SAFETY DATA SHEET 1. Identification Product identifier Antimony Chloride (SbCl3) Other means of identification SDS number 2EP Materion Code 2EP CAS number 10025-91-9 Synonyms ANTIMONY(III) TRICHLORIDE * Antimony chloride Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Materion Advanced Chemicals Inc. Address 407 N 13th Street 1316 W. St. Paul Avenue Milwaukee, WI 53233 United States Telephone 414.212.0257 E-mail [email protected] Contact person Laura Hamilton Emergency phone number Chemtrec 800.424.9300 2. Hazard(s) identification Physical hazards Not classified. Health hazards Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1 Specific target organ toxicity, single exposure Category 3 respiratory tract irritation Environmental hazards Hazardous to the aquatic environment, acute Category 2 hazard Hazardous to the aquatic environment, Category 2 long-term hazard OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. May cause respiratory irritation. Suspected of causing genetic defects. Suspected of damaging fertility or the unborn child. May cause damage to organs (). Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Material name: Antimony Chloride (SbCl3) SDS US 2EP Version #: 02 Revision date: 02-10-2020 Issue date: 01-15-2018 1 / 8 Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Take off contaminated clothing and wash it before reuse. Collect spillage. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information 100% of the substance consists of component(s) of unknown acute dermal toxicity. For further information, please contact the Product Stewardship Department at +1.800.862.4118. 3. Composition/information on ingredients Substances Chemical name Common name and synonyms CAS number % Antimony Chloride (SbCl3) ANTIMONY(III) TRICHLORIDE 10025-91-9 100 Antimony chloride 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a physician or poison control center immediately. Skin contact Take off immediately all contaminated clothing. Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. For minor skin contact, avoid spreading material on unaffected skin. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important May cause temporary blindness and severe eye damage. Burning pain and severe corrosive skin symptoms/effects, acute and damage. Causes serious eye damage. Corrosive effects. Symptoms may include stinging, tearing, delayed redness, swelling, and blurred vision. Permanent eye damage including blindness could result. May cause respiratory irritation. Indication of immediate medical Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water attention and special treatment immediately. While flushing, remove clothes which do not adhere to affected area. Call an needed ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Wear suitable protective equipment. and precautions for firefighters Fire fighting Water runoff can cause environmental damage. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. Material name: Antimony Chloride (SbCl3) SDS US 2EP Version #: 02 Revision date: 02-10-2020 Issue date: 01-15-2018 2 / 8 6. Accidental release measures Personal precautions, protective Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear equipment and emergency appropriate protective equipment and clothing during clean-up. Do not touch damaged containers procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Prevent entry into waterways, sewer, basements or confined areas. containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes, on skin, or on clothing. Do not taste or swallow. Do not get this material on clothing. Avoid contact during pregnancy/while nursing. Avoid prolonged exposure. When using, do not eat, drink or smoke. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Do not empty into drains. Observe good industrial hygiene practices. Conditions for safe storage, Store locked up. Store in a cool, dry place out of direct sunlight. Store in tightly closed container. including any incompatibilities Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Material Type Value Antimony Chloride (SbCl3) PEL 0.5 mg/m3 (CAS 10025-91-9) US. ACGIH Threshold Limit Values Material Type Value Antimony Chloride (SbCl3) TWA 0.5 mg/m3 (CAS 10025-91-9) US. NIOSH: Pocket Guide to Chemical Hazards Material Type Value Antimony Chloride (SbCl3) TWA 0.5 mg/m3 (CAS 10025-91-9) US. California Code of Regulations, Title 8, Section 5155. Airborne Contaminants Material Type Value Antimony Chloride (SbCl3) PEL 0.5 mg/m3 (CAS 10025-91-9) Biological limit values No biological exposure limits noted for the ingredient(s). Material name: Antimony Chloride (SbCl3) SDS US 2EP Version #: 02 Revision date: 02-10-2020 Issue date: 01-15-2018 3 / 8 Appropriate engineering controls Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear eye/face protection.