Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Potassium permanganate ≥99 %, p.a., ACS article number: P752 date of compilation: 2015-08-17 Version: 3.1 en Revision: 2021-03-03 Replaces version of: 2020-06-10 Version: (3) SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Identification of the substance Potassium permanganate ≥99 %, p.a., ACS Article number P752 Registration number (REACH) 01-2119480139-34-xxxx Index number in CLP Annex VI 025-002-00-9 EC number 231-760-3 CAS number 7722-64-7 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Laboratory chemical Laboratory and analytical use Uses advised against: Do not use for products which come into direct contact with the skin. Do not use for products which come into contact with foodstuffs. Do not use for private purposes (household). 1.3 Details of the supplier of the safety data sheet Carl Roth GmbH + Co KG Schoemperlenstr. 3-5 D-76185 Karlsruhe Germany Telephone:+49 (0) 721 - 56 06 0 Telefax: +49 (0) 721 - 56 06 149 e-mail: [email protected] Website: www.carlroth.de Competent person responsible for the safety data :Department Health, Safety and Environment sheet: e-mail (competent person): [email protected] 1.4 Emergency telephone number Name Street Postal Telephone Website code/city National Poisons Information Beaumont Road Dublin 9 01 809 2166 https:// Centre www.poisons.ie/ Beaumont Hospital Ireland (en) Page 1 / 17 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Potassium permanganate ≥99 %, p.a., ACS article number: P752 SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP) Section Hazard class Cat- Hazard class and Hazard egory category statement 2.14 Oxidising solid 2 Ox. Sol. 2 H272 3.1O Acute toxicity (oral) 4 Acute Tox. 4 H302 3.2 Skin corrosion/irritation 1C Skin Corr. 1C H314 3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318 3.7 Reproductive toxicity 2 Repr. 2 H361d 3.9 Specific target organ toxicity - repeated exposure 2 STOT RE 2 H373 4.1A Hazardous to the aquatic environment - acute hazard 1 Aquatic Acute 1 H400 4.1C Hazardous to the aquatic environment - chronic hazard 1 Aquatic Chronic 1 H410 For full text of abbreviations: see SECTION 16 The most important adverse physicochemical, human health and environmental effects Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi- dermis and into the dermis. Delayed or immediate effects can be expected after short or long-term exposure. Spillage and fire water can cause pollution of watercourses. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 (CLP) Signal word Danger Pictograms GHS03, GHS05, GHS07, GHS08, GHS09 Hazard statements H272 May intensify fire; oxidiser H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H361d Suspected of damaging the unborn child H373 May cause damage to organs (brain) through prolonged or repeated exposure (if inhaled) H410 Very toxic to aquatic life with long lasting effects Precautionary statements Precautionary statements - prevention P220 Keep away from clothing and other combustible materials P273 Avoid release to the environment P280 Wear protective gloves/eye protection Ireland (en) Page 2 / 17 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Potassium permanganate ≥99 %, p.a., ACS article number: P752 For professional users only Labelling of packages where the contents do not exceed 125 ml Signal word: Danger Symbol(s) H314 Causes severe skin burns and eye damage. H361d Suspected of damaging the unborn child. P280 Wear protective gloves/eye protection. 2.3 Other hazards Results of PBT and vPvB assessment According to the results of its assessment, this substance is not a PBT or a vPvB. SECTION 3: Composition/information on ingredients 3.1 Substances Name of substance Potassium permanganate Molecular formula KMnO₄ g Molar mass 158 /mol REACH Reg. No 01-2119480139-34-xxxx CAS No 7722-64-7 EC No 231-760-3 Index No 025-002-00-9 Specific Conc. Limits M-Factors ATE Exposure route mg M-factor (acute) = 10.0 500 /kg oral SECTION 4: First aid measures 4.1 Description of first aid measures General notes Take off immediately all contaminated clothing. Following inhalation Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice. Following skin contact After contact with skin, wash immediately with plenty of water. Immediate medical treatment re- quired because corrosive injuries that are not treated are hard to cure. Ireland (en) Page 3 / 17 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Potassium permanganate ≥99 %, p.a., ACS article number: P752 Following eye contact In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold- ing eyelids apart and consult an ophthalmologist. Protect uninjured eye. Following ingestion Rinse mouth immediately and drink plenty of water. Rinse mouth with water (only if the person is conscious). Call a physician immediately. If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects). 