oxidative coupling of methane: thirty years of studies. What we learned? 37 KN15 - The impact of markets on the economic viability of gas conversion technology 38 KN16 - Gaining insight into the short contact time CPO of methane through advanced experimental and modelling techniques 38 KN17 - From functionalised alkanes to hydrocarbons – MTO, MTG and beyond 39 KN18 - Selective oxidative activation of short hydrocarbons using structured reactors concepts 39 KN19 - A novel process with CO2 mitigation in plan 40 ORAL PRESENTATIONS Session I - Natural gas and biogas purification (filtration, CH4/CO2 separation, sulfur and nitrogen removal, etc) O36 - Kinetics and mechanisms of ZnO sulfidation reaction: a microstructural approach 45 O37 - Tuning the polarity of Metal-Open Frameworks for CO2 capture from Natural Gas 45 O38 - RkPSATM Gas Separation Technology by Xebec Adsorption Inc. 45 O39 - HyGenSys: a CO2 ready process for large scale H2 production 46 Session II - Production of synthesis gas from natural gas, coal, biomass or waste; clean coal; syngas chemistry: purification, water gas shift (WGS), reverse WGS and synthetic natural gas (SNG) O1 - Precious Metal Steam Reforming Catalysis: Effect of Sulphur 49 O2 - Sulphur poisoning during the catalytic partial oxidation of methane on Rh catalysts partially substituted with Pt or Pd 49 O3 - Development of monolith catalyst for catalytic partial oxidation of natural gas 49 O4 - CO2 reforming of CH4 on doped Rh/Al2O3 catalysts 50 O13 - Marked effect of mesopores for the prevention of Ni sintering and inactive carbon deposition in dry reforming of methane over ordered mesoporous Ni-Mg-Al2O3 nanocomposites 50 O14 - Reforming of tar model compounds present during biomass steam gasification by iron/olivine catalysts 50 O15 - Effect of Boron on the coking resistance of Ni/Al2O3 catalysts for the dry reforming of methane 51 O16 - Catalytic and DRIFTS study of the WGS reaction mechanism on Pt-based catalysts 51 O17 - COx free hydrogen production by water gas shift reaction in a multifunctional catalytic hollow fibre membrane reactor 51 O32 - A comparison between copper and nickel-based catalysts
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