4.2 Most important symptoms and effects, both acute and delayed Irritant effects, Corrosion, Risk of serious damage to eyes, Risk of blindness, Gastric perforation, Nausea, Vomiting, Gastrointestinal complaints, Cough, Dyspnoea 4.3 Indication of any immediate medical attention and special treatment needed none SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media co-ordinate firefighting measures to the fire surroundings water, foam, alcohol resistant foam, dry extinguishing powder, ABC-powder Unsuitable extinguishing media water jet 5.2 Special hazards arising from the substance or mixture Oxidising property. Non-combustible. 5.3 Advice for firefighters In case of fire and/or explosion do not breathe fumes. Do not allow firefighting water to enter drains or water courses. Fight fire with normal precautions from a reasonable distance. Wear self-contained breathing apparatus. Wear full chemical protective clothing. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not breathe dust. 6.2 Environmental precautions Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. 6.3 Methods and material for containment and cleaning up Ireland (en) Page 4 / 17 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Potassium permanganate ≥99 %, p.a., ACS article number: P752 Advice on how to contain a spill Covering of drains. Take up mechanically. Advice on how to clean up a spill Take up mechanically. Control of dust. Other information relating to spills and releases Place in appropriate containers for disposal. 6.4 Reference to other sections Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom- patible materials: see section 10. Disposal considerations: see section 13. SECTION 7: Handling and storage 7.1 Precautions for safe handling Handle and open container with care. Avoid exposure. Avoid dust formation. Clear contaminated areas thoroughly. Measures to prevent fire as well as aerosol and dust generation Removal of dust deposits. Keep away from combustible material. Measures to protect the environment Avoid release to the environment. Advice on general occupational hygiene Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs. 7.2 Conditions for safe storage, including any incompatibilities Store in a dry place. Keep container tightly closed. Keep away from combustible material. Incompatible substances or mixtures Observe hints for combined storage. Keep/store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Consideration of other advice Ventilation requirements Use local and general ventilation. Specific designs for storage rooms or vessels Recommended storage temperature: 15 – 25 °C 7.3 Specific end use(s) No information available. SECTION 8: Exposure controls/personal protection 8.1 Control parameters National limit values Ireland (en) Page 5 / 17 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Potassium permanganate ≥99 %, p.a., ACS article number: P752 Occupational exposure limit values (Workplace Exposure Limits) Coun Name of agent CAS No Identifi- TWA STEL Ceil- Nota- Source try er [mg/ [mg/ ing-C tion m³] m³] [mg/ m³] EU manganese, inorganic 7722-64-7 IOELV 0,05 r 2017/164/ compounds EU IE dusts non-specific OELV 10 i S.I. No. 619 of 2001 IE dusts non-specific OELV 4 r S.I. No. 619 of 2001 IE manganese, inorganic 7722-64-7 OELV 0,2 i S.I. No. 619 compounds of 2001 IE manganese, inorganic 7722-64-7 OELV 0,05 r S.I. No. 619 compounds of 2001 Notation Ceiling-C Ceiling value is a limit value above which exposure should not occur i Inhalable fraction r Respirable fraction STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15- minute period (unless otherwise specified) TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-weighted average (unless otherwise specified) Human health values Relevant DNELs and other threshold levels Endpoint Threshold Protection goal, Used in Exposure time level route of exposure DNEL 0,2 mg/m³ human, inhalatory worker (industry) chronic - systemic effects Environmental values Relevant PNECs and other threshold levels End- Threshold Organism Environmental com- Exposure time point level partment µg PNEC 0,06 /l aquatic organisms freshwater short-term (single instance) mg PNEC 1,64 /l aquatic organisms sewage treatment plant short-term (single instance) (STP) 8.2 Exposure controls Individual protection measures (personal protective equipment) Eye/face protection Use safety goggle with side protection.